WO2022200915A1 - 電子機器 - Google Patents
電子機器 Download PDFInfo
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- WO2022200915A1 WO2022200915A1 PCT/IB2022/052305 IB2022052305W WO2022200915A1 WO 2022200915 A1 WO2022200915 A1 WO 2022200915A1 IB 2022052305 W IB2022052305 W IB 2022052305W WO 2022200915 A1 WO2022200915 A1 WO 2022200915A1
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- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
- G06F3/042—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by opto-electronic means
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06N—COMPUTING ARRANGEMENTS BASED ON SPECIFIC COMPUTATIONAL MODELS
- G06N3/00—Computing arrangements based on biological models
- G06N3/02—Neural networks
- G06N3/04—Architecture, e.g. interconnection topology
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06N—COMPUTING ARRANGEMENTS BASED ON SPECIFIC COMPUTATIONAL MODELS
- G06N5/00—Computing arrangements using knowledge-based models
- G06N5/04—Inference or reasoning models
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/12—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof structurally associated with, e.g. formed in or on a common substrate with, one or more electric light sources, e.g. electroluminescent light sources, and electrically or optically coupled thereto
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K39/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic radiation-sensitive element covered by group H10K30/00
- H10K39/30—Devices controlled by radiation
- H10K39/32—Organic image sensors
- H10K39/34—Organic image sensors integrated with organic light-emitting diodes [OLED]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/90—Assemblies of multiple devices comprising at least one organic light-emitting element
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
- H10K59/351—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels comprising more than three subpixels, e.g. red-green-blue-white [RGBW]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/40—OLEDs integrated with touch screens
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/60—OLEDs integrated with inorganic light-sensitive elements, e.g. with inorganic solar cells or inorganic photodiodes
- H10K59/65—OLEDs integrated with inorganic image sensors
Definitions
- One embodiment of the present invention relates to a display device, a display module, and an electronic device.
- one embodiment of the present invention is not limited to the above technical field.
- Technical fields of one embodiment of the present invention include semiconductor devices, display devices, light-emitting devices, power storage devices, memory devices, electronic devices, lighting devices, input devices (e.g., touch sensors), and input/output devices (e.g., touch panels). ), their driving methods, or their manufacturing methods.
- information terminal devices such as mobile phones such as smart phones, tablet information terminals, and notebook PCs (personal computers) have become widespread.
- Such information terminal equipment often contains personal information and the like, and various authentication techniques have been developed to prevent unauthorized use.
- information terminal equipment having various functions such as an image display function, a touch sensor function, and a fingerprint imaging function for authentication.
- Patent Literature 1 discloses an electronic device having a fingerprint sensor in a push button switch section.
- a light-emitting device having a light-emitting device As a display device, for example, a light-emitting device having a light-emitting device (also referred to as a light-emitting element) has been developed.
- a light-emitting device also referred to as an EL device or EL element
- EL the phenomenon of electroluminescence
- EL is a DC constant-voltage power supply that can easily be made thin and light, can respond quickly to an input signal, and It is applied to a display device.
- Information terminal equipment that can be operated without contact is desired from the viewpoint of measures against infectious diseases and hygiene.
- An object of one embodiment of the present invention is to provide an electronic device that can be operated without contact.
- An object of one embodiment of the present invention is to provide a high-definition display device having a photodetection function.
- An object of one embodiment of the present invention is to provide a high-resolution display device having a photodetection function.
- An object of one embodiment of the present invention is to provide a highly reliable display device having a photodetection function.
- One embodiment of the present invention is an electronic device including a display portion, a processing portion, and a storage portion, and the display portion includes a display device including a light-emitting device and a light-receiving device.
- the display unit has a function of displaying an image using a light emitting device and a function of capturing an image using a light receiving device.
- the storage unit has a machine learning model using a neural network.
- the processing unit has a function of inferring position information of an object that is not in contact with the electronic device from image data captured by the display unit using a machine learning model.
- one embodiment of the present invention is an electronic device including a display portion, a processing portion, and a storage portion, and the display portion includes a display device including a first pixel.
- the first pixel has a first light-emitting device, a first light-receiving device, and a second light-receiving device, and the wavelength range of light detected by the first light-receiving device is the light emitted by the first light-emitting device.
- the second light receiving device has the function of detecting infrared light, including the maximum peak wavelength of the spectrum.
- the display unit has a function of displaying an image using the first light emitting device and a function of capturing an image using one or both of the first light receiving device and the second light receiving device.
- the storage unit has a machine learning model using a neural network.
- the processing unit has a function of inferring position information of an object that is not in contact with the electronic device from image data captured by the display unit using a machine learning model.
- one embodiment of the present invention is an electronic device including a display portion, a processing portion, and a storage portion, and the display portion includes a display device including a first pixel.
- the first pixel has a first subpixel, a second subpixel, a third subpixel, a fourth subpixel, and a fifth subpixel.
- the first subpixel has a first light emitting device and has the function of emitting red light.
- the second sub-pixel has a second light emitting device and has the function of emitting green light.
- the third sub-pixel has a third light-emitting device and has the function of emitting blue light.
- the fourth sub-pixel has a first light-receiving device, and the wavelength range of light detected by the first light-receiving device is the first light-emitting device, the second light-emitting device, and the third light-emitting device. It includes the maximum peak wavelength of the emission spectrum of at least one of the devices.
- a fifth sub-pixel has a second light receiving device and has a function of detecting infrared light.
- the display unit has a function of displaying an image using the first to third sub-pixels and a function of capturing an image using one or both of the first light receiving device and the second light receiving device. .
- the storage unit has a machine learning model using a neural network.
- the processing unit has a function of inferring position information of an object that is not in contact with the electronic device from image data captured by the display unit using a machine learning model.
- the area of the light receiving region of the first light receiving device is smaller than the area of the light receiving region of the second light receiving device.
- the display device comprises a second pixel comprising a first light emitting device, a first light receiving device and a sensor device.
- Electronic devices use sensor devices to measure force, displacement, position, velocity, acceleration, angular velocity, number of rotations, distance, magnetism, temperature, chemicals, time, hardness, electric field, current, voltage, power, radiation, flow rate, It preferably has a function of measuring at least one of humidity, gradient, vibration, smell, physical condition, pulse, body temperature, and blood oxygen concentration.
- the display device preferably has a second pixel with a first light-emitting device, a fourth light-emitting device and a first light-receiving device.
- the fourth light emitting device preferably has a function of emitting infrared light.
- the electronic device of one embodiment of the present invention may include, outside the display device, a fourth light-emitting device having a function of emitting infrared light.
- the fourth light emitting device may emit light to the outside of the electronic device through the display device.
- a display device that can be operated without contact can be provided.
- a high-definition display device having a photodetection function can be provided.
- a high-resolution display device having a photodetection function can be provided.
- a highly reliable display device having a photodetection function can be provided.
- FIG. 1A is a diagram illustrating an example of an electronic device
- FIG. 1B is a diagram illustrating an example of processing executed by an electronic device
- 2A to 2G are diagrams showing examples of pixels of a display device
- 3A and 3B are diagrams showing examples of pixels of a display device.
- 3C and 3D are cross-sectional views showing examples of electronic devices.
- 4A and 4B are cross-sectional views showing examples of electronic devices.
- 5A to 5D are diagrams showing examples of pixels of a display device.
- FIG. 5E is a cross-sectional view showing an example of an electronic device
- FIG. 6 is a diagram showing an example of the layout of the display device.
- FIG. 7 is a diagram showing an example of the layout of the display device.
- FIG. 1A is a diagram illustrating an example of an electronic device
- FIG. 1B is a diagram illustrating an example of processing executed by an electronic device
- 2A to 2G are diagrams showing examples of pixels of a display device.
- FIG. 8 is a diagram showing an example of the layout of the display device.
- FIG. 9 is a diagram showing an example of the layout of the display device.
- FIG. 10 is a diagram showing an example of a pixel circuit.
- FIG. 11A is a top view showing an example of a display device.
- FIG. 11B is a cross-sectional view showing an example of a display device;
- 12A to 12C are cross-sectional views showing examples of display devices.
- 13A and 13B are cross-sectional views showing examples of display devices.
- 14A to 14C are cross-sectional views showing examples of display devices.
- 15A to 15F are cross-sectional views showing examples of display devices.
- FIG. 16 is a perspective view showing an example of a display device.
- FIG. 16 is a perspective view showing an example of a display device.
- 17A is a cross-sectional view showing an example of a display device
- 17B and 17C are cross-sectional views showing examples of transistors
- 18A to 18D are cross-sectional views showing examples of display devices.
- 19A to 19F are diagrams showing configuration examples of light-emitting devices.
- 20A and 20B are diagrams illustrating examples of electronic devices.
- 21A to 21D are diagrams illustrating examples of electronic devices.
- 22A to 22F are diagrams illustrating examples of electronic devices.
- FIG. 23A is a diagram illustrating an explanation of the evaluation method of the example.
- 23B to 23D are photographs captured by the display device.
- film and “layer” can be interchanged depending on the case or situation.
- conductive layer can be changed to the term “conductive film.”
- insulating film can be changed to the term “insulating layer”.
- One embodiment of the present invention is an electronic device including a display portion, a processing portion, and a storage portion.
- the display has a display device with a light emitting device and a light receiving device.
- the display unit has a function of displaying an image using a light emitting device and a function of capturing an image using a light receiving device.
- the storage unit has a machine learning model using a neural network.
- the processing unit has a function of inferring position information of an object that is not in contact with the electronic device from image data captured by the display unit using a machine learning model.
- the electronic device can be multifunctional without increasing the number of components of the electronic device.
- the electronic device of one embodiment of the present invention preferably uses artificial intelligence (AI) for at least part of processing.
- AI artificial intelligence
- An electronic device of one embodiment of the present invention preferably uses an artificial neural network (ANN: hereinafter simply referred to as a neural network).
- ANN artificial neural network
- a neural network is realized by a circuit (hardware) or a program (software).
- neural network refers to a general model that imitates the neural network of an organism, determines the strength of connections between neurons through learning, and has problem-solving ability.
- a neural network has an input layer, an intermediate layer (hidden layer), and an output layer.
- determining the connection strength (also referred to as a weighting factor) between neurons from existing information may be referred to as "learning.”
- connection strength obtained by learning and deriving a new conclusion therefrom may be referred to as "inference”.
- FIG. 1A shows a block diagram of an electronic device of one embodiment of the present invention.
- An electronic device 10 shown in FIG. 1A has a processing unit 11 , a display unit 12 and a storage unit 13 .
- the display unit 12 has a display device having a light-emitting device and a light-receiving device.
- FIG. 1A shows an example of using a display device having a pixel 110 having a sub-pixel G, a sub-pixel B, a sub-pixel R, and a sub-pixel S in the display portion 12 .
- Subpixel G, subpixel B, and subpixel R each have a light emitting device.
- Sub-pixel R emits red light
- sub-pixel G emits green light
- sub-pixel B emits blue light.
- the sub-pixel S has a light receiving device.
- the wavelength of light detected by the light receiving device is not particularly limited.
- the sub-pixels S can be light receiving devices that detect one or both of visible light and infrared light.
- the display unit 12 has a function of displaying an image using the sub-pixels G, B, and R (light-emitting device) and a function of capturing an image using the sub-pixel S (light-receiving device).
- the storage unit 13 has a machine learning model using a neural network. Note that the storage unit 13 may be part of the processing unit 11 .
- the processing unit 11 has a function of inferring the position information of the target object from the imaging data captured by the display unit 12 using a machine learning model.
- the object may or may not be in contact with the electronic device 10 .
- a convolutional neural network (CNN) is preferably used for the machine learning model.
- the machine learning model is preferably trained using image data of the object to be detected.
- image data of one or more objects such as a finger, hand, and pen can be used.
- learning is performed using image data of objects of various materials and colors, for example, not only with bare hands but also with gloves.
- the position of the object can be inferred with high accuracy.
- learning is performed using image data when dust or water droplets are attached to the surface of the display unit 12 . As a result, even when dust or water droplets adhere to the surface of the display unit 12, the position of the object can be inferred with high accuracy.
- Either supervised machine learning or unsupervised machine learning may be used for learning the machine learning model.
- a machine learning model is not particularly limited, and for example, a regression model, a classification model, or a clustering model can be used.
- classification model For example, it is preferable to use supervised machine learning in which image data is given as input data (example) and classification data is given as output data (answer) for learning.
- the electronic device 10 can image an object on the display unit 12 and infer the position information of the object on the processing unit 11 .
- the processing unit 11 performs processing using a neural network NN.
- Image data 15 imaged by the display unit 12 is input to the processing unit 11 .
- An image 17 of an object is captured in the imaging data 15 .
- the imaging data 15 including the image 17 is obtained by detecting the light from the light source reflected by the object with the light receiving device.
- the processing unit 11 infers the position information 19 of the image 17 using a machine learning model using a neural network NN.
- the processing unit 11 can execute processing based on the inferred positional information. For example, the signal or potential supplied to the display unit 12 can be controlled.
- the non-contact sensor function of the electronic device 10 can be realized by detecting a non-contact object and inferring position information using the processing unit 11 and the display unit 12 .
- the non-contact sensor function can also be called a hover sensor function, a hover touch sensor function, a near touch sensor function, a touchless sensor function, or the like.
- the touch sensor function also referred to as a direct touch sensor function of the electronic device 10 can be achieved. can also be realized.
- the electronic device 10 By realizing one or both of the non-contact sensor function and the touch sensor function, the electronic device 10 detects operations such as tap, long tap, flick, drag, scroll, multi-touch, swipe, pinch-in, pinch-out, etc. Processing according to each operation can be executed.
- the processing unit 11 has a function of performing calculation, inference, etc. using data supplied from the display unit 12, the storage unit 13, and the like.
- the processing unit 11 can supply calculation results, inference results, and the like to the storage unit 13 and the like. Also, the processing unit 11 can control the signal or potential supplied to the display unit 12 based on the calculation result, the inference result, and the like.
- the processing unit 11 has, for example, an arithmetic circuit or a central processing unit (CPU: Central Processing Unit).
- CPU Central Processing Unit
- the processing unit 11 may have a microprocessor such as a DSP (Digital Signal Processor) or a GPU (Graphics Processing Unit).
- the microprocessor may have a configuration realized by PLD (Programmable Logic Device) such as FPGA (Field Programmable Gate Array), FPAA (Field Programmable Analog Array).
- PLD Programmable Logic Device
- FPGA Field Programmable Gate Array
- FPAA Field Programmable Analog Array
- the processing unit 11 can perform various data processing and program control by interpreting and executing instructions from various programs by the processor. Programs that can be executed by the processor are stored in at least one of the memory area of the processor and the storage unit 13 .
- the processing unit 11 may have a main memory.
- the main memory has at least one of volatile memory such as RAM (Random Access Memory) and non-volatile memory such as ROM (Read Only Memory).
- RAM for example, DRAM (Dynamic Random Access Memory), SRAM (Static Random Access Memory), etc. are used, and a memory space is virtually allocated and used as the work space of the processing unit 11 .
- the operating system, application programs, program modules, program data, lookup tables, etc. stored in the storage unit 13 are loaded into the RAM for execution. These data, programs, and program modules loaded into the RAM are directly accessed and manipulated by the processing unit 11, respectively.
- the ROM can store BIOS (Basic Input/Output System), firmware, etc., which do not require rewriting.
- BIOS Basic Input/Output System
- Examples of ROM include mask ROM, OTPROM (One Time Programmable Read Only Memory), EPROM (Erasable Programmable Read Only Memory), and the like.
- Examples of EPROM include UV-EPROM (Ultra-Violet Erasable Programmable Read Only Memory), EEPROM (Electrically Erasable Programmable Read Only Memory), flash memory, etc., which enables erasing of stored data by ultraviolet irradiation.
- a transistor also referred to as an OS transistor
- a metal oxide also referred to as an oxide semiconductor
- the processing portion 11 is preferably used for the processing portion 11 . Since the off-state current of the OS transistor is extremely low, the data can be held for a long time by using the OS transistor as a switch for holding charge (data) flowing into the capacitor functioning as a memory element. .
- the processing unit 11 is operated only when necessary, and in other cases, the information of the immediately preceding process is saved in the storage element. Thus, the processing section 11 can be turned off. That is, normally-off computing becomes possible, and low power consumption of electronic devices can be achieved.
- a transistor containing silicon in a channel formation region (also referred to as a Si transistor) may be used for the processing unit 11 .
- the storage unit 13 has a function of storing programs executed by the processing unit 11 .
- the storage unit 13 may also have a function of storing calculation results and inference results generated by the processing unit 11, image data captured by the display unit 12, and the like.
- the storage unit 13 has at least one of a volatile memory and a nonvolatile memory.
- the storage unit 13 may have, for example, volatile memory such as DRAM and SRAM.
- the storage unit 13 includes, for example, ReRAM (Resistive Random Access Memory), PRAM (Phase Change Random Access Memory), FeRAM (Ferroelectric Random Access Memory), MRAM (Magnetoresistive Random Access Memory), MRAM ), or non-volatile memory such as flash memory.
- the storage unit 13 may also have a recording media drive such as a hard disk drive (HDD) and a solid state drive (SSD).
- HDD hard disk drive
- SSD solid state drive
- Display unit 12 As described above, a display device having a light emitting device and a light receiving device can be used for the display section 12 .
- the three sub-pixels are R, G, and B sub-pixels, yellow (Y), cyan (C ), and magenta (M).
- the four sub-pixels include R, G, B, and white (W) sub-pixels, and R, G, B, and Y four-color sub-pixels. be done.
- the arrangement of sub-pixels includes, for example, a stripe arrangement, an S-stripe arrangement, a matrix arrangement, a delta arrangement, a Bayer arrangement, and a pentile arrangement.
- top surface shapes of sub-pixels include polygons such as triangles, quadrilaterals (including rectangles and squares), pentagons, and hexagons, and polygons with rounded corners, ellipses, and circles.
- the top surface shape of the sub-pixel corresponds to the top surface shape of the light emitting region of the light emitting device or the light receiving region of the light receiving device.
- the pixel 110 shown in FIGS. 2A-2C has G sub-pixel, B sub-pixel, R sub-pixel, and S sub-pixel. Note that there is no particular limitation on the order in which the sub-pixels are arranged. Note that when the sub-pixel S detects light of a specific color, it is preferable to arrange a sub-pixel that emits light of that color next to the sub-pixel S so that the detection accuracy can be improved. Also, sub-pixels with more reliable light-emitting devices can be made smaller.
- a pixel 110 shown in FIG. 2A is similar to the pixel 110 shown in FIG. 1A, and a stripe arrangement is applied.
- 1A and 2A show an example in which the sub-pixel R is located between the sub-pixel B and the sub-pixel S, but the sub-pixel R and the sub-pixel G may be adjacent to each other, for example.
- FIG. 2B shows an example in which sub-pixel R and sub-pixel S are located in the same row, and sub-pixel B and sub-pixel G are located in the same row. may be located on the same line.
- the sub-pixel R and the sub-pixel B are positioned in the same column and the sub-pixel S and the sub-pixel G are positioned in the same column is shown. may be located in the same column.
- a pixel 110 shown in FIG. 2C has a configuration in which a fourth sub-pixel is added to the S-stripe arrangement.
- the pixel 110 in FIG. 2C shows an example having vertically elongated sub-pixel B and horizontally elongated sub-pixels R, G, and S.
- the vertically elongated sub-pixel is either sub-pixel R, sub-pixel G, or sub-pixel S. , and the order in which the horizontally long sub-pixels are arranged is not limited.
- FIG. 2D shows an example in which pixels 109a and pixels 109b are alternately arranged.
- the pixel 109a has sub-pixel B, sub-pixel G, and sub-pixel S
- the pixel 109b has sub-pixel R, sub-pixel G, and sub-pixel S.
- FIG. 2D shows an example in which the sub-pixels included in both the pixel 109a and the pixel 109b are the sub-pixel G and the sub-pixel S, but the present invention is not particularly limited. It is preferable that both the pixel 109a and the pixel 109b have the sub-pixel S, so that the definition of imaging can be improved.
- the sub-pixel S detects the light emitted by the sub-pixel (the sub-pixel G in FIG. 2D) included in both the pixel 109a and the pixel 109b.
- FIG. 2E is a modification in which the sub-pixels of the pixels 109a and 109b shown in FIG. 2D each have a substantially rectangular top surface shape with rounded corners.
- FIG. 2F Two-dimensional hexagonal close-packing is applied to the pixel layout shown in FIG. 2F.
- a hexagonal close-packed layout is preferable because the aperture ratio of each sub-pixel can be increased.
- FIG. 2F shows an example in which each sub-pixel has a hexagonal top surface shape.
- FIG. 2G is a variation in which the pixel 110 shown in FIG. 2F has a substantially hexagonal top shape with rounded corners.
- the top surface shape of the sub-pixel may be a polygonal shape with rounded corners, an elliptical shape, a circular shape, or the like.
- the EL layer is processed into an island shape using a resist mask.
- the resist film formed on the EL layer needs to be cured at a temperature lower than the heat resistance temperature of the EL layer. Therefore, depending on the heat resistance temperature of the EL layer material and the curing temperature of the resist material, curing of the resist film may be insufficient.
- a resist film that is insufficiently hardened may take a shape away from the desired shape during processing.
- the top surface shape of the EL layer may be a polygon with rounded corners, an ellipse, or a circle. For example, when a resist mask having a square top surface is formed, a resist mask having a circular top surface is formed, and the EL layer may have a circular top surface.
- a technique for correcting the mask pattern in advance so that the design pattern and the transfer pattern match.
- OPC Optical Proximity Correction
- a pattern for correction is added to a corner portion of a figure on a mask pattern.
- one pixel may have two or more types of light receiving devices.
- a display device of one embodiment of the present invention includes a first pixel including a light-emitting device, a first light-receiving device, and a second light-receiving device.
- the first light receiving device has a smaller light receiving region area (also simply referred to as light receiving area) than the second light receiving device.
- the first light-receiving device can perform higher-definition imaging than the second light-receiving device.
- the first light receiving device can be used for imaging for personal authentication using a fingerprint, palm print, iris, pulse shape (including vein shape and artery shape), face, or the like.
- the first light receiving device can appropriately determine the wavelength of light to be detected according to the application.
- the first light receiving device preferably detects visible light.
- the second light receiving device can be used as a touch sensor, a non-contact sensor, or the like.
- the second light receiving device can appropriately determine the wavelength of light to be detected according to the application.
- the second light receiving device preferably detects infrared light. This enables detection even in dark places.
- the second light-receiving device detects infrared light, compared to a capacitive touch sensor, even if dust or water droplets adhere to the surface of the electronic device, it can be detected with high sensitivity.
- touch sensors or non-contact sensors can detect the proximity or contact of an object (such as a finger, hand, or pen).
- a touch sensor can detect an object by direct contact between the electronic device and the object.
- the non-contact sensor can detect the target even if the target does not come into contact with the electronic device.
- the display device can detect the object when the distance between the display device (or electronic device) and the object is 0.1 mm or more and 300 mm or less, preferably 3 mm or more and 50 mm or less.
- the electronic device can be operated without direct contact with the target object, in other words, the display device can be operated without contact (touchless).
- the display device of one embodiment of the present invention can have a variable refresh rate.
- the power consumption can be reduced by adjusting the refresh rate (for example, in the range of 1 Hz to 240 Hz) according to the content displayed on the display device.
- the drive frequency of the touch sensor or the non-contact sensor may be changed according to the refresh rate. For example, when the refresh rate of the display device is 120 Hz, the driving frequency of the touch sensor or the non-contact sensor can be higher than 120 Hz (typically 240 Hz). With this structure, low power consumption can be achieved and the response speed of the touch sensor or the non-contact sensor can be increased.
- the detection method of the object may be selected according to the function based on the difference in detection accuracy between the first light receiving device and the second light receiving device.
- the swipe function and the scroll function of the display screen are realized by a non-contact sensor function using the second light receiving device, and the input function with the keyboard displayed on the screen is realized by the first light receiving device. It may be realized by the high-definition touch sensor function used.
- the first light-receiving device is preferably provided for all pixels included in the display device in order to perform high-definition imaging.
- the second light-receiving device used for a touch sensor, a non-contact sensor, or the like does not require high accuracy compared to detection using the first light-receiving device, and is provided in some pixels of the display device. It is good if there is The detection speed can be increased by reducing the number of the second light-receiving devices included in the display device compared to the number of the first light-receiving devices.
- a display device of one embodiment of the present invention can have a structure in which a plurality of each of the above first pixels and second pixels is provided.
- the second pixel is similar to the first pixel in that it has a light-emitting device and a first light-receiving device, and does not have a second light-receiving device, but instead has another device. and is different from the first pixel.
- the second pixel can have various sensor devices, or light emitting devices that emit infrared light, or the like. By providing the second pixel with a device different from that of the first pixel in this manner, the display device can be multifunctional.
- a pixel when a pixel is provided with light-emitting devices of three colors of red, green, and blue in order to perform full-color display, by further providing two light-receiving devices, one pixel can be obtained from five sub-pixels. It will be configured. Thus, it is extremely difficult to achieve a high aperture ratio in a pixel having many sub-pixels. Alternatively, it is difficult to realize a high-definition display device using a pixel having many sub-pixels.
- the island-shaped EL layer is not formed using a fine metal mask, but is formed by forming an EL layer over one surface and then processing the EL layer. preferable.
- a high-definition display device or a display device with a high aperture ratio which has been difficult to achieve.
- the display device of one embodiment of the present invention can have a high aperture ratio, high definition, and multiple functions.
- FIG. 3A shows an example of a pixel included in a display device of one embodiment of the present invention.
- Pixel 180A shown in FIG. 3A has sub-pixel G, sub-pixel B, sub-pixel R, sub-pixel PS, and sub-pixel IRS.
- FIG. 3A shows an example in which one pixel 180A is composed of 2 rows and 3 columns.
- the pixel 180A has three sub-pixels (sub-pixel G, sub-pixel B, and sub-pixel R) in the upper row (first row) and two sub-pixels (sub-pixel R) in the lower row (second row).
- sub-pixel PS, sub-pixel IRS sub-pixel PS, sub-pixel IRS.
- the pixel 110 has two sub-pixels (sub-pixel G, sub-pixel PS) in the left column (first column) and sub-pixel B in the center column (second column). It has sub-pixels R in the right column (third column), and sub-pixels IRS from the center column to the right column.
- the lower row may also have three sub-pixels (sub-pixel PS and two sub-pixels IRS).
- sub-pixel PS sub-pixel PS
- IRS sub-pixels
- the two sub-pixels IRS may each have their own light receiving device, or may have one light receiving device in common. That is, the pixel 110 shown in FIG. 3B can be configured to have one light receiving device for the subpixel PS and one or two light receiving devices for the subpixel IRS.
- the light receiving area of the sub-pixel PS is smaller than the light receiving area of the sub-pixel IRS.
- the sub-pixels PS can be used to capture images for personal authentication using a fingerprint, palm print, iris, pulse shape (including vein shape and artery shape), face, or the like.
- the resolution of the sub-pixels PS should be 100 ppi or more, preferably 200 ppi or more, more preferably 300 ppi or more, more preferably 400 ppi or more, still more preferably 500 ppi or more, and 2000 ppi or less, 1000 ppi or less, or 600 ppi or less. can be done.
- by arranging the light-receiving device with a resolution of 200 ppi to 600 ppi, preferably 300 ppi to 600 ppi it can be suitably used for fingerprint imaging.
- the resolution is 500 ppi or more, it is preferable because it can conform to standards such as the US National Institute of Standards and Technology (NIST). Assuming that the resolution of the light-receiving device is 500 ppi, the size of one pixel is 50.8 ⁇ m. I understand.
- a clear fingerprint image can be obtained by setting the array interval of the light receiving devices to be smaller than the distance between two protrusions of the fingerprint, preferably smaller than the distance between adjacent recesses and protrusions. It is said that the distance between the concave and convex portions of a human fingerprint is approximately 200 ⁇ m.
- the width of a human fingerprint is said to be 300 ⁇ m or more and 500 ⁇ m or less, or 460 ⁇ m ⁇ 150 ⁇ m.
- the arrangement interval of the light receiving devices is 400 ⁇ m or less, preferably 200 ⁇ m or less, more preferably 150 ⁇ m or less, still more preferably 100 ⁇ m or less, further preferably 50 ⁇ m or less, and 1 ⁇ m or more, preferably 10 ⁇ m or more, more preferably 20 ⁇ m or more.
- the light-receiving device included in the subpixel PS preferably detects visible light, and preferably detects one or more of blue, purple, blue-violet, green, yellow-green, yellow, orange, and red light. . Also, the light receiving device included in the sub-pixel PS may detect infrared light (including near-infrared light).
- the sub-pixel IRS can be used for a touch sensor, a non-contact sensor, or the like.
- the sub-pixel IRS can appropriately determine the wavelength of light to be detected according to the application.
- sub-pixel IRS preferably detects infrared light. This enables touch detection even in dark places.
- 3C and 3D illustrate examples of cross-sectional views of electronic devices each including the display device of one embodiment of the present invention.
- the electronic devices shown in FIGS. 3C and 3D each have display device 100 and light source 104 between housing 103 and protective member 105 .
- the light source 104 has a light emitting device that emits infrared light 31IR.
- a light emitting diode LED: Light Emitting Diode
- FIG. 3C shows an example in which the light source 104 is arranged at a position that does not overlap with the display device 100 . At this time, light emitted from the light source 104 is emitted to the outside of the electronic device through the protective member 105 .
- FIG. 3D shows an example in which the display device and the light source 104 are overlapped. At this time, light emitted from the light source 104 is emitted to the outside of the electronic device through the display device 100 and the protective member 105 .
- the display device 100 shown in FIGS. 3C and 3D corresponds to the cross-sectional structure along the dashed-dotted line A1-A2 in FIG. 3A.
- Display device 100 has a plurality of light emitting devices and a plurality of light receiving devices between substrate 106 and substrate 102 .
- Subpixel R has a light emitting device 130R that emits red light 31R.
- Subpixel G has a light emitting device 130G that emits green light 31G.
- Subpixel B has a light emitting device 130B that emits blue light 31B.
- the sub-pixel PS has a light receiving device 150PS and the sub-pixel IRS has a light receiving device 150IRS.
- the wavelength of light detected by the sub-pixels PS and IRS is not particularly limited.
- the infrared light 31IR emitted by the light source 104 is reflected by the object 108 (finger here), and the reflected light 32IR from the object 108 is incident on the light receiving device 150IRS.
- the receiving device 150IRS can be used to detect the object 108 .
- the wavelength of light detected by light receiving device 150IRS is not particularly limited.
- the light receiving device 150IRS preferably detects infrared light.
- the light receiving device 150IRS may detect visible light, or both infrared light and visible light.
- detection of the object 108 may be performed using both the light receiving device 150PS and the light receiving device 150IRS.
- infrared light 31IR emitted by light source 104 is reflected by object 108 (here, a finger), and reflected light 32IR from object 108 is incident on light receiving device 150IRS. be done.
- green light 31G emitted by light emitting device 130G is also reflected by object 108, and reflected light 32G from object 108 is incident on light receiving device 150PS.
- the object 108 is not in contact with the electronics, the object 108 can be detected using the light receiving device 150IRS and the light receiving device 150PS.
- the light receiving device 150IRS (and the light receiving device 150PS) can also be used to detect the object 108 in contact with the electronic device.
- green light 31G emitted by light emitting device 130G is reflected by target 108, and reflected light 32G from target 108 is incident on light receiving device 150PS.
- a fingerprint of the object 108 can be imaged using the light receiving device 150PS.
- green light 31G emitted by light emitting device 130G is used to detect an object by light receiving device 150PS, but the wavelength of light detected by light receiving device 150PS is not particularly limited.
- the light-receiving device 150PS preferably detects visible light, preferably one or more of blue, purple, blue-violet, green, yellow-green, yellow, orange, and red light. Also, the light receiving device 150PS may detect infrared light.
- the light receiving device 150PS may have the function of detecting red light 31R emitted by the light emitting device 130R. Also, the light receiving device 150PS may have a function of detecting the blue light 31B emitted by the light emitting device 130B.
- the light-emitting device that emits the light detected by the light-receiving device 150PS is provided in a sub-pixel close to the sub-pixel PS in the pixel.
- the light receiving device 150PS detects light emitted from the light emitting device 130G of the subpixel G adjacent to the subpixel PS. With such a configuration, detection accuracy can be improved.
- all pixels may have the structure of the pixel 180A, some pixels may have the structure of the pixel 180A, and other pixels may have the structure of the pixel 180A. configuration may be applied.
- a display device of one embodiment of the present invention may include both the pixel 180A illustrated in FIG. 5A and the pixel 180B illustrated in FIG. 5B.
- a pixel 180B shown in FIG. 5B has sub-pixel G, sub-pixel B, sub-pixel R, sub-pixel PS, and sub-pixel X.
- FIG. 5B A pixel 180B shown in FIG. 5B has sub-pixel G, sub-pixel B, sub-pixel R, sub-pixel PS, and sub-pixel X.
- the pixel may have three sub-pixels (sub-pixel PS and two sub-pixels X) in the bottom row (second row).
- sub-pixel PS sub-pixel PS
- sub-pixel X sub-pixel X
- a device included in the sub-pixel X can be used to realize various functions in a display device or an electronic device equipped with the display device.
- a display device or an electronic device uses a device possessed by the sub-pixel X to detect force, displacement, position, speed, acceleration, angular velocity, number of rotations, distance, magnetism, temperature, chemicals, time, electric field, current, voltage, and so on. , power, radiation, flow rate, humidity, gradient, vibration, smell, physical condition, pulse, body temperature, blood oxygen concentration, and arterial blood oxygen saturation.
- Functions of the display device or electronic device include, for example, a strobe light function, a flash light function, a deterioration correction function, an acceleration sensor function, an odor sensor function, a physical condition detection function, a pulse detection function, a body temperature detection function, and a pulse oximeter. function as a monitor, blood oxygen concentration measurement function, and the like.
- the strobe light function can be realized, for example, by repeating light emission and non-light emission in a short cycle.
- the flashlight function can be realized by, for example, a configuration that generates a flash of light by instantaneously discharging using the principle of an electric double layer or the like.
- the strobe light function and the flash light function can be used, for example, for security purposes or self-defense purposes.
- white is preferable as the emission color of the strobe light and the flash light.
- the practitioner can select one of the most suitable emission colors, such as white, blue, purple, blue-violet, green, yellow-green, yellow, orange, and red. Or you can select multiple.
- the deterioration correcting function there is a function of correcting the deterioration of the light-emitting device of at least one sub-pixel selected from the sub-pixel G, sub-pixel B, and sub-pixel R. More specifically, when the reliability of the material used for the light-emitting device included in the sub-pixel G is poor, the sub-pixel X has the same configuration as the sub-pixel G so that two sub-pixels G can be formed in the pixel 180B. can be provided. With this structure, the area of the sub-pixel G can be doubled. By doubling the area of the sub-pixel G, it is possible to increase the reliability by about two times compared to the configuration in which the sub-pixel G is one.
- the other sub-pixel G can be used to A configuration in which the light emission of the pixel G is supplemented may be employed.
- the sub-pixel G has been described above, the sub-pixel B and the sub-pixel R can also have the same configuration.
- the acceleration sensor function, the odor sensor function, the physical condition detection function, the pulse detection function, the body temperature detection function, and the blood oxygen concentration measurement function can be realized by providing the sub-pixel X with a sensor device necessary for detection. can. Further, it can be said that the display device or the electronic device can realize various functions according to the sensor device provided in the sub-pixel X.
- the display device having the pixel 180B can be called a multi-function display device or a multi-function panel.
- the function of the sub-pixel X may be one or two or more, and the operator can appropriately select the optimum function.
- the display device of one embodiment of the present invention may include a pixel including four subpixels, which does not include both the subpixel X and the subpixel IRS. That is, it may have a pixel having sub-pixel G, sub-pixel B, sub-pixel R, and sub-pixel PS. Further, the display device may have different numbers of sub-pixels depending on the pixel. On the other hand, in order to make the quality of each pixel uniform, it is preferable that all pixels have the same number of sub-pixels.
- the display device of one embodiment of the present invention may include both the pixel 180A illustrated in FIG. 5A and the pixel 180C illustrated in FIG. 5D.
- Pixel 180C shown in FIG. 5D has sub-pixel G, sub-pixel B, sub-pixel R, sub-pixel PS, and sub-pixel IR.
- Sub-pixel IR has a light-emitting device that emits infrared light. That is, the sub-pixel IR can be used as the light source of the sensor. Since the display device includes a light-emitting device that emits infrared light, it is not necessary to provide a light source separately from the display device, and the number of parts of the electronic device can be reduced.
- FIG. 5E illustrates an example of a cross-sectional view of an electronic device including a display device of one embodiment of the present invention.
- the electronic device shown in FIG. 5E has display device 100 between housing 103 and protective member 105 .
- the display device 100 shown in FIG. 5E corresponds to the cross-sectional structure along the dashed-dotted line A1-A2 in FIG. 5A and the cross-sectional structure along the dashed-dotted line A3-A4 in FIG. 5D. That is, the display device 100 shown in FIG. 5E has a pixel 180A and a pixel 180C.
- Subpixel R has a light emitting device 130R that emits red light 31R.
- Subpixel G has a light emitting device 130G that emits green light 31G.
- Subpixel B has a light emitting device 130B that emits blue light 31B.
- the sub-pixel PS has a light receiving device 150PS and the sub-pixel IRS has a light receiving device 150IRS.
- Subpixel IR has a light emitting device 130IR that emits infrared light 31IR.
- the infrared light 31IR emitted by the light emitting device 130IR is reflected by the object 108 (finger in this case), and the reflected light 32IR from the object 108 enters the light receiving device 150IRS.
- the receiving device 150IRS can be used to detect the object 108 .
- 6 to 9 show an example of the layout of the display device.
- the non-contact sensor function for example, illuminates an object (such as a finger, hand, or pen) with a light source fixed at a specific location, detects the reflected light from the object with a plurality of subpixels IRS, and detects a plurality of subpixels It can be realized by estimating the position of the object from the detection intensity ratio in the IRS.
- an object such as a finger, hand, or pen
- the pixels 180A having the sub-pixels IRS can be arranged in the display section at regular intervals, or arranged in the periphery of the display section.
- the driving frequency can be increased by performing non-contact detection using only some pixels.
- the sub-pixel X or the sub-pixel IR can be mounted in another pixel, the display device can be multi-functionalized.
- the display device 100A shown in FIG. 6 has two types of pixels: pixels 180A and pixels 180B.
- one pixel 180A is provided for 3 ⁇ 3 pixels (9 pixels), and the configuration of the pixel 180B is applied to the other pixels.
- the period of arranging the pixels 180A is not limited to one per 3 ⁇ 3 pixels.
- the pixels used for touch detection are 1 pixel per 4 pixels (2 ⁇ 2 pixels), 1 pixel per 16 pixels (4 ⁇ 4 pixels), 1 pixel per 100 pixels (10 ⁇ 10 pixels), or 900 pixels (30 pixels). x30 pixels) can be determined as appropriate.
- the display device 100B shown in FIG. 7 has two types of pixels: pixels 180A and pixels 180C.
- one pixel 180A is provided for 3 ⁇ 3 pixels (9 pixels), and the configuration of the pixel 180C is applied to the other pixels.
- the display device 100C shown in FIG. 8 has two types of pixels: pixels 180A and pixels 180B.
- the pixels 180A are provided on the periphery of the display portion, and the configuration of the pixels 180B is applied to the other pixels.
- the pixels 180A When the pixels 180A are provided around the periphery of the display portion, the pixels 180A may be arranged so as to surround all four sides as shown in FIG. can be arranged and various arrangements can be applied.
- the display device 100D shown in FIG. 9 has two types of pixels: pixels 180A and pixels 180C.
- the pixels 180A are provided on the periphery of the display portion, and the configuration of the pixels 180C is applied to the other pixels.
- infrared light 31IR emitted by a light source 104 provided outside the display unit of the display device is reflected by an object 108, and reflected light 32IR from the object 108 enters a plurality of pixels 180A. be done.
- the reflected light 32IR is detected by the sub-pixel IRS provided in the pixel 180A, and the position of the target object 108 can be estimated from the detection intensity ratio of the plurality of sub-pixels IRS.
- the light source 104 is provided at least outside the display portion of the display device, and may be built in the display device or may be mounted in an electronic device separately from the display device.
- a light emitting diode that emits infrared light can be used.
- the infrared light 31IR emitted by the sub-pixel IR of the pixel 180C is reflected by the target 108, and the reflected light 32IR from the target 108 is incident on the plurality of pixels 180A.
- the reflected light 32IR is detected by the sub-pixel IRS provided in the pixel 180A, and the position of the target object 108 can be estimated from the detection intensity ratio of the plurality of sub-pixels IRS.
- the layout of the display device can take various forms.
- FIG. 10 shows an example of a pixel circuit with two light receiving devices.
- the pixel shown in FIG. 10 comprises transistors M11, M12, M13, M14, M15, capacitor C1, and photodetectors PD1, PD2.
- the transistor M11 has a gate electrically connected to the wiring TX, one of its source and drain electrically connected to the anode electrode of the light receiving device PD1 and one of the source and drain of the transistor M15. The other is electrically connected to one of the source and drain of the transistor M12, the first electrode of the capacitor C1, and the gate of the transistor M13.
- the transistor M12 has a gate electrically connected to the wiring RS and the other of the source and the drain electrically connected to the wiring VRS.
- the transistor M13 has one of its source and drain electrically connected to the wiring VPI, and the other of its source and drain electrically connected to one of its source and drain of the transistor M14.
- the transistor M14 has a gate electrically connected to the wiring SE and the other of the source and the drain electrically connected to the wiring WX.
- the transistor M15 has a gate electrically connected to the wiring SW, and the other of the source and the drain electrically connected to the anode electrode of the light receiving device PD2.
- Cathode electrodes of the light receiving device PD1 and the light receiving device PD2 are electrically connected to the wiring CL.
- a second electrode of the capacitor C1 is electrically connected to the wiring VCP.
- Transistor M11, transistor M12, transistor M14, and transistor M15 function as switches.
- the transistor M13 functions as an amplifying element (amplifier).
- transistors also referred to as OS transistors
- a metal oxide also referred to as an oxide semiconductor
- An OS transistor has extremely low off-state current and can hold charge accumulated in a capacitor connected in series with the transistor for a long time. Further, with the use of the OS transistor, power consumption of the display device can be reduced.
- transistors including silicon in a semiconductor layer in which a channel is formed are preferably used for all the transistors included in the pixel circuit.
- silicon include monocrystalline silicon, polycrystalline silicon, amorphous silicon, and the like.
- a transistor including low-temperature polysilicon (LTPS) in a semiconductor layer hereinafter also referred to as an LTPS transistor.
- the LTPS transistor has high field effect mobility and can operate at high speed.
- the pixel circuit preferably includes an OS transistor and an LTPS transistor.
- OS transistor an OS transistor
- LTPS transistor an LTPS transistor
- LTPS transistors using low-temperature polysilicon for semiconductor layers are preferably used for all of the transistors M11 to M15.
- an OS transistor using a metal oxide for a semiconductor layer as the transistor M11, the transistor M12, and the transistor M15, and use an LTPS transistor as the transistor M13.
- an OS transistor or an LTPS transistor may be used as the transistor M14.
- the potential held at the gate of the transistor M13 changes based on the charges generated in the light receiving device PD1 and the light receiving device PD2. Leakage through transistor M15 can be prevented.
- an LTPS transistor is preferably used as the transistor M13.
- An LTPS transistor can achieve higher field-effect mobility than an OS transistor, and has excellent driving capability and current capability. Therefore, the transistor M13 can operate faster than the transistors M11, M12, and M15. By using an LTPS transistor for the transistor M13, it is possible to quickly output to the transistor M14 a minute potential based on the amount of light received by the light receiving device PD1 or the light receiving device PD2.
- the transistors M11, M12, and M15 have low leakage current, and the transistor M13 has high driving capability. And the charge transferred through the transistor M15 can be held without leaking, and reading can be performed at high speed.
- the transistor M14 functions as a switch that passes the output from the transistor M13 to the wiring WX, unlike the transistors M11 to M13 and the transistor M15, low off-state current, high-speed operation, and the like are not necessarily required. Therefore, low-temperature polysilicon or an oxide semiconductor may be applied to the semiconductor layer of the transistor M14.
- transistors are shown as n-channel transistors in FIG. 10, p-channel transistors can also be used.
- the aperture ratio (light-receiving area) of the light-receiving device is small.
- the aperture ratio (light receiving area) of the light receiving device is large. Therefore, it is preferable that the aperture ratio (light-receiving area) of the light-receiving device PD1 is smaller than the aperture ratio (light-receiving area) of the light-receiving device PD2.
- imaging that requires high definition, it is preferable to perform imaging using only the light receiving device PD1 by turning on the transistor M11 and turning off the transistor M15.
- the amount of light that can be imaged can be increased, making it easier to detect an object at a distance from the electronic device.
- the electronic device of one embodiment of the present invention can detect non-contact objects and infer position information using the processing portion and the display portion. Inference accuracy can be improved by using a machine learning model in the processing unit.
- the display device of one embodiment of the present invention can have two functions in addition to a display function by mounting two types of light-receiving devices in one pixel. becomes possible. For example, it is possible to realize a high-definition imaging function and a sensing function such as a touch sensor or a non-contact sensor.
- a pixel equipped with two types of light receiving devices and a pixel with another configuration the functions of the electronic device can be further increased. For example, a light-emitting device that emits infrared light, or a pixel having various sensor devices can be used.
- a display device of one embodiment of the present invention includes a light-emitting device and a light-receiving device in a pixel.
- pixels have a light-receiving function, contact or proximity of an object can be detected while displaying an image. For example, in addition to displaying an image with all the sub-pixels of the display device, some sub-pixels exhibit light as a light source, some other sub-pixels perform light detection, and the remaining sub-pixels You can also display images with
- light-emitting devices are arranged in matrix in the display portion, and an image can be displayed on the display portion.
- light receiving devices are arranged in a matrix in the display section, and the display section has one or both of an imaging function and a sensing function in addition to an image display function.
- the display part can be used for an image sensor or a touch sensor. That is, by detecting light on the display portion, an image can be captured, or proximity or contact of an object (a finger, hand, pen, or the like) can be detected.
- the display device of one embodiment of the present invention can use a light-emitting device as a light source of a sensor. Therefore, it is not necessary to provide a light receiving portion and a light source separately from the display device, and the number of parts of the electronic device can be reduced.
- the light-receiving device when an object reflects (or scatters) light emitted by a light-emitting device included in the display portion, the light-receiving device can detect the reflected light (or scattered light).
- the reflected light or scattered light.
- imaging or touch detection is possible.
- a display device of one embodiment of the present invention has a function of displaying an image using a light-emitting device.
- the light-emitting device functions as a display device (also referred to as a display element).
- an OLED Organic Light Emitting Diode
- a QLED Quadantum-dot Light Emitting Diode
- Light-emitting substances also referred to as light-emitting materials
- Light-emitting substances included in the light-emitting device include substances that emit fluorescence (fluorescent materials), substances that emit phosphorescence (phosphorescence materials), and substances that exhibit thermally activated delayed fluorescence (thermally activated delayed fluorescence). Delayed Fluorescence (TADF) material) and the like.
- TADF Delayed Fluorescence
- As the TADF material a material in which a singlet excited state and a triplet excited state are in thermal equilibrium may be used.
- TADF material has a short emission lifetime (excitation lifetime), it is possible to suppress a decrease in efficiency in a high-luminance region of a light-emitting device.
- LEDs such as micro LED (Light Emitting Diode)
- micro LED Light Emitting Diode
- an inorganic compound quantum dot material or the like
- a display device of one embodiment of the present invention has a function of detecting light using a light-receiving device.
- the display device can capture an image using the light receiving device.
- the display device of this embodiment can be used as a scanner.
- an image sensor can be used to acquire biometric data such as fingerprints and palm prints. That is, the biometric authentication sensor can be incorporated in the display device.
- the biometric authentication sensor can be incorporated into the display device.
- the display device can detect proximity or contact of an object using the light receiving device.
- a pn-type or pin-type photodiode can be used as the light receiving device.
- a light-receiving device functions as a photoelectric conversion device (also referred to as a photoelectric conversion element) that detects light incident on the light-receiving device and generates an electric charge. The amount of charge generated from the light receiving device is determined based on the amount of light incident on the light receiving device.
- organic photodiode having a layer containing an organic compound as the light receiving device.
- Organic photodiodes can be easily made thinner, lighter, and larger, and have a high degree of freedom in shape and design, so that they can be applied to various display devices.
- an organic EL device is used as the light-emitting device and an organic photodiode is used as the light-receiving device.
- An organic EL device and an organic photodiode can be formed on the same substrate. Therefore, an organic photodiode can be incorporated in a display device using an organic EL device.
- the organic photodiode has many layers that can have the same configuration as the organic EL device, the layers that can have the same configuration can be formed at once, thereby suppressing an increase in the number of film forming steps.
- one of the pair of electrodes can be a layer having a structure common to the light receiving device and the light emitting device.
- at least one of the hole injection layer, the hole transport layer, the electron transport layer, and the electron injection layer is preferably a layer having a common configuration in the light receiving device and the light emitting device.
- a layer shared by the light-receiving device and the light-emitting device may have different functions in the light-emitting device and in the light-receiving device. Components are referred to herein based on their function in the light emitting device.
- a hole-injecting layer functions as a hole-injecting layer in light-emitting devices and as a hole-transporting layer in light-receiving devices.
- an electron-injecting layer functions as an electron-injecting layer in light-emitting devices and as an electron-transporting layer in light-receiving devices.
- a layer shared by the light-receiving device and the light-emitting device may have the same function in the light-emitting device as in the light-receiving device.
- a hole-transporting layer functions as a hole-transporting layer in both a light-emitting device and a light-receiving device
- an electron-transporting layer functions as an electron-transporting layer in both a light-emitting device and a light-receiving device.
- an island-shaped light-emitting layer can be formed by a vacuum evaporation method using a metal mask (also referred to as a shadow mask).
- a metal mask also referred to as a shadow mask.
- island-like formations occur due to various influences such as precision of the metal mask, misalignment between the metal mask and the substrate, bending of the metal mask, and broadening of the contour of the deposited film due to vapor scattering. Since the shape and position of the light-emitting layer deviate from the design, it is difficult to increase the definition and aperture ratio of the display device.
- an island-shaped pixel electrode (which can also be called a lower electrode) is formed, and a first layer (EL layer or EL layer) including a light-emitting layer that emits light of a first color is formed. layer) is formed over the entire surface, a first sacrificial layer is formed on the first layer. Then, a first resist mask is formed over the first sacrificial layer, and the first layer and the first sacrificial layer are processed using the first resist mask, thereby forming an island-shaped first layer.
- a second layer (which can be called an EL layer or part of an EL layer) including a light-emitting layer that emits light of a second color is formed as a second sacrificial layer. and an island shape using a second resist mask.
- the island-shaped EL layer is not formed using a fine metal mask, but is processed after the EL layer is formed over one surface. It is formed. Therefore, it is possible to realize a high-definition display device or a display device with a high aperture ratio, which has hitherto been difficult to achieve. Furthermore, since the EL layer can be separately formed for each color, a display device with extremely vivid, high-contrast, and high-quality display can be realized.
- a sacrificial layer (which may also be referred to as a mask layer) over the EL layer, damage to the EL layer during the manufacturing process of the display device can be reduced, and the reliability of the light-emitting device can be improved.
- the pattern of the EL layer itself (which can also be called a processing size) can be made much smaller than when a metal mask is used.
- the thickness of the EL layer varies between the center and the edge, so the effective area that can be used as the light emitting region is smaller than the area of the EL layer. Become.
- the manufacturing method described above since the EL layer is formed by processing a film formed to have a uniform thickness, the thickness can be made uniform within the EL layer, and even a fine pattern can be formed in almost the entire area. can be used as the light emitting region. Therefore, a display device having both high definition and high aperture ratio can be manufactured.
- the first layer and the second layer each include at least a light-emitting layer, and preferably consist of a plurality of layers. Specifically, it is preferable to have one or more layers on the light-emitting layer.
- the light-emitting layer can be prevented from being exposed to the outermost surface during the manufacturing process of the display device, and damage to the light-emitting layer can be reduced. This can improve the reliability of the light emitting device.
- a light-emitting device that emits light of different colors, it is not necessary to separately form all the layers constituting the EL layer, and some of the layers can be formed in the same process.
- the sacrificial layer is removed, and the remaining layers forming the EL layer are shared.
- An electrode also referred to as an upper electrode is formed in common for the light emitting devices of each color.
- a manufacturing method similar to that for the light-emitting device can also be applied to the light-receiving device.
- the island-shaped active layer (also called photoelectric conversion layer) of the light receiving device is not formed using a fine metal mask, but is formed by forming a film that will become the active layer over the surface and then processing it. Therefore, the island-shaped active layer can be formed with a uniform thickness. Further, by providing the sacrificial layer over the active layer, the damage to the active layer during the manufacturing process of the display device can be reduced, and the reliability of the light receiving device can be improved.
- FIG. 11A and 11B illustrate a display device of one embodiment of the present invention.
- FIG. 11A shows a top view of the display device 100E.
- the display device 100E has a display section in which a plurality of pixels 110 are arranged in a matrix and a connection section 140 outside the display section.
- One pixel 110 is composed of five sub-pixels 110a, 110b, 110c, 110d, and 110e. Note that the pixel is not limited to the configuration in FIG. 11A, and for example, each configuration exemplified in Embodiment 1 can be applied.
- FIG. 11A shows an example in which one pixel 110 is composed of 2 rows and 3 columns.
- the pixel 110 has three sub-pixels (sub-pixels 110a, 110b, 110c) in the upper row (first row) and two sub-pixels (sub-pixels 110d, 110d, 110c) in the lower row (second row). 110e).
- pixel 110 has two sub-pixels (sub-pixels 110a and 110d) in the left column (first column), has sub-pixel 110b in the center column (second column), and has sub-pixel 110b in the middle column (second column). It has a sub-pixel 110c in the column (third column), and further has sub-pixels 110e from the center column to the right column.
- sub-pixels 110a, 110b, and 110c each have light-emitting devices that emit light of different colors
- sub-pixels 110d and 110e each have light-receiving devices with different light-receiving areas.
- sub-pixels 110a, 110b, and 110c correspond to sub-pixels G, B, and R shown in FIG. 5A and the like.
- the sub-pixel 110d corresponds to the sub-pixel PS shown in FIG. 5A and the like
- the sub-pixel 110e corresponds to the sub-pixel IRS shown in FIG. 5A and the like.
- sub-pixel 110e may be changed for each pixel.
- some sub-pixels 110e may correspond to sub-pixels IRS, and other sub-pixels 110e may correspond to sub-pixels X (see FIG. 5B) or sub-pixels IR (see FIG. 5D).
- connection portion 140 is positioned below the display portion in a top view
- the connecting portion 140 may be provided at least one of the upper side, the right side, the left side, and the lower side of the display portion when viewed from above, and may be provided so as to surround the four sides of the display portion.
- the number of connection parts 140 may be singular or plural.
- FIG. 11B shows cross-sectional views along dashed-dotted lines X1-X2, X3-X4, and Y1-Y2 in FIG. 11A.
- FIGS. 12A to 12C, FIGS. 13A and 13B, and FIGS. 14A to 14C show cross-sectional views along dashed-dotted lines X1-X2 and Y1-Y2 in FIG. 11A.
- light emitting devices 130a, 130b, 130c and light receiving devices 150d, 150e are provided on a layer 101 including transistors, and a protective layer 131 is provided to cover these light emitting devices and light receiving devices. is provided.
- a substrate 120 is bonded onto the protective layer 131 with a resin layer 122 .
- an insulating layer 125 and an insulating layer 127 on the insulating layer 125 are provided in a region between two adjacent devices (a light-emitting device and a light-receiving device, two light-emitting devices, or two light-receiving devices). ing.
- a display device of one embodiment of the present invention is a top emission type in which light is emitted in a direction opposite to a substrate over which a light-emitting device is formed, and light is emitted toward a substrate over which a light-emitting device is formed.
- a bottom emission type bottom emission type
- a double emission type dual emission type in which light is emitted from both sides may be used.
- the layer 101 including transistors for example, a stacked-layer structure in which a plurality of transistors are provided over a substrate and an insulating layer is provided to cover the transistors can be applied.
- the layer 101 containing the transistors may have recesses between two adjacent devices.
- recesses may be provided in the insulating layer located on the outermost surface of the layer 101 including the transistor.
- a structural example of the layer 101 including a transistor will be described later in Embodiment 3.
- Light emitting devices 130a, 130b, 130c each emit different colors of light.
- Light-emitting devices 130a, 130b, and 130c are preferably a combination that emits three colors of light, red (R), green (G), and blue (B), for example.
- a light-emitting device has an EL layer between a pair of electrodes.
- one of a pair of electrodes may be referred to as a pixel electrode and the other may be referred to as a common electrode.
- one electrode functions as an anode and the other electrode functions as a cathode.
- the pixel electrode functions as an anode and the common electrode functions as a cathode will be described below as an example.
- the light-emitting device 130a includes a conductive layer 111a on the layer 101 including the transistor, a first island-shaped layer 113a on the conductive layer 111a, a fourth layer 114 on the first island-shaped layer 113a, and a fourth layer 114 on the conductive layer 111a. a common electrode 115 on the four layers 114;
- the conductive layer 111a functions as a pixel electrode.
- the first layer 113a and the fourth layer 114 can be collectively called an EL layer.
- the description in Embodiment 4 can be referred to for the structure example of the light-emitting device.
- the first layer 113a has, for example, a hole injection layer, a hole transport layer, a light emitting layer, and an electron transport layer.
- the first layer 113a has, for example, a first light-emitting unit, a charge generation layer, and a second light-emitting unit.
- the fourth layer 114 has, for example, an electron injection layer.
- the fourth layer 114 may have a laminate of an electron transport layer and an electron injection layer.
- the light emitting device 130b includes a conductive layer 111b on the layer 101 including the transistor, a second island layer 113b on the conductive layer 111b, a fourth layer 114 on the second island layer 113b, and a fourth layer 114 on the second layer 113b. a common electrode 115 on the four layers 114;
- the conductive layer 111b functions as a pixel electrode.
- the second layer 113b and the fourth layer 114 can be collectively called an EL layer.
- the light-emitting device 130c includes a conductive layer 111c on the layer 101 including the transistor, an island-shaped third layer 113c on the conductive layer 111c, a fourth layer 114 on the island-shaped third layer 113c, and a third layer 113c on the conductive layer 111c. a common electrode 115 on the four layers 114;
- the conductive layer 111c functions as a pixel electrode.
- the third layer 113c and the fourth layer 114 can be collectively referred to as EL layers.
- Light emitting devices 130a, 130b, 130c each emit different colors of light.
- Light-emitting devices 130a, 130b, and 130c are preferably a combination that emits three colors of light, red (R), green (G), and blue (B), for example.
- a light receiving device has an active layer between a pair of electrodes.
- one of a pair of electrodes may be referred to as a pixel electrode and the other may be referred to as a common electrode.
- one electrode functions as an anode and the other electrode functions as a cathode.
- the pixel electrode functions as an anode and the common electrode functions as a cathode will be described below as an example. That is, the light-receiving device can be driven by applying a reverse bias between the pixel electrode and the common electrode to detect light incident on the light-receiving device, generate charges, and extract them as current.
- the pixel electrode may function as a cathode and the common electrode may function as an anode.
- the light-receiving device 150d includes a conductive layer 111d on the layer 101 including the transistor, a fifth island-shaped layer 113d on the conductive layer 111d, a fourth layer 114 on the fifth island-shaped layer 113d, and a fifth layer 113d. a common electrode 115 on the four layers 114;
- the conductive layer 111d functions as a pixel electrode.
- the fifth layer 113d has, for example, a hole transport layer, an active layer, and an electron transport layer.
- the light-receiving device 150e includes a conductive layer 111e on the layer 101 including the transistor, a sixth island-shaped layer 113e on the conductive layer 111e, a fourth layer 114 on the sixth island-shaped layer 113e, and a fourth layer 114 on the sixth layer 113e. a common electrode 115 on the four layers 114;
- the conductive layer 111e functions as a pixel electrode.
- the sixth layer 113e has, for example, a hole transport layer, an active layer and an electron transport layer.
- a fourth layer 114 is a layer common to the light-emitting device and the light-receiving device.
- the fourth layer 114 comprises, for example, an electron injection layer, as described above.
- the fourth layer 114 may have a laminate of an electron transport layer and an electron injection layer.
- the common electrode 115 is electrically connected to the conductive layer 123 provided in the connecting portion 140 .
- FIG. 11B shows an example in which the fourth layer 114 is provided over the conductive layer 123 and the conductive layer 123 and the common electrode 115 are electrically connected through the fourth layer 114 .
- the connection portion 140 may not be provided with the fourth layer 114 .
- FIG. 12C shows an example in which the conductive layer 123 and the common electrode 115 are directly connected without the fourth layer 114 provided on the conductive layer 123 .
- regions where the fourth layer 114 and the common electrode 115 are formed can be changed.
- the fourth layer 114 includes the conductive layers 111a to 111e, the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and Contact with either side surface of the sixth layer 113e can be suppressed, and short-circuiting of the light emitting device and the light receiving device can be suppressed. Thereby, the reliability of the light-emitting device and the light-receiving device can be improved.
- the insulating layer 125 preferably covers at least side surfaces of the conductive layers 111a to 111e. Furthermore, the insulating layer 125 preferably covers the side surfaces of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e. The insulating layer 125 is in contact with side surfaces of the conductive layers 111a to 111e, the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e. can be configured.
- the insulating layer 127 is provided on the insulating layer 125 so as to fill the recess formed in the insulating layer 125 .
- the insulating layer 127 includes the conductive layers 111a to 111e, the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer with the insulating layer 125 interposed therebetween.
- 113e can be overlapped with each side surface (it can also be said that the side surface is covered).
- the space between adjacent island-shaped layers can be filled. can be made flatter. Therefore, it is possible to improve the coverage of the common electrode and prevent disconnection of the common electrode.
- the insulating layer 125 or the insulating layer 127 can be provided so as to be in contact with the island-shaped layer. This can prevent film peeling of the island-shaped layer. Adhesion between the insulating layer and the island-shaped layer has the effect of fixing or bonding the adjacent island-shaped layers by the insulating layer.
- An organic resin film is suitable for the insulating layer 127 .
- organic solvents and the like that may be contained in the photosensitive organic resin film may damage the EL layer.
- ALD atomic layer deposition
- one of the insulating layer 125 and the insulating layer 127 may be omitted.
- the insulating layer 125 by forming the insulating layer 125 with a single-layer structure using an inorganic material, the insulating layer 125 can be used as a protective insulating layer of the EL layer. Thereby, the reliability of the display device can be improved.
- the insulating layer 127 having a single-layer structure using an organic material the gap between the adjacent EL layers can be filled with the insulating layer 127 and planarized. Accordingly, the coverage of the common electrode (upper electrode) formed over the EL layer and the insulating layer 127 can be improved.
- FIG. 12A shows an example in which the insulating layer 125 is not provided.
- the insulating layer 127 includes the conductive layers 111a to 111e, the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer. It can be configured to be in contact with each side of the layer 113e.
- the insulating layer 127 can be provided so as to fill the space between the EL layers of each light-emitting device.
- the insulating layer 127 an organic material that causes little damage to the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e is used. is preferred.
- the insulating layer 127 is preferably made of an organic material such as polyvinyl alcohol (PVA), polyvinyl butyral, polyvinylpyrrolidone, polyethylene glycol, polyglycerin, pullulan, water-soluble cellulose, or alcohol-soluble polyamide resin.
- FIG. 12B shows an example in which the insulating layer 127 is not provided.
- the fourth layer 114 and the common electrode 115 are formed on the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, the sixth layer 113e, the insulating layer 125, and the insulating layer 127.
- a step is caused between a region where the pixel electrode and the EL layer are provided and a region where the pixel electrode and the EL layer are not provided (a region between the light emitting devices). ing.
- the step can be planarized, and coverage with the fourth layer 114 and the common electrode 115 can be improved. Therefore, it is possible to suppress poor connection due to disconnection. Alternatively, it is possible to prevent the common electrode 115 from being locally thinned due to a step and increasing the electrical resistance.
- the heights of the upper surface of the insulating layer 125 and the upper surface of the insulating layer 127 are adjusted to the heights of the first layer 113a and the second layer 113b, respectively. , third layer 113c, fifth layer 113d, and sixth layer 113e.
- the upper surface of the insulating layer 127 preferably has a flat shape, and may have a convex portion, a convex curved surface, a concave curved surface, or a concave portion.
- the insulating layer 125 has regions in contact with side surfaces of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e. , the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e.
- impurities oxygen, moisture, etc.
- a highly reliable display device can be obtained.
- the width (thickness) of the insulating layer 125 in the region in contact with the side surfaces of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e is If it is large, the gaps between the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e are increased, and the aperture ratio may be lowered. .
- the width (thickness) of the insulating layer 125 is small, the inner portions of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e are exposed from the sides. In some cases, the effect of suppressing the intrusion of impurities into the film becomes small.
- the width (thickness) of the insulating layer 125 in the region in contact with the side surfaces of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e is 3 nm or more.
- the display device can have a high aperture ratio and high reliability.
- Insulating layer 125 can be an insulating layer comprising an inorganic material.
- an inorganic insulating film such as an oxide insulating film, a nitride insulating film, an oxynitride insulating film, or a nitride oxide insulating film can be used, for example.
- the insulating layer 125 may have a single-layer structure or a laminated structure.
- the oxide insulating film includes a silicon oxide film, an aluminum oxide film, a magnesium oxide film, an indium gallium zinc oxide film, a gallium oxide film, a germanium oxide film, an yttrium oxide film, a zirconium oxide film, a lanthanum oxide film, a neodymium oxide film, and an oxide film.
- Examples include a hafnium film and a tantalum oxide film.
- Examples of the nitride insulating film include a silicon nitride film and an aluminum nitride film.
- As the oxynitride insulating film a silicon oxynitride film, an aluminum oxynitride film, or the like can be given.
- nitride oxide insulating film a silicon nitride oxide film, an aluminum nitride oxide film, or the like can be given.
- aluminum oxide is preferable because it has a high etching selectivity with respect to the EL layer and has a function of protecting the EL layer during formation of the insulating layer 127 described later.
- an inorganic insulating film such as an aluminum oxide film, a hafnium oxide film, or a silicon oxide film formed by an ALD method to the insulating layer 125, the insulating layer 125 with few pinholes and an excellent function of protecting the EL layer can be obtained. can be formed.
- the insulating layer 125 may have a layered structure of a film formed by an ALD method and a film formed by a sputtering method.
- the insulating layer 125 may have a laminated structure of, for example, an aluminum oxide film formed by ALD and a silicon nitride film formed by sputtering.
- oxynitride refers to a material whose composition contains more oxygen than nitrogen
- nitride oxide refers to a material whose composition contains more nitrogen than oxygen. point to the material.
- silicon oxynitride refers to a material whose composition contains more oxygen than nitrogen
- silicon nitride oxide refers to a material whose composition contains more nitrogen than oxygen. indicates
- the insulating layer 125 can be formed by a sputtering method, a chemical vapor deposition (CVD) method, a pulsed laser deposition (PLD) method, an ALD method, or the like.
- the insulating layer 125 is preferably formed by an ALD method with good coverage.
- the insulating layer 127 provided on the insulating layer 125 has a function of planarizing the concave portions of the insulating layer 125 formed between adjacent light emitting devices. In other words, the presence of the insulating layer 127 has the effect of improving the flatness of the surface on which the common electrode 115 is formed.
- an insulating layer containing an organic material can be preferably used.
- acrylic resin, polyimide resin, epoxy resin, imide resin, polyamide resin, polyimideamide resin, silicone resin, siloxane resin, benzocyclobutene-based resin, phenolic resin, and precursors of these resins are applied. can do.
- an organic material such as polyvinyl alcohol (PVA), polyvinyl butyral, polyvinylpyrrolidone, polyethylene glycol, polyglycerin, pullulan, water-soluble cellulose, or alcohol-soluble polyamide resin may be used for the insulating layer 127 .
- a photosensitive resin can be used as the insulating layer 127 .
- a photoresist may be used as the photosensitive resin.
- a positive material or a negative material can be used for the photosensitive resin.
- the height of the upper surface of the insulating layer 127 is preferably 0.5 times or less the thickness of the insulating layer 127, and more preferably 0.3 times or less.
- the upper surface of any one of the first layer 113a, the second layer 113b, the third layer 113c, the fifth layer 113d, and the sixth layer 113e is higher than the upper surface of the insulating layer 127.
- an insulating layer 127 may be provided.
- the insulating layer 127 may be provided so that the top surface of the insulating layer 127 is higher than the top surface of the light-emitting layer included in the first layer 113a, the second layer 113b, or the third layer 113c. good.
- a protective layer 131 on the light emitting devices 130a, 130b, 130c and the light receiving devices 150d, 150e.
- the conductivity of the protective layer 131 does not matter. At least one of an insulating film, a semiconductor film, and a conductive film can be used as the protective layer 131 .
- the protective layer 131 Since the protective layer 131 has an inorganic film, it prevents oxidation of the common electrode 115, suppresses the entry of impurities (moisture, oxygen, etc.) into the light-emitting devices 130a, 130b, 130c and the light-receiving devices 150d, 150e. Degradation of the light emitting device and the light receiving device can be suppressed, and the reliability of the display device can be improved.
- an inorganic insulating film such as an oxide insulating film, a nitride insulating film, an oxynitride insulating film, or a nitride oxide insulating film can be used.
- the oxide insulating film include a silicon oxide film, an aluminum oxide film, a gallium oxide film, a germanium oxide film, an yttrium oxide film, a zirconium oxide film, a lanthanum oxide film, a neodymium oxide film, a hafnium oxide film, a tantalum oxide film, and the like.
- nitride insulating film examples include a silicon nitride film and an aluminum nitride film.
- oxynitride insulating film a silicon oxynitride film, an aluminum oxynitride film, or the like can be given.
- nitride oxide insulating film a silicon nitride oxide film, an aluminum nitride oxide film, or the like can be given.
- the protective layer 131 preferably has a nitride insulating film or a nitride oxide insulating film, and more preferably has a nitride insulating film.
- the protective layer 131 includes In—Sn oxide (also referred to as ITO), In—Zn oxide, Ga—Zn oxide, Al—Zn oxide, or indium gallium zinc oxide (In—Ga—Zn oxide).
- Inorganic films containing materials such as IGZO can also be used.
- the inorganic film preferably has a high resistance, and specifically, preferably has a higher resistance than the common electrode 115 .
- the inorganic film may further contain nitrogen.
- the protective layer 131 When the light emitted from the light-emitting device is taken out through the protective layer 131, the protective layer 131 preferably has high transparency to visible light.
- the protective layer 131 preferably has high transparency to visible light.
- ITO, IGZO, and aluminum oxide are preferable because they are inorganic materials with high transparency to visible light.
- the protective layer 131 for example, a stacked structure of an aluminum oxide film and a silicon nitride film over the aluminum oxide film, or a stacked structure of an aluminum oxide film and an IGZO film over the aluminum oxide film, or the like can be used. can be done. By using the stacked structure, entry of impurities (water, oxygen, or the like) into the EL layer can be suppressed.
- the protective layer 131 may have an organic film.
- protective layer 131 may have both an organic film and an inorganic film.
- Edges of the upper surfaces of the conductive layers 111a to 111c are not covered with an insulating layer. Therefore, the interval between adjacent light emitting devices can be made very narrow. Therefore, a high-definition or high-resolution display device can be obtained.
- each end of the conductive layers 111a to 111c may be covered with an insulating layer 121.
- FIG. 13A and 13B each end of the conductive layers 111a to 111c may be covered with an insulating layer 121.
- the insulating layer 121 can have a single-layer structure or a laminated structure using one or both of an inorganic insulating film and an organic insulating film.
- organic insulating materials that can be used for the insulating layer 121 include acrylic resins, epoxy resins, polyimide resins, polyamide resins, polyimideamide resins, polysiloxane resins, benzocyclobutene resins, and phenol resins.
- an inorganic insulating film that can be used for the insulating layer 121 an inorganic insulating film that can be used for the protective layer 131 can be used.
- an inorganic insulating film is used as the insulating layer 121 covering the edge of the pixel electrode, impurities are less likely to enter the light-emitting device than when an organic insulating film is used, and the reliability of the light-emitting device can be improved.
- the step coverage is higher and the shape of the pixel electrode is less likely to affect the step coverage than when an inorganic insulating film is used. Therefore, short-circuiting of the light emitting device can be prevented.
- the shape of the insulating layer 121 can be processed into a tapered shape or the like.
- a tapered shape refers to a shape in which at least part of a side surface of a structure is inclined with respect to a substrate surface or a formation surface.
- the insulating layer 121 may not be provided. By not providing the insulating layer 121, the aperture ratio of the sub-pixel can be increased in some cases. Alternatively, the distance between sub-pixels can be reduced, which may increase the definition or resolution of the display.
- FIG. 13A shows an example in which the fourth layer 114 enters the regions of the first layer 113a and the second layer 113b, etc., but as shown in FIG. may be
- the voids 134 contain, for example, one or more selected from air, nitrogen, oxygen, carbon dioxide, and group 18 elements (typically helium, neon, argon, xenon, krypton, etc.). Alternatively, the gap 134 may be filled with resin or the like.
- FIG. 11B and the like show examples in which the end portions of the conductive layer 111a and the end portions of the first layer 113a are aligned or substantially aligned.
- the top surface shapes of the conductive layer 111a and the first layer 113a match or substantially match.
- FIG. 14A shows an example in which the end of the first layer 113a is located inside the end of the conductive layer 111a. In FIG. 14A, the edge of the first layer 113a is located on the conductive layer 111a. Also, FIG. 14B shows an example in which the end of the first layer 113a is located outside the end of the conductive layer 111a. In FIG. 14B, the first layer 113a is provided to cover the end of the conductive layer 111a.
- the ends are aligned or substantially aligned, and when the top surface shapes are matched or substantially matched, at least part of the outline overlaps between the stacked layers when viewed from the top.
- the upper layer and the lower layer may be processed with the same mask pattern or partially with the same mask pattern.
- the outlines do not overlap, and the top layer may be located inside the bottom layer, or the top layer may be located outside the bottom layer, and in this case also the edges are roughly aligned, or the shape of the top surface are said to roughly match.
- FIG. 14C A modification of the insulating layer 127 is shown in FIG. 14C.
- the upper surface of the insulating layer 127 has a shape that gently swells toward the center, that is, a convex curved surface, and a shape that is depressed at and near the center, that is, a concave curved surface, in a cross-sectional view.
- 15A to 15F show cross-sectional structures of a region 139 including the insulating layer 127 and its periphery.
- FIG. 15A shows an example in which the first layer 113a and the second layer 113b have different thicknesses.
- the height of the top surface of the insulating layer 125 matches or substantially matches the height of the top surface of the first layer 113a on the side of the first layer 113a, and the height of the top surface of the second layer 113b on the side of the second layer 113b. Matches or roughly matches height.
- the upper surface of the insulating layer 127 has a gentle slope with a higher surface on the side of the first layer 113a and a lower surface on the side of the second layer 113b.
- the insulating layers 125 and 127 may have flat portions that are level with the top surface of any of the adjacent EL layers.
- the top surface of the insulating layer 127 has a region higher than the top surface of the first layer 113a and the top surface of the second layer 113b.
- the upper surface of the insulating layer 127 can be configured to have a shape in which the center and the vicinity thereof bulge in a cross-sectional view, that is, have a convex curved surface.
- the upper surface of the insulating layer 127 has a shape that gently swells toward the center, that is, a convex curved surface, and a shape that is depressed at and near the center, that is, a concave curved surface, in a cross-sectional view.
- the insulating layer 127 has a region higher than the upper surface of the first layer 113a and the upper surface of the second layer 113b.
- the display device includes at least one of the sacrificial layer 118a and the sacrificial layer 119a, the insulating layer 127 is higher than the top surface of the first layer 113a and the top surface of the second layer 113b, and the insulating layer 125 It has a first region located outside the sacrificial layer 118a and the first region located on at least one of the sacrificial layer 118a and the sacrificial layer 119a.
- the display device has at least one of the sacrificial layer 118b and the sacrificial layer 119b, the insulating layer 127 is higher than the top surface of the first layer 113a and the top surface of the second layer 113b, and the insulating layer 125
- the second region is located outside the sacrificial layer 118b and the second region is located on at least one of the sacrificial layer 118b and the sacrificial layer 119b.
- the top surface of insulating layer 127 has a region that is lower than the top surface of first layer 113a and the top surface of second layer 113b.
- the upper surface of the insulating layer 127 has a shape in which the center and its vicinity are depressed in a cross-sectional view, that is, has a concave curved surface.
- the top surface of the insulating layer 125 has a higher area than the top surface of the first layer 113a and the top surface of the second layer 113b. That is, the insulating layer 125 protrudes from the formation surface of the fourth layer 114 to form a convex portion.
- the insulating layer 125 may protrude as shown in FIG. 15E. be.
- the top surface of the insulating layer 125 has a region that is lower than the top surface of the first layer 113a and the top surface of the second layer 113b. That is, the insulating layer 125 forms a concave portion on the formation surface of the fourth layer 114 .
- various shapes can be applied to the insulating layers 125 and 127 .
- an inorganic film such as a metal film, an alloy film, a metal oxide film, a semiconductor film, or an inorganic insulating film can be used.
- the sacrificial layer includes metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, titanium, aluminum, yttrium, zirconium, and tantalum, or the metal materials.
- metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, titanium, aluminum, yttrium, zirconium, and tantalum, or the metal materials.
- a metal oxide such as an In--Ga--Zn oxide can be used for the sacrificial layer.
- the sacrificial layer for example, an In--Ga--Zn oxide film can be formed using a sputtering method.
- indium oxide, In-Zn oxide, In-Sn oxide, indium titanium oxide (In-Ti oxide), indium tin zinc oxide (In-Sn-Zn oxide), indium titanium zinc oxide ( In--Ti--Zn oxide), indium gallium tin-zinc oxide (In--Ga--Sn--Zn oxide), or the like can be used.
- indium tin oxide containing silicon or the like can be used.
- element M is aluminum, silicon, boron, yttrium, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten , or one or more selected from magnesium
- M is aluminum, silicon, boron, yttrium, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten , or one or more selected from magnesium
- various inorganic insulating films that can be used for the protective layer 131 can be used as the sacrificial layer.
- an oxide insulating film is preferable because it has higher adhesion to the EL layer than a nitride insulating film.
- inorganic insulating materials such as aluminum oxide, hafnium oxide, and silicon oxide can be used for the sacrificial layer.
- an aluminum oxide film can be formed using the ALD method. Use of the ALD method is preferable because damage to the base (especially the EL layer or the like) can be reduced.
- a silicon nitride film can be formed using a sputtering method.
- a lamination structure of an inorganic insulating film (eg, an aluminum oxide film) formed by an ALD method and an In—Ga—Zn oxide film formed by a sputtering method can be used as the sacrificial layer.
- an inorganic insulating film (eg, aluminum oxide film) formed by an ALD method and an aluminum film, a tungsten film, or an inorganic insulating film (eg, a silicon nitride film) formed by a sputtering method are used as the sacrificial layer. , can be applied.
- a device manufactured using a metal mask or FMM may be referred to as a device with an MM (metal mask) structure.
- a device manufactured without using a metal mask or FMM may be referred to as a device with an MML (metal maskless) structure.
- SBS Side By Side
- the material and structure can be optimized for each light-emitting device, so the degree of freedom in selecting the material and structure increases, and it becomes easy to improve luminance and reliability.
- a light-emitting device capable of emitting white light is sometimes referred to as a white light-emitting device.
- a white light emitting device can be combined with a colored layer (for example, a color filter) to realize a full-color display device.
- light-emitting devices can be broadly classified into a single structure and a tandem structure.
- a single-structure device preferably has one light-emitting unit between a pair of electrodes, and the light-emitting unit preferably includes one or more light-emitting layers.
- light-emitting layers may be selected such that the colors of light emitted from the two light-emitting layers are in a complementary color relationship. For example, by making the luminescent color of the first luminescent layer and the luminescent color of the second luminescent layer have a complementary color relationship, it is possible to obtain a configuration in which the entire light emitting device emits white light.
- the light-emitting device as a whole may emit white light by combining the light-emitting colors of the three or more light-emitting layers.
- a device with a tandem structure preferably has two or more light-emitting units between a pair of electrodes, and each light-emitting unit includes one or more light-emitting layers.
- each light-emitting unit includes one or more light-emitting layers.
- a structure in which white light emission is obtained by combining light from the light emitting layers of a plurality of light emitting units may be employed. Note that the structure for obtaining white light emission is the same as the structure of the single structure. Note that in a tandem structure device, it is preferable to provide a charge generation layer between a plurality of light emitting units.
- the white light emitting device when comparing the white light emitting device (single structure or tandem structure) and the light emitting device having the SBS structure, the light emitting device having the SBS structure can consume less power than the white light emitting device. If it is desired to keep power consumption low, it is preferable to use a light-emitting device with an SBS structure. On the other hand, the white light emitting device is preferable because the manufacturing process is simpler than that of the SBS structure light emitting device, so that the manufacturing cost can be lowered or the manufacturing yield can be increased.
- the distance between the light-emitting devices can be reduced.
- the distance between light-emitting devices, the distance between EL layers, or the distance between pixel electrodes is less than 10 ⁇ m, 5 ⁇ m or less, 3 ⁇ m or less, 2 ⁇ m or less, 1 ⁇ m or less, 500 nm or less, 200 nm or less, 100 nm or less, or 90 nm or less. , 70 nm or less, 50 nm or less, 30 nm or less, 20 nm or less, 15 nm or less, or 10 nm or less.
- the space between the side surface of the first layer 113a and the side surface of the second layer 113b or the space between the side surface of the second layer 113b and the side surface of the third layer 113c is 1 ⁇ m or less. , preferably has a region of 0.5 ⁇ m (500 nm) or less, and more preferably has a region of 100 nm or less.
- the distance between the light-emitting device and the light-receiving device can also be within the above range. Also, in order to suppress leakage between the light emitting device and the light receiving device, it is preferable to make the distance between the light emitting device and the light receiving device wider than the distance between the light emitting devices. For example, the distance between the light emitting device and the light receiving device can be 8 ⁇ m or less, 5 ⁇ m or less, or 3 ⁇ m or less.
- a light shielding layer may be provided on the surface of the substrate 120 on the resin layer 122 side.
- various optical members can be arranged outside the substrate 120 .
- optical members include polarizing plates, retardation plates, light diffusion layers (diffusion films, etc.), antireflection layers, light collecting films, and the like.
- an antistatic film that suppresses adhesion of dust, a water-repellent film that prevents adhesion of dirt, a hard coat film that suppresses the occurrence of scratches due to use, a shock absorption layer, etc. are arranged on the outside of the substrate 120.
- an antistatic film that suppresses adhesion of dust
- a water-repellent film that prevents adhesion of dirt
- a hard coat film that suppresses the occurrence of scratches due to use
- a shock absorption layer, etc. are arranged.
- Glass, quartz, ceramic, sapphire, resin, metal, alloy, semiconductor, or the like can be used for the substrate 120 .
- a material that transmits the light is used for the substrate on the side from which the light from the light-emitting device is extracted.
- a flexible material is used for the substrate 120, the flexibility of the display device can be increased and a flexible display can be realized.
- a polarizing plate may be used as the substrate 120 .
- polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyacrylonitrile resins, acrylic resins, polyimide resins, polymethyl methacrylate resins, polycarbonate (PC) resins, and polyethersulfone (PES) resins.
- polyamide resin nylon, aramid, etc.
- polysiloxane resin cycloolefin resin
- polystyrene resin polyamideimide resin
- polyurethane resin polyvinyl chloride resin
- polyvinylidene chloride resin polypropylene resin
- PTFE polytetrafluoroethylene
- ABS resin cellulose nanofiber, etc.
- glass having a thickness that is flexible may be used.
- a substrate having high optical isotropy is preferably used as the substrate of the display device.
- a substrate with high optical isotropy has small birefringence (it can be said that the amount of birefringence is small).
- the absolute value of the retardation (retardation) value of the substrate with high optical isotropy is preferably 30 nm or less, more preferably 20 nm or less, and even more preferably 10 nm or less.
- Films with high optical isotropy include triacetylcellulose (TAC, also called cellulose triacetate) films, cycloolefin polymer (COP) films, cycloolefin copolymer (COC) films, and acrylic films.
- TAC triacetylcellulose
- COP cycloolefin polymer
- COC cycloolefin copolymer
- the film when a film is used as the substrate, the film may absorb water, which may cause a change in shape such as wrinkling of the display panel. Therefore, it is preferable to use a film having a low water absorption rate as the substrate. For example, it is preferable to use a film with a water absorption of 1% or less, more preferably 0.1% or less, and even more preferably 0.01% or less.
- various curable adhesives such as photocurable adhesives such as ultraviolet curable adhesives, reaction curable adhesives, thermosetting adhesives, and anaerobic adhesives can be used.
- These adhesives include epoxy resins, acrylic resins, silicone resins, phenol resins, polyimide resins, imide resins, PVC (polyvinyl chloride) resins, PVB (polyvinyl butyral) resins, EVA (ethylene vinyl acetate) resins, and the like.
- a material with low moisture permeability such as epoxy resin is preferable.
- a two-liquid mixed type resin may be used.
- an adhesive sheet or the like may be used.
- materials that can be used for conductive layers such as various wirings and electrodes constituting display devices include aluminum, titanium, chromium, nickel, copper, yttrium, zirconium, molybdenum, silver, Examples include metals such as tantalum and tungsten, and alloys containing these metals as main components. A film containing these materials can be used as a single layer or as a laminated structure.
- a conductive oxide such as indium oxide, indium tin oxide, indium zinc oxide, zinc oxide, zinc oxide containing gallium, or graphene
- metal materials such as gold, silver, platinum, magnesium, nickel, tungsten, chromium, molybdenum, iron, cobalt, copper, palladium, and titanium, or alloy materials containing such metal materials can be used.
- a nitride of the metal material eg, titanium nitride
- it is preferably thin enough to have translucency.
- a stacked film of any of the above materials can be used as the conductive layer.
- a laminated film of a silver-magnesium alloy and indium tin oxide because the conductivity can be increased.
- conductive layers such as various wirings and electrodes that constitute a display device, and conductive layers (conductive layers functioning as pixel electrodes or common electrodes) of light-emitting devices.
- Examples of insulating materials that can be used for each insulating layer include resins such as acrylic resins and epoxy resins, and inorganic insulating materials such as silicon oxide, silicon oxynitride, silicon nitride oxide, silicon nitride, and aluminum oxide.
- a conductive film that transmits visible light and infrared light is used for the electrode on the light extraction side of the pixel electrode and the common electrode.
- a conductive film that reflects visible light and infrared light is preferably used for the electrode on the side from which light is not extracted.
- metals, alloys, electrically conductive compounds, mixtures thereof, and the like can be used as appropriate.
- indium tin oxide also referred to as In—Sn oxide, ITO
- In—Si—Sn oxide also referred to as ITSO
- indium zinc oxide In—Zn oxide
- In—W— Zn oxide alloys containing aluminum (aluminum alloys) such as alloys of aluminum, nickel and lanthanum (Al-Ni-La), as well as alloys of silver and magnesium, alloys of silver, palladium and copper (Ag-Pd- Cu, also referred to as APC) and other silver-containing alloys.
- elements belonging to Group 1 or Group 2 of the periodic table of elements not exemplified above e.g., lithium (Li), cesium (Cs), calcium (Ca), strontium (Sr)), europium (Eu), ytterbium
- Yb rare earth metal
- an alloy containing an appropriate combination thereof, graphene, or the like can be used.
- a micro optical resonator (microcavity) structure is preferably applied to the light emitting device and the light receiving device. Therefore, one of the pair of electrodes included in the light-emitting device and the light-receiving device preferably has an electrode (semi-transmissive/semi-reflective electrode) that is transparent and reflective to visible light, and the other is reflective to visible light. It is preferable to have an electrode (reflective electrode) having a Since the light-emitting device has a microcavity structure, the light emitted from the light-emitting layer can be resonated between both electrodes, and the light emitted from the light-emitting device can be enhanced. Since the light receiving device has a microcavity structure, the light received by the active layer can be resonated between the two electrodes, the light can be strengthened, and the detection accuracy of the light receiving device can be improved.
- the semi-transmissive/semi-reflective electrode can have a laminated structure of a reflective electrode and an electrode (also referred to as a transparent electrode) having transparency to visible light.
- the light transmittance of the transparent electrode is set to 40% or more.
- the light-emitting device preferably uses an electrode having a transmittance of 40% or more for visible light (light with a wavelength of 400 nm or more and less than 750 nm).
- the visible light reflectance of the semi-transmissive/semi-reflective electrode is 10% or more and 95% or less, preferably 30% or more and 80% or less.
- the visible light reflectance of the reflective electrode is 40% or more and 100% or less, preferably 70% or more and 100% or less.
- the resistivity of these electrodes is preferably 1 ⁇ 10 ⁇ 2 ⁇ cm or less.
- the transmittance or reflectance of near-infrared light (light having a wavelength of 750 nm or more and 1300 nm or less) of these electrodes preferably satisfies the above numerical range, similarly to the transmittance or reflectance of visible light.
- the first layer 113a, the second layer 113b, and the third layer 113c each have a light-emitting layer.
- the first layer 113a, the second layer 113b, and the third layer 113c preferably have light-emitting layers that emit light of different colors.
- a light-emitting layer is a layer containing a light-emitting substance.
- the emissive layer can have one or more emissive materials.
- a substance exhibiting emission colors such as blue, purple, violet, green, yellow-green, yellow, orange, and red is used as appropriate.
- a substance that emits near-infrared light can be used as the light-emitting substance.
- Examples of light-emitting substances include fluorescent materials, phosphorescent materials, thermally activated delayed fluorescence (TADF) materials, and quantum dot materials.
- fluorescent materials include fluorescent materials, phosphorescent materials, thermally activated delayed fluorescence (TADF) materials, and quantum dot materials.
- TADF thermally activated delayed fluorescence
- fluorescent materials include pyrene derivatives, anthracene derivatives, triphenylene derivatives, fluorene derivatives, carbazole derivatives, dibenzothiophene derivatives, dibenzofuran derivatives, dibenzoquinoxaline derivatives, quinoxaline derivatives, pyridine derivatives, pyrimidine derivatives, phenanthrene derivatives, and naphthalene derivatives. be done.
- Examples of phosphorescent materials include organometallic complexes (especially iridium complexes) having a 4H-triazole skeleton, 1H-triazole skeleton, imidazole skeleton, pyrimidine skeleton, pyrazine skeleton, or pyridine skeleton, and phenylpyridine derivatives having an electron-withdrawing group.
- organometallic complexes especially iridium complexes
- platinum complexes, rare earth metal complexes, etc. which are used as ligands, can be mentioned.
- the light-emitting layer may contain one or more organic compounds (host material, assist material, etc.) in addition to the light-emitting substance (guest material).
- One or both of a hole-transporting material and an electron-transporting material can be used as the one or more organic compounds.
- Bipolar materials or TADF materials may also be used as one or more organic compounds.
- the light-emitting layer preferably includes, for example, a phosphorescent material and a combination of a hole-transporting material and an electron-transporting material that easily form an exciplex.
- ExTET Exciplex-Triplet Energy Transfer
- a combination that forms an exciplex that emits light that overlaps with the wavelength of the absorption band on the lowest energy side of the light-emitting substance energy transfer becomes smooth and light emission can be efficiently obtained. With this configuration, high efficiency, low-voltage driving, and long life of the light-emitting device can be realized at the same time.
- the first layer 113a, the second layer 113b, and the third layer 113c are layers other than the light-emitting layer, which are a substance with a high hole-injection property and a substance with a high hole-transport property (also called a hole-transport material). ), hole-blocking material, highly electron-transporting substance (also referred to as electron-transporting material), highly electron-injecting substance, electron-blocking material, or bipolar substance (highly electron- and hole-transporting It may further have a layer containing a substance (also referred to as a bipolar material).
- Both low-molecular-weight compounds and high-molecular-weight compounds can be used in the light-emitting device, and inorganic compounds may be included.
- Each of the layers constituting the light-emitting device can be formed by a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, a coating method, or the like.
- the first layer 113a, the second layer 113b, and the third layer 113c are respectively a hole-injecting layer, a hole-transporting layer, a hole-blocking layer, an electron-blocking layer, an electron-transporting layer, and an electron layer. It may have one or more of the injection layers. Further, each of the first layer 113a, the second layer 113b, and the third layer 113c may have a charge generation layer.
- the fourth layer 114 can have one or more of a hole injection layer, a hole transport layer, a hole blocking layer, an electron blocking layer, an electron transport layer, and an electron injection layer.
- the fourth layer 114 preferably has an electron-injection layer.
- the hole-injecting layer is a layer that injects holes from the anode to the hole-transporting layer, and contains a substance having a high hole-injecting property.
- Substances with high hole-injection properties include aromatic amine compounds and composite materials containing a hole-transporting material and an acceptor material (electron-accepting material).
- a hole-transporting layer is a layer that transports holes injected from the anode by the hole-injecting layer to the light-emitting layer.
- the hole-transporting layer is a layer that transports holes generated by incident light in the active layer to the anode.
- a hole-transporting layer is a layer containing a hole-transporting material.
- the hole-transporting material a substance having a hole mobility of 1 ⁇ 10 ⁇ 6 cm 2 /Vs or more is preferable. Note that substances other than these can be used as long as they have a higher hole-transport property than electron-transport property.
- hole-transporting materials include ⁇ -electron-rich heteroaromatic compounds (e.g., carbazole derivatives, thiophene derivatives, furan derivatives, etc.), aromatic amines (compounds having an aromatic amine skeleton), and other substances with high hole-transporting properties. is preferred.
- ⁇ -electron-rich heteroaromatic compounds e.g., carbazole derivatives, thiophene derivatives, furan derivatives, etc.
- aromatic amines compounds having an aromatic amine skeleton
- other substances with high hole-transporting properties is preferred.
- an electron-transporting layer is a layer that transports electrons injected from the cathode by the electron-injecting layer to the light-emitting layer.
- the electron transport layer is a layer that transports electrons generated by incident light in the active layer to the cathode.
- the electron-transporting layer is a layer containing an electron-transporting material.
- an electron-transporting material a substance having an electron mobility of 1 ⁇ 10 ⁇ 6 cm 2 /Vs or more is preferable. Note that substances other than these substances can be used as long as they have a higher electron-transport property than hole-transport property.
- electron-transporting materials include metal complexes having a quinoline skeleton, metal complexes having a benzoquinoline skeleton, metal complexes having an oxazole skeleton, metal complexes having a thiazole skeleton, oxadiazole derivatives, triazole derivatives, imidazole derivatives, ⁇ -electrons including oxazole derivatives, thiazole derivatives, phenanthroline derivatives, quinoline derivatives with quinoline ligands, benzoquinoline derivatives, quinoxaline derivatives, dibenzoquinoxaline derivatives, pyridine derivatives, bipyridine derivatives, pyrimidine derivatives, and other nitrogen-containing heteroaromatic compounds
- a substance having a high electron-transport property such as a deficient heteroaromatic compound can be used.
- the electron injection layer is a layer that injects electrons from the cathode to the electron transport layer, and is a layer that contains a substance with high electron injection properties.
- Alkali metals, alkaline earth metals, or compounds thereof can be used as the substance with a high electron-injecting property.
- a composite material containing an electron-transporting material and a donor material (electron-donating material) can also be used as the substance with high electron-injecting properties.
- the electron injection layer examples include lithium, cesium, ytterbium, lithium fluoride (LiF), cesium fluoride (CsF), calcium fluoride (CaF 2 ), 8-(quinolinolato)lithium (abbreviation: Liq), 2- (2-pyridyl)phenoratritium (abbreviation: LiPP), 2-(2-pyridyl)-3-pyridinolatritium (abbreviation: LiPPy), 4-phenyl-2-(2-pyridyl)phenoratritium (abbreviation: LiPPy) LiPPP), lithium oxide (LiO x ), alkali metals such as cesium carbonate, alkaline earth metals, or compounds thereof can be used.
- the electron injection layer may have a laminated structure of two or more layers. As the laminated structure, for example, lithium fluoride can be used for the first layer and ytterbium can be used for the second layer.
- an electron-transporting material may be used as the electron injection layer.
- a compound having a lone pair of electrons and an electron-deficient heteroaromatic ring can be used as the electron-transporting material.
- a compound having at least one of a pyridine ring, diazine ring (pyrimidine ring, pyrazine ring, pyridazine ring), and triazine ring can be used.
- the lowest unoccupied molecular orbital (LUMO) of the organic compound having an unshared electron pair is preferably ⁇ 3.6 eV or more and ⁇ 2.3 eV or less.
- CV cyclic voltammetry
- photoelectron spectroscopy optical absorption spectroscopy
- inverse photoelectron spectroscopy etc. are used to determine the highest occupied molecular orbital (HOMO: Highest Occupied Molecular Orbital) level and LUMO level of an organic compound. can be estimated.
- BPhen 4,7-diphenyl-1,10-phenanthroline
- NBPhen 2,9-bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline
- HATNA diquinoxalino [2,3-a:2′,3′-c]phenazine
- TmPPPyTz 2,4,6-tris[3′-(pyridin-3-yl)biphenyl-3-yl]-1,3 , 5-triazine
- TmPPPyTz 2,4,6-tris[3′-(pyridin-3-yl)biphenyl-3-yl]-1,3 , 5-triazine
- a material applicable to an electron injection layer such as lithium
- a material applicable to the hole injection layer can be preferably used.
- a layer containing a hole-transporting material and an acceptor material (electron-accepting material) can be used as the charge-generating layer.
- a layer containing an electron-transporting material and a donor material can be used for the charge generation layer.
- the fifth layer 113d and the sixth layer 113e each have an active layer.
- the fifth layer 113d and the sixth layer 113e may have active layers with the same configuration or may have active layers with different configurations.
- the light-receiving device has a microcavity structure
- light of different wavelengths can be detected between the fifth layer 113d and the sixth layer 113e even if the configuration of the active layer is the same.
- a microcavity structure can be produced by changing the thickness of the pixel electrode or the thickness of the optical adjustment layer in the light receiving devices 150d and 150e.
- the fifth layer 113d and the sixth layer 113e may have the same configuration.
- the active layer contains a semiconductor.
- the semiconductor include inorganic semiconductors such as silicon and organic semiconductors including organic compounds.
- an organic semiconductor is used as the semiconductor included in the active layer.
- the light-emitting layer and the active layer can be formed by the same method (for example, a vacuum deposition method), and a manufacturing apparatus can be shared, which is preferable.
- Electron-accepting organic semiconductor materials such as fullerenes ( eg, C60 fullerene, C70 fullerene, etc.) and fullerene derivatives can be used as n-type semiconductor materials for the active layer.
- Fullerenes have a soccer ball-like shape, which is energetically stable.
- Fullerene has both deep (low) HOMO and LUMO levels. Since fullerene has a deep LUMO level, it has an extremely high electron-accepting property (acceptor property).
- acceptor property electron-acceptor property
- C60 fullerene and C70 fullerene have a wide absorption band in the visible light region, and C70 is particularly preferable because it has a larger ⁇ -electron conjugated system than C60 and has a wide absorption band in the long wavelength region.
- [6,6]-Phenyl-C71- butylic acid methyl ester (abbreviation: PC70 BM), [6,6]-Phenyl-C61- butylic acid methyl ester (abbreviation: PC60 BM), 1′,1′′,4′,4′′-Tetrahydro-di[1,4]methanonaphthaleno[1,2:2′,3′,56,60:2′′,3′′][ 5,6]fullerene-C60 ( abbreviation: ICBA) and the like.
- PC70 BM [6,6]-Phenyl-C71- butylic acid methyl ester
- PC60 BM [6,6]-Phenyl-C61- butylic acid methyl ester
- ICBA 1,6]fullerene-C60
- Materials for the n-type semiconductor include metal complexes having a quinoline skeleton, metal complexes having a benzoquinoline skeleton, metal complexes having an oxazole skeleton, metal complexes having a thiazole skeleton, oxadiazole derivatives, triazole derivatives, imidazole derivatives, Oxazole derivatives, thiazole derivatives, phenanthroline derivatives, quinoline derivatives, benzoquinoline derivatives, quinoxaline derivatives, dibenzoquinoxaline derivatives, pyridine derivatives, bipyridine derivatives, pyrimidine derivatives, naphthalene derivatives, anthracene derivatives, coumarin derivatives, rhodamine derivatives, triazine derivatives, quinone derivatives, etc. is mentioned.
- Materials for the p-type semiconductor of the active layer include copper (II) phthalocyanine (CuPc), tetraphenyldibenzoperiflanthene (DBP), zinc phthalocyanine (ZnPc), tin ( II) electron-donating organic semiconductor materials such as phthalocyanine (SnPc) and quinacridone;
- Examples of p-type semiconductor materials include carbazole derivatives, thiophene derivatives, furan derivatives, and compounds having an aromatic amine skeleton.
- materials for p-type semiconductors include naphthalene derivatives, anthracene derivatives, pyrene derivatives, triphenylene derivatives, fluorene derivatives, pyrrole derivatives, benzofuran derivatives, benzothiophene derivatives, indole derivatives, dibenzofuran derivatives, dibenzothiophene derivatives, indolocarbazole derivatives, porphyrin derivatives, phthalocyanine derivatives, naphthalocyanine derivatives, quinacridone derivatives, polyphenylenevinylene derivatives, polyparaphenylene derivatives, polyfluorene derivatives, polyvinylcarbazole derivatives, polythiophene derivatives and the like.
- the HOMO level of the electron-donating organic semiconductor material is preferably shallower (higher) than the HOMO level of the electron-accepting organic semiconductor material.
- the LUMO level of the electron-donating organic semiconductor material is preferably shallower (higher) than the LUMO level of the electron-accepting organic semiconductor material.
- a spherical fullerene as the electron-accepting organic semiconductor material and an organic semiconductor material having a nearly planar shape as the electron-donating organic semiconductor material. Molecules with similar shapes tend to gather together, and when molecules of the same type aggregate, the energy levels of the molecular orbitals are close to each other, so the carrier transportability can be enhanced.
- the active layer is preferably formed by co-depositing an n-type semiconductor and a p-type semiconductor.
- the active layer may be formed by laminating an n-type semiconductor and a p-type semiconductor.
- the fifth layer 113d and the sixth layer 113e are layers other than the active layer, which are highly hole-transporting substances, electron-transporting substances, or bipolar substances (electron-transporting and hole-transporting substances). It may further have a layer containing, for example, a substance with a high degree of resistance.
- the fifth layer 113d and the sixth layer 113e may have various functional layers that can be used for the first layer 113a, the second layer 113b, and the third layer 113c. good.
- Either a low-molecular-weight compound or a high-molecular-weight compound can be used for the light-receiving device, and an inorganic compound may be included.
- the layers constituting the light-receiving device can be formed by methods such as a vapor deposition method (including a vacuum vapor deposition method), a transfer method, a printing method, an inkjet method, and a coating method.
- hole-transporting materials include polymer compounds such as poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonic acid) (PEDOT/PSS), molybdenum oxide, and copper iodide (CuI).
- Inorganic compounds such as can be used.
- an inorganic compound such as zinc oxide (ZnO) can be used as the electron-transporting material.
- 6-diyl]-2,5-thiophenediyl[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c′]dithiophene-1 ,3-diyl]]polymer (abbreviation: PBDB-T) or a polymer compound such as a PBDB-T derivative can be used.
- a method of dispersing an acceptor material in PBDB-T or a PBDB-T derivative can be used.
- three or more kinds of materials may be mixed in the active layer.
- a third material may be mixed in addition to the n-type semiconductor material and the p-type semiconductor material.
- the third material may be a low-molecular compound or a high-molecular compound.
- a thin film (an insulating film, a semiconductor film, a conductive film, or the like) forming a display device can be formed using a sputtering method, a CVD method, a vacuum deposition method, a PLD method, an ALD method, or the like.
- CVD methods include a plasma enhanced CVD (PECVD) method, a thermal CVD method, and the like. Also, one of the thermal CVD methods is the metal organic CVD (MOCVD) method.
- the thin films (insulating film, semiconductor film, conductive film, etc.) that make up the display device can be applied by spin coating, dipping, spray coating, inkjet, dispensing, screen printing, offset printing, doctor knife, slit coating, roll coating, It can be formed by methods such as curtain coating and knife coating.
- a vacuum process such as a vapor deposition method and a solution process such as a spin coating method or an inkjet method can be used for manufacturing a light-emitting device.
- vapor deposition methods include physical vapor deposition (PVD) such as sputtering, ion plating, ion beam vapor deposition, molecular beam vapor deposition, and vacuum vapor deposition, and chemical vapor deposition (CVD).
- the functional layers (hole injection layer, hole transport layer, light emitting layer, electron transport layer, electron injection layer, etc.) included in the EL layer may be formed by a vapor deposition method (vacuum vapor deposition method, etc.), a coating method (dip coating method, die coat method, bar coat method, spin coat method, spray coat method, etc.), printing method (inkjet method, screen (stencil printing) method, offset (lithographic printing) method, flexographic (letterpress printing) method, gravure method, or micro contact method, etc.).
- a vapor deposition method vacuum vapor deposition method, etc.
- a coating method dip coating method, die coat method, bar coat method, spin coat method, spray coat method, etc.
- printing method inkjet method, screen (stencil printing) method, offset (lithographic printing) method, flexographic (letterpress printing) method, gravure method, or micro contact method, etc.
- a photolithography method or the like can be used when processing a thin film forming a display device.
- the thin film may be processed by a nanoimprint method, a sandblast method, a lift-off method, or the like.
- an island-shaped thin film may be directly formed by a film formation method using a shielding mask such as a metal mask.
- the photolithography method there are typically the following two methods.
- One is a method of forming a resist mask on a thin film to be processed, processing the thin film by etching or the like, and removing the resist mask.
- the other is a method of forming a photosensitive thin film, then performing exposure and development to process the thin film into a desired shape.
- the light used for exposure can be, for example, i-line (wavelength 365 nm), g-line (wavelength 436 nm), h-line (wavelength 405 nm), or a mixture thereof.
- ultraviolet rays, KrF laser light, ArF laser light, or the like can also be used.
- extreme ultraviolet (EUV: Extreme Ultra-violet) light or X-rays may be used.
- An electron beam can also be used instead of the light used for exposure. The use of extreme ultraviolet light, X-rays, or electron beams is preferable because extremely fine processing is possible.
- a photomask is not necessary when exposure is performed by scanning a beam such as an electron beam.
- a dry etching method, a wet etching method, a sandblasting method, or the like can be used for etching the thin film.
- the island-shaped EL layer is not formed using a fine metal mask, but is formed by forming an EL layer over one surface and then processing the EL layer. Therefore, island-shaped EL layers can be formed with a uniform thickness.
- each EL layer can be manufactured with a configuration (material, film thickness, etc.) suitable for each color light-emitting device. Thereby, a light-emitting device with good characteristics can be produced.
- the display device of this embodiment can be a high-resolution display device or a large-sized display device. Therefore, the display device of the present embodiment includes a relatively large screen such as a television device, a desktop or notebook personal computer, a computer monitor, a digital signage, a large game machine such as a pachinko machine, or the like. In addition to electronic devices, it can be used for display portions of digital cameras, digital video cameras, digital photo frames, mobile phones, portable game machines, personal digital assistants, and sound reproducing devices.
- FIG. 16 shows a perspective view of the display device 100F
- FIG. 17A shows a cross-sectional view of the display device 100F.
- the display device 100F has a configuration in which a substrate 152 and a substrate 151 are bonded together.
- the substrate 152 is clearly indicated by dashed lines.
- the display device 100F includes a display portion 162, a connection portion 140, a circuit 164, wirings 165, and the like.
- FIG. 16 shows an example in which an IC 173 and an FPC 172 are mounted on the display device 100F. Therefore, the configuration shown in FIG. 16 can also be said to be a display module including the display device 100F, an IC (integrated circuit), and an FPC.
- the connecting portion 140 is provided outside the display portion 162 .
- the connection portion 140 can be provided along one side or a plurality of sides of the display portion 162 .
- the number of connection parts 140 may be singular or plural.
- FIG. 16 shows an example in which connecting portions 140 are provided so as to surround the four sides of the display portion.
- the connection part 140 the common electrode of the light emitting device and the conductive layer are electrically connected, and a potential can be supplied to the common electrode.
- a scanning line driver circuit can be used.
- the wiring 165 has a function of supplying signals and power to the display portion 162 and the circuit 164 .
- the signal and power are input to the wiring 165 from the outside through the FPC 172 or input to the wiring 165 from the IC 173 .
- FIG. 16 shows an example in which an IC 173 is provided on a substrate 151 by a COG (Chip On Glass) method, a COF (Chip On Film) method, or the like.
- a COG Chip On Glass
- COF Chip On Film
- the IC 173 for example, an IC having a scanning line driver circuit or a signal line driver circuit can be applied.
- the display device 100F and the display module may be configured without an IC.
- the IC may be mounted on the FPC by the COF method or the like.
- part of the area including the FPC 172, part of the circuit 164, part of the display part 162, part of the connection part 140, and part of the area including the end of the display device 100F are cut off.
- An example of a cross section is shown.
- a display device 100F illustrated in FIG. 17A includes a transistor 201 and a transistor 205, a light receiving device 150d, a light emitting device 130b that emits green light, a light emitting device 130c that emits blue light, and the like, between substrates 151 and 152. .
- the display device 100F for example, the pixel layouts shown in FIGS. 2A to 2G, 3A, 3B, and 5A to 5D described in Embodiment 1 can be applied.
- the light receiving device 150d can be provided in the sub-pixel PS or the sub-pixel IRS.
- the light receiving device 150d has a conductive layer 111d, a conductive layer 112d on the conductive layer 111d, and a conductive layer 126d on the conductive layer 112d. All of the conductive layers 111d, 112d, and 126d can be called pixel electrodes, and some of them can also be called pixel electrodes.
- the conductive layer 111 d is connected to the conductive layer 222 b included in the transistor 205 through an opening provided in the insulating layer 214 .
- the end of the conductive layer 112d is positioned outside the end of the conductive layer 111d.
- the end of the conductive layer 112d and the end of the conductive layer 126d are aligned or substantially aligned.
- a conductive layer functioning as a reflective electrode can be used for the conductive layers 111d and 112d
- a conductive layer functioning as a transparent electrode can be used for the conductive layer 126d.
- the light emitting device 130b has a conductive layer 111b, a conductive layer 112b on the conductive layer 111b, and a conductive layer 126b on the conductive layer 112b.
- the light emitting device 130c has a conductive layer 111c, a conductive layer 112c on the conductive layer 111c, and a conductive layer 126c on the conductive layer 112c.
- the conductive layers 111b, 112b, and 126b in the light-emitting device 130b and the conductive layers 111c, 112c, and 126c in the light-emitting device 130c are the same as the conductive layers 111d, 112d, and 126d in the light-receiving device 150d, so detailed description thereof is omitted. .
- Concave portions are formed in the conductive layers 111 b , 111 c , and 111 d so as to cover the openings provided in the insulating layer 214 .
- a layer 128 is embedded in the recess.
- the layer 128 has a function of planarizing recesses of the conductive layers 111b, 111c, and 111d.
- Conductive layers 112b, 112c, and 112d electrically connected to the conductive layers 111b, 111c, and 111d are provided over the conductive layers 111b, 111c, and 111d and the layer 128.
- FIG. Therefore, the regions overlapping the concave portions of the conductive layers 111b, 111c, and 111d can also be used as light emitting regions, and the aperture ratio of pixels can be increased.
- Layer 128 may be an insulating layer or a conductive layer.
- Various inorganic insulating materials, organic insulating materials, and conductive materials can be used as appropriate for layer 128 .
- layer 128 is preferably formed using an insulating material.
- an insulating layer containing an organic material can be preferably used.
- an acrylic resin, a polyimide resin, an epoxy resin, a polyamide resin, a polyimideamide resin, a siloxane resin, a benzocyclobutene resin, a phenol resin, precursors of these resins, or the like can be applied.
- a photosensitive resin can be used as the layer 128 .
- a positive material or a negative material can be used for the photosensitive resin.
- the layer 128 can be formed only through the steps of exposure and development, and the influence of dry etching, wet etching, or the like on the surfaces of the conductive layers 111b, 111c, and 111d can be reduced. can. Further, when the layer 128 is formed using a negative photosensitive resin, the layer 128 can be formed using the same photomask (exposure mask) used for forming the opening of the insulating layer 214 in some cases. be.
- the top and side surfaces of the conductive layer 112d and the top and side surfaces of the conductive layer 126d are covered with a fifth layer 113d.
- the fifth layer 113d has at least an active layer.
- the top and side surfaces of the conductive layer 112b and the top and side surfaces of the conductive layer 126b are covered with the second layer 113b.
- the top and side surfaces of the conductive layer 112c and the top and side surfaces of the conductive layer 126c are covered with the third layer 113c. Therefore, the entire regions where the conductive layers 112b and 112c are provided can be used as light-emitting regions of the light-emitting devices 130b and 130c, so that the aperture ratio of pixels can be increased.
- a sacrificial layer 118b is located between the second layer 113b and the insulating layer 125 .
- a sacrificial layer 118c is positioned between the third layer 113c and the insulating layer 125, and a sacrificial layer 118d is positioned between the fifth layer 113d and the insulating layer 125.
- FIG. A fourth layer 114 is provided over the second layer 113b, the third layer 113c, the fifth layer 113d, and the insulating layers 125 and 127, and the common electrode 115 is provided over the fourth layer 114. ing.
- the fourth layer 114 and the common electrode 115 are a series of films that are commonly provided for the light receiving device and the light emitting device, respectively.
- a protective layer 131 is provided on the light emitting devices 130b and 130c and the light receiving device 150d.
- the protective layer 131 and the substrate 152 are adhered via the adhesive layer 142 .
- a solid sealing structure, a hollow sealing structure, or the like can be applied to sealing the light-emitting device.
- the space between substrates 152 and 151 is filled with an adhesive layer 142 to apply a solid sealing structure.
- the space may be filled with an inert gas (such as nitrogen or argon) to apply a hollow sealing structure.
- the adhesive layer 142 may be provided so as not to overlap the light emitting device.
- the space may be filled with a resin different from the adhesive layer 142 provided in a frame shape.
- a conductive layer 123 is provided over the insulating layer 214 in the connection portion 140 .
- the conductive layer 123 includes a conductive film obtained by processing the same conductive film as the conductive layers 111b, 111c, and 111d and a conductive film obtained by processing the same conductive film as the conductive layers 112b, 112c, and 112d. , and a conductive film obtained by processing the same conductive film as the conductive layers 126b, 126c, and 126d.
- the ends of the conductive layer 123 are covered by a sacrificial layer, an insulating layer 125 and an insulating layer 127 .
- a fourth layer 114 is provided over the conductive layer 123 and a common electrode 115 is provided over the fourth layer 114 .
- the conductive layer 123 and common electrode 115 are electrically connected through the fourth layer 114 .
- the fourth layer 114 may not be formed on the connecting portion 140 . In this case, the conductive layer 123 and the common electrode 115 are directly contacted and electrically connected.
- the display device 100F is of a top emission type. Light emitted by the light emitting device is emitted to the substrate 152 side. A material having high visible light transmittance is preferably used for the substrate 152 .
- the pixel electrode contains a material that reflects visible light, and the counter electrode (common electrode 115) contains a material that transmits visible light.
- a stacked structure from the substrate 151 to the insulating layer 214 corresponds to the layer 101 including the transistor in Embodiment 1.
- FIG. 1 A stacked structure from the substrate 151 to the insulating layer 214 corresponds to the layer 101 including the transistor in Embodiment 1.
- Both the transistor 201 and the transistor 205 are formed over the substrate 151 . These transistors can be made with the same material and the same process.
- An insulating layer 211 , an insulating layer 213 , an insulating layer 215 , and an insulating layer 214 are provided in this order over the substrate 151 .
- Part of the insulating layer 211 functions as a gate insulating layer of each transistor.
- Part of the insulating layer 213 functions as a gate insulating layer of each transistor.
- An insulating layer 215 is provided over the transistor.
- An insulating layer 214 is provided over the transistor and functions as a planarization layer. Note that the number of gate insulating layers and the number of insulating layers covering a transistor are not limited, and each may have a single layer or two or more layers.
- a material into which impurities such as water and hydrogen are difficult to diffuse is preferably used for at least one insulating layer that covers the transistor. This allows the insulating layer to function as a barrier layer. With such a structure, diffusion of impurities from the outside into the transistor can be effectively suppressed, and the reliability of the display device can be improved.
- An inorganic insulating film is preferably used for each of the insulating layers 211 , 213 , and 215 .
- the inorganic insulating film for example, a silicon nitride film, a silicon oxynitride film, a silicon oxide film, a silicon oxynitride film, an aluminum oxide film, an aluminum nitride film, or the like can be used.
- a hafnium oxide film, an yttrium oxide film, a zirconium oxide film, a gallium oxide film, a tantalum oxide film, a magnesium oxide film, a lanthanum oxide film, a cerium oxide film, a neodymium oxide film, or the like may be used.
- two or more of the insulating films described above may be laminated and used.
- An organic insulating film is suitable for the insulating layer 214 that functions as a planarization layer.
- materials that can be used for the organic insulating film include acrylic resins, polyimide resins, epoxy resins, polyamide resins, polyimideamide resins, siloxane resins, benzocyclobutene-based resins, phenolic resins, precursors of these resins, and the like.
- the insulating layer 214 may have a laminated structure of an organic insulating film and an inorganic insulating film. The outermost layer of the insulating layer 214 preferably functions as an etching protection film.
- the insulating layer 214 may be provided with recesses when the conductive layer 111b, the conductive layer 112b, or the conductive layer 126b is processed.
- the transistors 201 and 205 include a conductive layer 221 functioning as a gate, an insulating layer 211 functioning as a gate insulating layer, conductive layers 222a and 222b functioning as sources and drains, a semiconductor layer 231, and an insulating layer functioning as a gate insulating layer. It has a layer 213 and a conductive layer 223 that functions as a gate. Here, the same hatching pattern is applied to a plurality of layers obtained by processing the same conductive film.
- the insulating layer 211 is located between the conductive layer 221 and the semiconductor layer 231 .
- the insulating layer 213 is located between the conductive layer 223 and the semiconductor layer 231 .
- the structure of the transistor included in the display device of this embodiment there is no particular limitation on the structure of the transistor included in the display device of this embodiment.
- a planar transistor, a staggered transistor, an inverted staggered transistor, or the like can be used.
- the transistor structure may be either a top-gate type or a bottom-gate type.
- gates may be provided above and below a semiconductor layer in which a channel is formed.
- a structure in which a semiconductor layer in which a channel is formed is sandwiched between two gates is applied to the transistors 201 and 205 .
- a transistor may be driven by connecting two gates and applying the same signal to them.
- the threshold voltage of the transistor may be controlled by applying a potential for controlling the threshold voltage to one of the two gates and applying a potential for driving to the other.
- crystallinity of a semiconductor material used for a transistor there is no particular limitation on the crystallinity of a semiconductor material used for a transistor, and an amorphous semiconductor, a single crystal semiconductor, or a semiconductor having a crystallinity other than a single crystal (a microcrystalline semiconductor, a polycrystalline semiconductor, or a semiconductor having a crystal region in part) can be used. semiconductor) may be used. A single crystal semiconductor or a crystalline semiconductor is preferably used because deterioration of transistor characteristics can be suppressed.
- a semiconductor layer of a transistor preferably includes a metal oxide (also referred to as an oxide semiconductor).
- the display device of this embodiment preferably uses a transistor including a metal oxide for a channel formation region (hereinafter referred to as an OS transistor).
- the semiconductor layer of the transistor may comprise silicon. Examples of silicon include amorphous silicon and crystalline silicon (low-temperature polysilicon, monocrystalline silicon, etc.).
- the semiconductor layer includes, for example, indium and M (M is gallium, aluminum, silicon, boron, yttrium, tin, copper, vanadium, beryllium, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, one or more selected from hafnium, tantalum, tungsten, and magnesium) and zinc.
- M is preferably one or more selected from aluminum, gallium, yttrium, and tin.
- an oxide containing indium (In), gallium (Ga), and zinc (Zn) (also referred to as IGZO) is preferably used for the semiconductor layer.
- an oxide containing indium, tin, and zinc is preferably used.
- oxides containing indium, gallium, tin, and zinc are preferably used.
- the In atomic ratio in the In-M-Zn oxide is preferably equal to or higher than the M atomic ratio.
- the transistors included in the circuit 164 and the transistors included in the display portion 162 may have the same structure or different structures.
- the plurality of transistors included in the circuit 164 may all have the same structure, or may have two or more types.
- the structures of the plurality of transistors included in the display portion 162 may all be the same, or may be of two or more types.
- 17B and 17C show other configuration examples of the transistor.
- the transistor 209 and the transistor 210 each include a conductive layer 221 functioning as a gate, an insulating layer 211 functioning as a gate insulating layer, a semiconductor layer 231 having a channel formation region 231i and a pair of low-resistance regions 231n, and one of the pair of low-resistance regions 231n.
- a conductive layer 222a connected to a pair of low-resistance regions 231n, a conductive layer 222b connected to the other of a pair of low-resistance regions 231n, an insulating layer 225 functioning as a gate insulating layer, a conductive layer 223 functioning as a gate, and an insulating layer 215 covering the conductive layer 223 have
- the insulating layer 211 is located between the conductive layer 221 and the channel formation region 231i.
- the insulating layer 225 is located at least between the conductive layer 223 and the channel formation region 231i.
- an insulating layer 218 may be provided to cover the transistor.
- the transistor 209 illustrated in FIG. 17B illustrates an example in which the insulating layer 225 covers the top and side surfaces of the semiconductor layer 231 .
- the conductive layers 222a and 222b are connected to the low-resistance region 231n through openings provided in the insulating layers 225 and 215, respectively.
- One of the conductive layers 222a and 222b functions as a source and the other functions as a drain.
- the insulating layer 225 overlaps with the channel formation region 231i of the semiconductor layer 231 and does not overlap with the low resistance region 231n.
- the insulating layer 215 is provided to cover the insulating layer 225 and the conductive layer 223, and the conductive layers 222a and 222b are connected to the low resistance region 231n through openings in the insulating layer 215, respectively.
- a connection portion 204 is provided in a region of the substrate 151 where the substrate 152 does not overlap.
- the wiring 165 is electrically connected to the FPC 172 via the conductive layer 166 and the connecting layer 242 .
- the conductive layer 166 includes a conductive film obtained by processing the same conductive film as the conductive layers 111b, 111c, and 111d and a conductive film obtained by processing the same conductive film as the conductive layers 112b, 112c, and 112d. , and a conductive film obtained by processing the same conductive film as the conductive layers 126b, 126c, and 126d.
- the conductive layer 166 is exposed on the upper surface of the connecting portion 204 . Thereby, the connecting portion 204 and the FPC 172 can be electrically connected via the connecting layer 242 .
- a light shielding layer 117 is preferably provided on the surface of the substrate 152 on the substrate 151 side.
- the light shielding layer 117 can be provided between adjacent light emitting devices, the connection portion 140, the circuit 164, and the like.
- various optical members can be arranged outside the substrate 152 . Examples of optical members include polarizing plates, retardation plates, light diffusion layers (diffusion films, etc.), antireflection layers, light collecting films, and the like.
- an antistatic film that suppresses adhesion of dust, a water-repellent film that prevents adhesion of dirt, a hard coat film that suppresses the occurrence of scratches due to use, a shock absorption layer, etc. are arranged on the outside of the substrate 152.
- an antistatic film that suppresses adhesion of dust, a water-repellent film that prevents adhesion of dirt, a hard coat film that suppresses the occurrence of scratches due to use, a shock absorption layer, etc. are arranged. may
- the protective layer 131 that covers the light-emitting device and the light-receiving device, it is possible to prevent impurities such as water from entering the light-emitting device and the light-receiving device and improve the reliability of the light-emitting device and the light-receiving device.
- the substrate 151 and the substrate 152 can each be formed using the material that can be used for the substrate 120 described in Embodiment 2.
- a material that transmits the light is used for the substrate on the side from which the light from the light-emitting device is extracted.
- a polarizing plate may be used as the substrate 151 or the substrate 152 .
- any of the materials that can be used for the resin layer 122 described in Embodiment 2 can be used.
- connection layer 242 an anisotropic conductive film (ACF), an anisotropic conductive paste (ACP), or the like can be used.
- ACF anisotropic conductive film
- ACP anisotropic conductive paste
- Display device 100G A display device 100G shown in FIG. 18A is mainly different from the display device 100F in that it is a bottom-emission type display device in which a white light emitting device and a color filter are combined. In the following description of the display device, the description of the same parts as those of the previously described display device may be omitted.
- Light emitted by the light emitting device is emitted to the substrate 151 side.
- Light enters the light receiving device from the substrate 151 side.
- a material having high visible light transmittance is preferably used for the substrate 151 .
- the material used for the substrate 152 may or may not be translucent.
- a light-blocking layer 117 is preferably formed between the substrate 151 and the transistor 201 and between the substrate 151 and the transistor 205 .
- FIG. 18A shows an example in which the light-blocking layer 117 is provided over the substrate 151 , the insulating layer 153 is provided over the light-blocking layer 117 , and the transistors 201 and 205 and the like are provided over the insulating layer 153 .
- the light emitting device 130a and the colored layer 132R overlap each other, and light emitted from the light emitting device 130a is extracted as red light to the outside of the display device 100G through the red colored layer 132R.
- the light emitting device 130a has a conductive layer 111a, a conductive layer 112a on the conductive layer 111a, and a conductive layer 126a on the conductive layer 112a.
- the light receiving device 150d has a conductive layer 111d, a conductive layer 112d on the conductive layer 111d, and a conductive layer 126d on the conductive layer 112d.
- a material having high visible light transmittance is used for each of the conductive layers 111a, 111d, 112a, 112d, 126a, and 126d.
- a material that reflects visible light is preferably used for the common electrode 115 .
- the top and side surfaces of the conductive layer 112a and the top and side surfaces of the conductive layer 126a are covered with the first layer 113a. Side surfaces of the first layer 113 a are covered with insulating layers 125 and 127 .
- a sacrificial layer 118 a is located between the first layer 113 a and the insulating layer 125 .
- a fourth layer 114 is provided over the first layer 113 a , the fifth layer 113 d , and the insulating layers 125 and 127 , and a common electrode 115 is provided over the fourth layer 114 .
- the fourth layer 114 and the common electrode 115 are a series of films that are commonly provided for the light receiving device and the light emitting device, respectively.
- a protective layer 131 is provided on the light emitting device 130a and the light receiving device 150d.
- FIG. 18A illustrates the first layer 113a as three layers, and specifically, a stacked structure of a first light-emitting unit, a charge generation layer, and a second light-emitting unit can be applied. .
- 17A and 18A show an example in which the upper surface of the layer 128 has a flat portion, but the shape of the layer 128 is not particularly limited.
- a variation of layer 128 is shown in Figures 18B-18D.
- the upper surface of the layer 128 can be configured to have a shape in which the center and the vicinity thereof are depressed in a cross-sectional view, that is, a shape having a concave curved surface.
- the upper surface of the layer 128 can be configured to have a shape in which the center and the vicinity thereof bulge in a cross-sectional view, that is, have a convex curved surface.
- the top surface of layer 128 may have one or both of convex and concave surfaces.
- the number of convex curved surfaces and concave curved surfaces that the upper surface of the layer 128 has is not limited, and may be one or more.
- the height of the top surface of the layer 128 and the height of the top surface of the conductive layer 111a may be the same or substantially the same, or may be different from each other.
- the height of the top surface of layer 128 may be lower or higher than the height of the top surface of conductive layer 111a.
- FIG. 18B can also be said to be an example in which the layer 128 is accommodated inside the recess formed in the conductive layer 111a.
- the layer 128 may exist outside the recess formed in the conductive layer 111a, that is, the upper surface of the layer 128 may be wider than the recess.
- the light emitting device has an EL layer 786 between a pair of electrodes (lower electrode 772, upper electrode 788).
- EL layer 786 can be composed of multiple layers such as layer 4420 , light-emitting layer 4411 , and layer 4430 .
- the layer 4420 can have, for example, a layer containing a substance with high electron-injection properties (electron-injection layer) and a layer containing a substance with high electron-transport properties (electron-transporting layer).
- the light-emitting layer 4411 contains, for example, a light-emitting compound.
- the layer 4430 can have, for example, a layer containing a substance with high hole-injection properties (hole-injection layer) and a layer containing a substance with high hole-transport properties (hole-transport layer).
- a structure having layer 4420, light-emitting layer 4411, and layer 4430 provided between a pair of electrodes can function as a single light-emitting unit, and the structure of FIG. 19A is referred to herein as a single structure.
- FIG. 19B is a modification of the EL layer 786 included in the light emitting device shown in FIG. 19A.
- the light-emitting device shown in FIG. It has a top layer 4422 and a top electrode 788 on layer 4422 .
- layer 4431 functions as a hole injection layer
- layer 4432 functions as a hole transport layer
- layer 4421 functions as an electron transport layer
- Layer 4422 functions as an electron injection layer.
- layer 4431 functions as an electron injection layer
- layer 4432 functions as an electron transport layer
- layer 4421 functions as a hole transport layer
- layer 4421 functions as a hole transport layer
- 4422 functions as a hole injection layer.
- a configuration in which a plurality of light emitting layers (light emitting layers 4411, 4412, and 4413) are provided between layers 4420 and 4430 as shown in FIGS. 19C and 19D is also a variation of the single structure.
- tandem structure a structure in which a plurality of light-emitting units (EL layers 786a and 786b) are connected in series via the charge generation layer 4440 is referred to as a tandem structure in this specification.
- the tandem structure may also be called a stack structure. Note that the tandem structure enables a light-emitting device capable of emitting light with high luminance.
- the light-emitting layers 4411, 4412, and 4413 may be made of a light-emitting material that emits light of the same color, or may be the same light-emitting material.
- the light-emitting layers 4411, 4412, and 4413 may be formed using a light-emitting material that emits blue light.
- a color conversion layer may be provided as the layer 785 shown in FIG. 19D.
- light-emitting materials that emit light of different colors may be used for the light-emitting layers 4411, 4412, and 4413, respectively.
- white light emission can be obtained.
- a color filter also referred to as a colored layer
- a desired color of light can be obtained by passing the white light through the color filter.
- the light-emitting layer 4411 and the light-emitting layer 4412 may be made of a light-emitting material that emits light of the same color, or may be the same light-emitting material. Alternatively, light-emitting materials that emit light of different colors may be used for the light-emitting layers 4411 and 4412 .
- the light emitted from the light-emitting layer 4411 and the light emitted from the light-emitting layer 4412 are complementary colors, white light emission can be obtained.
- FIG. 19F shows an example in which an additional layer 785 is provided. As the layer 785, one or both of a color conversion layer and a color filter (colored layer) can be used.
- the layer 4420 and the layer 4430 may have a laminated structure of two or more layers as shown in FIG. 19B.
- a structure in which different emission colors (eg, blue (B), green (G), and red (R)) are produced for each light emitting device is sometimes called an SBS (Side By Side) structure.
- the emission color of the light emitting device can be red, green, blue, cyan, magenta, yellow, white, or the like, depending on the material that composes the EL layer 786 . Further, the color purity can be further enhanced by providing the light-emitting device with a microcavity structure.
- a light-emitting device that emits white light preferably has a structure in which a light-emitting layer contains two or more kinds of light-emitting substances.
- two or more light-emitting substances may be selected so that the light emission of each light-emitting substance has a complementary color relationship.
- the emission color of the first light-emitting layer and the emission color of the second light-emitting layer have a complementary color relationship, it is possible to obtain a light-emitting device that emits white light as a whole. The same applies to light-emitting devices having three or more light-emitting layers.
- the light-emitting layer preferably contains two or more light-emitting substances that emit light such as R (red), G (green), B (blue), Y (yellow), and O (orange).
- R red
- G green
- B blue
- Y yellow
- O orange
- the metal oxide preferably contains at least indium or zinc. In particular, it preferably contains indium and zinc. In addition to these, aluminum, gallium, yttrium, tin and the like are preferably contained. In addition, one or more selected from boron, silicon, titanium, iron, nickel, germanium, zirconium, molybdenum, lanthanum, cerium, neodymium, hafnium, tantalum, tungsten, magnesium, cobalt, etc. may be contained. .
- the metal oxide is formed by chemical vapor deposition (CVD) such as sputtering, metal organic chemical vapor deposition (MOCVD), or atomic layer deposition (ALD). It can be formed by a layer deposition method or the like.
- CVD chemical vapor deposition
- MOCVD metal organic chemical vapor deposition
- ALD atomic layer deposition
- Crystal structures of oxide semiconductors include amorphous (including completely amorphous), CAAC (c-axis-aligned crystalline), nc (nanocrystalline), CAC (cloud-aligned composite), single crystal, and polycrystal. (polycrystal) and the like.
- the crystal structure of the film or substrate can be evaluated using an X-ray diffraction (XRD) spectrum.
- XRD X-ray diffraction
- it can be evaluated using an XRD spectrum obtained by GIXD (Grazing-Incidence XRD) measurement.
- GIXD Gram-Incidence XRD
- the GIXD method is also called a thin film method or a Seemann-Bohlin method.
- the peak shape of the XRD spectrum is almost symmetrical.
- the peak shape of the XRD spectrum is left-right asymmetric.
- the asymmetric shape of the peaks in the XRD spectra demonstrates the presence of crystals in the film or substrate. In other words, the film or substrate cannot be said to be in an amorphous state unless the shape of the peaks in the XRD spectrum is symmetrical.
- the crystal structure of the film or substrate can be evaluated by a diffraction pattern (also referred to as a nanobeam electron diffraction pattern) observed by nano beam electron diffraction (NBED).
- a diffraction pattern also referred to as a nanobeam electron diffraction pattern
- NBED nano beam electron diffraction
- a halo is observed in the diffraction pattern of a quartz glass substrate, and it can be confirmed that the quartz glass is in an amorphous state.
- a spot-like pattern is observed instead of a halo. Therefore, it is presumed that the IGZO film deposited at room temperature is neither crystalline nor amorphous, but in an intermediate state and cannot be concluded to be in an amorphous state.
- oxide semiconductors may be classified differently from the above when their structures are focused. For example, oxide semiconductors are classified into single-crystal oxide semiconductors and non-single-crystal oxide semiconductors. Examples of non-single-crystal oxide semiconductors include the above CAAC-OS and nc-OS. Non-single-crystal oxide semiconductors include polycrystalline oxide semiconductors, amorphous-like oxide semiconductors (a-like OS), amorphous oxide semiconductors, and the like.
- CAAC-OS is an oxide semiconductor that includes a plurality of crystal regions, and the c-axes of the plurality of crystal regions are oriented in a specific direction. Note that the specific direction is the thickness direction of the CAAC-OS film, the normal direction to the formation surface of the CAAC-OS film, or the normal direction to the surface of the CAAC-OS film.
- a crystalline region is a region having periodicity in atomic arrangement. If the atomic arrangement is regarded as a lattice arrangement, the crystalline region is also a region with a uniform lattice arrangement.
- CAAC-OS has a region where a plurality of crystal regions are connected in the a-b plane direction, and the region may have strain.
- the strain refers to a portion where the orientation of the lattice arrangement changes between a region with a uniform lattice arrangement and another region with a uniform lattice arrangement in a region where a plurality of crystal regions are connected. That is, CAAC-OS is an oxide semiconductor that is c-axis oriented and has no obvious orientation in the ab plane direction.
- each of the plurality of crystal regions is composed of one or a plurality of minute crystals (crystals having a maximum diameter of less than 10 nm).
- the maximum diameter of the crystalline region is less than 10 nm.
- the size of the crystal region may be about several tens of nanometers.
- CAAC-OS contains indium (In) and oxygen.
- a tendency to have a layered crystal structure also referred to as a layered structure in which a layer (hereinafter referred to as an In layer) and a layer containing the element M, zinc (Zn), and oxygen (hereinafter referred to as a (M, Zn) layer) are stacked.
- the (M, Zn) layer may contain indium.
- the In layer contains the element M.
- the In layer may contain Zn.
- the layered structure is observed as a lattice image in, for example, a high-resolution TEM (Transmission Electron Microscope) image.
- a plurality of bright points are observed in the electron beam diffraction pattern of the CAAC-OS film.
- a certain spot and another spot are observed at point-symmetrical positions with respect to the spot of the incident electron beam that has passed through the sample (also referred to as a direct spot) as the center of symmetry.
- the lattice arrangement in the crystal region is basically a hexagonal lattice, but the unit lattice is not always regular hexagon and may be non-regular hexagon. Moreover, the distortion may have a lattice arrangement such as a pentagon or a heptagon. Note that in CAAC-OS, no clear crystal grain boundary can be observed even near the strain. That is, it can be seen that the distortion of the lattice arrangement suppresses the formation of grain boundaries. This is because the CAAC-OS can tolerate strain due to the fact that the arrangement of oxygen atoms is not dense in the ab plane direction and the bond distance between atoms changes due to the substitution of metal atoms. it is conceivable that.
- a crystal structure in which clear grain boundaries are confirmed is called a so-called polycrystal.
- a grain boundary becomes a recombination center, traps carriers, and is highly likely to cause a decrease in on-current of a transistor, a decrease in field-effect mobility, and the like. Therefore, a CAAC-OS in which no clear grain boundaries are observed is one of crystalline oxides having a crystal structure suitable for a semiconductor layer of a transistor.
- a structure containing Zn is preferable for forming a CAAC-OS.
- In--Zn oxide and In--Ga--Zn oxide are preferable because they can suppress the generation of grain boundaries more than In oxide.
- a CAAC-OS is an oxide semiconductor with high crystallinity and no clear grain boundaries. Therefore, it can be said that the decrease in electron mobility due to grain boundaries is less likely to occur in CAAC-OS.
- a CAAC-OS can be said to be an oxide semiconductor with few impurities and defects (such as oxygen vacancies). Therefore, an oxide semiconductor including CAAC-OS has stable physical properties. Therefore, an oxide semiconductor including CAAC-OS is resistant to heat and has high reliability.
- CAAC-OS is also stable against high temperatures (so-called thermal budget) in the manufacturing process. Therefore, the use of the CAAC-OS for the OS transistor makes it possible to increase the degree of freedom in the manufacturing process.
- nc-OS has periodic atomic arrangement in a minute region (eg, a region of 1 nm to 10 nm, particularly a region of 1 nm to 3 nm).
- the nc-OS has minute crystals.
- the size of the minute crystal is, for example, 1 nm or more and 10 nm or less, particularly 1 nm or more and 3 nm or less, the minute crystal is also called a nanocrystal.
- nc-OS does not show regularity in crystal orientation between different nanocrystals. Therefore, no orientation is observed in the entire film.
- an nc-OS may be indistinguishable from an a-like OS or an amorphous oxide semiconductor depending on the analysis method.
- an nc-OS film is subjected to structural analysis using an XRD apparatus, out-of-plane XRD measurement using ⁇ /2 ⁇ scanning does not detect a peak indicating crystallinity.
- an nc-OS film is subjected to electron beam diffraction (also referred to as selected area electron beam diffraction) using an electron beam with a probe diameter larger than that of nanocrystals (for example, 50 nm or more), a diffraction pattern such as a halo pattern is obtained. is observed.
- an nc-OS film is subjected to electron diffraction (also referred to as nanobeam electron diffraction) using an electron beam with a probe diameter close to or smaller than the size of a nanocrystal (for example, 1 nm or more and 30 nm or less)
- an electron beam diffraction pattern is obtained in which a plurality of spots are observed within a ring-shaped area centered on the direct spot.
- An a-like OS is an oxide semiconductor having a structure between an nc-OS and an amorphous oxide semiconductor.
- An a-like OS has void or low density regions. That is, the a-like OS has lower crystallinity than the nc-OS and CAAC-OS. In addition, the a-like OS has a higher hydrogen concentration in the film than the nc-OS and the CAAC-OS.
- CAC-OS relates to material composition.
- CAC-OS is, for example, one structure of a material in which elements constituting a metal oxide are unevenly distributed with a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or in the vicinity thereof.
- the metal oxide one or more metal elements are unevenly distributed, and the region having the metal element has a size of 0.5 nm or more and 10 nm or less, preferably 1 nm or more and 3 nm or less, or a size in the vicinity thereof.
- the mixed state is also called mosaic or patch.
- CAC-OS is a structure in which the material is separated into a first region and a second region to form a mosaic shape, and the first region is distributed in the film (hereinafter, also referred to as a cloud shape). ). That is, CAC-OS is a composite metal oxide in which the first region and the second region are mixed.
- the atomic ratios of In, Ga, and Zn to the metal elements constituting the CAC-OS in the In—Ga—Zn oxide are represented by [In], [Ga], and [Zn], respectively.
- the first region is a region where [In] is larger than [In] in the composition of the CAC-OS.
- the second region is a region in which [Ga] is larger than [Ga] in the CAC-OS composition.
- the first region is a region in which [In] is larger than [In] in the second region and [Ga] is smaller than [Ga] in the second region.
- the second region is a region in which [Ga] is larger than [Ga] in the first region and [In] is smaller than [In] in the first region.
- the first region is a region containing indium oxide, indium zinc oxide, or the like as a main component.
- the second region is a region containing gallium oxide, gallium zinc oxide, or the like as a main component. That is, the first region can be rephrased as a region containing In as a main component. Also, the second region can be rephrased as a region containing Ga as a main component.
- the CAC-OS in the In—Ga—Zn oxide means a region containing Ga as a main component and a region containing In as a main component in a material structure containing In, Ga, Zn, and O. Each region is a mosaic, and refers to a configuration in which these regions exist randomly. Therefore, CAC-OS is presumed to have a structure in which metal elements are unevenly distributed.
- a CAC-OS can be formed, for example, by a sputtering method under conditions in which the substrate is not heated.
- a sputtering method one or more selected from an inert gas (typically argon), an oxygen gas, and a nitrogen gas may be used as a deposition gas. good.
- an inert gas typically argon
- oxygen gas typically argon
- a nitrogen gas may be used as a deposition gas. good.
- the lower the flow rate ratio of the oxygen gas to the total flow rate of the film formation gas during film formation, the better. is preferably 0% or more and 10% or less.
- an EDX mapping obtained using energy dispersive X-ray spectroscopy shows that a region containing In as a main component It can be confirmed that the (first region) and the region (second region) containing Ga as the main component are unevenly distributed and have a mixed structure.
- the first region is a region with higher conductivity than the second region. That is, when carriers flow through the first region, conductivity as a metal oxide is developed. Therefore, by distributing the first region in the form of a cloud in the metal oxide, a high field effect mobility ( ⁇ ) can be realized.
- the second region is a region with higher insulation than the first region.
- the leakage current can be suppressed by distributing the second region in the metal oxide.
- CAC-OS when used for a transistor, the conductivity caused by the first region and the insulation caused by the second region act in a complementary manner to provide a switching function (turning ON/OFF). functions) can be given to the CAC-OS.
- a part of the material has a conductive function
- a part of the material has an insulating function
- the whole material has a semiconductor function.
- CAC-OS is most suitable for various semiconductor devices including display devices.
- Oxide semiconductors have various structures and each has different characteristics.
- An oxide semiconductor of one embodiment of the present invention includes two or more of an amorphous oxide semiconductor, a polycrystalline oxide semiconductor, an a-like OS, a CAC-OS, an nc-OS, and a CAAC-OS. may
- an oxide semiconductor with low carrier concentration is preferably used for a transistor.
- the carrier concentration of the oxide semiconductor is 1 ⁇ 10 17 cm ⁇ 3 or less, preferably 1 ⁇ 10 15 cm ⁇ 3 or less, more preferably 1 ⁇ 10 13 cm ⁇ 3 or less, more preferably 1 ⁇ 10 11 cm ⁇ 3 or less. 3 or less, more preferably less than 1 ⁇ 10 10 cm ⁇ 3 and 1 ⁇ 10 ⁇ 9 cm ⁇ 3 or more.
- the impurity concentration in the oxide semiconductor film may be lowered to lower the defect level density.
- a low impurity concentration and a low defect level density are referred to as high-purity intrinsic or substantially high-purity intrinsic.
- an oxide semiconductor with a low carrier concentration is sometimes referred to as a highly purified intrinsic or substantially highly purified intrinsic oxide semiconductor.
- the trap level density may also be low.
- the charge trapped in the trap level of the oxide semiconductor takes a long time to disappear and may behave like a fixed charge. Therefore, a transistor whose channel formation region is formed in an oxide semiconductor with a high trap level density might have unstable electrical characteristics.
- Impurities include hydrogen, nitrogen, alkali metals, alkaline earth metals, iron, nickel, silicon, and the like.
- the concentration of silicon or carbon in the oxide semiconductor and the concentration of silicon or carbon in the vicinity of the interface with the oxide semiconductor are 2 ⁇ 10 18 atoms/cm 3 or less, preferably 2 ⁇ 10 17 atoms/cm 3 or less.
- the concentration of alkali metal or alkaline earth metal in the oxide semiconductor obtained by SIMS is set to 1 ⁇ 10 18 atoms/cm 3 or less, preferably 2 ⁇ 10 16 atoms/cm 3 or less.
- the nitrogen concentration in the oxide semiconductor obtained by SIMS is less than 5 ⁇ 10 19 atoms/cm 3 , preferably 5 ⁇ 10 18 atoms/cm 3 or less, more preferably 1 ⁇ 10 18 atoms/cm 3 or less. , more preferably 5 ⁇ 10 17 atoms/cm 3 or less.
- the oxide semiconductor reacts with oxygen that bonds to a metal atom to form water, which may cause oxygen vacancies.
- oxygen vacancies When hydrogen enters the oxygen vacancies, electrons, which are carriers, may be generated.
- part of hydrogen may bond with oxygen that bonds with a metal atom to generate an electron, which is a carrier. Therefore, a transistor including an oxide semiconductor containing hydrogen is likely to have normally-on characteristics. Therefore, hydrogen in the oxide semiconductor is preferably reduced as much as possible.
- the hydrogen concentration obtained by SIMS is less than 1 ⁇ 10 20 atoms/cm 3 , preferably less than 1 ⁇ 10 19 atoms/cm 3 , more preferably less than 5 ⁇ 10 18 atoms/cm. Less than 3 , more preferably less than 1 ⁇ 10 18 atoms/cm 3 .
- the electronic devices of this embodiment each include the display device of one embodiment of the present invention in a display portion.
- the display device of one embodiment of the present invention can easily have high definition and high resolution. Therefore, it can be used for display portions of various electronic devices.
- Examples of electronic devices include televisions, desktop or notebook personal computers, monitors for computers, digital signage, large game machines such as pachinko machines, and other electronic devices with relatively large screens. Examples include cameras, digital video cameras, digital photo frames, mobile phones, mobile game machines, mobile information terminals, and sound reproducing devices.
- the display device of one embodiment of the present invention can have high definition, it can be suitably used for electronic devices having a relatively small display portion.
- electronic devices include, for example, wristwatch-type and bracelet-type information terminals (wearable devices), VR (Virtual Reality) devices such as head-mounted displays, glasses-type AR (Augmented Reality) devices, and wearable devices that can be worn on the head, such as devices for MR (Mixed Reality).
- a display device of one embodiment of the present invention includes HD (1280 ⁇ 720 pixels), FHD (1920 ⁇ 1080 pixels), WQHD (2560 ⁇ 1440 pixels), WQXGA (2560 ⁇ 1600 pixels), 4K (2560 ⁇ 1600 pixels), 3840 ⁇ 2160) and 8K (7680 ⁇ 4320 pixels).
- the resolution it is preferable to set the resolution to 4K, 8K, or higher.
- the pixel density (definition) of the display device of one embodiment of the present invention is preferably 100 ppi or more, preferably 300 ppi or more, more preferably 500 ppi or more, more preferably 1000 ppi or more, more preferably 2000 ppi or more, and 3000 ppi or more.
- the display device can support various screen ratios such as 1:1 (square), 4:3, 16:9, 16:10.
- the electronic device of this embodiment includes sensors (force, displacement, position, velocity, acceleration, angular velocity, number of revolutions, distance, light, liquid, magnetism, temperature, chemical substance, sound, time, hardness, electric field, current, voltage , power, radiation, flow, humidity, gradient, vibration, odor or infrared).
- the electronic device of this embodiment can have various functions. For example, functions to display various information (still images, moving images, text images, etc.) on the display, touch panel functions, functions to display calendars, dates or times, functions to execute various software (programs), wireless communication function, a function of reading a program or data recorded on a recording medium, and the like.
- An electronic device 6500 illustrated in FIG. 20A is a mobile information terminal that can be used as a smart phone.
- An electronic device 6500 includes a housing 6501, a display portion 6502, a power button 6503, a button 6504, a speaker 6505, a microphone 6506, a camera 6507, a light source 6508, and the like.
- a display portion 6502 has a touch panel function.
- the display device of one embodiment of the present invention can be applied to the display portion 6502 .
- FIG. 20B is a schematic cross-sectional view including the end of the housing 6501 on the microphone 6506 side.
- a light-transmitting protective member 6510 is provided on the display surface side of the housing 6501, and a display panel 6511, an optical member 6512, a touch sensor panel 6513, and a printer are placed in a space surrounded by the housing 6501 and the protective member 6510.
- a substrate 6517, a battery 6518, and the like are arranged.
- a display panel 6511, an optical member 6512, and a touch sensor panel 6513 are fixed to the protective member 6510 with an adhesive layer (not shown).
- a portion of the display panel 6511 is folded back in a region outside the display portion 6502, and the FPC 6515 is connected to the folded portion.
- An IC6516 is mounted on the FPC6515.
- the FPC 6515 is connected to terminals provided on the printed circuit board 6517 .
- the flexible display of one embodiment of the present invention can be applied to the display panel 6511 . Therefore, an extremely lightweight electronic device can be realized. In addition, since the display panel 6511 is extremely thin, the thickness of the electronic device can be reduced and the large-capacity battery 6518 can be mounted. In addition, by folding back part of the display panel 6511 and arranging a connection portion with the FPC 6515 on the back side of the pixel portion, an electronic device with a narrow frame can be realized.
- FIG. 21A shows an example of a television device.
- a television set 7100 has a display portion 7000 incorporated in a housing 7101 .
- a configuration in which a housing 7101 is supported by a stand 7103 is shown.
- the display device of one embodiment of the present invention can be applied to the display portion 7000 .
- the operation of the television apparatus 7100 shown in FIG. 21A can be performed by operation switches provided in the housing 7101 and a separate remote controller 7111 .
- the display portion 7000 may be provided with a touch sensor, and the television device 7100 may be operated by touching the display portion 7000 with a finger or the like.
- the remote controller 7111 may have a display section for displaying information output from the remote controller 7111 .
- a channel and a volume can be operated with operation keys or a touch panel provided in the remote controller 7111 , and an image displayed on the display portion 7000 can be operated.
- the television device 7100 is configured to include a receiver, a modem, and the like.
- the receiver can receive general television broadcasts. Also, by connecting to a wired or wireless communication network via a modem, one-way (from the sender to the receiver) or two-way (between the sender and the receiver, or between the receivers, etc.) information communication. is also possible.
- FIG. 21B shows an example of a notebook personal computer.
- a notebook personal computer 7200 has a housing 7211, a keyboard 7212, a pointing device 7213, an external connection port 7214, and the like.
- the display portion 7000 is incorporated in the housing 7211 .
- the display device of one embodiment of the present invention can be applied to the display portion 7000 .
- FIG. 21C An example of digital signage is shown in FIG. 21C and FIG. 21D.
- a digital signage 7300 illustrated in FIG. 21C includes a housing 7301, a display portion 7000, speakers 7303, and the like. Furthermore, it can have an LED lamp, an operation key (including a power switch or an operation switch), connection terminals, various sensors, a microphone, and the like.
- FIG. 21D is a digital signage 7400 mounted on a cylindrical post 7401.
- FIG. A digital signage 7400 has a display section 7000 provided along the curved surface of a pillar 7401 .
- the display device of one embodiment of the present invention can be applied to the display portion 7000 in FIGS. 21C and 21D.
- the display portion 7000 As the display portion 7000 is wider, the amount of information that can be provided at one time can be increased. In addition, the wider the display unit 7000, the more conspicuous it is, and the more effective the advertisement can be, for example.
- a touch panel By applying a touch panel to the display portion 7000, not only an image or a moving image can be displayed on the display portion 7000 but also the user can intuitively operate the display portion 7000, which is preferable. Further, when used for providing information such as route information or traffic information, usability can be enhanced by intuitive operation.
- the digital signage 7300 or digital signage 7400 is preferably capable of cooperating with an information terminal 7311 or 7411 such as a smartphone possessed by the user through wireless communication.
- advertisement information displayed on the display unit 7000 can be displayed on the screen of the information terminal 7311 or the information terminal 7411 .
- display on the display portion 7000 can be switched.
- the digital signage 7300 or the digital signage 7400 can execute a game using the screen of the information terminal 7311 or 7411 as an operation means (controller). This allows an unspecified number of users to simultaneously participate in and enjoy the game.
- the electronic device shown in FIGS. 22A to 22F includes a housing 9000, a display unit 9001, a speaker 9003, operation keys 9005 (including a power switch or an operation switch), connection terminals 9006, sensors 9007 (force, displacement, position, speed , acceleration, angular velocity, number of rotations, distance, light, liquid, magnetism, temperature, chemical substances, sound, time, hardness, electric field, current, voltage, power, radiation, flow rate, humidity, gradient, vibration, smell, or infrared rays function), a microphone 9008, and the like.
- the display device of one embodiment of the present invention can be applied to the display portion 9001 in FIGS. 22A to 22F.
- the electronic devices shown in FIGS. 22A-22F have various functions. For example, a function to display various information (still images, moving images, text images, etc.) on the display unit, a touch panel function, a calendar, a function to display the date or time, a function to control processing by various software (programs), It can have a wireless communication function, a function of reading and processing programs or data recorded on a recording medium, and the like. Note that the functions of the electronic device are not limited to these, and can have various functions.
- the electronic device may have a plurality of display units.
- the electronic device is equipped with a camera, etc., and has the function of capturing still images or moving images and storing them in a recording medium (external or built into the camera), or the function of displaying the captured image on the display unit, etc. good.
- FIG. 22A is a perspective view showing a mobile information terminal 9101.
- the mobile information terminal 9101 can be used as a smart phone, for example.
- the portable information terminal 9101 may be provided with a speaker 9003, a connection terminal 9006, a sensor 9007, and the like.
- the mobile information terminal 9101 can display text and image information on its multiple surfaces.
- FIG. 22A shows an example in which three icons 9050 are displayed.
- Information 9051 indicated by a dashed rectangle can also be displayed on another surface of the display portion 9001 . Examples of the information 9051 include notification of incoming e-mail, SNS, telephone call, title of e-mail or SNS, sender name, date and time, remaining battery power, radio wave intensity, and the like.
- an icon 9050 or the like may be displayed at the position where the information 9051 is displayed.
- FIG. 22B is a perspective view showing the mobile information terminal 9102.
- the portable information terminal 9102 has a function of displaying information on three or more sides of the display portion 9001 .
- information 9052, information 9053, and information 9054 are displayed on different surfaces.
- the user can confirm the information 9053 displayed at a position where the mobile information terminal 9102 can be viewed from above the mobile information terminal 9102 while the mobile information terminal 9102 is stored in the chest pocket of the clothes.
- the user can check the display without taking out the portable information terminal 9102 from the pocket, and can determine, for example, whether to receive a call.
- FIG. 22C is a perspective view showing a wristwatch-type mobile information terminal 9200.
- the mobile information terminal 9200 can be used as a smart watch (registered trademark), for example.
- the display portion 9001 has a curved display surface, and display can be performed along the curved display surface.
- the mobile information terminal 9200 can also make hands-free calls by mutual communication with a headset capable of wireless communication, for example.
- the portable information terminal 9200 can transmit data to and from another information terminal through the connection terminal 9006, and can be charged. Note that the charging operation may be performed by wireless power supply.
- FIG. 22D to 22F are perspective views showing a foldable personal digital assistant 9201.
- FIG. 22D is a perspective view of the portable information terminal 9201 in an unfolded state
- FIG. 22F is a folded state
- FIG. 22E is a perspective view of a state in the middle of changing from one of FIGS. 22D and 22F to the other.
- the portable information terminal 9201 has excellent portability in the folded state, and has excellent display visibility due to a seamless wide display area in the unfolded state.
- a display portion 9001 included in the portable information terminal 9201 is supported by three housings 9000 connected by hinges 9055 .
- the display portion 9001 can be bent with a curvature radius of 0.1 mm or more and 150 mm or less.
- Example 1 results of inferring position information of a non-contact target using a display device of one embodiment of the present invention and a machine learning model using AI will be described.
- an image of a non-contact object was acquired using a display device.
- a machine learning model was trained using the data set of the images and position information. After that, images were input to the trained model, and the inference result of the position information of the object by the trained model was evaluated.
- FIG. 23A is a schematic diagram of an evaluation system showing the positional relationship between the display device and the light source used for evaluation.
- evaluation was performed using a display device 55 having sub-pixels R, G, B, and IRS as pixels.
- Sub-pixel R has a light-emitting device that emits red light.
- Sub-pixel G has a light-emitting device that emits green light.
- Sub-pixel B has a light-emitting device that emits blue light.
- An organic EL device was used as each light emitting device.
- the sub-pixel IRS has a light receiving device that detects infrared light.
- An organic photosensor was used as a light receiving device.
- the light source IR-LED an LED emitting infrared light with a wavelength of 880 nm was used and driven at 0.3A.
- the distance between the light source IR-LED and the display device 55 was about 3 cm.
- the infrared light (infrared light) emitted by the light source IR-LED is reflected by the target object 50 (reflected light), which is detected by the light receiving device of the sub-pixel IRS.
- the target object 50 three types of bare fingers, gray gloves, and glossy paper (total light reflectance of 80%) were used.
- the material of the gray gloves is a conductive fiber mixed with copper sulfide, which can be detected by a capacitive touch sensor.
- This evaluation was carried out by opening a 1 cm square opening (which can also be called a window) in the black plate 52 (total light reflectance of 5%) and exposing the object 50 through the opening.
- a 1 cm square opening which can also be called a window
- the black plate 52 total light reflectance of 5%
- the imaging data corresponds to an image obtained by cutting out a part of the image captured by the display device, which is used when estimating the position of the object.
- FIGS. 23B to 23D Examples of images of the object 50 actually captured by the display device 55 are shown in FIGS. 23B to 23D.
- FIG. 23B and FIG. 23C it was confirmed that even if the position of the target object 50 is the same, the imaging result differs depending on the type. Moreover, by comparing FIG. 23C and FIG. 23D, it was confirmed that even if the type of the target object 50 is the same, the imaging result differs depending on the position.
- 15000 images of the object 50 captured by the display device 55 were prepared as described above.
- the machine learning model was trained by giving image data as input data (example) and position information data as output data (answer) to the machine learning model.
- AlexNet Two types of machine learning models, AlexNet and MobileNet, which are models using a convolutional neural network (CNN), were used. Note that MobileNet is a lighter model with fewer parameters than AlexNet.
- CNN convolutional neural network
- each image data After resizing each image data to 100 pixels x 100 pixels, it was converted into a 100 x 100 array and input to the machine learning model.
- a regression model for estimating the value of position information (x, y, z) is created by inputting image data.
- image data was input to a trained model using MobileNet, and position information (x, y, z) was inferred.
- Table 2 shows the number of parameters of the trained model using AlexNet and the trained model using MobileNet, and the average errors of the inference results of 750 images.
- CL wiring, IR-LED: light source, IR: sub-pixel, IRS: sub-pixel, M11: transistor, M12: transistor, M13: transistor, M14: transistor, M15: transistor, NN: neural network, PS: sub-pixel, RS: Wiring, SE: Wiring, SW: Wiring, TX: Wiring, VCP: Wiring, VPI: Wiring, VRS: Wiring, WX: Wiring, 10: Electronic equipment, 11: Processing unit, 12: Display unit, 13: Storage Part, 15: Imaging data, 17: Image, 19: Position information, 31B: Light, 31G: Light, 31IR: Infrared light, 31R: Light, 32G: Reflected light, 32IR: Reflected light, 50: Object, 52 : black plate, 55: display device, 100A: display device, 100B: display device, 100C: display device, 100D: display device, 100E: display device, 100F: display device, 100G: display device, 100: display device, 101 : Layer including transistor 102: Sub
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Abstract
Description
図2A乃至図2Gは、表示装置の画素の一例を示す図である。
図3A及び図3Bは、表示装置の画素の一例を示す図である。図3C及び図3Dは、電子機器の一例を示す断面図である。
図4A及び図4Bは、電子機器の一例を示す断面図である。
図5A乃至図5Dは、表示装置の画素の一例を示す図である。図5Eは、電子機器の一例を示す断面図である。
図6は、表示装置のレイアウトの一例を示す図である。
図7は、表示装置のレイアウトの一例を示す図である。
図8は、表示装置のレイアウトの一例を示す図である。
図9は、表示装置のレイアウトの一例を示す図である。
図10は、画素回路の一例を示す図である。
図11Aは、表示装置の一例を示す上面図である。図11Bは、表示装置の一例を示す断面図である。
図12A乃至図12Cは、表示装置の一例を示す断面図である。
図13A及び図13Bは、表示装置の一例を示す断面図である。
図14A乃至図14Cは、表示装置の一例を示す断面図である。
図15A乃至図15Fは、表示装置の一例を示す断面図である。
図16は、表示装置の一例を示す斜視図である。
図17Aは、表示装置の一例を示す断面図である。図17B及び図17Cは、トランジスタの一例を示す断面図である。
図18A乃至図18Dは、表示装置の一例を示す断面図である。
図19A乃至図19Fは、発光デバイスの構成例を示す図である。
図20A及び図20Bは、電子機器の一例を示す図である。
図21A乃至図21Dは、電子機器の一例を示す図である。
図22A乃至図22Fは、電子機器の一例を示す図である。
図23Aは、実施例の評価方法の説明を示す図である。図23B乃至図23Dは、表示装置による撮像写真である。
本実施の形態では、本発明の一態様の電子機器及び表示装置について図1乃至図10を用いて説明する。
図1Aに、本発明の一態様の電子機器のブロック図を示す。
処理部11は、表示部12及び記憶部13などから供給されたデータを用いて、演算、推論などを行う機能を有する。処理部11は、演算結果、推論結果などを、記憶部13などに供給することができる。また、処理部11は、演算結果、推論結果などに基づいて、表示部12に供給する信号または電位を制御することができる。
記憶部13は、処理部11が実行するプログラムを記憶する機能を有する。また、記憶部13は、処理部11が生成した演算結果及び推論結果、並びに、表示部12が撮像した画像データなどを記憶する機能を有していてもよい。
上述の通り、表示部12には、発光デバイスと受光デバイスとを有する表示装置を用いることができる。ここで、表示装置の画素が、互いに異なる色を呈する副画素を3種類有する場合、当該3つの副画素としては、R、G、Bの3色の副画素、黄色(Y)、シアン(C)、及びマゼンタ(M)の3色の副画素などが挙げられる。当該副画素を4つ有する場合、当該4つの副画素としては、R、G、B、白色(W)の4色の副画素、R、G、B、Yの4色の副画素などが挙げられる。
本実施の形態では、本発明の一態様の表示装置について図11乃至図15を用いて説明する。
図11A及び図11Bに、本発明の一態様の表示装置を示す。
本実施の形態では、本発明の一態様の表示装置について図16乃至図18を用いて説明する。
図16に、表示装置100Fの斜視図を示し、図17Aに、表示装置100Fの断面図を示す。
図18Aに示す表示装置100Gは、白色発光の発光デバイスとカラーフィルタを組み合わせた、ボトムエミッション型の表示装置である点で、表示装置100Fと主に相違する。なお、以降の表示装置の説明においては、先に説明した表示装置と同様の部分については説明を省略することがある。
本実施の形態では、本発明の一態様の表示装置に用いることができる発光デバイスについて説明する。
本実施の形態では、上記の実施の形態で説明したOSトランジスタに用いることができる金属酸化物(酸化物半導体ともいう)について説明する。
酸化物半導体の結晶構造としては、アモルファス(completely amorphousを含む)、CAAC(c−axis−aligned crystalline)、nc(nanocrystalline)、CAC(cloud−aligned composite)、単結晶(single crystal)、及び多結晶(polycrystal)等が挙げられる。
なお、酸化物半導体は、構造に着目した場合、上記とは異なる分類となる場合がある。例えば、酸化物半導体は、単結晶酸化物半導体と、それ以外の非単結晶酸化物半導体と、に分けられる。非単結晶酸化物半導体としては、例えば、上述のCAAC−OS、及びnc−OSがある。また、非単結晶酸化物半導体には、多結晶酸化物半導体、擬似非晶質酸化物半導体(a−like OS:amorphous−like oxide semiconductor)、非晶質酸化物半導体、などが含まれる。
CAAC−OSは、複数の結晶領域を有し、当該複数の結晶領域はc軸が特定の方向に配向している酸化物半導体である。なお、特定の方向とは、CAAC−OS膜の厚さ方向、CAAC−OS膜の被形成面の法線方向、またはCAAC−OS膜の表面の法線方向である。また、結晶領域とは、原子配列に周期性を有する領域である。なお、原子配列を格子配列とみなすと、結晶領域とは、格子配列の揃った領域でもある。さらに、CAAC−OSは、a−b面方向において複数の結晶領域が連結する領域を有し、当該領域は歪みを有する場合がある。なお、歪みとは、複数の結晶領域が連結する領域において、格子配列の揃った領域と、別の格子配列の揃った領域と、の間で格子配列の向きが変化している箇所を指す。つまり、CAAC−OSは、c軸配向し、a−b面方向には明らかな配向をしていない酸化物半導体である。
nc−OSは、微小な領域(例えば、1nm以上10nm以下の領域、特に1nm以上3nm以下の領域)において原子配列に周期性を有する。別言すると、nc−OSは、微小な結晶を有する。なお、当該微小な結晶の大きさは、例えば、1nm以上10nm以下、特に1nm以上3nm以下であることから、当該微小な結晶をナノ結晶ともいう。また、nc−OSは、異なるナノ結晶間で結晶方位に規則性が見られない。そのため、膜全体で配向性が見られない。従って、nc−OSは、分析方法によっては、a−like OSまたは非晶質酸化物半導体と区別が付かない場合がある。例えば、nc−OS膜に対し、XRD装置を用いて構造解析を行うと、θ/2θスキャンを用いたOut−of−plane XRD測定では、結晶性を示すピークが検出されない。また、nc−OS膜に対し、ナノ結晶よりも大きいプローブ径(例えば50nm以上)の電子線を用いる電子線回折(制限視野電子線回折ともいう。)を行うと、ハローパターンのような回折パターンが観測される。一方、nc−OS膜に対し、ナノ結晶の大きさと近いかナノ結晶より小さいプローブ径(例えば1nm以上30nm以下)の電子線を用いる電子線回折(ナノビーム電子線回折ともいう。)を行うと、ダイレクトスポットを中心とするリング状の領域内に複数のスポットが観測される電子線回折パターンが取得される場合がある。
a−like OSは、nc−OSと非晶質酸化物半導体との間の構造を有する酸化物半導体である。a−like OSは、鬆または低密度領域を有する。即ち、a−like OSは、nc−OS及びCAAC−OSと比べて、結晶性が低い。また、a−like OSは、nc−OS及びCAAC−OSと比べて、膜中の水素濃度が高い。
次に、上述のCAC−OSの詳細について、説明を行う。なお、CAC−OSは材料構成に関する。
CAC−OSとは、例えば、金属酸化物を構成する元素が、0.5nm以上10nm以下、好ましくは、1nm以上3nm以下、またはその近傍のサイズで偏在した材料の一構成である。なお、以下では、金属酸化物において、一つまたは複数の金属元素が偏在し、該金属元素を有する領域が、0.5nm以上10nm以下、好ましくは、1nm以上3nm以下、またはその近傍のサイズで混合した状態をモザイク状、またはパッチ状ともいう。
続いて、上記酸化物半導体をトランジスタに用いる場合について説明する。
ここで、酸化物半導体中における各不純物の影響について説明する。
本実施の形態では、本発明の一態様の電子機器について、図20乃至図22を用いて説明する。
図23Aは、評価に使用した表示装置と光源との位置関係などを示す評価系の模式図である。
続いて、表示装置55で対象物50を撮像した画像と、位置情報(x,y,z)と、のデータセットを教師データに用いて、AIを利用した機械学習モデルの学習を行った。
まず、AlexNetを用いた学習済みモデルに、画像データを入力し、位置情報(x,y,z)の推論を行った。推論結果の例を表1に示す。
Claims (9)
- 表示部、処理部、及び、記憶部を有する電子機器であり、
前記表示部は、発光デバイスと受光デバイスとを有する表示装置を有し、
前記表示部は、前記発光デバイスを用いて画像を表示する機能と、前記受光デバイスを用いて撮像する機能と、を有し、
前記記憶部は、ニューラルネットワークを用いた機械学習モデルを有し、
前記処理部は、前記機械学習モデルを用いて、前記表示部で撮像された撮像データから、前記電子機器と接触していない対象物の位置情報を推論する機能を有する、電子機器。 - 表示部、処理部、及び、記憶部を有する電子機器であり、
前記表示部は、第1の画素を有する表示装置を有し、
前記第1の画素は、第1の発光デバイス、第1の受光デバイス、及び、第2の受光デバイスを有し、
前記第1の受光デバイスが検出する光の波長域は、前記第1の発光デバイスの発光スペクトルの最大ピーク波長を含み、
前記第2の受光デバイスは、赤外光を検出する機能を有し、
前記表示部は、前記第1の発光デバイスを用いて画像を表示する機能と、前記第1の受光デバイス及び前記第2の受光デバイスの一方または双方を用いて撮像する機能と、を有し、
前記記憶部は、ニューラルネットワークを用いた機械学習モデルを有し、
前記処理部は、前記機械学習モデルを用いて、前記表示部で撮像された撮像データから、前記電子機器と接触していない対象物の位置情報を推論する機能を有する、電子機器。 - 表示部、処理部、及び、記憶部を有する電子機器であり、
前記表示部は、第1の画素を有する表示装置を有し、
前記第1の画素は、第1の副画素、第2の副画素、第3の副画素、第4の副画素、及び、第5の副画素を有し、
前記第1の副画素は、第1の発光デバイスを有し、かつ、赤色の光を発する機能を有し、
前記第2の副画素は、第2の発光デバイスを有し、かつ、緑色の光を発する機能を有し、
前記第3の副画素は、第3の発光デバイスを有し、かつ、青色の光を発する機能を有し、
前記第4の副画素は、第1の受光デバイスを有し、かつ、前記第1の受光デバイスが検出する光の波長域は、前記第1の発光デバイス、前記第2の発光デバイス、及び、前記第3の発光デバイスのうち少なくとも一つの発光スペクトルの最大ピーク波長を含み、
前記第5の副画素は、第2の受光デバイスを有し、かつ、赤外光を検出する機能を有し、
前記表示部は、前記第1の副画素乃至前記第3の副画素を用いて画像を表示する機能と、前記第1の受光デバイス及び前記第2の受光デバイスの一方または双方を用いて撮像する機能と、を有し、
前記記憶部は、ニューラルネットワークを用いた機械学習モデルを有し、
前記処理部は、前記機械学習モデルを用いて、前記表示部で撮像された撮像データから、前記電子機器と接触していない対象物の位置情報を推論する機能を有する、電子機器。 - 請求項2または3において、
前記第1の受光デバイスの受光領域の面積は、前記第2の受光デバイスの受光領域の面積よりも小さい、電子機器。 - 請求項2乃至4のいずれか一において、
前記表示装置は、第2の画素を有し、
前記第2の画素は、前記第1の発光デバイス、前記第1の受光デバイス、及び、センサデバイスを有する、電子機器。 - 請求項5において、
前記電子機器は、前記センサデバイスを用いて、力、変位、位置、速度、加速度、角速度、回転数、距離、磁気、温度、化学物質、時間、硬度、電場、電流、電圧、電力、放射線、流量、湿度、傾度、振動、におい、体調、脈拍、体温、及び、血中の酸素濃度の少なくとも一つを測定する機能を有する、電子機器。 - 請求項2乃至4のいずれか一において、
前記表示装置は、第2の画素を有し、
前記第2の画素は、前記第1の発光デバイス、第4の発光デバイス、及び、前記第1の受光デバイスを有し、
前記第4の発光デバイスは、赤外光を発する機能を有する、電子機器。 - 請求項1乃至6のいずれか一において、
第4の発光デバイスを有し、
前記第4の発光デバイスは、赤外光を発する機能を有する、電子機器。 - 請求項8において、
前記第4の発光デバイスは、前記表示装置を介して、前記電子機器の外部に光を射出する、電子機器。
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