AR026638A1 - Procedimiento para llevar a cabo condensaciones aldolicas cataliticas por medio de una reaccion multifase, y el uso de los productos de la condensacionaldolica para preparar alcoholes, plastificantes, detergentes, solventes o acidos carboxilicos saturados - Google Patents

Procedimiento para llevar a cabo condensaciones aldolicas cataliticas por medio de una reaccion multifase, y el uso de los productos de la condensacionaldolica para preparar alcoholes, plastificantes, detergentes, solventes o acidos carboxilicos saturados

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Publication number
AR026638A1
AR026638A1 ARP000106271A ARP000106271A AR026638A1 AR 026638 A1 AR026638 A1 AR 026638A1 AR P000106271 A ARP000106271 A AR P000106271A AR P000106271 A ARP000106271 A AR P000106271A AR 026638 A1 AR026638 A1 AR 026638A1
Authority
AR
Argentina
Prior art keywords
products
condensation
aldehydes
procedure
catalytic
Prior art date
Application number
ARP000106271A
Other languages
English (en)
Original Assignee
Oxeno Olefinchemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7930808&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR026638(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Oxeno Olefinchemie Gmbh filed Critical Oxeno Olefinchemie Gmbh
Publication of AR026638A1 publication Critical patent/AR026638A1/es

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un procedimiento para la condensacion aldolica catalítica de aldehidos por medio de una reaccion multifase en un reactor tubular, donde el catalizador estápresente en la fase continua y al menos un aldehido está presente en una fase dispersa y el fac tor de carga B del reactor tubular es igual o mayor que 0,8. Losproductos de condensacion aldolica obtenidos de este modo pueden usarse para preparar alcoholes o ácidos carboxílicos. Técnicamente, el procedimiento descritomás arriba brinda los siguie ntes beneficios para un proceso multifase: Generacion de una alta y estable transferencia de masas entre las fases participantes;Simple de realizar, tanto como sea posible con los aparatos industriales convencionales; Una disipacion del calor simple y confiable; Una alta seguridadoperativa; Una forma simple y confiable de medicion. Respecto a la realizacion de la preparacion de aldehídos alfa, beta insaturados por condensacion aldolica,se agregan las ventajas siguientes: Alta selectividad evitan do, en particular, los subproductos de alto punto de ebullicion; Supresion de la reaccion deCannizzaro y, por lo tanto, sin descarga catalítica (o muy leve); Alto rendimiento espacio-tiempo, reactores pequenos; Producto de alta pureza. Además, estepr ocedimiento ofrece, en comparacion con las condiciones previas del arte, ventajas considerables, las que pueden mencionarse como sigue: Se pueden conseguiraltos rendimientos espacio-tiempo, a comparativamente bajas temperaturas. La formacion de subpr oductos es extremadamente bajas. El catalizador es tratado concuidado y sufre muy poca desactivacion; se minimiza la descarga continua. Otra ventaja de la preparacion de aldehidos alfa, beta-insaturados por condensacionaldolica de aldehídos segun el procedimiento descrito más arriba es que, debido a la alta velocidad de reaccion, aun los aldehídos con muy baja solubilidad enla fase catalítica pueden convertirse economicamente en los correspondientes productos de la condensacion aldolica.
ARP000106271A 1999-11-30 2000-11-29 Procedimiento para llevar a cabo condensaciones aldolicas cataliticas por medio de una reaccion multifase, y el uso de los productos de la condensacionaldolica para preparar alcoholes, plastificantes, detergentes, solventes o acidos carboxilicos saturados AR026638A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19957522A DE19957522A1 (de) 1999-11-30 1999-11-30 Verfahren zur katalytischen Durchführung von Aldolkondensationen mittels Mehrphasenreaktion

Publications (1)

Publication Number Publication Date
AR026638A1 true AR026638A1 (es) 2003-02-19

Family

ID=7930808

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP000106271A AR026638A1 (es) 1999-11-30 2000-11-29 Procedimiento para llevar a cabo condensaciones aldolicas cataliticas por medio de una reaccion multifase, y el uso de los productos de la condensacionaldolica para preparar alcoholes, plastificantes, detergentes, solventes o acidos carboxilicos saturados

Country Status (18)

Country Link
US (1) US6340778B1 (es)
EP (1) EP1106596B1 (es)
JP (1) JP2001163823A (es)
KR (1) KR100679469B1 (es)
CN (1) CN1227207C (es)
AR (1) AR026638A1 (es)
AT (1) ATE387956T1 (es)
BR (1) BR0005672A (es)
CA (1) CA2327047A1 (es)
CZ (1) CZ301057B6 (es)
DE (2) DE19957522A1 (es)
ES (1) ES2301466T3 (es)
MY (1) MY117787A (es)
PL (1) PL192943B1 (es)
RO (1) RO122776B1 (es)
SG (1) SG86452A1 (es)
TW (1) TW548264B (es)
ZA (1) ZA200007013B (es)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10106186A1 (de) * 2001-02-10 2002-08-14 Oxeno Olefinchemie Gmbh Verfahren zur Kondensation von Aldehyden mit Ketonen mittels Mehrphasenreaktion
EP1231194B1 (de) * 2001-02-10 2003-11-12 Oxeno Olefinchemie GmbH Herstellung von 1-Olefinen
CN100357453C (zh) * 2002-05-07 2007-12-26 巴斯福股份公司 基于二醛的鞣剂和固化剂
DE10249912A1 (de) 2002-10-26 2004-05-06 Oxeno Olefinchemie Gmbh Benzoesäureisodecyclestergemische, Herstellung und deren Verwendung
GB0322247D0 (en) * 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to an isobutylene containing stream
DE102004011081A1 (de) * 2004-03-06 2005-09-22 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von tertiären Carbonsäuren
DE102005047460A1 (de) * 2005-09-30 2007-04-05 Basf Ag Verfahren zur Behandlung von Abwasser aus Aldolisierungsverfahren
DE102008002187A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
RU2533117C2 (ru) * 2009-04-03 2014-11-20 Мицубиси Гэс Кемикал Компани, Инк. СПОСОБ ПОЛУЧЕНИЯ СЛОЖНЫХ ЭФИРОВ α-ГИДРОКСИКАРБОНОВЫХ КИСЛОТ
DE102009027978A1 (de) * 2009-07-23 2011-01-27 Evonik Oxeno Gmbh Verfahren zur Herstellung von Decancarbonsäuren
DE102009028976A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Ester der 2,5-Furandicarbonsäure mit isomeren Decanolen und ihre Verwendung
DE102009045139A1 (de) * 2009-09-30 2011-03-31 Evonik Oxeno Gmbh Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe
CN102432439A (zh) * 2010-09-29 2012-05-02 中国石油化工股份有限公司 一种二醚型给电子体的制备方法
KR101444976B1 (ko) * 2010-10-05 2014-09-26 주식회사 엘지화학 α,β-불포화 알데히드의 제조방법
DE102011012846B4 (de) 2011-03-03 2016-08-18 Oxea Gmbh Verfahren zur Durchführung von mehrphasigen Aldolkondensationsreaktionen zu gemischten α,β-ungesättigten Aldehyden
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
JP6362612B2 (ja) * 2012-11-30 2018-07-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 触媒を用いてアルデヒドをアルドール縮合するための方法
US9006495B2 (en) 2012-11-30 2015-04-14 Basf Se Process for the catalytic aldol condensation of aldehydes
US8710278B1 (en) 2013-01-31 2014-04-29 Eastman Chemical Company Process for producing polyols
US9056824B2 (en) 2013-01-31 2015-06-16 Eastman Chemical Company Preparation of hydroxy aldehydes
DE102013020322B4 (de) 2013-12-05 2019-04-18 Oxea Gmbh Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
US9688599B2 (en) * 2014-04-18 2017-06-27 Texmark Chemicals, Inc. Production of mixed aldol products from the products of hydroformylation reactions
CN108474039B (zh) 2015-12-03 2022-06-07 雷杰纳荣制药公司 抗vegf剂在制备用于治疗新生血管性年龄相关性黄斑变性患者的药物中的用途
ES2714899T3 (es) 2016-09-30 2019-05-30 Oxea Gmbh Método de producción continuo para 2-metilenos-alcanales
TWI784094B (zh) 2017-12-01 2022-11-21 德商贏創運營有限公司 自醛獲得醇之方法iii
ZA201808002B (en) 2017-12-01 2019-08-28 Evonik Degussa Gmbh Method for obtaining alcohols from aldehydes
ZA201808003B (en) 2017-12-01 2019-08-28 Evonik Degussa Gmbh Method for obtaining alcohols from aldehydes ii
US11519020B2 (en) 2018-05-25 2022-12-06 Regeneron Pharmaceuticals, Inc. Methods of associating genetic variants with a clinical outcome in patients suffering from age-related macular degeneration treated with anti-VEGF
CN111116385A (zh) * 2019-12-31 2020-05-08 芜湖天道绿色新材料有限公司 一种基于管式反应装置连续制备可降解固化剂的方法
CN111620767A (zh) * 2020-07-02 2020-09-04 中国天辰工程有限公司 一种提高羟醛缩合反应选择性的方法
CN113209930A (zh) * 2021-05-26 2021-08-06 中国海洋石油集团有限公司 一种醛缩合反应设备及反应方法
CN116063167A (zh) * 2021-11-01 2023-05-05 中国石油化工股份有限公司 一种制备2-丙基-2-庚烯醛的方法及装置和所得2-丙基-2-庚烯醛
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
GB202303617D0 (en) 2023-03-13 2023-04-26 Johnson Matthey Davy Technologies Ltd Method and apparatus for producing aldehyde

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB761203A (en) * 1953-10-16 1956-11-14 Melle Usines Sa Process for producing condensation products from saturated carbonyl-compounds
US3077500A (en) * 1955-06-23 1963-02-12 Celanese Corp Aldol condensation reactions
DE3234701A1 (de) * 1982-09-18 1984-04-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
US5254743A (en) * 1992-12-09 1993-10-19 Uop Solid bases as catalysts in aldol condensations
DE4307539B4 (de) 1993-03-10 2005-08-25 Karl Storz Gmbh & Co. Kg Medizinische Zange
WO1996031454A1 (fr) * 1995-04-04 1996-10-10 Kuraray Co., Ltd. Procede de preparation de la 6-methylheptan-2-one
DE19925385A1 (de) * 1999-06-02 2000-12-07 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Vinylierungen von Carbonsäuren
DE19925384A1 (de) * 1999-06-02 2000-12-07 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Hydroformylierungen

Also Published As

Publication number Publication date
BR0005672A (pt) 2001-11-27
EP1106596B1 (de) 2008-03-05
MY117787A (en) 2004-08-30
KR100679469B1 (ko) 2007-02-07
ZA200007013B (en) 2001-06-07
CA2327047A1 (en) 2001-05-30
US6340778B1 (en) 2002-01-22
DE50015016D1 (de) 2008-04-17
CZ20004077A3 (cs) 2001-07-11
EP1106596A2 (de) 2001-06-13
CZ301057B6 (cs) 2009-10-29
JP2001163823A (ja) 2001-06-19
RO122776B1 (ro) 2010-01-29
ES2301466T3 (es) 2008-07-01
EP1106596A9 (de) 2001-10-04
PL344210A1 (en) 2001-06-04
CN1297877A (zh) 2001-06-06
TW548264B (en) 2003-08-21
SG86452A1 (en) 2002-02-19
CN1227207C (zh) 2005-11-16
EP1106596A3 (de) 2002-04-17
PL192943B1 (pl) 2006-12-29
ATE387956T1 (de) 2008-03-15
KR20010052030A (ko) 2001-06-25
DE19957522A1 (de) 2001-05-31

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