ZA200303456B - Ligand and complex for catalytically bleaching a substrate. - Google Patents
Ligand and complex for catalytically bleaching a substrate. Download PDFInfo
- Publication number
- ZA200303456B ZA200303456B ZA200303456A ZA200303456A ZA200303456B ZA 200303456 B ZA200303456 B ZA 200303456B ZA 200303456 A ZA200303456 A ZA 200303456A ZA 200303456 A ZA200303456 A ZA 200303456A ZA 200303456 B ZA200303456 B ZA 200303456B
- Authority
- ZA
- South Africa
- Prior art keywords
- alkyl
- bleaching composition
- composition according
- pyridin
- ligand
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 title claims description 59
- 239000003446 ligand Substances 0.000 title claims description 49
- 239000000758 substrate Substances 0.000 title description 19
- 239000000203 mixture Substances 0.000 claims description 49
- 239000003054 catalyst Substances 0.000 claims description 26
- 229910052723 transition metal Inorganic materials 0.000 claims description 20
- 150000003624 transition metals Chemical class 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- 125000001072 heteroaryl group Chemical group 0.000 claims description 10
- -1 3-ethyl-pyridin-2-ylmethyl Chemical group 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims description 6
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000969 carrier Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 125000000160 oxazolidinyl group Chemical group 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000003386 piperidinyl group Chemical group 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000003363 1,3,5-triazinyl group Chemical group N1=C(N=CN=C1)* 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 2
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- CRVQUYKCAULKGD-UHFFFAOYSA-N diethyl 7-benzyl-3-(2-hydroxyethyl)-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OCC)C(C=3N=CC=CC=3)N(CCO)C(C=3N=CC=CC=3)C2(C(=O)OCC)CN1CC1=CC=CC=C1 CRVQUYKCAULKGD-UHFFFAOYSA-N 0.000 claims description 2
- QYDODLCXGSAOQP-UHFFFAOYSA-N dimethyl 9-oxo-2,4-dipyridin-2-yl-3,7-bis(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OC)C(C=3N=CC=CC=3)N(CC=3N=CC=CC=3)C(C=3N=CC=CC=3)C2(C(=O)OC)CN1CC1=CC=CC=N1 QYDODLCXGSAOQP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002883 imidazolyl group Chemical group 0.000 claims description 2
- 125000001041 indolyl group Chemical group 0.000 claims description 2
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 claims description 2
- 125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 125000002757 morpholinyl group Chemical group 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229960005141 piperazine Drugs 0.000 claims description 2
- 125000004193 piperazinyl group Chemical group 0.000 claims description 2
- 125000003373 pyrazinyl group Chemical group 0.000 claims description 2
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 2
- 125000002098 pyridazinyl group Chemical group 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 2
- 125000000719 pyrrolidinyl group Chemical group 0.000 claims description 2
- 125000001422 pyrrolinyl group Chemical group 0.000 claims description 2
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 2
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 claims description 2
- 125000001412 tetrahydropyranyl group Chemical group 0.000 claims description 2
- 125000003507 tetrahydrothiofenyl group Chemical group 0.000 claims description 2
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims description 2
- 125000000335 thiazolyl group Chemical group 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 125000001425 triazolyl group Chemical group 0.000 claims description 2
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- KKBIDYUDILUCRS-UHFFFAOYSA-N 6-[1,5-bis(methoxycarbonyl)-7-methyl-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonan-3-yl]hexanoic acid Chemical compound O=C1C2(C(=O)OC)CN(C)CC1(C(=O)OC)C(C=1N=CC=CC=1)N(CCCCCC(O)=O)C2C1=CC=CC=N1 KKBIDYUDILUCRS-UHFFFAOYSA-N 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- PTMNLCONTSIMOX-UHFFFAOYSA-N diethyl 9-oxo-2,4-dipyridin-2-yl-7-(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C(C)OC(=O)C12C(NC(C(CN(C1)CC1=NC=CC=C1)(C2=O)C(=O)OCC)C1=NC=CC=C1)C1=NC=CC=C1 PTMNLCONTSIMOX-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 description 26
- 239000004753 textile Substances 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 8
- 150000002431 hydrogen Chemical group 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 229940097156 peroxyl Drugs 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000004076 pulp bleaching Methods 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101100134922 Gallus gallus COR5 gene Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000006683 Mannich reaction Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- QJXIPSUPIMSFIQ-UHFFFAOYSA-N dimethyl 7-benzyl-3-(2-hydroxyethyl)-9-oxo-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate Chemical compound C1C(C2=O)(C(=O)OC)C(C=3N=CC=CC=3)N(CCO)C(C=3N=CC=CC=3)C2(C(=O)OC)CN1CC1=CC=CC=C1 QJXIPSUPIMSFIQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0030673.8A GB0030673D0 (en) | 2000-12-15 | 2000-12-15 | Ligand and complex for catalytically bleaching a substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200303456B true ZA200303456B (en) | 2004-08-13 |
Family
ID=9905193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200303456A ZA200303456B (en) | 2000-12-15 | 2003-05-06 | Ligand and complex for catalytically bleaching a substrate. |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6818149B2 (cs) |
| EP (1) | EP1379618B1 (cs) |
| CN (1) | CN1246432C (cs) |
| AR (1) | AR031908A1 (cs) |
| AT (1) | ATE329993T1 (cs) |
| AU (2) | AU3318702A (cs) |
| BR (1) | BR0116135B1 (cs) |
| CA (1) | CA2429629C (cs) |
| CZ (1) | CZ304488B6 (cs) |
| DE (1) | DE60120781T2 (cs) |
| ES (1) | ES2264707T3 (cs) |
| GB (1) | GB0030673D0 (cs) |
| HU (1) | HU229930B1 (cs) |
| MX (1) | MXPA03004887A (cs) |
| MY (1) | MY127232A (cs) |
| PL (1) | PL205956B1 (cs) |
| RU (1) | RU2283342C2 (cs) |
| WO (1) | WO2002048301A1 (cs) |
| ZA (1) | ZA200303456B (cs) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| JP4104966B2 (ja) * | 2002-03-06 | 2008-06-18 | 花王株式会社 | 漂白触媒 |
| PL374143A1 (en) * | 2002-06-06 | 2005-10-03 | Unilever N.V. | Ligand and complex for catalytically bleaching a substrate |
| GB0212991D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0212995D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| DE10257279A1 (de) * | 2002-12-07 | 2004-06-24 | Clariant Gmbh | Flüssige Bleichmittelkomponenten enthaltend amphiphile Polymere |
| RU2005136224A (ru) * | 2003-04-22 | 2006-06-10 | Анормед Инк. (Ca) | Гетероциклические соединения, связывающиеся с рецепторами хемокинов и обладающие повышенной эффективностью |
| GB0323275D0 (en) * | 2003-10-04 | 2003-11-05 | Unilever Plc | Bleaching composition |
| GB0325430D0 (en) * | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0325432D0 (en) | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0413058D0 (en) * | 2004-06-11 | 2004-07-14 | Unilever Plc | Bleaching composition |
| PL2009088T3 (pl) | 2004-09-23 | 2010-07-30 | Unilever Nv | Kompozycje do obróbki praniem |
| EP1700904A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid detergent composition |
| EP1700907A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid bleaching composition |
| DE102005027619A1 (de) * | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| WO2007051255A1 (en) * | 2005-11-04 | 2007-05-10 | The University Of Sydney | Process for the preparation of compounds containing an azacyclic ring system |
| ZA200900038B (en) | 2006-07-07 | 2010-04-28 | Unilever Plc | Liquid hardening |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| US8492324B2 (en) | 2008-04-09 | 2013-07-23 | Basf Se | Use of metal hydrazide complex compounds as oxidation catalysts |
| DE102008024084A1 (de) * | 2008-05-17 | 2009-11-19 | Clariant International Ltd. | Wasch- und Reinigungsmittel |
| DE102008038376A1 (de) | 2008-08-19 | 2010-02-25 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| DE102008045215A1 (de) | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Verwendung von Mangan-Oxalatenn als Bleichkatalysatoren |
| DE102008064009A1 (de) | 2008-12-19 | 2010-06-24 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metall-Komplexen |
| EP2228429A1 (en) | 2009-03-13 | 2010-09-15 | Unilever PLC | Shading dye and catalyst combination |
| EP2343336A1 (en) | 2010-01-06 | 2011-07-13 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Curing liquids |
| DE102010007058A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplex-Lösungen |
| DE102010007059A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplexen |
| CN101811068B (zh) * | 2010-03-31 | 2012-05-30 | 上海师范大学 | 哌嗪功能化有序介孔酚醛树脂固体碱催化剂的制备方法 |
| AU2011234744B2 (en) | 2010-03-31 | 2014-02-13 | Unilever Plc | Microcapsule incorporation in structured liquid detergents |
| WO2011120799A1 (en) | 2010-04-01 | 2011-10-06 | Unilever Plc | Structuring detergent liquids with hydrogenated castor oil |
| WO2011124282A1 (en) | 2010-04-08 | 2011-10-13 | Dsm Ip Assets B.V. | Unsaturated polyester resin or vinyl ester resin compositions |
| US9034785B2 (en) | 2010-06-16 | 2015-05-19 | Akzo Nobel Chemicals International B.V. | Accelerator solution and process for curing curable resins |
| ES2651319T3 (es) | 2010-06-28 | 2018-01-25 | Basf Se | Composición blanqueadora libre de metales |
| KR101895559B1 (ko) | 2010-10-11 | 2018-09-07 | 클라리언트 파이넌스 (비브이아이)리미티드 | ３，７디아자바이사이클로［３．３．１］노난 금속 착물의 제조방법 |
| EP2441820A1 (en) | 2010-10-14 | 2012-04-18 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Laundry detergent particles |
| BR112013008956A2 (pt) | 2010-10-22 | 2017-10-17 | Unilever Nv | kit de peças para tratar tecidos e uso do kit de peças |
| CA2820401C (en) | 2010-12-15 | 2018-10-02 | Ppg Europe Bv | Drier composition and use thereof |
| EP2474578A1 (en) | 2011-01-06 | 2012-07-11 | Rahu Catalytics Limited | Antiskinning compositions |
| MY163351A (en) | 2011-01-31 | 2017-09-15 | Unilever Plc | Alkaline liquid detergent compositions |
| EP2495300A1 (en) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuring detergent liquids with hydrogenated castor oil |
| EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2707472B1 (en) | 2011-05-13 | 2015-07-08 | Unilever PLC | Aqueous concentrated laundry detergent compositions |
| AU2012314532B2 (en) | 2011-09-26 | 2016-04-14 | Ppg Europe Bv | Coating composition and use thereof |
| KR101955058B1 (ko) | 2011-10-25 | 2019-03-06 | 헨켈 아게 운트 코 카게아아 | 세탁 과정에서의 오염 재부착방지제 및 방오제로서의 아크릴레이트 공중합체의 용도 |
| CN104105786A (zh) | 2011-10-25 | 2014-10-15 | 巴斯夫欧洲公司 | 梳形或嵌段共聚物作为抗污垢再沉积剂和去污剂在洗衣过程中的用途 |
| CN103174008A (zh) * | 2011-11-24 | 2013-06-26 | 东华大学 | 二吡啶基四氮金属配合物在纺织品低温练漂助剂中的应用 |
| EP2788443A1 (en) | 2011-12-06 | 2014-10-15 | DSM IP Assets B.V. | Resin composition |
| WO2013083632A1 (en) | 2011-12-06 | 2013-06-13 | Dsm Ip Assets B.V. | Multi-component system |
| CN103998593B (zh) * | 2011-12-20 | 2017-05-03 | 荷兰联合利华有限公司 | 包含脂肪酶和漂白催化剂的液体洗涤剂 |
| EP2794832B1 (en) | 2011-12-20 | 2016-05-25 | Unilever Plc. | Isotropic liquid detergents comprising soil release polymer |
| ES2556490T3 (es) | 2012-05-16 | 2016-01-18 | Unilever N.V. | Composiciones detergentes de lavado de ropa que comprenden polietilenimina polialcoxilada |
| US9187616B2 (en) | 2012-10-29 | 2015-11-17 | Ashland Licensing And Intellectual Property Llc | Resin compositions |
| WO2014114570A1 (en) | 2013-01-23 | 2014-07-31 | Unilever Plc | An uncoloured laundry additive material for promotion of anti redeposition of particulate soil |
| EP2770044A1 (en) | 2013-02-20 | 2014-08-27 | Unilever PLC | Lamellar gel with amine oxide |
| KR20150135489A (ko) | 2013-03-27 | 2015-12-02 | 바스프 에스이 | 세탁 과정에서 오염물 방출제로서 블록 공중합체 |
| US20160145464A1 (en) | 2013-07-25 | 2016-05-26 | Omg Uk Technology Limited | Encapsulated catalysts |
| BR112016003054B1 (pt) | 2013-08-16 | 2022-02-15 | Chemsenti Limited | Formulação de branqueamento, partícula, método e uso de uma partícula |
| CN103602268B (zh) * | 2013-10-10 | 2015-09-02 | 中钞油墨有限公司 | 环保型催干剂及其油墨组合物 |
| CN105873965B (zh) | 2013-11-27 | 2018-04-13 | 巴斯夫欧洲公司 | 在洗衣过程中作为去污剂的无规共聚物 |
| US20160304747A1 (en) | 2013-12-03 | 2016-10-20 | Ppg Europe B.V. | Drier Composition and Use Thereof |
| WO2016155993A1 (en) | 2015-04-02 | 2016-10-06 | Unilever Plc | Composition |
| AR104940A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método para generar dióxido de cloro |
| AR104939A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método oxidativo para generar dióxido de cloro |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| US10947480B2 (en) | 2016-05-17 | 2021-03-16 | Conopeo, Inc. | Liquid laundry detergent compositions |
| WO2017198574A1 (en) | 2016-05-17 | 2017-11-23 | Unilever Plc | Liquid laundry detergent compositions |
| WO2017202923A1 (en) | 2016-05-27 | 2017-11-30 | Unilever Plc | Laundry composition |
| EP3272823A1 (en) * | 2016-07-19 | 2018-01-24 | ALLNEX AUSTRIA GmbH | Drier compositions for alkyd resins |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| US12077652B2 (en) | 2018-07-05 | 2024-09-03 | Milliken Industrials Limited | Oxidatively curable coating composition |
| US20220073735A1 (en) | 2018-07-05 | 2022-03-10 | Borchers Catalyst (UK) Limited | Liquids |
| US11518834B2 (en) | 2019-01-02 | 2022-12-06 | Polynt Composites USA, Inc. | Radically polymerizable compositions |
| CZ309741B6 (cs) | 2020-06-24 | 2023-09-06 | Univerzita Pardubice | Nátěrová hmota obsahující sikativy na bázi sloučenin vanadu s kompenzujícími anionty sulfonových kyselin |
| EP3967742A1 (en) | 2020-09-15 | 2022-03-16 | WeylChem Performance Products GmbH | Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same |
| KR20240051242A (ko) | 2021-08-30 | 2024-04-19 | 보르헤르스 게엠베하 | 수지 성능을 개선하는 방법 |
| EP4408942A1 (en) | 2021-09-30 | 2024-08-07 | Borchers GmbH | Process for improving resin performance using lewis acids |
| CA3239645A1 (en) | 2021-12-22 | 2023-06-29 | Neil J. Simpson | Paints containing driers based on vanadium compounds bearing various acid anions |
| EP4299704A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A method of laundering and drying fabric |
| EP4299702A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A solid free-flowing particulate laundry detergent composition |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0070074B2 (en) | 1981-07-13 | 1997-06-25 | THE PROCTER & GAMBLE COMPANY | Foaming surfactant compositions |
| GB8803036D0 (en) | 1988-02-10 | 1988-03-09 | Unilever Plc | Liquid detergents |
| GB8813978D0 (en) | 1988-06-13 | 1988-07-20 | Unilever Plc | Liquid detergents |
| US5194416A (en) * | 1991-11-26 | 1993-03-16 | Lever Brothers Company, Division Of Conopco, Inc. | Manganese catalyst for activating hydrogen peroxide bleaching |
| DK144392D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| DK144192D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| JPH08506009A (ja) | 1992-12-01 | 1996-07-02 | ノボ ノルディスク アクティーゼルスカブ | 酵素反応の増強 |
| AU6870096A (en) | 1995-09-19 | 1997-04-09 | Novo Nordisk A/S | Stain bleaching |
| EP0892845A1 (en) | 1996-02-20 | 1999-01-27 | The Procter & Gamble Company | A cleaning composition comprising peroxidase |
| AU2287697A (en) | 1996-04-10 | 1997-10-29 | Unilever Plc | Cleaning process |
| AU2892897A (en) | 1996-06-19 | 1998-01-07 | Unilever Plc | Bleach activation |
| US5850086A (en) * | 1996-06-21 | 1998-12-15 | Regents Of The University Of Minnesota | Iron complexes for bleach activation and stereospecific oxidation |
| ATE282086T1 (de) | 1997-02-26 | 2004-11-15 | Novozymes As | Mikrobielle xyloglukanendotransglykosilase (xet) |
| US20030017941A1 (en) * | 1997-03-07 | 2003-01-23 | The Procter & Gamble Company | Catalysts and methods for catalytic oxidation |
| AU3717397A (en) | 1997-06-23 | 1999-01-04 | Procter & Gamble Company, The | Enzymatic detergent compositions |
| WO1999002638A1 (en) | 1997-07-09 | 1999-01-21 | The Procter & Gamble Company | Detergent compositions comprising a specific oxygenase |
| CA2295950A1 (en) | 1997-07-09 | 1999-01-21 | Alfred Busch | Cleaning compositions comprising a specific oxygenase |
| JP2001509535A (ja) | 1997-07-09 | 2001-07-24 | ザ、プロクター、エンド、ギャンブル、カンパニー | 特定のオキシゲナーゼを含有してなる洗浄組成物 |
| AU3668397A (en) | 1997-07-09 | 1999-02-08 | Procter & Gamble Company, The | Cleaning compositions comprising a cytochrome |
| CN1177536C (zh) | 1997-11-10 | 2004-12-01 | 诺沃奇梅兹有限公司 | 漆酶的抗微生物活性 |
| AU749512B2 (en) | 1998-06-15 | 2002-06-27 | Unilever Plc | Bleach catalysts and formulations containing them |
| PH11999002190B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Composition and method for bleaching a substrate |
| PH11999002188B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
| CA2349011A1 (en) | 1998-11-13 | 2000-05-25 | The Procter & Gamble Company | Bleach compositions comprising cross-bridged macropolycyclic transition metal bleach catalysts |
| US6117833A (en) | 1998-12-16 | 2000-09-12 | Lever Brothers Company | Bleaching compositions and method for bleaching substrates directly with air |
| AU4061900A (en) * | 1999-04-01 | 2000-10-23 | Procter & Gamble Company, The | Transition metal bleaching agents |
| GB0005090D0 (en) * | 2000-03-01 | 2000-04-26 | Unilever Plc | Bleaching and dye transfer inhibiting composition and method for laundry fabrics |
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0030877D0 (en) * | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
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- 2001-11-15 CA CA2429629A patent/CA2429629C/en not_active Expired - Fee Related
- 2001-11-15 DE DE60120781T patent/DE60120781T2/de not_active Expired - Lifetime
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- 2001-11-15 ES ES01984742T patent/ES2264707T3/es not_active Expired - Lifetime
- 2001-11-15 MX MXPA03004887A patent/MXPA03004887A/es unknown
- 2001-11-15 WO PCT/EP2001/013314 patent/WO2002048301A1/en active IP Right Grant
- 2001-11-15 BR BRPI0116135-0A patent/BR0116135B1/pt not_active IP Right Cessation
- 2001-11-15 AU AU2002233187A patent/AU2002233187B2/en not_active Ceased
- 2001-11-15 PL PL366179A patent/PL205956B1/pl unknown
- 2001-11-15 EP EP01984742A patent/EP1379618B1/en not_active Expired - Lifetime
- 2001-11-15 RU RU2003121409/04A patent/RU2283342C2/ru not_active IP Right Cessation
- 2001-11-15 CN CNB018205623A patent/CN1246432C/zh not_active Expired - Fee Related
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- 2001-11-15 HU HU0302768A patent/HU229930B1/hu not_active IP Right Cessation
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| EP1379618A1 (en) | 2004-01-14 |
| GB0030673D0 (en) | 2001-01-31 |
| EP1379618B1 (en) | 2006-06-14 |
| WO2002048301A1 (en) | 2002-06-20 |
| HU229930B1 (hu) | 2015-01-28 |
| HUP0302768A2 (hu) | 2003-11-28 |
| DE60120781D1 (de) | 2006-07-27 |
| MXPA03004887A (es) | 2003-08-19 |
| ES2264707T3 (es) | 2007-01-16 |
| US20020149000A1 (en) | 2002-10-17 |
| CN1481435A (zh) | 2004-03-10 |
| US20050032662A1 (en) | 2005-02-10 |
| RU2283342C2 (ru) | 2006-09-10 |
| AU3318702A (en) | 2002-06-24 |
| BR0116135B1 (pt) | 2012-06-12 |
| AU2002233187B2 (en) | 2006-03-30 |
| CA2429629C (en) | 2011-05-31 |
| MY127232A (en) | 2006-11-30 |
| PL205956B1 (pl) | 2010-06-30 |
| DE60120781T2 (de) | 2007-01-25 |
| ATE329993T1 (de) | 2006-07-15 |
| CZ304488B6 (cs) | 2014-05-28 |
| CA2429629A1 (en) | 2002-06-20 |
| CN1246432C (zh) | 2006-03-22 |
| BR0116135A (pt) | 2003-10-28 |
| PL366179A1 (en) | 2005-01-24 |
| CZ20031655A3 (cs) | 2003-12-17 |
| US6818149B2 (en) | 2004-11-16 |
| AR031908A1 (es) | 2003-10-08 |
| HUP0302768A3 (en) | 2012-10-29 |
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