GB2467292B - Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation - Google Patents

Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation

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Publication number
GB2467292B
GB2467292B GB0821450.4A GB0821450A GB2467292B GB 2467292 B GB2467292 B GB 2467292B GB 0821450 A GB0821450 A GB 0821450A GB 2467292 B GB2467292 B GB 2467292B
Authority
GB
United Kingdom
Prior art keywords
hydrogen
carbon dioxide
waste gas
gas processing
shift reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
GB0821450.4A
Other versions
GB2467292A (en
GB0821450D0 (en
Inventor
John Andrew Gordon Brown
David John Hanstock
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PROGRESSIVE ENERGY Ltd
Original Assignee
PROGRESSIVE ENERGY Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to GB0821450.4A priority Critical patent/GB2467292B/en
Publication of GB0821450D0 publication Critical patent/GB0821450D0/en
Publication of GB2467292A publication Critical patent/GB2467292A/en
Application granted granted Critical
Publication of GB2467292B publication Critical patent/GB2467292B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B7/00—Blast furnaces
    • C21B7/002—Evacuating and treating of exhaust gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0294—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing three or more CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/24—Increasing the gas reduction potential of recycled exhaust gases by shift reactions
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Gas Separation By Absorption (AREA)
GB0821450.4A 2008-11-24 2008-11-24 Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation Expired - Fee Related GB2467292B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB0821450.4A GB2467292B (en) 2008-11-24 2008-11-24 Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0821450.4A GB2467292B (en) 2008-11-24 2008-11-24 Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation

Publications (3)

Publication Number Publication Date
GB0821450D0 GB0821450D0 (en) 2008-12-31
GB2467292A GB2467292A (en) 2010-07-28
GB2467292B true GB2467292B (en) 2013-08-07

Family

ID=40230736

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0821450.4A Expired - Fee Related GB2467292B (en) 2008-11-24 2008-11-24 Waste Gas Processing using Water Shift Reaction with Hydrogen, Carbon Dioxide and Hydrogen Sulphide Separation

Country Status (1)

Country Link
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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385129A (en) * 2017-09-20 2017-11-24 中冶南方工程技术有限公司 A kind of blast furnace gas saturator method cleaning system
US11680299B2 (en) * 2019-09-04 2023-06-20 Palo Alto Research Center Incorporated Process and system for steel and hydrogen production using recycled ferrous scrap and natural gas

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615355A (en) * 1967-09-08 1971-10-26 Foster Wheeler Corp Method of collecting and treating exhaust gases containing carbon monoxide
US3822125A (en) * 1972-10-13 1974-07-02 Treadwell Corp Flash smelting of iron ore and concentrate
US3993457A (en) * 1973-07-30 1976-11-23 Exxon Research And Engineering Company Concurrent production of methanol and synthetic natural gas
US4062673A (en) * 1975-12-22 1977-12-13 Robert Ames Norton Flash smelting of iron with production of hydrogen of hydrogenation quality
US4235800A (en) * 1978-05-31 1980-11-25 Imperial Chemical Industries Limited Synthesis gas
JPS57129803A (en) * 1981-01-29 1982-08-12 Nippon Steel Corp Production of hydrogen-rich gas form gas containing carbon monoxide
BE897123A (en) * 1983-06-23 1983-10-17 Ct De Rech S Matallurgiques Ct Upgrading blast furnace gas - by catalytic conversion and hydrogen removal, for reuse in blast furnace
US6045602A (en) * 1998-10-28 2000-04-04 Praxair Technology, Inc. Method for integrating a blast furnace and a direct reduction reactor using cryogenic rectification
WO2000018680A1 (en) * 1998-09-16 2000-04-06 Den Norske Stats Oljeselskap A.S Process for preparing a h2-rich gas and a co2-rich gas at high pressure
WO2008115076A2 (en) * 2007-03-19 2008-09-25 Statoilhydro Asa Method and reactor for production of hydrogen
WO2009019497A2 (en) * 2007-08-03 2009-02-12 Johnson Matthey Plc Process for the generation of a synthesis gas
WO2009064962A2 (en) * 2007-11-14 2009-05-22 Texyn Hydrocarbon, Llc System and method for high pressure synthesis gas processing
EP2141118A1 (en) * 2008-07-03 2010-01-06 Haldor Topsoe A/S Chromium-free water gas shift catalyst

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615355A (en) * 1967-09-08 1971-10-26 Foster Wheeler Corp Method of collecting and treating exhaust gases containing carbon monoxide
US3822125A (en) * 1972-10-13 1974-07-02 Treadwell Corp Flash smelting of iron ore and concentrate
US3993457A (en) * 1973-07-30 1976-11-23 Exxon Research And Engineering Company Concurrent production of methanol and synthetic natural gas
US4062673A (en) * 1975-12-22 1977-12-13 Robert Ames Norton Flash smelting of iron with production of hydrogen of hydrogenation quality
US4235800A (en) * 1978-05-31 1980-11-25 Imperial Chemical Industries Limited Synthesis gas
JPS57129803A (en) * 1981-01-29 1982-08-12 Nippon Steel Corp Production of hydrogen-rich gas form gas containing carbon monoxide
BE897123A (en) * 1983-06-23 1983-10-17 Ct De Rech S Matallurgiques Ct Upgrading blast furnace gas - by catalytic conversion and hydrogen removal, for reuse in blast furnace
WO2000018680A1 (en) * 1998-09-16 2000-04-06 Den Norske Stats Oljeselskap A.S Process for preparing a h2-rich gas and a co2-rich gas at high pressure
US6045602A (en) * 1998-10-28 2000-04-04 Praxair Technology, Inc. Method for integrating a blast furnace and a direct reduction reactor using cryogenic rectification
WO2008115076A2 (en) * 2007-03-19 2008-09-25 Statoilhydro Asa Method and reactor for production of hydrogen
WO2009019497A2 (en) * 2007-08-03 2009-02-12 Johnson Matthey Plc Process for the generation of a synthesis gas
WO2009064962A2 (en) * 2007-11-14 2009-05-22 Texyn Hydrocarbon, Llc System and method for high pressure synthesis gas processing
EP2141118A1 (en) * 2008-07-03 2010-01-06 Haldor Topsoe A/S Chromium-free water gas shift catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Physical Chemistry Chemical Physics Vol. 5, May 2003, C Rhodes, G J Hutchings, "Studies of the role of the copper promoter in the iron oxide/chromia high temperature water gas shift catalyst", pages 2719 to 2723, especially pages 2720, 2721 *

Also Published As

Publication number Publication date
GB2467292A (en) 2010-07-28
GB0821450D0 (en) 2008-12-31

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20221124