BE1025613B1 - Polybutadien-Kautschuk mit niedrigem cis-Gehalt und Zusammensetzung und aromatisches Vinylharz und Herstellungsverfahren hierfür - Google Patents
Polybutadien-Kautschuk mit niedrigem cis-Gehalt und Zusammensetzung und aromatisches Vinylharz und Herstellungsverfahren hierfür Download PDFInfo
- Publication number
- BE1025613B1 BE1025613B1 BE2017/5773A BE201705773A BE1025613B1 BE 1025613 B1 BE1025613 B1 BE 1025613B1 BE 2017/5773 A BE2017/5773 A BE 2017/5773A BE 201705773 A BE201705773 A BE 201705773A BE 1025613 B1 BE1025613 B1 BE 1025613B1
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- Belgium
- Prior art keywords
- polybutadiene rubber
- organic
- solution
- low cis
- reaction
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L47/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/05—Bimodal or multimodal molecular weight distribution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710823162.9 | 2017-09-13 | ||
CN201710823162.9A CN109485772B (zh) | 2017-09-13 | 2017-09-13 | 低顺式聚丁二烯橡胶及其制备方法和组合物以及芳族乙烯基树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
BE1025613A1 BE1025613A1 (de) | 2019-04-29 |
BE1025613B1 true BE1025613B1 (de) | 2019-05-06 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE2017/5773A BE1025613B1 (de) | 2017-09-13 | 2017-10-27 | Polybutadien-Kautschuk mit niedrigem cis-Gehalt und Zusammensetzung und aromatisches Vinylharz und Herstellungsverfahren hierfür |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP6625595B2 (zh) |
KR (1) | KR102041171B1 (zh) |
CN (1) | CN109485772B (zh) |
BE (1) | BE1025613B1 (zh) |
DE (1) | DE102017219340B3 (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109485791B (zh) * | 2017-09-13 | 2021-10-19 | 中国石油化工股份有限公司 | 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法 |
CN111978446B (zh) * | 2019-05-21 | 2023-05-09 | 中国石油化工股份有限公司 | 聚丁二烯橡胶及制备方法和应用以及芳族乙烯基树脂及制备方法 |
CN111978445B (zh) * | 2019-05-21 | 2023-05-12 | 中国石油化工股份有限公司 | 低顺式聚丁二烯橡胶及制备方法和应用以及芳族乙烯基树脂及制备方法 |
CN113493582B (zh) * | 2020-03-18 | 2023-01-31 | 中国石油化工股份有限公司 | 一种增韧剂组合物及其应用和hips树脂及abs树脂和其制备方法 |
CN113698558B (zh) * | 2020-05-20 | 2024-07-02 | 中国石油化工股份有限公司 | 丁苯共聚物及其制备方法与应用 |
CN113698520B (zh) * | 2020-05-21 | 2023-07-21 | 中国石油化工股份有限公司 | 液体聚丁二烯及其制备方法和应用以及组合物和聚合物涂层和胶粘剂和交联剂 |
CN114957562A (zh) * | 2022-07-01 | 2022-08-30 | 北方华锦化学工业股份有限公司 | 一种高光泽高抗冲聚苯乙烯复合材料及制备方法 |
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JPS61203112A (ja) * | 1985-03-05 | 1986-09-09 | Denki Kagaku Kogyo Kk | ゴム変性スチレン系樹脂の製造方法 |
JPH02191615A (ja) * | 1989-01-20 | 1990-07-27 | Japan Synthetic Rubber Co Ltd | 耐衝撃性芳香族ビニル系樹脂の製造方法 |
JPH10110085A (ja) * | 1996-10-09 | 1998-04-28 | Sumitomo Chem Co Ltd | ゴム変性スチレン系樹脂組成物及びその成形品 |
EP0924256A1 (en) * | 1996-08-21 | 1999-06-23 | Nippon Zeon Co., Ltd. | Polybutadiene rubber and impact-resistant aromatic vinyl resin compositions |
US5985997A (en) * | 1997-05-23 | 1999-11-16 | Chevron Chemical Company | In situ process for making a bimodal HIPS having both high gloss and high impact strength |
CN101613440A (zh) * | 2009-08-06 | 2009-12-30 | 上海赛科石油化工有限责任公司 | 一种高抗冲高光泽双峰聚苯乙烯材料及其制备方法 |
KR20110079177A (ko) * | 2009-12-31 | 2011-07-07 | 제일모직주식회사 | 내열특성 특성이 우수한 고충격 폴리스티렌 수지 및 그 제조 방법 |
CN106589247A (zh) * | 2015-10-16 | 2017-04-26 | 中国石油化工股份有限公司 | 低顺式聚丁二烯橡胶及其制备方法和应用 |
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US3189592A (en) * | 1962-08-23 | 1965-06-15 | Phillips Petroleum Co | Production of bimodal cispolybutadiene |
JPH075789B2 (ja) * | 1986-01-31 | 1995-01-25 | 宇部興産株式会社 | ポリブタジエンゴム組成物 |
JPH03195753A (ja) * | 1989-12-25 | 1991-08-27 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
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JPH11236411A (ja) * | 1997-12-09 | 1999-08-31 | Ube Ind Ltd | ポリブタジエンの製造法 |
AU766724B2 (en) * | 1999-05-17 | 2003-10-23 | Styron Europe Gmbh | Bimodal rubbers and rubber modified high impact monovinylidene aromatic polymers produced therefrom |
ATE465211T1 (de) * | 1999-05-19 | 2010-05-15 | Bridgestone Corp | Niedermolekulares polybutadien mit hohem cis gehalt |
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AU2003238860A1 (en) * | 2002-05-31 | 2003-12-19 | Dow Global Technologies Inc. | A two-step butadiene polymerization process for manufacturing high-cis 1,4-ploybutadiene |
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2017
- 2017-09-13 CN CN201710823162.9A patent/CN109485772B/zh active Active
- 2017-10-27 DE DE102017219340.9A patent/DE102017219340B3/de active Active
- 2017-10-27 BE BE2017/5773A patent/BE1025613B1/de active IP Right Grant
- 2017-10-27 KR KR1020170141425A patent/KR102041171B1/ko active IP Right Grant
- 2017-10-27 JP JP2017207952A patent/JP6625595B2/ja active Active
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JPS61203112A (ja) * | 1985-03-05 | 1986-09-09 | Denki Kagaku Kogyo Kk | ゴム変性スチレン系樹脂の製造方法 |
JPH02191615A (ja) * | 1989-01-20 | 1990-07-27 | Japan Synthetic Rubber Co Ltd | 耐衝撃性芳香族ビニル系樹脂の製造方法 |
EP0924256A1 (en) * | 1996-08-21 | 1999-06-23 | Nippon Zeon Co., Ltd. | Polybutadiene rubber and impact-resistant aromatic vinyl resin compositions |
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CN101613440A (zh) * | 2009-08-06 | 2009-12-30 | 上海赛科石油化工有限责任公司 | 一种高抗冲高光泽双峰聚苯乙烯材料及其制备方法 |
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Also Published As
Publication number | Publication date |
---|---|
KR102041171B1 (ko) | 2019-11-06 |
CN109485772A (zh) | 2019-03-19 |
JP6625595B2 (ja) | 2019-12-25 |
CN109485772B (zh) | 2021-10-19 |
KR20190030137A (ko) | 2019-03-21 |
JP2019052284A (ja) | 2019-04-04 |
BE1025613A1 (de) | 2019-04-29 |
DE102017219340B3 (de) | 2018-12-20 |
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Effective date: 20190506 |