WO2022138398A1 - 油脂組成物 - Google Patents
油脂組成物 Download PDFInfo
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- WO2022138398A1 WO2022138398A1 PCT/JP2021/046374 JP2021046374W WO2022138398A1 WO 2022138398 A1 WO2022138398 A1 WO 2022138398A1 JP 2021046374 W JP2021046374 W JP 2021046374W WO 2022138398 A1 WO2022138398 A1 WO 2022138398A1
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- 235000021323 fish oil Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 235000021255 galacto-oligosaccharides Nutrition 0.000 description 1
- 150000003271 galactooligosaccharides Chemical class 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229930013686 lignan Natural products 0.000 description 1
- 150000005692 lignans Chemical class 0.000 description 1
- 235000009408 lignans Nutrition 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000012459 muffins Nutrition 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 235000021400 peanut butter Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000012830 plain croissants Nutrition 0.000 description 1
- 239000001259 polydextrose Substances 0.000 description 1
- 229940035035 polydextrose Drugs 0.000 description 1
- 235000013856 polydextrose Nutrition 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 235000012434 pretzels Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 235000012457 sweet doughs Nutrition 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- 235000012773 waffles Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
Definitions
- the present disclosure relates to oil and fat compositions suitable for spreads and fillings.
- Oily foods such as chocolate spread and peanut butter, which are mainly composed of fats and oils and sugars, are used for spreads or fillings. Such oily foods are required to have good melting in the mouth and easy to apply or pack, that is, soft physical characteristics. However, such oil-based foods have a problem that they harden over time and become difficult to apply. In addition, when the product is placed at a temperature higher than room temperature, there is a problem that fats and oils and solids are separated. In recent years, reducing the content of saturated fatty acids contained in oily foods has also become an issue. The properties of such oily foods are influenced by the fat and oil composition used. Therefore, the oil and fat composition has been improved.
- An example of the International Publication No. 2007/090477 pamphlet discloses a filling using a low SAFA fat (fat I).
- This low SAFA fat (fat I) is obtained through enzymatic transesterification and fractionation of 30% by weight, and has an iodine value (IV) of 33.7 SOS fats and oils and 70% by weight of high oleic acid. It consists of sunflower oil.
- the filling cream is disclosed.
- oil-based foods using low SAFA fats and oils (fat I) disclosed in International Publication No. 2007/090477 have a low saturated fatty acid content, but do not have sufficient heat resistance.
- oil-based food product using the formulation disclosed in International Publication No. 2018/149974 if the formulation does not contain a structuring agent, the oil-based food product does not have sufficient heat resistance.
- a formulation containing a structuring agent does not give a cold melt in the mouth.
- An object of the present disclosure is to develop an oil / fat composition which has a low saturated fatty acid content, good melting in the mouth, and good heat resistance, and is suitable for spreads and fillings.
- the present inventors have conducted diligent research to solve the above problems. As a result, it was found that the above-mentioned problems can be solved by using an oil / fat composition having a specific triglyceride composition, which is mainly characterized by the content of SU2 and the ratio of StUU contained in SU2. This completes this disclosure. That is, the present disclosure may take the following aspects.
- S Saturated fatty acids with 16 to 22 carbon atoms
- U Unsaturated fatty acid with 18 carbon atoms
- St stearic acid
- S3 Triglyceride containing 3 bound S molecules
- S2U A triglyceride containing two bound S molecules and one bound U molecule
- SU2 A triglyceride containing one bound S molecule and two bound U molecules
- U3 A triglyceride containing three bound U molecules
- StUU Triglyceride containing St bound to the 1-position, U bound to the 2- and 3-positions, and U bound to the 1- and 2-positions, and the U bound to the 3-position.
- Triglyceride which contains S and Show
- the oil / fat composition of [1] which has a mass ratio of the content of H3 to the content of S3 (H3 / S3) of 0.5 or more.
- H and H3 are respectively.
- H Saturated fatty acids with 18 to 22 carbon atoms
- H3 Triglyceride containing 3 bound H molecules, Show
- the oil / fat composition of [1] or [2] containing 1 to 10% by mass of diglyceride.
- Any of [1] to [3], wherein P of 30% by mass or less, St of 10 to 35% by mass, O of 40 to 65% by mass, and L of 5 to 30% by mass are constituent fatty acids.
- P of 30% by mass or less, St of 10 to 35% by mass, O of 40 to 65% by mass, and L of 5 to 30% by mass are constituent fatty acids.
- an oil / fat composition having a low saturated fatty acid content, good melting in the mouth, and good heat resistance, and suitable for spreads and fillings.
- a (numerical value) to B (numerical value) mean A or more and B or less.
- the preferable embodiment and the more preferable embodiment exemplified below can be used in combination with each other as appropriate regardless of the expressions such as “favorable” and “more preferable”.
- the description of the numerical range is an example. Regardless of expressions such as “preferable” or “more preferable”, a range defined by an appropriate combination of the upper limit or the lower limit of each numerical range and the numerical values of the examples can also be preferably applied.
- the main component of the oil and fat composition of the present disclosure is triglyceride (hereinafter, also referred to as TG).
- the oil and fat composition preferably contains 80% by mass or more, more preferably 85% by mass or more, still more preferably 90% by mass or more of triglyceride.
- the upper limit of the content of triglyceride contained in the oil / fat composition is not particularly limited.
- the content is preferably 99% by mass or less, more preferably 97% by mass or less, still more preferably 96% by mass or less.
- the fat and oil composition can be a mixture of two or more fats and oils.
- the fat and oil composition may contain trace components contained in natural fats and oils in addition to glycerides.
- trace components include free fatty acids, tocopherols, sterols, terpene alcohols, chlorophylls, chlorophyll degradation products and the like.
- the oil and fat composition of the present disclosure contains 1.0 to 8% by mass of S3.
- S refers to a saturated fatty acid having 16 to 22 carbon atoms. Specific examples of S include palmitic acid, stearic acid, arachidic acid, and behenic acid.
- S3 refers to a triglyceride containing three bound S molecules. In S3, two or three different S may be combined.
- the content of S3 contained in the oil / fat composition is preferably 1.5 to 7% by mass, more preferably 2 to 6.5% by mass, and further preferably 2 .5 to 6% by mass.
- the oil and fat composition of the present disclosure contains 5 to 30% by mass of S2U.
- U refers to an unsaturated fatty acid having 18 carbon atoms. Specific examples of U include oleic acid, linoleic acid, and linolenic acid.
- S2U refers to a triglyceride containing two bound S molecules and one bound U molecule. The binding position of two S and one U of S2U in the glycerin skeleton does not matter. Further, there is no limitation on the combination of S and U constituting S2U. Further, two different Ss may be combined. According to one aspect of the present disclosure, the content of S2U contained in the fat and oil composition is preferably 8 to 28% by mass, more preferably 9 to 26% by mass, and further preferably 10 to 25% by mass. Is.
- the oil and fat composition of the present disclosure contains 35 to 80% by mass of SU2.
- SU2 refers to a triglyceride containing one bound S molecule and two bound U molecules.
- the binding position of one S and two U of SU2 in the glycerin skeleton does not matter.
- two different Us may be combined.
- the content of SU2 contained in the fat and oil composition is preferably 40 to 75% by mass, more preferably 45 to 72% by mass, and further preferably 50 to 70% by mass. Is.
- the oil and fat composition of the present disclosure has a mass ratio of StUU content to SU2 content (StUU / SU2) of 0.15 to 0.95.
- St refers to stearic acid.
- StUU binds to triglycerides containing St bound to the 1st position of the glycerin skeleton and U bound to the 2nd and 3rd positions of the skeleton, and to the 1st and 2nd positions of the same skeleton. It is a triglyceride containing U and St bound to the 3-position of the same skeleton. In StUU, two different U may be combined.
- StUU / SU2 of the oil / fat composition when the content of S3 in the oil / fat composition is 1.0% by mass or more and less than 4% by mass, StUU / SU2 of the oil / fat composition is preferably 0.75 to 0.95. It is more preferably 0.81 to 0.93, still more preferably 0.85 to 0.92. Further, according to one aspect of the present disclosure, when the content of S3 contained in the oil / fat composition is 4 to 8% by mass, the StUU / SU2 of the oil / fat composition is preferably 0.15 to 0.75. Yes, more preferably 0.2 to 0.65, still more preferably 0.23 to 0.6, and even more preferably 0.25 to 0.55. When the content of S3 and StUU / SU2 are in the above range, the oil-based food containing the oil-and-fat composition has a good balance between heat resistance and melting in the mouth.
- the oil and fat composition of the present disclosure contains 5 to 45% by mass of U3.
- U3 refers to a triglyceride containing three bound U molecules.
- the content of U3 contained in the oil / fat composition is preferably 7 to 35% by mass, more preferably 8 to 30% by mass, still more preferably 9 to 28% by mass. Is.
- the oily food containing the oil and fat composition has good melting and heat resistance. And have. In addition, the phenomenon of hardening over time (post-hardening) is unlikely to occur.
- the fat and oil composition contains H3.
- H refers to a saturated fatty acid having 18 to 22 carbon atoms. Specific examples of H include stearic acid, arachidic acid, and behenic acid.
- H3 refers to a triglyceride containing three bound H molecules. In H3, two or three different Hs may be combined.
- the oil / fat composition is preferably 0.5 or more, more preferably 0.55 or more, still more preferably 0.60 or more, still more preferably 0.65 or more, most preferably 0.7 or more. It has a mass ratio of the content of H3 to the content of S3 (H3 / S3).
- the upper limit of H3 / S3 is 1.0 or less. However, the preferred H3 / S3 is 0.95 or less.
- the oil and fat composition contains 10 to 65% by mass of StUU.
- the content of StUU contained in the oil / fat composition is preferably 12 to 63% by mass, more preferably 14 to 61% by mass, and further preferably 15 to 58% by mass.
- the oily food containing the oil / fat composition has a good melting in the mouth.
- the oil / fat composition contains StOO with respect to the StUU content, preferably 0.7 or more, more preferably 0.75 or more, still more preferably 0.8 or more. It has a mass ratio of quantities (StOO / StUU).
- StOO is a triglyceride containing St bound to the 1st position of the glycerin skeleton and O bound to the 2nd and 3rd positions of the skeleton, and is bound to the 1st and 2nd positions of the skeleton. It is a triglyceride containing O and St bound to the 3-position of the same skeleton.
- the upper limit of StOO / StUU is 1.0, preferably 0.92.
- the fat and oil composition contains 1 to 10% by mass of diglyceride (hereinafter, also referred to as DG).
- Diglyceride is a glyceride containing two fatty acid molecules attached to the glycerin skeleton.
- the types of constituent fatty acids of diglyceride and their binding positions on the glycerin skeleton are not limited. However, the constituent fatty acids of diglyceride preferably have 16 to 22 carbon atoms.
- the content of diglyceride contained in the oil / fat composition is preferably 2 to 8% by mass, more preferably 3 to 6% by mass.
- the fat and oil composition may have the following fatty acid (hereinafter, also referred to as FA) composition. That is, the oil / fat composition contains 30% by mass or less of P, 10 to 35% by mass of St, 40 to 65% by mass of O, and 5 to 30% by mass of L.
- P refers to palmitic acid.
- L refers to a fatty acid having 18 carbon atoms and having two or more double bonds.
- the oil / fat composition preferably contains 5 to 28% by mass of P, 10 to 33% by mass of St, 43 to 63% by mass of O, and 6 to 20% by mass of L as constituent fatty acids.
- the fat and oil composition more preferably contains 8 to 27% by mass of P, 10 to 31% by mass of St, 45 to 62% by mass of O, and 7 to 15% by mass of L as constituent fatty acids. Further, the fat and oil composition preferably contains 25 to 45% by mass, more preferably 30 to 42% by mass of saturated fatty acids as constituent fatty acids. Further, the fat and oil composition preferably contains 0 to 3% by mass, more preferably 0 to 2% by mass, and a fatty acid having 14 or less carbon atoms as a constituent fatty acid. Further, the fat and oil composition preferably contains 0 to 2% by mass, more preferably 0 to 1% by mass, of a trans-type fatty acid as a constituent fatty acid.
- a conventionally known analysis method can be applied to the method of specifying the numerical value.
- the content of each triglyceride contained in fats and oils can be measured by a gas chromatography method (for example, based on AOCS Ce5-86).
- the symmetry of triglyceride can be measured according to a silver ion column chromatography method (for example, J. High Resol. Chromatogr., 18, 105-107 (1995)).
- the content of each constituent fatty acid contained in fats and oils can be measured by a gas chromatography method (for example, based on AOCS Ce1f-96).
- the method for preparing the oil and fat composition is not particularly limited.
- the fat and oil composition may be prepared with one fat and oil suitable for food or two or more fats and oils.
- edible fats and oils that can be used in fat and oil compositions include coconut oil, palm oil, shea butter, monkey fat, ilippe fat, kokum fat, mango fat, soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil and rice oil.
- processed fats and oils obtained by applying one or more of treatments such as mixing, fractionation, transesterification, and hydrogenation to these animal and vegetable fats and oils can be mentioned.
- One or more fats and oils selected from these exemplified fats and oils can be used.
- the fat and oil composition contains a fat and oil containing 50% by mass or more of StUU (hereinafter, also referred to as StUU fat and oil).
- StUU fats and oils are obtained from a reaction product obtained by a transesterification reaction using, for example, a mixture of high oleic sunflower oil and stearic acid ethyl ester and a 1,3-position selective lipase preparation based on a known method. It may be an oil or fat obtained by removing the fatty acid ethyl ester by distillation. Further, the StUU fat and oil may be a liquid portion obtained by further separation of the obtained fat and oil.
- the StUU fat and oil contains 30% by mass of StOSt (1,3-distearoyl-2-oleoylglycerol) such as monkey fat, shea butter, moler fat, mango kernel oil, allambracchia fat, and pentadesma fat. It may be a low melting point portion separated from fats and oils.
- StOSt (1,3-distearoyl-2-oleoylglycerol)
- monkey fat a butter
- moler fat moler fat
- mango kernel oil allambracchia fat
- pentadesma fat pentadesma fat.
- the StUU fats and oils have an iodine value of preferably 55 to 85, more preferably 60 to 80.
- the oil / fat composition contains an oil / fat containing 40% by mass or more of PU2 (hereinafter, also referred to as PU2 oil / fat).
- P refers to palmitic acid
- PU2 refers to a triglyceride containing one bound P molecule and two bound U molecules.
- the binding position of one P and two U of PU2 in the glycerin skeleton does not matter. There is no limitation on the combination of U constituting PU2. Two different U may be combined.
- Examples of PU2 fats and oils include a low melting point portion (palm olein) obtained by one-stage or two-stage separation of palm oil.
- the palm olein preferably has an iodine value of 62-75, more preferably 64-70.
- the PU2 fat and oil contains SU2 in an amount of 50% by mass or more, and the content of PU2 in SU2 is 80% by mass or more.
- the fat and oil composition contains a fat and oil containing 90% by mass or more of S3 (hereinafter, also referred to as S3 fat and oil).
- S3 oils and fats include various extremely hydrogenated oils.
- the raw material oils and fats of the extremely hardened oil include soybean oil, rapeseed oil, high erucic acid rapeseed oil, corn oil, cottonseed oil, red flower oil, sesame oil, sunflower oil, grape seed oil, palm oil, beef fat, pork fat, fish oil and the like.
- the above-mentioned separated oil for fats and oils and ester exchange oil can be mentioned.
- the extremely hydrogenated oil refers to an oil or fat obtained by hydrogenating a raw material oil or fat until the iodine value is 5 or less, preferably 2 or less.
- the S3 fat is preferably an extremely hardened high erucic acid rapeseed oil.
- the oil / fat composition contains an oil / fat containing 60% by mass or more of U3 (hereinafter, also referred to as U3 oil / fat).
- U3 fats and oils include soybean oil, rapeseed oil, corn oil, cottonseed oil, safflower oil, sesame oil, sunflower oil, grape seed oil, and these high oleic species.
- the oil and fat composition may contain 60 to 99% by mass of StUU oil and fat, 1 to 5% by mass of S3 oil and fat, and 0 to 39% by mass of U3 oil and fat.
- the fat composition may preferably contain 70-98% by weight of StUU fats and oils, 2-5% by weight of S3 fats and oils, and 0-28% by weight of U3 fats and oils.
- the fat and oil composition may more preferably contain 75 to 97% by mass of StUU fat and oil, 3 to 5% by mass of S3 fat and oil, and 0 to 22% by mass of U3 fat and oil.
- the oil / fat composition comprises 10 to 80% by mass of StUU oil, 19 to 89% by mass of PU2 oil, 1 to 5% by mass of S3 oil, and 0 to 30% by mass. It may contain U3 fats and oils.
- the fat and oil composition may preferably contain 20 to 70% by mass of StUU fat and oil, 28 to 78% by mass of PU2 fat and oil, 2 to 5% by mass of S3 fat and oil, and 0 to 20% by mass of U3 fat and oil.
- the fat and oil composition may more preferably contain 30 to 60% by mass of StUU fat and oil, 27 to 67% by mass of PU2 fat and oil, 3 to 5% by mass of S3 fat and oil, and 0 to 10% by mass of U3 fat and oil.
- ordinary additives used for edible fats and oils can be appropriately used in the fats and oils composition, if necessary.
- the use of additives is aimed at, for example, improvement of oxidative stability, improvement of thermal stability, or modification of physical properties.
- specific additives include anti-glycerides including glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polysorbate, and emulsifiers containing lecithin, tocopherol, ascorbic acid fatty acid ester, lignan, and coenzyme Q.
- examples include oxidants, colorants, and fragrances.
- the content of the additive contained in the oil / fat composition is preferably 0 to 2% by mass, more preferably 0 to 1% by mass, and further preferably 0 to 0.5% by mass.
- the fat and oil composition is prepared by heating and melting the raw material fats and oils such as StUU fats and oils, S3 fats and oils, or U3 fats and oils and an appropriately selected additive, if necessary, and then mixing them.
- the fat and oil composition may be plasticized by undergoing a step such as quenching and kneading after melting and mixing the raw material fat and oil.
- the oily foods disclosed in the present disclosure are foods having a continuous phase of fats and oils.
- the fat and oil contained in this oily food contains 80% by mass or more of the above-mentioned fat and oil composition of the present disclosure. That is, the ratio (content) of the fat and oil composition of the present disclosure to the fat and oil contained in the oily food is 80% by mass or more.
- the fats and oils contained in the oily food include fats and oils (for example, cocoa butter or milk fat) derived from an oil-containing raw material (for example, cocoa mass, cocoa powder, or whole fat powdered milk) in addition to the fat and oil composition of the present disclosure. ..
- the fat (cocoa butter) content of cocoa mass is 55% by mass (oil content 0.55).
- the fat (cocoa butter) content of the cocoa powder is 11% by mass (oil content 0.11).
- the fat (milk fat) content of the whole fat powder milk is 25% by mass (oil content 0.25).
- the total content of cocoa butter and milk fat in the fat and oil contained in the oily food is less than 20% by mass, and cocoa butter and milk fat are excluded from the fat and oil contained in the oily food.
- the oily food is included in the aspect of the oily food of the present disclosure. That is, the oily foods of the present disclosure include aspects of foods that substantially contain the oily and fat compositions of the present disclosure.
- the oil content of the oily food is preferably 25 to 55% by mass, more preferably 25 to 50% by mass, and further preferably 27 to 45% by mass. It is more preferably 28 to 42% by mass, and most preferably 29 to 40% by mass.
- the oily foods disclosed in this disclosure contain sugars.
- sugars contained in the oily foods of the present disclosure include sugar (sucrose), lactose, glucose, malt sugar, oligosaccharides, fructo-oligosaccharides, soybean oligosaccharides, galactooligosaccharides, milk fruit oligosaccharides, palatinose oligosaccharides, and enzyme saccharification.
- Examples thereof include water candy, reduced starch saccharified product, isomerized liquid sugar, sucrose-bound water candy, honey, reduced sugar polydextrose, raffinose, lactose, reduced lactose, sorbitol, xylose, xylitol, martitol, erythritol, mannitol, and trehalose.
- saccharide sugar alcohol may be used.
- the content of saccharides contained in the oily food is preferably 25 to 65% by mass, more preferably 30 to 60% by mass, still more preferably 35 to 55% by mass. Yes, more preferably 38-52% by mass.
- the amount of saccharides contained in the oily foods of the present disclosure does not include the amount of saccharides (for example, lactose contained in milk powder) contained in the raw materials of oily foods other than saccharides.
- the oily food may contain other raw materials commonly used in oily foods such as chocolate, butter cream, or sugar cream, which contain fats and sugars. ..
- other raw materials include dairy products containing whole fat powder and defatted milk powder, cocoa ingredients including cocoa mass and cocoa powder, pastes including nut paste and sesame paste, soy flour, soy protein, fruit processed powder, vegetable processing.
- powders including powder, matcha powder, and coffee powder, lecithin, lysolecithin, enzymatically decomposed lecithin, sucrose fatty acid ester, polyglycerin condensed lysinol acid ester, polyglycerin fatty acid ester, and emulsifier containing sorbitan fatty acid ester, tocopherol and ascorbic acid.
- Antioxidants, gums, starches, colorants, and fragrances including.
- the oily food can be produced by a conventionally known method.
- Soft chocolate-type oily foods use raw materials including, for example, fat compositions, sugars, cocoa ingredients, dairy products, and emulsifiers to mix, atomize (refining), scouring, and scouring. It can be manufactured through a cooling process.
- Sugar cream type oily foods are thoroughly stirred and mixed with a mixer with or without aeration using, for example, raw materials containing fat compositions, sugars, dairy products, and flavors. Thereby, it can be manufactured.
- a butter cream type oily food can be prepared, for example, by adding a raw material containing liquid sugar and a flavor to an oil / fat composition and sufficiently stirring and mixing with a mixer with or without aeration. Can be manufactured.
- oil-based foods have soft physical characteristics, good melting in the mouth, and good heat resistance. Therefore, it is suitable for spreading, filling, sanding, or coating bakery foods.
- bakery foods include donuts, bread, coppe bread, fruit bread, butter rolls, French bread, bread rolls, pastry bread, steamed bread, sweet dough, muffins, bagels, croissants, breads including Danish pastry, and castella, waffles, Bolo, Yatsuhashi, Senbei, Karinto, Sponge cake, Bread roll cake, Pound cake, Baumkuchen, Fruit cake, Madeleine, Shoe, Eclair, Milfille, Pie, Tart, Macaron, Biscuit, Cookies, Crackers, Pretzels, Wafers, Snacks, Examples include baked goods, including crepes, saffles, and puffs.
- the high melting point portion of the second stage was removed from the residual low melting point portion by acetone separation. Acetone was removed from the low melting point portion of the second stage thus obtained by a conventional method. Then, through decolorization treatment and deodorization treatment by a conventional method, StUU oil / fat-1 (iodine value 64, StUU content 62.6% by mass) was obtained. (StUU oil / fat-2) Refined shea olein fat (iodine value 70, StUU content 54.3% by mass) as a low melting point obtained by acetone separation of shea butter was used as StUU fat-2.
- PU2 oil / fat-1 Two-stage fractionated palm olein (iodine value 65, PU2 content 48.5% by mass, SU2 content 53.9% by mass) was used as PU2 fat-1.
- S3 fats and oils-1 Extremely hydrogenated oil of Hyelsin rapeseed oil was used as S3 oil-1.
- S3 fats and oils-2) Extremely hydrogenated rapeseed oil was used as S3 oil-2.
- S3 fats and oils-3) Extremely hydrogenated palm oil was used as S3 oil-3.
- U3 fats and oils-1) Hyoleic sunflower oil was used as U3 oil-1.
- U3 oil / fat-2) Canola oil was used as U3 oil-2.
Abstract
Description
(ただし、S、U、St、S3、S2U、SU2、U3、StU2は、それぞれ、
S:炭素数16~22の飽和脂肪酸、
U:炭素数18の不飽和脂肪酸、
St:ステアリン酸、
S3:3個の結合しているS分子を含有するトリグリセリド、
S2U:2個の結合しているS分子と、1個の結合しているU分子と、を含有するトリグリセリド、
SU2:1個の結合しているS分子と、2個の結合しているU分子と、を含有するトリグリセリド、
U3:3個の結合しているU分子を含有するトリグリセリド、
StUU:1位に結合しているStと、2位及び3位に結合しているUと、を含有するトリグリセリド、および、1位及び2位に結合しているUと、3位に結合しているSと、を含有するトリグリセリド、
を示す)
[2]0.5以上の、S3の含有量に対するH3の含有量の質量比(H3/S3)、を有する、[1]の油脂組成物。
(ただし、H、H3は、それぞれ、
H:炭素数18~22の飽和脂肪酸、
H3:3個の結合しているH分子を含有するトリグリセリド、
を示す)
[3]1~10質量%のジグリセリドを含む、[1]または[2]の油脂組成物。
[4]30質量%以下のP、10~35質量%のSt、40~65質量%のO、5~30質量%のL、を構成脂肪酸とする、[1]~[3]の何れか1つの油脂組成物。
(ただし、P、O、Lは、それぞれ、
P:パルミチン酸、
O:オレイン酸、
L:炭素数18の、2以上の二重結合を有する脂肪酸、
を示す)
[5]油脂および糖類を含む油性食品であって、前記油性食品に含まれる油脂に占める[1]~[4]の何れか1つの油脂組成物の割合が、80質量%以上である、前記油性食品。
(トリグリセリド)
油脂に含まれる各トリグリセリドの含有量は、ガスクロマトグラフィー法(AOCS Ce5-86準拠)により測定された。また、トリグリセリドの対称性は、J.High Resol.Chromatogr.,18,105-107(1995)に準じて銀イオンカラム-HPLC法で測定された。
(脂肪酸)
油脂を構成する各脂肪酸の含有量は、ガスクロマトグラフィー法(AOCS Ce1f-96準拠)により測定された。
油脂組成物の原料油脂として、以下の食用油脂(食用に適する程度に精製された油脂)を使用した。
(StUU油脂-1)
40質量部のハイオレイックヒマワリ油と、60質量部のステアリン酸エチルエステルと、の混合物と、1,3位選択性リパーゼ製剤と、を用いたエステル交換反応の後、ろ過処理によりリパーゼ製剤が除去された。このようにして得られたエステル交換反応物の薄膜蒸留により、反応物から脂肪酸エチルエステルが除去された。このようにして得られた蒸留残渣から、乾式分別により、高融点部が除去された。残余の低融点部から、アセトン分別により、2段目の高融点部が除去された。このようにして得られた2段目の低融点部から、常法により、アセトンが除去された。その後、常法による脱色処理及び脱臭処理を経て、StUU油脂-1(ヨウ素価64、StUU含有量62.6質量%)が得られた。
(StUU油脂-2)
シア脂のアセトン分別により得られた低融点部としてのシアオレインの精製油脂(ヨウ素価70、StUU含有量54.3質量%)がStUU油脂-2として使用された。
(PU2油脂-1)
2段分別パームオレイン(ヨウ素価65、PU2含有量48.5質量%、SU2含有量53.9質量%)がPU2油脂-1として使用された。
(S3油脂-1)
ハイエルシン菜種油の極度硬化油がS3油脂-1として使用された。
(S3油脂-2)
菜種油の極度硬化油がS3油脂-2として使用された。
(S3油脂-3)
パーム油の極度硬化油がS3油脂-3として使用された。
(U3油脂-1)
ハイオレイックヒマワリ油がU3油脂-1として使用された。
(U3油脂-2)
菜種油がU3油脂-2として使用された。
(その他油脂-1)
40質量部のハイオレイックヒマワリ油と、60質量部のステアリン酸エチルエステルと、の混合物と、1,3位選択性リパーゼ製剤と、を用いたエステル交換反応の後、ろ過処理によりリパーゼ製剤が除去された。このようにして得られたエステル交換反応物の薄膜蒸留により、反応物から脂肪酸エチルエステルが除去された。このようにして得られた蒸留残渣から、乾式分別により、高融点部が除去された。残余の低融点部から、アセトン分別により、2段目の低融点部が除去された。このようにして得られた中融点部から、常法により、アセトンが除去された。その後、常法による脱色処理及び脱臭処理を経て、その他油脂-1(S2U含有量89.7質量%、StOSt含有量73.1質量%)が得られた。
表1、2の配合に従って、油脂を加熱融解混合することにより、例1~例12の油脂組成物が調製された。表1及び2は、各油脂組成物の分析値を示す。
表3の配合にしたがって、原材料が混合された。常法にしたがって、微粒化(リファイニング)工程、および、精練(コンチング)工程、を経ることにより、例1から例14の油脂組成物を使用した融液状のチョコレート生地が得られた。このチョコレート生地を冷凍庫で固化することにより、各チョコレートスプレッドが得られた。
例1から例14の各油脂組成物を使用して得られたチョコレートスプレッドが、以下の手法により、評価された。評価は、AおよびBは合格を、Cは不合格を意味する。結果を、表1及び2に示した。
(耐熱性)
各スプレッドが、30℃および35℃の温度下に保存された。3ヵ月後に、油脂の分離状態(耐熱性)が観察された。
A:油脂の分離が無く、優良 (合格)
B:わずかに滲みがある程度、良(合格)
C:油脂の分離があり、不良 (不合格)
(硬さの変化)
各スプレッドが5℃の温度下に保存された。1ヵ月後および3ヵ月後に、テクスチャーアナライザー(ブルックフィールド社製、CT3)を用いて、以下の測定条件により、各スプレッドの応力(硬さ)が測定された。1ヵ月後の応力に対する3ヵ月後の応力の割合(3ヵ月後測定の応力/1ヵ月後測定の応力)を求めた。
測定条件:深度 10mm
速さ 2.0mm/s
A:1.2未満 硬さの変化がかなり少なく、優良(合格)
B:1.2以上1.5未満 硬さの変化が少なく、良 (合格)
C:1.5以上 硬さの変化があり、不良 (不合格)
(口どけ)
5℃で3ヵ月後保存された各スプレッドを、専門パネラー3名が、以下の基準で、総合的に評価した。
A:良好な口どけである (合格)
B:許容可能な口どけである (合格)
C:良くない口どけである (不合格)
Claims (5)
- 1.0~8質量%のS3、
5~30質量%のS2U、
35~80質量%のSU2、
5~45質量%のU3、を含み、
0.15~0.95の、SU2の含有量に対するStUUの含有量の質量比(StUU/SU2)、を有する、
油脂組成物。
(ただし、S、U、St、S3、S2U、SU2、U3、StU2は、それぞれ、
S:炭素数16~22の飽和脂肪酸、
U:炭素数18の不飽和脂肪酸、
St:ステアリン酸
S3:3個の結合しているS分子を含有するトリグリセリド、
S2U:2個の結合しているS分子と、1個の結合しているU分子と、を含有するトリグリセリド、
SU2:1個の結合しているS分子と、2個の結合しているU分子と、を含有するトリグリセリド、
U3:3個の結合しているU分子を含有するトリグリセリド、
StUU:1位に結合しているStと、2位及び3位に結合しているUと、を含有するトリグリセリド、および、1位及び2位に結合しているUと、3位に結合しているStと、を含有するトリグリセリド、
を示す) - 0.5以上の、S3の含有量に対するH3の含有量の質量比(H3/S3)、を有する、請求項1に記載の油脂組成物。
(ただし、H、H3は、それぞれ、
H:炭素数18~22の飽和脂肪酸
H3:3個の結合しているH分子を含有するトリグリセリド、
を示す) - 1~10質量%のジグリセリドを含む、請求項1または2に記載の油脂組成物。
- 30質量%以下のP、
10~35質量%のSt、
40~65質量%のO、
5~30質量%のL、
を構成脂肪酸とする、請求項1~3の何れか1項に記載の油脂組成物。
(ただし、P、O、Lは、それぞれ、
P:パルミチン酸、
O:オレイン酸、
L:炭素数18の、2以上の二重結合を有する脂肪酸、
を示す) - 油脂および糖類を含む油性食品であって、
前記油性食品に含まれる油脂に占める請求項1~4の何れか1項に記載の油脂組成物の割合が、80質量%以上である、前記油性食品。
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