BE1011940A3 - Composes stabilisants et leurs melanges, procede pour les preparer, composition les contenant et procede les utilisant. - Google Patents

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Publication number

BE1011940A3

BE1011940A3 BE9800408A BE9800408A BE1011940A3 BE 1011940 A3 BE1011940 A3 BE 1011940A3 BE 9800408 A BE9800408 A BE 9800408A BE 9800408 A BE9800408 A BE 9800408A BE 1011940 A3 BE1011940 A3 BE 1011940A3

Authority

BE

Belgium

Prior art keywords

group

formula

alkyl

substituted

compound

Prior art date

1997-05-27

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• 150000001875 compounds Chemical class 0.000 title claims abstract description 152
• 239000000203 mixture Substances 0.000 title claims description 111
• 238000000034 method Methods 0.000 title claims description 24
• 239000003381 stabilizer Substances 0.000 title abstract description 11
• 238000002360 preparation method Methods 0.000 title description 20
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 36
• 239000001257 hydrogen Substances 0.000 claims abstract description 35
• 239000011368 organic material Substances 0.000 claims abstract description 16
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 13
• 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims abstract description 9
• 230000003647 oxidation Effects 0.000 claims abstract description 8
• 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
• 229920001059 synthetic polymer Polymers 0.000 claims abstract description 7
• 230000015556 catabolic process Effects 0.000 claims abstract description 6
• 238000006731 degradation reaction Methods 0.000 claims abstract description 6
• 230000000087 stabilizing effect Effects 0.000 claims abstract description 5
• -1 piperazine-1, 4-diyl group Chemical group 0.000 claims description 160
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 63
• 125000002947 alkylene group Chemical group 0.000 claims description 38
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 36
• 125000000217 alkyl group Chemical group 0.000 claims description 33
• 150000002431 hydrogen Chemical class 0.000 claims description 21
• 238000006243 chemical reaction Methods 0.000 claims description 19
• 239000004743 Polypropylene Substances 0.000 claims description 17
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 16
• 125000003342 alkenyl group Chemical group 0.000 claims description 15
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 15
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 14
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 13
• 229920001155 polypropylene Polymers 0.000 claims description 13
• 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 12
• 125000003277 amino group Chemical group 0.000 claims description 11
• 239000003960 organic solvent Substances 0.000 claims description 11
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
• 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 10
• 125000003545 alkoxy group Chemical group 0.000 claims description 9
• 125000001183 hydrocarbyl group Chemical group 0.000 claims description 8
• 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 7
• 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 6
• 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 6
• 239000004698 Polyethylene Substances 0.000 claims description 6
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
• 229920000573 polyethylene Polymers 0.000 claims description 6
• 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 5
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 5
• 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims description 5
• 150000007529 inorganic bases Chemical class 0.000 claims description 5
• 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 4
• 229910052799 carbon Inorganic materials 0.000 claims description 4
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
• 125000004450 alkenylene group Chemical group 0.000 claims description 3
• 125000000304 alkynyl group Chemical group 0.000 claims description 3
• 125000002619 bicyclic group Chemical group 0.000 claims description 3
• 125000000392 cycloalkenyl group Chemical group 0.000 claims description 3
• 125000004956 cyclohexylene group Chemical group 0.000 claims description 3
• 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
• 238000004519 manufacturing process Methods 0.000 claims description 3
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 2
• 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims description 2
• 125000002252 acyl group Chemical group 0.000 claims description 2
• 125000004429 atom Chemical group 0.000 claims description 2
• 150000001721 carbon Chemical class 0.000 claims description 2
• JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 2
• 239000005416 organic matter Substances 0.000 abstract description 2
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• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
• 229910052757 nitrogen Inorganic materials 0.000 description 17
• 150000003254 radicals Chemical class 0.000 description 17
• 239000007858 starting material Substances 0.000 description 17
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• 150000002148 esters Chemical class 0.000 description 11
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• 239000007983 Tris buffer Substances 0.000 description 8
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• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 7
• 239000003054 catalyst Substances 0.000 description 7
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• 150000001993 dienes Chemical class 0.000 description 7
• 239000008187 granular material Substances 0.000 description 7
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• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
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• 125000004432 carbon atom Chemical group C* 0.000 description 6
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• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
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