WO2019080514A1 - 一种丙烯环氧化催化剂的制备方法及其用途 - Google Patents
一种丙烯环氧化催化剂的制备方法及其用途Info
- Publication number
- WO2019080514A1 WO2019080514A1 PCT/CN2018/091243 CN2018091243W WO2019080514A1 WO 2019080514 A1 WO2019080514 A1 WO 2019080514A1 CN 2018091243 W CN2018091243 W CN 2018091243W WO 2019080514 A1 WO2019080514 A1 WO 2019080514A1
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- Prior art keywords
- catalyst
- ester
- sol
- amount
- water
- Prior art date
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- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Definitions
- the invention relates to a preparation method of a propylene epoxidation catalyst, in particular to a preparation method of a Ti-SiO 2 composite oxide catalyst and a use thereof as a catalyst for catalyzing the epoxidation of propylene to produce propylene oxide.
- Ethylbenzene co-oxidation process PO/SM
- EBHP ethylbenzene hydroperoxide
- CHP cumene hydroperoxide
- the two processes overcome the disadvantages of large corrosion and large sewage of the chlorohydrin method, and have the advantages of low product cost and low environmental pollution.
- the catalyst used in the epoxidation process of the heterogeneous PO/SM process is a Ti-SiO 2 composite oxide, and the preparation method thereof is mainly disclosed in the US Patent Application No. 3,829,392, US Pat.
- the titanium halide vapor is brought into the reaction tube by N 2 or other inert gas to chemically react with the silica gel (this step is called chemical vapor deposition), calcined at a high temperature, and finally subjected to a step of washing to obtain a catalyst.
- Titanium active species have poor dispersibility on the surface of SiO 2 and easily form free TiO 2 , which leads to inefficient decomposition of oxidant and lower selectivity of PO.
- the catalyst used in the CHP process is also a Ti-SiO 2 composite oxide.
- the preparation method is a sol-gel method in which a silicon source and a titanium source are separately dissolved in an alcohol solvent, as disclosed in US Pat. No. 6,211, 388, US Pat.
- the quaternary ammonium ion (such as cetyl ammonium bromide) is added as a template, and the gel is formed by hydrolysis, polymerization and aging, and then calcined at a high temperature and silanized to obtain a catalyst.
- the sol-gel method can make different components mutually miscible at the molecular level, and obtain a titanium active center in a nano phase region or even a molecular state dispersion.
- the sol-gel method requires the addition of an expensive quaternary ammonium salt as a templating agent in the preparation process.
- the templating agent is removed by high-temperature calcination, and the templating agent is not recyclable, resulting in a high catalyst cost.
- the object of the present invention is to provide a preparation method of a propylene epoxidation catalyst, and the advantages of preparing the catalyst by the method include: facilitating dispersion of Ti active species on the surface of SiO 2 , high selectivity to PO, and low manufacturing cost.
- the invention also provides a catalyst prepared by the method (or referred to as a Ti-SiO 2 composite oxide catalyst), which can be used as a catalyst for preparing propylene oxide (PO) by epoxidation of propylene, and has high activity and High selectivity for propylene oxide.
- the propylene epoxidation catalyst of the invention is prepared by a sol method, formed in liquid ammonia, reamed, dried and calcined, and finally subjected to silanization treatment to obtain a catalyst; the invention does not require the use of a templating agent, thereby reducing the catalyst production cost. .
- the catalyst is modified by using Re and Zn, formed in liquid ammonia, reamed, dried, and calcined at a high temperature, and finally silanized;
- the present invention is formed in liquid ammonia without using a templating agent, and more preferably Reaming in liquid ammonia greatly reduces the cost of catalyst production;
- the catalyst is modified with Re and Zn, and the synergistic effect of Re, Zn and Ti can improve the activity of the catalyst and the selectivity to propylene oxide.
- a method for preparing a propylene epoxidation catalyst comprises the following steps:
- pre-hydrolysis of silicon source dissolving the silicon ester in the lower alcohol, adding the hydrolysis catalyst and reacting with water to obtain the liquid A; in a specific embodiment, it is preferred that the water is added in the step by adding dropwise, the water is specific Can be deionized water;
- the sol obtained in the step (2) is atomized and sprayed into liquid ammonia to form a catalyst precursor; the atomization can be specifically carried out by an atomizer;
- step (5) The product obtained in the step (5) is subjected to a silylation treatment to obtain a Ti-SiO 2 composite oxide catalyst.
- the silicon ester in the step (1) may be one or a mixture of tetraethyl orthosilicate, methyl orthosilicate, propyl orthosilicate, butyl orthosilicate, etc.; It is a C1-C3 alcohol, a lower alcohol is mainly used as a solvent, and a different alcohol is used as a solvent. There is no significant difference, for example, but not limited to one or more of methanol, ethanol, n-propanol and isopropanol.
- the concentration of the silicon ester in the lower alcohol is preferably from 20 to 30% by weight;
- the hydrolysis catalyst is preferably one or a mixture of two of formic acid and acetic acid, preferably in an amount of from 0.8 to 1.5% by weight of the silicon ester.
- the amount of water added in the step (1) is preferably the amount of water required to theoretically hydrolyze 30-80% by weight of the silicon ester.
- the reaction temperature of the step (1) is preferably from 40 to 70 ° C, and the reaction time is preferably from 1 to 3 h.
- pre-hydrolysis of the silicon ester is carried out in advance, and this step is one of the key steps, because the hydrolysis rate of the titanium ester is fast, and the hydrolysis rate of the silicon ester is slow, and the hydrolysis rates of the two do not match, the inventors found that if the silicon ester is not Pre-hydrolysis will cause uneven distribution of Ti active components, and even form free TiO 2 , while free TiO 2 will cause self-decomposition reaction of peroxide and reduce the selectivity of the catalyst. Moreover, the inventors found in experiments that The formation of a precipitate without the hydrolysis catalyst and without pre-hydrolysis of the silicon source does not form a gel.
- the titanium ester used in the step (2) may be tetramethyl titanate, tetraethyl titanate, tetrapropyl titanate, tetraisopropyl titanate, tetrabutyl titanate, titanate One or more of isobutyl esters.
- the amount of titanium ester Ti is theoretically complete hydrolysis step is preferably silicon ester starting material (1) for 2-5% SiO 2 by mass (i.e., based on the step (theoretically complete hydrolysis of silicon ester starting material 1) for the SiO 2
- the corresponding SiO 2 mass the concentration of the titanium ester in the lower alcohol is preferably from 30 to 50% by weight; the catalyst is prepared by using the preferred amount and concentration of the titanium ester to increase the activity of the catalyst and to prevent the formation of free titanium dioxide to a greater extent.
- the reaction time in the step (2) is from 1 h to 4 h.
- one solution is to add water to carry out the reaction to obtain a sol; and a more preferable solution is to add NH 4 ReO 4 without adding water.
- the mixture is reacted with a mixed aqueous solution of zinc salt to form a sol.
- the amount of water is preferably the amount of water required for the theoretically complete hydrolysis of the step (1) unhydrolyzed silicon ester and the step (2) titanium ester.
- the concentration of the mixed aqueous solution of NH 4 ReO 4 and the zinc salt used is not particularly required, and the molar ratio of Re in the NH 4 ReO 4 to Ti in the titanium ester used is preferably
- the molar ratio of Zn in the zinc salt used to Ti in the titanium ester used is from 0.05 to 0.15:1, and a preferred ratio of NH 4 ReO 4 and zinc salt is used, which can achieve better synergy. effect.
- the zinc salt used may be used as long as it is soluble in water, and may be, for example but not limited to, one or a mixture of ZnCl 2 and Zn(NO 3 ) 2 .
- the amount of water used in the aqueous mixed solution of NH 4 ReO 4 and zinc salt is the amount of water required for the theoretically complete hydrolysis of the step (1) unhydrolyzed silicon ester and the step (2) titanium ester.
- the amount of water required for the unhydrolyzed silicon ester in the step (1) is calculated based on the total amount of the silicon ester, and then the amount of water added by the step (1) pre-hydrolysis of the silicon ester is obtained.
- Re exists in the form of oxide Re 2 O 7 in the catalyst
- ZnO has basicity, and can be neutralized catalyst preparation
- the acidity of the free TiO 2 formed during the process reduces the decomposition of the peroxide and increases the selectivity to PO.
- the atomization device such as a centrifugal atomizer, is used for atomization in the step (3).
- the atomized sol has an average particle size ranging from 100 to 850 ⁇ m by adjusting the size and rotation speed of the nozzle.
- the average particle diameter is 400-580 ⁇ m; the advantage of molding the sol by spraying into the liquid ammonia through the atomizer is: directly obtaining the spherical-like particles, so that the reactor per unit volume can be loaded with more catalyst; the particle strength after molding High, the average strength reaches 23-26N/piece; compared to the oil forming process, there is no step of removing the oil from the shaped catalyst precursor, and the process is simpler.
- the step (4) is preferably performed by using liquid ammonia as a pore-expanding agent; the reaming process preferably comprises: the pore-expanding agent is liquid ammonia, the reaming temperature is 60-140 ° C, and the reaming time is 3-15h.
- the purpose of the reaming of the present invention is to form a certain pore structure of the catalyst to expose more active Ti species, which facilitates contact of the reactants with the active center.
- the pore-expanding catalyst has a specific surface area of from 180 to 300 m 2 /g, a pore volume of from 0.9 to 1.1 ml/g, and an average pore diameter of from 8.5 to 13 nm.
- the invention adopts liquid ammonia as the pore expanding agent instead of the ammonia water or the ammonium salt aqueous solution because the water in the aqueous solution of ammonia or ammonium salt causes the formed skeleton Ti species to become free TiO 2 and reduces the selectivity of the catalyst to PO. .
- the step (5) drying temperature is 80-120 ° C, the drying time is preferably 2-5 h; roasting under air or any inert atmosphere, the heating rate is not strictly limited, and the usual heating rate 1-3 ° C can be used. /min, the calcination temperature is 450-600 ° C, and the calcination time is 2-5 h.
- the silylating agent in the step (6) is hexamethyldisilazane in an amount of 5-15% by weight, based on the theoretical total hydrolysis of the silicon ester to SiO 2 (ie, based on the step (1). ) in complete hydrolysis of the ester starting material of silicon SiO 2 corresponding to the SiO 2 mass).
- the temperature of the hexamethyldisilazane used in the silylation treatment is preferably 126-150 ° C; in some embodiments, the silylation treatment is carried out in a reaction tube, and the flow rate of N 2 in the reaction tube is 0.5- 1cm / s, silanization temperature is 200-300 ° C, silanization time is 60-180min; the silanization reagent vapor is brought into the reaction tube with N 2 , the chemical reaction occurs:
- the purpose of the silylation treatment is to increase the hydrophobicity of the catalyst surface, reduce the decomposition ability of the catalyst to the peroxide, and improve the selectivity of the catalyst to PO.
- the catalyst prepared by the production process of the present invention is particularly suitable for use as a catalyst for the epoxidation of propylene to produce propylene oxide (PO).
- the reaction conditions may be: the molar ratio of propylene to CHP (cumene hydroperoxide) is 5-7:1, mass space velocity It is 2-3.5 hr -1 ; initial reaction temperature: 50-60 ° C, and the reaction temperature is gradually increased according to CHP conversion (guaranteed CHP conversion > 99%).
- the preparation method of the present invention can achieve the technical effects that can be achieved by using the catalyst prepared by the templating agent in the prior art without using a templating agent, and reduce the catalyst cost;
- the catalyst is modified by adding NH 4 ReO 4 , and the additive Re synergizes with the Ti active center to increase the activity of the catalyst and the selectivity to propylene oxide;
- the preferred scheme is to modify the catalyst by adding Zn.
- the ZnO has basicity, can neutralize the acidity of free TiO 2 formed during the preparation of the catalyst, reduce the decomposition of the peroxide oxidant, and improve the selectivity to PO.
- the average selectivity of the catalyst to PO is as high as 97.5%, which reduces the propylene single consumption of the PO product;
- the sol is sprayed into liquid ammonia for molding, and the particle strength after molding is high, and the average strength reaches 23-26 N/piece; compared with the oil forming process, the oil is not precursored from the molding catalyst.
- the body removal step makes the process simpler.
- Figure 1 is an XRD pattern of the catalyst of Example 1;
- Figure 2 is an XRD pattern of the catalyst of Example 2;
- Figure 3 is an XRD pattern of the catalyst of Example 3.
- Figure 4 is an XRD pattern of the catalyst of Example 4.
- Figure 5 is an XRD pattern of the catalyst of Comparative Example 2.
- the specific surface area and the pore structure determination method are the BET method (N 2 physical adsorption method), and the instrument model is: ASP2020, produced by American Instruments.
- the strength measuring instrument model is: KC-3 digital particle strength measuring instrument, produced by Jiangyan Analytical Instrument Factory.
- the PO content in the reaction liquid and the exhaust gas absorption liquid was analyzed by gas chromatography, and the conversion rate of CHP was analyzed by an iodometric method.
- the chromatographic conditions are shown in Table 1.
- the content of PO was determined by internal standard method.
- the liquid concentration was determined by DMF as solvent and DT (dioxane) as internal standard.
- Liquid phase PO concentration (0.6985 ⁇ (A PO / A DT ) - 0.0046) ⁇ 0.01 ⁇ dilution factor
- Liquid phase PO content liquid phase PO concentration ⁇ liquid phase sampling quality
- Gas phase PO content gas phase PO concentration ⁇ total amount of absorption liquid / gas phase sampling amount
- Total PO production gas phase PO content + liquid phase PO content
- the CHP conversion rate was titrated by an iodometric method and measured by a titrator.
- CHP conversion rate (CHP initial value - CHP remaining amount) / EBHP initial value.
- the silicone ester used in the examples was tetraethyl orthosilicate, and the titanium ester was tetrabutyl titanate.
- the catalyst when the catalyst was evaluated, the catalyst was catalyzed by epoxidation of propylene to propylene oxide: the oxidant was cumene hydroperoxide (CHP), and the reaction tube was a fixed bed reaction having an inner diameter of 24 mm.
- the catalyst loading amount is 10g; the molar ratio of propylene to CHP is 7:1, the mass space velocity is 3.5hr -1 ; the initial reaction temperature is 50 ° C, and the conversion rate according to CHP (guaranteed CHP conversion rate >99%) Increase the reaction temperature.
- the sol is sprayed into liquid ammonia using a centrifugal atomizer to obtain a catalyst precursor
- the catalyst precursor was then reamed at 80 ° C for 15 h (with liquid ammonia as a pore-expanding agent).
- the reamed catalyst precursor was dried in an oven at 80 ° C for 2 h and calcined at 550 ° C for 3 h in a muffle furnace.
- the calcined sample is subjected to gas phase silanization treatment: 3 g of hexamethyldisilazane is added to the vaporization tank, the vaporization tank is heated at 130 ° C, and the hexamethyldisilazane vapor is introduced into the reaction tube with N 2 The reaction was carried out with the calcined sample.
- the linear velocity of N 2 in the reaction tube was 1 cm/s, the silanization temperature was 200 ° C, and the silanization time was 180 min; the obtained catalyst was designated TS-A1.
- the specific surface area of the TS-A1 catalyst measured by the BET method was 278.9 m 2 /g, the pore volume was 0.93 ml/g, the average pore diameter was 9.7 nm, and the average strength was 26.2 N/piece.
- XRD characterization of the TS-A1 catalyst did not reveal diffraction peaks of Ti species (TiO 2 or other Ti-containing compounds), which may reflect the good dispersion of Ti species from the side.
- the TS-A1 was evaluated and continuously operated for 480 hr. The reaction temperature was raised from the initial 50 ° C to 65 ° C, and the sample was subjected to gas chromatography analysis. The CHP conversion rate was >99.9%, and the selectivity to PO was 96.8%, and the average was 96.1%.
- the sol is sprayed into liquid ammonia using a centrifugal atomizer to obtain a catalyst precursor
- the catalyst precursor was then reamed at 120 ° C for 6 h (with liquid ammonia as a pore-expanding agent).
- the reamed catalyst precursor was dried in an oven at 100 ° C for 3 h and calcined at 450 ° C for 5 h in a muffle furnace.
- the calcined sample was subjected to gas phase silanization treatment: 7.2 g of hexamethyldisilazane was added to the vaporization tank, the vaporization tank was heated at 140 ° C, and the hexamethyldisilazane vapor was introduced into the reaction tube with N 2 .
- the sample after the calcination was neutralized, and the linear velocity of N 2 in the reaction tube was 0.5 cm/s, the silanization temperature was 250 ° C, and the silanization time was 120 min; the obtained catalyst was designated as TS-A2.
- the specific surface area of the TS-A2 catalyst measured by the BET method was 248.4 m 2 /g, the pore volume was 1.04 ml/g, the average pore diameter was 11 nm, and the average strength was 27.1 N per particle.
- XRD characterization of the TS-A2 catalyst did not reveal diffraction peaks of Ti species (TiO 2 or other Ti-containing compounds), which may reflect the good dispersion of Ti species from the side.
- the TS-A2 was evaluated for 1000 hr continuous operation, and the reaction temperature was raised from the initial 50 ° C to 80 ° C.
- the sample was subjected to gas chromatography analysis.
- the CHP conversion rate was >99.9%, and the selectivity to PO was 97.8%, and the average was 97.5%.
- the sol is sprayed into liquid ammonia using a centrifugal atomizer to obtain a catalyst precursor
- the catalyst precursor was then reamed at 140 ° C for 3 h (with liquid ammonia as a pore-expanding agent).
- the reamed catalyst precursor was dried in an oven at 120 ° C for 5 h and calcined at 600 ° C for 2 h in a muffle furnace.
- the calcined sample was subjected to gas phase silanization treatment: 12.6 g of hexamethyldisilazane was added to the vaporization tank, the vaporization tank was heated at 150 ° C, and the hexamethyldisilazane vapor was introduced into the reaction tube with N 2 .
- the sample after the calcination was neutralized, and the linear velocity of N 2 in the reaction tube was 0.6 cm/s, the silanization time was 100 min, the silylation temperature was 300 ° C, and the obtained catalyst was designated as TS-A3.
- the specific surface area of the TS-A3 catalyst measured by the BET method was 208.6 m 2 /g, the pore volume was 1.2 ml/g, the average pore diameter was 12.8 nm, and the average strength was 26.0 N/piece.
- XRD characterization of the TS-A3 catalyst did not reveal diffraction peaks of Ti species (TiO 2 or other Ti-containing compounds), which may reflect the good dispersibility of the Ti species from the side.
- the TS-A3 was evaluated for 800 hr continuous operation, and the reaction temperature was raised from the initial 50 ° C to 90 ° C.
- the sample was subjected to gas chromatography analysis.
- the CHP conversion rate was >99.9%, and the selectivity to PO was 97.2%, with an average of 96.9%.
- the sol is sprayed into liquid ammonia using a centrifugal atomizer to obtain a catalyst precursor
- the catalyst precursor was then reamed at 120 ° C for 6 h (with liquid ammonia as a pore-expanding agent).
- the reamed catalyst precursor was dried in an oven at 100 ° C for 3 h and calcined at 450 ° C for 5 h in a muffle furnace.
- the calcined sample was subjected to gas phase silanization treatment: 7.2 g of hexamethyldisilazane was added to the vaporization tank, the vaporization tank was heated at 140 ° C, and the hexamethyldisilazane vapor was introduced into the reaction tube with N 2 .
- the sample after the calcination was neutralized, and the linear velocity of N 2 in the reaction tube was 0.5 cm/s, the silanization temperature was 250 ° C, and the silanization time was 120 min; the obtained catalyst was designated as TS-A4.
- the specific surface area of the TS-N1 catalyst measured by the BET method was 248.2 m 2 /g, the pore volume was 1.04 ml/g, the average pore diameter was 11 nm, and the average strength was 26.6 N/piece.
- XRD characterization of the TS-A4 catalyst did not reveal diffraction peaks of Ti species (TiO 2 or other Ti-containing compounds), which may reflect the good dispersion of Ti species from the side.
- the TS-A2 was evaluated for 600 hr continuous operation, and the reaction temperature was raised from the initial 60 ° C to 90 ° C.
- the sample was subjected to gas chromatography analysis.
- the CHP conversion rate was >99.9%, and the selectivity to PO was 93.8%, and the average was 92.7%.
- the sol was aged for 12 h to form a gel.
- the gel was then dried in an oven at 100 ° C for 3 h, crushed, sieved to 0.4-1.2 mm pellets, and calcined at 450 ° C for 5 h in a muffle furnace.
- the calcined sample was subjected to gas phase silanization treatment: 7.2 g of hexamethyldisilazane was added to the vaporization tank, the vaporization tank was heated at 140 ° C, and the hexamethyldisilazane vapor was introduced into the reaction tube with N 2 .
- the sample after the calcination was neutralized, and the linear velocity of N 2 in the reaction tube was 0.5 cm/s, the silanization temperature was 250 ° C, and the silanization time was 120 min; the obtained catalyst was designated as TS-A5.
- the specific surface area of the TS-A5 catalyst measured by the BET method was 17.6 m 2 /g, the pore volume was 12.3 ml/g, the average pore diameter was 1.2 nm, and the average strength of the single particles was 14.2 N/piece.
- the TS-A4 was evaluated for 10 hours of continuous operation, the reaction temperature was 80 ° C, and the sample was subjected to gas chromatography analysis.
- the CHP conversion rate was >99.9%, and the selectivity to PO was 7.4%.
- the silanization time was 120 min at 250 ° C; the resulting catalyst was designated TS-A6.
- the XRD characterization of the TS-A6 catalyst revealed that the diffraction peak of TiO 2 (sharp diffraction peak in Figure 5) indicates that the Ti-SiO 2 catalyst prepared by vapor phase deposition has poor dispersibility of Ti species. Ti species are prone to aggregation and free titanium dioxide is produced.
- the TS-A6 was evaluated for 200 hr continuous operation, and the reaction temperature was raised from the initial 50 ° C to 90 ° C. The sample was subjected to gas chromatography analysis. The CHP conversion rate was >99.9%, and the selectivity to PO was 92.8%, and the average was 91.7%.
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Abstract
一种丙烯环氧化催化剂的制备方法,先将硅源预水解,再加入钛源反应形成溶胶,将溶胶通过雾化后喷入液氨中成型,并进行扩孔,再经干燥、焙烧及硅烷化处理得到Ti-SiO 2复合氧化物催化剂。该催化剂可以应用于丙烯环氧化制备环氧丙烷化工过程中,对环氧丙烷平均选择性高达97.5%,具有工业化应用前景。
Description
本发明涉及一种丙烯环氧化催化剂的制备方法,具体地说是Ti-SiO
2复合氧化物催化剂的制备方法及其作为催化剂催化丙烯环氧化制备环氧丙烷的用途。
以乙苯过氧化氢(EBHP)为氧化剂的乙苯共氧化工艺(PO/SM)和以异丙苯过氧化氢(CHP)为氧化剂的CHP工艺是生产环氧丙烷的两种重要工艺;这两种工艺克服了氯醇法的腐蚀大、污水多等缺点,具有产品成本低和环境污染较小等优点。
非均相PO/SM工艺环氧化工序所用催化剂为Ti-SiO
2复合氧化物,美国公开专利申请US3829392、US2003166951,中国公开专利申请CN1894030、CN1720100中公开其制备方法主要为:先将硅胶载体进行干燥处理,然后用N
2或其它惰性气体将卤化钛蒸汽带入反应管中与硅胶发生化学反应(该步骤称为化学气相沉积),高温焙烧,最后经过水洗等步骤制备得到催化剂。钛活性物种在SiO
2表面分散性不好,而且容易形成游离的TiO
2,导致氧化剂无效分解,降低PO的选择性。
CHP工艺所用催化剂也为Ti-SiO
2复合氧化物,美国公开专利申请US6211388、US5744619和中国公开专利申请CN7250775公开其制备方法为溶胶凝胶法:将硅源与钛源分别溶解在醇溶剂中,并加入季铵离子(如十六烷基溴化铵)作为模板剂,经水解、聚合、老化形成凝胶,再高温焙烧和硅烷化处理得到催化剂。溶胶凝胶法相比气相沉积法可以使不同组分在分子水平相互混溶,得到纳米相区甚至分子态分散的钛活性中心。但是溶胶凝胶法最大的缺点之一是在制备过程中需要加入价格昂贵的季铵盐作为模板剂,一般还需要通过高温焙烧除去模板剂,模板剂不可回收,造成催化剂成本较高。
基于现有的Ti-SiO
2复合氧化物制备方法的缺陷,需要开发一种Ti活性物种在SiO
2表面分散好,对PO选择性高,制造成本低的新的 催化剂制备方法。
发明内容
本发明的目的在于提供一种丙烯环氧化催化剂的制备方法,利用该方法制备催化剂的优势包括:利于Ti活性物种在SiO
2表面的分散,对PO选择性高,制造成本低。
本发明还提供一种由所述方法制备的催化剂(或称之为Ti-SiO
2复合氧化物催化剂),可以用做丙烯环氧化制备环氧丙烷(PO)的催化剂,具有高活性和对环氧丙烷的高选择性。
为实现上述发明目的,本发明采用的技术方案如下:
本发明所述的丙烯环氧化催化剂采用溶胶法制备,在液氨中成型,经扩孔、干燥和焙烧,最后进行硅烷化处理得到催化剂;本发明无需使用模板剂,使催化剂制作成本得以降低。优选方案中,使用Re和Zn对催化剂进行改性,在液氨中成型,经扩孔、干燥、高温焙烧,最后进行硅烷化处理;本发明不使用模板剂,在液氨中成型,更优选在液氨中扩孔,大幅降低催化剂制作成本;用Re和Zn对催化剂进行改性,Re、Zn和Ti协同作用能够提高催化剂的活性和对环氧丙烷的选择性。
具体地,一种丙烯环氧化催化剂的制备方法,包括以下步骤:
(1)硅源预水解:将硅酯溶解于低碳醇中,加入水解催化剂和水反应后得到A液;在具体实施方式中,优选该步骤中水的加入方式为逐滴加入,水具体可以为去离子水;
(2)成胶:将钛酯溶于低碳醇后,加入到A液中;之后向其中加入水进行反应得到溶胶,或者向其中加入NH
4ReO
4和锌盐的混合水溶液进行反应得到溶胶;在具体实施方式中,该步骤中钛酯溶于低碳醇后可采用逐滴加入的方式将其加入A液中,该步骤中的水或者NH
4ReO
4和锌盐的混合水溶液也可采用逐滴加入方式;
(3)将步骤(2)得到的溶胶雾化后喷入液氨中成型,得到催化剂前驱体;所述雾化具体可通过雾化器实施;
(4)将步骤(3)得到的催化剂前驱体进行扩孔处理;
(5)将步骤(4)扩孔后的催化剂前驱体干燥和焙烧;
(6)将步骤(5)得到的产物进行硅烷化处理,得到Ti-SiO
2复合氧化物催化剂。
本发明中,所述步骤(1)中硅酯可以是正硅酸乙酯、正硅酸甲酯、正硅酸丙酯、正硅酸丁酯等的一种或几种混合物;低碳醇可以为C1-C3的醇,低碳醇主要作为溶剂,采用不同的醇做溶剂无明显差异,例如可以是但不限于甲醇、乙醇、正丙醇、异丙醇中的一种或多种,较优选异丙醇;硅酯在低碳醇中的浓度优选为20-30wt%;水解催化剂优选为甲酸、乙酸中的一种或两种的混合物,加入量优选为硅酯的0.8-1.5wt%;步骤(1)中加入的水量优选为理论上硅酯水解30-80wt%所需的水量。步骤(1)的反应温度优选为40-70℃,反应时间优选为1-3h。本发明的制备方法,预先进行硅酯预水解,该步骤为关键步骤之一,因为钛酯水解速率快,而硅酯水解速率慢,两者水解速率不匹配,发明人发现如果不将硅酯预水解,会造成Ti活性组分分布不均匀,甚至会形成游离的TiO
2,而游离TiO
2会造成过氧化物的自分解反应,降低催化剂的选择性;而且,发明人在实验中发现,不加水解催化剂和不将硅源进行预水解会形成沉淀,不能形成凝胶。
本发明中,所述步骤(2)中所用钛酯可以是钛酸四甲酯、钛酸四乙酯、钛酸四丙酯、钛酸四异丙酯、钛酸四丁酯、钛酸四异丁酯中的一种或多种。所用钛酯中Ti的量优选为步骤(1)中原料硅酯理论上完全水解为SiO
2质量的2-5%(即,基于步骤(1)中原料硅酯理论上完全水解为SiO
2所对应的SiO
2质量),钛酯在低碳醇中的浓度优选为30-50wt%;采用优选的钛酯用量和浓度制备催化剂,可提高催化剂活性和更大程度避免游离二氧化钛的形成。优选的,步骤(2)中的反应时间为1h-4h。
本发明中,步骤(2)中钛酯完全加入到步骤(1)中的A液后,一种方案是,加入水进行反应得到溶胶;而更优选的方案是不加水而加入NH
4ReO
4和锌盐混合水溶液进行反应,形成溶胶。在步骤(2)中,加入水进行反应的方案中,水的用量优选为步骤(1)未水解的硅酯和步骤(2)钛酯理论上完全水解所需要的水量。而在优选的方案中, 在步骤(2)中,所用的NH
4ReO
4和锌盐混合水溶液的浓度无特殊要求,所用NH
4ReO
4中的Re与所用钛酯中的Ti的摩尔比优选为0.01-0.05:1,所用锌盐中的Zn与所用钛酯中的Ti的摩尔比为0.05-0.15:1,采用优选比例的NH
4ReO
4和锌盐,二者可发挥较佳的协同作用。所用的锌盐只要能溶于水都可以采用,例如可以为但不限于ZnCl
2和Zn(NO
3)
2中的一种或两种混合物。在一些具体实施方式中,NH
4ReO
4和锌盐混合水溶液中所用水量为步骤(1)未水解的硅酯和步骤(2)钛酯理论上完全水解所需要的水量。其中步骤(1)中未水解的硅酯所需的水量根据硅酯的总量计算完全水解需要的水,然后再减去步骤(1)硅酯预水解添加的水量即可得到。实验发现加入一定量的Re对催化剂进行改性(Re在催化剂中以氧化物Re
2O
7形式存在),Re和Ti(在催化剂中,Ti的存在形式主要为T=O四面体或者称为四配位的骨架Ti)协同作用提高了催化剂对PO的选择性;加入一定量Zn对催化剂进行改性(Zn在催化剂中以氧化物ZnO形式存在),ZnO具有碱性,可以中和催化剂制备过程中形成的游离的TiO
2的酸性,减少过氧化物的分解,提高对PO的选择性。
本发明中,所述步骤(3)中使用雾化器例如离心式雾化器进行雾化,在一些优选实施方式中通过调整喷头大小和转速使雾化的溶胶平均粒径范围为100-850μm,优选平均粒径400-580μm;采用将溶胶通过雾化器喷入液氨中进行成型的优点为:直接得到类球形颗粒,使单位体积的反应器能装填更多的催化剂;成型后颗粒强度高,平均强度达到23-26N/颗;相比油中成型工艺,没有将油从成型催化剂前驱体脱除的步骤,工艺过程更简单。
本发明中,所述步骤(4)进行扩孔处理优选采用液氨作为扩孔剂;扩孔工艺条件优选包括:扩孔剂为液氨,扩孔温度为60-140℃,扩孔时间为3-15h。本发明进行扩孔的目的是使催化剂形成一定的孔道结构,使更多活性Ti物种暴露,有利于反应物接触到活性中心。本发明一些优选实施方式中,扩孔得到的催化剂比表面积为180-300m
2/g,孔容为0.9-1.1ml/g,平均孔径为8.5-13nm。本发明采用液氨为扩孔剂而不采用氨水或铵盐水溶液是因为:氨水或铵盐水溶液中的水会造成已 经形成的骨架Ti物种变成游离的TiO
2,降低催化剂对PO的选择性。
本发明中,所述步骤(5)干燥温度为80-120℃,干燥时间优选为2-5h;在空气或任何惰性气氛下焙烧,升温速率没有严格限制,可以采用常用升温速率1-3℃/min,焙烧温度为450-600℃,焙烧时间为2-5h。
本发明中,所述步骤(6)中硅烷化试剂为六甲基二硅胺烷,用量为5-15wt%,以硅酯理论上全部水解为SiO
2的质量计(即,基于步骤(1)中原料硅酯完全水解为SiO
2所对应的SiO
2质量)。进行所述硅烷化处理所用的六甲基二硅胺烷温度优选为126-150℃;在一些具体实施方式中,硅烷化处理在反应管中进行,N
2在反应管中的流速为0.5-1cm/s,硅烷化温度为200-300℃,硅烷化时间为60-180min;用N
2将硅烷化试剂蒸汽带入反应管中,发生的化学反应为:
~O-Si-OH+Si(CH
3)
3-NH-Si(CH
3)
3→~O-Si-O-Si(CH
3)
3
进行硅烷化处理的目的为提高催化剂表面的疏水性,降低催化剂对过氧化物的分解能力,提高催化剂对PO的选择性。
本发明的制备方法制得的的催化剂特别适用于作为丙烯环氧化制备环氧丙烷(PO)的催化剂。在将其应用于催化丙烯环氧化制备环氧丙烷(PO)时,反应的工艺条件可以为:丙烯和CHP(异丙苯过氧化氢)的摩尔比为5-7:1,质量空速为2-3.5hr
-1;起始反应温度:50-60℃,根据CHP转化率(保证CHP转化率>99%)逐渐升高反应温度。
采用本发明的技术方案,可取得的技术效果包括:
(1)本发明的制备方法无需使用模板剂,依然能达到现有技术中使用模板剂制备的催化剂所能达到的技术效果,降低了催化剂成本;
(2)优选的方案中通过添加NH
4ReO
4对催化剂进行改性,助剂Re与Ti活性中心协同作用,提高了催化剂的活性和对环氧丙烷的选择性;
(3)优选的方案中添加Zn对催化剂进行改性,ZnO具有碱性,可以中和催化剂制备过程中形成的游离的TiO
2的酸性,减少过氧化物氧化剂的分解,提高对PO的选择性;催化剂对PO的平均选择性高达97.5%,降低了PO产品丙烯单耗;
(4)采用将溶胶雾化后喷入液氨中进行成型直接得到球形颗粒或类球形颗粒,不用经过一般溶胶凝胶法非常耗时的老化步骤,提高生产效率;
(5)本发明在制备催化剂过程中,将溶胶喷入液氨中进行成型,成型后颗粒强度高,平均强度达到23-26N/颗;相比油中成型工艺,没有将油从成型催化剂前驱体脱除步骤,工艺过程更简单。
图1为实施例1催化剂的XRD图谱;
图2为实施例2催化剂的XRD图谱;
图3为实施例3催化剂的XRD图谱;
图4为实施例4催化剂的XRD图谱;
图5为对比例2催化剂的XRD图谱。
为了更好理解本发明,下面结合实施例进一步阐明本发明内容,但本发明的内容不仅仅局限于下面的实施例。
本发明实施例中比表面积及孔结构测定方法为BET法(N
2物理吸附法),仪器型号为:ASP2020,美国麦克仪器公司产。
本发明实施例中强度测定仪型号为:KC-3数显颗粒强度测定仪,姜堰市分析仪器厂产。
本发明实施例中通过气相色谱进行分析反应液及尾气吸收液中的PO含量,通过碘量法分析CHP的转化率。色谱分析条件如表1所示。
表1 色谱操作条件
通过内标法进行PO含量测定,液相浓度测定以DMF为溶剂,以DT(二氧六环)为内标物,测定PO与DT的内标标准曲线为y=0.6985x-0.0046,R
2=0.999;气相吸收液PO浓度测定以甲苯为内标物,测定PO与甲苯的内标标准曲线y=2.161x+0.0002,R
2=0.999。
液相PO浓度=(0.6985×(A
PO/A
DT)-0.0046)×0.01×稀释倍数
液相PO含量=液相PO浓度×液相取样质量
气相PO浓度=(2.162×(A
PO/A
甲苯)+0.0002)×甲苯质量
气相PO含量=气相PO浓度×吸收液总量/气相取样量
PO总生成量=气相PO含量+液相PO含量
PO的选择性=PO总生成量/理论上CHP所能氧化丙烯生成的PO量×100%
CHP转化率通过碘量法进行滴定,采用滴定仪进行测定。
CHP转化率=(CHP初始值-CHP剩余量)/EBHP初始值。
实施例中所用硅酯为正硅酸乙酯,钛酯为钛酸四丁酯。
以下实施例及对比例中评价催化剂时,催化剂在丙烯环氧化制环氧丙烷中进行催化的工艺条件为:氧化剂为异丙苯过氧化氢(CHP),反应管为内径24mm的固定床反应器,催化剂装填量为10g;丙烯和CHP的摩尔比为7:1,质量空速为3.5hr
-1;起始反应温度:50℃,根据CHP转化率(保证CHP转化率>99%)逐渐升高反应温度。
实施例1
将208g正硅酸乙酯溶解于792g异丙醇中,然后加入1.67g甲酸作为水解催化剂,逐滴加入10.8g去离子水,50℃反应1h,记做A液;
称取8.5g钛酸四丁酯溶于19.8g异丙醇后,逐滴加入到A液中,搅拌均匀,记为B液;称取0.067g NH
4ReO
4和0.17gZnCl
2溶于25.2g去离子水中,逐滴加入B液中,搅拌均匀,记为C液。C液反应4h形成溶胶;
将溶胶使用离心型雾化器喷入液氨中成型,得到催化剂前驱体;
然后将催化剂前驱体在80℃下扩孔处理15h(以液氨为扩孔剂)。
将扩孔后的催化剂前驱体在烘箱中80℃干燥2h,在马弗炉内550℃焙烧3h。
将焙烧后的样品进行气相硅烷化处理:在汽化罐中加入3g六甲基二硅胺烷,汽化罐加热温度为130℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和焙烧后的样品进行反应,N
2在反应管中线速度为1cm/s,硅烷化温度为200℃,硅烷化时间为180min;得到的催化剂记为TS-A1。
BET法测定TS-A1催化剂的比表面积为278.9m
2/g,孔容为0.93ml/g,平均孔径为9.7nm;平均强度为26.2N/颗。对TS-A1催化剂进行XRD表征(见图1)没有发现有Ti物种(TiO
2或其它含Ti化合物)的衍射峰,该结果可从侧面反映出Ti物种分散性良好。对TS-A1进行评价,连续运行480hr,反应温度由最初50℃升温至65℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性最高达到96.8%,平均达到96.1%。
实施例2
将249.6g正硅酸乙酯溶解于750.4g异丙醇中,然后加入2.5g甲酸作为水解催化剂,逐滴加入21.6g去离子水,60℃反应90min,记做A液;
称取17.85g钛酸四丁酯溶于26.78g异丙醇后,逐滴加入到A液中,搅拌均匀,记为B液;称取0.422g NH
4ReO
4和0.714gZnCl
2溶于 21.6g去离子水中,逐滴加入B液中,搅拌均匀,记为C液。C液反应2h形成溶胶;
将溶胶使用离心型雾化器喷入液氨中成型,得到催化剂前驱体;
然后将催化剂前驱体在120℃下扩孔处理6h(以液氨为扩孔剂)。
将扩孔后的催化剂前驱体在烘箱中100℃干燥3h,在马弗炉内450℃焙烧5h。
将焙烧后的样品进行气相硅烷化处理:在汽化罐中加入7.2g六甲基二硅胺烷,汽化罐加热温度为140℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和焙烧后的样品进行反应,N
2在反应管中线速度为0.5cm/s,硅烷化温度为250℃,硅烷化时间为120min;得到的催化剂记为TS-A2。
BET法测定TS-A2催化剂的比表面积为248.4m
2/g,孔容为1.04ml/g,平均孔径为11nm;平均强度为27.1N/颗。对TS-A2催化剂进行XRD表征(见图2)没有发现有Ti物种(TiO
2或其它含Ti化合物)的衍射峰,该结果可从侧面反映出Ti物种分散性良好。
对TS-A2进行评价,连续运行1000hr,反应温度由最初50℃升温至80℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性最高达到97.8%,平均达到97.5%。
实施例3
将291.2g正硅酸乙酯溶解于707.8g异丙醇中,然后加入4.36g乙酸作为水解催化剂,逐滴加入50.4g去离子水,70℃反应140min,记做A液;
称取29.75g钛酸四丁酯溶于29.75g异丙醇后,逐滴加入到A液中,搅拌均匀,记为B液;称取1.172g NH
4ReO
4和1.785gZnCl
2溶于10.08g去离子水中,逐滴加入B液中,搅拌均匀,记为C液。C液反应1h形成溶胶;
将溶胶使用离心型雾化器喷入液氨中成型,得到催化剂前驱体;
然后将催化剂前驱体在140℃下扩孔处理3h(以液氨为扩孔剂)。
将扩孔后的催化剂前驱体在烘箱中120℃干燥5h,在马弗炉内600℃焙烧2h。
将焙烧后的样品进行气相硅烷化处理:在汽化罐中加入12.6g六甲基二硅胺烷,汽化罐加热温度为150℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和焙烧后的样品进行反应,N
2在反应管中线速度为0.6cm/s,硅烷化时间为100min;硅烷化温度为300℃,得到的催化剂记为TS-A3。
BET法测定TS-A3催化剂的比表面积为208.6m
2/g,孔容为1.2ml/g,平均孔径为12.8nm;平均强度为26.0N/颗。对TS-A3催化剂进行XRD表征(见图3)没有发现有Ti物种(TiO
2或其它含Ti化合物)的衍射峰,该结果可从侧面反映出Ti物种分散性良好。
对TS-A3进行评价,连续运行800hr,反应温度由最初50℃升温至90℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性最高达到97.2%,平均达到96.9%。
实施例4
将249.6g正硅酸乙酯溶解于750.4g异丙醇中,然后加入2.5g甲酸作为水解催化剂,逐滴加入21.6g去离子水,60℃反应90min,记做A液;
称取17.85g钛酸四丁酯溶于26.78g异丙醇后,逐滴加入到A液中,搅拌均匀,记为B液;将21.6g去离子水,逐滴加入B液中。B液反应3h形成溶胶。
将溶胶使用离心型雾化器喷入液氨中成型,得到催化剂前驱体;
然后将催化剂前驱体在120℃下扩孔处理6h(以液氨为扩孔剂)。
将扩孔后的催化剂前驱体在烘箱中100℃干燥3h,在马弗炉内450℃焙烧5h。
将焙烧后的样品进行气相硅烷化处理:在汽化罐中加入7.2g六甲基二硅胺烷,汽化罐加热温度为140℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和焙烧后的样品进行反应,N
2在反应管中线速度为 0.5cm/s,硅烷化温度为250℃,硅烷化时间为120min;得到的催化剂记为TS-A4。
BET法测定TS-N1催化剂的比表面积为248.2m
2/g,孔容为1.04ml/g,平均孔径为11nm;平均强度为26.6N/颗。对TS-A4催化剂进行XRD表征(见图4)没有发现有Ti物种(TiO
2或其它含Ti化合物)的衍射峰,该结果可从侧面反映出Ti物种分散性良好。
对TS-A2进行评价,连续运行600hr,反应温度由最初60℃升温至90℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性最高达到93.8%,平均达到92.7%。
对比例1
将249.6g正硅酸乙酯溶解于750.4g异丙醇中,然后加入2.5g甲酸作为水解催化剂,逐滴加入21.6g去离子水,60℃反应90min,记做A液;
称取17.85g钛酸四丁酯溶于26.78g异丙醇后,逐滴加入到A液中,搅拌均匀,记为B液;将21.6g去离子水中,逐滴加入B液中,搅拌均匀,记为C液。C液反应1h形成溶胶;
将溶胶经过12h老化形成凝胶。
然后将凝胶在烘箱中100℃干燥3h,破碎,筛分0.4-1.2mm颗粒,在马弗炉内450℃焙烧5h。
将焙烧后的样品进行气相硅烷化处理:在汽化罐中加入7.2g六甲基二硅胺烷,汽化罐加热温度为140℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和焙烧后的样品进行反应,N
2在反应管中线速度为0.5cm/s,硅烷化温度为250℃,硅烷化时间为120min;得到的催化剂记为TS-A5。
BET法测定TS-A5催化剂的比表面积为17.6m
2/g,孔容为12.3ml/g,平均孔径为1.2nm;单颗粒平均强度为14.2N/颗。
对TS-A4进行评价,连续运行10hr,反应温度80℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性为7.4%。
对比例2
参考专利CN1894030进行催化剂制备:
称取30g硅胶载体装填入反应管中,在N
2气氛下,240℃下干燥240min,N
2在反应管中线速度为2cm/s;在TiCl
4汽化罐中加入4.17g TiCl
4,TiCl
4汽化罐加热温度为145℃,用N
2将TiCl
4蒸汽带入反应管中和硅胶进行反应,N
2在反应管中线速度为0.8cm/s,沉积时间为200min;以2℃/min升温速率升至600℃,N
2在反应管中线速度为2cm/s,焙烧200min;在水和硅烷化试剂汽化罐中加入33.5g蒸馏水,水和硅烷化试剂汽化罐加热温度为160℃,用N
2将水蒸汽带入反应管中进行水洗,N
2在反应管中线速度为2cm/s,水洗时间为200min;在水和硅烷化试剂汽化罐中加入2.4g六甲基二硅胺烷,水和硅烷化试剂汽化罐加热温度为140℃,用N
2将六甲基二硅胺烷蒸汽带入反应管中和硅胶进行反应,N
2在反应管中线速度为0.5cm/s,硅烷化温度为250℃,硅烷化时间为120min;得到的催化剂记为TS-A6。
对TS-A6催化剂进行XRD表征(见图5),发现有TiO
2的衍射峰(图5中尖锐的衍射峰),说明气相沉积法制备的Ti-SiO
2催化剂Ti物种的分散性不好,Ti物种易聚集,有游离的二氧化钛产生。对TS-A6进行评价,连续运行200hr,反应温度由最初50℃升温至90℃,取样进行气相色谱分析,CHP转化率>99.9%,对PO的选择性最高达到92.8%,平均达到91.7%。
Claims (12)
- 一种丙烯环氧化催化剂的制备方法,包括以下步骤:(1)硅源预水解:将硅酯溶解于低碳醇中,加入水解催化剂和水反应后得到A液;(2)成胶:将钛酯溶于低碳醇后加入到A液中;加入水或者加入NH 4ReO 4和锌盐的混合水溶液,反应后得到溶胶;(3)将步骤(2)得到的溶胶雾化后喷入液氨中进行成型,得到催化剂前驱体;(4)将步骤(3)得到的催化剂前驱体进行扩孔处理;(5)将步骤(4)扩孔后的催化剂前驱体干燥和焙烧;(6)将步骤(5)得到的产物进行硅烷化处理。
- 根据权利要求1所述的方法,其特征在于,步骤(1)中所述硅酯选自正硅酸乙酯、正硅酸甲酯、正硅酸丙酯、正硅酸丁酯中的一种或多种,硅酯在低碳醇中的浓度优选为20-30wt%。
- 根据权利要求1或2所述的方法,其特征在于,所述步骤(1)中水解催化剂为乙酸、甲酸中的一种或两种的混合物;优选的,步骤(1)中,水解催化剂的加入量为硅酯的0.8-1.5wt%;加入的水量为理论上硅酯水解30-80wt%所需的水量;优选的,步骤(1)的反应温度为40-70℃,反应时间为1-3h。
- 根据权利要求1-3任一项所述的方法,其特征在于,步骤(2)中所用的钛酯选自钛酸四甲酯、钛酸四乙酯、钛酸四丙酯、钛酸四异丙酯、钛酸四丁酯、钛酸四异丁酯中的一种或多种;优选的,基于步骤(1)中原料硅酯完全水解为SiO 2所对应的SiO 2质量,步骤(2)中所用钛酯中Ti的量为所述SiO 2质量的2-5%;优选的,步骤(2)中,所述钛酯在低碳醇中的浓度为30-50wt%,优选的,步骤(2)的反应时间为1-4h。
- 根据权利要求1-4中任一项所述的方法,其特征在于,步骤(2)中,所用NH 4ReO 4中的Re与所用钛酯中的Ti的摩尔比为0.01-0.05:1,所用锌盐中的Zn与所用钛酯中的Ti的摩尔比为0.05-0.15:1。
- 根据权利要求1-5任一项所述的方法,其特征在于,步骤(2)中,若加入水进行反应形成溶胶,所加入的水的量为步骤(1)未水解的硅酯和步骤(2)钛酯理论上完全水解需要的水量;步骤2)中,若加入NH 4ReO 4和锌盐混合水溶液进行反应形成溶胶,该NH 4ReO 4和锌盐混合水溶液所含的水的量为步骤(1)未水解的硅酯和步骤(2)钛酯理论上完全水解需要的水量。
- 根据权利要求1-6中任一项所述的方法,其特征在于,所述步骤(3)中使用雾化器优选使用离心式雾化器雾化溶胶,雾化器喷出的溶胶平均粒径范围为100-850μm,优选平均粒径为400-580μm。
- 根据权利要求1-7中任一项所述的方法,其特征在于,步骤(4)中进行所述扩孔处理所采用的扩孔剂为液氨;优选的,步骤(4)进行扩孔处理的工艺条件包括:扩孔剂为液氨,扩孔温度优选为60-140℃;扩孔时间优选为3-15h。
- 根据权利要求1-8中任一项所述的方法,其特征在于,所述步骤(5)干燥温度为80-120℃,优选干燥时间为2-5h;焙烧温度为450-600℃,优选焙烧时间为2-5h。
- 根据权利要求1-9任一项所述的方法,其特征在于,步骤(6)中所述硅烷化处理采用的硅烷化试剂为六甲基二硅胺烷;基于步骤(1)中原料硅酯完全水解为SiO 2所对应的SiO 2质量,所述六甲基二硅胺烷的用量为5-15wt%;优选的,进行所述硅烷化处理所用的六甲基二硅胺烷的温度为126-150℃,硅烷化处理的温度为200-300℃,硅烷化处理的时间为60-180min。
- 根据权利要求1-10任一项所述的方法,其特征在于,步骤(1)和步骤(2)中所述低碳醇选自C1-C3的醇。
- 一种根据权利要求1-11中任一项所述的方法制备的催化剂作为丙烯环氧化制备环氧丙烷催化剂的用途。
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