WO2018154409A1 - 用于深色纺织物或工程塑料的色母组成物及其制品 - Google Patents

用于深色纺织物或工程塑料的色母组成物及其制品 Download PDF

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Publication number
WO2018154409A1
WO2018154409A1 PCT/IB2018/050864 IB2018050864W WO2018154409A1 WO 2018154409 A1 WO2018154409 A1 WO 2018154409A1 IB 2018050864 W IB2018050864 W IB 2018050864W WO 2018154409 A1 WO2018154409 A1 WO 2018154409A1
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Prior art keywords
pigment
blue
pet
yellow
color master
Prior art date
Application number
PCT/IB2018/050864
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English (en)
French (fr)
Inventor
苏文渊
Original Assignee
李耀辉
苏文渊
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 李耀辉, 苏文渊 filed Critical 李耀辉
Priority to KR1020197026505A priority Critical patent/KR102280464B1/ko
Priority to MYPI2019004791A priority patent/MY193530A/en
Priority to US16/487,090 priority patent/US11034803B2/en
Priority to EP18757103.9A priority patent/EP3587475A4/en
Priority to JP2019565998A priority patent/JP6934137B2/ja
Publication of WO2018154409A1 publication Critical patent/WO2018154409A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/203—Solid polymers with solid and/or liquid additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D01F6/625—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters derived from hydroxy-carboxylic acids, e.g. lactones
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/23—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3437—Six-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C08K5/3447—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3462—Six-membered rings
    • C08K5/3465—Six-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/02—Reinforcing materials; Prepregs

Definitions

  • the present invention relates to a color masterbatch composition, and more particularly to a masterbatch composition for textiles or engineering plastics and articles thereof. Background technique
  • Dark textiles are commonly used in clothing, curtains and sofas.
  • Dark engineering plastics are widely used in electrical appliances and automotive components. They have good light-shielding properties and avoid dirt.
  • the pre-spinning coloring of a deep woven fabric or an engineering plastic is obtained by adding carbon black which is easily obtained as a pigment to a raw material, but also causes a problem that the infrared ray is easily absorbed and the product is rapidly heated.
  • TW 1509038 discloses an infrared low-temperature pigment composition which, by combining a plurality of specific pigments, can reduce the temperature rise effect by absorbing infrared rays.
  • the inventors of the present invention have noticed that most of the pigment compositions disclosed in the above patents and the films formed of thermoplastic polyesters are processed through textiles or engineering plastics (for example: at 285-300). After heating in °C:), the original color of the pigment composition cannot be maintained, and dyeing must be carried out after the product is formed to obtain a dark textile (spinning coloring:) or engineering plastic, thus increasing the complexity of processing. Sexual and wastewater pollution problems. Summary of the invention
  • a first object of the present disclosure is to provide a color master composition that overcomes the disadvantages of the above-described background art.
  • the masterbatch composition of the present disclosure comprises a thermoplastic polyester, a yellow color component, a red color component, and a blue color component.
  • the yellow colorant component is selected from the group consisting of Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Solvent Brown 53 or combinations thereof.
  • the red colorant component is selected from the group consisting of Pigment Red 122, Pigment Red 144, Pigment Red 202, Pigment Red 214, or a combination thereof.
  • the blue color component is selected from the group consisting of pigment blue 60, solvent blue 67, or a combination thereof.
  • the above color materials are expressed in terms of a color index (color mdex) common name.
  • a second object of the present disclosure is to provide a colloidal particle which is a color master as described above.
  • the composition is obtained by coloring in a base material mainly composed of a thermoplastic polyester.
  • a third object of the present disclosure is to provide a fiber obtained by spinning a rubber particle as described above.
  • a fourth object of the present disclosure is to provide a plastic obtained by molding the colloidal particles as described above. detailed description
  • the present disclosure provides a masterbatch composition
  • a masterbatch composition comprising a thermoplastic polyester, a yellow color component, a red color component, and a blue color component.
  • the yellow colorant component is selected from the group consisting of Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Dye Brown 53, or a combination thereof.
  • the red color component is selected from Pigment Red 122, Pigment Red 144, Pigment Red 202, Pigment Red 214, or a combination thereof.
  • the blue color component is selected from Pigment Blue 60, Dye Blue 67, or a combination thereof.
  • the above pigments are expressed according to the color index common name.
  • the color master composition may further comprise titanium dioxide.
  • the total weight of the masterbatch composition is 100 wt%, and the content of the titania may range from more than 0 wt% to 5 wt%.
  • thermoplastic polyesters suitable for use in the present disclosure include, but are not limited to: polyethylene terephthalate (PET:), polybutylene terephthalate (PBT:), functionalized poly Functionalized derivatives of PET, functionalized derivatives of PB T, copolymers thereof, etc. Blends.
  • the total content of the color master composition is 100 wt%, and the content of the red color component may range from 8 wt% to 15 wt%.
  • the total weight of the color masterbatch is 100 wt%, and the content of the yellow colorant component ranges from 7 wt% to 15 wt%.
  • the total weight of the color masterbatch is 100 wt%, and the content of the blue toner component ranges from 5 wt% to 15 wt%.
  • the total weight of the color master composition is 100 wt%, and the yellow color component is dye brown 53 in an amount ranging from 7 wt% to 10 wt%.
  • the blue colorant is dye blue 67 in an amount ranging from 5 wt% to 10 wt%.
  • the masterbatch composition may also comprise existing additives such as ultraviolet absorbers, antioxidants, flame retardants, or combinations thereof.
  • the present disclosure provides a colloidal particle obtained by developing a color master composition as described above in a base material mainly composed of a thermoplastic polyester.
  • the present disclosure also provides a method of preparing a colloidal particle comprising developing a color master composition as described above in a thermoplastic polyester based substrate.
  • the content of the color masterbatch ranges from 1 wt% to 10 wt%, based on the total weight of the micelles being 100 wt%.
  • thermoplastic polyester in the substrate may be the same as or different from the thermoplastic polyester in the above-described masterbatch composition.
  • processed articles such as fibers or plastics
  • processed articles made from the above-mentioned rubber particles have the effect of slowing down and reducing the heat absorption and maintaining their original color during the necessary processing. It is beneficial for textiles or engineering plastics, especially dark textiles or engineering plastics.
  • the present disclosure provides a fiber obtained by spinning a colloidal particle as described above.
  • the present disclosure also provides a method of making a fiber comprising spinning a colloidal particle as described above.
  • the above spinning can be carried out according to the operating conditions conventionally used in the art, for example, 285-300 °C.
  • the present disclosure provides a plastic obtained by molding a colloidal particle as described above.
  • the present disclosure also provides a method of making a plastic comprising molding a colloidal particle as described above.
  • examples of plastics include, but are not limited to, film and plastic film.
  • molding means a method of forming a raw material using a mold or a matrix.
  • molding methods suitable for use in the present disclosure include, but are not limited to, injection molding, extrusion molding, compression molding, and rotational molding. ) and similar methods.
  • the molding can be carried out according to the operating conditions conventionally used in the art, for example, 285 ° C to 300 ° C.
  • the coloring materials were added to the pulverized thermoplastic polyester granules according to the content ratio of Table 1 below, and further subjected to extrusion kneading at 240 to 280 ° C in a twin-screw extruder to obtain Examples A1 to A32. Masterbatch composition. Table 1
  • the colorant was added to the pulverized thermoplastic polyester granules according to the content ratio of Table 2 below (95 wt% total), and 5 wt% of titanium dioxide was added, followed by extrusion at 240-280 ° C in a twin-screw extruder. The mixture was kneaded to obtain a color master composition of Examples B 1 to B32. Table 2
  • Examples C1 - C32 and D1 - D32 were similar to Examples A1 - A32 and B 1-B32, respectively, except that PET was replaced by PBT to obtain the color masterbatch of Examples C1 - C32 and D1 - D32, respectively. Composition.
  • the color master compositions of the above Examples Al-A32, Bl-B32, C1-C32, and D1-D32 were pelletized, and then added to PET for color development (color masterbatch composition accounted for 6 wt% of total weight:).
  • PET pellets PET A1-A32 , PET B1-B32 , PET C1-C32, and PET D1-D32 of Example 1 were used.
  • the PET colloidal particles PET A1 . A32 , PET B1 . B32 , PET C1 . C32 and PET D1-D32 of the above application example 1 were drawn at 285-300 ° C to obtain the fiber F A1-A32 of Application Example 2.
  • F B1-B32 , Fci-C32 and F D1-D32 fiber fineness is 3 DPF).
  • the fibers F A1-A32 and F B1- B32 are black, fiber? 1 . folk 2 and F D1 . D32 is dark grey and can be applied to dark textiles.
  • PET colloidal particles PET A1 . A32 , PET B1 . B32 , PET C1 . C32 and PET D1-D32 of the above application example 1 were shot at 285-300 ° C to obtain the film S A1-A32 of Application Example 3, S B1-B32 ,
  • the films S A1-A32 and s B1-B32 are black, and the films S C1-C32 and s D1 . D32 are dark gray, which can be applied to dark engineering plastics.
  • the color master composition of the above Comparative Example CB and Z1 -Z4 was pelletized and added to PET for color development (the color master composition accounted for 5.5 wt% of the total weight), and the carbon black PET colloidal PETCB of Comparative Application Example 1 was obtained. Black PET colloidal PET Z 1 . Z4 .
  • the carbon black PET colloidal PET CB of Comparative Application Example 1 and the black PET colloidal particles of Comparative Application Example 2 were compared as described above.
  • £ 21 . 24 was drawn at 285 -300 °C to produce the fibers of Comparative Application Example 3, respectively. 13 and F Z 1 . Z4 .
  • the fibers F Z 1 . Z4 are faded and light brown, and cannot be directly applied to dark textiles.
  • the infrared heating test results in Table 4 show that the PET colloidal PET A 1 .
  • A32 obtained by using the color master composition of the present disclosure absorbs infrared rays for 10 minutes. The temperature is below 67 °C, and the temperature after absorbing infrared rays for 55 minutes is maintained below 74 °C; and the carbon black PET colloidal PET CB made of carbon black has a high temperature after 10 minutes of absorbing infrared rays. At 100 °C, it shows that the heating rate is faster and the temperature rise is larger.
  • the temperature rise test results of £1 ⁇ . complaint 2 and PET D 1 . D32 are similar to the results of the temperature rise test of PET colloidal PET A 1 . A32 .
  • the above experimental results indicate the contents of this disclosure.
  • the color masterbatch composition slows down and reduces the warming effect caused by the absorption of infrared rays.
  • the color masterbatch of the present disclosure can reduce and reduce the temperature rise effect caused by absorbing infrared rays without additionally adding other heat dissipating materials or modifying, and can still be maintained during the processing of preparing fibers or plastics. Its original color is therefore suitable for the preparation of dark textiles or engineering plastics, so it is indeed possible to achieve the object of the present invention.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Artificial Filaments (AREA)

Abstract

一种色母组成物，包含热塑性聚酯、黄色色料组分、红色色料组分及蓝色色料组分。该黄色色料组分是选自于颜料黄147、颜料黄18 、颜料黄183、染料棕53或其组合。该红色色料组分是选自于颜料红 22、颜料红144、颜料红202、颜料红214或其组合。该蓝色色料组分是选自于颜料蓝60、染料蓝67或其组合。本发明另提供一种胶粒，是将如上所述的色母组成物在以热塑性聚酯为主的基材中展色而得。本揭露内容所制得的制品具有减缓并降低吸热的效果，且在加工过程中仍可维持其原有的颜色。

Description

用于深色纺织物或工程塑料的色母组成物及其制品 技术领域
本发明涉及一种色母组成物（color masterbatch composition) ,特别 是涉及一种用于纺织物或工程塑料（engineering plastics)的色母组成 物及其制品。 背景技术
深色纺织物普遍用于衣着、 窗帘及沙发等， 深色工程塑料广泛用 于电器及汽车零组件等， 具有良好遮光性及避免脏污的功能。 一般深 色纺织物或工程塑料的纺前着色是在原料中添加容易取得且供作为 颜料的碳黑（carbon black)而制得， 但也因此产生容易吸收红外线而导 致其制品快速升温的问题。
TW 1509038 公开一种红外线低升温颜料组成物， 通过选择数种 特定的颜料加以组合，可降低因吸收红外线而造成的升温效果。然而， 本案发明人注意到上述专利案所公开的大部分颜料组成物与热塑性 聚酯（thermoplastic poly esters)所形成的胶片， 在经过纺织物或工程塑 料的必要加工过程（例如： 在 285-300 °C中加热：)后， 无法维持其颜料组 成物原有的颜色， 必须在形成制品后再进行染色才能制得深色纺织物 (纺后着色：)或工程塑料，因此增加了加工的复杂性及废水污染的问题。 发明内容
本揭露内容的第一目的在于提供一种色母组成物， 可以克服上述 背景技术的缺点。
本揭露内容的色母组成物包含热塑性聚酯、 黄色色料组分、 红色 色料组分及蓝色色料组分。 该黄色色料组分是选自于颜料黄 147 (pigment yellow 147)、 颜料黄 181、 颜料黄 183、 染料棕 53 (solvent brown 53)或其组合。该红色色料组分是选自于颜料红 122 (pigment red 122) , 颜料红 144、 颜料红 202、 颜料红 214 或其组合。 该蓝色色料 组分是选自于颜料蓝 60 (pigment blue 60)、染料蓝 67 (solvent blue 67) 或其组合。 上述色料是依据颜色索引（color mdex)通用名称表示。
本揭露内容的第二目的在于提供一种胶粒， 是将如上所述的色母 组成物在以热塑性聚酯为主的基材中进行展色 (coloring)而得。
本揭露内容的第三目的在于提供一种纤维， 是将如上所述的胶粒 进行抽丝而得。
本揭露内容的第四目的在于提供一种塑料， 是将如上所述的胶粒 进行模制（molding)而得。 具体实施方式
本发明的上述以及其它目的、 特征与优点， 在参照以下的详细说 明与较佳实施例后， 将变得明显。
除非另外有所定义， 在本文中所使用的所有技术性与科学术语具 有本领域技术人员所共同了解的意义。 熟悉本技艺者会认知到许多与 那些被描述于本文中者相似或等效的方法和材料， 它们可被用于实施 本发明。 当然， 本发明决不受到所描述的方法和材料的限制。
本揭露內容提供一種色母组成物， 包含热塑性聚酯、 黄色色料组 分、 红色色料组分及蓝色色料组分。 该黄色色料组分是选自于颜料黄 147、 颜料黄 181、 颜料黄 183、 染料棕 53或其组合。 该红色色料组 分是选自于颜料红 122、 颜料红 144、 颜料红 202、 颜料红 214或其组 合。 该蓝色色料组分是选自于颜料蓝 60、 染料蓝 67或其组合。 上述 色料是依据颜色索引通用名称表示。
在某些具體例中， 该色母组成物还可包含二氧化钛。 以该色母组 成物的总重为 100 wt% , 该二氧化钛的含量范围可为大于 0 wt%至 5 wt%。
適用於本揭露內容的热塑性聚酯的實例， 包括， 但不限於： 聚对 苯二甲酸乙二酯 (PET：)、 聚对苯二甲酸丁二酯 (PBT：)、 经官能基化的聚 对苯二甲酸乙二酯衍生物（functionalized derivatives of PET)、 经官能 基化的聚对苯二甲酸丁二酯衍生物（functionalized derivatives of PB T)、 其等的共聚物（copolymers)或其等的掺混物（blends)。
依據本揭露內容， 以该色母组成物的总重为 100 wt%， 该红色色 料组分的含量范围可为 8 wt%至 15 wt%。 以该色母组成物的总重为 100 wt% , 该黄色色料组分的含量范围为 7 wt%至 15 wt%。 以该色母 组成物的总重为 100 wt%， 该蓝色色料组分的含量范围为 5 wt%至 15 wt%。 在某些具體例中， 以该色母组成物的总重为 100 wt%， 该黄色色 料组分是含量范围为 7 wt%至 10 wt%的染料棕 53。
在某些具體例中，该蓝色色料是含量范围为 5 wt%至 10 wt%的染 料蓝 67。
依據本揭露內容， 该色母组成物还可包含现有的添加剂， 例如紫 外线吸收剂、 抗氧化剂、 阻燃剂或其组合。
此外， 本揭露內容提供一种胶粒， 該胶粒是将如上所述的色母组 成物在一以热塑性聚酯为主的基材中進行展色而得。 本揭露內容亦提 供一種製備膠粒的方法， 包括将如上所述的色母组成物在一以热塑性 聚酯为主的基材中進行展色。在某些具體例中，以该胶粒的总重为 100 wt% , 该色母组成物的含量范围为 1 wt%至 10 wt%。
依据本揭露内容， 该基材中的热塑性聚酯可以与上述色母组成物 中的热塑性聚酯相同或不同。
再者， 本案申请人发现到， 由上述胶粒所制得的加工制品 （如纤 维或塑料） ， 具有减缓并降低吸热的效果且在必要的加工过程中仍可 维持其原有的颜色， 而有利于应用于纺织物或工程塑料， 特别是深色 纺织物或工程塑料。
因此， 本揭露內容提供一种纤维， 該纖維是将如上所述的胶粒進 行抽丝而得。 本揭露內容也提供一種製備纤维的方法， 包括将如上所 述的胶粒進行抽丝。上述抽絲可依據此技術領域中所慣用之操作條件 來進行， 例如 285-300 °C。
此外， 本揭露內容还提供一种塑料， 該塑料是将如上所述的胶粒 進行模制 (moldmg)而得。 本揭露內容也提供一種製備塑料的方法， 包 括将如上所述的胶粒進行模制 。依據本揭露內容， 塑料的實例包括， 但不限於， 胶片以及塑料薄膜。
如此处所用的， 术语 "模制 "意指使用模具（mold)或铸模 (matrix) 将原料 (raw material)成形之制备方法。 适用于本揭露内容的模制方法 的实例包括， 但不限于， 射出模制（injection molding) , 挤出模制 (extrusion molding)、 压缩模制 (compression molding)、 方定转模制 (rotational molding)及其类似方法。该模制可依据此技术领域中所惯用 之操作条件来进行， 例如 285 °C至 300 °C。 本揭露內容将就以下实施例来作进一歩说明， 但应了解的是， 所 述实施例仅为例示说明用， 而不应被解释为本揭露內容实施的限制。 <实施例 >
[实施例 A1-A32] 色母组成物
依据下表 1 的含量比例将色料加入粉碎后的热塑性聚酯粒中混 合， 再于 240-280 °C中以双螺杆挤压机进行挤压混炼， 以制得实施例 A1 -A32的色母组成物。 表 1
Figure imgf000005_0001
颜料黄 183 颜料红 122 颜料蓝 60 PET
Al l
(15 wt%) (10 wt%) (15 wt%) (60 wt%) 颜料黄 183 颜料红 202 颜料蓝 60 PET
A12
(15 wt%) (10 wt%) (15 wt%) (60 wt%) 颜料黄 183 颜料红 144 染料蓝 67 PET
A13
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 214 染料蓝 67 PET
A14
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 122 染料蓝 67 PET
A15
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 202 染料蓝 67 PET
A16
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 染料棕 53 颜料红 144 颜料蓝 60 PET
A17
(10 wt%) (10 wt%) (15 wt%) (65 wt%) 染料棕 53 颜料红 214 颜料蓝 60 PET
A18
(10 wt%) (10 wt%) (15 wt%) (65 wt%) 染料棕 53 颜料红 122 颜料蓝 60 PET
A19
(10 wt%) (10 wt%) (15 wt%) (65 wt%) 染料棕 53 颜料红 202 颜料蓝 60 PET
A20
(10 wt%) (10 wt%) (15 wt%) (65 wt%) 染料棕 53 颜料红 144 染料蓝 67 PET
A21
(8 wt%) (15 wt%) (8 wt%) (69 wt%) 染料棕 53 颜料红 214 染料蓝 67 PET
A22
(8 wt%) (15 wt%) (8 wt%) (69 wt%) 染料棕 53 颜料红 122 染料蓝 67 PET
A23
(8 wt%) (15 wt%) (8 wt%) (69 wt%) 染料棕 53 颜料红 202 染料蓝 67 PET
A24
(8 wt%) (15 wt%) (8 wt%) (69 wt%) 颜料黄 181 颜料红 144 颜料蓝 60 PET
A25
(15 wt%) (10 wt%) (15wt%) (60 wt%)
A26 颜料黄 181 颜料红 214 颜料蓝 60 PET (15 wt%) (10 wt%) (15 wt%) (60 wt%) 颜料黄 181 颜料红 122 颜料蓝 60 PET
A27
(15 wt%) (10 wt%) (15 wt%) (60 wt%) 颜料黄 181 颜料红 202 颜料蓝 60 PET
A28
(15wt%) (10 wt%) (15 wt%) (60 wt%) 颜料黄 181 颜料红 144 染料蓝 67 PET
A29
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 颜料黄 181 颜料红 214 染料蓝 67 PET
A30
(15wt%) (10wt%) (5wt%) (70wt%) 颜料黄 181 颜料红 122 染料蓝 67 PET
A31
(15 wt%) (10 wt%) (5 wt%) (70 wt%) 颜料黄 181 颜料红 202 染料蓝 67 PET
A32
(15 wt%) (10 wt%) (5 wt%) (70 wt%)
[实施例 B1-B32] 色母组成物
依据下表 2的含量比例将色料加入粉碎后的热塑性聚酯粒中混合 (共 95 wt%) , 并添加 5 wt%二氧化钛， 再于 240-280 °C中以双螺杆挤 压机进行挤压混炼， 以制得实施例 B 1 -B32的色母组成物。 表 2
黄色色料 红色色料 蓝色色料 热塑性聚酯 (含量 wt %) (含量 wt %) (含量 wt %) (含量 wt %) 颜料黄 147 颜料红 144 颜料蓝 60 PET
B 1
(11 wt%) (9 wt%) (12 wt%) (63 wt%) 颜料黄 147 颜料红 214 颜料蓝 60 PET
B2
(11 wt%) (9 wt%) (12 wt%) (63 wt%) 颜料黄 147 颜料红 122 颜料蓝 60 PET
B3
(11 wt%) (9 wt%) (12 wt%) (63 wt%) 颜料黄 147 颜料红 202 颜料蓝 60 PET
B4
(11 wt%) (9 wt%) (12 wt%) (63 wt%) 颜料黄 147 颜料红 144 染料蓝 67 PET
B5
(9 wt%) (12 wt%) (9 wt%) (65 wt%) 颜料黄 147 颜料红 214 染料蓝 67 PET
B6
(9 wt%) (12 wt%) (9 wt%) (65 wt%) 颜料黄 147 颜料红 122 染料蓝 67 PET
B7
(9 wt%) (12 wt%) (9 wt%) (65 wt%) 颜料黄 147 颜料红 202 染料蓝 67 PET
B8
(9 wt%) (12 wt%) (9 wt%) (65 wt%) 颜料黄 183 颜料红 144 颜料蓝 60 PET
B9
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 183 颜料红 214 颜料蓝 60 PET
B I O
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 183 颜料红 122 颜料蓝 60 PET
B l l
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 183 颜料红 202 颜料蓝 60 PET
B 12
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 183 颜料红 144 染料蓝 67 PET
B 13
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 214 染料蓝 67 PET
B 14
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 122 染料蓝 67 PET
B 15
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 183 颜料红 202 染料蓝 67 PET
B 16
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 染料棕 53 颜料红 144 颜料蓝 60 PET
B 17
(9 wt%) (9 wt%) (12 wt%) (65 wt%) 染料棕 53 颜料红 214 颜料蓝 60 PET
B 18
(9 wt%) (9 wt%) (12wt%) (65wt%) 染料棕 53 颜料红 122 颜料蓝 60 PET
B 19
(9 wt%) (9 wt%) (12 wt%) (65 wt%) 染料棕 53 颜料红 202 颜料蓝 60 PET
B20
(9 wt%) (9 wt%) (12 wt%) (65 wt%)
B21 染料棕 53 颜料红 144 染料蓝 67 PET (7 wt%) (12 wt%) (7 wt%) (69 wt%) 染料棕 53 颜料红 214 染料蓝 67 PET
B22
(7 wt%) (12 wt%) (7 wt%) (69 wt%) 染料棕 53 颜料红 122 染料蓝 67 PET
B23
(7 wt%) (12 wt%) (7 wt%) (69 wt%) 染料棕 53 颜料红 202 染料蓝 67 PET
B24
(7wt%) (12 wt%) (7 wt%) (69 wt%) 颜料黄 181 颜料红 144 颜料蓝 60 PET
B25
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 181 颜料红 214 颜料蓝 60 PET
B26
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 181 颜料红 122 颜料蓝 60 PET
B27
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 181 颜料红 202 颜料蓝 60 PET
B28
(13 wt%) (9 wt%) (13 wt%) (60 wt%) 颜料黄 181 颜料红 144 颜料蓝 67 PET
B29
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 181 颜料红 214 颜料蓝 67 PET
B30
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 181 颜料红 122 颜料蓝 67 PET
B31
(12 wt%) (8 wt%) (5 wt%) (70 wt%) 颜料黄 181 颜料红 202 颜料蓝 67 PET
B32
(12 wt%) (8 wt%) (5 wt%) (70 wt%)
[实施例 Cl-C32、 D1-D32] 色母组成物
实施例 C1 -C32及 D1 -D32的歩骤分别与实施例 A1 -A32及 B 1-B32 相似， 差异处在于以 PBT 取代 PET , 以分别制得实施例 C1 -C32 及 D1 -D32的色母组成物。
<比较例 >
[比较例 CB、 Z1-Z4] 色母组成物
将碳黑 P 0 wt%：)加入粉碎后的热塑性聚酯粒 (：70 wt%：)中混合， 再于 240-280°C中以双螺杆挤压机进行挤压混炼， 以制得比较例 CB的色母 组成物。 另外， 依据下表 3的含量比例将色料加入粉碎后的热塑性聚 酯粒中混合， 再于 240-280°C中以双螺杆挤压机进行挤压混炼， 以制 得比较例 Z1-Z4的色母组成物。 表 3
Figure imgf000010_0001
<应用例 >
[应用例 1】 PET胶粒
将上述实施例 Al-A32、 Bl-B32、 C1-C32及 D1-D32的色母组成 物切粒后， 加入 PET中展色（色母组成物占总重的 6 wt%：)， 以制得应 用例 1 的 PET胶粒 PETA1-A32、 PETB1-B32、 PETC1-C32及 PETD1-D32。
[应用例 2】纤维
将上述应用例 1 的 PET胶粒 PETA1.A32、 PETB1.B32、 PETC1.C32及 PETD1-D32在 285-300°C中抽丝，以制得应用例 2的纤维 FA1-A32、FB1-B32、 Fci-C32及 FD1-D32 (纤维细度为 3 DPF)。 其中， 纤维 F A1-A32及 FB1-B32为 黑色， 纤维？ 1.„2及 FD1.D32为深灰色， 可适用于深色纺织物。
[应用例 3】胶片
将上述应用例 1 的 PET胶粒 PETA1.A32、 PETB1.B32、 PETC1.C32及 PETD1-D32在 285-300°C中射出，以制得应用例 3的胶片 SA1-A32、 SB1-B32、
Sci-C32及 SD1-D32。 其中， 胶片 S A1-A32及 s B1-B32为黑色， 胶片 S C1-C32 及 sD1.D32为深灰色， 可适用于深色工程塑料。 <比较应用例〉
[比较应用例 1】 PET胶粒
将上述比较例 CB與 Z1 -Z4的色母组成物切粒后加入 PET中展色 (：色母组成物占总重的 5.5 wt%) , 得到比较应用例 1 的碳黑 PET胶粒 PETCB以及黑色 PET胶粒 PETZ 1.Z4。
[比较应用例 2】 纤维
将上述比较应用例 1的碳黑 PET胶粒 PETCB及比较应用例 2的黑 色 PET胶粒？£121.24在 285 -300 °C中抽丝， 以分别制得比较应用例 3 的纤维？ 13及 FZ 1.Z4。 其中， 纤维 FZ 1.Z4皆褪色变浅呈偏棕色， 而无法 直接应用于深色纺织物。
<测试例 >
红外线升温测试
在 23 °C下， 以红外线灯（Philips PA 38 I Red 150W 125- 130V , 波长范围 600- 1400 nm)与 PET胶粒距离 17厘米照射 55分钟，并以红 外线温度计每隔 5分钟分别量测上述比较应用例 1的 PETCB与应用例 1 的 PET胶粒温度， 其结果如下表 4所示。 表 4
PET 照射时间（分钟）
胶粒 5 10 15 20 25 30 35 40 45 50 55 胶粒温度（°c )
CB 68 >100 >100 >100 >100 >100 >100 >100 >100 >100 >100
Al 62 66 68 71 72 72 72 72 72 72 72
A2 60 65 67 69 70 71 71 71 71 71 71
A3 60 66 68 71 72 72 72 72 72 72 72
A4 61 65 66 69 70 71 71 71 71 71 71
A5 60 65 67 67 69 71 71 71 71 71 71
A6 61 65 66 69 69 70 70 70 70 70 70
A7 60 65 67 67 69 70 70 70 70 70 70
A8 61 65 66 69 70 71 71 71 71 71 71
A9 60 66 68 71 72 72 72 72 72 72 72 A10 61 65 66 69 70 71 71 71 71 71 71
Al l 62 66 68 70 71 71 71 71 71 71 71
A12 60 65 67 69 70 71 71 71 71 71 71
A13 61 66 68 71 72 72 72 72 72 72 72
A14 60 65 68 71 72 72 72 72 72 72 72
A15 61 67 69 70 71 71 71 71 71 71 71
A16 61 65 66 69 70 70 70 70 70 70 70
A17 60 65 67 70 71 72 72 72 72 72 72
A18 62 66 68 70 72 72 72 72 72 72 72
A19 61 65 66 69 70 71 71 71 71 71 71
A20 60 65 67 69 70 71 71 71 71 71 71
A21 61 65 66 69 70 70 70 70 70 70 70
A22 49 58 62 68 68 69 69 69 69 69 69
A23 54 61 63 64 66 68 68 68 68 68 68
A24 61 65 66 69 69 70 70 70 70 70 70
A25 61 66 69 71 72 72 72 72 72 72 72
A26 60 67 69 70 71 72 72 72 72 72 72
A27 62 66 68 70 72 74 74 74 74 74 74
A28 61 67 69 72 73 74 74 74 74 74 74
A29 60 66 68 70 72 73 73 73 73 73 73
A30 61 66 68 70 72 73 73 73 73 73 73
A31 62 66 68 71 73 74 74 74 74 74 74
A32 61 66 69 71 72 73 73 73 73 73 73 表 4的红外线升温测试结果显示， 使用本揭露內容的色母组成物 所制得的 PET 胶粒 PETA 1.A32， 其吸收红外线 10 分钟后的温度皆在 67 °C以下， 其吸收红外线 55分钟后的温度皆维持在 74 °C以下； 而使 用碳黑所制得的碳黑 PET胶粒 PETCB， 其吸收红外线 10分钟后的温 度已高于 100 °C， 说明其升温速率较快且升温幅度较大。 此外， PET 胶粒 PETB 1.B32、 ？£1 ^.„2及 PETD 1.D32的升温测试结果皆分别与 PET 胶粒 PETA 1.A32 的升温测试结果相似。 上述实验结果表示本揭露内容 的色母组成物可减缓并降低因吸收红外线而造成的升温效果。
综上所述， 本揭露内容的色母组成物无需另外添加其他散热物质 或进行改性即可减缓并降低因吸收红外线而造成的升温效果， 且在制 备纤维或塑料的加工过程中仍可维持其原有的颜色， 因而适用于制备 深色纺织物或工程塑料， 所以确实能达成本发明的目的。
以上所述， 仅为本发明的实施例而已， 当不能以此限定本发明实 施的范围， 即凡依本发明权利要求书及说明书内容所作的简单的等效 变化与修饰， 皆仍属本发明的范围。

Claims

权 利 要 求
1 . 一种色母组成物， 其特征在于其包含：
热塑性聚酯；
黄色色料组分，选自于由颜料黄 147、颜料黄 181、颜料黄 183 、 染料棕 53及其等的组合所构成的群组；
红色色料组分，选自于由颜料红 122、颜料红 144、颜料红 202 、 颜料红 214及其等的组合所构成的群组； 及
蓝色色料组分， 选自于由颜料蓝 60、 染料蓝 67及其组合所构 成的群组， 上述色料是依据颜色索引通用名称表示。
2. 根据权利要求 1所述的色母组成物， 其特征在于其还包含二 氧化钛， 以该色母组成物的总重为 100 wt% , 该二氧化钛的含量范围 为大于 0 wt%至 5 wt%。
3. 根据权利要求 1所述的色母组成物， 其特征在于： 该热塑性 聚酯是选自于由聚对苯二甲酸乙二酯、 聚对苯二甲酸丁二酯、 经官能 基化的聚对苯二甲酸乙二酯衍生物、 经官能基化的聚对苯二甲酸丁二 酯衍生物、 其等的共聚物及其等的掺混物所构成的群组。
4. 根据权利要求 1所述的色母组成物， 其特征在于： 以该色母 组成物的总重为 100 wt% , 该黄色色料组分的含量范围为 7 wt%至 15 wt% , 该红色色料组分的含量范围为 8 wt%至 15 wt% , 该蓝色色料组 分的含量范围为 5 wt%至 15 wt%。
5. 根据权利要求 4所述的色母组成物， 其特征在于： 以该色母 组成物的总重为 100 wt% , 该黄色色料组分是含量范围为 7 wt%至 10 wt%的染料棕 53。
6. 根据权利要求 4所述的色母组成物， 其特征在于： 以该色母 组成物的总重为 100 wt% ,该蓝色色料是含量范围为 5 wt%至 10 wt%的 染料蓝 67。
7. 一种胶粒， 其特征在于其是将根据权利要求 1所述的色母组 成物在以热塑性聚酯为主的基材中进行展色而得。
8. 根据权利要求 7所述的用于深色纺织物或工程塑料的胶粒， 其特征在于： 以该胶粒的总重为 100 wt% , 该色母组成物的含量范围 为 1 wt%至 10 wt%。
9. 一种纤维， 其特征在于其是将根据权利要求 7所述的胶粒进 行抽丝而得。
10. 一种塑料， 其特征在于其是将根据权利要求 7所述的胶粒进 行模制而得。
PCT/IB2018/050864 2017-02-21 2018-02-13 用于深色纺织物或工程塑料的色母组成物及其制品 WO2018154409A1 (zh)

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