ATE465868T1 - Laminierte struktur und verfahren zu ihrer herstellung - Google Patents
Laminierte struktur und verfahren zu ihrer herstellungInfo
- Publication number
- ATE465868T1 ATE465868T1 AT00986863T AT00986863T ATE465868T1 AT E465868 T1 ATE465868 T1 AT E465868T1 AT 00986863 T AT00986863 T AT 00986863T AT 00986863 T AT00986863 T AT 00986863T AT E465868 T1 ATE465868 T1 AT E465868T1
- Authority
- AT
- Austria
- Prior art keywords
- layer
- green
- shrinkage rate
- edge strip
- laminated structure
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000463 material Substances 0.000 abstract 5
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
- B32B37/0015—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid warp or curl
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/016—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on manganites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/734—Dimensional stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
- B32B2315/02—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/34—Oxidic
- C04B2237/345—Refractory metal oxides
- C04B2237/348—Zirconia, hafnia, zirconates or hafnates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/52—Pre-treatment of the joining surfaces, e.g. cleaning, machining
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/56—Using constraining layers before or during sintering
- C04B2237/561—Constraining layers not covering the whole surface of the layers to be sintered, e.g. constraining layers with holes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/56—Using constraining layers before or during sintering
- C04B2237/565—Using constraining layers before or during sintering made of refractory metal oxides, e.g. zirconia
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/58—Forming a gradient in composition or in properties across the laminate or the joined articles
- C04B2237/586—Forming a gradient in composition or in properties across the laminate or the joined articles by joining layers or articles of the same composition but having different densities
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/68—Forming laminates or joining articles wherein at least one substrate contains at least two different parts of macro-size, e.g. one ceramic substrate layer containing an embedded conductor or electrode
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/70—Forming laminates or joined articles comprising layers of a specific, unusual thickness
- C04B2237/702—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the constraining layers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/70—Forming laminates or joined articles comprising layers of a specific, unusual thickness
- C04B2237/704—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the ceramic layers or articles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Sustainable Energy (AREA)
- Quality & Reliability (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPQ4921A AUPQ492199A0 (en) | 1999-12-30 | 1999-12-30 | Laminated structure and method of forming same |
| PCT/AU2000/001560 WO2001049485A1 (en) | 1999-12-30 | 2000-12-19 | Laminated structure and method of forming same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE465868T1 true ATE465868T1 (de) | 2010-05-15 |
Family
ID=3819057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00986863T ATE465868T1 (de) | 1999-12-30 | 2000-12-19 | Laminierte struktur und verfahren zu ihrer herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7045239B2 (enExample) |
| EP (1) | EP1255641B1 (enExample) |
| JP (1) | JP4845315B2 (enExample) |
| AT (1) | ATE465868T1 (enExample) |
| AU (1) | AUPQ492199A0 (enExample) |
| CA (1) | CA2395060C (enExample) |
| DE (1) | DE60044304D1 (enExample) |
| WO (1) | WO2001049485A1 (enExample) |
| ZA (1) | ZA200205067B (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4252453B2 (ja) * | 2001-09-26 | 2009-04-08 | 日本碍子株式会社 | 電気化学セルおよびその製造方法 |
| JP4923407B2 (ja) * | 2004-01-16 | 2012-04-25 | 三菱マテリアル株式会社 | 固体酸化物形燃料電池の製造方法 |
| CN101855767A (zh) | 2007-11-13 | 2010-10-06 | 博隆能源股份有限公司 | 针对较长寿命和较高电力设计的电解质支撑型电池 |
| US9246184B1 (en) | 2007-11-13 | 2016-01-26 | Bloom Energy Corporation | Electrolyte supported cell designed for longer life and higher power |
| EP2083465B1 (en) * | 2008-01-23 | 2012-08-01 | Institute of Nuclear Energy Research | A Process for Fabrication of a Fully Dense Electrolyte layer embedded in membrane electrolyte assembly of solid oxide fuel cell |
| JP4960903B2 (ja) * | 2008-02-27 | 2012-06-27 | 本田技研工業株式会社 | 積層体の検査方法、検査装置及び検査プログラム |
| JP5428178B2 (ja) * | 2008-03-28 | 2014-02-26 | 大日本印刷株式会社 | 固体酸化物形燃料電池の製造方法、及び積層体 |
| JP2009245717A (ja) * | 2008-03-31 | 2009-10-22 | Dainippon Printing Co Ltd | 固体酸化物形燃料電池の製造方法、この方法により製造された固体酸化物形燃料電池、及び固体酸化物形燃料電池用電解質・電極積層体 |
| JP5932232B2 (ja) * | 2011-03-25 | 2016-06-08 | 株式会社日本触媒 | アノード支持型ハーフセル及びこれを用いたアノード支持型セル、並びにアノード支持型ハーフセルの製造方法 |
| KR101351221B1 (ko) | 2011-09-21 | 2014-01-14 | 한국전력공사 | 테이프 캐스팅을 이용한 지지체식 코팅막의 제조방법 |
| US9206086B2 (en) | 2012-04-18 | 2015-12-08 | Nitto Denko Corporation | Method and apparatus for sintering flat ceramics |
| US9205571B2 (en) | 2012-04-18 | 2015-12-08 | Nitto Denko Corporation | Method and apparatus for sintering flat ceramics |
| JP5973377B2 (ja) * | 2013-04-24 | 2016-08-23 | 株式会社ノリタケカンパニーリミテド | 固体酸化物形燃料電池用グリーンシートおよびその製造方法 |
| JP5699347B2 (ja) * | 2013-09-12 | 2015-04-08 | 大日本印刷株式会社 | 固体酸化物形燃料電池、及び、固体酸化物形燃料電池の製造方法 |
| JP6162572B2 (ja) * | 2013-10-25 | 2017-07-12 | 日本特殊陶業株式会社 | 固体酸化物形燃料電池単セルの製造方法及び固体酸化物形燃料電池スタックの製造方法 |
| US9673470B2 (en) | 2014-01-22 | 2017-06-06 | King Fahd University Of Petroleum And Minerals | Electrolyte layer having a patchwork-type nanoporous grain boundary and a method of preparation thereof |
| JP6443662B2 (ja) * | 2014-10-21 | 2018-12-26 | 日産自動車株式会社 | 燃料電池セルの製造方法 |
| US10347930B2 (en) | 2015-03-24 | 2019-07-09 | Bloom Energy Corporation | Perimeter electrolyte reinforcement layer composition for solid oxide fuel cell electrolytes |
| JP6060297B2 (ja) * | 2016-04-28 | 2017-01-11 | 株式会社日本触媒 | アノード支持型ハーフセル及びこれを用いたアノード支持型セル |
| CN116826101A (zh) | 2022-03-26 | 2023-09-29 | 博隆能源股份有限公司 | 用于防止大占地面积固体氧化物燃料电池柱中的热致应力裂纹的方法和装置 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3879509A (en) | 1971-09-07 | 1975-04-22 | Gilbert James Elderbaum | Method of producing thin ceramic sheets with minimal distortion |
| NL7310168A (nl) * | 1973-07-20 | 1975-01-22 | Hitachi Ltd | Werkwijze voor de vervaardiging van een samen- gestelde gesinterde structuur. |
| CH626314A5 (en) * | 1976-09-02 | 1981-11-13 | Gail Tonwerke Wilhelm | Ceramic veneer |
| JPH037086Y2 (enExample) * | 1986-01-29 | 1991-02-21 | ||
| US5130067A (en) * | 1986-05-02 | 1992-07-14 | International Business Machines Corporation | Method and means for co-sintering ceramic/metal mlc substrates |
| JPS63112473A (ja) * | 1986-10-28 | 1988-05-17 | 太陽誘電株式会社 | セラミツク基板の製造方法 |
| US4883497A (en) * | 1988-03-28 | 1989-11-28 | Arch Development Corporation | Formation of thin walled ceramic solid oxide fuel cells |
| JPH037086A (ja) * | 1989-05-31 | 1991-01-14 | Sanken Electric Co Ltd | モータ制御方法 |
| JPH03271165A (ja) * | 1990-03-20 | 1991-12-03 | Fujitsu General Ltd | シート積層体の焼成方法 |
| JPH04298964A (ja) | 1991-03-27 | 1992-10-22 | Ngk Insulators Ltd | 固体電解質型燃料電池及びその製造方法 |
| JP2945157B2 (ja) | 1991-03-27 | 1999-09-06 | 日本碍子株式会社 | 固体電解質型燃料電池及びその製造方法 |
| JPH04298963A (ja) * | 1991-03-27 | 1992-10-22 | Ngk Insulators Ltd | 固体電解質型燃料電池及びその製造方法 |
| JP3413880B2 (ja) * | 1993-07-16 | 2003-06-09 | 松下電器産業株式会社 | 多層セラミック焼結体の製造方法 |
| JPH07335239A (ja) * | 1994-06-08 | 1995-12-22 | Ngk Insulators Ltd | 接合体の製造方法 |
| DE19512146A1 (de) * | 1995-03-31 | 1996-10-02 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von schwindungsangepaßten Keramik-Verbundwerkstoffen |
| JP3230423B2 (ja) * | 1995-09-12 | 2001-11-19 | 日本電信電話株式会社 | 中空平板状電極基板およびその製造方法 |
| US5670270A (en) * | 1995-11-16 | 1997-09-23 | The Dow Chemical Company | Electrode structure for solid state electrochemical devices |
| JPH09143512A (ja) * | 1995-11-29 | 1997-06-03 | Chichibu Onoda Cement Corp | 多層焼結体の製造方法 |
| JP3492492B2 (ja) * | 1996-06-14 | 2004-02-03 | 日本碍子株式会社 | セラミックダイヤフラム構造体の製造方法 |
| DE69707359T2 (de) | 1996-06-14 | 2002-06-27 | Ngk Insulators, Ltd. | Verfahren zur Herstellung einer keramischen Membranstruktur |
| JPH10167842A (ja) * | 1996-12-16 | 1998-06-23 | Sumitomo Kinzoku Erekutorodebaisu:Kk | 拘束層用セラミックグリーンシート及びこれを用いたセラミック基板の製造方法 |
| US5935727A (en) | 1997-04-10 | 1999-08-10 | The Dow Chemical Company | Solid oxide fuel cells |
| AUPO724997A0 (en) * | 1997-06-10 | 1997-07-03 | Ceramic Fuel Cells Limited | A fuel cell assembly |
| JP4300493B2 (ja) * | 1998-06-05 | 2009-07-22 | 日立金属株式会社 | セラミック積層体及びその製造方法 |
| US6458170B1 (en) * | 1998-12-03 | 2002-10-01 | The Regents Of The University Of California | Method for making thin, flat, dense membranes on porous substrates |
-
1999
- 1999-12-30 AU AUPQ4921A patent/AUPQ492199A0/en not_active Abandoned
-
2000
- 2000-12-19 DE DE60044304T patent/DE60044304D1/de not_active Expired - Lifetime
- 2000-12-19 CA CA002395060A patent/CA2395060C/en not_active Expired - Fee Related
- 2000-12-19 US US10/169,386 patent/US7045239B2/en not_active Expired - Fee Related
- 2000-12-19 EP EP00986863A patent/EP1255641B1/en not_active Expired - Lifetime
- 2000-12-19 JP JP2001549832A patent/JP4845315B2/ja not_active Expired - Fee Related
- 2000-12-19 AT AT00986863T patent/ATE465868T1/de not_active IP Right Cessation
- 2000-12-19 WO PCT/AU2000/001560 patent/WO2001049485A1/en not_active Ceased
-
2002
- 2002-06-24 ZA ZA200205067A patent/ZA200205067B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AUPQ492199A0 (en) | 2000-02-03 |
| EP1255641A4 (en) | 2005-01-12 |
| US7045239B2 (en) | 2006-05-16 |
| JP2003519023A (ja) | 2003-06-17 |
| CA2395060C (en) | 2008-07-08 |
| JP4845315B2 (ja) | 2011-12-28 |
| US20030129460A1 (en) | 2003-07-10 |
| EP1255641B1 (en) | 2010-04-28 |
| WO2001049485A1 (en) | 2001-07-12 |
| ZA200205067B (en) | 2003-10-07 |
| DE60044304D1 (de) | 2010-06-10 |
| CA2395060A1 (en) | 2001-07-12 |
| EP1255641A1 (en) | 2002-11-13 |
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