AU624024B2 - A catalyst for the catalytic gas-phase oxidation of olefins to unsaturated aldehydes - Google Patents

A catalyst for the catalytic gas-phase oxidation of olefins to unsaturated aldehydes Download PDF

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Publication number
AU624024B2
AU624024B2 AU62459/90A AU6245990A AU624024B2 AU 624024 B2 AU624024 B2 AU 624024B2 AU 62459/90 A AU62459/90 A AU 62459/90A AU 6245990 A AU6245990 A AU 6245990A AU 624024 B2 AU624024 B2 AU 624024B2
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AU
Australia
Prior art keywords
catalyst
spray
dried powder
dried
extruded
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU62459/90A
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English (en)
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AU6245990A (en
Inventor
Dietrich Arntz
Wolfgang Bock
Werner Burkhardt
Gunter Prescher
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Evonik Operations GmbH
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Degussa GmbH
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Publication of AU6245990A publication Critical patent/AU6245990A/en
Application granted granted Critical
Publication of AU624024B2 publication Critical patent/AU624024B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU62459/90A 1989-09-13 1990-09-12 A catalyst for the catalytic gas-phase oxidation of olefins to unsaturated aldehydes Ceased AU624024B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3930533A DE3930533C1 (enExample) 1989-09-13 1989-09-13
DE3930533 1989-09-13

Publications (2)

Publication Number Publication Date
AU6245990A AU6245990A (en) 1991-03-21
AU624024B2 true AU624024B2 (en) 1992-05-28

Family

ID=6389314

Family Applications (1)

Application Number Title Priority Date Filing Date
AU62459/90A Ceased AU624024B2 (en) 1989-09-13 1990-09-12 A catalyst for the catalytic gas-phase oxidation of olefins to unsaturated aldehydes

Country Status (13)

Country Link
US (1) US5082819A (enExample)
EP (1) EP0417722B1 (enExample)
JP (1) JP3145101B2 (enExample)
CN (1) CN1027045C (enExample)
AT (1) ATE97026T1 (enExample)
AU (1) AU624024B2 (enExample)
BR (1) BR9004581A (enExample)
DD (1) DD297574A5 (enExample)
DE (2) DE3930533C1 (enExample)
DK (1) DK0417722T3 (enExample)
ES (1) ES2022070T3 (enExample)
MX (1) MX174107B (enExample)
ZA (1) ZA907041B (enExample)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
FR2670686B1 (fr) * 1990-12-20 1994-08-12 Rhone Poulenc Chimie Composition catalytique pour la preparation d'aldehydes alpha,beta-insatures par oxydation d'olefines en phase gazeuse et procede d'oxydation.
FR2670685B1 (fr) * 1990-12-20 1995-03-10 Rhone Poulenc Chimie Procede de preparation de catalyseurs enrobes a base de molybdates de bismuth et de fer dopes par du phosphore et du potassium.
IT1256156B (it) * 1992-10-06 1995-11-29 Montecatini Tecnologie Srl Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide
IT1282267B1 (it) * 1995-03-14 1998-03-16 Montecatini Tecnologie Srl Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura
IT1283207B1 (it) * 1996-03-08 1998-04-16 Montecatini Tecnologie Srl Catalizzatori per la deidrogenazione di etilbenzene a stirene
US6437193B1 (en) 1997-07-15 2002-08-20 E. I. Du Pont De Nemours And Company Vapor phase oxidation of propylene to acrolein
US6281384B1 (en) 1998-06-26 2001-08-28 E. I. Du Pont Nemours And Company Vapor phase catalytic oxidation of propylene to acrylic acid
TW511105B (en) 1999-03-11 2002-11-21 Murata Manufacturing Co Method of firing magnetic core
DE69918672T2 (de) 1999-05-21 2005-07-21 Evc Technology Ag Katalysator und Oxychlorinierungsverfahren unter Verwendung derselben
US6250722B1 (en) 1999-11-09 2001-06-26 Deere & Company Two-piece hub extension
EP1184077B1 (en) * 2000-08-30 2005-10-19 Haldor Topsoe A/S Hydrotreating catalyst particles
JP4933709B2 (ja) * 2001-09-26 2012-05-16 三菱レイヨン株式会社 不飽和カルボン酸合成用触媒の製造方法
CN101066528B (zh) * 2001-11-08 2010-09-29 三菱化学株式会社 复合氧化物催化剂及其制备方法
EP2343123B1 (en) * 2001-11-08 2021-01-06 Mitsubishi Chemical Corporation METHOD FOR PREPARATION of a COMPOSITE OXIDE CATALYST
EP1386664B1 (en) 2002-07-31 2016-05-11 Ineos Technologies (Vinyls) Limited A hollow parallelepiped pellet suitable as carrier of catalysts for selective exothermic reactions
DE10344149A1 (de) * 2003-09-22 2004-04-08 Basf Ag Verfahren zur Herstellung von ringförmigen Vollkatalysatoren
MY144024A (en) * 2003-09-22 2011-07-29 Basf Ag Preparation of annular unsupported catalysts
WO2005035115A1 (en) * 2003-10-14 2005-04-21 Lg Chem, Ltd. A catalyst for gaseous partial oxidation of propylene and method for preparing the same
WO2005053844A1 (ja) 2003-12-04 2005-06-16 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸の製造用触媒の製造方法
WO2005058497A1 (ja) * 2003-12-18 2005-06-30 Mitsubishi Rayon Co., Ltd. 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒およびその製造方法ならびに不飽和アルデヒドおよび不飽和カルボン酸の製造方法
CN1917956B (zh) * 2004-02-10 2010-06-16 三菱丽阳株式会社 α,β-不饱和羧酸制造用催化剂及其制造方法,以及α,β-不饱和羧酸的制造方法
US20070173662A1 (en) 2004-02-10 2007-07-26 Mitsubishi Rayon Co., Ltd. Catalyst for producing alpha, beta-unsaturated carboxylic acid and method for preparation thereof, and method for producing alpha, beta-unsaturated carboxylic acid
JP4947756B2 (ja) * 2005-03-25 2012-06-06 三菱レイヨン株式会社 不飽和アルデヒドおよび不飽和カルボン酸合成用触媒の製造方法、並びに不飽和アルデヒドおよび不飽和カルボン酸の製造方法
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
DE102006015710A1 (de) * 2005-10-14 2007-04-26 Degussa Gmbh Mischoxidationskatalysatoren für die katalytische Gasphasenoxidation von Olefinen und Verfahren zu ihrer Herstellung
JP4749943B2 (ja) * 2006-06-13 2011-08-17 東罐興業株式会社 ホワイトアスパラ栽培用被覆フィルムとそれを用いた栽培用ハウス
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
CN102203040B (zh) * 2008-11-06 2014-04-16 日本化药株式会社 甲基丙烯酸的制造方法及甲基丙烯酸制造用催化剂
JP2011102249A (ja) * 2009-11-10 2011-05-26 Nippon Shokubai Co Ltd アクリル酸の製造方法
DE102010052126A1 (de) 2010-11-22 2012-05-24 Süd-Chemie AG Katalysatorformkörper für durchströmte Festbettreaktoren
JP5394457B2 (ja) * 2011-09-02 2014-01-22 三菱レイヨン株式会社 不飽和アルデヒドおよび不飽和カルボン酸合成用触媒、その製造方法、並びに不飽和アルデヒドおよび不飽和カルボン酸の製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
CA2860773C (en) 2012-01-13 2020-11-03 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN103524312A (zh) * 2012-07-03 2014-01-22 中国石油化工股份有限公司 制备甲基丙烯醛的方法
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
AU2013355038B2 (en) 2012-12-07 2017-11-02 Lummus Technology Llc Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
WO2015081122A2 (en) 2013-11-27 2015-06-04 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2935937A1 (en) 2014-01-08 2015-07-16 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
CA2935946C (en) 2014-01-09 2022-05-03 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3263213B1 (en) * 2015-02-27 2020-02-12 Nippon Kayaku Kabushiki Kaisha Catalyst for manufacturing unsaturated aldehyde and/or unsaturated carboxylic acid and manufacturing method of same, and manufacturing method of unsaturated aldehyde and/or unsaturated carboxylic acid
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
WO2016156042A1 (de) 2015-03-27 2016-10-06 Basf Se Katalysatorformkörper für die katalytische oxidation von so2 zu so3
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
JP6540422B2 (ja) * 2015-09-24 2019-07-10 三菱ケミカル株式会社 複合酸化物触媒
EP3786138A1 (en) 2015-10-16 2021-03-03 Lummus Technology LLC Oxidative coupling of methane
TWI781916B (zh) 2016-01-09 2022-11-01 美商阿散德性能材料營運公司 用於在丙烯腈反應器饋入流中氰化氫之直接製備的催化劑組合物及方法
EP3442934A4 (en) 2016-04-13 2019-12-11 Siluria Technologies, Inc. OXIDATIVE COUPLING OF METHANE FOR THE PRODUCTION OF OLEFIN
CN107282056B (zh) * 2016-04-13 2020-12-29 中国石油化工股份有限公司 丙烯氧化合成丙烯醛和丙烯酸的催化剂
EP3554672A4 (en) 2016-12-19 2020-08-12 Siluria Technologies, Inc. PROCEDURES AND SYSTEMS FOR CHEMICAL DEPOSITION
WO2018114900A1 (en) * 2016-12-20 2018-06-28 Shell Internationale Research Maatschappij B.V. Oxidative dehydrogenation (odh) of ethane
KR20200034961A (ko) 2017-05-23 2020-04-01 루머스 테크놀로지 엘엘씨 메탄의 산화적 커플링 공정의 통합
AU2018298234B2 (en) 2017-07-07 2022-11-17 Lummus Technology Llc Systems and methods for the oxidative coupling of methane
EP3431178A1 (de) 2017-07-20 2019-01-23 Basf Se Katalysatoren und verfahren für die katalytische oxidation von so2 zu so3
US11642666B2 (en) 2018-03-07 2023-05-09 Basf Se Shaped catalyst body in the form of tetralobes of uniform wall thickness
RU2020132866A (ru) 2018-03-07 2022-04-07 Басф Се Формованное тело катализатора в форме четырехлистника с центральным сквозным отверстием
EP3569308A1 (de) 2018-05-18 2019-11-20 Basf Se Formkörper in form von multiloben
WO2020196853A1 (ja) * 2019-03-27 2020-10-01 三菱ケミカル株式会社 触媒成形体、メタクロレイン及び／又はメタクリル酸製造用の触媒成形体、並びに、メタクロレイン及び／又はメタクリル酸の製造方法
CN112569957A (zh) * 2019-09-29 2021-03-30 中国石油化工股份有限公司 一种烯烃氧化催化剂及其制备方法和应用
WO2021211466A1 (en) 2020-04-14 2021-10-21 Kellogg Brown & Root Llc Method for catalyst production for c5-c12 paraffin's isomerization
CA3138540A1 (en) 2020-11-13 2022-05-13 Lummus Technology Llc Methods and systems for converting carbon oxides to olefins
CN118302400A (zh) 2021-08-31 2024-07-05 鲁玛斯科技有限责任公司 用于进行甲烷氧化偶联的方法和系统

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102641A2 (en) * 1982-09-06 1984-03-14 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyst for manufacturing methacrolein
EP0355664A1 (de) * 1988-08-16 1990-02-28 BASF Aktiengesellschaft Katalysator für die Oxidation und Ammonoxidation von alpha-, beta-ungesättigten Kohlenwasserstoffen

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2941007A (en) * 1957-06-10 1960-06-14 Standard Oil Co Process for the oxidation of olefins
FR2016707A1 (enExample) * 1968-08-31 1970-05-08 Degussa
JPS5498717A (en) * 1978-01-17 1979-08-03 Nippon Zeon Co Ltd Preparation of unsaturated carboxylic acid
DE3125061C2 (de) * 1981-06-26 1984-03-15 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein bzw. Methacrolein durch katalytische Oxidation von Propylen bzw. Isobutylen oder tertiär-Butanol in sauerstoffhaltigen Gasgemischen
JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
US4510261A (en) * 1983-10-17 1985-04-09 W. R. Grace & Co. Catalyst with high geometric surface area
EP0296285B1 (en) * 1987-06-24 1992-07-29 The Dow Chemical Company A dehydrogenation catalyst having improved moisture stability and a process for making the same
CN1009340B (zh) * 1986-03-24 1990-08-29 三菱油化株式会社 含钼-铋的复合氧化物催化剂的制法
DE3867249D1 (de) * 1987-02-17 1992-02-13 Nippon Catalytic Chem Ind Katalysator zur oxydation von olefin oder tertiaerem alkohol und verfahren zu seiner herstellung.
DE3740271A1 (de) * 1987-11-27 1989-06-01 Basf Ag Verfahren zur herstellung einer fuer die gasphasenoxidation von propylen zu acrolein und acrylsaeure katalytisch aktiven masse

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102641A2 (en) * 1982-09-06 1984-03-14 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyst for manufacturing methacrolein
US4511671A (en) * 1982-09-06 1985-04-16 Nippon Shokubai Kagaku Kogyo Co., Ltd. Catalyst for manufacturing methacrolein
EP0355664A1 (de) * 1988-08-16 1990-02-28 BASF Aktiengesellschaft Katalysator für die Oxidation und Ammonoxidation von alpha-, beta-ungesättigten Kohlenwasserstoffen

Also Published As

Publication number Publication date
ATE97026T1 (de) 1993-11-15
BR9004581A (pt) 1991-09-10
ES2022070A4 (es) 1991-12-01
MX174107B (es) 1994-04-21
EP0417722A1 (de) 1991-03-20
AU6245990A (en) 1991-03-21
US5082819A (en) 1992-01-21
CN1050340A (zh) 1991-04-03
DE59003442D1 (de) 1993-12-16
DK0417722T3 (da) 1996-04-22
JPH03109946A (ja) 1991-05-09
ZA907041B (en) 1991-06-26
EP0417722B1 (de) 1993-11-10
DD297574A5 (de) 1992-01-16
JP3145101B2 (ja) 2001-03-12
ES2022070T3 (es) 1994-03-01
CN1027045C (zh) 1994-12-21
DE3930533C1 (enExample) 1991-05-08

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