ZA200904643B - Chromium-free water gas shift catalyst - Google Patents
Chromium-free water gas shift catalyst Download PDFInfo
- Publication number
- ZA200904643B ZA200904643B ZA200904643A ZA200904643A ZA200904643B ZA 200904643 B ZA200904643 B ZA 200904643B ZA 200904643 A ZA200904643 A ZA 200904643A ZA 200904643 A ZA200904643 A ZA 200904643A ZA 200904643 B ZA200904643 B ZA 200904643B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- catalysts
- molar ratio
- gas mixture
- reactor
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 197
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 29
- 229910001868 water Inorganic materials 0.000 title description 24
- 238000006243 chemical reaction Methods 0.000 claims description 46
- 239000011701 zinc Substances 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 43
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 32
- 230000015572 biosynthetic process Effects 0.000 claims description 29
- 238000003786 synthesis reaction Methods 0.000 claims description 24
- 229910052725 zinc Inorganic materials 0.000 claims description 22
- 229910052700 potassium Inorganic materials 0.000 claims description 19
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 239000011787 zinc oxide Substances 0.000 claims description 15
- 150000001340 alkali metals Chemical class 0.000 claims description 14
- 229910052792 caesium Inorganic materials 0.000 claims description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 11
- 239000011591 potassium Substances 0.000 claims description 11
- 229910052596 spinel Inorganic materials 0.000 claims description 10
- 239000011029 spinel Substances 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 3
- 230000036647 reaction Effects 0.000 claims description 3
- 229910052701 rubidium Inorganic materials 0.000 claims description 3
- 102100022704 Amyloid-beta precursor protein Human genes 0.000 claims 1
- 101000823051 Homo sapiens Amyloid-beta precursor protein Proteins 0.000 claims 1
- DZHSAHHDTRWUTF-SIQRNXPUSA-N amyloid-beta polypeptide 42 Chemical compound C([C@@H](C(=O)N[C@@H](C)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)NCC(=O)N[C@@H](CO)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CCCCN)C(=O)NCC(=O)N[C@@H](C)C(=O)N[C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)NCC(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCSC)C(=O)N[C@@H](C(C)C)C(=O)NCC(=O)NCC(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](C)C(O)=O)[C@@H](C)CC)C(C)C)NC(=O)[C@H](CC=1C=CC=CC=1)NC(=O)[C@@H](NC(=O)[C@H](CC(C)C)NC(=O)[C@H](CCCCN)NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@@H](NC(=O)[C@H](CCC(O)=O)NC(=O)[C@H](CC=1C=CC(O)=CC=1)NC(=O)CNC(=O)[C@H](CO)NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@H](CCCNC(N)=N)NC(=O)[C@H](CC=1C=CC=CC=1)NC(=O)[C@H](CCC(O)=O)NC(=O)[C@H](C)NC(=O)[C@@H](N)CC(O)=O)C(C)C)C(C)C)C1=CC=CC=C1 DZHSAHHDTRWUTF-SIQRNXPUSA-N 0.000 claims 1
- 229940105305 carbon monoxide Drugs 0.000 claims 1
- 239000007789 gas Substances 0.000 description 67
- 230000000694 effects Effects 0.000 description 40
- 239000010949 copper Substances 0.000 description 22
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- 229910052802 copper Inorganic materials 0.000 description 17
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
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- 239000001257 hydrogen Substances 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
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- 230000000052 comparative effect Effects 0.000 description 10
- 235000007686 potassium Nutrition 0.000 description 10
- 229960003975 potassium Drugs 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 239000011651 chromium Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 8
- 239000008188 pellet Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 231100000614 poison Toxicity 0.000 description 7
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- 239000011593 sulfur Substances 0.000 description 7
- 235000001508 sulfur Nutrition 0.000 description 7
- 229960005349 sulfur Drugs 0.000 description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
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- 229910019589 Cr—Fe Inorganic materials 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 230000002035 prolonged effect Effects 0.000 description 5
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- 230000000875 corresponding effect Effects 0.000 description 4
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- 238000000975 co-precipitation Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
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- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
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- BHKKSKOHRFHHIN-MRVPVSSYSA-N 1-[[2-[(1R)-1-aminoethyl]-4-chlorophenyl]methyl]-2-sulfanylidene-5H-pyrrolo[3,2-d]pyrimidin-4-one Chemical compound N[C@H](C)C1=C(CN2C(NC(C3=C2C=CN3)=O)=S)C=CC(=C1)Cl BHKKSKOHRFHHIN-MRVPVSSYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 244000205754 Colocasia esculenta Species 0.000 description 2
- 235000006481 Colocasia esculenta Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910020068 MgAl Inorganic materials 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
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- 229910000611 Zinc aluminium Inorganic materials 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical class [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 description 2
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 2
- JYMITAMFTJDTAE-UHFFFAOYSA-N aluminum zinc oxygen(2-) Chemical class [O-2].[Al+3].[Zn+2] JYMITAMFTJDTAE-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
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- 230000007613 environmental effect Effects 0.000 description 2
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- 238000000629 steam reforming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- LCFFREMLXLZNHE-GBOLQPHISA-N (e)-2-[(3r)-3-[4-amino-3-(2-fluoro-4-phenoxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]piperidine-1-carbonyl]-4-methyl-4-[4-(oxetan-3-yl)piperazin-1-yl]pent-2-enenitrile Chemical compound C12=C(N)N=CN=C2N([C@@H]2CCCN(C2)C(=O)C(/C#N)=C/C(C)(C)N2CCN(CC2)C2COC2)N=C1C(C(=C1)F)=CC=C1OC1=CC=CC=C1 LCFFREMLXLZNHE-GBOLQPHISA-N 0.000 description 1
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
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- 101000713585 Homo sapiens Tubulin beta-4A chain Proteins 0.000 description 1
- 241001397173 Kali <angiosperm> Species 0.000 description 1
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- 101100173048 Mus musculus Mcat gene Proteins 0.000 description 1
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- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
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- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200800934 | 2008-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200904643B true ZA200904643B (en) | 2010-05-26 |
Family
ID=40984690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200904643A ZA200904643B (en) | 2008-07-03 | 2009-07-02 | Chromium-free water gas shift catalyst |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7998897B2 (de) |
| EP (1) | EP2141118B1 (de) |
| CN (1) | CN101618318B (de) |
| PL (1) | PL2141118T3 (de) |
| RU (1) | RU2498851C9 (de) |
| UA (1) | UA102815C2 (de) |
| ZA (1) | ZA200904643B (de) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2467292B (en) * | 2008-11-24 | 2013-08-07 | Progressive Energy Ltd | Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation |
| PT2599541T (pt) | 2011-12-02 | 2017-06-30 | L`Air Liquide Société Anonyme Pour L`Etude Et L`Exploitation Des Procédés Georges Claude | Processo de preparação de um catalisador para troca em água gás, operando a temperaturas médias |
| NL2008313C2 (en) | 2012-02-17 | 2013-09-02 | Stichting Energie | Water gas shift process. |
| WO2013135663A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxid-katalysatoren umfassend edelmetalle |
| WO2013135699A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren für die synthesegasherstellung im wechselbetrieb zwischen zwei betriebsarten |
| WO2013135662A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxidkatalysatoren |
| WO2014056535A1 (en) * | 2012-10-11 | 2014-04-17 | Haldor Topsøe A/S | Process for the production of synthesis gas |
| CN103055865A (zh) * | 2013-01-04 | 2013-04-24 | 福州大学 | 一种Cu-Fe耦合的一氧化碳宽温变换催化剂及其制备方法 |
| EP2801550A1 (de) * | 2013-05-10 | 2014-11-12 | Ammonia Casale S.A. | Verfahren zur Herstellung von Ammoniaksynthesegas mit Hochtemperaturkonvertierung und niedrigem Dampf-Kohlen-Verhältnis |
| CN105080564B (zh) * | 2014-05-14 | 2017-09-15 | 中国石油化工股份有限公司 | 用于二氧化碳转化制一氧化碳的催化剂及其使用方法 |
| CN106660020A (zh) | 2014-07-17 | 2017-05-10 | 沙特基础全球技术有限公司 | 橄榄石催化剂用于甲烷的二氧化碳重整的用途 |
| EP3006108A1 (de) * | 2014-10-10 | 2016-04-13 | Repsol, S.A. | Geträgerte Mehrmetallverbindung aus geschichtetem Doppelhydroxid-Hydrotalcit |
| US10022707B2 (en) | 2015-01-13 | 2018-07-17 | Fuzhou University | Sulfur-tolerant CO shift conversion catalyst and preparation method thereof |
| GB201519133D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| GB201519139D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| UA123999C2 (uk) | 2015-10-29 | 2021-07-07 | Джонсон Метті Паблік Лімітед Компані | Каталізатор конверсії водяного газу |
| CA3010549C (en) * | 2016-02-02 | 2023-01-17 | Haldor Topsoe A/S | Atr based ammonia process and plant |
| GB201603298D0 (en) | 2016-02-25 | 2016-04-13 | Johnson Matthey Plc | Process |
| AR107702A1 (es) | 2016-02-29 | 2018-05-23 | Haldor Topsoe As | Renovación con baja cantidad de vapor / carbono |
| EP3254760A1 (de) | 2016-06-07 | 2017-12-13 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Verfahren zur synthese eines katalysators zur durchführung einer wasser-gas-konvertierungsreaktion bei hoher temperatur |
| KR102556774B1 (ko) | 2017-03-07 | 2023-07-19 | 토프쉐 에이/에스 | 개선된 전환 과정을 사용한 암모니아 과정 |
| EA202090244A1 (ru) | 2017-07-13 | 2020-04-28 | Хальдор Топсёэ А/С | Способ и катализаторы для получения синтез-газа для производства аммиака |
| BR102020020748A2 (pt) | 2020-10-08 | 2022-04-19 | Petróleo Brasileiro S.A. - Petrobras | Métodos de preparo de catalisadores de deslocamento do gás d'água a alta tempertaura, catalisadores e processo para redução de monóxido de carbono |
| WO2022112309A1 (en) | 2020-11-24 | 2022-06-02 | Topsoe A/S | Method of starting-up a water gas shift reactor |
| CA3196607A1 (en) | 2020-11-24 | 2022-06-02 | Topsoe A/S | Process for producing hydrogen from co-rich gases |
| EP4251561A1 (de) | 2020-11-24 | 2023-10-04 | Topsoe A/S | Wassergaskonvertierungskatalysator |
| BR102020025161A2 (pt) * | 2020-12-09 | 2022-06-21 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de um catalisador de deslocamento do gás dágua a alta tempertaura e processo para reduzir o teor de monóxido de carbono |
| WO2023163899A1 (en) * | 2022-02-24 | 2023-08-31 | Basf Corporation | Nickel promoted copper alumina catalyst for slurry phase process for producing fatty alcohol |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3961037A (en) * | 1965-01-05 | 1976-06-01 | Imperial Chemical Industries Limited | Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium |
| US3626021A (en) * | 1968-07-01 | 1971-12-07 | Atlantic Richfield Co | Dehydrogenation of aliphatics over alkali metal oxide-chromia-zinc aluminate spinel catalyst |
| FR2370684A1 (fr) * | 1976-11-10 | 1978-06-09 | Shell France | Procede pour la preparation d'un gaz riche en hydrogene |
| US4104318A (en) * | 1977-05-27 | 1978-08-01 | Gulf Research & Development Company | Process for removing organic oxygen-containing impurities from an organic composition in the presence of steam |
| FR2523957A1 (fr) | 1982-03-26 | 1983-09-30 | Inst Francais Du Petrole | Procede de fabrication d'un melange de methanol et d'alcools superieurs, a partir de gaz de synthese |
| JPS59122432A (ja) | 1982-12-29 | 1984-07-14 | Res Assoc Petroleum Alternat Dev<Rapad> | 混合アルコ−ルの製造方法 |
| FR2564091B1 (fr) | 1984-05-10 | 1986-10-03 | Inst Francais Du Petrole | Procede de synthese d'un melange d'alcools primaires a partir de gaz de synthese en presence d'un catalyseur contenant du cuivre, du cobalt, du zinc et de l'aluminium |
| FR2567866B1 (fr) * | 1984-07-20 | 1987-01-02 | Shell Int Research | Procede de preparation d'un gaz riche en hydrogene |
| JP3908313B2 (ja) | 1996-12-24 | 2007-04-25 | 千代田化工建設株式会社 | 脱水素触媒 |
| DE19715203A1 (de) * | 1997-04-11 | 1998-10-15 | Basf Ag | Katalysator und Verfahren zur Seitenkettenalkylierung |
| CN1066415C (zh) * | 1997-12-07 | 2001-05-30 | 中国石化齐鲁石油化工公司 | 一种一氧化碳耐硫变换催化剂及制备方法 |
| FR2779071B1 (fr) * | 1998-05-26 | 2000-08-18 | Rhodia Chimie Sa | Aluminate de zinc a surface specifique elevee, son procede de preparation et son utilisation dans le traitement de gaz d'echappement d'automobile |
| FR2794768B1 (fr) | 1999-06-11 | 2006-07-07 | Inst Francais Du Petrole | Procede de fabrication d'esters a partir d'huile de ricin et d'alcools utilisant un catalyseur heterogene |
| EP1149799B1 (de) * | 2000-04-27 | 2003-10-08 | Haldor Topsoe A/S | Verfahren zur Herstellung eines wasserstoffreichen Gases |
| CN1286214A (zh) * | 2000-09-25 | 2001-03-07 | 四川华泰投资有限责任公司 | 在以天然气水蒸汽转化的合成气为原料的合成工艺中调节合成气氢碳成分比的方法 |
| GB0121680D0 (en) * | 2001-09-08 | 2001-10-31 | Ici Plc | Catalysts |
| US20040105804A1 (en) * | 2002-11-29 | 2004-06-03 | Industrial Technology Research Institute | Catalyst for water-gas shift reaction and method for converting carbon monoxide and water to hydrogen and carbon dioxide |
| JP2004321924A (ja) | 2003-04-24 | 2004-11-18 | Toyota Central Res & Dev Lab Inc | 水性ガスシフト反応用触媒 |
| WO2005063364A1 (en) * | 2003-12-29 | 2005-07-14 | National University Of Singapore | Catalyst for conversion of gases, a method for its production and use of the same |
-
2009
- 2009-06-10 EP EP09007679.5A patent/EP2141118B1/de active Active
- 2009-06-10 PL PL09007679T patent/PL2141118T3/pl unknown
- 2009-06-11 US US12/483,043 patent/US7998897B2/en active Active
- 2009-07-02 RU RU2009125333/04A patent/RU2498851C9/ru active
- 2009-07-02 ZA ZA200904643A patent/ZA200904643B/en unknown
- 2009-07-02 UA UAA200906938A patent/UA102815C2/ru unknown
- 2009-07-02 CN CN2009101595691A patent/CN101618318B/zh active Active
-
2010
- 2010-12-01 US US12/957,496 patent/US8119099B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US7998897B2 (en) | 2011-08-16 |
| RU2498851C2 (ru) | 2013-11-20 |
| EP2141118B1 (de) | 2013-08-07 |
| RU2009125333A (ru) | 2011-01-10 |
| EP2141118A1 (de) | 2010-01-06 |
| CN101618318B (zh) | 2013-07-03 |
| UA102815C2 (ru) | 2013-08-27 |
| US20100000155A1 (en) | 2010-01-07 |
| US20110101277A1 (en) | 2011-05-05 |
| CN101618318A (zh) | 2010-01-06 |
| PL2141118T3 (pl) | 2014-01-31 |
| US8119099B2 (en) | 2012-02-21 |
| RU2498851C9 (ru) | 2014-09-10 |
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