WO2020218102A1 - Composition déodorante en poudre - Google Patents

Composition déodorante en poudre Download PDF

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Publication number
WO2020218102A1
WO2020218102A1 PCT/JP2020/016518 JP2020016518W WO2020218102A1 WO 2020218102 A1 WO2020218102 A1 WO 2020218102A1 JP 2020016518 W JP2020016518 W JP 2020016518W WO 2020218102 A1 WO2020218102 A1 WO 2020218102A1
Authority
WO
WIPO (PCT)
Prior art keywords
component
deodorant
powder composition
weight
average particle
Prior art date
Application number
PCT/JP2020/016518
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English (en)
Japanese (ja)
Inventor
慧記 唐澤
拓海 阿児
Original Assignee
小林製薬株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 小林製薬株式会社 filed Critical 小林製薬株式会社
Publication of WO2020218102A1 publication Critical patent/WO2020218102A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present invention relates to a deodorant powder composition having improved sprayability on a spray surface.
  • Deodorant products are usually provided in liquid or solid (stick) form.
  • the components to be blended in such deodorant products are selected according to the deodorizing mechanism. For example, antibacterial components that act on odor-causing bacteria and antiperspirants that suppress sweat that causes odors. Examples include components and deodorant components that adsorb odors.
  • Patent Document 1 alum (Patent Document 1), zinc undecylene (Patent Document 2) and the like are known as antibacterial components, and alum, aluminum hydroxychloride and the like (Patent Document 3) are known as antiperspirant components.
  • Patent Document 3 alum, aluminum hydroxychloride and the like
  • deodorant components metal oxides such as silica gel, alumina, titanium oxide, and zinc oxide (Patent Document 4) are known.
  • the deodorant product contains an inorganic powder such as talc, silica, or aluminum oxide in order to suppress stickiness against moisture such as sweat and give a good feeling of use (Patent Document 5). Often.
  • the powdery deodorant composition is used by spraying it on the surface to be deodorized.
  • the powdery deodorant composition is sprayed at the time of use. It needs to be spread (spread) over the entire surface and evenly adhered to the sprayed surface. Therefore, when the uniformity of adhesion and the ease of deployment (easiness of spreading) of the powdery deodorant composition on the spraying surface were examined, the problem that the uniformity of adhesion and the ease of deployment were incompatible was faced.
  • adhesion uniformity and deployability on the spray surface are compatible (hereinafter, the adhesion uniformity and deployability are collectively referred to as "sprayability”. )
  • An object is to provide a deodorant composition.
  • the present inventor has made a deodorizing composition by blending 10 to 45% by weight of silicon dioxide having an average particle size of 20 ⁇ m or less with talc and / or alum having an average particle size of 20 ⁇ m or less. Although it is a powder, it has been found that both uniformity of adhesion to the sprayed surface and ease of deployment can be achieved. The present invention has been completed by further studies based on this finding. That is, the present invention provides the inventions of the following aspects.
  • Item 1 It contains (A) silicon dioxide, (B) talc and / or (C) alum, and has an average particle size of 20 ⁇ m or less for the component (A), the component (B), and the component (C).
  • a deodorant powder composition containing 10 to 45% by weight of the component (A).
  • Item 2. Item 2. The deodorant powder composition according to Item 1, wherein the total amount of the product of the average particle size ( ⁇ m) and the content (% by weight) of the component (A) is 40 to 510.
  • Powder composition Item 4.
  • Item 2. The deodorant powder composition according to any one of Items 1 to 3, wherein the total amount of the component (B) and the component (C) is 35 to 65% by weight.
  • Item 5. Item 2.
  • Item 6. Item 2.
  • a powdery deodorant composition in a powdery deodorant composition, it is possible to achieve both uniformity of adhesion to the sprayed surface and ease of deployment, so that it is easy to use and effectively exerts a deodorizing effect. can do.
  • the deodorant powder composition of the present invention is also described as (A) silicon dioxide (hereinafter, also referred to as “(A) component”) and (B) talc (hereinafter, also referred to as “(B) component”). ) And / or (C) alum (hereinafter, also referred to as “component (C)”), and the component (A), the component (B), and the component (C) are specific average particles. It has a diameter and is characterized in that the component (A) is contained in a specific amount.
  • the deodorant powder composition of the present invention contains silicon dioxide as a component (A).
  • Silicon dioxide is a component known as a deodorant component in a deodorant composition, and is synonymous with silica and silicic anhydride.
  • the average particle size of the component (A) used in the deodorant powder composition of the present invention is 20 ⁇ m or less from the viewpoint of effectively obtaining the dispersability of the deodorant powder composition. From the viewpoint of obtaining more excellent dispersibility, the average particle size of the component (A) is preferably 18.5 ⁇ m or less, more preferably 17 ⁇ m or less.
  • the lower limit of the average particle size of the component (A) is not particularly limited, but is preferably 2 ⁇ m or more from the viewpoint of more preferably the effect of improving the ease of deployment by combining with the component (B).
  • "average particle diameter” means the cumulative 50% particle diameter (D 50 ) when measured using a laser diffraction scattering type particle size distribution measuring apparatus.
  • the component (A) silicon dioxide having the same average particle size may be used alone, or two or more different types of silicon dioxide may be used in combination.
  • the balance between the average particle size and the content of silicon dioxide affects the dispersability. Therefore, from the viewpoint of obtaining even better dispersibility, the total amount of the product of the average particle size ( ⁇ m) and the content (% by weight) of the component (A) is, for example, 40 to 510, preferably 45 to 300.
  • the component (A) can be blended so as to be more preferably 46 to 250, further preferably 47 to 200, and even more preferably 48 to 190.
  • the deodorant powder composition of the present invention has a characteristic of being in the form of powder, and therefore, when sprayed, it is excellent in handling by suppressing the risk of hand contamination due to scattering of the powder composition and contamination of parts other than the object to be sprayed. It is more preferable to have sex. Such handleability is also affected by the balance between the average particle size and the content of silicon dioxide. From the viewpoint of obtaining excellent handleability, the total amount of the product of the average particle size ( ⁇ m) and the content (% by weight) of the component (A) is 70 or more, preferably 80 or more, more preferably 90 or more. More preferably, it is 130 or more, and even more preferably 170 or more.
  • the content of the component (A) in the deodorant powder composition of the present invention is 10 to 45% by weight from the viewpoint of effectively obtaining dispersability. From the viewpoint of obtaining even better dispersibility, preferred examples of the content of the component (A) are 15 to 45% by weight, more preferably 15 to 25% by weight, still more preferably 18 to 23% by weight. ..
  • the ratio of the content of the component (A) to the total amount of the component (B) and the component (C) is not particularly limited and is determined by the content of each component. From the viewpoint of obtaining even better sprayability, the content of the component (A) per 1 part by weight of the total amount of the component (B) and the component (C) is 0.2 to 1.4 parts by weight, preferably 0. .25 to 1.35 parts by weight, more preferably 0.3 to 1.3 parts by weight.
  • the deodorant powder composition of the present invention may contain talc as a component (B).
  • Talc is a component known as a bulking agent in powder compositions and is synonymous with talc. Talc itself has good adhesion uniformity, but poor expandability (difficult to spread).
  • the ease of developing the component (A) can be improved by combining the component (B) with the component (A).
  • talc is a mineral composed of magnesium hydroxide and silicate, and more specifically, hydrous magnesium silicate (Mg 3 Si 4 O 10 (OH) 2 ).
  • the average particle size of the component (B) used in the deodorant powder composition of the present invention is 20 ⁇ m or less from the viewpoint of effectively obtaining the dispersability of the deodorant powder composition. From the viewpoint of obtaining even better dispersibility, the average particle size of the component (B) is preferably 18.5 ⁇ m or less, more preferably 17 ⁇ m or less, still more preferably 16.5 ⁇ m or less.
  • the lower limit of the average particle size of the component (B) is not particularly limited, but is preferably 10 ⁇ m or more, more preferably 14 ⁇ m or more, and further, from the viewpoint of more preferably the effect of improving the ease of deployment by combining with the component (A). It is preferably 16 ⁇ m or more.
  • the content of the component (B) in the deodorant powder composition of the present invention is not particularly limited, but from the viewpoint of obtaining even more excellent sprayability, for example, 25 to 60% by weight, preferably 25 to 50% by weight. Can be mentioned. Further, as the content of the component (B) in the deodorant powder composition of the present invention, the total amount of the component (B) and the component (C) is preferably 35 to 35 from the viewpoint of obtaining even more excellent sprayability. Examples thereof include an amount of 65% by weight, more preferably 40 to 60% by weight, still more preferably 50 to 60% by weight.
  • the deodorant powder composition of the present invention can contain alum as a component (C).
  • Alum itself has good adhesion uniformity, but poor expandability (difficult to spread).
  • the ease of developing the component (A) can be improved by combining the component (C) with the component (A).
  • alum has the general formula R III R I (SO 4) 2 ⁇ mH 2 O or R I [R III (H 2 O) 6] (SO 4) 2 ⁇ mH 2 O (m,, represents a 12,10,6,4,3,2 or 0.) represented by is the trivalent metal ion (R III) and monovalent metal ion or an ammonium ion (double salt of sulfate R I) .
  • R III trivalent metal ion
  • monovalent metal ion or an ammonium ion double salt of sulfate R I
  • RI examples of the monovalent metal ion or ammonium ion
  • potassium alum and grilled potassium alum are preferably mentioned, and more preferably grilled potassium alum is mentioned.
  • the average particle size of the component (C) used in the deodorant powder composition of the present invention is 20 ⁇ m or less from the viewpoint of effectively obtaining the dispersability of the deodorant powder composition. From the viewpoint of obtaining even better dispersibility, the average particle size of the component (C) is preferably 18.5 ⁇ m or less, more preferably 17 ⁇ m or less.
  • the lower limit of the average particle size of the component (C) is not particularly limited, but is preferably 10 ⁇ m or more, more preferably 14 ⁇ m or more, and further, from the viewpoint of more preferably the effect of improving the ease of deployment by combining with the component (A). It is preferably 16 ⁇ m or more.
  • the content of the component (C) in the deodorant powder composition of the present invention is not particularly limited, and can be appropriately determined according to the sprayability, the antibacterial effect to be exerted, and / or the antiperspirant effect. From the viewpoint of obtaining these effects better, a preferable example of the content of the component (C) is 5% by weight or more.
  • the upper limit of the content of the component (C) is not particularly limited, but from the viewpoint of reducing irritation to the skin by the alum itself, it is preferably less than 20% by weight, more preferably 15% by weight or less, still more preferably 12% by weight. Hereinafter, more preferably 10% by weight or less can be mentioned.
  • the deodorant powder composition of the present invention may contain an aluminum chloro compound as the component (D).
  • the aluminum chloro compound is a compound known as an antiperspirant component.
  • the aluminum chloro compound also exhibits antibacterial properties.
  • the aluminum chloro compound itself is excellent in expandability, but when combined with the component (B) and / or the component (C), the expandability is extremely deteriorated.
  • the deodorant powder composition of the present invention has excellent dispersability due to adhesion uniformity and improved ease of deployment due to the combination of the component (A), the component (B) and / or the component (C). Therefore, even if the component (D) is further combined, excellent sprayability can be effectively obtained.
  • the aluminum chloro species 1) the general formula Al 2 (OH) 6 - X Cl X (x is an aluminum chloride and aluminum hydroxychloride having the structure represented by the representative) 0-6. 2) Examples thereof include the above-mentioned derivatives of aluminum hydroxychloride.
  • the aluminum chloro compound may be anhydrous or hydrated.
  • AlCl 3 preferably, hexahydrate is mentioned.
  • the aluminum hydroxychloride include Al 2 (OH) 4 Cl 2 , Al 2 (OH) 4.5 Cl 1.5 , and Al 2 (OH) 5 Cl.
  • Derivatives of aluminum hydroxychloride include allantoin chlorohydroxyaluminum. Among these, aluminum hydroxychloride is preferable from the viewpoint of obtaining more preferable dispersibility.
  • the average particle size of the component (D) used in the deodorant powder composition of the present invention is 20 ⁇ m or less from the viewpoint of effectively obtaining the dispersability of the deodorant powder composition. From the viewpoint of obtaining even better dispersibility, the average particle size of the component (C) is preferably 15 ⁇ m or less, more preferably 10 ⁇ m or less, still more preferably 8 ⁇ m or less.
  • the lower limit of the average particle size of the component (C) is not particularly limited, but may be 2 ⁇ m or more, more preferably 5 ⁇ m or more, from the viewpoint of obtaining preferable ease of deployment.
  • the content of the component (D) in the deodorant powder composition of the present invention is not particularly limited, and can be appropriately determined according to the antiperspirant effect (astringent effect) and / or the antibacterial effect to be exerted.
  • Specific examples of the content of the component (D) include 5% by weight or more. From the viewpoint of obtaining a higher antiperspirant effect (astringent effect) and / or antibacterial effect, preferably 8% by weight or more, more preferably 9% by weight or more, still more preferably 10% by weight or more.
  • the upper limit of the content of the component (D) is not particularly limited, and examples thereof include 60% by weight or less.
  • the content of the component (D) is more preferably 50% by weight or less, more preferably 40% by weight or less, still more preferably 30% by weight or less, still more preferable. Is 20% by weight or less.
  • the deodorant powder composition of the present invention may contain other active ingredients, if necessary.
  • the average particle size of the other active ingredient is preferably 20 ⁇ m or less, more preferably 18 ⁇ m or less.
  • the active ingredient include antibacterial ingredients other than the above ingredients (benzalkonium chloride, benzethonium chloride, chlorhexidine hydrochloride, phenol, trichlorocarbanilide, chlorhexidine gluconate, isopropylmethylphenol, triclosan, salicylic acid, sorbic acid, lysoteam chloride, etc.
  • Hinokithiol, silver oxide, etc.), antiperspirant components other than the above components aluminum sulfate, aluminum acetate, aluminum chloride, etc.
  • deodorant components other than the above components active charcoal, montmorillonite, aluminosilicate, zinc oxide, copper oxide, alumina, etc.
  • Titanium oxide, iron oxide, zirconium oxide, zirconium hydroxide, etc. antihistamines (diphenhydramine, diphenhydramine hydrochloride, chlorpheniramine maleate, etc.), local anesthetics (lydocaine, dibucaine, methyl aminobenzoate, procaine, tetracaine, bupipacaine, etc.)
  • Mepipacine chloroprocine, proparakine, meprilcaine or salts thereof, orthokine, oxesesazein, oxypolyentoxydecane, funnel extract, percaminpase, tesitdecitin, etc.), anti
  • the deodorant powder composition of the present invention may contain a base or an additive, if necessary, in addition to the above-mentioned components, depending on the formulation form.
  • the average particle size of the other bases and additives is preferably 20 ⁇ m or less, more preferably 18 ⁇ m or less.
  • the base and additives are not particularly limited as long as they are pharmaceutically or cosmetically acceptable, but for example, bulking agents other than the above (calcium carbonate, clay, kaolin); water; monohydric alcohols ( Ethanol, propanol, etc.) Natural oils (olive oil, saflower oil, soybean oil, camellia oil, corn oil, rapeseed oil, sunflower oil, cottonseed oil, peanut oil, lard, squalane, fish oil, etc.); Mineral oil (liquid paraffin, paraffin, paraffin, Gelled hydrocarbons, vaseline, etc.), waxes / waxes (mitsurou, carnauba wax, candelilla wax, ceresin, rice wax, microcrystalin wax, etc.), ester oils (isopropyl myristate, isopropyl adipate, diethyl sebacate, sebacin) Isopropyl acid, isopropyl palmitate, cetyl palmitate, ethyl o
  • Oil-based bases such as phytosterol, lauryl alcohol, cetostearyl alcohol, linoleil alcohol, octyldodecanol, hexyldecanol, isostearyl alcohol, etc.), cetyl 2-ethylhexanoate, silicone oil (dimethylpolysiloxane, cyclic silicone, etc.); POE (10-50 mol) Phytosterol ether, POE (10-50 mol) dihydrocholesterol ether, POE (10-50 mol) 2-octyldodecyl ether, POE (10-50 mol) decyltetradecyl ether, POE (10-50 mol) Mol) oleyl ether, POE (2-50 mol) cetyl ether, POE (5-50 mol) behenyl ether, POE (5-30 mol) polyoxypropylene (5-30 mol) 2-decyltetradecyl ether, POE (mol) Polyoxyethylene
  • pH adjuster phosphate, hydrochloric acid, succinic acid, tartrate acid, triethanolamine, triisopropanolamine, etc.
  • stabilizer dibutylhydroxytoluene, butylhydroxyanisole, sodium edetate, sodium metaphosphate, L, etc.
  • antioxidants UV absorbers, chelating agents , Adhesives, buffers, solubilizers, solubilizers, preservatives and other additives.
  • the formulation form of the deodorant powder composition of the present invention is in the form of powder.
  • the particles of the active ingredient itself can be directly applied to the target. Applying the active ingredient to the subject in the form of particles is liquid and because the deodorant effect is maximized by applying the active ingredient at the maximum concentration in the microscopic region where the applied particles are in contact. It is significantly superior to the deodorant composition formulated in solid form.
  • the deodorant powder composition of the present invention is excellent in the ease of adhesion and thus the uniformity of the particles adhering on the target surface, the fine region to which the active ingredient is applied at the maximum concentration is formed. Each is formed evenly over the entire surface of the object. Therefore, the deodorant powder composition of the present invention is extremely excellent in deodorant properties.
  • the deodorant powder composition of the present invention may be in any form of an external preparation that is directly applied to the skin and a non-external preparation that is not directly applied to the skin.
  • an external preparation it may be in any of a skin external medicine, a quasi-drug, and a cosmetic. Since the deodorant powder composition of the present invention is excellent in sprayability, it is particularly useful when it is used as a non-external agent which is inherently difficult to spray on a subject.
  • the deodorant powder composition of the present invention can be used as a deodorant (deodorant) product.
  • the deodorant powder composition of the present invention is an external preparation, it can be used for direct application or spraying on the skin in the same manner as in the usual method of using the external preparation (powder preparation).
  • the deodorant powder composition of the present invention is a non-external preparation, it can be used by directly spraying it on an antibacterial object.
  • Antibacterial targets include articles that are prone to sweat and germs due to direct or indirect contact with the skin, more preferably inside footwear (shoes, slippers, sandals), footwear (socks, stockings), etc.
  • rugs carpets, carpets, cushion floors, flooring
  • rugs which are hot and humid and have a lot of contact with sweat and germs, more preferably the opportunity to wash.
  • the inside of footwear with no or few is mentioned. Even in footwear, by covering the instep and heel, there are more opportunities for contact with sweat and germs due to higher temperature and humidity, and due to its structure, it is inherently difficult to spray the powder composition inside. , Shoes are especially preferred.
  • deodorant powder compositions having the compositions shown in Tables 2 to 4 were prepared.
  • Al 2 (OH) 5 Cl was used as the aluminum hydroxychloride
  • baked potassium alum was used as the alum.
  • About 0.25 cm 3 of the deodorant powder composition was allowed to stand in the center of the synthetic leather (1 cm ⁇ 1 cm).
  • the petri dish was installed in a vibrator (ALMIGHTY SHAKER AS-1) and vibrated in the vertical direction for 10 seconds (amplitude 4 cm, 250 reciprocations / minute) and then in the horizontal direction for 10 seconds (same conditions as in the vertical direction).
  • AFMIGHTY SHAKER AS-1 The deodorant powder composition spread on synthetic leather was evaluated for adhesion uniformity and ease of deployment by the following methods.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Cosmetics (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

L'objet de la présente invention consiste à fournir une composition déodorante qui se présente sous la forme d'une poudre et permet néanmoins d'obtenir à la fois une adhérence uniforme à une surface d'application et une aptitude à l'étalement facile pour ainsi avoir d'excellentes propriétés d'application. Une composition déodorante en poudre comprend (A) du dioxyde de silicium, (B) du talc et/ou (C) de l'alun, le diamètre moyen des particules des constituants (A), (B) et (C) étant inférieur ou égal à 20 µm et la teneur en constituant (A) étant de 10 à 45 % en poids. Cette composition déodorante en poudre permet d'obtenir à la fois une adhérence uniforme à une surface d'application et une aptitude à l'étalement facile et présente ainsi d'excellentes propriétés d'application.
PCT/JP2020/016518 2019-04-26 2020-04-15 Composition déodorante en poudre WO2020218102A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019-084870 2019-04-26
JP2019084870A JP7486287B2 (ja) 2019-04-26 2019-04-26 消臭用粉末組成物

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WO2020218102A1 true WO2020218102A1 (fr) 2020-10-29

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7313243B2 (ja) * 2019-09-18 2023-07-24 ライオン株式会社 靴用粉末消臭剤組成物、容器入り粉末消臭剤組成物、及び消臭方法
JP2021101886A (ja) * 2019-12-25 2021-07-15 ライオン株式会社 靴用粉末消臭剤組成物

Citations (8)

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Publication number Priority date Publication date Assignee Title
JP2004307375A (ja) * 2003-04-04 2004-11-04 Shiseido Co Ltd 皮膚外用剤
JP2005530724A (ja) * 2002-04-12 2005-10-13 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 消臭剤及び制汗剤におけるアリールスルファターゼ阻害剤としてのヒドロキシジフェニルエーテル誘導体の使用
JP2005306847A (ja) * 2004-03-26 2005-11-04 Kose Corp 固形粉末化粧料
JP2012224556A (ja) * 2011-04-15 2012-11-15 Kose Corp 含水粉末状化粧料
JP2014105186A (ja) * 2012-11-28 2014-06-09 Shiseido Co Ltd 皮膚外用剤
WO2014187739A1 (fr) * 2013-05-23 2014-11-27 L'oreal Utilisation cosmétique de particules de silice hydrophobe en tant que principe actif déodorant
JP2016000719A (ja) * 2014-05-20 2016-01-07 ライオン株式会社 エアゾール型デオドラント組成物
JP2018048088A (ja) * 2016-09-21 2018-03-29 株式会社シービック 肌色補正用化粧料組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005530724A (ja) * 2002-04-12 2005-10-13 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 消臭剤及び制汗剤におけるアリールスルファターゼ阻害剤としてのヒドロキシジフェニルエーテル誘導体の使用
JP2004307375A (ja) * 2003-04-04 2004-11-04 Shiseido Co Ltd 皮膚外用剤
JP2005306847A (ja) * 2004-03-26 2005-11-04 Kose Corp 固形粉末化粧料
JP2012224556A (ja) * 2011-04-15 2012-11-15 Kose Corp 含水粉末状化粧料
JP2014105186A (ja) * 2012-11-28 2014-06-09 Shiseido Co Ltd 皮膚外用剤
WO2014187739A1 (fr) * 2013-05-23 2014-11-27 L'oreal Utilisation cosmétique de particules de silice hydrophobe en tant que principe actif déodorant
JP2016000719A (ja) * 2014-05-20 2016-01-07 ライオン株式会社 エアゾール型デオドラント組成物
JP2018048088A (ja) * 2016-09-21 2018-03-29 株式会社シービック 肌色補正用化粧料組成物

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JP2020180086A (ja) 2020-11-05

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