WO2022180480A1 - 半導体装置、及び電子機器 - Google Patents
半導体装置、及び電子機器 Download PDFInfo
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Definitions
- One embodiment of the present invention relates to semiconductor devices, display devices, display modules, and electronic devices.
- One embodiment of the present invention relates to a method for manufacturing a display device.
- one aspect of the present invention is not limited to the above technical field.
- Technical fields of one embodiment of the present invention include semiconductor devices, display devices, light-emitting devices, power storage devices, memory devices, electronic devices, lighting devices, input devices (eg, touch sensors), and input/output devices (eg, touch panels). , their driving method or their manufacturing method can be mentioned as an example.
- information terminal devices such as mobile phones such as smartphones, tablet information terminals, and notebook PCs (personal computers) have become widespread.
- Such information terminal equipment often contains personal information and the like, and various authentication techniques have been developed to prevent unauthorized use.
- information terminal equipment having various functions such as an image display function, a touch sensor function, and a fingerprint imaging function for authentication.
- Patent Document 1 discloses an electronic device having a fingerprint sensor in a push button switch section.
- a light-emitting device having a light-emitting device has been developed.
- a light-emitting device also referred to as an EL device or EL element
- EL the phenomenon of electroluminescence
- EL is a DC constant-voltage power supply that can easily be made thin and light, can respond quickly to an input signal, and It is applied to a display device.
- An object of one embodiment of the present invention is to provide a semiconductor device having a photodetection function and a high-definition display portion.
- An object of one embodiment of the present invention is to provide a semiconductor device having a photodetection function and a high-resolution display portion.
- An object of one embodiment of the present invention is to provide a semiconductor device having a light detection function and including a large-sized display portion.
- An object of one embodiment of the present invention is to provide a highly reliable semiconductor device having a photodetection function.
- An object of one embodiment of the present invention is to provide a method for manufacturing a semiconductor device having a photodetection function and a high-definition display portion.
- An object of one embodiment of the present invention is to provide a method for manufacturing a semiconductor device having a light detection function and a high-resolution display portion.
- An object of one embodiment of the present invention is to provide a method for manufacturing a semiconductor device having a light detection function and a large display portion.
- An object of one embodiment of the present invention is to provide a method for manufacturing a highly reliable semiconductor device having a photodetection function.
- An object of one embodiment of the present invention is to provide a method for manufacturing a semiconductor device having a photodetection function with high yield.
- One embodiment of the present invention is a semiconductor device including a plurality of pixels.
- the pixel has a first pixel circuit.
- the first pixel circuit includes a first light receiving device, a second light receiving device, a first transistor, a second transistor, a third transistor, a fourth transistor, and a fifth transistor. , a capacitor, and a first wiring.
- One electrode of the first light receiving device is electrically connected to the first wiring, and the other electrode of the first light receiving device is electrically connected to one of the source and the drain of the first transistor.
- One electrode of the second light receiving device is electrically connected to the first wiring, and the other electrode of the second light receiving device is electrically connected to one of the source and the drain of the second transistor. .
- the other of the source and drain of the second transistor is electrically connected to the other of the source and drain of the first transistor.
- the other of the source and drain of the first transistor is electrically connected to one electrode of the capacitor.
- the other of the source or drain of the first transistor is electrically connected to one of the source or drain of the third transistor.
- the other of the source or drain of the first transistor is electrically connected to the gate of the fourth transistor.
- One of the source or drain of the fourth transistor is electrically connected to one of the source or drain of the fifth transistor.
- the first light receiving device has a function of detecting visible light
- the second light receiving device has a function of detecting infrared light
- the semiconductor device described above preferably has a second wiring.
- the second wiring is electrically connected to the other of the source and drain of the third transistor.
- the potential of the second wiring is preferably lower than the potential of the first wiring.
- the semiconductor device described above preferably has a second wiring.
- the second wiring is electrically connected to the other of the source and drain of the third transistor.
- the potential of the second wiring is preferably higher than the potential of the first wiring.
- the pixel preferably has a second pixel circuit.
- a second pixel circuit has a first light emitting device.
- the first light emitting device has a function of emitting visible light, and one electrode of the first light emitting device is electrically connected to the first wiring.
- the pixel preferably has a third pixel circuit.
- a third pixel circuit has a second light emitting device.
- the second light emitting device has a function of emitting infrared light, and one electrode of the second light emitting device is electrically connected to the first wiring.
- One embodiment of the present invention is an electronic device including the above semiconductor device, a second light-emitting device, and a housing.
- the second light emitting device has a function of emitting infrared light
- the second light emitting device has a function of emitting light to the outside through the semiconductor device.
- a semiconductor device having a photodetection function and a high-definition display portion can be provided.
- a semiconductor device having a photodetection function and a high-resolution display portion can be provided.
- a semiconductor device having a semiconductor device having a light detection function and a large display portion can be provided.
- a highly reliable semiconductor device having a photodetection function can be provided.
- a method for manufacturing a semiconductor device having a photodetection function and a high-definition display portion can be provided.
- a method for manufacturing a semiconductor device having a photodetection function and a high-resolution display portion can be provided.
- a method for manufacturing a semiconductor device having a light detection function and a large display portion can be provided.
- a method for manufacturing a highly reliable semiconductor device having a photodetection function can be provided.
- a method for manufacturing a semiconductor device having a photodetection function with high yield can be provided.
- FIG. 1A is a block diagram showing an example of a display device.
- FIG. 1B is a diagram illustrating an example of a pixel of a display device; 2A and 2B are diagrams showing examples of pixel circuits.
- FIG. 3 is a diagram showing an example of a pixel circuit.
- FIG. 4A is a block diagram showing an example of a read circuit.
- FIG. 4B is a circuit diagram of a readout circuit.
- FIG. 5 is a diagram illustrating an example of a display unit of a display device.
- FIG. 6 is a diagram illustrating an example of a display unit of a display device.
- FIG. 7 is a diagram showing an example of a display device.
- 8A and 8B are diagrams for explaining an example of the operation method of the display device.
- FIG. 1A is a block diagram showing an example of a display device.
- FIG. 1B is a diagram illustrating an example of a pixel of a display device
- FIG. 9 is a diagram illustrating an example of a method of operating the display device.
- FIG. 10 is a diagram illustrating an example of a display unit of a display device;
- FIG. 11 is a diagram illustrating an example of a display unit of a display device;
- 12A and 12B are diagrams showing an example of a display unit of a display device.
- 13A and 13B are diagrams showing an example of a display unit of a display device.
- FIG. 14A is a diagram showing an example of pixels of a display device.
- 14B and 14C are cross-sectional views showing examples of electronic devices.
- 15A and 15B are cross-sectional views showing examples of electronic devices.
- 16A to 16C are diagrams showing examples of pixels of a display device.
- FIG. 16D is a cross-sectional view showing an example of an electronic device
- FIG. 17 is a diagram showing an example of the layout of the display device.
- FIG. 18 is a diagram showing an example of the layout of the display device.
- FIG. 19 is a diagram showing an example of the layout of the display device.
- FIG. 20 is a diagram showing an example of the layout of the display device.
- 21A and 21B are diagrams showing examples of pixels of a display device.
- 21C and 21D are cross-sectional views showing examples of electronic devices.
- FIG. 22 is a diagram illustrating an example of a layout of a display device
- 23A to 23C are diagrams illustrating an example of a display device.
- 24A to 24C are diagrams illustrating examples of electronic devices.
- 25A is a top view showing an example of a display device.
- FIG. 25B is a cross-sectional view showing an example of a display device;
- 26A to 26D are diagrams illustrating an example of a method for manufacturing a display device.
- 27A to 27C are diagrams illustrating an example of a method for manufacturing a display device.
- 28A to 28C are diagrams illustrating an example of a method for manufacturing a display device.
- 29A to 29C are diagrams illustrating an example of a method for manufacturing a display device.
- FIG. 30A is a top view showing an example of a display device;
- FIG. 30B is a cross-sectional view showing an example of a display device;
- FIG. 31 is a perspective view showing an example of a display device;
- FIG. 30A is a top view showing an example of a display device;
- FIG. 30B is a cross-sectional view showing an example of a display device;
- FIG. 31 is a perspective view
- 32A is a cross-sectional view showing an example of a display device
- 32B and 32C are cross-sectional views showing examples of transistors.
- 33A to 33D are diagrams showing configuration examples of light-emitting devices.
- 34A and 34B are cross-sectional views showing an example of a display device.
- 35A and 35B are cross-sectional views showing examples of display devices.
- 36A and 36B are cross-sectional views showing examples of display devices.
- 37A to 37C are cross-sectional views showing examples of display devices.
- 38A and 38B are diagrams illustrating examples of electronic devices.
- 39A to 39D are diagrams showing examples of electronic devices.
- 40A to 40F are diagrams showing examples of electronic devices.
- FIG. 41 is a diagram showing an example of a vehicle.
- film and “layer” can be interchanged depending on the case or situation.
- conductive layer can be changed to the term “conductive film.”
- insulating film can be changed to the term “insulating layer”.
- a display device In this embodiment, a display device will be described as a semiconductor device of one embodiment of the present invention.
- a display device of one embodiment of the present invention includes a pixel including a light-emitting device, a first light-receiving device, and a second light-receiving device.
- a display device of one embodiment of the present invention can display an image using a light-emitting device. Further, the display device of one embodiment of the present invention can perform one or both of imaging and sensing using the first light receiving device or the second light receiving device.
- FIG. 1A A block diagram of a display device which is one embodiment of the present invention is shown in FIG. 1A.
- a display device 10 shown in FIG. 1A includes a display section 11 , a drive circuit section 12 , a drive circuit section 13 , a drive circuit section 14 and a circuit section 15 .
- the display unit 11 has a plurality of pixels 30 arranged in a matrix.
- FIG. 1B A configuration example of the pixel 30 is shown in FIG. 1B.
- the pixel 30 has subpixels G, subpixels B, subpixels R, subpixels PS, and subpixels IRS.
- Each of the sub-pixel G, sub-pixel B, and sub-pixel R has a function of emitting light (hereinafter also referred to as a light emitting function).
- Each of the sub-pixels PS and sub-pixels IRS has a function of receiving light (hereinafter also referred to as a light receiving function).
- a display portion of a display device which is one embodiment of the present invention has one or both of an imaging function and a sensing function in addition to a function of displaying an image.
- the sub-pixel R may be red
- the sub-pixel G may be green
- the sub-pixel B may be blue. Accordingly, the display device 10 can perform full-color display.
- the pixel 30 may have sub-pixels of three colors.
- the pixel 30 may have sub-pixels of four or more colors.
- the pixel 30 may have sub-pixels exhibiting light other than red, green, and blue.
- the pixel 30 may have a sub-pixel that emits white light, a sub-pixel that emits yellow light, or the like.
- the sub-pixel PS has a function of receiving visible light.
- the sub-pixel IRS has a function of receiving infrared light.
- Each of sub-pixel R, sub-pixel G, and sub-pixel B has a light-emitting device (also referred to as a light-emitting element).
- Sub-pixel R has a light-emitting device that exhibits red light.
- Sub-pixel G has a light-emitting device that exhibits green light.
- Sub-pixel B has a light-emitting device that emits blue light.
- Each of the sub-pixels PS and sub-pixels IRS has a light receiving device (also referred to as a light receiving element) that functions as a photoelectric conversion element.
- a light-receiving device functions as a photoelectric conversion device that detects light incident on the light-receiving device and generates an electric charge. The amount of charge generated is determined based on the amount of light incident on the light receiving device.
- the sub-pixel PS has a light receiving device capable of receiving visible light.
- the sub-pixel IRS has a light receiving device capable of receiving infrared light.
- a light receiving device having a function of receiving visible light is sensitive to visible light (light having a wavelength of 400 nm or more and less than 700 nm).
- a light receiving device that receives infrared light has sensitivity to infrared light (light with a wavelength of 700 nm or more and less than 900 nm).
- the light emitting region of subpixel R is R
- the light emitting region of subpixel G is G
- the light emitting region of subpixel B is B
- the light receiving region of subpixel PS is B.
- IRS is attached to the light-receiving region of PS and sub-pixel IRS.
- FIG. 1B shows the light-emitting region and the light-receiving region as rectangles, one embodiment of the present invention is not limited to this.
- the shapes of the light-emitting region and the light-receiving region are not particularly limited.
- the area of the light-receiving region of the sub-pixel PS (also simply referred to as the light-receiving area) is preferably smaller than the light-receiving area of the sub-pixel IRS.
- the sub-pixel PS can perform higher-definition imaging than the sub-pixel IRS.
- the sub-pixel PS can be used for imaging for personal authentication using a fingerprint, palm print, iris, pulse shape (including vein shape and artery shape), face, or the like.
- the sub-pixel PS may appropriately determine the wavelength of light to be detected according to the application.
- the sub-pixel IRS can be used for a touch sensor (also called a direct touch sensor) or a near-touch sensor (also called a hover sensor, hover touch sensor, non-contact sensor, touchless sensor), or the like.
- a touch sensor also called a direct touch sensor
- a near-touch sensor also called a hover sensor, hover touch sensor, non-contact sensor, touchless sensor
- the sub-pixel IRS enables touch detection even in a dark place.
- the sub-pixel IRS may appropriately determine the wavelength of light to be detected according to the application.
- the touch sensor or near-touch sensor can detect the proximity or contact of an object (finger, hand, pen, etc.).
- a touch sensor can detect an object by direct contact between the display device and the object.
- the near-touch sensor can detect the object even if the object does not touch the display device.
- the display device can detect the object when the distance between the display device and the object is 0.1 mm or more and 300 mm or less, preferably 3 mm or more and 50 mm or less.
- the display device can be operated without direct contact with the object, in other words, the display device can be operated without contact.
- the risk of staining or scratching the display device can be reduced, or the object can be displayed without directly touching the stain (for example, dust or virus) attached to the display device. It becomes possible to operate the device.
- a display device of one embodiment of the present invention can have a variable refresh rate. For example, it is possible to reduce power consumption by adjusting the refresh rate (for example, in the range of 1 Hz to 240 Hz) according to the content displayed on the display device. Further, the drive frequency of the touch sensor or the near-touch sensor may be changed according to the refresh rate. For example, when the refresh rate of the display device is 120 Hz, the driving frequency of the touch sensor or the near-touch sensor can be higher than 120 Hz (typically 240 Hz). With this structure, low power consumption can be achieved and the response speed of the touch sensor or the near touch sensor can be increased.
- a target detection method may be selected according to the function, based on the difference in detection accuracy between the light receiving device of the sub-pixel PS and the light receiving device of the sub-pixel IRS.
- the scrolling function of the display screen is realized by the near touch sensor function using the sub-pixel IRS
- the input function with the keyboard displayed on the screen is realized by the high-definition touch sensor function using the sub-pixel PS.
- the sub-pixels PS are provided in all the pixels included in the display device.
- the sub-pixel IRS used for a touch sensor or a near-touch sensor does not require high accuracy as compared to detection using the sub-pixel PS, so it may be provided in some pixels included in the display device.
- FIG. 1B shows an example in which sub-pixels are provided over 2 rows and 3 columns for one pixel 30 .
- the pixel 30 has three sub-pixels (sub-pixel G, sub-pixel B, sub-pixel R) in the upper row (first row) and two sub-pixels (sub-pixel R) in the lower row (second row).
- sub-pixel PS, sub-pixel IRS sub-pixel IRS
- the pixel 30 has two sub-pixels (sub-pixel G, sub-pixel PS) in the left column (first column) and sub-pixel B in the center column (second column). It has sub-pixels R in the right column (third column), and sub-pixels IRS over these two columns. Note that the arrangement of sub-pixels is not limited to the configuration shown in FIG. 1B.
- the pixel 30 has a pixel circuit 21R, a pixel circuit 21G, a pixel circuit 21B, and a pixel circuit 22.
- the pixel circuit 21R has a function of controlling light emission of the sub-pixel R.
- the pixel circuit 21G has a function of controlling light emission of the sub-pixel G.
- FIG. The pixel circuit 21B has a function of controlling light emission of the sub-pixel B.
- FIG. The pixel circuit 22 has a function of controlling light reception by the sub-pixel PS and a function of controlling light reception by the sub-pixel IRS. It can be said that the sub-pixel PS and the sub-pixel IRS share the pixel circuit 22 .
- a wiring SE, a wiring RE, a wiring TX, a wiring SW, and a wiring WX are electrically connected to the pixel circuit 22 .
- the wiring SE, the wiring RE, the wiring TX, and the wiring SW are each electrically connected to the pixel circuits 22 arranged in the row direction (the extending direction of the wiring SE and the like).
- the wiring SE, the wiring RE, the wiring TX, and the wiring SW are each electrically connected to the drive circuit section 14 .
- the drive circuit unit 14 has a function of generating a signal for driving the pixel circuit 22 and outputting the signal to the pixel circuit 22 via the wiring SE, the wiring RE, the wiring TX, and the wiring SW.
- the drive circuit unit 14 has a function of selecting the pixels 30 from which imaging data are read. Specifically, by supplying a signal to the wiring SE, it is possible to select the pixel 30 from which the imaging data is read.
- the wiring WX is electrically connected to the pixel circuits 22 arranged in the column direction (the extending direction of the wiring WX).
- the wiring WX is electrically connected to the circuit section 15 .
- the circuit unit 15 has a function of receiving a signal output from the pixel circuit 22 via the wiring WX and outputting it to the outside as imaging data.
- the circuit section 15 functions as a readout circuit. Further, the wiring WX can be called a readout line.
- imaging data refers to data corresponding to the amount of light incident on the light receiving device of the pixel circuit 22 .
- a signal output from the pixel circuit 22 to the circuit unit 15 may be referred to as imaging data.
- the signal output from the circuit section 15 to the outside may be referred to as imaging data.
- a wiring SLR, a wiring GL1, and a wiring GL2 are electrically connected to the pixel circuit 21R.
- a wiring SLG, a wiring GL1, and a wiring GL2 are electrically connected to the pixel circuit 21G.
- a wiring SLB, a wiring GL1, and a wiring GL2 are electrically connected to the pixel circuit 21B.
- the wiring SLR, the wiring SLG, and the wiring SLB are electrically connected to the pixel circuits 21R, 21G, or 21B arranged in the column direction (the direction in which the wiring SLR and the like extend).
- the wiring SLR, the wiring SLG, and the wiring SLB are each electrically connected to the driver circuit section 12 .
- the driver circuit portion 12 functions as a source line driver circuit (also referred to as a source driver), and supplies data signals (data signals) to the pixel circuits 21R, 21G, and 21B via the wirings SLR, SLG, and SLB. potential).
- the wiring GL1 and the wiring GL2 are electrically connected to the pixel circuits 21R, 21G, and 21B arranged in the row direction (the extending direction of the wiring GL1 and the wiring GL2), respectively.
- the wiring GL1 and the wiring GL2 are electrically connected to the driving circuit section 13 respectively.
- the driver circuit portion 13 functions as a gate line driver circuit (also referred to as a gate driver) and supplies selection signals to the wirings GL1 and GL2.
- pixels 30 including pixel circuits 21R, 21G, 21B, and 22 in a matrix, display resolution (the number of pixels) and imaging resolution ( number of pixels) can be the same. Note that high resolution may not be necessary when the pixel circuit 22 is used only as a touch panel. In that case, the pixel 30 including the pixel circuit 22 and the pixel not including the pixel circuit 22 (that is, the pixel including the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B) may be mixed.
- FIG. 2A An example of a pixel circuit that can be applied to pixel circuit 22 is shown in FIG. 2A.
- the pixel circuit 22 has a transistor M11, a transistor M12, a transistor M13, a transistor M14, a transistor M15, a capacitor C11, a light receiving device PD1, and a light receiving device PD2.
- One terminal of the light receiving device PD1 is electrically connected to one of the source and drain of the transistor M11.
- the other terminal of the light receiving device PD1 is electrically connected to the wiring CL.
- a gate of the transistor M11 is electrically connected to the wiring TX.
- One terminal of light receiving device PD2 is electrically connected to one of the source and drain of transistor M15.
- the other terminal of light receiving device PD2 is electrically connected to line CL.
- a gate of the transistor M15 is electrically connected to the wiring SW.
- the other of the source and the drain of the transistor M15 is electrically connected to the other of the source and the drain of the transistor M11.
- the other of the source and the drain of transistor M11 is electrically connected to one electrode of capacitor C11.
- the other electrode of the capacitor C11 is electrically connected to the wiring VCP.
- the other of the source and drain of the transistor M11 is electrically connected to one of the source and drain of the transistor M12.
- a gate of the transistor M12 is electrically connected to the wiring RS.
- the other of the source and drain of the transistor M12 is electrically connected to the wiring VRS.
- the other of the source and drain of transistor M11 is electrically connected to the gate of transistor M13.
- One of the source and drain of the transistor M13 is electrically connected to the wiring VPI.
- the other of the source and drain of the transistor M13 is electrically connected to one of the source and drain of the transistor M14.
- a gate of the transistor M14 is electrically connected to the wiring SE.
- the other of the source and drain of the transistor M14 is electrically connected to the wiring WX.
- a signal for controlling the conduction/non-conduction of the transistor M14 is applied to the wire SE.
- a signal for controlling conduction/non-conduction of the transistor M12 is supplied to the wiring RS.
- a signal for controlling conduction/non-conduction of the transistor M11 is supplied to the wiring TX.
- a signal for controlling conduction/non-conduction of the transistor M15 is supplied to the wiring SW.
- a constant potential is applied to the wiring VCP.
- a constant potential is applied to the wiring VRS as a reset potential.
- a constant potential is applied to the wiring VPI.
- the transistor M11, transistor M12, transistor M14, and transistor M15 function as switches.
- the transistor M13 functions as an amplifying element (amplifier).
- the potential applied to the wiring VRS is higher than the potential applied to the wiring CL. Low is preferred.
- the potential applied to the wiring VRS is preferably higher than the potential applied to the wiring CL.
- a light receiving device having a function of receiving visible light can be used as the light receiving device PD1, and a light receiving device having a function of receiving infrared light can be used as the light receiving device PD2.
- a light receiving device having a function of receiving infrared light may be used as the light receiving device PD1
- a light receiving device having a function of receiving visible light may be used as the light receiving device PD2.
- the pixel circuit 22 has a function of controlling light reception by the subpixel PS and a function of controlling light reception by the subpixel IRS.
- the pixel circuit 22 includes transistors, wiring, and the like. Since the number can be reduced and the pixel size can be reduced, a high-definition display device can be obtained.
- all of the transistors included in the pixel circuit 22 include a transistor including a metal oxide (hereinafter also referred to as an oxide semiconductor) in a semiconductor layer in which a channel is formed (hereinafter also referred to as an OS transistor). ) is preferably used.
- An OS transistor has extremely low off-state current and can hold charge accumulated in a capacitor connected in series with the transistor for a long time. Further, with the use of the OS transistor, power consumption of the display device can be reduced.
- transistors including silicon in a semiconductor layer in which a channel is formed are preferably used for all the transistors included in the pixel circuit.
- silicon include monocrystalline silicon, polycrystalline silicon, amorphous silicon, and the like.
- a transistor including low-temperature polysilicon (LTPS) in a semiconductor layer is preferably used.
- the LTPS transistor has high field effect mobility and can operate at high speed.
- the pixel circuit preferably includes an OS transistor and an LTPS transistor.
- OS transistor an OS transistor
- LTPS transistor an LTPS transistor
- LTPS transistors using low-temperature polysilicon for semiconductor layers for all of the transistors M11 to M15.
- an OS transistor using a metal oxide for a semiconductor layer as the transistor M11, the transistor M12, and the transistor M15, and use an LTPS transistor as the transistor M13.
- an OS transistor or an LTPS transistor may be used as the transistor M14.
- the potential held at the gate of the transistor M13 changes based on the charges generated in the light receiving device PD1 and the light receiving device PD2. Leakage through transistor M15 can be prevented.
- an LTPS transistor it is preferable to apply an LTPS transistor to the transistor M13.
- An LTPS transistor can achieve higher field-effect mobility than an OS transistor, and has excellent driving capability and current capability. Therefore, the transistor M13 can operate faster than the transistors M11, M12, and M15.
- an LTPS transistor for the transistor M13, it is possible to quickly output to the transistor M14 a minute potential based on the amount of light received by the light receiving device PD1 or the light receiving device PD2.
- the transistors M11, M12, and M15 have low leakage current, and the transistor M13 has high driving capability. Charge transferred through M11 and transistor M15 can be held without leaking, and reading can be performed at high speed.
- the transistor M14 functions as a switch that passes the output from the transistor M13 to the wiring WX, unlike the transistors M11 to M13 and the transistor M15, low off-state current, high-speed operation, and the like are not necessarily required. Therefore, low-temperature polysilicon or an oxide semiconductor may be applied to the semiconductor layer of the transistor M14.
- transistors are shown as n-channel transistors in FIG. 2A, p-channel transistors can also be used.
- the aperture ratio (light-receiving area) of the light-receiving device is small.
- the aperture ratio (light receiving area) of the light receiving device is large. Therefore, it is preferable that the aperture ratio (light-receiving area) of the light-receiving device PD1 is smaller than the aperture ratio (light-receiving area) of the light-receiving device PD2.
- imaging that requires high definition it is preferable to perform imaging using only the light receiving device PD1 by turning on the transistor M11 and turning off the transistor M15.
- the display device of this embodiment by mounting two types of light receiving devices in one pixel, two functions can be added in addition to the display function.
- the functions of the display device can be further increased.
- a light-emitting device that emits infrared light, or a pixel having various sensor devices can be used.
- FIG. 2B An example of a pixel circuit that can be applied to the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B is shown in FIG. 2B.
- the pixel circuit 21 shown in FIG. 2B has a transistor M1, a transistor M2, a transistor M3, a transistor M4, a capacitor C1, a capacitor C2, and a light emitting device EL.
- the transistor M1 has a gate electrically connected to the wiring GL1, one of its source and drain electrically connected to the wiring SL, and the other electrically connected to one electrode of the capacitor C1, one electrode of the capacitor C2, and the transistor M2. electrically connected to the gate.
- the transistor M2 has one of its source and drain electrically connected to the wiring AL, and the other of its source and drain connected to one electrode of the light-emitting device EL, the other electrode of the capacitor C1, and one of the source and drain of the transistor M3. electrically connected.
- the transistor M3 has a gate electrically connected to the wiring GL1, and the other of its source and drain electrically connected to the other electrode of the capacitor C2.
- the transistor M4 has a gate electrically connected to the wiring GL2, one of its source and drain electrically connected to the other electrode of the capacitor C2, and the other electrically connected to the wiring V0L.
- the other electrode of the light emitting device EL is electrically connected to the wiring CL.
- the transistor M1, transistor M3 and transistor M4 function as switches.
- the transistor M2 functions as a transistor for controlling the current flowing through the light emitting device EL.
- LTPS transistors it is preferable to apply LTPS transistors to all of the transistors M1 to M4.
- OS transistor for the transistor M1, the transistor M3, and the transistor M4, and an LTPS transistor for the transistor M2.
- a data potential is applied to the wiring SL.
- a selection signal is supplied to each of the wiring GL1 and the wiring GL2.
- the selection signal includes a potential that makes the transistor conductive and a potential that makes the transistor non-conductive.
- a constant potential is applied to the wiring AL.
- a constant potential is applied to the wiring CL.
- the potential applied to the wiring AL is preferably higher than the potential applied to the wiring CL.
- the potential applied to the wiring AL is preferably lower than the potential applied to the wiring CL.
- pixel circuits that can be applied to the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B are not limited to the pixel circuit 21 shown in FIG. 2B.
- FIG. 1 An example of a circuit diagram of the pixel 30 having the pixel circuit 22, the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B is shown in FIG.
- the pixel circuit 21R has a light emitting device ELR that emits red light.
- the pixel circuit 21G has a light emitting device ELG that emits green light.
- the pixel circuit 21B has a light emitting device ELB that emits blue light.
- the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B have the same configuration except for the light emitting device.
- one electrode of the light receiving device PD1, one electrode of the light receiving device PD2, one electrode of the light emitting device ELR, one electrode of the light emitting device ELG, and one electrode of the light emitting device ELB are connected to the wiring CL. It shows an electrically connected configuration. With such a structure, the number of wirings included in the pixel 30 can be reduced and the size of the pixel 30 can be reduced, so that a high-definition display device can be obtained.
- One electrode of the light receiving device PD1, one electrode of the light receiving device PD2, one electrode of the light emitting device ELR, one electrode of the light emitting device ELG, and one electrode of the light emitting device ELB are connected to different wirings. It may be configured to be
- the configurations of the pixel circuit 21R, the pixel circuit 21G, and the pixel circuit 21B are not limited to the configuration shown in FIG.
- FIG. 4A An example of a circuit that can be used as a readout circuit is shown in FIG. 4A.
- the circuit 50 shown in FIG. 4A can be applied to the circuit portion 15 shown in FIG. 1A.
- Circuit 50 includes multiple circuits 51 , multiple circuits 52 , circuit 53 , circuit 54 , and circuit 55 .
- a signal is input to the circuit 50 from the K-th to K+p-th (K is an integer equal to or more than 1 and equal to or less than N) wirings WX[K:K+p].
- One circuit 50 can receive signals from the wirings WX in a number obtained by dividing the number N (N is an integer of 2 or more) of the pixels 30 arranged in the row direction by an arbitrary integer x. That is, p is an integer that satisfies N/x ⁇ 1, and the circuit 50 receives signals from N/x wirings WX.
- the display device can have a structure including x circuits 50 as readout circuits. If N is not a multiple of x, the number of wirings WX connected to one circuit 50 may be adjusted as appropriate.
- the circuit 51 is a circuit that converts a current output to one of the wirings WX into a voltage and outputs the voltage.
- the circuit 51 can use a circuit forming a source follower circuit together with the transistor M13 of the pixel circuit 22 described above.
- the circuit 52 can preferably use a correlated double sampling (CDS) circuit. Circuit 52 can generate a signal with reduced noise.
- CDS correlated double sampling
- the circuit 53 can use a multiplexer circuit.
- the circuit 53 can convert parallel signals input from the plurality of circuits 52 into serial signals and output the serial signals to the circuit 54 .
- the circuit 54 can use a source follower circuit.
- the circuit 54 has a function of amplifying and outputting the signal input from the circuit 53 .
- Circuit 55 can use an analog-to-digital conversion circuit.
- the circuit 55 has a function of converting the analog signal input from the circuit 54 into a signal SOUT, which is a digital signal, and outputting the signal.
- FIG. 4B shows a circuit 51[j], a circuit 52[j], a part of the circuit 53, a circuit 54, a circuit 55, and a circuit 56 connected to the j-th wiring WX[j]. ing.
- a part of the circuit 53 connected to the circuit 52[j] is shown as a circuit 53[j].
- the circuit 53 includes multiple circuits 53[j].
- the circuit 51[j] has transistors 61 and 62 .
- a wiring IVB and a wiring VIV to which a constant potential is supplied are connected to the circuit 51[j].
- the transistor 62 forms a source follower circuit together with the transistor M13 included in the pixel circuit 22 .
- Transistor 61 functions as a constant current source.
- the transistors 61 and 62 form a current mirror.
- the circuit 52[j] has transistors 63 to 68, a capacitor 81, and a capacitor .
- the circuit 52[j] is connected to a wiring SEL1, a wiring SEL2, and a wiring SCL to which a signal for controlling the conduction state of the transistor is applied, and a wiring VCL, a wiring CDB, a wiring VDD1, and a wiring VSS1 to which a constant potential is applied.
- a high potential can be supplied to the wiring VCL, the wiring VDD1, and the wiring CDB, and a low potential can be supplied to the wiring VSS1.
- a source follower circuit is configured with the transistor 66 and the transistor 68 .
- Transistor 67 functions as a constant current source and forms a current mirror with transistor 68 .
- a capacitor 81 is provided between the gate of the transistor 66 and the output wiring of the circuit 51[j]. A signal applied from circuit 51[j] to circuit 52[j] is transmitted to the gate of transistor 66 via capacitor 81.
- the transistor 65 has a function of applying a constant potential (also called an initial potential) to the node SH to which the gate of the transistor 66 is connected.
- a constant potential also called an initial potential
- the potential of the wiring WX[j] is obtained while the initial potential is applied to the node SH from the wiring VCL.
- the transistor 65 is turned off and the transistor M12 included in the pixel circuit 22 is turned on to obtain the potential of the wiring WX[j].
- the potential corresponding to the difference from the initial potential can be read out as imaging data.
- the circuit 50 can output a signal with reduced noise.
- the transistor 63 has a function of adjusting the capacitance value of the CDS circuit. By turning on the transistor 63, the capacitors 81 and 82 are connected in parallel. This can improve the sensitivity of the CDS circuit. On the other hand, by turning off the transistor 63, the speed of the reading operation can be increased. For example, when an object with low contrast or brightness is to be imaged, sensitivity can be improved by setting the transistor 63 to a conductive state and increasing the capacitance value of the CDS circuit. On the other hand, when high-speed reading is required, the capacitance value of the CDS circuit can be reduced by making the transistor 63 non-conductive. These can be switched by a signal supplied to the wiring SEL1.
- the transistor 64 has a function of connecting the wiring WX[j] and the node SH. By making transistor 64 conductive, a read operation without correlated double sampling can be performed. These can be switched by a signal supplied to the wiring SEL2.
- the circuit 53[j] has a transistor 69, a capacitor 83, and a capacitor 84.
- a wiring SEL3 to which a signal for controlling the conduction state of the transistor is applied and a wiring VDD2 to which a constant potential is applied are connected to the circuit 53[j].
- the capacitors 83 and 84 have a function of holding the potential of the wiring. One or both of the capacitors 83 and 84 may be omitted if unnecessary.
- the transistor 69 When selecting the circuit 53[j] out of the circuits 53, the transistor 69 is made conductive. Accordingly, the signal output from the circuit 52[j] can be output to the circuit 54 through the transistor 69. FIG. By sequentially selecting the plurality of transistors 69 included in the circuit 53 , parallel signals input from the plurality of circuits 52 can be converted into serial signals and output to the circuit 54 .
- the circuit 54 includes transistors 71 to 74.
- the circuit 54 is connected to a wiring SFR to which a signal for controlling the conduction state of the transistor is applied, and a wiring VRSF, a wiring SFB, a wiring VDD3, and a wiring VSS3 to which a constant potential is applied.
- a source follower circuit is configured with the transistor 72 and the transistor 74 .
- the transistor 73 functions as a constant current source and forms a current mirror with the transistor 74 .
- the transistor 71 has a function of resetting the potential of the node to which the gate of the transistor 72 is connected using the potential applied to the wiring VRSF.
- a circuit 56 that functions as an amplifier circuit may be provided between the circuits 54 and 55 .
- the circuit 56 has a function of amplifying the signal input from the circuit 54 and outputting it to the circuit 55 .
- n-channel transistors are used for all of the transistors forming the circuits 51, 52, 53, and 54.
- transistors in which an oxide semiconductor is used for a semiconductor layer in which a channel is formed are preferable to use.
- transistors with extremely low off-state current are preferably used for the transistors 63, 64, 65, 69, 71, and the like that function as switches.
- transistors to which silicon is applied may be used for some or all of the transistors.
- p-channel transistors may be applied to some or all of the transistors.
- FIG. 4B shows an example in which a pair of gates of transistors that are electrically connected to each of the transistors forming the circuits 51, 52, 53, and 54 is applied. Note that the present invention is not limited to this, and a transistor having a single gate may be used as part or all of the transistors. Alternatively, a transistor in which one gate is electrically connected to one of the source and the drain may be used as part or all of the transistors. Alternatively, a transistor whose one gate is supplied with a constant potential or a signal for controlling the threshold voltage may be applied to some or all of the transistors.
- the circuits 51, 52, 53, and 54 are preferably formed over a substrate provided with pixels through the same process as the pixels. As a result, the number of parts of the display device can be reduced, and the cost can be reduced.
- One or both of the circuits 56 and 55 may be an IC chip, or one or both of the circuits 56 and 55 may be formed over a substrate provided with pixels.
- circuits that can be applied to the circuit section 15 are not limited to the configurations shown in FIGS. 4A and 4B.
- a back gate may be provided in the transistor included in the display device which is one embodiment of the present invention.
- the on current of the transistor can be increased.
- the threshold voltage of the transistor can be adjusted.
- FIGS. 5 and 6 An example of the configuration of the display unit 11 is shown in FIGS. 5 and 6.
- FIG. The display unit 11 has a configuration in which pixels 30 are arranged in a matrix of M rows and N columns (M and N are independently integers of 2 or more). 5 and 6 show four pixels 30 from the i-th row and j-th column (where i and j are independently integers of 1 or more) to the i+1-th row and j+1-th column.
- the code is "[1]”, “[m]”, “[1, 1]”, “ [m, n]”, etc., may be added and described.
- the i-th row and j-th column pixel 30 is described as pixel 30[i, j].
- FIG. 5 shows the arrangement of sub-pixels R, sub-pixels G, sub-pixels B, sub-pixels PS and sub-pixels IRS.
- FIG. 6 shows the connection relationship between the pixel circuit 21R, the pixel circuit 21G, the pixel circuit 21B, the pixel circuit 22, and each wiring.
- the wiring SE[i], the wiring RE[i], the wiring TX[i], and the wiring SW[i] are the pixel circuits 22[i,j] and the pixel circuits 22[i,j+1] arranged in the i row direction, respectively. is electrically connected to The wiring SE[i+1], the wiring RE[i+1], the wiring TX[i+1], and the wiring SW[i+1] are the pixel circuits 22[i+1, j] and the pixel circuits 22[i+1, j+1] arranged in the i+1 row direction, respectively. is electrically connected to
- the wiring WX[j] is electrically connected to the pixel circuits 22[i,j] and the pixel circuits 22[i+1,j] arranged in the j column direction.
- the wiring WX[j+1] is electrically connected to the pixel circuits 22[i, j+1] and the pixel circuits 22[i+1, j+1] arranged in the j+1 column direction.
- the wiring GL1[i] and the wiring GL2[i] are pixel circuits 21R[i,j], pixel circuits 21G[i,j], pixel circuits 21B[i,j] and pixel circuits arranged in the i row direction, respectively.
- the wiring GL1[i+1] and the wiring GL2[i+1] are pixel circuits 21R[i+1,j], pixel circuits 21G[i+1,j], pixel circuits 21B[i+1,j], and pixel circuits arranged in the i+1 row direction, respectively.
- the wiring SLR[j] is electrically connected to the pixel circuits 21R[i,j] and the pixel circuits 21R[i+1,j] arranged in the j column direction.
- the wiring SLG[j] is electrically connected to the pixel circuits 21G[i,j] and the pixel circuits 21G[i+1,j] arranged in the j column direction.
- the wiring SLB[j] is electrically connected to the pixel circuits 21B[i,j] and the pixel circuits 21B[i+1,j] arranged in the j column direction.
- the wiring SLR[j+1] is electrically connected to the pixel circuits 21R[i, j+1] and the pixel circuits 21R[i+1, j+1] arranged in the j+1 column direction.
- the wiring SLG[j+1] is electrically connected to the pixel circuits 21G[i, j+1] and the pixel circuits 21G[i+1, j+1] arranged in the j+1 column direction.
- the wiring SLB[j+1] is electrically connected to the pixel circuits 21B[i, j+1] and the pixel circuits 21B[i+1, j+1] arranged in the j+1 column direction.
- FIG. 7 shows pixel circuit 22[i,j], pixel circuit 22[i+1,j], and circuit 52[j] functioning as a CDS circuit.
- FIGS. 8A, 8B and 9 Timing charts relating to the operation of the pixel circuit 22 are shown in FIGS. 8A, 8B and 9.
- FIG. 8A, 8B, and 9 the wiring TX, the wiring SW, the i-th wiring SE[i], the i-th wiring RS[i], the i+1-th wiring SE[i+1], the i+1-th wiring 1 shows signals input to the wiring RS[i+1] and the wiring SCL.
- exposure refers to acquisition of imaging data.
- a period from time T11 to time T12 corresponds to an initialization period (also referred to as a reset period).
- the wiring TX and the wiring RS are each supplied with a potential (here, a high-level potential) that makes the transistor conductive.
- a potential (here, a low-level potential) that makes the transistor non-conductive is applied to each of the wiring SW and the wiring SE. As a result, the transistor M11 and the transistor M12 are rendered conductive.
- the charge accumulated in the capacitor C11 is initialized (reset) by turning on the transistor M11 and the transistor M12. Further, a potential lower than that of the cathode electrode is applied to the anode electrode of the light receiving device PD1 from the wiring VRS via the transistors M11 and M12. That is, a state in which a reverse bias voltage is applied to the light receiving device PD1 is established.
- a period from time T12 to time T13 corresponds to an exposure period (a period during which imaging data is acquired).
- a low-level potential is applied to the wiring TX and the wiring RS.
- the transistor M11 and the transistor M12 are rendered non-conductive.
- the light receiving device PD1 Since the transistor M11 is in a non-conducting state, the light receiving device PD1 is held in a state in which a reverse bias voltage is applied. Here, photoelectric conversion occurs due to light (in this case, visible light) incident on the light receiving device PD1, and charges are accumulated in the anode electrode of the light receiving device PD1.
- the length of the exposure period may be set according to the sensitivity of the light-receiving device PD1, the amount of incident light, etc., but it is preferable to set a sufficiently long period at least as compared with the initialization period.
- a period from time T13 to time T14 corresponds to a transfer period.
- a high-level potential is applied to the wiring TX.
- the transistor M11 becomes conductive, and the charge accumulated in the light receiving device PD1 is transferred to one electrode of the capacitor C11 via the transistor M11.
- the potential of the node to which one electrode of the capacitor C11 is connected rises according to the amount of charge accumulated in the light receiving device PD1.
- the gate of the transistor M13 is applied with a potential corresponding to the exposure amount of the light receiving device PD1.
- the above is a description of an example of the operation related to exposure of the sub-pixel PS having the function of receiving visible light.
- a period from time T21 to time T22 corresponds to an initialization period (also referred to as a reset period).
- a high-level potential is applied to each of the wiring SW and the wiring RS.
- a low-level potential is applied to each of the wiring TX and the wiring SE.
- the transistor M15 and the transistor M12 are rendered conductive.
- the charge accumulated in the capacitor C11 is initialized (reset) by turning on the transistor M15 and the transistor M12. Further, a potential lower than that of the cathode electrode is applied to the anode electrode of the light receiving device PD2 from the wiring VRS via the transistor M15 and the transistor M12. That is, a state in which a reverse bias voltage is applied to the light receiving device PD2 is established.
- a period from time T22 to time T23 corresponds to an exposure period.
- a low-level potential is applied to the wiring SW and the wiring RS.
- the transistor M15 and the transistor M12 are rendered non-conductive.
- the light receiving device PD2 Since the transistor M15 is in a non-conducting state, the light receiving device PD2 is held in a state in which a reverse bias voltage is applied. Here, photoelectric conversion occurs due to light (infrared light in this case) incident on the light receiving device PD2, and charges are accumulated in the anode electrode of the light receiving device PD2.
- the length of the exposure period may be set according to the sensitivity of the light-receiving device PD2, the amount of incident light, etc., but it is preferable to set a sufficiently long period at least as compared with the initialization period.
- a period from time T23 to time T24 corresponds to a transfer period.
- a high-level potential is applied to the wiring SW.
- the transistor M15 becomes conductive, and the charge accumulated in the light receiving device PD2 is transferred to one electrode of the capacitor C11 via the transistor M15.
- the potential of the node to which one electrode of the capacitor C11 is connected rises according to the amount of charge accumulated in the light receiving device PD2.
- the gate of the transistor M13 is applied with a potential corresponding to the exposure amount of the light receiving device PD2.
- a period T31-T41 indicates readout of the i-th pixel circuit 22, and a period T41-T51 indicates readout of the i+1-th pixel circuit 22.
- FIG. 1 A period T31-T41 indicates readout of the i-th pixel circuit 22, and a period T41-T51 indicates readout of the i+1-th pixel circuit 22.
- a period from time T31 to time T34 corresponds to a correlated double sampling (CDS) processing period.
- CDS correlated double sampling
- the potential of the node SH electrically connected to the gate of the transistor 66 becomes the potential (initial potential) supplied to the wiring VCL.
- the transistor M14 of the pixel circuit 22[i, j] is turned on, image data is output from the pixel circuit 22[i, j], and a potential corresponding to the image data is applied to one electrode of the capacitor 81. supplied.
- the potential of one electrode of the capacitor 81 is held at a potential corresponding to the imaging data output from the pixel circuit 22[i, j] by turning off the transistor 65 . At this time, due to feedthrough, the potential of the node SH becomes lower than the potential (initial potential) supplied to the wiring VCL.
- the potential (reset potential) supplied to the wiring VRS is supplied to the circuit 52[j] through the wiring WX[j].
- the potential corresponding to the difference from the initial potential can be read out as imaging data.
- a signal with reduced noise can be output from the circuit 52[j].
- a period from time T34 to time T41 corresponds to an output period.
- a low-level potential is applied to the wiring RS[i].
- the transistor M12 of the pixel circuit 22[i,j] is rendered non-conductive.
- a potential corresponding to the imaging data is output from the circuit 52[j] to the circuit 53[j].
- the above is the operation related to the readout of the i-th pixel circuit 22 .
- ⁇ Period T41-T44> A period from time T41 to time T44 corresponds to a correlated double sampling (CDS) processing period.
- CDS correlated double sampling
- the potential of the node SH electrically connected to the gate of the transistor 66 becomes the potential (initial potential) supplied to the wiring VCL.
- the transistor M14 of the pixel circuit 22[i+1,j] is turned on, image data is output from the pixel circuit 22[i+1,j], and a potential corresponding to the image data is applied to one electrode of the capacitor 81. supplied.
- the potential of one electrode of the capacitor 81 is held at a potential corresponding to the imaging data output from the pixel circuit 22[i+1,j]. At this time, due to feedthrough, the potential of the node SH becomes lower than the potential (initial potential) supplied to the wiring VCL.
- the potential (reset potential) supplied to the wiring VRS is supplied to the circuit 52[j] through the wiring WX[j].
- the potential corresponding to the difference from the initial potential can be read out as imaging data.
- a signal with reduced noise can be output from the circuit 52[j].
- a period from time T44 to time T51 corresponds to an output period.
- a low-level potential is applied to the wiring RS[i+1].
- the transistor M12 of the pixel circuit 22[i+1,j] is rendered non-conductive.
- a potential corresponding to the imaging data is output from the circuit 52[j] to the circuit 53[j].
- the read operation is performed in order from the 1st row to the Mth row.
- M data potentials are sequentially output to the wiring WX.
- the exposure period and the readout period can be set separately.
- the data can then be read out sequentially.
- so-called global shutter driving can be realized.
- global shutter driving an oxide semiconductor with extremely low leakage current in a non-conducting state is applied to the transistors (especially the transistors M11, M12, and M15) functioning as switches in the pixel circuit 22. It is preferable to use a transistor with
- FIG. 10 An example different from the display unit 11 shown in FIGS. 5 and 6 is shown in FIGS. 10 and 11.
- FIG. 10 and 11 An example different from the display unit 11 shown in FIGS. 5 and 6 is shown in FIGS. 10 and 11.
- FIG. 10 and 11 An example different from the display unit 11 shown in FIGS. 5 and 6 is shown in FIGS. 10 and 11.
- FIG. 10 and 11 An example different from the display unit 11 shown in FIGS. 5 and 6 is shown in FIGS. 10 and 11.
- the display section 11A shown in FIGS. 10 and 11 is mainly different from the display section 11 shown in FIGS. 5 and 6 in that the pixel circuits 22 are provided every two rows of the pixels 30. It can also be said that two pixels 30 adjacent in the column direction share one pixel circuit 22 in the display section 11A. Specifically, one pixel circuit 22[k,j] is provided for pixel 30[i,j] and pixel 30[i+1,j], and pixel 30[i,j+1] and pixel 30[i+1] are provided. , j+1], one pixel circuit 22 [k, j+1] is provided. Here, k is an integer of 1 or more and M/2 or less. In the display section 11A, two pixels 30 adjacent in the column direction have one sub-pixel PS and one sub-pixel IRS.
- FIG. 11 shows an example in which the wiring SE[k], the wiring RE[k], the wiring TX[k], and the wiring SW[k] are provided for the pixel 30 in the i-th row and the pixel 30 in the i+1-th row. is shown.
- the wiring SE[k], the wiring RE[k], the wiring TX[k], and the wiring SW[k] are electrically connected to the pixel circuit 22[k,j] and the pixel circuit 22[k,j+1], respectively. be.
- FIG. 10 shows an example in which the pixel 30 on the i-th row is provided with the sub-pixel PS and the pixel 30 on the i+1-th row is provided with the sub-pixel IRS. Note that the arrangement of the sub-pixels PS and sub-pixels IRS is not limited to the configuration shown in FIG.
- the sub-pixels PS and the sub-pixels IRS may be alternately arranged as in the display section 11B shown in FIG. 12A.
- a sub-pixel PS may be provided instead of the sub-pixel IRS as in the display section 11C shown in FIG. 12B. That is, one pixel circuit 22 can be configured to have two light receiving devices having a function of receiving visible light. In this case, one pixel circuit 22 has the function of controlling the light reception of two sub-pixels PS.
- a sub-pixel IRS may be provided instead of the sub-pixel PS as in the display section 11D shown in FIG. 13A. That is, one pixel circuit 22 can be configured to have two light receiving devices having a function of receiving infrared light. In this case, one pixel circuit 22 has the function of controlling the light reception of two sub-pixels IRS.
- FIGS. 10 and 12A show configurations in which the sub-pixels PS and the sub-pixels IRS are arranged in the row direction, one aspect of the present invention is not limited to this. As in the display section 11E shown in FIG. 13B, the sub-pixels PS and the sub-pixels IRS may be arranged in the column direction.
- the display device described in Embodiment 1 can be applied to the electronic device of one embodiment of the present invention.
- An example of a pixel included in a display device of one embodiment of the present invention is shown in FIG. 14A.
- Examples of cross-sectional views of electronic devices each including a display device of one embodiment of the present invention are shown in FIGS. 14B and 14C.
- a pixel 180A shown in FIG. 14A has sub-pixels G, sub-pixels B, sub-pixels R, sub-pixels PS, and sub-pixels IRS.
- the description regarding the pixel 30 described above can be referred to, so a detailed description thereof will be omitted.
- the electronic devices shown in FIGS. 14B and 14C each have a display device 100 and a light source 104 between a housing 103 and a protective member 105.
- the display device 10 described in Embodiment 1 can be used as the display device 100 .
- the light source 104 has a light emitting device that emits infrared light 31IR.
- a light emitting diode LED: Light Emitting Diode
- FIG. 14B shows an example in which the light source 104 is arranged at a position that does not overlap with the display device 100. FIG. At this time, light emitted from the light source 104 is emitted to the outside of the electronic device through the protective member 105 .
- FIG. 14C shows an example in which the display device and the light source 104 are overlapped. At this time, light emitted from the light source 104 is emitted to the outside of the electronic device through the display device 100 and the protective member 105 .
- Display device 100 has a plurality of light emitting devices and a plurality of light receiving devices between substrate 106 and substrate 102 .
- the sub-pixel R has a light-emitting device 130R that emits red light 31R.
- Subpixel G has a light emitting device 130G that emits green light 31G.
- Subpixel B has a light emitting device 130B that emits blue light 31B.
- the sub-pixel PS has a light receiving device 150PS
- the sub-pixel IRS has a light receiving device 150IRS.
- the infrared light 31IR emitted by the light source 104 is reflected by the object 108 (here, the finger), and the reflected light 32IR from the object 108 enters the light receiving device 150IRS.
- the receiving device 150IRS can be used to detect the object 108 .
- the wavelength of light detected by the light receiving device 150IRS is not particularly limited.
- the light receiving device 150IRS preferably detects infrared light.
- the light receiving device 150IRS may detect visible light, or both infrared light and visible light.
- detection of the object 108 may be performed using both the light receiving device 150PS and the light receiving device 150IRS.
- infrared light 31IR emitted by light source 104 is reflected by object 108 (here, a finger), and reflected light 32IR from object 108 enters light receiving device 150IRS. be done.
- green light 31G emitted by light emitting device 130G is also reflected by object 108, and reflected light 32G from object 108 is incident on light receiving device 150PS.
- the object 108 is not in contact with the electronics, the object 108 can be detected using the light receiving device 150IRS and the light receiving device 150PS.
- the light receiving device 150IRS (and the light receiving device 150PS) can also be used to detect the object 108 in contact with the electronic device.
- the light receiving area of the sub-pixel PS is smaller than the light receiving area of the sub-pixel IRS.
- the sub-pixels PS can be used to capture images for personal authentication using a fingerprint, palm print, iris, pulse shape (including vein shape and artery shape), face, or the like.
- the green light 31G emitted by the light emitting device 130G is reflected by the target 108, and the reflected light 32G from the target 108 enters the light receiving device 150PS.
- a fingerprint of the object 108 can be imaged using the light receiving device 150PS.
- the light receiving device 150PS detects an object using the green light 31G emitted by the light emitting device 130G
- the wavelength of the light detected by the light receiving device 150PS is not particularly limited.
- the light receiving device 150PS preferably detects visible light, preferably one or more of colors such as blue, purple, violet, green, yellow-green, yellow, orange, and red. Also, the light receiving device 150PS may detect infrared light.
- the light receiving device 150PS may have the function of detecting the red light 31R emitted by the light emitting device 130R. Also, the light receiving device 150PS may have a function of detecting the blue light 31B emitted by the light emitting device 130B.
- the light-emitting device that emits the light detected by the light-receiving device 150PS is provided in a sub-pixel close to the sub-pixel PS in the pixel.
- the light receiving device 150PS detects light emitted from the light emitting device 130G of the subpixel G adjacent to the subpixel PS. With such a configuration, detection accuracy can be improved.
- all pixels may have the structure of the pixel 180A, some pixels may have the structure of the pixel 180A, and other pixels may have the structure of the pixel 180A. configuration may be applied.
- the display device of one embodiment of the present invention may include both the pixel 180A illustrated in FIG. 16A and the pixel 180B illustrated in FIG. 16B. Since the pixel 180A shown in FIG. 16A has the same configuration as the pixel 30 shown in FIG. 1B, detailed description thereof will be omitted.
- a pixel 180B shown in FIG. 16B has a sub-pixel G, a sub-pixel B, a sub-pixel R, a sub-pixel PS, and a sub-pixel X.
- various functions can be realized in a display device or an electronic device equipped with the display device.
- a display device or an electronic device uses the device of the sub-pixel X to detect force, displacement, position, speed, acceleration, angular velocity, number of rotations, distance, magnetism, temperature, chemicals, time, hardness, electric field, current, and so on. , voltage, power, radiation, flow rate, humidity, gradient, vibration, smell, physical condition, pulse, body temperature, and blood oxygen concentration.
- Functions possessed by the display device or the electronic device include, for example, strobe light function, flash light function, deterioration correction function, acceleration sensor function, odor sensor function, physical condition detection function, pulse detection function, body temperature detection function, or blood oxygen concentration measurement. functions, etc.
- the strobe light function can be realized, for example, by a configuration that repeats light emission and non-light emission in a short cycle.
- the flashlight function can be realized, for example, by using the principle of an electric double layer to generate a flash of light by instantaneous discharge.
- the strobe light function and flash light function can be used, for example, for crime prevention or self-defense purposes.
- the emission color of the strobe light and the flash light is preferably white.
- the emission color of the strobe light flashlight is not particularly limited. Multiple selections are allowed.
- the deterioration correction function there is a function of correcting the deterioration of the light-emitting device of at least one sub-pixel selected from sub-pixel G, sub-pixel B, and sub-pixel R. More specifically, when the reliability of the material used for the light-emitting device included in the sub-pixel G is poor, the sub-pixel X has the same configuration as the sub-pixel G so that two sub-pixels G can be formed in the pixel 180B. can be provided. With this structure, the area of the sub-pixel G can be doubled. By doubling the area of the sub-pixel G, it is possible to increase the reliability by about two times compared to the configuration in which the sub-pixel G is one.
- the other sub-pixel G can be used to A configuration in which the light emission of the pixel G is supplemented may be employed.
- sub-pixel G is explicitly described above, the sub-pixel B and the sub-pixel R can also have the same configuration.
- the acceleration sensor function, the odor sensor function, the physical condition detection function, the pulse detection function, the body temperature detection function, and the blood oxygen concentration measurement function can be realized by providing the sub-pixel X with a sensor device necessary for detection. can. Further, it can be said that the display device or the electronic device can realize various functions according to the sensor device provided in the sub-pixel X.
- the display device having the pixels 180B can be called a multi-function display device or a multi-function panel.
- the function of the sub-pixel X may be one or two or more, and the operator can appropriately select the optimum function.
- the display device of one embodiment of the present invention may include a pixel including four subpixels, which does not include both the subpixel X and the subpixel IRS. That is, it may have a pixel having sub-pixel G, sub-pixel B, sub-pixel R, and sub-pixel PS. Further, the display device may have different numbers of sub-pixels depending on the pixel. On the other hand, in order to make the quality of each pixel uniform, it is preferable that all pixels have the same number of sub-pixels.
- a display device of one embodiment of the present invention may include both a pixel 180A illustrated in FIG. 16A and a pixel 180C illustrated in FIG. 16C.
- a pixel 180C shown in FIG. 16C has sub-pixels G, sub-pixels B, sub-pixels R, sub-pixels PS, and sub-pixels IR.
- the sub-pixel IR has a light-emitting device that emits infrared light. That is, the sub-pixel IR can be used as the light source of the sensor. Since the display device includes a light-emitting device that emits infrared light, it is not necessary to provide a light source separately from the display device, and the number of parts of the electronic device can be reduced.
- FIG. 16D illustrates an example of a cross-sectional view of an electronic device including a display device of one embodiment of the present invention.
- the electronic device shown in FIG. 16D has display device 100 between housing 103 and protective member 105 .
- the display device 100 shown in FIG. 16D corresponds to the cross-sectional structure between the dashed-dotted lines A1-A2 in FIG. 16A and the cross-sectional structure between the dashed-dotted lines A3-A4 in FIG. 16C. That is, the display device 100 shown in FIG. 16D has a pixel 180A and a pixel 180C.
- the sub-pixel R has a light-emitting device 130R that emits red light 31R.
- Subpixel G has a light emitting device 130G that emits green light 31G.
- Subpixel B has a light emitting device 130B that emits blue light 31B.
- the sub-pixel PS has a light receiving device 150PS
- the sub-pixel IRS has a light receiving device 150IRS
- Subpixel IR has a light emitting device 130IR that emits infrared light 31IR.
- the infrared light 31IR emitted by the light emitting device 130IR is reflected by the object 108 (here, the finger), and the reflected light 32IR from the object 108 enters the light receiving device 150IRS.
- the receiving device 150IRS can be used to detect the object 108 .
- 17 to 20 show an example of the layout of the display device.
- the near-touch sensor function for example, illuminates an object (such as a finger, hand, or pen) with a light source fixed at a specific location, detects reflected light from the object with a plurality of sub-pixels IRS, and detects a plurality of sub-pixels It can be realized by estimating the position of the object from the detection intensity ratio in the IRS.
- the pixels 180A having the sub-pixels IRS can be arranged in the display section at regular intervals, or arranged in the periphery of the display section.
- the driving frequency can be increased. Further, since the sub-pixel X or the sub-pixel IR can be mounted in another pixel, a multifunctional display device can be realized.
- a display device 100A shown in FIG. 17 has two types of pixels: pixels 180A and pixels 180B.
- one pixel 180A is provided for 3 ⁇ 3 pixels (9 pixels), and the configuration of the pixel 180B is applied to the other pixels.
- the period for arranging the pixels 180A is not limited to one per 3 ⁇ 3 pixels.
- the pixels used for touch detection are 1 pixel per 4 pixels (2 ⁇ 2 pixels), 1 pixel per 16 pixels (4 ⁇ 4 pixels), 1 pixel per 100 pixels (10 ⁇ 10 pixels), or 900 pixels (30 pixels). x30 pixels) can be determined as appropriate.
- a display device 100B shown in FIG. 18 has two types of pixels: pixels 180A and pixels 180C.
- one pixel 180A is provided for 3 ⁇ 3 pixels (9 pixels), and the configuration of the pixel 180C is applied to the other pixels.
- a display device 100C shown in FIG. 19 has two types of pixels: pixels 180A and pixels 180B.
- the pixels 180A are provided on the periphery of the display portion, and the configuration of the pixels 180B is applied to the other pixels.
- the pixels 180A When the pixels 180A are provided around the periphery of the display portion, the pixels 180A may be arranged so as to surround all four sides as shown in FIG. can be arranged and various arrangements can be applied.
- a display device 100D shown in FIG. 20 has two types of pixels: pixels 180A and pixels 180C.
- the pixels 180A are provided on the periphery of the display portion, and the configuration of the pixels 180C is applied to the other pixels.
- infrared light 31IR emitted by a light source 104 provided outside the display unit of the display device is reflected by an object 108, and reflected light 32IR from the object 108 enters a plurality of pixels 180A. be done.
- the reflected light 32IR is detected by the sub-pixel IRS provided in the pixel 180A, and the position of the target object 108 can be estimated from the detection intensity ratio of the plurality of sub-pixels IRS.
- the light source 104 is provided at least outside the display unit of the display device, and may be built in the display device or may be mounted in an electronic device separately from the display device.
- a light emitting diode that emits infrared light can be used.
- the infrared light 31IR emitted by the sub-pixel IR of the pixel 180C is reflected by the object 108, and the reflected light 32IR from the object 108 enters the plurality of pixels 180A.
- the reflected light 32IR is detected by the sub-pixel IRS provided in the pixel 180A, and the position of the target object 108 can be estimated from the detection intensity ratio of the plurality of sub-pixels IRS.
- the layout of the display device can take various forms.
- FIG. 21A An example different from the pixels 180A to 180C described above is shown in FIG. 21A.
- a pixel 180D shown in FIG. 21A has a sub-pixel G, a sub-pixel B, a sub-pixel R, a sub-pixel IR, a sub-pixel PS, and a sub-pixel IRS.
- FIG. 21A shows an example in which sub-pixels are provided over two rows and three columns for one pixel 180D.
- the pixel 180D has three sub-pixels (sub-pixel G, sub-pixel B, sub-pixel R) in the upper row (first row) and three sub-pixels (sub-pixel R) in the lower row (second row). sub-pixel IR, sub-pixel PS, and sub-pixel IRS).
- the pixel 180D has two sub-pixels (sub-pixel G, sub-pixel IR) in the left column (first column) and two sub-pixels (sub-pixel B, sub-pixel PS), and two sub-pixels (sub-pixel R, sub-pixel IRS) in the right column (third column).
- the arrangement of sub-pixels is not limited to the configuration in FIG. 21A.
- sub-pixel G sub-pixel B, sub-pixel R, sub-pixel IR, sub-pixel PS, and sub-pixel IRS, since the above description can be referred to, detailed description thereof will be omitted.
- the pixel 180D has a pixel circuit 21R, a pixel circuit 21G, a pixel circuit 21B, a pixel circuit 21IR, and a pixel circuit 22. Since the pixel circuit 21R, the pixel circuit 21G, the pixel circuit 21B, and the pixel circuit 22 can refer to the above description, detailed description thereof will be omitted.
- the pixel circuit 21IR has a function of controlling light emission of the sub-pixel IR.
- the configuration of the pixel circuit 21R, the pixel circuit 21G, or the pixel circuit 21B can be applied to the pixel circuit 21IR.
- the pixel circuit 21IR can use the pixel circuit 21 shown in FIG. 2B.
- FIG. 21C and 21D show the cross-sectional structure between dashed-dotted lines A5-A6 in Fig. 21A.
- FIG. 21C shows how infrared light 31IR emitted by light-emitting device 130IR is reflected by object 108 (here, a finger), and reflected light 32IR from object 108 enters light-receiving device 150IRS.
- FIG. 21D shows how green light 31G emitted by light emitting device 130G is reflected by object 108 (here, a finger), and reflected light 32G from object 108 is incident on light receiving device 150PS.
- a display device 100E shown in FIG. 22 has a pixel 180D. As shown in FIG. 22, the infrared light 31IR emitted by the pixel 180D is reflected by the target 108 (here, the finger), and the reflected light 32IR from the target 108 is incident on the light receiving device 150IRS of the pixel 180D. be.
- the display device 100E can detect that the object 108 touches or approaches.
- FIG. 22 illustrates an example of the display device including the pixel 180D
- one embodiment of the present invention is not limited to this.
- a display device may be configured by combining the pixel 180D and one or more of the pixels 180A, 180B, and 180C.
- a display device of one embodiment of the present invention may emit light of a specific color and receive reflected light reflected by an object.
- FIG. 23A schematically shows red light emitted from the display device and red light incident on the display device after being reflected by the object 108 (finger in this case), respectively, with arrows.
- FIG. 23B schematically shows, with arrows, infrared light emitted from the display device and infrared light incident on the display device after being reflected by the object 108 (here, a finger).
- the transmittance of the object for red light can be measured.
- the transmittance of the object to infrared light can be measured by emitting infrared light while the object is in contact with or in close proximity to the display device and causing the reflected light from the object to enter the display device.
- FIG. 23C shows an enlarged view of the region P indicated by the dashed-dotted line in FIG. 23A.
- the light 31R emitted from the light-emitting device 130R is scattered by the surface of the target object 108 and the internal biological tissue, and part of the scattered light travels from the biological interior toward the light-receiving device 150PS. This scattered light passes through the blood vessel 91, and the transmitted light 32R enters the light receiving device 150PS.
- the infrared light emitted from the light emitting device 130IR is scattered by the surface of the object 108 and the living tissue inside, and part of the scattered light travels from inside the living body toward the light receiving device 150IRS. This scattered light passes through the blood vessel 91, and the transmitted infrared light enters the light receiving device 150IRS.
- the light 32R is light that has passed through the living tissue 93 and blood vessels 91 (arteries and veins). Since arterial blood pulsates with heartbeat, the absorption of light by arteries varies with heartbeat. On the other hand, since the body tissue 93 and the veins are not affected by the heartbeat, the light absorption by the body tissue 93 and the light absorption by the veins are constant. Therefore, the light transmittance of the artery can be calculated by excluding a component that is constant over time from the light 32R incident on the display device. Further, the transmittance of red light is lower for hemoglobin not bound to oxygen (also called reduced hemoglobin) than for hemoglobin bound to oxygen (also called oxygenated hemoglobin).
- hemoglobin not bound to oxygen also called reduced hemoglobin
- oxygenated hemoglobin also called oxygenated hemoglobin
- Oxygenated hemoglobin and reduced hemoglobin have the same transmittance of infrared light.
- the ratio of oxygenated hemoglobin to the sum of oxygenated hemoglobin and deoxyhemoglobin, or oxygen saturation can be calculated.
- the display device of one embodiment of the present invention can function as a reflective pulse oximeter.
- the position information of the area touched by the finger is acquired.
- red light is emitted from the region where the finger is in contact and the pixels in the vicinity thereof, and the transmittance of the artery to the red light is measured.
- Oxygen saturation can then be calculated by emitting infrared light and measuring the transmittance of the artery to infrared light.
- the order of measuring the transmittance for red light and the transmittance for infrared light is not particularly limited. After measuring the transmittance for infrared light, the transmittance for red light may be measured. Further, although an example of calculating the oxygen saturation using a finger is shown here, one embodiment of the present invention is not limited to this.
- Oxygen saturation can also be calculated at sites other than fingers.
- the oxygen saturation can be calculated by measuring the transmittance of the artery to red light and the transmittance of the artery to infrared light while the palm is in contact with the display unit of the display device.
- FIG. 24A An example of an electronic device to which the display device of one embodiment of the present invention is applied is shown in FIG. 24A.
- a mobile information terminal 400 shown in FIG. 24A can be used as, for example, a smart phone.
- the mobile information terminal 400 has a housing 402 and a display section 404 .
- the display unit 404 preferably has the aforementioned pixels 180D.
- the display device 100E described above can be applied to the display unit 404 .
- FIG. 24A shows how a finger 406 is in contact with the display unit 404 of the mobile information terminal 400.
- FIG. FIG. 24A shows a region where a touch is detected and a region 408 in the vicinity thereof by a dashed line.
- the mobile information terminal 400 emits red light from the pixels in the area 408 and detects the red light incident on the display section 404 .
- the oxygen saturation of the finger 406 can be measured by emitting infrared light from pixels in the region 408 and detecting the infrared light incident on the display portion 404 .
- FIG. 24B shows how the pixels in region 408 are illuminated.
- FIG. 24B shows the finger 406 as transparent, only the outline is shown in dashed lines, and the region 408 is hatched. As shown in FIG. 24B, illuminated area 408 is hidden by finger 406 and is less visible to the user. Therefore, the oxygen saturation can be measured without making the user feel stressed.
- portable information terminal 400 can measure oxygen saturation at any position within display unit 404 .
- the obtained oxygen saturation may be displayed on the display unit 404 .
- FIG. 24C shows how an image 412 indicating oxygen saturation is displayed in the area 410 .
- FIG. 24C shows characters “SpO 2 97%” as an example of the image 412 .
- the image 412 may be an image, and may include an image and characters.
- the region 410 may be provided at any position on the display portion 404 .
- a display device of one embodiment of the present invention includes a light-emitting device and a light-receiving device in a pixel.
- pixels have a light-receiving function, contact or proximity of an object can be detected while displaying an image. For example, not only can an image be displayed by all the sub-pixels of the display device, but also some sub-pixels can emit light as a light source and the remaining sub-pixels can be used to display an image.
- light-emitting devices are arranged in matrix in the display portion, and an image can be displayed on the display portion.
- light receiving devices are arranged in a matrix in the display section, and the display section has one or both of an imaging function and a sensing function in addition to an image display function.
- the display part can be used for an image sensor or a touch sensor. That is, by detecting light on the display portion, an image can be captured, or proximity or contact of an object (a finger, hand, pen, or the like) can be detected.
- the display device of one embodiment of the present invention can use a light-emitting device as a light source of a sensor. Therefore, it is not necessary to provide a light receiving portion and a light source separately from the display device, and the number of parts of the electronic device can be reduced.
- the light-receiving device when an object reflects (or scatters) light emitted by a light-emitting device included in the display portion, the light-receiving device can detect the reflected light (or scattered light).
- the reflected light or scattered light.
- imaging or touch detection is possible.
- a display device of one embodiment of the present invention has a function of displaying an image using a light-emitting device.
- the light-emitting device functions as a display device (also referred to as a display element).
- an EL device such as an OLED (Organic Light Emitting Diode) or a QLED (Quantum-dot Light Emitting Diode) as the light emitting device.
- OLED Organic Light Emitting Diode
- QLED Quadantum-dot Light Emitting Diode
- light-emitting substances in EL devices include substances that emit fluorescence (fluorescent materials), substances that emit phosphorescence (phosphorescent materials), inorganic compounds (quantum dot materials, etc.), and substances that exhibit heat-activated delayed fluorescence (heat-activated delayed fluorescence ( Thermally Activated Delayed Fluorescence (TADF) material) and the like.
- LEDs such as micro LED (Light Emitting Diode), can also be used as a light emitting device.
- the TADF material a material in which the singlet excited state and the triplet excited state are in thermal equilibrium may be used. Since such a TADF material has a short emission lifetime (excitation lifetime), it is possible to suppress a decrease in efficiency in a high-luminance region of a light-emitting device.
- a display device of one embodiment of the present invention has a function of detecting light using a light-receiving device.
- the display device can capture an image using the light receiving device.
- the display device of this embodiment can be used as a scanner.
- an image sensor can be used to acquire data related to biometric information such as fingerprints and palm prints. That is, the biometric authentication sensor can be incorporated in the display device.
- the biometric authentication sensor can be incorporated into the display device.
- the display device can detect proximity or contact of an object using the light receiving device.
- a pn-type or pin-type photodiode can be used as the light receiving device.
- a light-receiving device functions as a photoelectric conversion device (also referred to as a photoelectric conversion element) that detects light incident on the light-receiving device and generates an electric charge. The amount of charge generated from the light receiving device is determined based on the amount of light incident on the light receiving device.
- organic photodiode having a layer containing an organic compound as the light receiving device.
- Organic photodiodes can be easily made thinner, lighter, and larger, and have a high degree of freedom in shape and design, so that they can be applied to various display devices.
- an organic EL device is used as the light emitting device and an organic photodiode is used as the light receiving device.
- An organic EL device and an organic photodiode can be formed on the same substrate. Therefore, an organic photodiode can be incorporated in a display device using an organic EL device.
- the organic photodiode has many layers that can be configured in common with the organic EL device, it is possible to suppress an increase in the number of deposition processes by collectively depositing layers that can be configured in common.
- one of the pair of electrodes can be a layer common to the light receiving device and the light emitting device.
- at least one of the hole injection layer, the hole transport layer, the electron transport layer, and the electron injection layer is preferably a layer common to the light receiving device and the light emitting device.
- a layer shared by the light-receiving device and the light-emitting device may have different functions in the light-emitting device and in the light-receiving device. Components are referred to herein based on their function in the light emitting device.
- a hole-injecting layer functions as a hole-injecting layer in light-emitting devices and as a hole-transporting layer in light-receiving devices.
- an electron-injecting layer functions as an electron-injecting layer in light-emitting devices and as an electron-transporting layer in light-receiving devices.
- a layer shared by the light-receiving device and the light-emitting device may have the same function in the light-emitting device as in the light-receiving device.
- a hole-transporting layer functions as a hole-transporting layer in both a light-emitting device and a light-receiving device
- an electron-transporting layer functions as an electron-transporting layer in both a light-emitting device and a light-receiving device.
- an island-shaped light-emitting layer can be formed by a vacuum deposition method using a metal mask (also called a shadow mask).
- a metal mask also called a shadow mask
- island-like formations occur due to various influences such as precision of the metal mask, misalignment between the metal mask and the substrate, bending of the metal mask, and broadening of the contour of the deposited film due to vapor scattering. Since the shape and position of the light-emitting layer deviate from the design, it is difficult to increase the definition and aperture ratio of the display device.
- an island-shaped pixel electrode (which can also be called a lower electrode) is formed, and a first layer (EL layer or EL layer) including a light-emitting layer that emits light of a first color is formed. layer) is formed over the entire surface, a first sacrificial layer is formed on the first layer. Then, a first resist mask is formed over the first sacrificial layer, and the first layer and the first sacrificial layer are processed using the first resist mask, thereby forming an island-shaped first layer.
- a second layer (which can be called an EL layer or part of an EL layer) including a light-emitting layer that emits light of a second color is formed as a second sacrificial layer. and an island shape using a second resist mask.
- the island-shaped EL layer is not formed using a fine metal mask, but is processed after the EL layer is formed over one surface. It is formed. Therefore, it is possible to realize a high-definition display device or a display device with a high aperture ratio, which has hitherto been difficult to achieve. Furthermore, since the EL layer can be separately formed for each color, a display device with extremely vivid, high-contrast, and high-quality display can be realized. Further, by providing the sacrificial layer over the EL layer, damage to the EL layer during the manufacturing process of the display device can be reduced, and the reliability of the light-emitting device can be improved.
- the pattern of the EL layer itself can also be made much smaller than when a metal mask is used.
- the thickness varies between the center and the edge of the pattern, so the effective area that can be used as the light emitting region is smaller than the area of the entire pattern. .
- the pattern is formed by processing a film formed to have a uniform thickness, the thickness can be made uniform within the pattern, and even if the pattern is fine, almost the entire area of the pattern can emit light. It can be used as a region. Therefore, a display device having both high definition and high aperture ratio can be manufactured.
- the first layer and the second layer each include at least a light-emitting layer, and preferably consist of a plurality of layers. Specifically, it is preferable to have one or more layers on the light-emitting layer.
- the light-emitting layer can be prevented from being exposed to the outermost surface during the manufacturing process of the display device, and damage to the light-emitting layer can be reduced. This can improve the reliability of the light emitting device.
- a manufacturing method similar to that for the light-emitting device can also be applied to the light-receiving device.
- the island-shaped active layer (also called photoelectric conversion layer) of the light receiving device is not formed using a fine metal mask, but is formed by forming a film that will become the active layer over the surface and then processing it. Therefore, the island-shaped active layer can be formed with a uniform thickness. Further, by providing the sacrificial layer over the active layer, the damage to the active layer during the manufacturing process of the display device can be reduced, and the reliability of the light receiving device can be improved.
- [Configuration example 1 of display device] 25A and 25B illustrate a display device of one embodiment of the present invention.
- a display device of one embodiment of the present invention is a top emission type in which light is emitted in a direction opposite to a substrate over which a light-emitting device is formed, and light is emitted toward a substrate over which a light-emitting device is formed.
- a bottom emission type bottom emission type
- a double emission type dual emission type in which light is emitted from both sides may be used.
- FIG. 25A A top view of the display device 100F is shown in FIG. 25A.
- the display device 100F has a display section in which a plurality of pixels 110 are arranged in a matrix and a connection section 140 outside the display section.
- One pixel 110 is composed of five sub-pixels: sub-pixel 110a, sub-pixel 110b, sub-pixel 110c, sub-pixel 110d, and sub-pixel 110e.
- the connection portion 140 can be referred to as a cathode contact portion.
- FIG. 25A shows an example in which sub-pixels are provided over 2 rows and 3 columns for one pixel 110 .
- the pixel 110 has three sub-pixels (sub-pixels 110a, 110b, 110c) in the upper row (first row) and two sub-pixels (sub-pixels 110d, 110d, 110c) in the lower row (second row). 110e).
- pixel 110 has two sub-pixels (sub-pixels 110a and 110d) in the left column (first column), has sub-pixel 110b in the center column (second column), and has sub-pixel 110b in the middle column (second column). It has a sub-pixel 110c in a column (third column), and further has a sub-pixel 110e over these two columns.
- This embodiment shows an example in which sub-pixels 110a, 110b, and 110c have light-emitting devices that emit light of different colors, and sub-pixels 110d and 110e have light-receiving devices with different light-receiving areas.
- sub-pixels 110a, 110b, and 110c correspond to sub-pixel G, sub-pixel B, and sub-pixel R shown in FIG. 14A and the like.
- the sub-pixel 110d corresponds to the sub-pixel PS shown in FIG. 14A and the like
- the sub-pixel 110e corresponds to the sub-pixel IRS shown in FIG. 14A and the like.
- sub-pixel 110e may be changed for each pixel.
- some sub-pixels 110e may correspond to sub-pixels IRS, and other sub-pixels 110e may correspond to sub-pixels X (see FIG. 16B) or sub-pixels IR (see FIG. 16C).
- FIG. 25A shows an example in which the connecting portion 140 is positioned below the display portion when viewed from above
- the connecting portion 140 may be provided at least one of the upper side, the right side, the left side, and the lower side of the display portion when viewed from above, and may be provided so as to surround the four sides of the display portion.
- the number of connection parts 140 may be singular or plural.
- FIG. 25B shows cross-sectional views along dashed-dotted lines X1-X2, Y3-Y4, and Y1-Y2 in FIG. 25A.
- the display device 100F includes a light-emitting device 130a, a light-emitting device 130b, a light-emitting device 130c, a light-receiving device 150d (see FIG. 29B), and a light-receiving device 150e on a layer 101 including transistors.
- a protective layer 131 is provided to cover the light emitting device and the light receiving device.
- a substrate 120 is bonded onto the protective layer 131 with a resin layer 119 .
- the layer 101 including transistors for example, a stacked structure in which a plurality of transistors are provided on a substrate and an insulating layer is provided to cover these transistors can be applied.
- a structural example of the layer 101 including a transistor will be described later in Embodiment 4. FIG.
- the light emitting devices 130a, 130b, and 130c each emit light of different colors.
- Light-emitting devices 130a, 130b, and 130c are preferably a combination that emits three colors of light, red (R), green (G), and blue (B), for example.
- a light-emitting device has an EL layer between a pair of electrodes.
- one of a pair of electrodes may be referred to as a pixel electrode and the other may be referred to as a common electrode.
- one electrode functions as an anode and the other electrode functions as a cathode.
- the pixel electrode functions as an anode and the common electrode functions as a cathode will be described below as an example.
- the light-emitting device 130a has a pixel electrode 111a on the layer 101 containing the transistor, a first layer 113a on the pixel electrode 111a, a sixth layer 114 on the first layer 113a, and a sixth layer 114 on the sixth layer 114. and a common electrode 115 .
- the first layer 113a and the sixth layer 114 can be collectively called an EL layer.
- the first layer 113a includes a first hole-injection layer 181a on the pixel electrode 111a, a first hole-transport layer 182a on the first hole-injection layer 181a, and a first hole-transport layer 182a. It has a first light emitting layer 183a on top and a first electron transport layer 184a on the first light emitting layer 183a.
- the sixth layer 114 has, for example, an electron injection layer.
- the sixth layer 114 may have a laminate of an electron transport layer and an electron injection layer.
- the light-emitting device 130b has a pixel electrode 111b on the layer 101 containing the transistor, a second layer 113b on the pixel electrode 111b, a sixth layer 114 on the second layer 113b, and a sixth layer 114 on the sixth layer 114. and a common electrode 115 .
- the second layer 113b and the sixth layer 114 can be collectively called an EL layer.
- the second layer 113b includes a second hole-injection layer 181b over the pixel electrode 111b, a second hole-transport layer 182b over the second hole-injection layer 181b, and a second hole-transport layer 182b. It has a second light emitting layer 183b on top and a second electron transport layer 184b on the second light emitting layer 183b.
- the light-emitting device 130c has a pixel electrode 111c on the layer 101 containing the transistor, a third layer 113c on the pixel electrode 111c, a sixth layer 114 on the third layer 113c, and a sixth layer 114 on the sixth layer 114. and a common electrode 115 .
- the third layer 113c and the sixth layer 114 can be collectively referred to as EL layers.
- the third layer 113c includes a third hole-injection layer 181c over the pixel electrode 111c, a third hole-transport layer 182c over the third hole-injection layer 181c, and a third hole-transport layer 182c. It has a third light-emitting layer 183c on top and a third electron-transporting layer 184c on the third light-emitting layer 183c.
- the light emitting devices 130a, 130b, and 130c each emit light of different colors.
- Light-emitting devices 130a, 130b, and 130c are preferably a combination that emits three colors of light, red (R), green (G), and blue (B), for example.
- a light receiving device has an active layer between a pair of electrodes.
- one of a pair of electrodes may be referred to as a pixel electrode and the other may be referred to as a common electrode.
- one electrode functions as an anode and the other electrode functions as a cathode.
- the pixel electrode functions as an anode and the common electrode functions as a cathode will be described below as an example. That is, the light-receiving device can be driven by applying a reverse bias between the pixel electrode and the common electrode to detect light incident on the light-receiving device, generate charges, and extract them as current.
- the light receiving device 150d includes a pixel electrode 111d on the layer 101 including the transistor, a fourth layer 113d on the pixel electrode 111d, and a sixth layer 114 on the fourth layer 113d. , and a common electrode 115 on the sixth layer 114 .
- the fourth layer 113d includes a fourth hole-transport layer 182d on the pixel electrode 111d, a first active layer 185d on the fourth hole-transport layer 182d, and a fourth layer 185d on the first active layer 185d. and an electron transport layer 184d of .
- a sixth layer 114 is a layer shared by the light-emitting device and the light-receiving device.
- the sixth layer 114 comprises, for example, an electron injection layer, as described above.
- the sixth layer 114 may have a laminate of an electron transport layer and an electron injection layer.
- a layer shared by the light-receiving device and the light-emitting device may have different functions in the light-emitting device and in the light-receiving device. Components are sometimes referred to herein based on their function in the light emitting device.
- a hole-injecting layer functions as a hole-injecting layer in light-emitting devices and as a hole-transporting layer in light-receiving devices.
- an electron-injecting layer functions as an electron-injecting layer in light-emitting devices and as an electron-transporting layer in light-receiving devices.
- a layer shared by the light-receiving device and the light-emitting device may have the same function in the light-emitting device as in the light-receiving device.
- a hole-transporting layer functions as a hole-transporting layer in both a light-emitting device and a light-receiving device
- an electron-transporting layer functions as an electron-transporting layer in both a light-emitting device and a light-receiving device.
- the light receiving device 150e includes a pixel electrode 111e on the layer 101 including the transistor, a fifth layer 113e on the pixel electrode 111e, a sixth layer 114 on the fifth layer 113e, and a and a common electrode 115 .
- the fifth layer 113e includes a fifth hole-transport layer 182e on the pixel electrode 111e, a second active layer 185e on the fifth hole-transport layer 182e, and a fifth layer 185e on the second active layer 185e. and an electron transport layer 184e of
- the common electrode 115 is electrically connected to the conductive layer 123 provided on the connecting portion 140 . As a result, the same potential is supplied to the common electrodes 115 of the light emitting devices of each color.
- a conductive film that transmits visible light and infrared light is used for the electrode on the light extraction side of the pixel electrode and the common electrode.
- a conductive film that reflects visible light and infrared light is preferably used for the electrode on the side from which light is not extracted.
- indium tin oxide also referred to as In—Sn oxide, ITO
- In—Si—Sn oxide also referred to as ITSO
- indium zinc oxide In—Zn oxide
- In—W— Zn oxides aluminum-containing alloys (aluminum alloys) such as alloys of aluminum, nickel, and lanthanum (Al-Ni-La)
- Al-Ni-La aluminum-containing alloys
- Al-Ni-La aluminum-containing alloys
- alloys of silver, palladium and copper Ag-Pd-Cu, also referred to as APC
- elements belonging to Group 1 or Group 2 of the periodic table of elements not exemplified above e.g., lithium (Li), cesium (Cs), calcium (Ca), strontium (Sr)), europium (Eu), ytterbium
- Yb rare earth metal
- an alloy containing an appropriate combination thereof, graphene, or the like can be used.
- a micro optical resonator (microcavity) structure is preferably applied to the light emitting device and the light receiving device. Therefore, one of the pair of electrodes included in the light-emitting device and the light-receiving device preferably has an electrode (semi-transmissive/semi-reflective electrode) that is transparent and reflective to visible light, and the other is reflective to visible light. It is preferable to have an electrode (reflective electrode) having a Since the light-emitting device has a microcavity structure, the light emitted from the light-emitting layer can be resonated between both electrodes, and the light emitted from the light-emitting device can be enhanced. Since the light receiving device has a microcavity structure, the light received by the active layer can be resonated between the two electrodes, the light can be strengthened, and the detection accuracy of the light receiving device can be improved.
- the semi-transmissive/semi-reflective electrode can have a laminated structure of a reflective electrode and an electrode having transparency to visible light (also referred to as a transparent electrode).
- the light transmittance of the transparent electrode is set to 40% or more.
- the light-emitting device preferably uses an electrode having a transmittance of 40% or more for visible light (light with a wavelength of 400 nm or more and less than 750 nm).
- the visible light reflectance of the semi-transmissive/semi-reflective electrode is 10% or more and 95% or less, preferably 30% or more and 80% or less.
- the visible light reflectance of the reflective electrode is 40% or more and 100% or less, preferably 70% or more and 100% or less.
- the resistivity of these electrodes is preferably 1 ⁇ 10 ⁇ 2 ⁇ cm or less.
- the transmittance or reflectance of near-infrared light (light having a wavelength of 750 nm or more and 1300 nm or less) of these electrodes preferably satisfies the above numerical range, similarly to the transmittance or reflectance of visible light.
- the first layer 113a, the second layer 113b, and the third layer 113c each have a light-emitting layer.
- the first layer 113a, the second layer 113b, and the third layer 113c preferably have light-emitting layers that emit light of different colors.
- a light-emitting layer is a layer containing a light-emitting substance.
- the emissive layer can have one or more emissive materials.
- a light-emitting substance a substance exhibiting emission colors such as blue, purple, blue-violet, green, yellow-green, yellow, orange, and red is used as appropriate.
- a substance that emits near-infrared light can be used as the light-emitting substance.
- Examples of light-emitting substances include fluorescent materials, phosphorescent materials, thermally activated delayed fluorescence (TADF) materials, and quantum dot materials.
- fluorescent materials include fluorescent materials, phosphorescent materials, thermally activated delayed fluorescence (TADF) materials, and quantum dot materials.
- TADF thermally activated delayed fluorescence
- fluorescent materials include pyrene derivatives, anthracene derivatives, triphenylene derivatives, fluorene derivatives, carbazole derivatives, dibenzothiophene derivatives, dibenzofuran derivatives, dibenzoquinoxaline derivatives, quinoxaline derivatives, pyridine derivatives, pyrimidine derivatives, phenanthrene derivatives, naphthalene derivatives, and the like. .
- a phosphorescent material for example, a 4H-triazole skeleton, a 1H-triazole skeleton, an imidazole skeleton, a pyrimidine skeleton, a pyrazine skeleton, or an organometallic complex (especially an iridium complex) having a pyridine skeleton, or a phenylpyridine derivative having an electron-withdrawing group is coordinated.
- Organometallic complexes particularly iridium complexes
- platinum complexes, rare earth metal complexes and the like can be mentioned.
- the light-emitting layer may contain one or more organic compounds (host material, assist material, etc.) in addition to the light-emitting substance (guest material).
- One or both of a hole-transporting material and an electron-transporting material can be used as the one or more organic compounds.
- Bipolar materials or TADF materials may also be used as one or more organic compounds.
- the light-emitting layer preferably includes, for example, a phosphorescent material and a combination of a hole-transporting material and an electron-transporting material that easily form an exciplex.
- ExTET Exciplex-Triplet Energy Transfer
- a combination that forms an exciplex that emits light that overlaps with the wavelength of the absorption band on the lowest energy side of the light-emitting substance energy transfer becomes smooth and light emission can be efficiently obtained. With this configuration, high efficiency, low-voltage driving, and long life of the light-emitting device can be realized at the same time.
- the first layer 113a, the second layer 113b, and the third layer 113c include, as layers other than the light-emitting layer, a substance with a high hole-injection property, a substance with a high hole-transport property, a hole-blocking material, and an electron layer.
- a layer containing a highly transportable substance, a highly electron-injecting substance, an electron-blocking material, a bipolar substance (a substance with high electron-transporting and hole-transporting properties), or the like may be further included.
- Both low-molecular-weight compounds and high-molecular-weight compounds can be used in the light-emitting device, and inorganic compounds may be included.
- Each of the layers constituting the light-emitting device can be formed by a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like.
- the first layer 113a, the second layer 113b, and the third layer 113c are respectively a hole-injecting layer, a hole-transporting layer, a hole-blocking layer, an electron-blocking layer, an electron-transporting layer, and an electron layer. It may have one or more of the injection layers.
- the sixth layer 114 may have one or more of a hole injection layer, a hole transport layer, a hole block layer, an electron block layer, an electron transport layer, and an electron injection layer.
- a hole injection layer e.g., a hole injection layer
- a hole transport layer e.g., a hole transport layer
- a hole block layer e.g., a hole block layer
- an electron injection layer
- the hole-injecting layer is a layer that injects holes from the anode into the hole-transporting layer, and contains a material with high hole-injecting properties.
- Materials with high hole-injection properties include composite materials containing a hole-transporting material (for example, an aromatic amine compound) and an acceptor material (electron-accepting material).
- a hole-transporting layer is a layer that transports holes injected from the anode to the light-emitting layer by means of a hole-injecting layer.
- the hole-transporting layer is a layer that transports holes generated by incident light in the active layer to the anode.
- a hole-transporting layer is a layer containing a hole-transporting material.
- the hole-transporting material is preferably a substance having a hole mobility of 1 ⁇ 10 ⁇ 6 cm 2 /Vs or more. Note that substances other than these can be used as long as they have a higher hole-transport property than electron-transport property.
- the hole-transporting materials include materials with high hole-transporting properties such as ⁇ -electron-rich heteroaromatic compounds (e.g., carbazole derivatives, thiophene derivatives, furan derivatives, etc.) and aromatic amines (compounds having an aromatic amine skeleton). preferable.
- ⁇ -electron-rich heteroaromatic compounds e.g., carbazole derivatives, thiophene derivatives, furan derivatives, etc.
- aromatic amines compounds having an aromatic amine skeleton.
- an electron-transporting layer is a layer that transports electrons injected from the cathode to the light-emitting layer by the electron-injecting layer.
- the electron transport layer is a layer that transports electrons generated by incident light in the active layer to the cathode.
- the electron-transporting layer is a layer containing an electron-transporting material.
- the electron-transporting material is preferably a substance having an electron mobility of 1 ⁇ 10 ⁇ 6 cm 2 /Vs or more. Note that substances other than these substances can be used as long as they have a higher electron-transport property than hole-transport property.
- Electron-transporting materials include metal complexes having a quinoline skeleton, metal complexes having a benzoquinoline skeleton, metal complexes having an oxazole skeleton, metal complexes having a thiazole skeleton, oxadiazole derivatives, triazole derivatives, imidazole derivatives, and oxazole. derivatives, thiazole derivatives, phenanthroline derivatives, quinoline derivatives with quinoline ligands, benzoquinoline derivatives, quinoxaline derivatives, dibenzoquinoxaline derivatives, pyridine derivatives, bipyridine derivatives, pyrimidine derivatives, and other nitrogen-containing heteroaromatic compounds.
- a material having a high electron-transport property such as a heteroaromatic compound can be used.
- the electron injection layer is a layer that injects electrons from the cathode to the electron transport layer, and is a layer that contains a material with high electron injection properties.
- Alkali metals, alkaline earth metals, or compounds thereof can be used as materials with high electron injection properties.
- a composite material containing an electron-transporting material and a donor material (electron-donating material) can also be used as a material with high electron-injecting properties.
- the electron injection layer is, for example, lithium, cesium, lithium fluoride (LiF), cesium fluoride (CsF), calcium fluoride (CaF 2 ), 8-(quinolinolato)lithium (abbreviation: Liq), 2-(2- pyridyl)phenoratritium (abbreviation: LiPP), 2-(2-pyridyl)-3-pyridinolatritium (abbreviation: LiPPy), 4-phenyl-2-(2-pyridyl)phenoratritium (abbreviation: LiPPP), Lithium oxide (LiO x ), alkali metals such as cesium carbonate, alkaline earth metals, or compounds thereof can be used.
- Liq lithium, cesium, lithium fluoride
- CsF cesium fluoride
- CaF 2 calcium fluoride
- Liq 8-(quinolinolato)lithium
- LiPP 2-(2- pyridyl)phenoratritium
- an electron-transporting material may be used as the electron injection layer.
- a compound having a lone pair of electrons and an electron-deficient heteroaromatic ring can be used as the electron-transporting material.
- a compound having at least one of a pyridine ring, diazine ring (pyrimidine ring, pyrazine ring, pyridazine ring), and triazine ring can be used.
- the lowest unoccupied molecular orbital (LUMO) of the organic compound having an unshared electron pair is preferably -3.6 eV or more and -2.3 eV or less.
- CV cyclic voltammetry
- photoelectron spectroscopy optical absorption spectroscopy
- inverse photoelectron spectroscopy etc. are used to determine the highest occupied molecular orbital (HOMO) level and LUMO level of an organic compound. can be estimated.
- BPhen 4,7-diphenyl-1,10-phenanthroline
- NBPhen 2,9-bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline
- HATNA diquinoxalino [2,3-a:2′,3′-c]phenazine
- TmPPPyTz 2,4,6-tris[3′-(pyridin-3-yl)biphenyl-3-yl]-1,3 , 5-triazine
- TmPPPyTz 2,4,6-tris[3′-(pyridin-3-yl)biphenyl-3-yl]-1,3 , 5-triazine
- the fourth layer 113d and the fifth layer 113e each have an active layer.
- the fourth layer 113d and the fifth layer 113e may have active layers with the same configuration or may have active layers with different configurations.
- a microcavity structure can be produced by changing the thickness of the pixel electrode or the thickness of the optical adjustment layer in the light receiving devices 150d and 150e. In this case, the fourth layer 113d and the fifth layer 113e may have the same configuration.
- the first active layer 185d and the second active layer 185e each contain a semiconductor.
- the semiconductor include inorganic semiconductors such as silicon and organic semiconductors including organic compounds.
- an organic semiconductor is used as the semiconductor included in the active layer.
- the light-emitting layer and the active layer can be formed by the same method (for example, a vacuum deposition method), and a manufacturing apparatus can be shared, which is preferable.
- Electron-accepting organic semiconductor materials such as fullerenes (eg, C 60 , C 70 , etc.) and fullerene derivatives are examples of the n-type semiconductor material of the active layer.
- Fullerenes have a soccer ball-like shape, which is energetically stable.
- Fullerene has both deep (low) HOMO and LUMO levels. Since fullerene has a deep LUMO level, it has an extremely high electron-accepting property (acceptor property).
- acceptor property Normally, like benzene, when the ⁇ -electron conjugation (resonance) spreads in the plane, the electron-donating property (donor property) increases. , the electron acceptability becomes higher.
- a high electron-accepting property is useful as a light-receiving device because charge separation occurs quickly and efficiently.
- Both C 60 and C 70 have broad absorption bands in the visible light region, and C 70 is particularly preferable because it has a larger ⁇ -electron conjugated system than C 60 and has a wide absorption band in the long wavelength region.
- [6,6]-Phenyl-C71-butylic acid methyl ester (abbreviation: PC70BM), [6,6]-Phenyl-C61-butylic acid methyl ester (abbreviation: PC60BM), 1′,1 '',4',4''-Tetrahydro-di[1,4]methanonaphthaleno[1,2:2',3',56,60:2'',3''][5,6]fullerene-C60 (abbreviation: ICBA) and the like.
- PC70BM [6,6]-Phenyl-C71-butylic acid methyl ester
- PC60BM [6,6]-Phenyl-C61-butylic acid methyl ester
- ICBA 1,6]fullerene-C60
- n-type semiconductor materials include metal complexes having a quinoline skeleton, metal complexes having a benzoquinoline skeleton, metal complexes having an oxazole skeleton, metal complexes having a thiazole skeleton, oxadiazole derivatives, triazole derivatives, imidazole derivatives, oxazole derivatives, Thiazole derivatives, phenanthroline derivatives, quinoline derivatives, benzoquinoline derivatives, quinoxaline derivatives, dibenzoquinoxaline derivatives, pyridine derivatives, bipyridine derivatives, pyrimidine derivatives, naphthalene derivatives, anthracene derivatives, coumarin derivatives, rhodamine derivatives, triazine derivatives, quinone derivatives, etc. .
- Materials for the p-type semiconductor of the active layer include copper (II) phthalocyanine (CuPc), tetraphenyldibenzoperiflanthene (DBP), zinc phthalocyanine (ZnPc), tin phthalocyanine ( SnPc), quinacridone, and other electron-donating organic semiconductor materials.
- CuPc copper
- DBP tetraphenyldibenzoperiflanthene
- ZnPc zinc phthalocyanine
- SnPc tin phthalocyanine
- quinacridone quinacridone
- Examples of p-type semiconductor materials include carbazole derivatives, thiophene derivatives, furan derivatives, and compounds having an aromatic amine skeleton. Furthermore, materials for p-type semiconductors include naphthalene derivatives, anthracene derivatives, pyrene derivatives, triphenylene derivatives, fluorene derivatives, pyrrole derivatives, benzofuran derivatives, benzothiophene derivatives, indole derivatives, dibenzofuran derivatives, dibenzothiophene derivatives, indolocarbazole derivatives, and porphyrins.
- phthalocyanine derivatives phthalocyanine derivatives, naphthalocyanine derivatives, quinacridone derivatives, polyphenylenevinylene derivatives, polyparaphenylene derivatives, polyfluorene derivatives, polyvinylcarbazole derivatives, polythiophene derivatives and the like.
- the HOMO level of the electron-donating organic semiconductor material is preferably shallower (higher) than the HOMO level of the electron-accepting organic semiconductor material.
- the LUMO level of the electron-donating organic semiconductor material is preferably shallower (higher) than the LUMO level of the electron-accepting organic semiconductor material.
- a spherical fullerene as the electron-accepting organic semiconductor material, and use an organic semiconductor material with a shape close to a plane as the electron-donating organic semiconductor material. Molecules with similar shapes tend to gather together, and when molecules of the same type aggregate, the energy levels of the molecular orbitals are close to each other, so the carrier transportability can be enhanced.
- the active layer is preferably formed by co-depositing an n-type semiconductor and a p-type semiconductor.
- the active layer may be formed by laminating an n-type semiconductor and a p-type semiconductor.
- the fourth layer 113d and the fifth layer 113e are layers other than the active layer, which are highly hole-transporting substances, highly electron-transporting substances, or bipolar substances (electron-transporting and hole-transporting substances). It may further have a layer containing, for example, a substance with a high degree of resistance. Further, the fourth layer 113d and the fifth layer 113e may have various functional layers that can be used for the first layer 113a, the second layer 113b and the third layer 113c. good.
- Both low-molecular-weight compounds and high-molecular-weight compounds can be used in the light-receiving device, and inorganic compounds may be included.
- the layers constituting the light-receiving device can be formed by methods such as a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, and a coating method.
- hole-transporting materials include polymer compounds such as poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonic acid) (PEDOT/PSS), molybdenum oxide, and copper iodide (CuI).
- Inorganic compounds such as can be used.
- an inorganic compound such as zinc oxide (ZnO) can be used as the electron-transporting material.
- PBDB-T polymer compound such as a PBDB-T derivative
- a method of dispersing an acceptor material in PBDB-T or a PBDB-T derivative can be used.
- a third material may be mixed in addition to the n-type semiconductor material and the p-type semiconductor material.
- the third material may be a low-molecular compound or a high-molecular compound.
- a protective layer 131 on the light emitting devices 130a, 130b, 130c and the light receiving devices 150d, 150e.
- the conductivity of the protective layer 131 does not matter. At least one of an insulating film, a semiconductor film, and a conductive film can be used as the protective layer 131 .
- the protective layer 131 Since the protective layer 131 has an inorganic film, it prevents oxidation of the common electrode 115, suppresses the entry of impurities (moisture, oxygen, etc.) into the light-emitting devices 130a, 130b, 130c and the light-receiving devices 150d, 150e. Degradation of the light emitting device and the light receiving device can be suppressed, and the reliability of the display device can be improved.
- inorganic insulating films such as an oxide insulating film, a nitride insulating film, an oxynitride insulating film, and a nitride oxide insulating film can be used.
- oxide insulating film include a silicon oxide film, an aluminum oxide film, a gallium oxide film, a germanium oxide film, an yttrium oxide film, a zirconium oxide film, a lanthanum oxide film, a neodymium oxide film, a hafnium oxide film, a tantalum oxide film, and the like.
- nitride insulating film examples include a silicon nitride film, an aluminum nitride film, and the like.
- oxynitride insulating film examples include a silicon oxynitride film, an aluminum oxynitride film, and the like.
- nitride oxide insulating film a silicon nitride oxide film, an aluminum nitride oxide film, or the like can be given.
- oxynitride refers to a material whose composition contains more oxygen than nitrogen
- nitride oxide refers to a material whose composition contains more nitrogen than oxygen. point to the material.
- the protective layer 131 preferably has a nitride insulating film or a nitride oxide insulating film, and more preferably has a nitride insulating film.
- the protective layer 131 includes In—Sn oxide (also referred to as ITO), In—Zn oxide, Ga—Zn oxide, Al—Zn oxide, or indium gallium zinc oxide (In—Ga—Zn oxide, An inorganic film containing IGZO) or the like can also be used.
- the inorganic film preferably has a high resistance, and specifically, preferably has a higher resistance than the common electrode 115 .
- the inorganic film may further contain nitrogen.
- the protective layer 131 When the light emitted from the light-emitting device is taken out through the protective layer 131, the protective layer 131 preferably has high transparency to visible light.
- the protective layer 131 preferably has high transparency to visible light.
- ITO, IGZO, and aluminum oxide are preferable because they are inorganic materials with high transparency to visible light.
- the protective layer 131 for example, a stacked structure of an aluminum oxide film and a silicon nitride film over the aluminum oxide film, a stacked structure of an aluminum oxide film and an IGZO film over the aluminum oxide film, or the like can be used. can. By using the stacked structure, entry of impurities (water, oxygen, or the like) into the EL layer can be suppressed.
- the protective layer 131 may have an organic film.
- protective layer 131 may have both an organic film and an inorganic film.
- Each end of the pixel electrodes 111a, 111b, and 111c is covered with an insulating layer 121.
- a device manufactured using a metal mask or FMM may be referred to as a device with an MM (metal mask) structure.
- a device manufactured without using a metal mask or FMM may be referred to as a device with an MML (metal maskless) structure.
- a structure in which a light-emitting layer is separately formed or a light-emitting layer is separately painted in each color light-emitting device is referred to as SBS (Side By Side) structure.
- SBS Side By Side
- a light-emitting device capable of emitting white light is sometimes referred to as a white light-emitting device.
- a white light emitting device can be combined with a colored layer (for example, a color filter) to realize a full-color display device.
- Light-emitting devices can be broadly classified into single structures and tandem structures.
- a single-structure device preferably has one light-emitting unit between a pair of electrodes, and the light-emitting unit preferably includes one or more light-emitting layers.
- the light-emitting unit preferably includes one or more light-emitting layers.
- the luminescent color of the first luminescent layer and the luminescent color of the second luminescent layer have a complementary color relationship, it is possible to obtain a configuration in which the entire light emitting device emits white light.
- a tandem structure device preferably has two or more light-emitting units between a pair of electrodes, and each light-emitting unit preferably includes one or more light-emitting layers.
- each light-emitting unit preferably includes one or more light-emitting layers.
- a structure in which white light emission is obtained by combining light from the light emitting layers of a plurality of light emitting units may be employed. Note that the structure for obtaining white light emission is the same as the structure of the single structure.
- the light emitting device with the SBS structure can consume less power than the white light emitting device. If it is desired to keep power consumption low, it is preferable to use a light-emitting device with an SBS structure.
- the white light emitting device is preferable because the manufacturing process is simpler than that of the SBS structure light emitting device, so that the manufacturing cost can be lowered or the manufacturing yield can be increased.
- the display device of this embodiment can reduce the distance between the light emitting devices.
- the distance between the light emitting devices is 1 ⁇ m or less, preferably 500 nm or less, more preferably 200 nm or less, 100 nm or less, 90 nm or less, 70 nm or less, 50 nm or less, 30 nm or less, 20 nm or less, 15 nm or less, or 10 nm.
- the display device of this embodiment has a gap between the side surface of the first layer 113a and the side surface of the second layer 113b, or a gap between the side surface of the second layer 113b and the side surface of the third layer 113c. It has regions with a spacing of 1 ⁇ m or less, preferably 0.5 ⁇ m (500 nm) or less, and more preferably 100 nm or less.
- the distance between the light-emitting device and the light-receiving device can also be within the above range. Also, in order to suppress leakage between the light emitting device and the light receiving device, it is preferable to make the distance between the light emitting device and the light receiving device wider than the distance between the light emitting devices. For example, the distance between the light emitting device and the light receiving device can be 8 ⁇ m or less, 5 ⁇ m or less, or 3 ⁇ m or less.
- FIGS. 26A to 26D show side by side a cross-sectional view along dashed line X1-X2, a cross-sectional view along X3-X4, and a cross-sectional view along Y1-Y2 in FIG. 25A. 27 to 29 are similar to FIG. 26.
- FIG. 26A to 26D show side by side a cross-sectional view along dashed line X1-X2, a cross-sectional view along X3-X4, and a cross-sectional view along Y1-Y2 in FIG. 25A. 27 to 29 are similar to FIG. 26.
- FIG. 26A to 26D show side by side a cross-sectional view along dashed line X1-X2, a cross-sectional view along X3-X4, and a cross-sectional view along Y1-Y2 in FIG. 25A. 27 to 29 are similar to FIG. 26.
- FIG. 26A to 26D show side by side a cross-sectional view along dashed line X
- the thin films (insulating films, semiconductor films, conductive films, etc.) that make up the display device are formed by sputtering, chemical vapor deposition (CVD), vacuum deposition, pulsed laser deposition (PLD). ) method, ALD method, or the like.
- the CVD method includes a plasma enhanced CVD (PECVD) method, a thermal CVD method, and the like. Also, one of the thermal CVD methods is the metal organic CVD (MOCVD) method.
- Thin films (insulating films, semiconductor films, conductive films, etc.) that make up the display device are spin-coated, dipped, spray-coated, inkjet, dispense, screen-printed, offset-printed, doctor-knife, slit-coated, roll-coated, curtain-coated. , knife coating, or the like.
- vacuum processes such as vapor deposition and solution processes such as spin coating and inkjet can be used to fabricate light-emitting devices.
- vapor deposition methods include physical vapor deposition (PVD) such as sputtering, ion plating, ion beam vapor deposition, molecular beam vapor deposition, and vacuum vapor deposition, and chemical vapor deposition (CVD).
- PVD physical vapor deposition
- CVD chemical vapor deposition
- the functional layers (hole injection layer, hole transport layer, light emitting layer, electron transport layer, electron injection layer, etc.) included in the EL layer may be formed by a vapor deposition method (vacuum vapor deposition method, etc.), a coating method (dip coating method, die coat method, bar coat method, spin coat method, spray coat method, etc.), printing method (inkjet method, screen (stencil printing) method, offset (lithographic printing) method, flexographic (letterpress printing) method, gravure method, or micro contact method, etc.).
- a vapor deposition method vacuum vapor deposition method, etc.
- a coating method dip coating method, die coat method, bar coat method, spin coat method, spray coat method, etc.
- printing method inkjet method, screen (stencil printing) method, offset (lithographic printing) method, flexographic (letterpress printing) method, gravure method, or micro contact method, etc.
- the thin film that constitutes the display device When processing the thin film that constitutes the display device, it can be processed using a photolithography method or the like. Alternatively, the thin film may be processed by a nanoimprint method, a sandblast method, a lift-off method, or the like. Alternatively, an island-shaped thin film may be directly formed by a film formation method using a shielding mask such as a metal mask.
- the photolithography method typically includes the following two methods. One is a method of forming a resist mask on a thin film to be processed, processing the thin film by etching or the like, and removing the resist mask. The other is a method of forming a photosensitive thin film, then performing exposure and development to process the thin film into a desired shape.
- the light used for exposure can be, for example, i-line (wavelength 365 nm), g-line (wavelength 436 nm), h-line (wavelength 405 nm), or a mixture of these.
- ultraviolet rays, KrF laser light, ArF laser light, or the like can also be used.
- extreme ultraviolet (EUV: Extreme Ultra-violet) light or X-rays may be used.
- An electron beam can also be used instead of the light used for exposure. The use of extreme ultraviolet light, X-rays, or electron beams is preferable because extremely fine processing is possible.
- a photomask is not necessary when exposure is performed by scanning a beam such as an electron beam.
- a dry etching method, a wet etching method, a sandblasting method, or the like can be used to etch the thin film.
- pixel electrodes 111a, 111b, 111c, 111d, and 111e and a conductive layer 123 are formed over a layer 101 including transistors.
- Each pixel electrode is provided in the display portion, and the conductive layer 123 is provided in the connection portion 140 .
- an insulating layer 121 covering the ends of the pixel electrodes 111a, 111b, 111c, 111d, and 111e and the ends of the conductive layer 123 is formed.
- a first hole injection layer 181A, a first hole transport layer 182A, a first light emitting layer 183A, and a first hole transport layer 183A are formed. are formed in this order, a first sacrificial layer 118A is formed on the first electron transport layer 184A, and a second sacrificial layer 119A is formed on the first sacrificial layer 118A.
- the present invention is not limited to this.
- the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, the first electron-transport layer 184A, and the first sacrificial layer 118A overlap with the conductive layer 123. It doesn't have to be. Further, end portions of the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, and the first electron-transport layer 184A on the side of the connection portion 140 are the first sacrificial layers. 118A and the end of the second sacrificial layer 119A may be located inside. For example, by using a mask (also referred to as an area mask, a rough metal mask, etc.
- a mask also referred to as an area mask, a rough metal mask, etc.
- the first hole injection layer 181A and the first hole transport layer 182A are formed.
- the first light-emitting layer 183A, the first electron-transporting layer 184A, and the first sacrificial layer 118A and the second sacrificial layer 119A can vary.
- a light-emitting device is formed using a resist mask. By combining with an area mask as described above, a light-emitting device can be manufactured through a relatively simple process.
- the materials that can be used as pixel electrodes are as described above.
- a sputtering method or a vacuum deposition method can be used to form the pixel electrode.
- the insulating layer 121 can have a single layer structure or a laminated structure using one or both of an inorganic insulating film and an organic insulating film.
- organic insulating materials that can be used for the insulating layer 121 include acrylic resins, epoxy resins, polyimide resins, polyamide resins, polyimideamide resins, polysiloxane resins, benzocyclobutene resins, and phenol resins.
- an inorganic insulating film that can be used for the insulating layer 121 an inorganic insulating film that can be used for the protective layer 131 can be used.
- an inorganic insulating film is used as the insulating layer 121 covering the edge of the pixel electrode, impurities are less likely to enter the light-emitting device than when an organic insulating film is used, and the reliability of the light-emitting device can be improved.
- the step coverage is higher and the shape of the pixel electrode is less likely to affect the step coverage than when an inorganic insulating film is used. Therefore, short-circuiting of the light emitting device can be prevented.
- the shape of the insulating layer 121 can be processed into a tapered shape or the like.
- a tapered shape refers to a shape in which at least a part of the side surface of the structure is inclined with respect to the substrate surface.
- a region in which the angle formed by the inclined side surface and the substrate surface also referred to as a taper angle) is less than 90°.
- the insulating layer 121 may not be provided. By not providing the insulating layer 121, the aperture ratio of the sub-pixel can be increased in some cases. Alternatively, the distance between sub-pixels can be reduced, which may increase the definition or resolution of the display.
- the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, and the first electron-transport layer 184A are respectively later referred to as the first hole-injection layer 181a, the first These layers are to be the hole-transporting layer 182a, the first light-emitting layer 183a, and the first electron-transporting layer 184a. Therefore, the above-described structures applicable to the first hole-injection layer 181a, the first hole-transport layer 182a, the first light-emitting layer 183a, and the first electron-transport layer 184a can be applied.
- the first hole-injecting layer 181A, the first hole-transporting layer 182A, the first light-emitting layer 183A, and the first electron-transporting layer 184A are each formed by vapor deposition (including vacuum vapor deposition), transfer method, It can be formed by a method such as a printing method, an inkjet method, or a coating method. Also, the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first electron transport layer 184A may each be formed using a premix material. . In this specification and the like, a premix material is a composite material in which a plurality of materials are blended or mixed in advance.
- the sacrificial layer has a two-layer structure of a first sacrificial layer and a second sacrificial layer.
- the sacrificial layer includes a first hole-injection layer 181A, a first hole-transport layer 182A, a first light-emitting layer 183A, a first electron-transport layer 184A, and various functional layers formed in later steps.
- a film (a hole injection layer, a hole transport layer, a light-emitting layer, an electron transport layer, an active layer, etc.) having high resistance to processing conditions, specifically, a film having a high etching selectivity is used.
- a sputtering method for example, a sputtering method, an ALD method (thermal ALD method, PEALD method), or a vacuum deposition method can be used to form the sacrificial layer.
- a formation method that causes less damage to the EL layer is preferable, and the sacrificial layer is preferably formed by an ALD method or a vacuum evaporation method rather than a sputtering method.
- a film that can be removed by wet etching is preferably used for the sacrificial layer.
- the wet etching method the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first hole injection layer 181A, the first hole transport layer 182A, and the first light emitting layer 183A are easily etched during processing of the sacrificial layer, compared to the case of using the dry etching method. Damage to the first electron transport layer 184A can be reduced.
- various functional layers hole injection layer, hole transport layer, light emitting layer, active layer, and electron It is desirable that the transport layer, etc.) is difficult to process, and that various sacrificial layers are difficult to process in the process of processing the functional layer. It is desirable to select the material of the sacrificial layer, the processing method, and the processing method of the functional layer in consideration of these.
- inorganic films such as metal films, alloy films, metal oxide films, semiconductor films, and inorganic insulating films can be used.
- the sacrificial layer includes metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, titanium, aluminum, yttrium, zirconium, and tantalum, or the metal materials.
- metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, titanium, aluminum, yttrium, zirconium, and tantalum, or the metal materials.
- a metal oxide such as an In--Ga--Zn oxide can be used for the sacrificial layer.
- the sacrificial layer for example, an In--Ga--Zn oxide film can be formed using a sputtering method.
- indium oxide, In-Zn oxide, In-Sn oxide, indium titanium oxide (In-Ti oxide), indium tin zinc oxide (In-Sn-Zn oxide), indium titanium zinc oxide ( In--Ti--Zn oxide), indium gallium tin-zinc oxide (In--Ga--Sn--Zn oxide), or the like can be used.
- indium tin oxide containing silicon or the like can be used.
- element M is aluminum, silicon, boron, yttrium, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten , or one or more selected from magnesium
- M is preferably one or more selected from gallium, aluminum, and yttrium.
- Various inorganic insulating films that can be used for the protective layer 131 can be used for the sacrificial layer.
- an oxide insulating film is preferable because it has higher adhesion to the EL layer than a nitride insulating film.
- inorganic insulating materials such as aluminum oxide, hafnium oxide, and silicon oxide can be used for the sacrificial layer.
- an aluminum oxide film can be formed using the ALD method. Use of the ALD method is preferable because damage to the base (especially the EL layer or the like) can be reduced.
- a lamination structure of an In—Ga—Zn oxide film formed by a sputtering method and an aluminum oxide film formed on the In—Ga—Zn oxide film by an ALD method is applied as the sacrificial layer.
- a lamination structure of an aluminum oxide film formed by an ALD method and an In--Ga--Zn oxide film formed over the aluminum oxide film by a sputtering method can be used as the sacrificial layer.
- a single-layer structure of an aluminum oxide film formed by an ALD method can be applied as the sacrificial layer.
- a resist mask 190a is formed on the second sacrificial layer 119A.
- a resist mask can be formed by applying a photosensitive resin (photoresist), followed by exposure and development.
- the resist mask 190a is provided at a position overlapping with the pixel electrode 111a.
- the resist mask 190a preferably does not overlap with the pixel electrodes 111b, 111c, 111d, and 111e and the conductive layer 123.
- FIG. When the resist mask 190a overlaps with the pixel electrodes 111b, 111c, 111d, and 111e or the conductive layer 123, it is preferable to interpose the insulating layer 121 therebetween.
- a resist mask 190a is used to partially remove the second sacrificial layer 119A.
- a region of the second sacrificial layer 119A that does not overlap with the resist mask 190a can be removed. Therefore, the second sacrificial layer 119a remains at the position overlapping with the pixel electrode 111a. After that, the resist mask 190a is removed.
- the second sacrificial layer 119a is used to partially remove the first sacrificial layer 118A.
- the region of the first sacrificial layer 118A that does not overlap with the second sacrificial layer 119a can be removed. Therefore, a laminated structure of the first sacrificial layer 118a and the second sacrificial layer 119a remains at the position overlapping with the pixel electrode 111a.
- a portion of the first hole injection layer 181A and a portion of the first hole transport layer 182A are formed.
- a portion of the first light-emitting layer 183A and a portion of the first electron-transporting layer 184A are removed.
- the first sacrificial layer 118a and the second sacrificial layer of the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first electron transport layer 184A are formed. Areas not overlapping layer 119a can be removed.
- the pixel electrodes 111b, 111c, 111d, 111e and the conductive layer 123 are exposed. Then, on the pixel electrode 111a, a first hole-injection layer 181a, a first hole-transport layer 182a, a first light-emitting layer 183a, a first electron-transport layer 184a, a first sacrificial layer 118a, and A laminated structure of the second sacrificial layer 119a remains. Note that the stacked structure of the first hole-injection layer 181a, the first hole-transport layer 182a, the first light-emitting layer 183a, and the first electron-transport layer 184a is also referred to as the first layer 113a.
- the first sacrificial layer 118A and the second sacrificial layer 119A can be processed by wet etching or dry etching, respectively.
- the first sacrificial layer 118A and the second sacrificial layer 119A are preferably processed by anisotropic etching.
- the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first hole injection layer 181A, the first hole transport layer 182A, and the first light emitting layer 183A are easily etched during processing of the sacrificial layer, compared to the case of using the dry etching method. , damage to the first electron transport layer 184A can be reduced.
- a developer for example, a tetramethylammonium hydroxide aqueous solution (TMAH), dilute hydrofluoric acid, oxalic acid, phosphoric acid, acetic acid, nitric acid, or a chemical solution using a mixed liquid thereof can be used.
- TMAH tetramethylammonium hydroxide aqueous solution
- the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, and the first hole-injection layer 183A are formed by not using a gas containing oxygen as an etching gas. can suppress deterioration of the electron transport layer 184A.
- a gas containing a noble gas also referred to as a noble gas
- the sacrificial layer has a laminated structure, some layers are processed using the resist mask 190a, and after removing the resist mask 190a, the partial layers are used as a hard mask to process the remaining layers. be able to.
- the resist mask 190a is removed by ashing using oxygen plasma.
- the first sacrificial layer 118A is located on the outermost surface, and the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first electron transport layer 184A are formed. are not exposed, the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, and the first electron-transport layer 184A are exposed in the step of removing the resist mask 190a. You can prevent damage from occurring.
- the first sacrificial layer 118A can be processed.
- One hole-injection layer 181A, first hole-transport layer 182A, first light-emitting layer 183A, and first electron-transport layer 184A can be processed.
- the first hole injection layer 181A, the first hole transport layer 182A, the first light emitting layer 183A, and the first electron transport layer 184A are preferably processed by anisotropic etching.
- Anisotropic dry etching is particularly preferred.
- As the etching gas a gas containing nitrogen, a gas containing hydrogen, a gas containing noble gas, a gas containing nitrogen and argon, a gas containing nitrogen and hydrogen, or the like is preferably used.
- a gas containing oxygen By not using a gas containing oxygen as an etching gas, deterioration of the first hole-injection layer 181A, the first hole-transport layer 182A, the first light-emitting layer 183A, and the first electron-transport layer 184A can be prevented. can be suppressed.
- a second hole-injecting layer 181B and a second hole-transporting layer are formed on the second sacrificial layer 119a, the pixel electrodes 111b, 111c, 111d, and 111e, and the insulating layer 121.
- a layer 182B, a second light-emitting layer 183B, and a second electron-transporting layer 184B are formed in this order, a first sacrificial layer 118B is formed on the second electron-transporting layer 184B, and a first sacrificial layer 118B is formed.
- a second sacrificial layer 119B is formed thereon.
- the second hole-injection layer 181B, the second hole-transport layer 182B, the second light-emitting layer 183B, and the second electron-transport layer 184B are later formed into the second hole-injection layer 181b and the second electron-transport layer 184B, respectively. These layers are to be the hole-transporting layer 182b, the second light-emitting layer 183b, and the second electron-transporting layer 184b.
- the second light emitting layer 183b emits light of a color different from that of the first light emitting layer 183a.
- the structures, materials, and the like that can be applied to the second hole-injection layer 181b, the second hole-transport layer 182b, the second light-emitting layer 183b, and the second electron-transport layer 184b are the Similar to layer 181a, first hole-transporting layer 182a, first light-emitting layer 183a, and first electron-transporting layer 184a.
- the second hole-transport layer 182B, the second light-emitting layer 183B, and the second electron-transport layer 184B are the first hole-injection layer 181A, the first hole-transport layer 182A, and the first light-emitting layer, respectively.
- Layer 183A and the first electron-transporting layer 184A can be deposited using a similar method.
- the first sacrificial layer 118B and the second sacrificial layer 119B can be formed using materials applicable to the first sacrificial layer 118A and the second sacrificial layer 119A.
- a resist mask 190b is formed on the first sacrificial layer 118B.
- the resist mask 190b is provided at a position overlapping with the pixel electrode 111b.
- the resist mask 190b is removed. As a result, a region of the second sacrificial layer 119B that does not overlap with the resist mask 190b can be removed. Therefore, the second sacrificial layer 119b remains at the position overlapping with the pixel electrode 111b. After that, as shown in FIG. 28A, the resist mask 190b is removed.
- the first sacrificial layer 118B is processed to form the first sacrificial layer 118b. Then, as shown in FIG. 28B, the first sacrificial layer 118b and the second sacrificial layer 119b are used as hard masks to form a second hole injection layer 181B, a second hole transport layer 182B, a second hole transport layer 182B, and a second hole transport layer 182B.
- the second hole-injection layer 181b, the second hole-transport layer 182b, the second light-emitting layer 183b, and the second An electron transport layer 184b is formed.
- the stacked structure of the second hole-injection layer 181b, the second hole-transport layer 182b, the second light-emitting layer 183b, and the second electron-transport layer 184b is also referred to as a second layer 113b.
- the first sacrificial layer 118B and the second sacrificial layer 119B can be processed using a method applicable to the processing of the first sacrificial layer 118A and the second sacrificial layer 119A.
- the second hole-injection layer 181B, the second hole-transport layer 182B, the second light-emitting layer 183B, and the second electron-transport layer 184B are the first hole-injection layer 181A and the first hole-transport layer. It can be processed using methods applicable to the processing of layer 182A, first light-emitting layer 183A, and first electron-transporting layer 184A.
- the resist mask 190b can be removed by a method and timing applicable to removing the resist mask 190a.
- a stacked structure of a third layer 113c, a first sacrificial layer 118c, and a second sacrificial layer 119c is formed on the pixel electrode 111c, and a fourth layer 113d is formed on the pixel electrode 111d.
- a first sacrificial layer 118d, and a second sacrificial layer 119d are formed, and a fifth layer 113e, a first sacrificial layer 118e, and a second sacrificial layer 119e are formed on the pixel electrode 111e.
- a laminated structure In this embodiment, an example in which the fourth layer 113d and the fifth layer 113e have different structures is shown. It can be made in a process.
- the resist mask provided for forming the fifth layer 113 e is preferably provided so as to overlap with the conductive layer 123 .
- a laminated structure of the first sacrificial layer 118e and the second sacrificial layer 119e remains on the conductive layer 123 as shown in FIG. 28C.
- Such a structure is preferable because the conductive layer 123 can be prevented from being damaged in the next step of removing the first sacrificial layer and the second sacrificial layer.
- the first sacrificial layers 118a, 118b, 118c, 118d and 118e and the second sacrificial layers 119a, 119b, 119c, 119d and 119e are removed.
- the first electron-transporting layer 184a is exposed on the pixel electrode 111a
- the second electron-transporting layer 184b is exposed on the pixel electrode 111b
- the third electron-transporting layer 184c is exposed on the pixel electrode 111c.
- the fourth electron-transporting layer 184d is exposed on the pixel electrode 111d
- the fifth electron-transporting layer 184e is exposed on the pixel electrode 111e
- the conductive layer 123 is exposed on the connection portion 140.
- the same method as the sacrificial layer processing process can be used.
- the first layer 113a, the second layer 113b, the third layer 113c, and the fourth layer can be removed more easily than when the dry etching method is used. Damage to 113d and fifth layer 113e can be reduced.
- a sixth layer 114 is formed and a common electrode 115 is formed over the sixth layer 114 , the insulating layer 121 and the conductive layer 123 .
- the materials that can be used for the sixth layer 114 are as described above.
- Each of the layers constituting the sixth layer 114 can be formed by a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like.
- the layers constituting the sixth layer 114 may be formed using a premix material. Note that the sixth layer 114 may be omitted if unnecessary.
- the materials that can be used as the common electrode 115 are as described above.
- a sputtering method or a vacuum deposition method can be used.
- a protective layer 131 is formed on the common electrode 115 .
- the materials that can be used for the protective layer 131 are as described above.
- Methods for forming the protective layer 131 include a vacuum deposition method, a sputtering method, a CVD method, an ALD method, and the like.
- the protective layer 131 may have a single layer structure or a laminated structure.
- the protective layer 131 may have a laminated structure of two layers formed using different film formation methods.
- FIG. 29B shows an example in which the sixth layer 114 enters the regions of the first layer 113a and the second layer 113b, etc., but as shown in FIG. may be
- the voids 133 contain, for example, one or more selected from air, nitrogen, oxygen, carbon dioxide, and group 18 elements (typically helium, neon, argon, xenon, krypton, etc.).
- the refractive index of the air gap 133 is lower than that of the sixth layer 114 , the light emitted from the light emitting device will be reflected at the interface between the sixth layer 114 and the air gap 133 . This makes it possible to suppress the light emitted from the light emitting device from entering adjacent pixels (or sub-pixels). As a result, it is possible to prevent light of different colors from being mixed, so that the display quality of the display device can be improved.
- the display device 100F shown in FIG. 25B can be manufactured.
- the island-shaped EL layer is not formed by the pattern of the metal mask, but is formed by forming the EL layer over one surface and then processing the EL layer. Therefore, the island-shaped EL layer can be formed with a uniform thickness.
- each EL layer can be manufactured with a configuration (material, film thickness, etc.) suitable for each color light-emitting device. Thereby, a light-emitting device with good characteristics can be produced.
- FIGS. 30A and 30B An example different from the display device 100F shown in FIGS. 25A and 25B is shown in FIGS. 30A and 30B.
- a display device 100G shown in FIG. 30A has a display section in which a plurality of pixels 110A are arranged in a matrix and a connection section 140 outside the display section.
- One pixel 110A is composed of six sub-pixels: sub-pixel 110a, sub-pixel 110b, sub-pixel 110c, sub-pixel 110d, sub-pixel 110e, and sub-pixel 110f.
- FIG. 30A shows an example in which sub-pixels are provided over two rows and three columns for one pixel 110A.
- Pixel 110A has three sub-pixels (sub-pixel 110a, sub-pixel 110b, and sub-pixel 110c) in the upper row (first row) and three sub-pixels in the lower row (second row).
- sub-pixel 110d, sub-pixel 110e, and sub-pixel 110f sub-pixel 110d, sub-pixel 110e, and sub-pixel 110f.
- the pixel 110A has two subpixels (subpixel 110a and subpixel 110f) in the left column (first column) and two subpixels (subpixel 110f) in the center column (second column).
- pixel 110b and sub-pixel 110d) two sub-pixels (sub-pixel 110c and sub-pixel 110e) in the right column (third column).
- subpixel 110a, subpixel 110b, subpixel 110c, and subpixel 110f each have light-emitting devices that emit light in different wavelength ranges, and subpixels 110d and 110e are sensitive to different wavelength ranges.
- 1 shows an example having a light receiving device with
- the sub-pixel 110a, the sub-pixel 110b, the sub-pixel 110c, the sub-pixel 110d, the sub-pixel 110e, and the sub-pixel 110f are the sub-pixel G, the sub-pixel B, the sub-pixel R, the sub-pixel IR, the sub-pixel IR shown in FIG. It corresponds to the pixel PS and the sub-pixel IRS.
- FIG. 30B shows cross-sectional views along dashed-dotted lines X1-X2, X5-X6, and Y1-Y2 in FIG. 30A.
- the display device 100G includes a light-emitting device 130a, a light-emitting device 130b, a light-emitting device 130c, a light-emitting device 130f, a light-receiving device 150d, and a light-receiving device 150e on a layer 101 including transistors.
- a protective layer 131 is provided to cover the device and the light receiving device.
- a substrate 120 is bonded onto the protective layer 131 with a resin layer 119 .
- the light-emitting device 130a, the light-emitting device 130b, the light-emitting device 130c, and the light-emitting device 130f emit light in different wavelength ranges.
- Light emitting device 130f preferably emits infrared (IR) light, for example.
- the light-emitting device 130f includes a pixel electrode 111f on the layer 101 containing the transistor, a seventh layer 113f on the pixel electrode 111f, a sixth layer 114 on the seventh layer 113f, and a and a common electrode 115 .
- the seventh layer 113f and the sixth layer 114 can be collectively called an EL layer.
- the seventh layer 113f includes a seventh hole-injection layer 181f on the pixel electrode 111f, a seventh hole-transport layer 182f on the seventh hole-injection layer 181f, and a seventh hole-transport layer 182f. It has a fourth light emitting layer 183f on top and a seventh electron transport layer 184f on the fourth light emitting layer 183f.
- the above description can be referred to, so detailed description thereof will be omitted.
- the description related to the manufacturing method of the display device 100F can be referred to, so detailed description is omitted. Similar to forming light emitting devices 130a-c, light emitting device 130f can be formed. The order of forming the light emitting device 130a, the light emitting device 130b, the light emitting device 130c, the light emitting device 130f, the light receiving device 150d, and the light receiving device 150e is not particularly limited.
- the display device of this embodiment can be a high-resolution display device or a large-sized display device. Therefore, the display device of the present embodiment includes a relatively large screen such as a television device, a desktop or notebook personal computer, a computer monitor, a digital signage, a large game machine such as a pachinko machine, or the like. In addition to electronic devices, it can be used for display portions of digital cameras, digital video cameras, digital photo frames, mobile phones, portable game machines, personal digital assistants, and sound reproducing devices.
- a flexible printed circuit board Flexible Printed Circuit
- a connector such as a TCP (Tape Carrier Package) is attached to the display device, or a COG (Chip On Glass) method or a COF (A display device in which an integrated circuit (IC) is mounted by a Chip On Film method or the like is sometimes called a display panel module, a display module, or simply a display panel.
- FPC Flexible Printed Circuit
- TCP Transmission Carrier Package
- COG Chip On Glass
- COF A display device in which an integrated circuit (IC) is mounted by a Chip On Film method or the like is sometimes called a display panel module, a display module, or simply a display panel.
- FIG. 31 shows a perspective view of the display device 100H
- FIG. 32A shows a cross-sectional view of the display device 100H.
- the display device 100H has a configuration in which a substrate 152 and a substrate 151 are bonded together.
- the substrate 152 is clearly indicated by dashed lines.
- the display device 100H has a display section 162, a circuit 164, wiring 165, and the like.
- FIG. 31 shows an example in which an IC 173 and an FPC 172 are mounted on the display device 100H. Therefore, the configuration shown in FIG. 31 can also be said to be a display module including the display device 100H, an integrated circuit (IC), and an FPC.
- IC integrated circuit
- a scanning line driving circuit can be used.
- the wiring 165 has a function of supplying signals and power to the display section 162 and the circuit 164 .
- the signal and power are input to the wiring 165 from the outside through the FPC 172 or from the IC 173 .
- FIG. 31 shows an example in which an IC 173 is provided on a substrate 151 by a COG (Chip On Glass) method, a COF (Chip on Film) method, or the like.
- a COG Chip On Glass
- COF Chip on Film
- the IC 173 for example, an IC having a scanning line driver circuit or a signal line driver circuit can be applied.
- the display device 100H and the display module may be configured without an IC.
- the IC may be mounted on the FPC by the COF method or the like.
- FIG. 32A shows an example of a cross-section of the display device 100H when a portion of the region including the FPC 172, a portion of the circuit 164, a portion of the display portion 162, and a portion of the region including the edge are cut. show.
- a display device 100H shown in FIG. 32A includes a transistor 201, a transistor 205a, a transistor 205e, a light emitting device 130a, a light receiving device 150e, and the like between substrates 151 and 152.
- FIG. Light emitting device 130a emits red, green, or blue light, for example. Alternatively, light emitting device 130a may emit infrared light.
- the light receiving device 150e detects infrared light, for example. Alternatively, the light receiving device 150e may detect visible light, or both visible light and infrared light.
- the three sub-pixels are R, G, and B sub-pixels, yellow (Y), yellow (Y), and yellow (Y).
- Three sub-pixels of cyan (C) and magenta (M) can be used.
- the four sub-pixels include R, G, B, and white (W) sub-pixels, and R, G, B, and Y sub-pixels. .
- the protective layer 131 and the substrate 152 are adhered via the adhesive layer 142 .
- a solid sealing structure, a hollow sealing structure, or the like can be applied to sealing the light-emitting device.
- the space between substrates 152 and 151 is filled with an adhesive layer 142 to apply a solid sealing structure.
- the space may be filled with an inert gas (such as nitrogen or argon) to apply a hollow sealing structure.
- the adhesive layer 142 may be provided so as not to overlap the light emitting device.
- the space may be filled with a resin different from the adhesive layer 142 provided in a frame shape.
- the light emitting device 130a has a layered structure similar to that of the light emitting device 130a shown in FIG. 25B, and the light receiving device 150e has a layered structure similar to that of the light receiving device 150e shown in FIG. 25B.
- Embodiment 3 can be referred to for details of the light-emitting device and the light-receiving device.
- the end of the light emitting device 130a and the end of the light receiving device 150e are each covered with a protective layer 131. As shown in FIG.
- the pixel electrodes 111a and 111e are connected to the conductive layers 222b of the transistors 205a and 205e through openings provided in the insulating layer 214, respectively.
- the edge of the pixel electrode is covered with an insulating layer 121 .
- the pixel electrode contains a material that reflects visible light
- the common electrode contains a material that transmits visible light.
- the light emitted by the light emitting device is emitted to the substrate 152 side. Also, the light receiving device detects light incident from the substrate 152 side. Therefore, for the substrate 152, it is preferable to use a material having high transparency to visible light and infrared light.
- a laminated structure from the substrate 151 to the insulating layer 214 corresponds to the layer 101 including the transistor in the third embodiment.
- the transistors 201 , 205 a, and 205 e are all formed over the substrate 151 . These transistors can be made with the same material and the same process.
- An insulating layer 211, an insulating layer 213, an insulating layer 215, and an insulating layer 214 are provided on the substrate 151 in this order.
- Part of the insulating layer 211 functions as a gate insulating layer of each transistor.
- Part of the insulating layer 213 functions as a gate insulating layer of each transistor.
- An insulating layer 215 is provided over the transistor.
- An insulating layer 214 is provided over the transistor and functions as a planarization layer. Note that the number of gate insulating layers and the number of insulating layers covering a transistor are not limited, and each may have a single layer or two or more layers.
- a material in which impurities such as water and hydrogen are difficult to diffuse for at least one insulating layer covering the transistor.
- an inorganic insulating film for each of the insulating layer 211, the insulating layer 213, and the insulating layer 215.
- the inorganic insulating film for example, a silicon nitride film, a silicon oxynitride film, a silicon oxide film, a silicon nitride oxide film, an aluminum oxide film, an aluminum nitride film, or the like can be used.
- a hafnium oxide film, an yttrium oxide film, a zirconium oxide film, a gallium oxide film, a tantalum oxide film, a magnesium oxide film, a lanthanum oxide film, a cerium oxide film, a neodymium oxide film, or the like may be used.
- two or more of the insulating films described above may be laminated and used.
- the organic insulating film preferably has an opening near the end of the display device 100H. As a result, it is possible to prevent impurities from entering through the organic insulating film from the end portion of the display device 100H.
- the organic insulating film may be formed so that the edges of the organic insulating film are located inside the edges of the display device 100H so that the organic insulating film is not exposed at the edges of the display device 100H.
- An organic insulating film is suitable for the insulating layer 214 that functions as a planarization layer.
- Materials that can be used for the organic insulating film include acrylic resins, polyimide resins, epoxy resins, polyamide resins, polyimideamide resins, siloxane resins, benzocyclobutene resins, phenolic resins, precursors of these resins, and the like.
- An opening is formed in the insulating layer 214 in a region 228 shown in FIG. 32A.
- the transistor 201, the transistor 205a, and the transistor 205e include a conductive layer 221 functioning as a gate, an insulating layer 211 functioning as a gate insulating layer, conductive layers 222a and 222b functioning as sources and drains, a semiconductor layer 231, and a gate insulating layer. It has an insulating layer 213 functioning as a gate and a conductive layer 223 functioning as a gate.
- the same hatching pattern is applied to a plurality of layers obtained by processing the same conductive film.
- the insulating layer 211 is located between the conductive layer 221 and the semiconductor layer 231 .
- the insulating layer 213 is located between the conductive layer 223 and the semiconductor layer 231 .
- the structure of the transistor included in the display device of this embodiment there is no particular limitation on the structure of the transistor included in the display device of this embodiment.
- a planar transistor, a staggered transistor, an inverted staggered transistor, or the like can be used.
- the transistor structure may be either a top-gate type or a bottom-gate type.
- gates may be provided above and below a semiconductor layer in which a channel is formed.
- a structure in which a semiconductor layer in which a channel is formed is sandwiched between two gates is applied to the transistors 201, 205a, and 205e.
- a transistor may be driven by connecting two gates and applying the same signal to them.
- the threshold voltage of the transistor may be controlled by applying a potential for controlling the threshold voltage to one of the two gates and applying a potential for driving to the other.
- Crystallinity of a semiconductor material used for a transistor is not particularly limited, either an amorphous semiconductor or a semiconductor having crystallinity (a microcrystalline semiconductor, a polycrystalline semiconductor, a single crystal semiconductor, or a semiconductor partially including a crystal region). may be used. It is preferable to use a crystalline semiconductor because deterioration of transistor characteristics can be suppressed.
- a semiconductor layer of a transistor preferably includes a metal oxide (also referred to as an oxide semiconductor).
- the display device of this embodiment preferably uses a transistor including a metal oxide for a channel formation region (hereinafter referred to as an OS transistor).
- the semiconductor layer of the transistor may comprise silicon. Examples of silicon include amorphous silicon and crystalline silicon (low-temperature polysilicon, monocrystalline silicon, etc.).
- the semiconductor layer includes, for example, indium and M (M is gallium, aluminum, silicon, boron, yttrium, tin, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, one or more selected from hafnium, tantalum, tungsten, and magnesium) and zinc.
- M is preferably one or more selected from aluminum, gallium, yttrium, and tin.
- an oxide also referred to as IGZO
- IGZO oxide containing indium (In), gallium (Ga), and zinc (Zn) as the semiconductor layer.
- the atomic ratio of In in the In-M-Zn oxide is preferably equal to or higher than the atomic ratio of M.
- the transistor included in the circuit 164 and the transistor included in the display portion 162 may have the same structure or different structures.
- the plurality of transistors included in the circuit 164 may all have the same structure, or may have two or more types.
- the structures of the plurality of transistors included in the display portion 162 may all be the same, or may be of two or more types.
- 32B and 32C show other configuration examples of the transistor.
- the transistor 209 and the transistor 210 each include a conductive layer 221 functioning as a gate, an insulating layer 211 functioning as a gate insulating layer, a semiconductor layer 231 having a channel formation region 231i and a pair of low-resistance regions 231n, and one of the pair of low-resistance regions 231n.
- a conductive layer 222a connected to a pair of low-resistance regions 231n, a conductive layer 222b connected to the other of a pair of low-resistance regions 231n, an insulating layer 225 functioning as a gate insulating layer, a conductive layer 223 functioning as a gate, and an insulating layer 215 covering the conductive layer 223 have
- the insulating layer 211 is located between the conductive layer 221 and the channel formation region 231i.
- the insulating layer 225 is located at least between the conductive layer 223 and the channel formation region 231i.
- an insulating layer 218 may be provided to cover the transistor.
- the transistor 209 shown in FIG. 32B shows an example in which the insulating layer 225 covers the top surface and side surfaces of the semiconductor layer 231 .
- the conductive layers 222a and 222b are connected to the low-resistance region 231n through openings provided in the insulating layers 225 and 215, respectively.
- One of the conductive layers 222a and 222b functions as a source and the other functions as a drain.
- the insulating layer 225 overlaps the channel formation region 231i of the semiconductor layer 231 and does not overlap the low resistance region 231n.
- the insulating layer 215 is provided to cover the insulating layer 225 and the conductive layer 223, and the conductive layers 222a and 222b are connected to the low resistance region 231n through openings in the insulating layer 215, respectively.
- a connecting portion 204 is provided in a region of the substrate 151 where the substrate 152 does not overlap.
- the wiring 165 is electrically connected to the FPC 172 via the conductive layer 166 and the connecting layer 242 .
- the conductive layer 166 is a conductive film obtained by processing the same conductive film as the pixel electrode is shown.
- the conductive layer 166 is exposed on the upper surface of the connecting portion 204 .
- the connecting portion 204 and the FPC 172 can be electrically connected via the connecting layer 242 .
- a light shielding layer 148 is preferably provided on the surface of the substrate 152 on the substrate 151 side.
- various optical members can be arranged outside the substrate 152 .
- optical members include polarizing plates, retardation plates, light diffusion layers (diffusion films, etc.), antireflection layers, light collecting films, and the like.
- an antistatic film that suppresses adhesion of dust, a water-repellent film that prevents adhesion of dirt, a hard coat film that suppresses the occurrence of scratches due to use, a shock absorption layer, etc. are arranged on the outside of the substrate 152.
- an antistatic film that suppresses adhesion of dust
- a water-repellent film that prevents adhesion of dirt
- a hard coat film that suppresses the occurrence of scratches due to use
- a shock absorption layer, etc. are arranged.
- the protective layer 131 that covers the light-emitting device, it is possible to suppress the entry of impurities such as water into the light-emitting device and improve the reliability of the light-emitting device.
- the insulating layer 215 and the protective layer 131 are in contact with each other through the opening of the insulating layer 214 in the region 228 near the edge of the display device 100H.
- the inorganic insulating films are in contact with each other. This can prevent impurities from entering the display section 162 from the outside through the organic insulating film. Therefore, the reliability of the display device 100H can be improved.
- the substrates 151 and 152 glass, quartz, ceramics, sapphire, resins, metals, alloys, semiconductors, etc. can be used, respectively.
- a material that transmits the light is used for the substrate on the side from which the light from the light-emitting device is extracted.
- the flexibility of the display device can be increased.
- a polarizing plate may be used as the substrate 151 or the substrate 152 .
- the substrates 151 and 152 are made of polyester resin such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyacrylonitrile resin, acrylic resin, polyimide resin, polymethyl methacrylate resin, polycarbonate (PC) resin, and polyethersulfone, respectively.
- PET polyethylene terephthalate
- PEN polyethylene naphthalate
- PES polyacrylonitrile resin
- acrylic resin acrylic resin
- polyimide resin polymethyl methacrylate resin
- PC polycarbonate
- PC polyethersulfone
- PS polyamide resin
- polysiloxane resin polysiloxane resin
- cycloolefin resin polystyrene resin
- polyamideimide resin polyurethane resin
- polyvinyl chloride resin polyvinylidene chloride resin
- polypropylene resin polytetrafluoroethylene (PTFE) resin
- PTFE polytetrafluoroethylene
- ABS resin cellulose nanofiber,
- a substrate having high optical isotropy has small birefringence (it can be said that the amount of birefringence is small).
- the absolute value of the retardation (retardation) value of the substrate with high optical isotropy is preferably 30 nm or less, more preferably 20 nm or less, and even more preferably 10 nm or less.
- Films with high optical isotropy include triacetylcellulose (TAC, also called cellulose triacetate) films, cycloolefin polymer (COP) films, cycloolefin copolymer (COC) films, and acrylic films.
- TAC triacetylcellulose
- COP cycloolefin polymer
- COC cycloolefin copolymer
- the film When a film is used as a substrate, the film may absorb water, which may cause the display panel to wrinkle and change its shape. Therefore, it is preferable to use a film having a low water absorption rate as the substrate. For example, it is preferable to use a film with a water absorption of 1% or less, more preferably 0.1% or less, and even more preferably 0.01% or less.
- various curable adhesives such as photocurable adhesives such as ultraviolet curable adhesives, reaction curable adhesives, thermosetting adhesives, and anaerobic adhesives can be used.
- These adhesives include epoxy resins, acrylic resins, silicone resins, phenol resins, polyimide resins, imide resins, PVC (polyvinyl chloride) resins, PVB (polyvinyl butyral) resins, EVA (ethylene vinyl acetate) resins, and the like.
- a material with low moisture permeability such as epoxy resin is preferable.
- a two-liquid mixed type resin may be used.
- an adhesive sheet or the like may be used.
- An anisotropic conductive film (ACF: Anisotropic Conductive Film), an anisotropic conductive paste (ACP: Anisotropic Conductive Paste), or the like can be used for the connection layer 242 .
- ACF Anisotropic Conductive Film
- ACP Anisotropic Conductive Paste
- Aluminum, titanium, chromium, nickel, copper, yttrium, zirconium, molybdenum, silver, and tantalum can be used for conductive layers such as gates, sources, and drains of transistors, as well as various wirings and electrodes that constitute display devices. , metals such as tungsten, and alloys containing these metals as main components. A film containing these materials can be used as a single layer or as a laminated structure.
- Conductive oxides such as indium oxide, indium tin oxide, indium zinc oxide, zinc oxide, gallium-containing zinc oxide, or graphene can be used as the conductive material having translucency.
- metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, and titanium, or alloy materials containing such metal materials can be used.
- a nitride of the metal material eg, titanium nitride
- it is preferably thin enough to have translucency.
- a stacked film of any of the above materials can be used as the conductive layer.
- a laminated film of a silver-magnesium alloy and indium tin oxide because the conductivity can be increased.
- conductive layers such as various wirings and electrodes that constitute a display device, and conductive layers (conductive layers functioning as pixel electrodes or common electrodes) of light-emitting devices.
- Examples of insulating materials that can be used for each insulating layer include resins such as acrylic resins and epoxy resins, and inorganic insulating materials such as silicon oxide, silicon oxynitride, silicon nitride oxide, silicon nitride, and aluminum oxide.
- the light-emitting device shown in FIG. 33A has an electrode 772, an EL layer 786, and an electrode 788.
- One of electrode 772 and electrode 788 functions as an anode and the other functions as a cathode.
- One of the electrodes 772 and 788 functions as a pixel electrode and the other functions as a common electrode. Further, it is preferable that the electrode on the side from which light is extracted out of the electrodes 772 and 788 has a property of transmitting visible light, and the other electrode reflects visible light.
- the EL layer 786 of the light-emitting device can be composed of multiple layers such as a layer 4420, a light-emitting layer 4411, and a layer 4430, as shown in FIG. 33A.
- the layer 4420 can have, for example, a layer containing a substance with high electron-injection properties (electron-injection layer) and a layer containing a substance with high electron-transport properties (electron-transporting layer).
- the light-emitting layer 4411 contains, for example, a light-emitting compound.
- the layer 4430 can have, for example, a layer containing a substance with high hole-injection properties (hole-injection layer) and a layer containing a substance with high hole-transport properties (hole-transport layer).
- a structure having a layer 4420, a light-emitting layer 4411, and a layer 4430 provided between a pair of electrodes can function as a single light-emitting unit, and the structure of FIG. 33A is referred to herein as a single structure.
- FIG. 33B is a modification of the EL layer 786 of the light emitting device shown in FIG. 33A. Specifically, the light-emitting device shown in FIG. layer 4420-1, layer 4420-2 on layer 4420-1, and electrode 788 on layer 4420-2. For example, if electrode 772 were the anode and electrode 788 was the cathode, layer 4430-1 would function as a hole injection layer, layer 4430-2 would function as a hole transport layer, and layer 4420-1 would function as an electron transport layer. and layer 4420-2 functions as an electron injection layer.
- layer 4430-1 functions as an electron-injecting layer
- layer 4430-2 functions as an electron-transporting layer
- layer 4420-1 functions as a hole-transporting layer. function
- layer 4420-2 functions as a hole injection layer.
- a configuration in which a plurality of light-emitting layers (light-emitting layers 4411, 4412, and 4413) are provided between layers 4420 and 4430 as shown in FIG. 33C is also a variation of the single structure.
- tandem structure a structure in which a plurality of light-emitting units (EL layers 786a and 786b) are connected in series via an intermediate layer 4440 (also referred to as a charge generation layer) is referred to as a tandem structure in this specification. call.
- EL layers 786a and 786b light-emitting units
- intermediate layer 4440 also referred to as a charge generation layer
- tandem structure enables a light-emitting device capable of emitting light with high luminance.
- each of the layers 4420 and 4430 can have a laminated structure composed of two or more layers.
- the emission color of the light-emitting device can be red, green, blue, cyan, magenta, yellow, white, or the like, depending on the material forming the EL layer 786 . Further, the color purity can be further enhanced by providing the light-emitting device with a microcavity structure.
- a light-emitting device that emits white light preferably has a structure in which two or more types of light-emitting substances are contained in the light-emitting layer.
- light-emitting substances may be selected so that each emission has a complementary color relationship. For example, by making the emission color of the first light-emitting layer and the emission color of the second light-emitting layer have a complementary color relationship, it is possible to obtain a light-emitting device that emits white light as a whole.
- a structure in which white light is emitted can be obtained by mixing respective emission colors.
- the light-emitting layer preferably contains two or more light-emitting substances that emit light such as R (red), G (green), B (blue), Y (yellow), and O (orange).
- R red
- G green
- B blue
- Y yellow
- O orange
- FIG. 34A A schematic cross-sectional view of the display device 500 is shown in FIG. 34A.
- the display device 500 has a light emitting device 550R that emits red light, a light emitting device 550G that emits green light, and a light emitting device 550B that emits blue light. Note that in this embodiment mode, a description of a light-receiving device included in a display device is omitted.
- the light-emitting device 550R has a structure in which two light-emitting units (light-emitting unit 512R_1 and light-emitting unit 512R_2) are stacked via an intermediate layer 531 between a pair of electrodes (electrodes 501 and 502).
- the light emitting device 550G has a light emitting unit 512G_1 and a light emitting unit 512G_2
- the light emitting device 550B has a light emitting unit 512B_1 and a light emitting unit 512B_2.
- the electrode 501 functions as a pixel electrode and is provided for each light emitting device.
- the electrode 502 functions as a common electrode and is commonly provided for a plurality of light emitting devices.
- the light emitting unit 512R_1 has layers 521, 522, 523R, 524, and the like.
- the light-emitting unit 512R_2 includes a layer 522, a light-emitting layer 523R, a layer 524, and the like.
- the light-emitting device 550R has a layer 525 and the like between the light-emitting unit 512R_2 and the electrode 502. FIG. Note that the layer 525 can also be considered part of the light emitting unit 512R_2.
- the layer 521 has, for example, a layer (hole injection layer) containing a highly hole-injecting substance.
- the layer 522 includes, for example, a layer containing a substance with a high hole-transport property (hole-transport layer).
- the layer 524 includes, for example, a layer containing a highly electron-transporting substance (electron-transporting layer).
- the layer 525 includes, for example, a layer containing a highly electron-injecting substance (electron-injection layer).
- the layer 521 may have an electron-injection layer
- the layer 522 may have an electron-transport layer
- the layer 524 may have a hole-transport layer
- the layer 525 may have a hole-injection layer.
- the layer 522, the light-emitting layer 523R, and the layer 524 may have the same configuration (material, film thickness, etc.) in the light-emitting unit 512R_1 and the light-emitting unit 512R_2, or may have different configurations.
- the layers are not limited to this.
- the layer 521 has a function of both a hole-injection layer and a hole-transport layer, or when the layer 521 has a function of both an electron-injection layer and an electron-transport layer , the layer 522 may be omitted.
- the intermediate layer 531 has a function of injecting electrons into one of the light emitting units 512R_1 and 512R_2 and holes into the other when a voltage is applied between the electrodes 501 and 502 .
- the intermediate layer 531 can also be called a charge generation layer.
- a material applicable to an electron injection layer such as lithium fluoride
- a material applicable to the hole injection layer can be suitably used.
- a layer containing a hole-transporting material and an acceptor material can be used for the intermediate layer.
- a layer containing an electron-transporting material and a donor material can be used for the intermediate layer.
- the light-emitting layer 523R included in the light-emitting device 550R includes a light-emitting substance that emits red light
- the light-emitting layer 523G included in the light-emitting device 550G includes a light-emitting substance that emits green light
- 523B has a luminescent material that exhibits blue emission.
- the light-emitting device 550G and the light-emitting device 550B each have a configuration in which the light-emitting layer 523R of the light-emitting device 550R is replaced with a light-emitting layer 523G and a light-emitting layer 523B, and other configurations are the same as those of the light-emitting device 550R. .
- the layers 521, 522, 524, and 525 may have the same configuration (material, film thickness, etc.) in the light emitting device of each color, or may have different configurations.
- tandem structure A configuration in which a plurality of light-emitting units are connected in series via an intermediate layer 531, such as the light-emitting device 550R, the light-emitting device 550G, and the light-emitting device 550B, is referred to herein as a tandem structure.
- a structure having one light-emitting unit between a pair of electrodes is called a single structure.
- the tandem structure it is called a tandem structure, but it is not limited to this, and for example, the tandem structure may be called a stack structure.
- the tandem structure enables a light-emitting device capable of emitting light with high luminance.
- the tandem structure can reduce the current required to obtain the same luminance as compared with the single structure, so reliability can be improved.
- a structure in which a light-emitting layer is separately formed for each light-emitting device, such as the light-emitting device 550R, the light-emitting device 550G, and the light-emitting device 550B, is sometimes called an SBS (side-by-side) structure.
- SBS side-by-side
- the material and structure can be optimized for each light-emitting device, so the degree of freedom in selecting the material and structure increases, and it becomes easy to improve luminance and reliability.
- the display device 500 has a tandem structure and an SBS structure. Therefore, it is possible to have both the merit of the tandem structure and the merit of the SBS structure.
- the display device 500 may be called a two-stage tandem structure because it has a structure in which two light-emitting units are formed in series as shown in FIG. 34A. Further, in the two-stage tandem structure shown in FIG. 34A, the structure is such that the second light-emitting unit having the red light-emitting layer is stacked on the first light-emitting unit having the red light-emitting layer. Similarly, the two-stage tandem structure shown in FIG.
- 34A has a structure in which a second light-emitting unit having a green light-emitting layer is stacked on a first light-emitting unit having a green light-emitting layer. A structure is obtained in which the second light-emitting unit having a blue light-emitting layer is stacked on the first light-emitting unit.
- the light-emitting unit 512R_1, the intermediate layer 531, the light-emitting unit 512R_2, and the layer 525 can be formed as island-shaped layers. Further, the light-emitting unit 512G_1, the intermediate layer 531, the light-emitting unit 512G_2, and the layer 525 can be formed as island-shaped layers. The light-emitting unit 512B_1, the intermediate layer 531, the light-emitting unit 512B_2, and the layer 525 can be formed as island-shaped layers. That is, the layer 113 shown in FIG. 34A corresponds to the first layer 113a, the second layer 113b, or the third layer 113c shown in FIG. 25B and the like.
- FIG. 34B is a modification of the display device 500 shown in FIG. 34A.
- a display device 500 shown in FIG. 34B is an example in which a layer 525 is commonly provided between light emitting devices, like the electrode 502 .
- layer 525 can be referred to as a common layer.
- the light-emitting unit 512R_1, the intermediate layer 531, and the light-emitting unit 512R_2 can be formed as island-shaped layers.
- the light-emitting unit 512G_1, the intermediate layer 531, and the light-emitting unit 512G_2 can be formed as island-shaped layers.
- the light-emitting unit 512B_1, the intermediate layer 531, and the light-emitting unit 512B_2 can be formed as island-shaped layers. That is, the layer 113 shown in FIG. 34B corresponds to the first layer 113a, the second layer 113b, or the third layer 113c shown in FIG. 25B and the like. Also, the layer 525 corresponds to the sixth layer 114 shown in FIG. 25B. 35 to 37, the layer corresponding to the first layer 113a, the second layer 113b, or the third layer 113c shown in FIG.
- a display device 500 shown in FIG. 35A is an example in which three light emitting units are stacked.
- a light-emitting device 550R has a light-emitting unit 512R_3 laminated on a light-emitting unit 512R_2 with an intermediate layer 531 interposed therebetween.
- the light-emitting unit 512R_3 includes a layer 522, a light-emitting layer 523R, a layer 524, and the like.
- a configuration similar to that of the light emitting unit 512R_2 can be applied to the light emitting unit 512R_3.
- FIG. 35B shows an example of stacking n light-emitting units (n is an integer of 2 or more).
- the luminance obtained from the light-emitting device with the same amount of current can be increased according to the number of stacked layers. Further, by increasing the number of stacked light-emitting units, the current required to obtain the same luminance can be reduced, so the power consumption of the light-emitting device can be reduced according to the number of stacked layers.
- a display device 500 shown in FIG. 36A shows an example in which two adjacent light-emitting devices are spaced apart and electrodes 502 are provided along the side surfaces of the light-emitting units and intermediate layer 531 .
- the intermediate layer 531 and the electrode 502 come into contact with each other, an electrical short may occur. Therefore, it is preferable to insulate the intermediate layer 531 and the electrode 502 .
- FIG. 36A shows an example in which an insulating layer 541 is provided to cover the side surfaces of the electrode 501, each light emitting unit, and the intermediate layer 531.
- the insulating layer 541 can be called a sidewall, a sidewall protective layer, a sidewall insulating film, or the like.
- the intermediate layer 531 and the electrode 502 can be electrically insulated.
- each light-emitting unit and intermediate layer 531 are preferably perpendicular or substantially perpendicular to the formation surface.
- the angle formed by the surface to be formed and these side surfaces be 60 degrees or more and 90 degrees or less.
- FIG. 36B shows an example in which the layer 525 and the electrode 502 are provided along the sides of the light emitting unit and the intermediate layer 531.
- FIG. Furthermore, a two-layer structure of an insulating layer 541 and an insulating layer 542 is provided as a side wall protective layer.
- FIG. 37A is a modification of FIG. 36B.
- 37B is an enlarged view of region 503 shown in FIG. 37A.
- 37A and 36B differ in the shape of the end portion of the insulating layer 542.
- the shape of the edge of the insulating layer 542 is different, and the layer 525 and the electrode 502 are formed along the shape of the insulating layer 542, so the shapes of the layer 525 and the electrode 502 are also different.
- 37A differs from FIG. 36B in that the insulating layer 542 is thicker than the insulating layer 541.
- FIG. The shape of the end of the insulating layer 542 can be rounded as shown in FIG. 37B.
- the end portion of the insulating layer 542 is rounded as shown in FIG. Become.
- the coverage of the layer 525 and the electrode 502 is improved, which is preferable.
- FIGS. 37A and 37B by making the thickness of the insulating layer 542 thicker than the thickness of the insulating layer 541, the shape of the end portion may be easily rounded.
- the insulating layer 541 (and the insulating layer 542) functioning as a side wall protective layer can prevent electrical short-circuiting between the electrode 502 and the intermediate layer 531.
- electrical short-circuiting between the electrodes 501 and 502 can be prevented. This can prevent electrical shorts at the four corners of the light emitting device.
- An inorganic insulating film is preferably used for each of the insulating layers 541 and 542 .
- oxides or nitrides can be used, such as silicon oxide, silicon oxynitride, silicon oxynitride, silicon nitride, aluminum oxide, aluminum oxynitride, or hafnium oxide.
- yttrium oxide, zirconium oxide, gallium oxide, tantalum oxide, magnesium oxide, lanthanum oxide, cerium oxide, neodymium oxide, or the like may be used.
- the insulating layer 541 and the insulating layer 542 can be formed by various film forming methods such as sputtering, vapor deposition, CVD, and ALD.
- the ALD method causes little film formation damage to a layer to be formed
- the insulating layer 541 that is directly formed over the light-emitting unit and the intermediate layer 531 is preferably formed by the ALD method.
- an aluminum oxide film formed by an ALD method can be used for the insulating layer 541, and a silicon nitride film formed by a sputtering method can be used for the insulating layer 542.
- one or both of the insulating layer 541 and the insulating layer 542 have a function as a barrier insulating film against at least one of water and oxygen.
- one or both of the insulating layer 541 and the insulating layer 542 preferably have a function of suppressing diffusion of at least one of water and oxygen.
- one or both of the insulating layer 541 and the insulating layer 542 preferably have a function of capturing or fixing at least one of water and oxygen (also referred to as gettering).
- a barrier insulating film indicates an insulating film having barrier properties.
- barrier property refers to a function of suppressing diffusion of a corresponding substance (also referred to as low permeability).
- the corresponding substance has a function of capturing or fixing (also called gettering).
- One or both of the insulating layer 541 and the insulating layer 542 have the barrier insulating film function or gettering function described above, so that impurities (typically, water or oxygen) that can diffuse into each light-emitting device from the outside are prevented. It becomes a configuration that can suppress the intrusion of With such a structure, a highly reliable display device can be provided.
- the configuration may be such that the insulating layer 541 and the insulating layer 542 functioning as side wall protective layers are not provided.
- layer 525 is provided on the sides of each light emitting unit and intermediate layer 531 .
- the light-emitting material of the light-emitting layer is not particularly limited.
- the light-emitting layer 523R included in the light-emitting unit 512R_1 includes a phosphorescent material
- the light-emitting layer 523R included in the light-emitting unit 512R_2 includes a phosphorescent material
- the light-emitting layer 523G included in the light-emitting unit 512G_1 includes
- the light-emitting layer 523G of the light-emitting unit 512G_2 contains a fluorescent material
- the light-emitting layer 523B of the light-emitting unit 512B_1 contains a fluorescent material
- the light-emitting layer 523B of the light-emitting unit 512B_2 contains It can be configured to have a fluorescent material.
- the light-emitting layer 523R included in the light-emitting unit 512R_1 includes a phosphorescent material
- the light-emitting layer 523R included in the light-emitting unit 512R_2 includes a phosphorescent material
- the light-emitting layer 523G included in the light-emitting unit 512G_1 includes The light-emitting layer 523G of the light-emitting unit 512G_2 contains a phosphorescent material
- the light-emitting layer 523B of the light-emitting unit 512B_1 contains a fluorescent material
- the light-emitting layer 523B of the light-emitting unit 512B_2 contains It can be configured to have a fluorescent material.
- the display device of one embodiment of the present invention may have a structure in which all the light-emitting layers are made of a fluorescent material, or all of the light-emitting layers are made of a phosphorescent material.
- the light-emitting layer 523R of the light-emitting unit 512R_1 is made of a phosphorescent material and the light-emitting layer 523R of the light-emitting unit 512R_2 is made of a fluorescent material, or the light-emitting layer 523R of the light-emitting unit 512R_1 is made of a fluorescent material.
- a phosphorescent material may be used for the light-emitting layer 523R included in the light-emitting unit 512R_2, that is, a structure in which the light-emitting layer in the first stage and the light-emitting layer in the second stage are formed using different materials.
- the description here is made for the light-emitting unit 512R_1 and the light-emitting unit 512R_2, the same configuration can be applied to the light-emitting unit 512G_1 and the light-emitting unit 512G_2, and the light-emitting unit 512B_1 and the light-emitting unit 512B_2. can.
- the metal oxide preferably contains at least indium or zinc. In particular, it preferably contains indium and zinc. In addition to these, aluminum, gallium, yttrium, tin and the like are preferably contained. In addition, one or more selected from boron, silicon, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, magnesium, cobalt, etc. may be contained. .
- the metal oxide is formed by chemical vapor deposition (CVD) such as sputtering, metal organic chemical vapor deposition (MOCVD), or atomic layer deposition (ALD). ) method or the like.
- CVD chemical vapor deposition
- MOCVD metal organic chemical vapor deposition
- ALD atomic layer deposition
- Crystal structures of oxide semiconductors include amorphous (including completely amorphous), CAAC (c-axis-aligned crystalline), nc (nanocrystalline), CAC (cloud-aligned composite), single crystal, and polycrystalline ( poly crystal) and the like.
- the crystal structure of the film or substrate can be evaluated using an X-ray diffraction (XRD) spectrum.
- XRD X-ray diffraction
- it can be evaluated using an XRD spectrum obtained by GIXD (Grazing-Incidence XRD) measurement.
- GIXD Gram-Incidence XRD
- the GIXD method is also called a thin film method or a Seemann-Bohlin method.
- the shape of the peak of the XRD spectrum is almost bilaterally symmetrical.
- the peak shape of the XRD spectrum is left-right asymmetric.
- the asymmetric shape of the peaks in the XRD spectra demonstrates the presence of crystals in the film or substrate. In other words, the film or substrate cannot be said to be in an amorphous state unless the shape of the peaks in the XRD spectrum is symmetrical.
- the crystal structure of a film or substrate can be evaluated by a diffraction pattern (also referred to as a nano beam electron diffraction pattern) observed by nano beam electron diffraction (NBED).
- a diffraction pattern also referred to as a nano beam electron diffraction pattern
- NBED nano beam electron diffraction
- a halo is observed in the diffraction pattern of a quartz glass substrate, and it can be confirmed that the quartz glass is in an amorphous state.
- a spot-like pattern is observed instead of a halo. Therefore, it is presumed that the IGZO film deposited at room temperature is neither crystalline nor amorphous, but in an intermediate state and cannot be concluded to be in an amorphous state.
- oxide semiconductors may be classified differently from the above when their structures are focused. For example, oxide semiconductors are classified into single-crystal oxide semiconductors and non-single-crystal oxide semiconductors.
- Non-single-crystal oxide semiconductors include, for example, the above CAAC-OS and nc-OS.
- Non-single-crystal oxide semiconductors include polycrystalline oxide semiconductors, amorphous-like oxide semiconductors (a-like OS), amorphous oxide semiconductors, and the like.
- CAAC-OS is an oxide semiconductor that includes a plurality of crystal regions, and the c-axes of the plurality of crystal regions are oriented in a specific direction. Note that the specific direction is the thickness direction of the CAAC-OS film, the normal direction to the formation surface of the CAAC-OS film, or the normal direction to the surface of the CAAC-OS film.
- a crystalline region is a region having periodicity in atomic arrangement. If the atomic arrangement is regarded as a lattice arrangement, the crystalline region is also a region with a uniform lattice arrangement.
- CAAC-OS has a region where a plurality of crystal regions are connected in the a-b plane direction, and the region may have strain.
- the strain refers to a portion where the orientation of the lattice arrangement changes between a region with a uniform lattice arrangement and another region with a uniform lattice arrangement in a region where a plurality of crystal regions are connected. That is, CAAC-OS is an oxide semiconductor that is c-axis oriented and has no obvious orientation in the ab plane direction.
- each of the plurality of crystal regions is composed of one or more microcrystals (crystals having a maximum diameter of less than 10 nm).
- the maximum diameter of the crystalline region is less than 10 nm.
- the size of the crystal region may be about several tens of nanometers.
- CAAC-OS is a layer containing indium (In) and oxygen ( It tends to have a layered crystal structure (also referred to as a layered structure) in which an In layer) and a layer containing the element M, zinc (Zn), and oxygen (hereinafter, a (M, Zn) layer) are laminated.
- the (M, Zn) layer may contain indium.
- the In layer contains the element M.
- the In layer may contain Zn.
- the layered structure is observed as a lattice image in, for example, a high-resolution TEM (Transmission Electron Microscope) image.
- spots are observed in the electron beam diffraction pattern of the CAAC-OS film.
- a certain spot and another spot are observed at point-symmetrical positions with respect to the spot of the incident electron beam that has passed through the sample (also referred to as a direct spot) as the center of symmetry.
- the lattice arrangement in the crystal region is basically a hexagonal lattice, but the unit cell is not always a regular hexagon and may be a non-regular hexagon. Moreover, the distortion may have a lattice arrangement such as a pentagon or a heptagon. Note that in CAAC-OS, no clear crystal grain boundary can be observed even near the strain. That is, it can be seen that the distortion of the lattice arrangement suppresses the formation of grain boundaries. This is because the CAAC-OS can tolerate strain due to the fact that the arrangement of oxygen atoms is not dense in the ab plane direction and the bond distance between atoms changes due to the substitution of metal atoms. it is conceivable that.
- a crystal structure in which clear grain boundaries are confirmed is called a polycrystal.
- a grain boundary becomes a recombination center, traps carriers, and is highly likely to cause a decrease in on-current of a transistor, a decrease in field-effect mobility, and the like. Therefore, a CAAC-OS in which no clear grain boundaries are observed is one of crystalline oxides having a crystal structure suitable for a semiconductor layer of a transistor.
- a structure containing Zn is preferable for forming a CAAC-OS.
- In--Zn oxide and In--Ga--Zn oxide are preferable because they can suppress the generation of grain boundaries more than In oxide.
- CAAC-OS is an oxide semiconductor with high crystallinity and no clear crystal grain boundaries. Therefore, it can be said that the decrease in electron mobility due to grain boundaries is less likely to occur in CAAC-OS.
- a CAAC-OS can be said to be an oxide semiconductor with few impurities and defects (such as oxygen vacancies). Therefore, an oxide semiconductor including CAAC-OS has stable physical properties. Therefore, an oxide semiconductor including CAAC-OS is resistant to heat and has high reliability.
- CAAC-OS is also stable against high temperatures (so-called thermal budget) in the manufacturing process. Therefore, the use of the CAAC-OS for the OS transistor makes it possible to increase the degree of freedom in the manufacturing process.
- nc-OS has periodic atomic arrangement in a minute region (eg, a region of 1 nm to 10 nm, particularly a region of 1 nm to 3 nm).
- the nc-OS has minute crystals.
- the size of the minute crystal is, for example, 1 nm or more and 10 nm or less, particularly 1 nm or more and 3 nm or less, the minute crystal is also called a nanocrystal.
- nc-OS does not show regularity in crystal orientation between different nanocrystals. Therefore, no orientation is observed in the entire film.
- an nc-OS may be indistinguishable from an a-like OS or an amorphous oxide semiconductor depending on the analysis method.
- an nc-OS film is subjected to structural analysis using an XRD apparatus, out-of-plane XRD measurement using ⁇ /2 ⁇ scanning does not detect a peak indicating crystallinity.
- an nc-OS film is subjected to electron beam diffraction (also referred to as selected area electron beam diffraction) using an electron beam with a probe diameter larger than that of nanocrystals (for example, 50 nm or more), a diffraction pattern such as a halo pattern is obtained. is observed.
- an nc-OS film is subjected to electron diffraction (also referred to as nanobeam electron diffraction) using an electron beam with a probe diameter close to or smaller than the size of a nanocrystal (for example, 1 nm or more and 30 nm or less)
- an electron beam diffraction pattern is obtained in which a plurality of spots are observed within a ring-shaped area centered on the direct spot.
- An a-like OS is an oxide semiconductor having a structure between an nc-OS and an amorphous oxide semiconductor.
- An a-like OS has void or low density regions. That is, the a-like OS has lower crystallinity than the nc-OS and CAAC-OS. In addition, the a-like OS has a higher hydrogen concentration in the film than the nc-OS and the CAAC-OS.
- CAC-OS relates to material composition.
- CAC-OS is, for example, one structure of a material in which elements constituting a metal oxide are unevenly distributed with a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or in the vicinity thereof.
- the metal oxide one or more metal elements are unevenly distributed, and the region having the metal element has a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or a size in the vicinity thereof.
- the mixed state is also called mosaic or patch.
- CAC-OS is a structure in which the material is separated into a first region and a second region to form a mosaic shape, and the first region is distributed in the film (hereinafter, also referred to as a cloud shape). ). That is, CAC-OS is a composite metal oxide in which the first region and the second region are mixed.
- the atomic ratios of In, Ga, and Zn to the metal elements constituting the CAC-OS in the In--Ga--Zn oxide are denoted by [In], [Ga], and [Zn], respectively.
- the first region is a region where [In] is larger than [In] in the composition of the CAC-OS film.
- the second region is a region where [Ga] is greater than [Ga] in the composition of the CAC-OS film.
- the first region is a region in which [In] is larger than [In] in the second region and [Ga] is smaller than [Ga] in the second region.
- the second region is a region in which [Ga] is larger than [Ga] in the first region and [In] is smaller than [In] in the first region.
- the first region is a region whose main component is indium oxide, indium zinc oxide, or the like.
- the second region is a region containing gallium oxide, gallium zinc oxide, or the like as a main component. That is, the first region can be rephrased as a region containing In as a main component. Also, the second region can be rephrased as a region containing Ga as a main component.
- a clear boundary between the first region and the second region may not be observed.
- CAC-OS in In--Ga--Zn oxide means a region containing Ga as a main component and a region containing In as a main component in a material structure containing In, Ga, Zn, and O. , and , are mosaic-like, and refer to a configuration in which these regions are randomly present. Therefore, CAC-OS is presumed to have a structure in which metal elements are unevenly distributed.
- the CAC-OS can be formed, for example, by sputtering under the condition that the substrate is not heated.
- a sputtering method one or more selected from an inert gas (typically argon), an oxygen gas, and a nitrogen gas may be used as a deposition gas. good.
- an inert gas typically argon
- oxygen gas typically argon
- a nitrogen gas may be used as a deposition gas. good.
- the lower the flow rate ratio of the oxygen gas to the total flow rate of the film formation gas during film formation, the better. is preferably 0% or more and 10% or less.
- a region containing In as the main component (first 1 region) and a region containing Ga as a main component (second region) are unevenly distributed and can be confirmed to have a mixed structure.
- the first region is a region with higher conductivity than the second region. That is, when carriers flow through the first region, conductivity as a metal oxide is developed. Therefore, by distributing the first region in the form of a cloud in the metal oxide, a high field effect mobility ( ⁇ ) can be realized.
- the second region is a region with higher insulation than the first region.
- the leakage current can be suppressed by distributing the second region in the metal oxide.
- CAC-OS when used for a transistor, the conductivity caused by the first region and the insulation caused by the second region act in a complementary manner to provide a switching function (turning ON/OFF). functions) can be given to the CAC-OS.
- a part of the material has a conductive function
- a part of the material has an insulating function
- the whole material has a semiconductor function.
- CAC-OS A transistor using CAC-OS is highly reliable. Therefore, CAC-OS is most suitable for various semiconductor devices including display devices.
- Oxide semiconductors have a variety of structures, each with different characteristics.
- An oxide semiconductor of one embodiment of the present invention includes two or more of an amorphous oxide semiconductor, a polycrystalline oxide semiconductor, an a-like OS, a CAC-OS, an nc-OS, and a CAAC-OS. may
- an oxide semiconductor with low carrier concentration is preferably used for a transistor.
- the carrier concentration of the oxide semiconductor is 1 ⁇ 10 17 cm ⁇ 3 or less, preferably 1 ⁇ 10 15 cm ⁇ 3 or less, more preferably 1 ⁇ 10 13 cm ⁇ 3 or less, more preferably 1 ⁇ 10 11 cm ⁇ 3 or less. 3 or less, more preferably less than 1 ⁇ 10 10 cm ⁇ 3 and 1 ⁇ 10 ⁇ 9 cm ⁇ 3 or more.
- the impurity concentration in the oxide semiconductor film may be lowered to lower the defect level density.
- a low impurity concentration and a low defect level density are referred to as high-purity intrinsic or substantially high-purity intrinsic.
- an oxide semiconductor with a low carrier concentration is sometimes referred to as a highly purified intrinsic or substantially highly purified intrinsic oxide semiconductor.
- a high-purity intrinsic or substantially high-purity intrinsic oxide semiconductor film has a low defect level density, so the trap level density may also be low.
- the charge trapped in the trap level of the oxide semiconductor takes a long time to disappear and may behave as if it were a fixed charge. Therefore, a transistor whose channel formation region is formed in an oxide semiconductor with a high trap level density might have unstable electrical characteristics.
- Impurities include hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel, silicon, and the like.
- the concentration of silicon or carbon in the oxide semiconductor and the concentration of silicon or carbon in the vicinity of the interface with the oxide semiconductor are 2 ⁇ 10 18 atoms/cm 3 or less, preferably 2 ⁇ 10 17 atoms/cm 3 or less.
- the concentration of alkali metal or alkaline earth metal in the oxide semiconductor obtained by SIMS is set to 1 ⁇ 10 18 atoms/cm 3 or less, preferably 2 ⁇ 10 16 atoms/cm 3 or less.
- the nitrogen concentration in the oxide semiconductor obtained by SIMS is less than 5 ⁇ 10 19 atoms/cm 3 , preferably 5 ⁇ 10 18 atoms/cm 3 or less, more preferably 1 ⁇ 10 18 atoms/cm 3 or less. , more preferably 5 ⁇ 10 17 atoms/cm 3 or less.
- Hydrogen contained in an oxide semiconductor reacts with oxygen that bonds to a metal atom to form water, which may cause oxygen vacancies. When hydrogen enters the oxygen vacancies, electrons, which are carriers, may be generated. In addition, part of hydrogen may bond with oxygen that bonds with a metal atom to generate an electron, which is a carrier. Therefore, a transistor including an oxide semiconductor containing hydrogen is likely to have normally-on characteristics. Therefore, hydrogen in the oxide semiconductor is preferably reduced as much as possible.
- the hydrogen concentration obtained by SIMS is less than 1 ⁇ 10 20 atoms/cm 3 , preferably less than 1 ⁇ 10 19 atoms/cm 3 , more preferably less than 5 ⁇ 10 18 atoms/cm. Less than 3 , more preferably less than 1 ⁇ 10 18 atoms/cm 3 .
- An electronic device of this embodiment includes the display device of one embodiment of the present invention in a display portion.
- the display device of one embodiment of the present invention can easily have high definition and high resolution. Therefore, it can be used for display portions of various electronic devices.
- Electronic devices include, for example, televisions, desktop or notebook personal computers, monitors for computers, digital signage, electronic devices with relatively large screens such as large game machines such as pachinko machines, and digital cameras. , digital video cameras, digital photo frames, mobile phones, portable game machines, personal digital assistants, sound reproduction devices, and the like.
- the display device of one embodiment of the present invention can have high definition, it can be suitably used for an electronic device having a relatively small display portion.
- electronic devices include wristwatch-type and bracelet-type information terminals (wearable devices), VR devices such as head-mounted displays, glasses-type AR devices, and MR devices. wearable devices that can be attached to
- a display device of one embodiment of the present invention includes HD (1280 ⁇ 720 pixels), FHD (1920 ⁇ 1080 pixels), WQHD (2560 ⁇ 1440 pixels), WQXGA (2560 ⁇ 1600 pixels), 4K (2560 ⁇ 1600 pixels), 3840 ⁇ 2160) and 8K (7680 ⁇ 4320 pixels).
- the resolution it is preferable to set the resolution to 4K, 8K, or higher.
- the pixel density (definition) of the display device of one embodiment of the present invention is preferably 100 ppi or more, preferably 300 ppi or more, more preferably 500 ppi or more, more preferably 1000 ppi or more, more preferably 2000 ppi or more, and 3000 ppi or more.
- the display device can support various screen ratios such as 1:1 (square), 4:3, 16:9, 16:10.
- the electronic device of this embodiment includes sensors (force, displacement, position, velocity, acceleration, angular velocity, number of revolutions, distance, light, liquid, magnetism, temperature, chemical substance, sound, time, hardness, electric field, current, voltage , power, radiation, flow, humidity, gradient, vibration, odor or infrared).
- the electronic device of this embodiment can have various functions. For example, functions to display various information (still images, moving images, text images, etc.) on the display, touch panel functions, functions to display calendars, dates or times, functions to execute various software (programs), wireless communication function, a function of reading a program or data recorded on a recording medium, and the like.
- An electronic device 6500 shown in FIG. 38A is a mobile information terminal that can be used as a smartphone.
- the electronic device 6500 has a housing 6501, a display unit 6502, a power button 6503, a button 6504, a speaker 6505, a microphone 6506, a camera 6507, a light source 6508, and the like.
- a display portion 6502 has a touch panel function.
- the display device of one embodiment of the present invention can be applied to the display portion 6502 .
- FIG. 38B is a schematic cross-sectional view including the end of the housing 6501 on the microphone 6506 side.
- a light-transmitting protective member 6510 is provided on the display surface side of the housing 6501, and a display panel 6511, an optical member 6512, a touch sensor panel 6513, and a printer are placed in a space surrounded by the housing 6501 and the protective member 6510.
- a substrate 6517, a battery 6518, and the like are arranged.
- a display panel 6511, an optical member 6512, and a touch sensor panel 6513 are fixed to the protective member 6510 with an adhesive layer (not shown).
- a portion of the display panel 6511 is folded back in a region outside the display portion 6502, and the FPC 6515 is connected to the folded portion.
- An IC6516 is mounted on the FPC6515.
- the FPC 6515 is connected to terminals provided on the printed circuit board 6517 .
- the flexible display of one embodiment of the present invention can be applied to the display panel 6511 . Therefore, an extremely lightweight electronic device can be realized. In addition, since the display panel 6511 is extremely thin, the thickness of the electronic device can be reduced and the large-capacity battery 6518 can be mounted. In addition, by folding back part of the display panel 6511 and arranging a connection portion with the FPC 6515 on the back side of the pixel portion, an electronic device with a narrow frame can be realized.
- FIG. 39A An example of a television device is shown in FIG. 39A.
- a television set 7100 has a display portion 7000 incorporated in a housing 7101 .
- a configuration in which a housing 7101 is supported by a stand 7103 is shown.
- the display device of one embodiment of the present invention can be applied to the display portion 7000 .
- the operation of the television apparatus 7100 shown in FIG. 39A can be performed using operation switches provided on the housing 7101 and a separate remote control operation device 7111 .
- the display portion 7000 may be provided with a touch sensor, and the television device 7100 may be operated by touching the display portion 7000 with a finger or the like.
- the remote controller 7111 may have a display section for displaying information output from the remote controller 7111 .
- a channel and a volume can be operated with operation keys or a touch panel provided in the remote controller 7111 , and an image displayed on the display portion 7000 can be operated.
- the television device 7100 is configured to include a receiver, a modem, and the like.
- the receiver can receive general television broadcasts. Also, by connecting to a wired or wireless communication network via a modem, one-way (from the sender to the receiver) or two-way (between the sender and the receiver, or between the receivers, etc.) information communication is performed. is also possible.
- FIG. 39B shows an example of a notebook personal computer.
- a notebook personal computer 7200 has a housing 7211, a keyboard 7212, a pointing device 7213, an external connection port 7214, and the like.
- the display portion 7000 is incorporated in the housing 7211 .
- the display device of one embodiment of the present invention can be applied to the display portion 7000 .
- FIGS. 39C and 39D An example of digital signage is shown in FIGS. 39C and 39D.
- a digital signage 7300 shown in FIG. 39C has a housing 7301, a display unit 7000, speakers 7303, and the like. Furthermore, it can have an LED lamp, an operation key (including a power switch or an operation switch), connection terminals, various sensors, a microphone, and the like.
- FIG. 39D shows a digital signage 7400 attached to a cylindrical pillar 7401.
- the digital signage 7400 has a display section 7000 provided along the curved surface of the pillar 7401.
- FIG. 39D shows a digital signage 7400 attached to a cylindrical pillar 7401.
- the digital signage 7400 has a display section 7000 provided along the curved surface of the pillar 7401.
- the display device of one embodiment of the present invention can be applied to the display portion 7000 in FIGS. 39C and 39D.
- the wider the display unit 7000 the more information can be provided at once.
- the wider the display unit 7000 the more conspicuous it is, and the more effective the advertisement can be, for example.
- a touch panel By applying a touch panel to the display unit 7000, not only can images or moving images be displayed on the display unit 7000, but also the user can intuitively operate the display unit 7000, which is preferable. Further, when used for providing information such as route information or traffic information, usability can be enhanced by intuitive operation.
- the digital signage 7300 or digital signage 7400 is preferably capable of cooperating with an information terminal 7311 or information terminal 7411 such as a smartphone possessed by the user through wireless communication.
- advertisement information displayed on the display unit 7000 can be displayed on the screen of the information terminal 7311 or the information terminal 7411 .
- display on the display portion 7000 can be switched.
- the digital signage 7300 or 7400 can execute a game using the screen of the information terminal 7311 or 7411 as an operating means (controller). This allows an unspecified number of users to simultaneously participate in and enjoy the game.
- the electronic device shown in FIGS. 40A to 40F includes a housing 9000, a display unit 9001, a speaker 9003, operation keys 9005 (including a power switch or an operation switch), connection terminals 9006, sensors 9007 (force, displacement, position, speed). , acceleration, angular velocity, number of rotations, distance, light, liquid, magnetism, temperature, chemical substances, sound, time, hardness, electric field, current, voltage, power, radiation, flow rate, humidity, gradient, vibration, smell, or infrared rays function), a microphone 9008, and the like.
- the electronic devices shown in FIGS. 40A to 40F have various functions. For example, a function to display various information (still images, moving images, text images, etc.) on the display unit, a touch panel function, a calendar, a function to display the date or time, a function to control processing by various software (programs), It can have a wireless communication function, a function of reading and processing programs or data recorded on a recording medium, and the like. Note that the functions of the electronic device are not limited to these, and can have various functions.
- the electronic device may have a plurality of display units.
- the electronic device is equipped with a camera, etc., and has the function of capturing still images or moving images and storing them in a recording medium (external or built into the camera), or the function of displaying the captured image on the display unit, etc. good.
- FIGS. 40A to 40F Details of the electronic devices shown in FIGS. 40A to 40F will be described below.
- FIG. 40A is a perspective view showing a mobile information terminal 9101.
- the mobile information terminal 9101 can be used as a smart phone, for example.
- the portable information terminal 9101 may be provided with a speaker 9003, a connection terminal 9006, a sensor 9007, and the like.
- the mobile information terminal 9101 can display text and image information on its multiple surfaces.
- FIG. 40A shows an example in which three icons 9050 are displayed.
- Information 9051 indicated by a dashed rectangle can also be displayed on another surface of the display portion 9001 . Examples of the information 9051 include notification of incoming e-mail, SNS, phone call, title of e-mail or SNS, sender name, date and time, remaining battery power, radio wave intensity, and the like.
- an icon 9050 or the like may be displayed at the position where the information 9051 is displayed.
- FIG. 40B is a perspective view showing the mobile information terminal 9102.
- the portable information terminal 9102 has a function of displaying information on three or more sides of the display portion 9001 .
- information 9052, information 9053, and information 9054 are displayed on different surfaces.
- the user can confirm the information 9053 displayed at a position where the mobile information terminal 9102 can be viewed from above the mobile information terminal 9102 while the mobile information terminal 9102 is stored in the chest pocket of the clothes.
- the user can check the display without taking out the portable information terminal 9102 from the pocket, and can determine, for example, whether to receive a call.
- FIG. 40C is a perspective view showing a wristwatch-type mobile information terminal 9200.
- the mobile information terminal 9200 can be used as a smart watch (registered trademark), for example.
- the display portion 9001 has a curved display surface, and display can be performed along the curved display surface.
- the mobile information terminal 9200 can also make hands-free calls by mutual communication with a headset capable of wireless communication, for example.
- the portable information terminal 9200 can transmit data to and from another information terminal through the connection terminal 9006, and can be charged. Note that the charging operation may be performed by wireless power supply.
- FIG. 40D to 40F are perspective views showing a foldable personal digital assistant 9201.
- FIG. 40D is a state in which the portable information terminal 9201 is unfolded
- FIG. 40F is a state in which it is folded
- FIG. 40E is a perspective view in the middle of changing from one of FIGS. 40D and 40F to the other.
- the portable information terminal 9201 has excellent portability in the folded state, and has excellent display visibility due to a seamless wide display area in the unfolded state.
- a display portion 9001 included in the portable information terminal 9201 is supported by three housings 9000 connected by hinges 9055 .
- the display portion 9001 can be bent with a curvature radius of 0.1 mm or more and 150 mm or less.
- a display device and an electronic device that are one aspect of the present invention can be incorporated into the inner or outer wall of a house or building, or the interior or exterior of a vehicle.
- FIG. 41 An example in which the display device of one embodiment of the present invention is mounted on a vehicle is shown in FIG.
- the vehicle shown in FIG. 41 has a dashboard 5002 mounted with a display device 5000a, a display device 5000b, and a display device 5000c.
- a display device 5000d is mounted on the ceiling 5004 on the driver's seat side.
- FIG. 41 shows an example in which the display device 5000d is mounted on a right-hand drive vehicle, it is not particularly limited, and can also be mounted on a left-hand drive vehicle. In this case, the left and right arrangement of the configuration shown in FIG. 41 is changed.
- FIG. 41 shows a steering wheel 5006, a windshield 5008, etc. arranged around the driver's seat and passenger's seat.
- any one or more of the display devices 5000a to 5000d preferably have a near touch sensor function.
- the user can operate the display device without staring at the display device.
- the driver can operate the display device without taking his or her line of sight from the front, which can improve safety while driving and stopping the vehicle.
- the diagonal length of the display portions of the display devices 5000a to 5000d is preferably 5 inches or more, preferably 10 inches or more.
- a display device having a display portion with a diagonal length of about 13 inches can be preferably used.
- the display devices 5000a to 5000d may have flexibility. Having flexibility makes it possible to incorporate along a curved surface, even if the object to be incorporated is a curved surface.
- the display device can be provided along a curved surface such as the dashboard 5002 or the ceiling 5004 .
- a plurality of cameras 5005 may be provided outside the vehicle. By providing the camera 5005, it is possible to photograph the surroundings of the vehicle, for example, the situation behind the vehicle.
- FIG. 41 shows an example in which a camera 5005 is installed instead of the side mirror, both the side mirror and the camera may be installed.
- a CCD camera, a CMOS camera, or the like can be used as the camera 5005 .
- an infrared camera may be used in combination. Since the output level of the infrared camera increases as the temperature of the subject increases, it is possible to detect or extract a living body such as a person or an animal.
- An image captured by the camera 5005 can be output to one or more of the display devices 5000a to 5000d.
- the display devices 5000a to 5000d are mainly used to assist driving of the vehicle.
- the camera 5005 captures the rear side situation with a wide angle of view, and displays the image on one or more of the display devices 5000a to 5000d, so that the driver's blind spot area can be visually recognized, and an accident can occur. can be prevented from occurring.
- a distance image sensor may be provided on the roof of a car or the like, and an image obtained by the distance image sensor may be displayed on any one or more of the display devices 5000a to 5000d.
- An image sensor, a lidar (LIDAR: Light Detection and Ranging), or the like can be used as the distance image sensor.
- Any one or more of the display devices 5000a to 5000d may have a function of displaying map information, traffic information, television images, DVD images, and the like.
- a display panel having an imaging function is preferably applied to at least one of the display devices 5000a to 5000d.
- the vehicle can perform biometric authentication such as fingerprint authentication or palm print authentication.
- biometric authentication such as fingerprint authentication or palm print authentication.
- the vehicle may have the ability to personalize the environment if the driver is authenticated by biometrics. For example, seat position adjustment, steering wheel position adjustment, camera 5005 orientation adjustment, brightness setting, air conditioner setting, wiper speed (frequency) setting, audio volume setting, audio playlist reading, etc. preferably performed after authentication.
- the car When the driver is authenticated by biometric authentication, the car can be put into a drivable state, for example, the engine is running, which is preferable because it eliminates the need for a key that was conventionally required.
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Abstract
Description
図2A及び図2Bは、画素回路の一例を示す図である。
図3は、画素回路の一例を示す図である。
図4Aは、読み出し回路の一例を示すブロック図である。図4Bは、読み出し回路の回路図である。
図5は、表示装置の表示部の一例を示す図である。
図6は、表示装置の表示部の一例を示す図である。
図7は、表示装置の一例を示す図である。
図8A及び図8Bは、表示装置の動作方法の一例を説明する図である。
図9は、表示装置の動作方法の一例を説明する図である。
図10は、表示装置の表示部の一例を示す図である。
図11は、表示装置の表示部の一例を示す図である。
図12A及び図12Bは、表示装置の表示部の一例を示す図である。
図13A及び図13Bは、表示装置の表示部の一例を示す図である。
図14Aは、表示装置の画素の一例を示す図である。図14B及び図14Cは、電子機器の一例を示す断面図である。
図15A及び図15Bは、電子機器の一例を示す断面図である。
図16A乃至図16Cは、表示装置の画素の一例を示す図である。図16Dは、電子機器の一例を示す断面図である。
図17は、表示装置のレイアウトの一例を示す図である。
図18は、表示装置のレイアウトの一例を示す図である。
図19は、表示装置のレイアウトの一例を示す図である。
図20は、表示装置のレイアウトの一例を示す図である。
図21A及び図21Bは、表示装置の画素の一例を示す図である。図21C及び図21Dは、電子機器の一例を示す断面図である。
図22は、表示装置のレイアウトの一例を示す図である。
図23A乃至図23Cは、表示装置の一例を示す図である。
図24A乃至図24Cは、電子機器の一例を示す図である。
図25Aは、表示装置の一例を示す上面図である。図25Bは、表示装置の一例を示す断面図である。
図26A乃至図26Dは、表示装置の作製方法の一例を示す図である。
図27A乃至図27Cは、表示装置の作製方法の一例を示す図である。
図28A乃至図28Cは、表示装置の作製方法の一例を示す図である。
図29A乃至図29Cは、表示装置の作製方法の一例を示す図である。
図30Aは、表示装置の一例を示す上面図である。図30Bは、表示装置の一例を示す断面図である。
図31は、表示装置の一例を示す斜視図である。
図32Aは、表示装置の一例を示す断面図である。図32B及び図32Cは、トランジスタの一例を示す断面図である。
図33A乃至図33Dは、発光デバイスの構成例を示す図である。
図34A及び図34Bは、表示装置の一例を示す断面図である。
図35A及び図35Bは、表示装置の一例を示す断面図である。
図36A及び図36Bは、表示装置の一例を示す断面図である。
図37A乃至図37Cは、表示装置の一例を示す断面図である。
図38A及び図38Bは、電子機器の一例を示す図である。
図39A乃至図39Dは、電子機器の一例を示す図である。
図40A乃至図40Fは、電子機器の一例を示す図である。
図41は、車両の一例を示す図である。
本実施の形態では、本発明の一態様の半導体装置として、表示装置について説明する。
本発明の一態様である表示装置のブロック図を、図1Aに示す。図1Aに示す表示装置10は、表示部11、駆動回路部12、駆動回路部13、駆動回路部14、及び回路部15を有する。表示部11は、マトリクス状に配置された複数の画素30を有する。
画素回路22に適用することができる画素回路の例を、図2Aに示す。
画素回路21R、画素回路21G、及び画素回路21Bに適用することができる画素回路の例を、図2Bに示す。図2Bに示す画素回路21は、トランジスタM1、トランジスタM2、トランジスタM3、トランジスタM4、容量C1、容量C2、及び発光デバイスELを有する。
画素回路22、画素回路21R、画素回路21G、及び画素回路21Bを有する画素30の回路図の一例を、図3に示す。
読み出し回路として用いることができる回路の例を、図4Aに示す。図4Aに示す回路50は、図1Aに示した回路部15に適用することができる。
表示部11の構成の一例を、図5及び図6に示す。表示部11は、画素30がM行N列(M、Nはそれぞれ独立に2以上の整数)のマトリクス状に配列した構成を有する。図5及び図6は、i行j列目(i,jはそれぞれ独立に1以上の整数)から、i+1行j+1列目までの4つの画素30を示している。
画素回路22の駆動方法の一例について、図7に示す構成を用いて説明する。ここでは、回路50として図4Bに示した構成を用いた例を挙げている。図7は、画素回路22[i,j]、画素回路22[i+1,j]、及びCDS回路として機能する回路52[j]を示している。
時刻T11以前において、配線TX、配線SW、配線SE、及び配線RSにはローレベル電位が与えられる。
時刻T11から時刻T12までの期間は、初期化期間(リセット期間ともいう)に相当する。時刻T11において、配線TXと配線RSにそれぞれ、トランジスタを導通状態とする電位(ここではハイレベル電位)が与えられる。配線SWと配線SEにそれぞれ、トランジスタを非導通状態とする電位(ここではローレベル電位)が与えられる。これにより、トランジスタM11及びトランジスタM12が導通状態となる。
時刻T12から時刻T13までの期間は、露光期間(撮像データの取得を行う期間)に相当する。時刻T12において、配線TX及び配線RSに、ローレベル電位が与えられる。これにより、トランジスタM11及びトランジスタM12が非導通状態となる。
時刻T13から時刻T14までの期間は、転送期間に相当する。時刻T13において、配線TXにハイレベル電位が与えられる。これにより、トランジスタM11が導通状態となり、受光デバイスPD1に蓄積された電荷が、トランジスタM11を介して容量C11の一方の電極に転送される。これにより、容量C11の一方の電極が接続されるノードの電位は、受光デバイスPD1に蓄積された電荷量に応じて上昇する。その結果、トランジスタM13のゲートには、受光デバイスPD1の露光量に応じた電位が与えられた状態となる。
時刻T14において、配線TXにローレベル電位が与えられる。これにより、トランジスタM11が非導通状態となり、トランジスタM13のゲートが接続されるノードがフローティング状態となる。受光デバイスPD1の露光は常に生じているため、期間T13−T14における転送動作が完了した後に、トランジスタM11を非導通状態とすることで、トランジスタM13のゲートが接続されるノードの電位が変化することを防ぐことができる。
時刻T21以前において、配線TX、配線SW、配線SE、及び配線RSにはローレベル電位が与えられる。
時刻T21から時刻T22までの期間は、初期化期間(リセット期間ともいう)に相当する。時刻T21において、配線SWと配線RSにそれぞれ、ハイレベル電位が与えられる。配線TXと配線SEにそれぞれ、ローレベル電位が与えられる。これにより、トランジスタM15及びトランジスタM12が導通状態となる。
時刻T22から時刻T23までの期間は、露光期間に相当する。時刻T22において、配線SW及び配線RSに、ローレベル電位が与えられる。これにより、トランジスタM15及びトランジスタM12が非導通状態となる。
時刻T23から時刻T24までの期間は、転送期間に相当する。時刻T23において、配線SWにハイレベル電位が与えられる。これにより、トランジスタM15が導通状態となり、受光デバイスPD2に蓄積された電荷が、トランジスタM15を介して容量C11の一方の電極に転送される。これにより、容量C11の一方の電極が接続されるノードの電位は、受光デバイスPD2に蓄積された電荷量に応じて上昇する。その結果、トランジスタM13のゲートには、受光デバイスPD2の露光量に応じた電位が与えられた状態となる。
時刻T24において、配線SWにローレベル電位が与えられる。これにより、トランジスタM15が非導通状態となり、トランジスタM13のゲートが接続されるノードがフローティング状態となる。受光デバイスPD2の露光は常に生じているため、期間T23−T24における転送動作が完了した後に、トランジスタM15を非導通状態とすることで、トランジスタM13のゲートが接続されるノードの電位が変化することを防ぐことができる。
時刻T31以前において、配線TX、配線SW、配線SE、配線RS、及び配線SCLにはローレベル電位が与えられる。
時刻T31から時刻T34までの期間は、相関二重サンプリング(CDS)処理期間に相当する。
時刻T34から時刻T41までの期間は、出力期間に相当する。
時刻T41から時刻T44までの期間は、相関二重サンプリング(CDS)処理期間に相当する。
時刻T44から時刻T51までの期間は、出力期間に相当する。
時刻T51において、配線SE[i+1]にローレベル電位が与えられる。これにより、トランジスタM14が非導通状態となる。これにより、i+1行目の画素回路22のデータの読み出しが完了する。時刻T51以降は、次の行以降のデータの読み出し動作が順次行われる。
図5及び図6に示した表示部11と異なる例を、図10及び図11に示す。
本実施の形態では、本発明の一態様の表示装置を有する電子機器について、図を用いて説明する。
本実施の形態では、本発明の一態様の表示装置とその作製方法について図25乃至図29を用いて説明する。
図25A及び図25Bに、本発明の一態様の表示装置を示す。
次に、図26乃至図29を用いて表示装置の作製方法例を説明する。図26A乃至図26Dには、図25Aにおける一点鎖線X1−X2間の断面図と、X3−X4間の断面図と、Y1−Y2間の断面図と、を並べて示す。図27乃至図29についても、図26と同様である。
図25A及び図25Bに示した表示装置100Fと異なる例を、図30A及び図30Bに示す。
本実施の形態では、本発明の一態様の表示装置について図31及び図32を用いて説明する。
図31に、表示装置100Hの斜視図を示し、図32Aに、表示装置100Hの断面図を示す。
本実施の形態では、本発明の一態様の表示装置に用いることができる発光デバイスについて説明する。
図34乃至図37を用いて、発光デバイスの構成例を説明する。
本実施の形態では、上記の実施の形態で説明したOSトランジスタに用いることができる金属酸化物(酸化物半導体ともいう)について説明する。
酸化物半導体の結晶構造として、アモルファス(completely amorphousを含む)、CAAC(c−axis−aligned crystalline)、nc(nanocrystalline)、CAC(cloud−aligned composite)、単結晶(single crystal)、及び多結晶(poly crystal)等が挙げられる。
なお、酸化物半導体は、構造に着目した場合、上記とは異なる分類となる場合がある。例えば、酸化物半導体は、単結晶酸化物半導体と、それ以外の非単結晶酸化物半導体と、に分けられる。非単結晶酸化物半導体は、例えば、上述のCAAC−OS、及びnc−OSがある。また、非単結晶酸化物半導体には、多結晶酸化物半導体、擬似非晶質酸化物半導体(a−like OS:amorphous−like oxide semiconductor)、非晶質酸化物半導体、などが含まれる。
CAAC−OSは、複数の結晶領域を有し、当該複数の結晶領域はc軸が特定の方向に配向している酸化物半導体である。なお、特定の方向とは、CAAC−OS膜の厚さ方向、CAAC−OS膜の被形成面の法線方向、またはCAAC−OS膜の表面の法線方向である。また、結晶領域とは、原子配列に周期性を有する領域である。なお、原子配列を格子配列とみなすと、結晶領域とは、格子配列の揃った領域でもある。さらに、CAAC−OSは、a−b面方向において複数の結晶領域が連結する領域を有し、当該領域は歪みを有する場合がある。なお、歪みとは、複数の結晶領域が連結する領域において、格子配列の揃った領域と、別の格子配列の揃った領域と、の間で格子配列の向きが変化している箇所を指す。つまり、CAAC−OSは、c軸配向し、a−b面方向には明らかな配向をしていない酸化物半導体である。
nc−OSは、微小な領域(例えば、1nm以上10nm以下の領域、特に1nm以上3nm以下の領域)において原子配列に周期性を有する。別言すると、nc−OSは、微小な結晶を有する。なお、当該微小な結晶の大きさは、例えば、1nm以上10nm以下、特に1nm以上3nm以下であることから、当該微小な結晶をナノ結晶ともいう。また、nc−OSは、異なるナノ結晶間で結晶方位に規則性が見られない。そのため、膜全体で配向性が見られない。従って、nc−OSは、分析方法によっては、a−like OSまたは非晶質酸化物半導体と区別が付かない場合がある。例えば、nc−OS膜に対し、XRD装置を用いて構造解析を行うと、θ/2θスキャンを用いたOut−of−plane XRD測定では、結晶性を示すピークが検出されない。また、nc−OS膜に対し、ナノ結晶よりも大きいプローブ径(例えば50nm以上)の電子線を用いる電子線回折(制限視野電子線回折ともいう。)を行うと、ハローパターンのような回折パターンが観測される。一方、nc−OS膜に対し、ナノ結晶の大きさと近いかナノ結晶より小さいプローブ径(例えば1nm以上30nm以下)の電子線を用いる電子線回折(ナノビーム電子線回折ともいう。)を行うと、ダイレクトスポットを中心とするリング状の領域内に複数のスポットが観測される電子線回折パターンが取得される場合がある。
a−like OSは、nc−OSと非晶質酸化物半導体との間の構造を有する酸化物半導体である。a−like OSは、鬆または低密度領域を有する。即ち、a−like OSは、nc−OS及びCAAC−OSと比べて、結晶性が低い。また、a−like OSは、nc−OS及びCAAC−OSと比べて、膜中の水素濃度が高い。
次に、上述のCAC−OSの詳細について、説明を行う。なお、CAC−OSは材料構成に関する。
CAC−OSとは、例えば、金属酸化物を構成する元素が、0.5nm以上10nm以下、好ましくは、1nm以上3nm以下、またはその近傍のサイズで偏在した材料の一構成である。なお、以下では、金属酸化物において、一つまたは複数の金属元素が偏在し、該金属元素を有する領域が、0.5nm以上10nm以下、好ましくは、1nm以上3nm以下、またはその近傍のサイズで混合した状態をモザイク状、またはパッチ状ともいう。
続いて、上記酸化物半導体をトランジスタに用いる場合について説明する。
ここで、酸化物半導体中における各不純物の影響について説明する。
本実施の形態では、本発明の一態様の電子機器について、図38乃至図40を用いて説明する。
Claims (7)
- 複数の画素を有し、
前記画素は、第1の画素回路を有し、
前記第1の画素回路は、第1の受光デバイスと、第2の受光デバイスと、第1のトランジスタと、第2のトランジスタと、第3のトランジスタと、第4のトランジスタと、第5のトランジスタと、容量と、第1の配線と、を有し、
前記第1の受光デバイスの一方の電極は、前記第1の配線と電気的に接続され、
前記第1の受光デバイスの他方の電極は、前記第1のトランジスタのソースまたはドレインの一方と電気的に接続され、
前記第2の受光デバイスの一方の電極は、前記第1の配線と電気的に接続され、
前記第2の受光デバイスの他方の電極は、前記第2のトランジスタのソースまたはドレインの一方と電気的に接続され、
前記第2のトランジスタのソースまたはドレインの他方は、前記第1のトランジスタのソースまたはドレインの他方と電気的に接続され、
前記第1のトランジスタのソースまたはドレインの他方は、前記容量の一方の電極と電気的に接続され、
前記第1のトランジスタのソースまたはドレインの他方は、前記第3のトランジスタのソースまたはドレインの一方と電気的に接続され、
前記第1のトランジスタのソースまたはドレインの他方は、前記第4のトランジスタのゲートと電気的に接続され、
前記第4のトランジスタのソースまたはドレインの一方は、前記第5のトランジスタのソースまたはドレインの一方と電気的に接続される半導体装置。 - 請求項1において、
前記第1の受光デバイスは、可視光を検出する機能を有し、
前記第2の受光デバイスは、赤外光を検出する機能を有する半導体装置。 - 請求項1または請求項2において、
第2の配線を有し
前記第2の配線は、前記第3のトランジスタのソースまたはドレインの他方と電気的に接続され
前記第2の配線の電位は、前記第1の配線の電位より低い半導体装置。 - 請求項1または請求項2において、
第2の配線を有し
前記第2の配線は、前記第3のトランジスタのソースまたはドレインの他方と電気的に接続され
前記第2の配線の電位は、前記第1の配線の電位より高い半導体装置。 - 請求項1乃至請求項4のいずれか一において、
前記画素は、第2の画素回路を有し、
前記第2の画素回路は、第1の発光デバイスを有し、
前記第1の発光デバイスは、可視光を射出する機能を有し、
前記第1の発光デバイスの一方の電極は、前記第1の配線と電気的に接続される半導体装置。 - 請求項1乃至請求項4のいずれか一において、
前記画素は、第3の画素回路を有し、
前記第3の画素回路は、第2の発光デバイスを有し、
前記第2の発光デバイスは、赤外光を射出する機能を有し、
前記第2の発光デバイスの一方の電極は、前記第1の配線と電気的に接続される半導体装置。 - 請求項1乃至請求項5のいずれか一に記載の半導体装置と、第2の発光デバイスと、筐体と、を有し、
前記第2の発光デバイスは、赤外光を射出する機能を有し、
前記第2の発光デバイスは、前記半導体装置を介して、外部に光を射出する機能を有する電子機器。
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