ZA200504127B - Magnesium dichloride-based adducts and catalyst components obtained therefrom. - Google Patents
Magnesium dichloride-based adducts and catalyst components obtained therefrom. Download PDFInfo
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- ZA200504127B ZA200504127B ZA200504127A ZA200504127A ZA200504127B ZA 200504127 B ZA200504127 B ZA 200504127B ZA 200504127 A ZA200504127 A ZA 200504127A ZA 200504127 A ZA200504127 A ZA 200504127A ZA 200504127 B ZA200504127 B ZA 200504127B
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- ZA
- South Africa
- Prior art keywords
- solid
- groups
- adduct
- ethers
- roh
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 34
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title claims description 11
- 235000011147 magnesium chloride Nutrition 0.000 title description 4
- -1 LB compound Chemical class 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 27
- 239000002879 Lewis base Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 20
- 150000007527 lewis bases Chemical class 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- 150000002170 ethers Chemical class 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 8
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 150000003623 transition metal compounds Chemical class 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 150000004292 cyclic ethers Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- 150000004756 silanes Chemical class 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 239000012808 vapor phase Substances 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 125000004185 ester group Chemical group 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 230000000707 stereoselective effect Effects 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- NOAIBMQZUGBONL-UHFFFAOYSA-N (1,3-dimethoxy-2-methylpropan-2-yl)benzene Chemical compound COCC(C)(COC)C1=CC=CC=C1 NOAIBMQZUGBONL-UHFFFAOYSA-N 0.000 description 1
- HPOWOWTVWZELDK-UHFFFAOYSA-N (1,3-dimethoxy-2-methylpropan-2-yl)cyclohexane Chemical compound COCC(C)(COC)C1CCCCC1 HPOWOWTVWZELDK-UHFFFAOYSA-N 0.000 description 1
- HBMODDNTUPGVFW-UHFFFAOYSA-N (1,3-dimethoxy-2-phenylpropan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(COC)(COC)C1=CC=CC=C1 HBMODDNTUPGVFW-UHFFFAOYSA-N 0.000 description 1
- MEPSBRTXOHFWCF-UHFFFAOYSA-N (2-cyclohexyl-1,3-dimethoxypropan-2-yl)cyclohexane Chemical compound C1CCCCC1C(COC)(COC)C1CCCCC1 MEPSBRTXOHFWCF-UHFFFAOYSA-N 0.000 description 1
- BEDHCUAJOBASSZ-UHFFFAOYSA-N (2-cyclopentyl-1,3-dimethoxypropan-2-yl)cyclopentane Chemical compound C1CCCC1C(COC)(COC)C1CCCC1 BEDHCUAJOBASSZ-UHFFFAOYSA-N 0.000 description 1
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- OTIJMHPVYPMCPU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2,3-dimethylindene Chemical compound C1=CC=C2C(COC)(COC)C(C)=C(C)C2=C1 OTIJMHPVYPMCPU-UHFFFAOYSA-N 0.000 description 1
- HHGPZISECHQRLO-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-methyl-4-phenylindene Chemical compound COCC1(COC)C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 HHGPZISECHQRLO-UHFFFAOYSA-N 0.000 description 1
- FXWFWIIEIAUQHQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-phenylindene Chemical compound C=1C2=CC=CC=C2C(COC)(COC)C=1C1=CC=CC=C1 FXWFWIIEIAUQHQ-UHFFFAOYSA-N 0.000 description 1
- OSTKQRYZSROERR-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-3,6-dimethylindene Chemical compound C1=C(C)C=C2C(COC)(COC)C=C(C)C2=C1 OSTKQRYZSROERR-UHFFFAOYSA-N 0.000 description 1
- ZKXOLTKRGCQGJN-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,5,6,7-tetrahydroindene Chemical compound C1CCCC2=C1C(COC)(COC)C=C2 ZKXOLTKRGCQGJN-UHFFFAOYSA-N 0.000 description 1
- OGMUHNYKQFIZMP-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,7-dimethyl-4,5,6,7-tetrahydroindene Chemical compound CC1CCC(C)C2=C1C(COC)(COC)C=C2 OGMUHNYKQFIZMP-UHFFFAOYSA-N 0.000 description 1
- ZZPVNMUQOQQUHU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,7-dimethylindene Chemical compound CC1=CC=C(C)C2=C1C(COC)(COC)C=C2 ZZPVNMUQOQQUHU-UHFFFAOYSA-N 0.000 description 1
- REYOVQKLCXXZTD-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4-phenylindene Chemical compound COCC1(COC)C=CC2=C1C=CC=C2C1=CC=CC=C1 REYOVQKLCXXZTD-UHFFFAOYSA-N 0.000 description 1
- JEENAIJBWUBGSW-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(3,3,3-trifluoropropyl)indene Chemical compound C1=CC(CCC(F)(F)F)=C2C(COC)(COC)C=CC2=C1 JEENAIJBWUBGSW-UHFFFAOYSA-N 0.000 description 1
- RMXREGKBZYAVSC-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(trifluoromethyl)indene Chemical compound C1=CC(C(F)(F)F)=C2C(COC)(COC)C=CC2=C1 RMXREGKBZYAVSC-UHFFFAOYSA-N 0.000 description 1
- ZOIKOBDBSUJRNE-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-methylindene Chemical compound C1=CC(C)=C2C(COC)(COC)C=CC2=C1 ZOIKOBDBSUJRNE-UHFFFAOYSA-N 0.000 description 1
- UQGOQZUZKNXSTQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-phenylindene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1=CC=CC=C1 UQGOQZUZKNXSTQ-UHFFFAOYSA-N 0.000 description 1
- VJTYHGPEEHLNGJ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-propan-2-ylindene Chemical compound C1=CC(C(C)C)=C2C(COC)(COC)C=CC2=C1 VJTYHGPEEHLNGJ-UHFFFAOYSA-N 0.000 description 1
- ILXXAZBXJLMEQM-UHFFFAOYSA-N 1,1-bis(methoxymethyl)indene Chemical compound C1=CC=C2C(COC)(COC)C=CC2=C1 ILXXAZBXJLMEQM-UHFFFAOYSA-N 0.000 description 1
- KWXZYQJINBQUCF-UHFFFAOYSA-N 1,2,3,4-tetrafluoro-5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C(F)=C(F)C(F)=C1F KWXZYQJINBQUCF-UHFFFAOYSA-N 0.000 description 1
- CELOJHLXFPSJPH-UHFFFAOYSA-N 1,3-dimethoxypropan-2-ylbenzene Chemical compound COCC(COC)C1=CC=CC=C1 CELOJHLXFPSJPH-UHFFFAOYSA-N 0.000 description 1
- NOWCPSTWMDNKTI-UHFFFAOYSA-N 1,3-dimethoxypropan-2-ylcyclohexane Chemical compound COCC(COC)C1CCCCC1 NOWCPSTWMDNKTI-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HPFWUWXYBFOJAD-UHFFFAOYSA-N 1-chloro-4-(1,3-dimethoxypropan-2-yl)benzene Chemical compound COCC(COC)C1=CC=C(Cl)C=C1 HPFWUWXYBFOJAD-UHFFFAOYSA-N 0.000 description 1
- PUBYKMSPAJMOGX-UHFFFAOYSA-N 1-chloro-4-[2-(4-chlorophenyl)-1,3-dimethoxypropan-2-yl]benzene Chemical compound C=1C=C(Cl)C=CC=1C(COC)(COC)C1=CC=C(Cl)C=C1 PUBYKMSPAJMOGX-UHFFFAOYSA-N 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- XAGXJWYEHBCLPN-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2-methylbutane Chemical compound COCC(C)(CC)COC XAGXJWYEHBCLPN-UHFFFAOYSA-N 0.000 description 1
- SVJCEDKUVMVBKM-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2-methylpentane Chemical compound CCCC(C)(COC)COC SVJCEDKUVMVBKM-UHFFFAOYSA-N 0.000 description 1
- WZGYJLJMTYSGCS-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3,3-dimethylbutane Chemical compound COCC(C(C)(C)C)COC WZGYJLJMTYSGCS-UHFFFAOYSA-N 0.000 description 1
- NGMVWDKVVMVTTM-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3-methylbutane Chemical compound COCC(C(C)C)COC NGMVWDKVVMVTTM-UHFFFAOYSA-N 0.000 description 1
- FDLMLTYTOFIPCK-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3-methylpentane Chemical compound CCC(C)C(COC)COC FDLMLTYTOFIPCK-UHFFFAOYSA-N 0.000 description 1
- PPHMKLXXVBJEHR-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)hexane Chemical compound CCCCC(COC)COC PPHMKLXXVBJEHR-UHFFFAOYSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- FGQLGYBGTRHODR-UHFFFAOYSA-N 2,2-diethoxypropane Chemical compound CCOC(C)(C)OCC FGQLGYBGTRHODR-UHFFFAOYSA-N 0.000 description 1
- OONQZFJQVHEJFR-UHFFFAOYSA-N 2,3,6,7-tetrafluoro-1,1-bis(methoxymethyl)indene Chemical compound C1=C(F)C(F)=C2C(COC)(COC)C(F)=C(F)C2=C1 OONQZFJQVHEJFR-UHFFFAOYSA-N 0.000 description 1
- IJELOUNJJDDDAU-UHFFFAOYSA-N 2,3-dicyclopentyl-5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound C1CCCC1C1=CC(COC)(COC)C=C1C1CCCC1 IJELOUNJJDDDAU-UHFFFAOYSA-N 0.000 description 1
- YIBYCVPCWUSPQY-UHFFFAOYSA-N 2-(1,3-dimethoxypropyl)-1,1-dimethylcyclohexane Chemical compound COCCC(OC)C1CCCCC1(C)C YIBYCVPCWUSPQY-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- SKWKIEFIPVHTHJ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)pentane Chemical compound COCC(CC)(CC)COC SKWKIEFIPVHTHJ-UHFFFAOYSA-N 0.000 description 1
- PYHOSWIHPZRHDU-UHFFFAOYSA-N 4,4-bis(butoxymethyl)-2,6-dimethylheptane Chemical compound CCCCOCC(CC(C)C)(CC(C)C)COCCCC PYHOSWIHPZRHDU-UHFFFAOYSA-N 0.000 description 1
- VVEYETJZOMJKNK-UHFFFAOYSA-N 4,4-bis(ethoxymethyl)-2,6-dimethylheptane Chemical compound CCOCC(CC(C)C)(CC(C)C)COCC VVEYETJZOMJKNK-UHFFFAOYSA-N 0.000 description 1
- DDONJMJAIMKSOS-UHFFFAOYSA-N 4,4-bis(ethoxymethyl)heptane Chemical compound CCOCC(CCC)(CCC)COCC DDONJMJAIMKSOS-UHFFFAOYSA-N 0.000 description 1
- LBLBZVROWJKOOY-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,2,6,6-tetramethylheptane Chemical compound COCC(COC)(CC(C)(C)C)CC(C)(C)C LBLBZVROWJKOOY-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- WOLQDDKBJWHVQK-UHFFFAOYSA-N 4,4-bis(methoxymethyl)heptane Chemical compound CCCC(CCC)(COC)COC WOLQDDKBJWHVQK-UHFFFAOYSA-N 0.000 description 1
- LHBLDRAQSNFIEY-UHFFFAOYSA-N 4-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound COCC1(COC)C=CC2=C1C=CC=C2C1CCCCC1 LHBLDRAQSNFIEY-UHFFFAOYSA-N 0.000 description 1
- CWVKCYDPJZCDMC-UHFFFAOYSA-N 4-ethyl-1-methoxy-2-(methoxymethyl)-2-methyloctane Chemical compound CCCCC(CC)CC(C)(COC)COC CWVKCYDPJZCDMC-UHFFFAOYSA-N 0.000 description 1
- VIJVFTUOJNTXCA-UHFFFAOYSA-N 4-ethyl-1-methoxy-2-(methoxymethyl)octane Chemical compound CCCCC(CC)CC(COC)COC VIJVFTUOJNTXCA-UHFFFAOYSA-N 0.000 description 1
- NDTLNHGFAUSCAE-UHFFFAOYSA-N 5,5-bis(ethoxymethyl)nonane Chemical compound CCCCC(CCCC)(COCC)COCC NDTLNHGFAUSCAE-UHFFFAOYSA-N 0.000 description 1
- NUPABKVXQKZAHY-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-1,2,3,4-tetramethylcyclopenta-1,3-diene Chemical compound COCC1(COC)C(C)=C(C)C(C)=C1C NUPABKVXQKZAHY-UHFFFAOYSA-N 0.000 description 1
- DNQBFNSYXQGWEA-UHFFFAOYSA-N 5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C=CC=C1 DNQBFNSYXQGWEA-UHFFFAOYSA-N 0.000 description 1
- UAVYNJZKEVSSFO-UHFFFAOYSA-N 5,5-bis(methoxymethyl)nonane Chemical compound CCCCC(COC)(COC)CCCC UAVYNJZKEVSSFO-UHFFFAOYSA-N 0.000 description 1
- TYYSEGNSDSKJDW-UHFFFAOYSA-N 7-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCCC1 TYYSEGNSDSKJDW-UHFFFAOYSA-N 0.000 description 1
- OQYGKBOREGNKLC-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)-2-methylindene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C(C)=CC2=C1 OQYGKBOREGNKLC-UHFFFAOYSA-N 0.000 description 1
- XBHBMIOEDQWGPY-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)indene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C=CC2=C1 XBHBMIOEDQWGPY-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- VDZDYDLIDXQASZ-UHFFFAOYSA-N [1-cyclohexyl-3-methoxy-2-(methoxymethyl)propan-2-yl]cyclohexane Chemical compound C1CCCCC1C(COC)(COC)CC1CCCCC1 VDZDYDLIDXQASZ-UHFFFAOYSA-N 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- ZVGIBQMBZHWERX-UHFFFAOYSA-N [2-(cyclohexylmethyl)-3-methoxy-2-(methoxymethyl)propyl]cyclohexane Chemical compound C1CCCCC1CC(COC)(COC)CC1CCCCC1 ZVGIBQMBZHWERX-UHFFFAOYSA-N 0.000 description 1
- URYLLQVLNOEEBA-UHFFFAOYSA-N [2-benzyl-3-methoxy-2-(methoxymethyl)propyl]benzene Chemical compound C=1C=CC=CC=1CC(COC)(COC)CC1=CC=CC=C1 URYLLQVLNOEEBA-UHFFFAOYSA-N 0.000 description 1
- JSDWVMORIKLNNU-UHFFFAOYSA-N [3,3-bis(methoxymethyl)-2,4,5-triphenylcyclopenta-1,4-dien-1-yl]benzene Chemical compound COCC1(COC)C(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 JSDWVMORIKLNNU-UHFFFAOYSA-N 0.000 description 1
- RORSEGNGPOMSSV-UHFFFAOYSA-N [3,3-bis(methoxymethyl)-5-phenylpentyl]benzene Chemical compound C=1C=CC=CC=1CCC(COC)(COC)CCC1=CC=CC=C1 RORSEGNGPOMSSV-UHFFFAOYSA-N 0.000 description 1
- WVEZHRZEAFZJOI-UHFFFAOYSA-N [3-methoxy-2-(methoxymethyl)-1-phenylpropyl]benzene Chemical compound C=1C=CC=CC=1C(C(COC)COC)C1=CC=CC=C1 WVEZHRZEAFZJOI-UHFFFAOYSA-N 0.000 description 1
- UKEUPAFEWAEVGQ-UHFFFAOYSA-N [3-methoxy-2-(methoxymethyl)-2-methylpropyl]benzene Chemical compound COCC(C)(COC)CC1=CC=CC=C1 UKEUPAFEWAEVGQ-UHFFFAOYSA-N 0.000 description 1
- ZOUNQYODSPCWEH-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)-2-methylbutan-2-yl]benzene Chemical compound COCC(COC)C(C)(C)C1=CC=CC=C1 ZOUNQYODSPCWEH-UHFFFAOYSA-N 0.000 description 1
- JXQCBJLNEGKSCN-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]benzene Chemical compound COCC(COC)CCC1=CC=CC=C1 JXQCBJLNEGKSCN-UHFFFAOYSA-N 0.000 description 1
- AWLBWJXVYGYRNY-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]cyclohexane Chemical compound COCC(COC)CCC1CCCCC1 AWLBWJXVYGYRNY-UHFFFAOYSA-N 0.000 description 1
- IFKPQKNFYPMKNL-UHFFFAOYSA-N [5-cyclohexyl-3,3-bis(methoxymethyl)pentyl]cyclohexane Chemical compound C1CCCCC1CCC(COC)(COC)CCC1CCCCC1 IFKPQKNFYPMKNL-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- XCIXKGXIYUWCLL-UHFFFAOYSA-N cyclopentanol Chemical compound OC1CCCC1 XCIXKGXIYUWCLL-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- OMRDZQXXMYCHBU-UHFFFAOYSA-N ethanol;propan-1-ol Chemical compound CCO.CCCO OMRDZQXXMYCHBU-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 235000019439 ethyl acetate Nutrition 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02080616 | 2002-12-18 |
Publications (1)
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| ZA200504127B true ZA200504127B (en) | 2006-02-22 |
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| ZA200504127A ZA200504127B (en) | 2002-12-18 | 2005-05-20 | Magnesium dichloride-based adducts and catalyst components obtained therefrom. |
| ZA200504131A ZA200504131B (en) | 2002-12-18 | 2005-05-20 | Catalyst components for the polymerization of oelefins. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200504131A ZA200504131B (en) | 2002-12-18 | 2005-05-20 | Catalyst components for the polymerization of oelefins. |
Country Status (16)
| Country | Link |
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| US (1) | US7427653B2 (enExample) |
| EP (1) | EP1572756B1 (enExample) |
| JP (2) | JP2006510751A (enExample) |
| KR (1) | KR101102793B1 (enExample) |
| CN (2) | CN1726080A (enExample) |
| AR (1) | AR042496A1 (enExample) |
| AU (1) | AU2003292199A1 (enExample) |
| BR (1) | BR0316913B1 (enExample) |
| CA (1) | CA2510679C (enExample) |
| ES (2) | ES2420879T3 (enExample) |
| MX (1) | MXPA05006584A (enExample) |
| RU (1) | RU2322457C2 (enExample) |
| SA (1) | SA03240450B1 (enExample) |
| TW (1) | TW200417554A (enExample) |
| WO (1) | WO2004055065A1 (enExample) |
| ZA (2) | ZA200504127B (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2527357A1 (en) * | 2003-05-29 | 2004-12-09 | Basell Poliolefine Italia S.R.L. | Process for the preparation of a catalyst component and components therefrom obtained |
| EP1780225A1 (en) | 2005-11-01 | 2007-05-02 | Borealis Technology Oy | Ziegler-Natta catalyst and its use to prepare multimodal polyolefin |
| BRPI0709454B8 (pt) * | 2006-04-06 | 2018-02-27 | Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp | complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas |
| CN101165074B (zh) * | 2006-10-20 | 2010-12-22 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
| CN101486776B (zh) * | 2008-01-17 | 2010-12-22 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
| RU2493175C2 (ru) * | 2008-09-26 | 2013-09-20 | Базелль Полиолефин Италия С.Р.Л. | Каталитические компоненты для полимеризации олефинов |
| RU2567391C2 (ru) | 2009-08-21 | 2015-11-10 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора |
| SA3686B1 (ar) | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
| US20110319571A1 (en) * | 2010-06-29 | 2011-12-29 | Botros Maged G | Polyolefin adhesive composition |
| US10138310B2 (en) * | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
| RU2579371C2 (ru) * | 2010-08-24 | 2016-04-10 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов |
| US20120053305A1 (en) * | 2010-08-24 | 2012-03-01 | Equistar Chemicals, Lp | Preparation of LLDPE having controlled xylene solubles or hexane extractables |
| RU2584694C2 (ru) * | 2010-09-28 | 2016-05-20 | Базелль Полиолефине Гмбх | Полиэтиленовые экструдированные изделия |
| CN103119072B (zh) * | 2010-09-30 | 2016-03-30 | 巴塞尔聚烯烃意大利有限责任公司 | 二氯化镁-醇加合物和由其获得的催化剂组分 |
| CN102585056A (zh) * | 2011-01-05 | 2012-07-18 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合反应的催化剂 |
| EP2610273B1 (en) * | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
| EP2692743A1 (en) | 2012-08-03 | 2014-02-05 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| EP2712875A1 (en) | 2012-09-28 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN103788246B (zh) * | 2012-10-29 | 2015-10-21 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂载体及其制备方法和应用 |
| CN104981487B (zh) * | 2013-01-31 | 2017-03-08 | 沙特基础工业公司 | 用于烯烃聚合的催化剂组合物 |
| KR102100006B1 (ko) * | 2013-02-27 | 2020-05-26 | 도호 티타늄 가부시키가이샤 | 프로필렌계 블록 공중합체의 제조 방법 |
| CN104231140B (zh) * | 2013-06-21 | 2016-12-07 | 中国石油天然气集团公司 | 一种乙烯-α-烯烃共聚催化剂及其制备和应用 |
| WO2015012963A1 (en) * | 2013-07-25 | 2015-01-29 | Exxonmobil Chemical Patents Inc. | Methods for polyolefin polymerization with high activity catalyst systems |
| FI3116921T3 (fi) * | 2014-03-14 | 2024-02-14 | Basell Poliolefine Italia Srl | Katalyyttikomponentteja olefiinien polymerointiin |
| FR3023183A1 (fr) * | 2014-07-04 | 2016-01-08 | IFP Energies Nouvelles | Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1 |
| CA2970848C (en) | 2014-12-18 | 2023-04-11 | Borealis Ag | Ziegler-natta catalyst and preparation thereof |
| CN112979842B (zh) | 2015-02-05 | 2022-11-11 | 博里利斯股份公司 | 用于生产聚乙烯的方法 |
| WO2017042058A1 (en) * | 2015-09-11 | 2017-03-16 | Basell Poliolefine Italia S.R.L. | Process for the preparation of catalyst components for the polymerization of olefins |
| BR112019000090A2 (pt) | 2016-07-15 | 2019-04-09 | Basell Poliolefine Italia Srl | catalisador para a polimerização de olefinas |
| BR112019011717B1 (pt) * | 2016-12-19 | 2022-11-01 | Basell Poliolefine Italia S.R.L. | Componente catalisador para a polimerização de olefinas, catalisadores obtidos a partir dos mesmos e processo para a (co)polimerização de olefinas |
| EP3339333B1 (en) | 2016-12-22 | 2020-10-07 | Borealis AG | Ziegler-natta catalyst and preparation thereof |
| BR112020001201B1 (pt) | 2017-07-19 | 2023-03-21 | Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation | Sistema catalisador ziegler-natta para polimerização olefínica, componente catalisador sólido para polimerização olefínica e processo de polimerização olefínica |
| SG11202005004UA (en) * | 2017-12-05 | 2020-06-29 | Univation Tech Llc | Activated spray-dried ziegler-natta catalyst system |
| SG11202004922SA (en) | 2017-12-05 | 2020-06-29 | Univation Tech Llc | Modified spray-dried ziegler-natta (pro)catalyst systems |
| EP3732208A1 (en) | 2017-12-27 | 2020-11-04 | Borealis AG | Ziegler-natta catalyst and preparation thereof |
| CA3086639A1 (en) | 2017-12-28 | 2019-07-04 | Borealis Ag | Catalyst and preparation thereof |
| WO2019231815A1 (en) * | 2018-06-01 | 2019-12-05 | Dow Global Technologies Llc | Ziegler-natta catalyst system having a thermally treated magnesium chloride component |
| CN114585654B (zh) | 2019-10-04 | 2023-11-07 | 北欧化工公司 | 用于烯烃聚合的齐格勒-纳塔催化剂 |
| WO2021064083A1 (en) | 2019-10-04 | 2021-04-08 | Borealis Ag | Ziegler-natta catalysts for olefin polymerization |
| EP4038110B1 (en) | 2019-10-04 | 2026-01-21 | Borealis GmbH | Ziegler-natta catalysts for olefin polymerization |
| CN114466872B (zh) | 2019-10-04 | 2024-01-30 | 北欧化工公司 | 用于烯烃聚合的齐格勒纳塔催化剂 |
| CN112812205B (zh) * | 2019-11-18 | 2023-05-09 | 中国石油化工股份有限公司 | 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用 |
| EP4143241A1 (en) | 2020-04-30 | 2023-03-08 | Dow Global Technologies LLC | Ziegler-natta (pro)catalyst systems made with (multi-alkoxy)silane compound |
| WO2022089423A1 (zh) * | 2020-10-26 | 2022-05-05 | 中国石油化工股份有限公司 | 用于制备烯烃聚合催化剂的固体组分及其制备方法和应用 |
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| RU2144041C1 (ru) * | 1992-08-31 | 2000-01-10 | Мицуи Кемикалз Инк. | Твердый титановый компонент катализатора для полимеризации олефинов, способ его получения, катализатор для полимеризации олефинов и способ полимеризации олефинов |
| JP3280477B2 (ja) * | 1992-08-31 | 2002-05-13 | 三井化学株式会社 | オレフィン重合用固体状チタン触媒成分の調製方法 |
| BR9405129A (pt) * | 1993-12-17 | 1995-08-22 | Union Carbide Chem Plastic | Sistema catalisador;processo para a polimerzação de etileno;processo para a produção de uma composição de tricloreto de titânio |
| JPH10158319A (ja) * | 1996-11-29 | 1998-06-16 | Tokuyama Corp | ポリプロピレンの製造方法 |
| ID20547A (id) | 1997-03-29 | 1999-01-14 | Montell Technology Company Bv | Hasil adisi magnesium diklorida-alkohol, proses untuk penyediaannya dan komponen katalis yang dihasilkannya |
| JP3895050B2 (ja) * | 1997-08-11 | 2007-03-22 | 三井化学株式会社 | 固体状チタン触媒成分の調製方法 |
| JP2002538244A (ja) * | 1999-03-03 | 2002-11-12 | イーストマン ケミカル カンパニー | ポリエチレンの製造方法 |
| CN1194993C (zh) | 2002-06-06 | 2005-03-30 | 中国石油化工股份有限公司 | 用于乙烯聚合的固体催化剂组分及其催化剂 |
| US7275148B2 (en) * | 2003-09-08 | 2007-09-25 | Freescale Semiconductor, Inc. | Data processing system using multiple addressing modes for SIMD operations and method thereof |
-
2003
- 2003-11-25 BR BRPI0316913-8A patent/BR0316913B1/pt active IP Right Grant
- 2003-11-25 CA CA2510679A patent/CA2510679C/en not_active Expired - Lifetime
- 2003-11-25 AU AU2003292199A patent/AU2003292199A1/en not_active Abandoned
- 2003-11-25 ES ES03767757T patent/ES2420879T3/es not_active Expired - Lifetime
- 2003-11-25 US US10/537,077 patent/US7427653B2/en not_active Expired - Lifetime
- 2003-11-25 RU RU2005122489/04A patent/RU2322457C2/ru active
- 2003-11-25 EP EP03767757.2A patent/EP1572756B1/en not_active Revoked
- 2003-11-25 MX MXPA05006584A patent/MXPA05006584A/es unknown
- 2003-11-25 WO PCT/EP2003/013807 patent/WO2004055065A1/en not_active Ceased
- 2003-11-25 CN CNA200380106191XA patent/CN1726080A/zh active Pending
- 2003-11-25 KR KR1020057011380A patent/KR101102793B1/ko not_active Expired - Lifetime
- 2003-11-25 ES ES03789154T patent/ES2368425T3/es not_active Expired - Lifetime
- 2003-11-25 CN CNB2003801061943A patent/CN100554287C/zh not_active Expired - Lifetime
- 2003-11-25 JP JP2004559767A patent/JP2006510751A/ja not_active Withdrawn
- 2003-12-10 TW TW092134831A patent/TW200417554A/zh unknown
- 2003-12-17 AR ARP030104667A patent/AR042496A1/es unknown
- 2003-12-20 SA SA03240450A patent/SA03240450B1/ar unknown
-
2005
- 2005-05-20 ZA ZA200504127A patent/ZA200504127B/en unknown
- 2005-05-20 ZA ZA200504131A patent/ZA200504131B/en unknown
-
2010
- 2010-07-30 JP JP2010172060A patent/JP5366898B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR0316913B1 (pt) | 2014-09-09 |
| TW200417554A (en) | 2004-09-16 |
| CA2510679A1 (en) | 2004-07-01 |
| ES2368425T3 (es) | 2011-11-17 |
| CN1726230A (zh) | 2006-01-25 |
| SA03240450B1 (ar) | 2009-01-19 |
| RU2322457C2 (ru) | 2008-04-20 |
| RU2005122489A (ru) | 2006-01-20 |
| ES2420879T3 (es) | 2013-08-27 |
| KR101102793B1 (ko) | 2012-01-05 |
| ZA200504131B (en) | 2006-02-22 |
| BR0316913A (pt) | 2005-10-18 |
| AU2003292199A1 (en) | 2004-07-09 |
| WO2004055065A1 (en) | 2004-07-01 |
| CN100554287C (zh) | 2009-10-28 |
| JP2006510751A (ja) | 2006-03-30 |
| AR042496A1 (es) | 2005-06-22 |
| JP5366898B2 (ja) | 2013-12-11 |
| JP2010280894A (ja) | 2010-12-16 |
| EP1572756A1 (en) | 2005-09-14 |
| EP1572756B1 (en) | 2013-04-10 |
| MXPA05006584A (es) | 2005-08-16 |
| US7427653B2 (en) | 2008-09-23 |
| CN1726080A (zh) | 2006-01-25 |
| KR20050084415A (ko) | 2005-08-26 |
| CA2510679C (en) | 2013-04-23 |
| US20060089251A1 (en) | 2006-04-27 |
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