WO2022137649A1 - 炭化珪素半導体装置 - Google Patents
炭化珪素半導体装置 Download PDFInfo
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- WO2022137649A1 WO2022137649A1 PCT/JP2021/031694 JP2021031694W WO2022137649A1 WO 2022137649 A1 WO2022137649 A1 WO 2022137649A1 JP 2021031694 W JP2021031694 W JP 2021031694W WO 2022137649 A1 WO2022137649 A1 WO 2022137649A1
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- silicon carbide
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 88
- 239000004065 semiconductor Substances 0.000 title claims abstract description 38
- 210000000746 body region Anatomy 0.000 claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 42
- 239000011229 interlayer Substances 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 22
- 239000013078 crystal Substances 0.000 description 14
- 238000010586 diagram Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 238000005530 etching Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000012535 impurity Substances 0.000 description 7
- 238000005468 ion implantation Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 238000001020 plasma etching Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
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- 238000004544 sputter deposition Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
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- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 239000011737 fluorine Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
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- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 1
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- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- PEUPIGGLJVUNEU-UHFFFAOYSA-N nickel silicon Chemical compound [Si].[Ni] PEUPIGGLJVUNEU-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7801—DMOS transistors, i.e. MISFETs with a channel accommodating body or base region adjoining a drain drift region
- H01L29/7802—Vertical DMOS transistors, i.e. VDMOS transistors
- H01L29/7813—Vertical DMOS transistors, i.e. VDMOS transistors with trench gate electrode, e.g. UMOS transistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0684—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
- H01L29/0692—Surface layout
- H01L29/0696—Surface layout of cellular field-effect devices, e.g. multicellular DMOS transistors or IGBTs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/08—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/0843—Source or drain regions of field-effect devices
- H01L29/0847—Source or drain regions of field-effect devices of field-effect transistors with insulated gate
- H01L29/0852—Source or drain regions of field-effect devices of field-effect transistors with insulated gate of DMOS transistors
- H01L29/0856—Source regions
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/10—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode not carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/1095—Body region, i.e. base region, of DMOS transistors or IGBTs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
- H01L29/1608—Silicon carbide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66053—Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide
- H01L29/66068—Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
Definitions
- This disclosure relates to silicon carbide semiconductor devices.
- a trench gate type MOSFET Metal Oxide Semiconductor
- FieldEffectTransistor FieldEffectTransistor
- the silicon carbide semiconductor device of the present disclosure includes a silicon carbide substrate having a first main surface and a second main surface opposite to the first main surface, and the silicon carbide substrate is a drift having a first conductive type.
- a plurality of gate trenches defined by a side surface leading to the drift region and a bottom surface connected to the side surface and extending in the first direction parallel to the first main surface are provided, and the contact region is the plurality of gate trenches.
- One of the first gate trenches is in contact with the first gate trench from both sides in the second direction perpendicular to the first direction, and is separated from the second gate trench adjacent to the first gate trench in the second direction.
- FIG. 7 is a cross-sectional view (No. 4) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 8 is a cross-sectional view (No. 5) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 9 is a cross-sectional view (No. 6) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 10 is a cross-sectional view (No. 7) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 11 is a cross-sectional view (No. 8) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 12 is a cross-sectional view (No. 9) showing a method of manufacturing the silicon carbide semiconductor device according to the embodiment.
- FIG. 13 is a diagram showing a relationship between a source region and a contact region in the method for manufacturing a silicon carbide semiconductor device according to an embodiment.
- FIG. 14 is a diagram showing a relationship between a gate trench, a source region, and a contact region in the method for manufacturing a silicon carbide semiconductor device according to an embodiment.
- FIG. 15 is a diagram showing a relationship between an interlayer insulating film, a source region, and a contact region in the method for manufacturing a silicon carbide semiconductor device according to an embodiment.
- An object of the present disclosure is to provide a silicon carbide semiconductor device capable of improving the uniformity of temperature distribution during operation.
- the silicon carbide semiconductor device includes a silicon carbide substrate having a first main surface and a second main surface opposite to the first main surface, and the silicon carbide substrate is a silicon carbide substrate.
- a drift region having a first conductive type, a body region provided on the drift region and having a second conductive type different from the first conductive type, and a body region provided on the body region so as to be separated from the drift region. It also has a source region having the first conductive type and a contact region provided on the body region and having the second conductive type, and the source region and the said are on the first main surface.
- the contact area is in contact with the first gate trench and away from the second gate trench.
- the source region is divided by the contact region in the first direction.
- the source region becomes a conductive region and the contact region becomes a non-conducting region. Therefore, in this case, the conductive region is divided by the non-conducting region in the first direction.
- a source region exists between the second gate trench and the contact region, and the source region is continuous in the first direction. Therefore, according to the silicon carbide semiconductor device according to this aspect, a continuous conduction region can be secured in the first direction.
- the conduction region is continuous in the first direction, the uniformity of heat generation can be improved and the uniformity of temperature distribution can be improved. Further, since the contact region is in contact with the first gate trench from both sides in the second direction, the total area of the contact region can be kept constant even if the pattern is displaced during the formation of the contact region. Therefore, stable characteristics can be obtained even if the contact region is displaced.
- the plurality of gate trenches are arranged in the second direction at the first pitch, and the dimension of the contact region in the second direction is 0.90 times or more the first pitch. . It may be 10 times or less. In this case, it is easy to apply an electric potential to the body region through the contact region, and it is easy to pass a sufficient current through the source region.
- a plurality of the contact regions may be arranged in the first direction along the first gate trench. In this case, it is easy to improve the uniformity of the temperature distribution.
- the plurality of contact regions may be arranged in an oblique grid pattern with respect to the first direction and the second direction. In this case, it is easy to pass a large current, and it is easy to apply an electric potential to the body region through the contact region.
- the side surface of the gate trench may include a ⁇ 0-33-8 ⁇ surface or a ⁇ 11-20 ⁇ surface. In this case, good mobility can be obtained on the side surface of the gate trench, and channel resistance can be reduced.
- FIG. 1 is a diagram showing a relationship between an interlayer insulating film, a source region, and a contact region in the silicon carbide semiconductor device according to the embodiment.
- 2 and 3 are cross-sectional views showing the configuration of the silicon carbide semiconductor device according to the embodiment.
- FIG. 1 corresponds to a plan view showing the arrangement of the gate trench, the source region, and the contact region on the first main surface of the silicon carbide substrate.
- FIG. 2 corresponds to a cross-sectional view taken along line II-II in FIG.
- FIG. 3 corresponds to a cross-sectional view taken along line III-III in FIG.
- the MOSFET 100 includes a silicon carbide substrate 10, a gate insulating film 81, a gate electrode 82, an interlayer insulating film 83, a source electrode 60, and a drain electrode 70.
- the silicon carbide substrate 10 includes a silicon carbide single crystal substrate 50 and a silicon carbide epitaxial layer 40 on the silicon carbide single crystal substrate 50.
- the silicon carbide substrate 10 has a first main surface 1 and a second main surface 2 opposite to the first main surface 1.
- the silicon carbide epitaxial layer 40 constitutes the first main surface 1
- the silicon carbide single crystal substrate 50 constitutes the second main surface 2.
- the silicon carbide single crystal substrate 50 and the silicon carbide epitaxial layer 40 are made of, for example, polytype 4H hexagonal silicon carbide.
- the silicon carbide single crystal substrate 50 contains a donor (n-type impurity) such as nitrogen (N) and has an n-type (first conductive type).
- the first main surface 1 is a surface on which the ⁇ 0001 ⁇ surface or the ⁇ 0001 ⁇ surface is inclined by an off angle of 8 ° or less in the off direction.
- the first main surface 1 is a surface on which the (000-1) surface or the (000-1) surface is inclined by an off angle of 8 ° or less in the off direction.
- the off direction may be, for example, the ⁇ 11-20> direction or the ⁇ 1-100> direction.
- the off angle may be, for example, 1 ° or more, or 2 ° or more.
- the off angle may be 6 ° or less, or 4 ° or less.
- the silicon carbide epitaxial layer 40 mainly has a drift region 11, a body region 12, a source region 13, and a contact region 18.
- the drift region 11 has an n-type due to the addition of a donor such as nitrogen or phosphorus (P). It is preferable that the addition of the donor to the drift region 11 is performed not by ion implantation but by the addition of impurities during the epitaxial growth of the drift region 11.
- the donor concentration in the drift region 11 is preferably lower than the donor concentration in the silicon carbide single crystal substrate 50.
- the donor concentration in the drift region 11 is preferably 1 ⁇ 10 15 cm -3 or more and 5 ⁇ 10 16 cm -3 or less, for example, about 8 ⁇ 10 15 cm -3 .
- the body region 12 is provided on the drift region 11.
- the body region 12 has a p-type (second conductive type) due to the addition of an acceptor (p-type impurity) such as aluminum (Al).
- the acceptor concentration of the body region 12 is, for example, about 1 ⁇ 10 18 cm -3 .
- the source region 13 is provided on the body region 12 so as to be separated from the drift region 11 by the body region 12.
- the source region 13 has an n-type due to the addition of a donor such as nitrogen or phosphorus.
- the source region 13 constitutes the first main surface 1.
- the donor concentration in the source region 13 is, for example, about 1 ⁇ 10 19 cm -3 .
- the contact region 18 has a p-type due to the addition of an acceptor such as aluminum.
- the contact area 18 constitutes the first main surface 1.
- the contact region 18 penetrates the source region 13 and touches the body region 12.
- the acceptor concentration of the contact region 18 is, for example, 1 ⁇ 10 18 cm -3 or more and 1 ⁇ 10 20 cm -3 or less.
- a plurality of gate trenches 5 are provided on the first main surface 1.
- the gate trench 5 extends in a first direction parallel to, for example, the first main surface 1, and a plurality of gate trenches 5 are arranged in a second direction parallel to the first main surface 1 and orthogonal to the first direction.
- the gate trench 5 has a bottom surface 4 composed of a drift region 11.
- the gate trench 5 has a side surface 3 that penetrates the contact region 18, the source region 13, and the body region 12 and is connected to the bottom surface 4.
- the bottom surface 4 is, for example, a plane parallel to the second main surface 2.
- the angle ⁇ 1 of the side surface 3 with respect to the plane including the bottom surface 4 is, for example, 45 ° or more and 65 ° or less.
- the angle ⁇ 1 may be, for example, 50 ° or more.
- the angle ⁇ 1 may be, for example, 60 ° or less.
- the side surface 3 preferably has a ⁇ 0-33-8 ⁇ surface or a ⁇ 11-20 ⁇ surface.
- the ⁇ 0-33-8 ⁇ plane and the ⁇ 11-20 ⁇ plane are crystal planes from which excellent mobility can be obtained.
- a plurality of contact areas 18 are lined up along the gate trench 5 in the first direction. Each contact region 18 contacts one of the plurality of gate trenches 5 from both sides in a second direction. Assuming that the gate trench 5 in contact with the contact region 18 is the first gate trench and the gate trench 5 adjacent to the first gate trench in the second direction is the second gate trench, the contact region 18 is separated from the second gate trench. There may be a source region 13 between the contact region 18 and the second gate trench. The source region 13 may be continuous in the first direction between the first gate trench and the second gate trench. A plurality of contact regions 18 may be arranged in the second direction at every other of the plurality of gate trenches 5. The plurality of contact regions 18 may be arranged in an oblique grid pattern with respect to the first direction and the second direction.
- the gate insulating film 81 is, for example, an oxide film.
- the gate insulating film 81 is made of, for example, a material containing silicon dioxide.
- the gate insulating film 81 is in contact with the side surface 3 and the bottom surface 4.
- the gate insulating film 81 is in contact with the drift region 11 on the bottom surface 4.
- the gate insulating film 81 is in contact with each of the contact region 18, the source region 13, the body region 12, and the drift region 11 on the side surface 3.
- the gate insulating film 81 may be in contact with the source region 13 on the first main surface 1.
- the interlayer insulating film 83 is provided in contact with the gate electrode 82 and the gate insulating film 81.
- the interlayer insulating film 83 is made of a material containing, for example, silicon dioxide.
- the interlayer insulating film 83 electrically insulates the gate electrode 82 and the source electrode 60.
- Contact holes 90 are formed in the interlayer insulating film 83 and the gate insulating film 81 at regular intervals in the second direction.
- the contact hole 90 is provided so that the gate trench 5 is located between the contact holes 90 adjacent to each other in the second direction.
- the contact hole 90 extends in the first direction. Through the contact hole 90, the source region 13 and the contact region 18 are exposed from the interlayer insulating film 83 and the gate insulating film 81.
- the source electrode 60 is in contact with the first main surface 1.
- the source electrode 60 has a contact electrode 61 provided in the contact hole 90 and a source wiring 62.
- the contact electrode 61 is in contact with the source region 13 and the contact region 18 on the first main surface 1.
- the contact electrode 61 is made of a material containing, for example, nickel silicide (NiSi).
- the contact electrode 61 may be made of a material containing titanium (Ti), Al, and Si.
- the contact electrode 61 is ohmic contacted with the source region 13 and the contact region 18.
- the source wiring 62 covers the upper surface and the side surface of the interlayer insulating film 83 and the upper surface of the contact electrode 61.
- the source wiring 62 is in contact with the contact electrode 61.
- the source wiring 62 is made of, for example, a material containing Al.
- the drain electrode 70 is in contact with the second main surface 2.
- the drain electrode 70 is in contact with the silicon carbide single crystal substrate 50 on the second main surface 2.
- the drain electrode 70 is electrically connected to the drift region 11.
- the drain electrode 70 is made of a material containing, for example, NiSi.
- the drain electrode 70 may be made of a material containing Ti, Al, and Si.
- the drain electrode 70 is ohmic-bonded to the silicon carbide single crystal substrate 50.
- the acceptor concentration and donor concentration in each of the impurity regions are measured by, for example, measurement using a scanning capacitance microscope (SCM) or secondary ion mass spectrometry (SIMS). Can be measured.
- SCM scanning capacitance microscope
- SIMS secondary ion mass spectrometry
- a drift region 11 is formed on the silicon carbide single crystal substrate 50 by epitaxial growth.
- a mixed gas of silane (SiH 4 ) and propane (C 3 H 8 ) is used as a raw material gas, and for example, hydrogen gas (H 2 ) is used as a carrier gas.
- Chemical Vapor Deposition It can be carried out by the CVD) method. At this time, it is preferable to introduce, for example, nitrogen (N) or phosphorus (P) as a donor.
- N nitrogen
- P phosphorus
- the ion implantation for forming the body region 12 an acceptor such as aluminum (Al) is ion-implanted.
- a donor such as phosphorus (P) is ion-implanted.
- the silicon carbide substrate 10 having the drift region 11, the body region 12, and the source region 13 is formed.
- epitaxial growth may be used with the addition of impurities.
- the contact region 18 is formed by ion implantation. As shown in FIG. 13, the contact region 18 is formed in an island shape so as to intersect the region where the gate trench 5 is formed. Next, an activation heat treatment is performed to activate the impurities added by ion implantation.
- the temperature of this heat treatment is preferably 1500 ° C. or higher and 1900 ° C. or lower, for example, about 1700 ° C.
- the heat treatment time is, for example, about 30 minutes.
- the atmosphere of the heat treatment is preferably an inert gas atmosphere, for example, an Ar atmosphere.
- the silicon carbide substrate 10 is prepared as described above.
- a mask 9 having an opening that partially exposes the source region 13 and the contact region 18 is formed on the silicon carbide substrate 10.
- the opening is formed corresponding to the position of the gate trench 5.
- a silicon oxide film formed by thermal oxidation can be used as the mask 9, for example.
- the source region 13, the contact region 18, the body region 12, and a part of the drift region 11 are removed by etching.
- etching method for example, reactive ion etching (RIE), particularly Inductive Coupled Plasma (ICP) RIE can be used.
- ICP-RIE Inductive Coupled Plasma
- SF 6 or a mixed gas of SF 6 and O 2 can be used as the reaction gas.
- the reaction gas may contain a carrier gas in addition to the chlorine gas and the oxygen gas.
- a carrier gas for example, nitrogen (N 2 ) gas, argon gas, helium gas and the like can be used.
- the etching rate of SiC is, for example, about 70 ⁇ m / hour.
- the mask 9 made of silicon oxide has an extremely large selectivity with respect to SiC, so that the mask 9 is not substantially etched during the etching of SiC.
- a gate trench 5 having a side surface 3 and a bottom surface 4 is formed on the silicon carbide substrate 10 by the above thermal etching.
- the silicon carbide substrate 10 is etched so as to be side-etched from the opening of the mask 9 as indicated by the arrow SE. Further, during thermal etching, a ⁇ 0-33-8 ⁇ surface is self-formed on the side surface 3.
- the mask 9 is removed from the first main surface 1 to form the gate insulating film 81.
- a gate insulating film 81 in contact with the source region 13, the body region 12, the drift region 11, and the contact region 18 is formed.
- the silicon carbide substrate 10 is heated at a temperature of, for example, 1300 ° C. or higher and 1400 ° C. or lower in an atmosphere containing oxygen.
- the first main surface 1 and the gate insulating film 81 in contact with the side surface 3 and the bottom surface 4 are formed.
- the gate insulating film 81 is formed by thermal oxidation, a part of the silicon carbide substrate 10 is incorporated into the gate insulating film 81. Therefore, in the subsequent treatment, it is assumed that the first main surface 1, the side surface 3 and the bottom surface 4 are slightly moved to the interface between the gate insulating film 81 after thermal oxidation and the silicon carbide substrate 10.
- heat treatment may be performed on the silicon carbide substrate 10 in a nitric oxide (NO) gas atmosphere.
- NO nitric oxide
- the silicon carbide substrate 10 is held for about 1 hour under the condition of, for example, 1100 ° C. or higher and 1400 ° C. or lower.
- nitrogen atoms are introduced into the interface region between the gate insulating film 81 and the body region 12.
- the formation of the interface state in the interface region is suppressed, so that the channel mobility can be improved.
- the gate electrode 82 is formed.
- the gate electrode 82 is formed on the gate insulating film 81.
- the gate electrode 82 is formed by, for example, a reduced pressure CVD (Low Pressure-Chemical Vapor Deposition: LP-CVD) method.
- the gate electrode 82 is formed so as to face each of the source region 13, the body region 12, and the drift region 11.
- the interlayer insulating film 83 is formed. Specifically, the interlayer insulating film 83 is formed so as to cover the gate electrode 82 and contact the gate insulating film 81.
- the interlayer insulating film 83 is formed by, for example, a CVD method.
- the interlayer insulating film 83 is made of a material containing, for example, silicon dioxide. A part of the interlayer insulating film 83 may be formed inside the gate trench 5.
- a contact hole 90 is formed in the interlayer insulating film 83 and the gate insulating film 81.
- the source region 13 and the contact region 18 are exposed from the interlayer insulating film 83 and the gate insulating film 81.
- a metal film (not shown) for the contact electrode 61 in contact with the source region 13 and the contact region 18 is formed on the first main surface 1.
- the metal film for the contact electrode 61 is formed by, for example, a sputtering method.
- the metal film for the contact electrode 61 is made of, for example, a material containing Ni.
- a metal film (not shown) for the drain electrode 70 in contact with the silicon carbide single crystal substrate 50 is formed on the second main surface 2.
- the metal film for the drain electrode 70 is formed by, for example, a sputtering method.
- the metal film for the drain electrode 70 is made of, for example, a material containing Ni.
- the metal film for the contact electrode 61 and the metal film for the drain electrode 70 are held at a temperature of, for example, 900 ° C. or higher and 1100 ° C. or lower for about 5 minutes. As a result, at least a part of the metal film for the contact electrode 61 and at least a part of the metal film for the drain electrode 70 react with the silicon contained in the silicon carbide substrate 10 to silicide. As a result, a contact electrode 61 that ohmic-bonds the source region 13 and the contact region 18 and a drain electrode 70 that ohmic-bonds the silicon carbide single crystal substrate 50 are formed.
- the contact electrode 61 may be made of a material containing Ti, Al, and Si.
- the drain electrode 70 may be made of a material containing Ti, Al, and Si.
- the source wiring 62 is formed. Specifically, the source wiring 62 that covers the contact electrode 61 and the interlayer insulating film 83 is formed.
- the source wiring 62 is formed by, for example, film formation by a sputtering method and RIE.
- the source wiring 62 is made of a material containing, for example, aluminum. In this way, the source electrode 60 having the contact electrode 61 and the source wiring 62 is formed.
- a current flows between the source electrode 60 and the drain electrode 70 when it is turned on, but this current flows through the source region 13 but not in the contact region 18. That is, the source region 13 becomes a conductive region, and the contact region 18 becomes a non-conducting region.
- the contact region 18 is in contact with one gate trench 5 and away from the adjacent gate trench 5. Therefore, the source region 13 exists between the adjacent gate trench 5 and the contact region 18, and the source region 13 is continuous in the first direction.
- the contact region 18 is in contact with the two gate trenches 5, the source region 13 is divided by the contact region 18 in the first direction. Therefore, according to the present embodiment, a continuous conduction region can be secured in the first direction. Further, although heat is generated by the flow of an electric current, since the conduction region is continuous in the first direction, the uniformity of heat generation can be improved and the uniformity of temperature distribution can be improved.
- FIG. 16 to 18 are diagrams showing the MOSFET 100 when the position of the pattern is displaced.
- FIG. 16 is a diagram showing the relationship between the source region 13 and the contact region 18 when the pattern is displaced in the manufacturing method of the MOSFET 100 according to the embodiment.
- FIG. 17 is a diagram showing the relationship between the interlayer insulating film 83, the source region 13, and the contact region 18 when the pattern is displaced in the manufacturing method of the MOSFET 100 according to the embodiment.
- FIG. 18 is a cross-sectional view showing the configuration of the MOSFET 100 according to the embodiment in which the pattern is displaced.
- each contact region 18 still has a misalignment.
- the total area of the contact region 18 exposed to each contact hole 90 is the same as the total area when there is no misalignment (see FIG. 15). Therefore, even if the position of the contact region 18 is displaced, the characteristics are unlikely to fluctuate, and stable characteristics can be obtained.
- the source region 13 is continuous in the first direction, a wide conduction region is secured and it is easy for current to flow in a wider range. That is, it is easy to pass a large current.
- the plurality of contact regions 18 are arranged in an oblique grid pattern with respect to the first direction and the second direction, it is easy to pass a large current, and it is easy to apply a potential to the body region 12 from the source electrode 60.
- a plurality of gate trenches 5 are arranged in the second direction at the first pitch P, and the dimension L of the contact region 18 in the second direction is 0.90 times or more the first pitch P. It is preferably 1.10 times or less, and more preferably 0.92 times or more and 1.08 times or less. If the dimension L is less than 0.90 times the first pitch P, the contact region 18 may become too small and it may be difficult to sufficiently apply the potential to the body region 12. If the dimension L is more than 1.10 times the first pitch P, the contact region 18 may become excessive and the contact region 18 may come into contact with two adjacent gate trenches 5 when a pattern shift occurs. .. When the contact region 18 comes into contact with two adjacent gate trenches 5, the conductive region is divided by the non-conducting region in the first direction, the heat generation uniformity may decrease, and the temperature distribution uniformity may decrease.
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Abstract
Description
従来のコンタクト領域が断続的に配置されたMOSFETでは、動作時の温度分布の均一性が低くなりやすい。これは、ソース-ドレイン間の電流はソース領域を流れる一方で、コンタクト領域を流れず、温度のむらが生じやすいためである。また、コンタクト領域をコンタクトホールの内側に配置した場合には、製造時にパターンの位置ずれが生じると、コンタクト領域の面積が不足し、特性が変動してしまう。
本開示によれば、動作時の温度分布の均一性を向上できる。
最初に本開示の実施態様を列記して説明する。以下の説明では、同一または対応する要素には同一の符号を付し、それらについて同じ説明は繰り返さない。本明細書中の結晶学的記載においては、個別方位を[]、集合方位を<>、個別面を()、集合面を{}でそれぞれ示している。また結晶学上の指数が負であることは、通常、”-”(バー)を数字の上に付すことによって表現されるが、本明細書中では数字の前に負の符号を付している。
本開示の実施形態は、いわゆる縦型のMOSFET(炭化珪素半導体装置)に関する。図1は、実施形態に係る炭化珪素半導体装置における層間絶縁膜と、ソース領域と、コンタクト領域との間の関係を示す図である。図2及び図3は、実施形態に係る炭化珪素半導体装置の構成を示す断面図である。図1は、炭化珪素基板の第1主面におけるゲートトレンチ、ソース領域及びコンタクト領域の配置を示す平面図に相当する。図2は、図1中のII-II線に沿った断面図に相当する。図3は、図1中のIII-III線に沿った断面図に相当する。
2 第2主面
3 側面
3A 内面
4 底面
5 ゲートトレンチ
5A 凹部
9 マスク
10 炭化珪素基板
11 ドリフト領域
12 ボディ領域
13 ソース領域
18 コンタクト領域
40 炭化珪素エピタキシャル層
50 炭化珪素単結晶基板
60 ソース電極
61 コンタクト電極
62 ソース配線
70 ドレイン電極
81 ゲート絶縁膜
82 ゲート電極
83 層間絶縁膜
90 コンタクトホール
100 MOSFET
Claims (7)
- 第1主面と、前記第1主面と反対側の第2主面とを有する炭化珪素基板を備え、
前記炭化珪素基板は、
第1導電型を有するドリフト領域と、
前記ドリフト領域上に設けられ、前記第1導電型と異なる第2導電型を有するボディ領域と、
前記ドリフト領域から隔てられるように前記ボディ領域上に設けられ、かつ前記第1導電型を有するソース領域と、
前記ボディ領域上に設けられ、かつ前記第2導電型を有するコンタクト領域と、
を有し、
前記第1主面には、前記ソース領域及び前記ボディ領域を貫通して前記ドリフト領域に至る側面と、前記側面と連なる底面とにより規定され、前記第1主面に平行な第1方向に延びる複数のゲートトレンチが設けられており、
前記コンタクト領域は、前記複数のゲートトレンチのうちの1つの第1ゲートトレンチに、前記第1方向に垂直な第2方向で両側から接し、かつ、前記第2方向で前記第1ゲートトレンチに隣接する第2ゲートトレンチから離れている炭化珪素半導体装置。 - 複数の前記ゲートトレンチは、前記第2方向に第1ピッチで配列し、
前記コンタクト領域の前記第2方向の寸法は、前記第1ピッチの0.90倍以上1.10倍以下である請求項1に記載の炭化珪素半導体装置。 - 複数の前記コンタクト領域が前記第1方向に、前記第1ゲートトレンチに沿って並んでいる請求項1または請求項2に記載の炭化珪素半導体装置。
- 前記第1ゲートトレンチと前記第2ゲートトレンチとの間で、前記ソース領域は前記第1方向で連続している請求項1から請求項3のいずれか1項に記載の炭化珪素半導体装置。
- 複数の前記コンタクト領域が前記第2方向に、複数の前記ゲートトレンチの1つおきに並んでいる請求項1から請求項4のいずれか1項に記載の炭化珪素半導体装置。
- 複数の前記コンタクト領域が、前記第1方向及び前記第2方向に対して斜め格子状に並んでいる請求項1から請求項5のいずれか1項に記載の炭化珪素半導体装置。
- 前記ゲートトレンチの前記側面は、{0-33-8}面又は{11-20}面を含む請求項1から請求項6のいずれか1項に記載の炭化珪素半導体装置。
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2016040844A (ja) * | 2008-03-03 | 2016-03-24 | 富士電機株式会社 | トレンチゲート型半導体装置の製造方法 |
WO2017126472A1 (ja) * | 2016-01-20 | 2017-07-27 | ローム株式会社 | 半導体装置 |
JP2019106483A (ja) * | 2017-12-13 | 2019-06-27 | 富士電機株式会社 | 絶縁ゲート型半導体装置及びその製造方法 |
JP2020043243A (ja) * | 2018-09-11 | 2020-03-19 | 富士電機株式会社 | 半導体装置 |
JP2020512682A (ja) * | 2016-12-08 | 2020-04-23 | クリー インコーポレイテッドCree Inc. | イオン注入側壁を有するゲート・トレンチを備えるパワー半導体デバイス及び関連方法 |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016040844A (ja) * | 2008-03-03 | 2016-03-24 | 富士電機株式会社 | トレンチゲート型半導体装置の製造方法 |
WO2017126472A1 (ja) * | 2016-01-20 | 2017-07-27 | ローム株式会社 | 半導体装置 |
JP2020512682A (ja) * | 2016-12-08 | 2020-04-23 | クリー インコーポレイテッドCree Inc. | イオン注入側壁を有するゲート・トレンチを備えるパワー半導体デバイス及び関連方法 |
JP2019106483A (ja) * | 2017-12-13 | 2019-06-27 | 富士電機株式会社 | 絶縁ゲート型半導体装置及びその製造方法 |
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