AU730331B2 - Process for the preparation of random propylene copolymers and products obtained therefrom - Google Patents

Process for the preparation of random propylene copolymers and products obtained therefrom Download PDF

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Publication number
AU730331B2
AU730331B2 AU20397/97A AU2039797A AU730331B2 AU 730331 B2 AU730331 B2 AU 730331B2 AU 20397/97 A AU20397/97 A AU 20397/97A AU 2039797 A AU2039797 A AU 2039797A AU 730331 B2 AU730331 B2 AU 730331B2
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AU
Australia
Prior art keywords
weight
process according
content
copolymers
radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU20397/97A
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English (en)
Other versions
AU2039797A (en
Inventor
Gianni Collina
Giampiero Morini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell North America Inc
Original Assignee
Montell North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell North America Inc filed Critical Montell North America Inc
Publication of AU2039797A publication Critical patent/AU2039797A/en
Application granted granted Critical
Publication of AU730331B2 publication Critical patent/AU730331B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
AU20397/97A 1996-02-27 1997-02-25 Process for the preparation of random propylene copolymers and products obtained therefrom Ceased AU730331B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT96MI000357A IT1282691B1 (it) 1996-02-27 1996-02-27 Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti
ITMI96A000357 1996-02-27
PCT/IB1997/000336 WO1997031954A1 (en) 1996-02-27 1997-02-25 Process for the preparation of random propylene copolymers and products obtained therefrom

Publications (2)

Publication Number Publication Date
AU2039797A AU2039797A (en) 1997-09-16
AU730331B2 true AU730331B2 (en) 2001-03-01

Family

ID=11373395

Family Applications (1)

Application Number Title Priority Date Filing Date
AU20397/97A Ceased AU730331B2 (en) 1996-02-27 1997-02-25 Process for the preparation of random propylene copolymers and products obtained therefrom

Country Status (13)

Country Link
US (2) US6365685B1 (enExample)
EP (1) EP0822945B1 (enExample)
JP (1) JPH11504679A (enExample)
KR (2) KR100475760B1 (enExample)
AR (1) AR006009A1 (enExample)
AT (1) ATE236199T1 (enExample)
AU (1) AU730331B2 (enExample)
BR (1) BR9702095A (enExample)
CA (1) CA2218997A1 (enExample)
DE (1) DE69720338T2 (enExample)
ES (1) ES2193356T3 (enExample)
IT (1) IT1282691B1 (enExample)
WO (1) WO1997031954A1 (enExample)

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US6124507A (en) * 1997-12-10 2000-09-26 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
US5968865A (en) * 1997-12-10 1999-10-19 Union Carbide Chemicals & Plastics Technology Corporation Electron donor containing compositions
SG73622A1 (en) * 1998-03-11 2000-06-20 Sumitomo Chemical Co Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
US6657025B2 (en) * 2001-01-12 2003-12-02 Fina Technology, Inc. Production of ultra high melt flow polypropylene resins
EP1607433B1 (en) 2001-06-27 2016-08-10 Borealis Technology Oy Polymer film comprising a propylene random copolymer
SG99976A1 (en) * 2002-03-26 2003-11-27 Sumitomo Chemical Co Propylene-based polymer and injection molded article made of the same
JP2008508123A (ja) * 2004-07-29 2008-03-21 ビーエフエス デバーシファイド プロダクツ エルエルシー 組立用積層体
ATE435245T1 (de) † 2005-05-12 2009-07-15 Basell Poliolefine Srl Propylen-ethylen-copolymere und herstellungsverfahren dafür
ES2329422T3 (es) * 2006-04-24 2009-11-25 Total Petrochemicals Research Feluy Proceso para la produccion de polimeros de propileno que tienen un contenido bajo de cenizas.
EP2226337A1 (en) * 2009-03-02 2010-09-08 Borealis AG Process for the production of polypropylene random copolymers for injection moulding applications
KR101207628B1 (ko) 2010-01-13 2012-12-03 삼성토탈 주식회사 프로필렌 중합용 고체촉매 및 그 제조 방법
EP2644628A4 (en) 2010-11-24 2014-07-23 Samsung Total Petrochemicals SOLID CATALYST FOR POLYMERIZING PROPYLENE AND METHOD FOR THE PRODUCTION THEREOF
TWI572630B (zh) 2011-09-16 2017-03-01 班茲研發公司 疏水性眼內透鏡
US9303108B2 (en) 2011-10-29 2016-04-05 China Petroleum & Chemical Corporation Propylene random copolymer, method for its preparation, and compositions and articles containing the same
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US9522968B2 (en) * 2012-11-26 2016-12-20 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof
US9284392B2 (en) 2013-03-15 2016-03-15 Basf Corporation Mixed internal donor structures for 1-olefin polymerization catalysts
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
EP3140329B2 (en) * 2014-05-06 2026-04-29 Basell Poliolefine Italia S.r.l. Random propylene-ethylene copolymers
WO2015169652A1 (en) * 2014-05-06 2015-11-12 Basell Poliolefine Italia S.R.L. Multilayer film random propylene-ethylene copolymers
JP6307178B2 (ja) * 2014-05-06 2018-04-04 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ランダムプロピレン−エチレン共重合体及びその製造方法
KR101836008B1 (ko) 2016-12-05 2018-03-07 한화토탈 주식회사 프로필렌 중합용 촉매 및 이를 이용한 프로필렌 중합체 또는 공중합체의 제조방법
PL3802639T3 (pl) 2018-06-11 2025-04-28 W. R. Grace & Co.-Conn. Losowe kopolimery propylenu i etylenu o niskim stosunku xs/et i wysokim mfr
EP3841132A1 (en) 2018-08-22 2021-06-30 Basell Poliolefine Italia S.r.l. Random propylene-ethylene copolymers
KR102178630B1 (ko) 2018-12-20 2020-11-13 한화토탈 주식회사 프로필렌 중합용 고체 촉매 및 이를 이용한 블록 공중합체의 제조방법
JP7410184B2 (ja) * 2019-06-14 2024-01-09 スリーディー システムズ インコーポレーテッド 付加製造のためのポリプロピレン系粒子
KR102259306B1 (ko) 2019-10-21 2021-05-31 한화토탈 주식회사 프로필렌 중합용 고체 촉매의 제조 방법
CN113621098B (zh) 2020-05-09 2022-11-04 中国石油天然气股份有限公司 丙烯聚合催化剂、丙烯聚合催化剂体系及其制备与应用
KR102864236B1 (ko) 2022-10-24 2025-09-25 한화토탈에너지스 주식회사 프로필렌계 중합용 고체 촉매 및 이를 이용한 프로필렌계 중합체의 제조방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0318049A1 (en) * 1987-11-27 1989-05-31 Montell Technology Company bv New crystalline copolymers of propylene
EP0341724A1 (en) * 1988-05-12 1989-11-15 Union Carbide Corporation Process for the preparation of random copolymers
EP0362705A2 (en) * 1988-09-30 1990-04-11 Montell North America Inc. Catalysts for the polymerization of olefins

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IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
ES2052004T5 (es) * 1988-06-17 2002-05-16 Mitsui Chemicals Inc Procedimiento de preparacion de poliolefinas y catalizador de polimerizacion.
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
US5221651A (en) * 1989-04-28 1993-06-22 Himont Incorporated Component and catalysts for the polymerization of olefins
DE4011160A1 (de) * 1990-04-06 1991-10-17 Basf Ag Copolymerisate des propylens mit anderen alk-1-enen
US5618895A (en) 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes
ATE156843T1 (de) * 1990-04-13 1997-08-15 Mitsui Petrochemical Ind Festes titan enthaltendes katalysatorbestandteil und katalysator für olefinpolymerisation, vorpolymerisierte olefinpolymerisationskatalysator und verfahren für olefinpolymerisation
IT1256663B (it) * 1992-12-15 1995-12-12 Himont Inc Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto.
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TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
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JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム

Patent Citations (3)

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EP0318049A1 (en) * 1987-11-27 1989-05-31 Montell Technology Company bv New crystalline copolymers of propylene
EP0341724A1 (en) * 1988-05-12 1989-11-15 Union Carbide Corporation Process for the preparation of random copolymers
EP0362705A2 (en) * 1988-09-30 1990-04-11 Montell North America Inc. Catalysts for the polymerization of olefins

Also Published As

Publication number Publication date
JPH11504679A (ja) 1999-04-27
US20020137860A1 (en) 2002-09-26
ITMI960357A1 (it) 1997-08-27
KR100475760B1 (ko) 2005-03-14
ATE236199T1 (de) 2003-04-15
DE69720338D1 (de) 2003-05-08
US6693161B2 (en) 2004-02-17
KR100491387B1 (ko) 2005-08-31
EP0822945A1 (en) 1998-02-11
US6365685B1 (en) 2002-04-02
ES2193356T3 (es) 2003-11-01
IT1282691B1 (it) 1998-03-31
KR19990008107A (ko) 1999-01-25
AU2039797A (en) 1997-09-16
ITMI960357A0 (enExample) 1996-02-27
KR20040103975A (ko) 2004-12-09
AR006009A1 (es) 1999-07-21
BR9702095A (pt) 1999-07-20
DE69720338T2 (de) 2004-02-12
EP0822945B1 (en) 2003-04-02
CA2218997A1 (en) 1997-09-04
WO1997031954A1 (en) 1997-09-04

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