AR036105A1 - Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos - Google Patents

Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos

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Publication number
AR036105A1
AR036105A1 ARP020102347A ARP020102347A AR036105A1 AR 036105 A1 AR036105 A1 AR 036105A1 AR P020102347 A ARP020102347 A AR P020102347A AR P020102347 A ARP020102347 A AR P020102347A AR 036105 A1 AR036105 A1 AR 036105A1
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AR
Argentina
Prior art keywords
formula
substituted
compound
alkyl
compounds
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Application number
ARP020102347A
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English (en)
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Aventis Cropscience Gmbh
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Publication of AR036105A1 publication Critical patent/AR036105A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/643—2-Phenoxypyridines; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/69—Two or more oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Piridinas sustituidas que tienen la fórmula (1) y/o sus sales, en la cual: R1, iguales o diferentes entre sí, son H, halógeno, CN, nitro, SF5, alquilo C1-8, alquenilo C2-8, alquinilo C2-8, alcoxi C1-8, [alquil C1-8]-carbonilo o alquilsulfonilo C1-8, donde cada uno de los seis radicales mencionados en último término no está sustituido o está sustituido; S(O)p-R7, donde p = 0, 1 ó 2 y R7 es alquilo C1-8, haloalquilo C1-8 o NR8R9, donde R8 y R9, independientemente entre sí, representan H, alquilo C1-8, alquenilo C2-8, arilalquilo C7-10, alquilarilo C7-10 o arilo C6-10, donde cada uno de los cinco radicales mencionados en último término no está sustituido o está sustituido, o es un grupo de la fórmula (2) en la cual R10 es alquilo C1-8 no sustituido o sustituido, y W = O ó S; A es arilo opcionalmente sustituido o un radical heterocíclico opcionalmente sustituido; X es O ó S; R2, R3, R4, R5, iguales o diferentes entre sí, son, H, halógeno, CN, alcoxi C1-8 o alquilo C1-8, donde cada uno de ambos radicales mencionados en último término no está sustituido o está sustituido; m es 0 ó 1; R6 es H, alquilo C1-8, alcoxi C1-8, alquenilo C2-8 o alquinilo C2-8, donde cada uno de los cuatro radicales mencionados en último término no están sustituidos o están sustituidos, o es hidroxi o un radical acilo; y B es un radical acilo; o B y R6 forman conjuntamente una cadena de 5 o 6 miembros, con la excepción de la N-hidroxi-N[(6-fenoxi-2-piridil)metil]-acetamida y sus sales; agente herbicida o regulador del crecimiento de las plantas, procedimiento para combatir las plantas perjudiciales o para la regulación del crecimiento de las plantas de cultivo, su utilización como herbicidas y como reguladores del crecimiento de las plantas, y procedimiento para la preparación de dichos compuestos. Estos compuestos son adecuados por ejemplo como herbicidas y reguladores del crecimiento. Además presentan una efectividad herbicida destacada contra un amplio espectro de importantes plantas perjudiciales monocotiledóneas y dicotiledóneas. También son bien controladas las malezas perennes difíciles de combatir, que se propagan por rizomas, racimos de raíces, u otros órganos duraderos. Al respecto estos compuestos pueden ser aplicados en el procedimiento antes del sembrado, antes del brote desde la tierra o después de dicho brote. Un procedimiento para la preparación de un compuesto de fórmula (1) y/o de sus sales, de acuerdo con una o más de las reivindicaciones 1 a 6; caracterizado porque: a) un compuesto de la fórmula (3), en la cual los radicales R1 son como se definen en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6 y L es un grupo de partida o un grupo de la fórmula A-X-, donde A y X tal como se definen en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6, se alquila y a continuación se hace reaccionar con cianuro, obteniéndose un nitrilo de la fórmula general (4), en la cual R1 y L son como se define para la fórmula (1); b) el compuesto de la fórmula (4), en la cual L representa un grupo de partida, se hace reaccionar con un compuesto A-X-H y/o sus sales, en la cual A y X son como se define para la fórmula (1) de acuerdo con uno o más de las reivindicaciones 1 a 6, obteniéndose un compuesto de la fórmula (4), en la cual L representa un grupo de la fórmula A-X-; c) el compuesto obtenido de la fórmula general (4); obtenido en el paso a) o b), en el cual L representa un grupo A-X- y en la cual A, X y R1 son tal como se define en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6, se convierte por reducción en el compuesto amino de la fórmula general (5) en la cual R1, R2, R3, A y X son como se define en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6; y a continuación: d1) el compuesto de la fórmula (5) se convierte por reacción con reactivos de acilación, obteniéndose un compuesto de la fórmula (1), en la cual R6 = H, m = 0 y A, X, R1, R2, R3 y B son como se definen para la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6; y opcionalmente los compuestos de la fórmula (1) en la cual R6 = H, se acilan a continuación; o d2) el compuesto de la fórmula (5) se alquila de manera reductiva con aldehidos, y a continuación se acila.
ARP020102347A 2001-06-23 2002-06-21 Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos AR036105A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10130397A DE10130397A1 (de) 2001-06-23 2001-06-23 Herbizide substituierte Pyridine, Verfahren zu ihrer Herstellung und ihre Verwendung als Herbzide und Pflanzenwachstumsregulatoren

Publications (1)

Publication Number Publication Date
AR036105A1 true AR036105A1 (es) 2004-08-11

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ARP020102347A AR036105A1 (es) 2001-06-23 2002-06-21 Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos

Country Status (20)

Country Link
US (1) US6794336B2 (es)
EP (1) EP1401827A2 (es)
JP (1) JP2004536094A (es)
KR (1) KR20040010775A (es)
CN (1) CN1520407A (es)
AR (1) AR036105A1 (es)
AU (1) AU2002319249B2 (es)
BR (1) BR0210638A (es)
CA (1) CA2451354A1 (es)
CZ (1) CZ20033547A3 (es)
DE (1) DE10130397A1 (es)
IL (1) IL159503A0 (es)
MX (1) MXPA03011782A (es)
PL (1) PL367131A1 (es)
RU (1) RU2304141C2 (es)
SK (1) SK15692003A3 (es)
TW (1) TWI259057B (es)
UA (1) UA76476C2 (es)
WO (1) WO2003000679A2 (es)
ZA (1) ZA200309245B (es)

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