WO2019098228A1 - 液晶ポリエステル組成物および樹脂成形体 - Google Patents
液晶ポリエステル組成物および樹脂成形体 Download PDFInfo
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- WO2019098228A1 WO2019098228A1 PCT/JP2018/042107 JP2018042107W WO2019098228A1 WO 2019098228 A1 WO2019098228 A1 WO 2019098228A1 JP 2018042107 W JP2018042107 W JP 2018042107W WO 2019098228 A1 WO2019098228 A1 WO 2019098228A1
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- crystal polyester
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/38—Polymers
- C09K19/3804—Polymers with mesogenic groups in the main chain
- C09K19/3809—Polyesters; Polyester derivatives, e.g. polyamides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
Definitions
- the present invention relates to a liquid crystal polyester composition and a resin molded product.
- Priority is claimed on Japanese Patent Application No. 2017-220365, filed Nov. 15, 2017, the content of which is incorporated herein by reference.
- Liquid crystal polyester is a material that is easy to mold and process and has high heat resistance, high mechanical strength, or excellent insulation. In addition, liquid crystal polyester has high flame retardancy. Taking advantage of these features, liquid crystal polyester is applied to various applications including parts for electric and electronic parts and parts for optical devices.
- the liquid crystalline polyester is usually not used alone, and is used as a liquid crystalline polyester composition in which a filler is contained in LCP (liquid crystalline polyester) in order to satisfy the required characteristics (for example, bending strength) in various applications. There is.
- the electric / electronic part or optical may be caused due to foreign matter generated from the molded article.
- the yield in the assembly process of equipment parts may be reduced.
- malfunction may be caused due to foreign matter generated from the molded products. Then, the molded object by which generation
- Patent Document 1 describes a liquid crystal polyester resin composition that can prevent the generation of surface particles (foreign matter).
- the liquid crystal polyester resin composition described in Patent Document 1 contains 0.01 to 10 parts by weight of activated carbon, 5 to 50 parts by weight of glass fiber, and 1 to 50 parts by weight of flaky mica with respect to 100 parts by weight of liquid crystal polyester. ing.
- liquid crystal polyester resin composition described in Patent Document 1 can not necessarily suppress the generation of foreign matter, and further improvement is required.
- This invention is made in view of such a situation, Comprising: It aims at providing the liquid-crystal polyester composition and resin molded object by which generation
- one mode of the present invention contains liquid crystalline polyester and a fibrous filler, and the fibrous filler is a long fiber having a fiber length of 80 ⁇ m or more, 30 for the number of the fibrous filler. %, And the number average fiber diameter of the fibrous filler is 12 ⁇ m or less.
- One aspect of the present invention includes a liquid crystalline polyester and a fibrous filler, the number average fiber length of the fibrous filler is 15 ⁇ m or more and 60 ⁇ m or less, and the number average fiber diameter of the fibrous filler is 12 ⁇ m or less Liquid crystalline polyester composition is provided.
- the fibrous filler may have a number average fiber diameter of 6 ⁇ m or less.
- the content of the fibrous filler may be 10 parts by mass or more and 150 parts by mass or less with respect to 100 parts by mass of the liquid crystal polyester.
- One aspect of the present invention provides a resin molded product using the above-mentioned liquid crystal polyester composition as a forming material.
- the present invention includes the following aspects.
- the "foreign matter” is a component derived from the liquid crystal polyester composition which is generated when assembling or using an electric / electronic device or an optical device using the resin molded body formed from the liquid crystal polyester composition as a component.
- it means fibrous fillers, liquid crystal polyester resins, and mixtures thereof.
- the liquid crystal polyester composition of the present embodiment is used as a forming material of a resin molded body described later.
- the liquid crystal polyester composition of the present embodiment contains a liquid crystal polyester and a fibrous filler.
- the liquid crystal polyester according to the liquid crystal polyester composition of the present embodiment is a material exhibiting liquid crystallinity in a molten state.
- the liquid crystalline polyester may be a liquid crystalline polyester amide, a liquid crystalline polyester ether, a liquid crystalline polyester carbonate, or a liquid crystalline polyester imide.
- the flow start temperature of the liquid crystal polyester according to the present embodiment is preferably 330 ° C. or more.
- the flow start temperature of the liquid crystalline polyester is more preferably 330 ° C. or more and 450 ° C. or less, still more preferably 330 ° C. or more and 400 ° C. or less, and particularly preferably 330 ° C. or more and 390 ° C. or less.
- the flow start temperature may be 340 ° C. or higher, 350 ° C. or higher, or 360 ° C. or higher.
- the flow start temperature may be 340 ° C. or more and 450 ° C. or less, may be 350 ° C. or more and 400 ° C. or less, and may be 360 ° C. or more and 390 ° C. or less.
- the liquid crystal polyester With the flow start temperature, the liquid crystal polyester is melted while raising the temperature at a rate of 4 ° C./min under a load of 9.8 MPa (100 kg / cm 2 ) using a capillary rheometer (capillary rheometer), and the inner diameter is The temperature at which a viscosity of 4800 Pa ⁇ s (48000 poises) is exhibited when extruded from a nozzle of 1 mm and a length of 10 mm, and serves as a measure of the molecular weight of liquid crystalline polyesters -Application-", CMC Co., Ltd., June 5, 1987, p. 95).
- the liquid crystal polyester according to the present embodiment is preferably a wholly aromatic liquid crystal polyester in which only an aromatic compound is polymerized as a raw material monomer.
- the liquid crystal polyester As a typical example of the liquid crystal polyester according to the present embodiment, at least one compound selected from the group consisting of an aromatic diol, an aromatic hydroxyamine and an aromatic diamine, an aromatic hydroxycarboxylic acid, and an aromatic dicarboxylic acid
- aromatic hydroxycarboxylic acid, aromatic dicarboxylic acid, aromatic diol, aromatic hydroxyamine and aromatic diamine are each independently substituted for part or all of them, using its polymerizable derivative It is also good.
- Examples of polymerizable derivatives of compounds having a carboxyl group such as aromatic hydroxycarboxylic acids and aromatic dicarboxylic acids include those in which a carboxyl group is substituted with an alkoxycarbonyl group or an aryloxycarbonyl group (ie, an ester), Those in which a carboxyl group is substituted by a haloformyl group (that is, an acid halide) and those in which a carboxyl group is substituted by an acyloxycarbonyl group (that is, an acid anhydride) can be mentioned.
- hydroxylated group is acylated to be substituted by acyloxyl group (ie, hydroxylated group) (Acylated compounds of
- polymerizable derivatives of compounds having an amino group such as aromatic hydroxyamines and aromatic diamines include those wherein the amino group is acylated and substituted with an acylamino group (that is, the acylated product of the amino group) .
- the liquid crystal polyester according to the present embodiment preferably has a repeating unit represented by the following formula (1) (hereinafter sometimes referred to as “repeating unit (1)”), and the repeating unit (1):
- the repeating unit represented by the formula (2) hereinafter sometimes referred to as “repeating unit (2)”
- the repeating unit represented by the following formula (3) hereinafter referred to as “repeating unit (3)” It is more preferable to have and.
- Ar 1 represents a phenylene group, a naphthylene group or a biphenylylene group.
- Ar 2 and Ar 3 each independently represent a phenylene group, a naphthylene group, a biphenylylene group or a group represented by the following formula (4).
- X and Y each independently represent an oxygen atom or an imino group (-NH-).
- the hydrogen atoms in the groups represented by Ar 1 , Ar 2 or Ar 3 may be each independently substituted with a halogen atom, an alkyl group or an aryl group.
- Ar 4 and Ar 5 each independently represent a phenylene group or a naphthylene group.
- Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group or an alkylidene group.
- Hydrogen atoms contained in the group represented by a Ar 4 or Ar 5 independently of one another, a halogen atom, an alkyl group or an aryl group which may be substituted.
- halogen atom which can be substituted with a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are mentioned.
- the alkyl group which can be substituted with a hydrogen atom is preferably an alkyl group having 1 to 10 carbon atoms, and examples thereof include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group and an s-butyl group. And t-butyl, n-hexyl, 2-ethylhexyl, n-octyl and n-decyl groups.
- aryl group which can be substituted with a hydrogen atom
- at least one of the hydrogen atoms constituting the above-mentioned aryl group may be substituted, and an aryl group having a total carbon number of 6 to 20 including the above-mentioned substituent is Preferred examples include phenyl group, o-tolyl group, m-tolyl group, p-tolyl group, 1-naphthyl group and 2-naphthyl group.
- the number of substitution is the same as that of the group represented by Ar 1 , Ar 2 or Ar 3 In each case, the number is usually 2 or less, preferably 1 or less.
- the alkylidene group is preferably an alkylidene group having 1 to 10 carbon atoms, and examples thereof include a methylene group, an ethylidene group, an isopropylidene group, an n-butylidene group and a 2-ethylhexylidene group.
- the repeating unit (1) is a repeating unit derived from a predetermined aromatic hydroxycarboxylic acid.
- the repeating unit (1) those in which Ar 1 is a p-phenylene group (for example, repeating units derived from p-hydroxybenzoic acid) and those in which Ar 1 is a 2,6-naphthylene group (for example, 6 Preferred is a repeating unit derived from -hydroxy-2-naphthoic acid.
- derived from means that the chemical structure changes due to the polymerization of the raw material monomer and no other structural change occurs.
- the repeating unit (2) is a repeating unit derived from a predetermined aromatic dicarboxylic acid.
- the repeating unit (2) one in which Ar 2 is a p-phenylene group (for example, a repeating unit derived from terephthalic acid), one in which Ar 2 is a m-phenylene group (for example, a repeating unit derived from isophthalic acid ), Ar 2 is a 2,6-naphthylene group (eg, a repeating unit derived from 2,6-naphthalenedicarboxylic acid), and Ar 2 is a diphenylether-4,4′-diyl group (For example, a repeating unit derived from diphenyl ether-4,4'-dicarboxylic acid) is preferred.
- the repeating unit (3) is a repeating unit derived from a predetermined aromatic diol, aromatic hydroxylamine or aromatic diamine.
- the repeating unit (3) those in which Ar 3 is a p-phenylene group (for example, repeating units derived from hydroquinone, p-aminophenol or p-phenylenediamine), and Ar 3 is a 4,4′-biphenylylene group (For example, repeating units derived from 4,4′-dihydroxybiphenyl, 4-amino-4′-hydroxybiphenyl or 4,4′-diaminobiphenyl) are preferred.
- the content of the repeating unit (1) in the liquid crystal polyester is usually 30 mol% or more, preferably 30 to 80 mol%, more preferably 40 to 70 mol%, based on the total amount of all repeating units constituting the liquid crystal polyester. More preferably, it is 45 to 65 mol%.
- the total amount of all repeating units constituting liquid crystalline polyester is obtained by dividing the mass of each repeating unit constituting liquid crystalline polyester by the formula weight of each repeating unit to determine the equivalent amount (mole) of each repeating unit. , It is the value which totaled them.
- the mass of each repeating unit which comprises liquid crystalline polyester is computed from the usage-amount of the raw material monomer to be used, and this becomes a numerical value when all raw material monomers react.
- the content of the repeating unit (2) in the liquid crystal polyester is usually 35 mol% or less, preferably 10 to 35 mol%, more preferably 15 to 35 mol%, based on the total amount of all repeating units constituting the liquid crystal polyester. It is preferably 30 mol%, more preferably 17.5 to 27.5 mol%.
- the content of the returning unit (3) in the liquid crystal polyester is usually 35 mol% or less, preferably 10 to 35 mol%, more preferably 15 to 30 mol%, based on the total amount of all repeating units constituting the liquid crystal polyester. More preferably, it is 17.5 to 27.5 mol%.
- the content ratio of the repeating unit (1) in the liquid crystal polyester is increased, the melt flowability, the heat resistance, the strength and the rigidity are easily improved. However, if the content of the repeating unit (1) is more than 80 mol%, the melting temperature and the melt viscosity tend to be high, and the temperature required for molding tends to be high.
- the ratio of the content of the repeating unit (2) to the content of the repeating unit (3) is [content of repeating unit (2)] / [content of repeating unit (3) ] (Mol% / mol%) It calculates from the formula represented.
- the ratio of the content of the repeating unit (2) to the content of the repeating unit (3) is usually 0.9 to 1.11, preferably 0.95 to 1.05, and more preferably 0.98 to 1. It is 02.
- the repeating units (1) to (3) possessed by the liquid crystal polyester may be each independently derived from one type of raw material monomer, or may be derived from two or more types of raw material monomers.
- the liquid crystalline polyester may also have repeating units other than the repeating units (1) to (3).
- the content of repeating units other than the repeating units (1) to (3) is usually 0 mol% or more and 10 mol% or less, preferably 0 mol% or more, based on the total amount of all the repeating units constituting the liquid crystal polyester. It is less than mol%.
- the liquid crystalline polyester preferably has a repeating unit (3) in which each of X and Y is an oxygen atom. That is, it is preferable to have a repeating unit derived from a predetermined aromatic diol because the melt viscosity tends to be low. Moreover, it is more preferable to have only what has X and Y each an oxygen atom as a repeating unit (3).
- the liquid crystal polyester according to the method for producing a liquid crystal polyester composition of the present embodiment may be one commercially available, or may be one synthesized from a raw material monomer corresponding to a repeating unit constituting the liquid crystal polyester. .
- liquid crystalline polyester When liquid crystalline polyester is synthesized, it is preferable to manufacture by melt-polymerizing the raw material monomers and solid-phase polymerizing the obtained polymer (hereinafter sometimes referred to as "prepolymer"). Thereby, for example, a liquid crystal polyester having a flow start temperature of 330 ° C. or higher and a high flow start temperature can be produced with good operability.
- Melt polymerization may be carried out in the presence of a catalyst.
- catalysts that may be used for melt polymerization include metal compounds such as magnesium acetate, stannous acetate, tetrabutyl titanate, lead acetate, sodium acetate, potassium acetate, antimony trioxide and 4- (dimethylamino) pyridine
- nitrogen-containing heterocyclic compounds such as 1-methylimidazole, and nitrogen-containing heterocyclic compounds are preferably used.
- the liquid crystalline polyester may have the same repeating unit in the above-mentioned range, and one having a different content of the repeating unit may be used in combination.
- Fibrous filler As a material which comprises the fibrous filler which concerns on this embodiment, an inorganic substance is preferable from a viewpoint from which a high-strength resin molding is obtained.
- the fibrous filler according to the present embodiment glass fibers, ceramic fibers, PAN carbon fibers, pitch carbon fibers, alumina fibers, silica fibers, silica alumina fibers can be mentioned.
- the fibrous filler glass fiber is more preferable because the wear load given to the device at the time of molding is small and it is easy to obtain.
- the fibrous filler which concerns on this embodiment does not contain a whisker filler.
- whiskers refer to whisker-like single crystal fibers formed by crystal growth.
- the number average fiber diameter of the fibrous filler in the liquid crystal polyester composition of the present embodiment is 12 ⁇ m or less, and the number average fiber length of the fibrous filler is 15 ⁇ m to 60 ⁇ m.
- the resin molded product molded from the liquid crystal polyester composition of the present embodiment can suppress the generation of foreign matter during assembly and use.
- the number average fiber length of the fibrous filler may be 26 ⁇ m or more and 59 ⁇ m or less.
- the number average fiber diameter of the fibrous filler is preferably 11 ⁇ m or less. Moreover, 6 micrometers or less are more preferable, and, as for the number average fiber diameter of the said fibrous filler, 5 micrometers or less are more preferable. Although the cause is unclear when the number average fiber diameter of the fibrous filler is 5 ⁇ m or less, the strength of the resin molded product is improved.
- the lower limit of the number average fiber diameter of the fibrous filler is not particularly limited, but is practically 2 ⁇ m or more for the convenience of melt-kneading at the time of production of the liquid crystal polyester composition.
- the number average fiber diameter of the fibrous filler is 2 ⁇ m to 12 ⁇ m, preferably 2 ⁇ m to 11 ⁇ m, more preferably 2 ⁇ m to 6 ⁇ m, and still more preferably 2 ⁇ m to 5 ⁇ m.
- the fibrous filler in the liquid crystal polyester composition of the present embodiment has a fiber length of 80 ⁇ m or more and the number of long fibers contained in the fibrous filler is 0% with respect to the number of fibrous fillers. More than 30%.
- the content of the long fibers in the liquid crystal polyester composition of the present embodiment is 0% or more and 30% or less, it is possible to mold a resin molded body in which the generation of foreign matter is suppressed.
- the content of the long fibers is preferably 0% or more and 25% or less with respect to the number of fibrous fillers.
- the content of the long fibers may be 0 or more and 22% or less, or 1% or more and 11% or less, with respect to the number of fibrous fillers.
- the number average fiber diameter of the fibrous filler in the liquid crystal polyester composition is contained in the liquid crystal polyester composition. It can be determined from a photomicrograph of fibrous filler. Specifically, these measurement methods will be described. In the following measurement method, the number of observations (the number of fibrous fillers) in the micrograph is 400.
- the liquid crystalline polyester composition is incinerated at 600 ° C. or higher.
- the obtained residue is dispersed in methanol, and while being spread on a slide glass, a photomicrograph is taken at a magnification of 100 times.
- the length (fiber length) of the fibrous filler is read from the obtained photograph, and the number average fiber length of the fibrous filler is determined by calculating the average value of the number (400) of fibrous fillers.
- the number average fiber diameter of the above fibrous filler is obtained by taking a photomicrograph at a magnification of 500, reading the fiber diameter of the fibrous filler from the obtained photograph, and calculating the average value of the number (400) of fibrous fillers. It can be determined by
- the content of long fibers having a fiber length of 80 ⁇ m or more is obtained by dividing the number of long fibers having a fiber length of 80 ⁇ m or more by the number of fibrous fillers (400) using the measurement value of the fiber length obtained by the above measurement. It can be calculated by
- fiber length means the largest length in the fibrous filler.
- the “fiber diameter” means, for example, the maximum diameter (length) in the direction orthogonal to the longitudinal direction of the fibrous filler.
- the upper limit of the length of the long fibers contained in the fibrous filler is usually 1000 ⁇ m or less.
- the fibrous filler which concerns on this embodiment is not giving the surface coating process.
- the generated gas from the surface coating agent attached to the fibrous filler of the resin molding obtained can be prevented, and the chemical stability of the resin molding can be improved.
- the gas generated from the resin molded body is less likely to contaminate the peripheral members.
- the surface coating treatment includes a surface coating treatment with a coupling agent such as a silane coupling agent or a titanium coupling agent, or a surface coating treatment with a thermoplastic resin or a thermosetting resin other than liquid crystal polyester. .
- the liquid crystal polyester composition of the present embodiment preferably contains 10 parts by mass or more and 150 parts by mass or less of the fibrous filler with respect to 100 parts by mass of the liquid crystal polyester.
- the amount of the fibrous filler exceeds 150 parts by mass, the resulting resin molded product tends to easily generate foreign matter during assembly or use.
- the content of the fibrous filler is less than 10 parts by mass, the dimensional stability of the obtained resin molded product tends to be reduced, and it tends to be difficult to obtain a resin molded product of a desired size.
- the anisotropy of the liquid crystal polyester is strongly developed, and the resin molded product may be warped or the like. Furthermore, when there are few fibrous fillers, the effect of mechanical strength improvement may fall.
- the content of the fibrous filler in the liquid crystal polyester composition of the present embodiment is 100 parts by mass of the liquid crystal polyester in consideration of the balance of characteristics such as generation of foreign matter, dimensional stability, warp and mechanical strength of the resin molded body described above.
- 15 parts by mass or more is more preferable, 20 parts by mass or more is more preferable, 25 parts by mass or more is particularly preferable, and 30 parts by mass or more is particularly preferable.
- 140 mass parts or less are more preferable with respect to 100 mass parts of liquid crystal polyester, and, as for content of the fibrous filler in the liquid-crystal polyester composition of this embodiment, 70 mass parts or less are more preferable.
- the content of the fibrous filler in the liquid crystal polyester composition of the present embodiment is more preferably 15 parts by mass or more and 140 parts by mass or less, and 20 parts by mass or more and 140 parts by mass with respect to 100 parts by mass of the liquid crystal polyester.
- the following is more preferable, 20 to 70 parts by mass is more preferable, 25 to 70 parts by mass is particularly preferable, and 30 to 70 parts by mass is particularly preferable.
- the content of the liquid crystal polyester in the liquid crystal polyester composition of the present embodiment is preferably 42 to 87% by mass with respect to the total mass of the liquid crystal polyester composition.
- the content of the fibrous filler in the liquid crystal polyester composition of the present embodiment is preferably 13 to 58% by mass with respect to the total mass of the liquid crystal polyester composition.
- additives may be contained in the liquid crystal polyester composition of the present embodiment as long as the effects of the present invention are not impaired.
- additives include plate-like fillers, coloring components, lubricants, stabilizers and the like.
- the content of the other components is preferably 0.0001 to 5 parts by mass with respect to 100 parts by mass of the liquid crystal polyester.
- the content of the other components in the liquid crystal polyester composition of the present embodiment is preferably 0.01 to 5% by mass with respect to the total mass of the liquid crystal polyester composition.
- the liquid crystalline polyester and the fibrous filler are melt-kneaded in advance to produce a pellet-like liquid crystalline polyester composition (hereinafter sometimes referred to as a "composition"). It is preferable to keep it.
- the additive and the like may be combined together with the liquid crystalline polyester and the fibrous filler and melt-kneaded to obtain a composition.
- the resin molding of this embodiment uses the above-mentioned liquid crystal polyester composition as a forming material. According to the resin molded product of the present embodiment, the generation of foreign substances is suppressed at the time of assembly or use of the resin molded product (that is, at the time of assembly or use of electric / electronic equipment or optical equipment using the resin molded product as parts). it can. The effect of suppressing the generation of such foreign matter can be confirmed by the following test.
- injection molding is carried out using an injection molding machine (PS40E-5ASE type manufactured by Nissei Resin Co., Ltd.) at a cylinder temperature of 350 ° C., a mold temperature of 130 ° C. and an injection speed of 60%.
- the test piece (resin molding) of length 64 mm, width 64 mm, and thickness 1 mm is obtained.
- the film gate of 64 mm x 1 mm is provided in the edge side of the cavity of the metal mold
- a tape (Sellotape (registered trademark) No. 405 manufactured by Nichiban Co., Ltd.) is attached to the upper surface of the test piece along the flow direction of the liquid crystal polyester in the test piece over the entire length of the test piece, and the above-mentioned flow direction The tape is quickly pulled off from one end to the other end of the tape. This operation is performed once, and a tape peeling test repeated 20 times is performed.
- the surface roughness Sa is measured using a 3D shape measuring machine ("VR3000" manufactured by Keyence Corporation) at the place where the above test was performed on the test piece.
- the surface roughness Sa of the resin molded product of the present embodiment is preferably 0 ⁇ m or more and 0.55 ⁇ m or less, and more preferably 0.50 ⁇ m or less.
- the resin molded product can suppress the generation of foreign matter at the time of assembly or production.
- the said tape peeling test can be considered as an accelerated test which generate
- the number average fiber diameter of the fibrous filler according to the present embodiment is 2 ⁇ m or more and 6 ⁇ m or less, the Izod impact strength of the resin molded body can be improved.
- the Izod impact strength of a resin molded body is measured as follows. First, after the composition is dried, injection molding is carried out using an injection molding machine (PS40E-5ASE type manufactured by Nissei Resin Co., Ltd.) at a cylinder temperature of 350 ° C., a mold temperature of 130 ° C. and an injection speed of 60%. Conduct to obtain a test piece 64 mm long, 12.7 mm wide, 6.4 mm thick.
- PS40E-5ASE type manufactured by Nissei Resin Co., Ltd. an injection molding machine
- Izod impact strength is measured about the obtained test piece based on ASTMD256.
- composition obtained by the above-mentioned method is injection-molded to obtain a resin molded product.
- the flow start temperature FT (° C.) of the composition to be used is determined.
- the composition described above at a temperature of [FT + 30] ° C. or more and [FT + 80] ° C. or less with respect to the flow start temperature FT (° C.)
- the composition is preferably dried before injection molding.
- the resin melt temperature is injection molded at a temperature of [FT + 80] ° C. or less
- the liquid crystal polyester stagnating inside the molding machine is not easily decomposed.
- the resulting resin molded product is less likely to generate gas or the like, and can be applied to, for example, applications of electric and electronic parts and optical parts.
- the resin melting temperature is injection molding at a temperature of [FT + 80] ° C. or less
- the molten resin hardly flows out from the nozzle when the mold is opened and the resin molded body is taken out after the injection molding. As a result, it is not necessary to cope with the outflow of the molten resin, and the productivity of the resin molded product is improved.
- the mold temperature to be used is preferably 80 ° C. or more. If the mold temperature is 80 ° C. or higher, the surface of the resulting resin molded product tends to be smooth, and the amount of foreign matter generated tends to be suppressed.
- the higher the temperature of the mold used the more advantageous, but if it is too high, the cooling effect is reduced and the time required for the cooling step becomes longer.
- the productivity of the resin molded product may be reduced, and problems such as deformation of the resin molded product may occur due to the difficulty in releasing the resin molded product after molding.
- the temperature of the mold used is too high, the meshing between the molds may be impaired, and the resin molded product may be damaged when the mold is opened and closed. Therefore, it is preferable to appropriately optimize the upper limit of the mold temperature to be used according to the type of the composition to be used. Thereby, the decomposition of the liquid crystal polyester contained in the composition can be suppressed.
- the mold temperature used is preferably 100 ° C. or more and 220 ° C. or less. 130 degreeC or more and 200 degrees C or less are more preferable.
- a tape peeling test is performed to determine a surface roughness Sa of the standard molded body after the test.
- the injection molding conditions can be optimized as follows.
- the composition is first melted and injection molded into a mold set at 80 ° C. to produce a standard molded body.
- the resin melting temperature is set in the range of approximately the center value [FT + 40] to [FT + 50] ° C. of the preferable resin melting temperature with respect to the flow start temperature FT (° C.) obtained in advance.
- a tape peeling test is performed on the obtained standard molded body to determine the surface roughness Sa of the standard molded body after the test.
- the temperature of the mold to be used is gradually raised, each standard molded body is molded, and the surface roughness Sa of the standard molded body after the test is similarly determined.
- the mold temperature and the resin melting temperature can be optimized respectively.
- the injection speed of the above composition may be set in various suitable ranges depending on the molding machine to be used, but 50 mm / sec or more is preferable. A higher injection speed of the composition is preferable because the productivity of the resin molded product can be enhanced, and is preferably 100 mm / sec or more, and more preferably 200 mm / sec or more.
- the injection molding conditions are optimized in the preliminary experiment for forming the standard molded body, and the mold for obtaining the standard molded body is changed to a mold for obtaining the target resin molded body to mold the composition. Do. By doing this, it is possible to obtain a resin molded body that can further suppress the generation of foreign matter.
- the resin molded product of the present embodiment can be suitably used, for example, as a component for an electric / electronic device or an optical device.
- the tape peeling test was implemented about the resin molded object of the target shape, and the surface of the resin molded object after a test is carried out.
- the molding conditions can be optimized by means of determining the roughness Sa.
- Specific examples of members to which the resin molded product of the present embodiment can be suitably applied include, for example, connectors, sockets, relay parts, coil bobbins, optical pickups, oscillators, printed wiring boards, circuit boards, semiconductor packages, computer related parts, etc.
- Electric and electronic parts such as IC tray or wafer carrier, VTR, TV, iron, air conditioner, stereo, vacuum cleaner, refrigerator, household appliance parts such as rice cooker or lighting equipment, lamp reflector or lamp Luminaire parts such as holders, compact disc, acoustic product parts such as laser disc (registered trademark) or speakers, ferrules for optical cables, telephone parts, communication parts such as facsimile parts or modems, multiple parts such as separation claws or heater holders Machine parts, machine parts such as impellers, fan gears, gears, bearings, motor parts or cases, mechanical parts for vehicles, engine parts, parts in engine room, parts for automobile parts such as electrical parts or interior parts, microwaves Cooking utensils such as cooking pots or heat-resistant dishes, materials for heat insulation and sound insulation such as flooring or wall materials, building materials such as support materials (beams, columns, etc.) or roofing materials, parts for aircraft, spacecraft, space equipment Radiation facility members such as nuclear reactors, marine facility members, cleaning jigs, optical components, or optical fiber
- the resin molding of this embodiment can be used for various uses.
- the resin molded product of the present embodiment has an extremely small amount of foreign matter generated during assembly or use. Therefore, when using the resin molding of this embodiment for these uses, the reliability of a resin molding improves.
- the resin molded product of the present embodiment is useful for switches, relays, image sensors and various other sensors, light emitting diodes (also referred to as LEDs), and optical mechanism systems.
- the liquid crystal polyester composition of the present embodiment has, as one aspect, A liquid crystal polyester composition comprising a liquid crystal polyester and a fibrous filler,
- the liquid crystalline polyester is a liquid crystalline polyester having a repeating unit derived from p-hydroxybenzoic acid, a repeating unit derived from terephthalic acid, and a repeating unit derived from isophthalic acid, or a repeat derived from 6-hydroxy-2-naphthoic acid
- a liquid crystal polyester having a unit, a repeating unit derived from 2,6-naphthalenedicarboxylic acid, a repeating unit derived from terephthalic acid and a repeating unit derived from hydroquinone;
- the fibrous filler is at least one selected from the group consisting of ceramic fibers and glass fibers, and the ceramic fibers are preferably alkaline earth silicate fibers;
- the number average fiber length of the fibrous filler is 15 ⁇ m or more and 60 ⁇ m or less, preferably 26 ⁇ m
- the Izod impact strength of the test piece is preferably 250 J / m or more and 1030 or less J / m. May be 700 J / m or more and 1030 J / m or less;
- the surface roughness Sa of the test piece is 0.55 ⁇ m or less, preferably 0.50 ⁇ m or less It may be.
- the temperature was raised to 320 ° C. over 2 hours and 50 minutes while distilling off the by-product acetic acid distilled off and the unreacted acetic anhydride, and the prepolymer was obtained with the point in time where the increase in torque was observed as the reaction completion.
- the obtained prepolymer is cooled to room temperature and crushed by a coarse crusher to obtain a liquid crystalline polyester powder (particle diameter: about 0.1 mm to about 1 mm), and then from room temperature to 250 ° C. under a nitrogen atmosphere 1
- the temperature was raised over time, and the temperature was raised from 250 ° C. to 285 ° C. over 5 hours, held at 285 ° C. for 3 hours, and the polymerization reaction was advanced in the solid phase.
- the flow start temperature of the obtained liquid crystal polyester (1) was 327 ° C.
- the temperature is raised from 145 ° C. to 310 ° C. over 3 hours and 30 minutes while distilling off by-product acetic acid and unreacted acetic anhydride, and maintained at 310 ° C. for 3 hours, then the contents are removed from the reactor It cooled to room temperature.
- the obtained solid was crushed by a grinder to obtain a powdery prepolymer.
- This prepolymer is heated in a nitrogen gas atmosphere from room temperature to 250 ° C. in 1 hour, heated from 250 ° C. to 293 ° C. in 5 hours, and maintained at 293 ° C. for 5 hours to perform solid phase polymerization.
- the reaction product was cooled to obtain a powdery liquid crystal polyester 2.
- the flow start temperature of the obtained liquid crystal polyester (2) was 319 ° C.
- the content rate was calculated by dividing the number of long fibers having a fiber length of 80 ⁇ m or more by the number (400) of fibrous fillers.
- a tape (Sellotape (registered trademark) No. 405 manufactured by Nichiban Co., Ltd.) is attached to the upper surface of the test piece along the flow direction of the liquid crystal polyester in the test piece over the entire length of the test piece, and the above-mentioned flow direction The tape was quickly pulled off from one end to the other end of the tape. This operation was performed once, and a tape peeling test was repeated 20 times in all.
- the Izod impact strength of the obtained test piece was measured in accordance with ASTM D256. The results are shown in Tables 1 to 3.
Abstract
Description
本願は、2017年11月15日に、日本に出願された特願2017-220365号に基づき優先権を主張し、その内容をここに援用する。
[1] 液晶ポリエステルと、繊維状フィラーと、を含み、
前記繊維状フィラーにおいて、繊維状フィラーに含まれる繊維長が80μm以上の長繊維の本数が前記繊維状フィラーの本数に対して30%以下であり、
前記繊維状フィラーの数平均繊維径は12μm以下である液晶ポリエステル組成物。
[2] 液晶ポリエステルと、繊維状フィラーと、を含み、
前記繊維状フィラーの数平均繊維長は、15μm以上60μm以下であり、
前記繊維状フィラーの数平均繊維径は、12μm以下である液晶ポリエステル組成物。
[3] 前記繊維状フィラーの数平均繊維径が6μm以下である[1]または[2]に記載の液晶ポリエステル組成物。
[4] 前記繊維状フィラーの含有量が、前記液晶ポリエステル100質量部に対して、10質量部以上150質量部以下である[1]~[3]のいずれか1つに記載の液晶ポリエステル組成物。
[5] [1]~[4]のいずれか1つに記載の液晶ポリエステル組成物から形成される樹脂成形体。
本明細書において「異物」とは、液晶ポリエステル組成物から形成される樹脂成形体を部品とした電気・電子機器や光学機器の組立時や使用時に発生する前記液晶ポリエステル組成物由来の成分である。例えば繊維状フィラーや液晶ポリエステル樹脂やそれらの混合物を意味する。
本実施形態の液晶ポリエステル組成物に係る液晶ポリエステルは、溶融状態で液晶性を示す材料である。前記液晶ポリエステルは、液晶ポリエステルアミドであってもよいし、液晶ポリエステルエーテルであってもよいし、液晶ポリエステルカーボネートであってもよいし、液晶ポリエステルイミドであってもよい。
1つの側面として、前記流動開始温度は340℃以上450℃以下であってもよく、350℃以上400℃以下であってもよく、360℃以上390℃以下であってもよい。
(2)-CO-Ar2-CO-
(3)-X-Ar3-Y-
Ar4又はAr5で表される前記基に含まれる水素原子は、互いに独立に、ハロゲン原子、アルキル基またはアリール基で置換されていてもよい。
本実施形態に係る繊維状フィラーを構成する材料としては、より高強度の樹脂成形体が得られる観点から無機物質が好ましい。具体的に例示すると、本実施形態に係る繊維状フィラーとしては、ガラス繊維、セラミック繊維、PAN系炭素繊維、ピッチ系炭素繊維、アルミナ繊維、シリカ繊維、シリカアルミナ繊維が挙げられる。なかでも、繊維状フィラーとしては、成形加工時の装置に与える摩耗負荷が少なく、かつ入手しやすいことから、ガラス繊維がより好ましい。なお、本実施形態に係る繊維状フィラーは、ウィスカフィラーを含まない。一般に、ウィスカとは結晶成長でできるヒゲ状の単結晶繊維を指す。
1つの側面として、前記繊維状フィラーの数平均繊維長は、26μm以上59μm以下であってもよい。
1つの側面として、上記繊維状フィラーの数平均繊維径は2μm以上12μm以下であり、2μm以上11μm以下が好ましく、2μm以上6μm以下がより好ましく、2μm以上5μm以下がさらに好ましい。
具体的に、これらの測定方法について説明する。なお、以下の測定方法では、顕微鏡写真における観測本数(繊維状フィラーの本数)を400本とする。
なお、「繊維長」とは、その繊維状フィラーにおける最大長を意味する。
「繊維径」とは、例えば、その繊維状フィラーの長さ方向に直交する方向における最大径(長さ)を意味する。
繊維状フィラー中に含まれる長繊維の長さの上限は、通常1000μm以下である。
1つの側面として、本実施形態の液晶ポリエステル組成物における繊維状フィラーの含有量は、液晶ポリエステル100質量部に対して、15質量部以上140質量部以下がより好ましく、20質量部以上140質量部以下がさらに好ましく、20質量部以上70質量部以下がよりさらに好ましく、25質量部以上70質量部以下がとりわけ好ましく、30質量部以上70質量部以下が特に好ましい。
1つの側面として、本実施形態の液晶ポリエステル組成物における液晶ポリエステルの含有量は、液晶ポリエステル組成物の総質量に対して、42~87質量%が好ましい。
1つの側面として、本実施形態の液晶ポリエステル組成物における繊維状フィラーの含有量は、液晶ポリエステル組成物の総質量に対して、13~58質量%が好ましい。
1つの側面として、前記その他の成分の含有量は、液晶ポリエステル100質量部に対して、0.0001~5質量部が好ましい。
別の側面として、本実施形態の液晶ポリエステル組成物におけるその他の成分の含有量は、液晶ポリエステル組成物の総質量に対して、0.01~5質量%が好ましい。
本実施形態の樹脂成形体を得るには、予め液晶ポリエステルと、繊維状フィラーとを溶融混練して、ペレット状の液晶ポリエステル組成物(以下、「組成物」と呼ぶことがある。)を製造しておくことが好ましい。なお、上述の液晶ポリエステル、および繊維状フィラー以外の添加剤などを用いる場合は、液晶ポリエステルおよび繊維状フィラーとともに、前記添加剤なども合わせて溶融混練して組成物とすればよい。
本実施形態の樹脂成形体は、上述の液晶ポリエステル組成物を形成材料とする。本実施形態の樹脂成形体によれば、樹脂成形体の組立時または使用時(すなわち、樹脂成形体を部品とした電気・電子機器や光学機器の組立時や使用時)における異物の発生を抑制できる。このような異物の発生を抑制する効果は、以下のような試験で確認することができる。
上述の方法で得られた組成物を射出成形して、樹脂成形体を得る。
したがって、用いる金型温度の上限を使用する組成物の種類に応じて適宜最適化することが好ましい。これにより、組成物に含まれる液晶ポリエステルの分解を抑制することができる。
本実施形態の樹脂成形体は、例えば電気・電子用機器あるいは光学機器用の部品に好適に使用することができる。
本実施形態の樹脂成形体を好適に適用できる部材としては、具体的に例えば、コネクター、ソケット、リレー部品、コイルボビン、光ピックアップ、発振子、プリント配線板、回路基板、半導体パッケージまたはコンピュータ関連部品などの電気・電子部品、ICトレーまたはウエハーキャリヤーなどの半導体製造プロセス関連部品、VTR、テレビ、アイロン、エアコン、ステレオ、掃除機、冷蔵庫、炊飯器または照明器具などの家庭電気製品部品、ランプリフレクターまたはランプホルダーなどの照明器具部品、コンパクトディスク、レーザーディスク(登録商標)またはスピーカーなどの音響製品部品、光ケーブル用フェルール、電話機部品、ファクシミリ部品またはモデムなどの通信機器部品、分離爪またはヒータホルダーなどの複写機・印刷機関連部品、インペラー、ファン歯車、ギヤ、軸受け、モーター部品またはケースなどの機械部品、自動車用機構部品、エンジン部品、エンジンルーム内部品、電装部品または内装部品などの自動車部品、マイクロ波調理用鍋または耐熱食器などの調理用器具、床材または壁材などの断熱・防音用材料、支持材料(梁、柱など)または屋根材などの建築資材、航空機、宇宙機、宇宙機器用部品、原子炉などの放射線施設部材、海洋施設部材、洗浄用治具、光学機器部品、バルブ類、パイプ類、ノズル類、フィルター類、医療用機器部品、医療用材料、センサー類部品、サニタリー備品、スポーツ用品、レジャー用品が挙げられる。
液晶ポリエステルと、繊維状フィラーと、を含む液晶ポリエステル組成物であって、
前記液晶ポリエステルは、p-ヒドロキシ安息香酸に由来する繰返し単位、テレフタル酸に由来する繰返し単位、およびイソフタル酸に由来する繰返し単位を有する液晶ポリエステル、または6-ヒドロキシ-2-ナフトエ酸に由来する繰返し単位、2,6-ナフタレンジカルボン酸に由来する繰返し単位、テレフタル酸に由来する繰返し単位およびヒドロキノンに由来する繰返し単位を有する液晶ポリエステルであり;
前記繊維状フィラーは、セラミック繊維およびガラス繊維からなる群から選択される少なくとも1つであり、セラミック繊維は、アルカリ土類シリケートファイバーであることが好ましく;
前記繊維状フィラーの数平均繊維長は、15μm以上60μm以下、好ましくは26μm以上59μm以下であり;
前記繊維状フィラーの数平均繊維径は、2μm以上12μm以下、好ましくは2μm以上11μm以下、より好ましくは2μm以上6μm以下、特に好ましくは2μm以上5μm以下であり;
繊維長が80μm以上の長繊維の含有率は、前記繊維状フィラーの本数に対して0%以上30%以下、好ましくは0%以上25%以下、より好ましくは0以上22%以下、さらに好ましくは1%以上11%以下である、
液晶ポリエステル組成物が挙げられる。
さらに、前記液晶ポリエステル組成物は、後述の実施例に記載の条件で試験片を作成しアイゾット衝撃強度を測定したとき、前記試験片のアイゾット衝撃強度は250J/m以上1030以下J/m、好ましくは700J/m以上1030J/m以下であってもよく;
後述の実施例に記載の条件で試験片を作成しテープ剥離試験後の表面粗さSaを測定したとき、前記試験片の表面粗さSaは、0.55μm以下、好ましくは0.50μm以下であってもよい。
フローテスター(株式会社島津製作所の「CFT-500型」)を用いて、液晶ポリエステル約2gを、内径1mmおよび長さ10mmのノズルを有するダイを取り付けたシリンダーに充填し、9.8MPa(100kg/cm2)の荷重下、4℃/分の速度で昇温しながら、液晶ポリエステルを溶融させ、ノズルから押し出し、4800Pa・s(48000ポイズ)の粘度を示す温度を測定した。
[製造例1]
攪拌装置、トルクメータ、窒素ガス導入管、温度計および還流冷却器を備えた反応器に、パラヒドロキシ安息香酸994.5g(7.2モル)、4,4’-ジヒドロキシビフェニル446.9g(2.4モル)、テレフタル酸299.0g(1.8モル)、イソフタル酸99.7g(0.6モル)および無水酢酸1347.6g(13.2モル)および触媒として1-メチルイミダゾール0.194gを添加し、室温で15分間攪拌して反応器内を十分に窒素ガスで置換した後、攪拌しながら昇温した。内温が145℃となったところで、同温度を保持したまま1時間攪拌した。
攪拌装置、トルクメータ、窒素ガス導入管、温度計および還流冷却器を備えた反応器に、6-ヒドロキシ-2-ナフトエ酸1034.99g(5.5モル)、2,6-ナフタレンジカルボン酸378.33g(1.75モル)、テレフタル酸83.07g(0.5モル)、ヒドロキノン272.52g(2.475モル:2,6-ナフタレンジカルボン酸およびテレフタル酸の合計量に対して0.225モル過剰)、無水酢酸1226.87g(12モル)および触媒として1-メチルイミダゾール0.17gを入れ、反応器内のガスを窒素ガスで置換した後、窒素ガス気流下、攪拌しながら、室温から145℃まで30分かけて昇温し、145℃で1時間還流させた。
[実施例1~6、比較例1~11]
製造例1および2で得られた、液晶ポリエステル、および下記の成分(繊維状フィラー)を、表1~3に示す組成で二軸押出機(池貝鉄工株式会社製、「PCM-30」)を用いて、シリンダー温度340℃で造粒し、ペレット状の組成物を得た。なお、繊維状フィラーの平均繊維長および数平均繊維径は、繊維状フィラーのメーカーの公称値である。
フィラー(1):BS20/99(株式会社ITM製、アルカリ土類シリケートファイバー、平均繊維長20μm、数平均繊維径3μm)
フィラー(2):BS50/99(株式会社ITM製、アルカリ土類シリケートファイバー、平均繊維長50μm、数平均繊維径3μm)
フィラー(3):BS100/99(株式会社ITM製、アルカリ土類シリケートファイバー、平均繊維長100μm、数平均繊維径3μm)
フィラー(4):PF20E-001(日東紡績株式会社製、ガラス繊維、平均繊維長20μm、数平均繊維径11μm)
フィラー(5):EFH75-01(セントラルグラスファイバー株式会社製、ガラス繊維、平均繊維長75μm、数平均繊維径11μm)
フィラー(6):PF40E-001(日東紡績株式会社製、ガラス繊維、平均繊維長40μm、数平均繊維径11μm)
フィラー(7):EFDE50-01(セントラルグラスファイバー株式会社製、ガラス繊維、平均繊維長50μm、数平均繊維径6μm)
フィラー(8):EFH50-01(セントラルグラスファイバー株式会社製、ガラス繊維、平均繊維長50μm、数平均繊維径11μm)
フィラー(9):EFK80-31(セントラルグラスファイバー株式会社製、ガラス繊維、平均繊維長80μm、数平均繊維径13μm)
上述の方法で得られた組成物の一部を該ペレットに含まれる繊維状フィラーの分析に用いた。なお、以下の分析では、顕微鏡写真における観測本数(繊維状フィラーの本数)を400本とした。
まず、ペレット1gをるつぼにとり、電気炉内600℃で6時間処理して灰化させた。
次に、得られた残渣をメタノールに分散させ、スライドガラス上に展開させた状態で100倍の倍率で顕微鏡写真を撮影した。得られた写真から繊維状フィラーの長さを読み取り、繊維状フィラーの本数(400本)における平均値を算出した。
上記測定で得られた繊維長の測定値を用い、繊維長が80μm以上である長繊維の本数を繊維状フィラーの本数(400本)で除して含有率を算出した。
上述の方法で得られた組成物を乾燥後、射出成形機(日精樹脂工業株式会社製のPS40E-5ASE型)を用い、シリンダー温度350℃、金型温度130℃、射出速度60%の成形条件で、射出成形を行い、長さ64mm、幅64mm、厚さ1mmの試験片(樹脂成形体)を得た。なお、用いた金型のキャビティの端辺には64mm×1mmのフィルムゲートが設けられている。
上述の方法で得られた組成物を乾燥後、射出成形機(日精樹脂工業株式会社製のPS40E-5ASE型)を用い、シリンダー温度350℃、金型温度130℃、射出速度60%の成形条件で、射出成形を行い、長さ64mm、幅12.7mm、厚さ6.4mmの試験片を得た。
Claims (5)
- 液晶ポリエステルと、繊維状フィラーと、を含み、
前記繊維状フィラーにおいて、繊維状フィラーに含まれる繊維長が80μm以上の長繊維の本数が前記繊維状フィラーの本数に対して30%以下であり、
前記繊維状フィラーの数平均繊維径は12μm以下である液晶ポリエステル組成物。 - 液晶ポリエステルと、繊維状フィラーと、を含み、
前記繊維状フィラーの数平均繊維長は、15μm以上60μm以下であり、
前記繊維状フィラーの数平均繊維径は、12μm以下である液晶ポリエステル組成物。 - 前記繊維状フィラーの数平均繊維径が6μm以下である請求項1または2に記載の液晶ポリエステル組成物。
- 前記繊維状フィラーの含有量が、前記液晶ポリエステル100質量部に対して、10質量部以上150質量部以下である請求項1~3のいずれか1項に記載の液晶ポリエステル組成物。
- 請求項1~4のいずれか1項に記載の液晶ポリエステル組成物から形成される樹脂成形体。
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US16/763,155 US20200308487A1 (en) | 2017-11-15 | 2018-11-14 | Liquid crystal polyester composition and resin molded body |
KR1020207012946A KR20200078523A (ko) | 2017-11-15 | 2018-11-14 | 액정 폴리에스테르 조성물 및 수지 성형체 |
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US11258184B2 (en) | 2019-08-21 | 2022-02-22 | Ticona Llc | Antenna system including a polymer composition having a low dissipation factor |
US11637365B2 (en) | 2019-08-21 | 2023-04-25 | Ticona Llc | Polymer composition for use in an antenna system |
US11912817B2 (en) | 2019-09-10 | 2024-02-27 | Ticona Llc | Polymer composition for laser direct structuring |
US11555113B2 (en) | 2019-09-10 | 2023-01-17 | Ticona Llc | Liquid crystalline polymer composition |
US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
US11721888B2 (en) | 2019-11-11 | 2023-08-08 | Ticona Llc | Antenna cover including a polymer composition having a low dielectric constant and dissipation factor |
CN113527844A (zh) * | 2021-08-31 | 2021-10-22 | 重庆沃特智成新材料科技有限公司 | 一种低表面粗度液晶聚酯复合物及其制备方法 |
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