AU2013223391B2 - Catalyst for hydrolysis of carbonyl sulfide and hydrogen cyanide and use of titanium dioxide-based composition - Google Patents

Catalyst for hydrolysis of carbonyl sulfide and hydrogen cyanide and use of titanium dioxide-based composition Download PDF

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Publication number
AU2013223391B2
AU2013223391B2 AU2013223391A AU2013223391A AU2013223391B2 AU 2013223391 B2 AU2013223391 B2 AU 2013223391B2 AU 2013223391 A AU2013223391 A AU 2013223391A AU 2013223391 A AU2013223391 A AU 2013223391A AU 2013223391 B2 AU2013223391 B2 AU 2013223391B2
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AU
Australia
Prior art keywords
titanium dioxide
catalyst
hydrolysis
active component
hydrogen cyanide
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Ceased
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AU2013223391A
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AU2013223391A1 (en
Inventor
Shuji Fujii
Koji Higashino
Makoto Susaki
Toshinobu Yasutake
Masanao Yonemura
Kaori Yoshida
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Mitsubishi Heavy Industries Engineering Ltd
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Mitsubishi Heavy Industries Engineering Ltd
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Assigned to Mitsubishi Heavy Industries Engineering, Ltd. reassignment Mitsubishi Heavy Industries Engineering, Ltd. Request for Assignment Assignors: MITSUBISHI HEAVY INDUSTRIES, LTD.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/25—Nitrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2042—Barium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
AU2013223391A 2012-02-24 2013-02-14 Catalyst for hydrolysis of carbonyl sulfide and hydrogen cyanide and use of titanium dioxide-based composition Ceased AU2013223391B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012038796A JP5955026B2 (ja) 2012-02-24 2012-02-24 硫化カルボニルおよびシアン化水素の加水分解用触媒ならびに酸化チタン系組成物の使用
JP2012-038796 2012-02-24
PCT/JP2013/053524 WO2013125437A1 (ja) 2012-02-24 2013-02-14 硫化カルボニルおよびシアン化水素の加水分解用触媒ならびに酸化チタン系組成物の使用

Publications (2)

Publication Number Publication Date
AU2013223391A1 AU2013223391A1 (en) 2014-08-14
AU2013223391B2 true AU2013223391B2 (en) 2016-06-02

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AU2013223391A Ceased AU2013223391B2 (en) 2012-02-24 2013-02-14 Catalyst for hydrolysis of carbonyl sulfide and hydrogen cyanide and use of titanium dioxide-based composition

Country Status (8)

Country Link
US (1) US9878310B2 (enExample)
EP (1) EP2818240B1 (enExample)
JP (1) JP5955026B2 (enExample)
CN (1) CN104039440A (enExample)
AU (1) AU2013223391B2 (enExample)
DK (1) DK2818240T3 (enExample)
PL (1) PL2818240T3 (enExample)
WO (1) WO2013125437A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6147663B2 (ja) 2013-12-27 2017-06-14 三菱重工業株式会社 Ｃｏｓ転換触媒の触媒再生方法
EA039851B1 (ru) 2016-09-13 2022-03-21 8 Риверз Кэпитл, Ллк Система и способ выработки энергии с использованием частичного окисления
JP7039286B2 (ja) * 2017-12-27 2022-03-22 三菱重工エンジニアリング株式会社 硫化カルボニルの加水分解用触媒及びその製造方法
JP7051451B2 (ja) * 2018-01-12 2022-04-11 三菱重工エンジニアリング株式会社 硫化カルボニルの加水分解用触媒及びその製造方法
JP7016734B2 (ja) 2018-03-14 2022-02-07 三菱重工エンジニアリング株式会社 ガス精製装置
CN109248692B (zh) * 2018-08-22 2021-06-18 昆明理工大学 一种氰化氢水解增效催化剂的制备方法及应用
CN110639494A (zh) * 2019-10-31 2020-01-03 北京北科环境工程有限公司 一种高炉煤气羰基硫水解剂及其制备方法
WO2021226052A1 (en) * 2020-05-06 2021-11-11 Basf Corporation Control of sox emissions during catalyst manufacture
CN113145104A (zh) * 2021-04-21 2021-07-23 山西普丽环境工程股份有限公司 一种水解脱硫催化剂的制备方法
CN114367279B (zh) * 2021-12-31 2024-06-25 东南大学 高炉煤气精脱硫的低温抗中毒水解催化剂及其制备方法
CN114196448B (zh) * 2022-02-16 2022-05-10 北京中航天业科技有限公司 一种全流程干式高炉煤气精脱硫系统及方法
CN117258774B (zh) * 2023-11-20 2024-01-16 淄博鲁源工业催化剂有限公司 一种高压羰基硫水解催化剂及其制法

Citations (3)

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Publication number Priority date Publication date Assignee Title
US5466427A (en) * 1993-07-14 1995-11-14 Cabot Corporation Catalysis and treatment of gases with the catalysts
JPH11276897A (ja) * 1998-03-30 1999-10-12 Mitsubishi Heavy Ind Ltd 硫化カルボニルの加水分解触媒及び加水分解方法
US20040247507A1 (en) * 2001-10-09 2004-12-09 Christophe Nedez Use of a tiO2 composition as catalyst for hydrolyzing cos and/or hcn

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US4511668A (en) * 1983-10-25 1985-04-16 Catalysts & Chemicals Industries Co., Ltd. Catalyst for use in hydrolysis of carbonyl sulfide
DE4431788A1 (de) * 1994-09-07 1996-03-14 Huels Chemische Werke Ag Katalysator und Verfahren zur Zersetzung von HCN in Gasen
US5922294A (en) * 1997-03-10 1999-07-13 Ford Global Technologies, Inc. High surface area, thermally stabilized titania automotive catalyst support
JPH1199319A (ja) 1997-07-28 1999-04-13 Petroleum Energy Center Found 排ガス浄化方法
US6956006B1 (en) * 1998-02-24 2005-10-18 Rotem Amfert Negev Ltd. Modified titanium dioxide and a method for its preparation
JP4436068B2 (ja) 2003-04-30 2010-03-24 株式会社クリーンコールパワー研究所 石炭ガス化プラント、および石炭ガス化方法、および石炭ガス化発電プラント、並びに石炭ガス化プラントの増設設備
CN101239319B (zh) * 2008-03-17 2010-12-29 中国石油大学(北京) 羰基硫水解催化剂
JP2010209296A (ja) * 2009-03-12 2010-09-24 Chiyoda Kako Kensetsu Kk 原料ガス中の有機硫黄化合物の除去方法及びそれに使用する触媒

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5466427A (en) * 1993-07-14 1995-11-14 Cabot Corporation Catalysis and treatment of gases with the catalysts
JPH11276897A (ja) * 1998-03-30 1999-10-12 Mitsubishi Heavy Ind Ltd 硫化カルボニルの加水分解触媒及び加水分解方法
US20040247507A1 (en) * 2001-10-09 2004-12-09 Christophe Nedez Use of a tiO2 composition as catalyst for hydrolyzing cos and/or hcn

Also Published As

Publication number Publication date
JP2013173099A (ja) 2013-09-05
EP2818240A4 (en) 2015-10-14
EP2818240B1 (en) 2020-06-17
US20140369915A1 (en) 2014-12-18
CN104039440A (zh) 2014-09-10
JP5955026B2 (ja) 2016-07-20
WO2013125437A1 (ja) 2013-08-29
PL2818240T3 (pl) 2021-01-11
DK2818240T3 (da) 2020-08-17
EP2818240A1 (en) 2014-12-31
US9878310B2 (en) 2018-01-30
AU2013223391A1 (en) 2014-08-14

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