WO2021085268A1 - エポキシ化合物の製造方法 - Google Patents

エポキシ化合物の製造方法 Download PDF

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Publication number
WO2021085268A1
WO2021085268A1 PCT/JP2020/039561 JP2020039561W WO2021085268A1 WO 2021085268 A1 WO2021085268 A1 WO 2021085268A1 JP 2020039561 W JP2020039561 W JP 2020039561W WO 2021085268 A1 WO2021085268 A1 WO 2021085268A1
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WO
WIPO (PCT)
Prior art keywords
ion
epoxy compound
formula
represented
olefin
Prior art date
Application number
PCT/JP2020/039561
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
穣 人見
北山　健司
Original Assignee
株式会社ダイセル
学校法人同志社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社ダイセル, 学校法人同志社 filed Critical 株式会社ダイセル
Priority to CN202080075921.8A priority Critical patent/CN114981482A/zh
Publication of WO2021085268A1 publication Critical patent/WO2021085268A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/28—Per-compounds
    • C25B1/30—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation

Definitions

  • Examples of the salt (a) include sodium hydrogen carbonate, sodium hydrogen sulfate, disodium hydrogen phosphate and the like.
  • R 11 ⁇ R 14 in the formula (p) corresponds to the R 11 ⁇ R 14 in the formula (s).
  • the molar ratio of olefin to salt (a) supplied to the reaction system is, for example, 1/1000 to 1000/1, preferably 1/100 to 100/1, particularly preferably 1/10 to 10 /. It is 1.
  • the reaction through the steps [1] and [2] is carried out in a two-phase solvent of an aqueous phase containing the salt (a) and a water-insoluble organic solvent for dissolving the olefin in an aqueous phase / organic solvent phase.
  • a high-purity epoxy compound can be produced.
  • Examples of the ring in which two groups selected from R 1 to R 4 or R 7 to R 10 may be linked to each other to form together with adjacent carbon atoms include carbons such as a cyclopentene ring and a cyclohexene ring. It is a cycloalkene ring of the number 3-8. Further , examples of the ring in which R 5 and R 6 may be connected to each other and formed together with adjacent carbon atoms are, for example, a cycloalkane ring having 3 to 8 carbon atoms such as a cyclopentane ring and a cyclohexane ring.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
PCT/JP2020/039561 2019-10-29 2020-10-21 エポキシ化合物の製造方法 WO2021085268A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202080075921.8A CN114981482A (zh) 2019-10-29 2020-10-21 环氧化合物的制造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019-196508 2019-10-29
JP2019196508A JP7327758B2 (ja) 2019-10-29 2019-10-29 エポキシ化合物の製造方法

Publications (1)

Publication Number Publication Date
WO2021085268A1 true WO2021085268A1 (ja) 2021-05-06

Family

ID=75712602

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2020/039561 WO2021085268A1 (ja) 2019-10-29 2020-10-21 エポキシ化合物の製造方法

Country Status (4)

Country Link
JP (1) JP7327758B2 (zh)
CN (1) CN114981482A (zh)
TW (1) TW202124402A (zh)
WO (1) WO2021085268A1 (zh)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS496285A (zh) * 1972-05-22 1974-01-19
JPH05213919A (ja) * 1992-02-04 1993-08-24 Tosoh Corp 脂環式オレフィンのエポキシ化法
JPH06321924A (ja) * 1993-03-30 1994-11-22 Natl Starch & Chem Investment Holding Corp マンガン錯体によるオレフィン類のエポキシ化方法
JPH07305187A (ja) * 1994-05-11 1995-11-21 Sumitomo Chem Co Ltd エポキシ化合物及びフェノール類化合物の同時製造方法
JP2000248394A (ja) * 1999-03-02 2000-09-12 Permelec Electrode Ltd １，２−ジオール類及びその等価体類の製造方法
JP2003340286A (ja) * 2002-05-23 2003-12-02 Kao Corp エポキシ化触媒
JP2010001256A (ja) * 2008-06-20 2010-01-07 Osaka Univ エポキシ化合物の製造方法
JP2016525446A (ja) * 2013-07-24 2016-08-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ チタン含有ゼオライトの再生

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8310260D0 (en) * 1982-04-30 1983-05-18 Ici Plc Preparation of selected epoxides
JPS5974285A (ja) * 1982-10-19 1984-04-26 Asahi Chem Ind Co Ltd ヘキサフルオロプロピレンのエポキシ化方法
JPH09249984A (ja) * 1996-03-13 1997-09-22 Otsuka Chem Co Ltd 光学活性エポキシド誘導体の製造方法
CN102877086B (zh) * 2012-09-13 2014-12-31 华南理工大学 以烯烃与二氧化碳为原料电化学法制备环状碳酸酯的方法
CN105745195A (zh) * 2013-11-15 2016-07-06 康宁股份有限公司 氧化烯合成

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS496285A (zh) * 1972-05-22 1974-01-19
JPH05213919A (ja) * 1992-02-04 1993-08-24 Tosoh Corp 脂環式オレフィンのエポキシ化法
JPH06321924A (ja) * 1993-03-30 1994-11-22 Natl Starch & Chem Investment Holding Corp マンガン錯体によるオレフィン類のエポキシ化方法
JPH07305187A (ja) * 1994-05-11 1995-11-21 Sumitomo Chem Co Ltd エポキシ化合物及びフェノール類化合物の同時製造方法
JP2000248394A (ja) * 1999-03-02 2000-09-12 Permelec Electrode Ltd １，２−ジオール類及びその等価体類の製造方法
JP2003340286A (ja) * 2002-05-23 2003-12-02 Kao Corp エポキシ化触媒
JP2010001256A (ja) * 2008-06-20 2010-01-07 Osaka Univ エポキシ化合物の製造方法
JP2016525446A (ja) * 2013-07-24 2016-08-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ チタン含有ゼオライトの再生

Also Published As

Publication number Publication date
CN114981482A (zh) 2022-08-30
JP2021070835A (ja) 2021-05-06
JP7327758B2 (ja) 2023-08-16
TW202124402A (zh) 2021-07-01

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