WO2017166835A1 - 一种非氢化代可可脂巧克力及其制备方法 - Google Patents
一种非氢化代可可脂巧克力及其制备方法 Download PDFInfo
- Publication number
- WO2017166835A1 WO2017166835A1 PCT/CN2016/107570 CN2016107570W WO2017166835A1 WO 2017166835 A1 WO2017166835 A1 WO 2017166835A1 CN 2016107570 W CN2016107570 W CN 2016107570W WO 2017166835 A1 WO2017166835 A1 WO 2017166835A1
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- WO
- WIPO (PCT)
- Prior art keywords
- chocolate
- hydrogenated
- cocoa butter
- powder
- vegetable oil
- Prior art date
Links
- 244000299461 Theobroma cacao Species 0.000 title claims abstract description 73
- 235000019219 chocolate Nutrition 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 235000019875 cocoa butter alternative Nutrition 0.000 title abstract 3
- 239000000843 powder Substances 0.000 claims abstract description 52
- 239000008172 hydrogenated vegetable oil Substances 0.000 claims abstract description 30
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229930006000 Sucrose Natural products 0.000 claims abstract description 25
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims abstract description 14
- 239000005913 Maltodextrin Substances 0.000 claims abstract description 13
- 229920002774 Maltodextrin Polymers 0.000 claims abstract description 13
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 13
- 235000009470 Theobroma cacao Nutrition 0.000 claims abstract description 13
- 235000013305 food Nutrition 0.000 claims abstract description 13
- 229940035034 maltodextrin Drugs 0.000 claims abstract description 13
- 239000005720 sucrose Substances 0.000 claims abstract description 13
- -1 sucrose fatty acid ester Chemical class 0.000 claims abstract description 13
- 235000019868 cocoa butter Nutrition 0.000 claims description 26
- 229940110456 cocoa butter Drugs 0.000 claims description 26
- 239000000796 flavoring agent Substances 0.000 claims description 22
- 235000019634 flavors Nutrition 0.000 claims description 22
- 239000003921 oil Substances 0.000 claims description 19
- 235000019198 oils Nutrition 0.000 claims description 19
- 229920000223 polyglycerol Polymers 0.000 claims description 14
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims description 14
- 229940066675 ricinoleate Drugs 0.000 claims description 14
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000008347 soybean phospholipid Substances 0.000 claims description 13
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 12
- 229940001941 soy protein Drugs 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 10
- 235000019864 coconut oil Nutrition 0.000 claims description 9
- 239000003240 coconut oil Substances 0.000 claims description 9
- 235000013336 milk Nutrition 0.000 claims description 9
- 239000008267 milk Substances 0.000 claims description 9
- 210000004080 milk Anatomy 0.000 claims description 9
- 239000005862 Whey Substances 0.000 claims description 7
- 102000007544 Whey Proteins Human genes 0.000 claims description 7
- 108010046377 Whey Proteins Proteins 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 235000020183 skimmed milk Nutrition 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- 235000014593 oils and fats Nutrition 0.000 claims description 6
- 239000004519 grease Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000003346 palm kernel oil Substances 0.000 claims description 4
- 235000019865 palm kernel oil Nutrition 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims 2
- 239000003925 fat Substances 0.000 abstract description 6
- 235000019197 fats Nutrition 0.000 abstract description 6
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 235000008935 nutritious Nutrition 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract 2
- 206010013911 Dysgeusia Diseases 0.000 abstract 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 abstract 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 abstract 1
- 235000021552 granulated sugar Nutrition 0.000 abstract 1
- 239000003996 polyglycerol polyricinoleate Substances 0.000 abstract 1
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 abstract 1
- 235000008476 powdered milk Nutrition 0.000 abstract 1
- 229940083466 soybean lecithin Drugs 0.000 abstract 1
- 235000019710 soybean protein Nutrition 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 230000036541 health Effects 0.000 description 6
- 235000019866 hydrogenated palm kernel oil Nutrition 0.000 description 5
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 5
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 5
- 235000012141 vanillin Nutrition 0.000 description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 description 5
- 239000008158 vegetable oil Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000010692 trans-unsaturated fatty acids Nutrition 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 235000016709 nutrition Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 235000001497 healthy food Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
- A23G1/38—Cocoa butter substitutes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/0003—Processes of manufacture not relating to composition or compounding ingredients
- A23G1/0006—Processes specially adapted for manufacture or treatment of cocoa or cocoa products
- A23G1/0009—Manufacture or treatment of liquid, cream, paste, granule, shred or powder
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/0003—Processes of manufacture not relating to composition or compounding ingredients
- A23G1/0026—Mixing; Roller milling for preparing chocolate
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/40—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/44—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing peptides or proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/46—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing dairy products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/48—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/08—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing cocoa fat if specifically mentioned or containing products of cocoa fat or containing other fats, e.g. fatty acid, fatty alcohol, their esters, lecithin, paraffins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/10—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing amino-acids, proteins, e.g. gelatine, peptides, polypeptides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/12—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing dairy products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/40—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the fats used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/42—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- the present invention relates to a chocolate and a method of producing the same, and in particular to a non-hydrogenated cocoa butter chocolate and a method of producing the same.
- Hydrogenated vegetable oil is an artificial oil, including well-known creamers, creamers, margarines, cocoa butter, and the like. It is a hydrogenation of common vegetable oil under certain temperature and pressure.
- the hydrogenated vegetable oil system is uniform, has no odor, has increased hardness and high melting point, so it can maintain the shape of solid at room temperature, and the plasticity, fusion and emulsifying properties are enhanced, which can make the food more crisp.
- it is also able to extend the shelf life of the product, so it is widely used in food processing.
- some of the hydrogenated vegetable oils that have not been fully hydrogenated have a chemical structure that is trans-bonded to become a trans-fatty acid. It does not have the nutrients of pure natural vegetable oils and is not conducive to human health.
- hydrogenated oils also contain some metal catalysts, which have an impact on human health, which severely limits their safety in food processing.
- Non-hydrogenated fats and oils are oils which are extracted from pure natural plants without hydrogenation reaction. Since they are not subjected to hydrogenation reaction, they do not contain trans fatty acids and are beneficial to human health.
- the non-hydrogenated vegetable oil contains more than 16% of the unsaturated fatty acids beneficial to the human body relative to the hydrogenated vegetable oil. From a nutritional point of view, it is nutritious and contains no cholesterol and trans fatty acids, and has a high content of unsaturated fatty acids.
- non-hydrogenated vegetable oil can participate in human metabolism normally, has high nutritional value and is beneficial to human health, it has become a general trend for people to pursue healthy food, and is an ideal edible oil.
- the present invention is mainly for solving the above problems of non-hydrogenated fats and oils, and the above disadvantages of non-hydrogenated oils and fats in use are improved by the use of emulsifiers and stabilizers, the formulation of different non-hydrogenated fats and oils, and the improvement of the process, thereby improving the emulsification thereof.
- the characteristics of uniformity, stability, handling and mouthfeel are made into non-hydrogenated cocoa butter chocolate to improve the nutritional value and health characteristics of the product.
- the object of the present invention is to provide a non-hydrogenated cocoa butter chocolate and a preparation method thereof, which use non-hydrogenated vegetable oil instead of hydrogenated vegetable oil in the raw material to avoid harm to human body caused by saturated fatty acid and trans fatty acid in hydrogenated vegetable oil, and overcome non-hydrogenated vegetable oil
- the drawbacks of producing chocolate make the product performance and quality equal and exceed the products made with hydrogenated oil.
- the present invention provides a chocolate produced using non-hydrogenated cocoa butter, which is composed of the following percentages of raw materials:
- Non-hydrogenated vegetable oil 35-50%
- Cocoa powder 6-30%
- Soy protein 2-8%
- Glyceryl monostearate 1-5%
- Soybean phospholipid 0.2-0.5%
- the non-hydrogenated vegetable oil is refined palm kernel oil and coconut oil in a weight ratio of 25-28:10-12.
- the milk powder is skimmed milk powder and whey powder.
- the present invention also provides a preparation method of non-hydrogenated cocoa butter chocolate, and the non-hydrogenated chocolate prepared by the method has good flavor and operability, and mainly comprises the following steps:
- the white sugar is pulverized into a powdered sugar using a powder sugar machine.
- Non-hydrogenated vegetable oil, sucrose fatty acid ester, and glyceryl monostearate are all put together in a melting oil pot to be melted to obtain an oil phase, which is kept at 70-90 ° C for use.
- the non-hydrogenated vegetable oil is prepared by blending two non-hydrogenated fats of palm kernel oil and coconut oil, and solves the problem of low melting point of using a single non-hydrogenated vegetable oil.
- step 3 during the fine grinding process, the mixture is grounded three times for fine grinding, the grinding time is 8-10 hours, and the heating temperature is 50-75 ° C until the chocolate slurry is refined to 15-30 microns. Mill Songge. Then add soybean phospholipid, polyglycerol ricinoleate, and mix the flavorant for half an hour, then transfer it to the chocolate holding tank and fill it.
- the present invention has the following advantages:
- the non-hydrogenated cocoa butter chocolate of the present invention does not contain hydrogenated vegetable oil and does not contain trans fatty acids, and can satisfy the needs of people in today's society for healthy and nutritious foods.
- non-hydrogenated cocoa butter chocolate formula non-hydrogenated palm kernel oil 28kg, non-hydrogenated coconut oil 10kg, white sugar 32kg, cocoa powder 8kg, skim milk powder 10kg, whey powder 2.5kg, maltodextrin 4.85kg, soy protein Powder 1.8kg, glyceryl monostearate 2kg, soybean phospholipid 0.4kg, polyglycerol ricinoleate 0.2kg, sucrose fatty acid ester 0.2kg, food flavor vanillin 0.05kg.
- the white sugar is pulverized into a powdered sugar using a powder sugar machine.
- Non-hydrogenated vegetable oil, sucrose fatty acid ester, and glyceryl monostearate are all put together in a melting oil pot to be melted to obtain an oil phase, which is kept at 70-90 ° C for use.
- the finished product warehouse temperature should be maintained at 18-25 degrees, relative humidity ⁇ 60%.
- the chocolate obtained by the above method has a trans fatty acid content of 0, and its texture is no longer soft, and the workability is good, the taste of the vegetable oil is not good, and the flavor is good. This was compared with hydrogenated cocoa butter chocolate, and the specific results are shown in Table 1.
- non-hydrogenated cocoa butter chocolate formula non-hydrogenated palm kernel oil 25kg, non-hydrogenated coconut oil 12kg, white sugar 35kg, cocoa powder 7kg, skim milk powder 8kg, whey powder 4kg, maltodextrin 3.5kg, soy protein powder 2kg, 2.5kg of glyceryl monostearate, 0.5kg of soybean phospholipid, 0.2kg of polyglycerol ricinoleate, 0.2kg of sucrose fatty acid ester, 0.1kg of edible flavor vanillin.
- the white sugar is pulverized into a powdered sugar using a powder sugar machine.
- Non-hydrogenated vegetable oil, sucrose fatty acid ester, and glyceryl monostearate are all put together in a melting oil pot to be melted to obtain an oil phase, which is kept at 70-90 ° C for use.
- the finished product warehouse temperature should be maintained at 18-25 degrees, relative humidity ⁇ 60%.
- the chocolate obtained by the above method has a trans fatty acid content of 0, and its texture is no longer soft, and the workability is good, the taste of the vegetable oil is not good, and the flavor is good. This was compared with hydrogenated cocoa butter chocolate, and the specific results are shown in Table 2.
- non-hydrogenated cocoa butter chocolate formula non-hydrogenated palm kernel oil 28kg, non-hydrogenated coconut oil 12kg, white sugar 30kg, cocoa powder 9kg, skim milk powder 7kg, whey powder 3kg, maltodextrin 5kg, soy protein powder 2.6 Kg, 2.5 kg of glyceryl monostearate, 0.45 kg of soybean phospholipid, 0.2 kg of polyglycerol ricinoleate, 0.2 kg of sucrose fatty acid ester, and 0.05 kg of edible flavor vanillin.
- the white sugar is pulverized into a powdered sugar using a powder sugar machine.
- Non-hydrogenated vegetable oil, sucrose fatty acid ester, and glyceryl monostearate are all put together in a melting oil pot to be melted to obtain an oil phase, which is kept at 70-90 ° C for use.
- the finished product warehouse temperature should be maintained at 18-25 degrees, relative humidity ⁇ 60%.
- the chocolate obtained by the above method has a trans fatty acid content of 0, and its texture is no longer soft, and the workability is good, the taste of the vegetable oil is not good, and the flavor is good. This was compared with hydrogenated cocoa butter chocolate, and the specific results are shown in Table 3.
- the comparative examples mainly investigated the effects of the synergistic use of emulsifiers on the properties of chocolate products such as stability, handling and hardness.
- non-hydrogenated palm kernel oil 28kg non-hydrogenated coconut oil 12kg, white sugar 30kg, cocoa powder 9kg, skim milk powder 7kg, whey powder 3kg, maltodextrin 5kg, soy protein powder 2.6kg, glyceryl monostearate 0kg, soybean phosphatide 0.45kg, polyglycerol ricinoleate 0.2kg, sucrose fatty acid ester 0.2kg, food flavor vanillin 0.05kg.
- non-hydrogenated palm kernel oil 28kg non-hydrogenated coconut oil 12kg, white sugar 30kg, cocoa powder 9kg, skim milk powder 7kg, whey powder 3kg, maltodextrin 5kg, soy protein powder 2.6kg, glyceryl monostearate 2.5kg, soybean phospholipid 0.45kg, polyglycerol ricinoleate 0.2kg, sucrose 0kg of fatty acid ester, 0.05kg of edible flavor vanillin.
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Abstract
一种非氢化代可可脂巧克力，由下列百分比计的原料组成：非氢化植物油：35-50％；白砂糖：30-50％；可可粉：6-30％；奶粉：5％-40％；麦芽糊精：1-10％；大豆蛋白：2-8％；单硬脂酸甘油酯：1-5％；大豆磷脂：0.2-0.5％；聚甘油蓖麻醇酯：0.1-0.3％；蔗糖脂肪酸酯：0.1-0.3％；食用香精：0.01-0.1％。与现有技术相比，具有如下优点：(1)不含氢化植物油，不含反式脂肪酸，能够满足当今社会人们在健康、营养食品上的需求，(2)使用非氢化植物油为原料制备代可可脂巧克力时，通过乳化剂的协同作用，克服了非氢化植物油生产巧克力过程中质构较软，不易操作，风味口感差的缺点，满足了客户的质量要求。
Description
本发明涉及一种巧克力及其制造方法，具体涉及一种非氢化代可可脂巧克力及其制造方法。
在国内传统的代可可脂巧克力生产中，都是以氢化植物油为主要原料。氢化植物油是一种人工油脂，包括人们熟知的奶精、植脂末、人造奶油、代可可脂等。它是普通植物油在一定的温度和压力下加氢催化而成。经过氢化的植物油体系均一，无杂味，硬度增加，熔点高，故在室温下能保持固体的形状，可塑性、融合性、乳化性都增强，可以使食物更加酥脆。同时，还能够延长产品的保质期，因此被广泛地应用于食品加工中。但是某些未能完全氢化的氢化植物油的化学结构呈反式键连接，成为反式脂肪酸，它不具有纯天然植物油脂的营养，而且不利于人体健康。氢化油加工过程中除了会产生一些反式脂肪酸以外，也会残留一些金属催化剂，这些物质对人体健康有影响，这就严重限制了其在食品加工中应用的安全性。
当今社会，人们对生活品质有更高的追求，对食品安全越来越关注，健康安全成为消费者购买产品的首要标准，所以采用非氢化植物
油代替氢化植物油应用到食品加工中是非常必要的。非氢化油脂是不经过加氢反应从纯天然植物中提取而得的油脂，因为没有经过加氢反应，故不含反式脂肪酸，益于人体健康。相对于氢化植物油来说，非氢化植物油中含有的对人体有益的不饱和脂肪酸达到16％以上。从营养角度看，它营养且不含胆固醇和反式脂肪酸，不饱和脂肪酸含量高。此外，由于非氢化植物油能正常参与人体代谢，营养价值较高，且对人体健康有利，已经成为人们追求健康食品的大趋势，是一种理想的食用油脂。但是非氢化油脂在食品中应用时存在骨架偏软，不易操作，风味口感差的缺点，这严重限制了其在食品加工中的应用。所以本发明主要是为了解决非氢化油脂的上述问题，通过乳化剂和稳定剂的调配使用、不同口感非氢化油脂的调配以及工艺的改进解决非氢化油脂在使用中存在的上述缺点，改善其乳化均一性、稳定性、操作性和口感等应用特性，制成非氢化代可可脂巧克力，提高产品的营养价值和健康特性。
发明内容
本发明目的是提供一种非氢化代可可脂巧克力及其制造方法，其原料中采用非氢化植物油代替氢化植物油，避免氢化植物油中饱和脂肪酸和反式脂肪酸给人体带来危害，并克服非氢化植物油生产巧克力的弊端，使产品性能和质量等同并超越采用氢化油制得的产品。
为了达到上述目的，本发明提供一种采用非氢化代可可脂生产的巧克力，其由下列百分比计的原料组成：
非氢化植物油：35-50％；
白砂糖：30-50％；
可可粉：6-30％；
奶粉：5％-40％；
麦芽糊精：1-10％；
大豆蛋白：2-8％；
单硬脂酸甘油酯：1-5％；
大豆磷脂：0.2-0.5％；
聚甘油蓖麻醇酯：0.1-0.3％；
蔗糖脂肪酸酯：0.1-0.3％；
食用香精：0.01-0.1％。
所述非氢化植物油为精炼棕榈仁油和椰子油，其重量比例为：25-28:10-12。
所述奶粉为脱脂奶粉和乳清粉。
此外，本发明还提供一种非氢化代可可脂巧克力的制备方法，通过该方法制得的非氢化巧克力有良好的风味口感和操作性，主要包括如下步骤：
1)将白砂糖用粉糖机粉碎成糖粉。
2)将非氢化植物油、蔗糖脂肪酸酯、单硬脂酸甘油酯一起投入融油锅中全部融化，制得油相，并保持在70-90℃备用。
3)将糖粉、可可粉、奶粉、大豆蛋白粉、麦芽糊精、部分油脂混合后输送至二辊碾磨机结合五辊碾磨机，碾磨至15-30微米，然后
将碾磨好的混合料输送至具有剪切搅拌功能的混合缸中，加入剩余油脂，剪切，搅拌，直至形成均匀的巧克力浆料，最后加入大豆磷脂，聚甘油蓖麻醇酯，食用香料。
4)将精磨好的物料输送至巧克力保温缸，然后采用浇注机，或者人工浇注，进入冷道冷却，冷道温度3-10℃，冷却成型之后，包装，检验，入库。
本发明中非氢化植物油是由精炼棕榈仁油和椰子油两种非氢化油脂调配而成的，解决了使用单种非氢化植物油熔点低的问题。
步骤3)中，混合物在精磨过程中，累计三次紧格精磨，精磨时间8-10小时，加热温度为50-75℃，直至巧克力浆料精磨至15-30微米时，给精磨机松格。然后再加入大豆磷脂，聚甘油蓖麻醇酯，食用香料混合半小时后输送至巧克力保温缸，灌装。
与现有技术相比，本发明具有如下优点：
(1)本发明的非氢化代可可脂巧克力不含氢化植物油，不含反式脂肪酸，能够满足当今社会人们在健康、营养食品上的需求。
(2)本发明在使用非氢化植物油为原料制备代可可脂巧克力时，通过乳化剂的协同作用，克服了非氢化植物油生产巧克力过程中质构较软，不易操作，风味口感差的缺点，满足了客户的质量要求。
下面结合具体实施例进一步阐述本发明的技术特点。
实施例1：
生产100kg非氢化代可可脂巧克力配方：非氢化精炼棕榈仁油28kg，非氢化椰子油10kg，白砂糖32kg，可可粉8kg，脱脂奶粉10kg，乳清粉2.5kg，麦芽糊精4.85kg，大豆蛋白粉1.8kg，单硬脂酸甘油酯2kg，大豆磷脂0.4kg，聚甘油蓖麻醇酯0.2kg，蔗糖脂肪酸酯0.2kg，食用香精香兰素0.05kg。
制备工艺：
1)将白砂糖用粉糖机粉碎成糖粉。
2)将非氢化植物油、蔗糖脂肪酸酯、单硬脂酸甘油酯一起投入融油锅中全部融化，制得油相，并保持在70-90℃备用。
3)将糖粉、可可粉、奶粉、大豆蛋白粉、麦芽糊精、部分油脂混合后输送至二辊碾磨机结合五辊碾磨机，碾磨至15-30微米，然后将碾磨好的混合料输送至具有剪切搅拌功能的混合缸中，加入剩余油脂，剪切，搅拌，直至形成均匀的巧克力浆料，最后加入大豆磷脂，聚甘油蓖麻醇酯，食用香料。
4)将精磨好的物料输送至巧克力保温缸，然后采用浇注机，或者人工浇注，进入冷道冷却，冷道温度3-10℃，冷却成型之后，包装，检验，入库。
成品仓库温度要保持在18-25度，相对湿度≤60％。
通过上述方法得到的巧克力，经测试，其反式脂肪酸含量为0，且其质构不再偏软，操作性很好，无植物油的味道，风味口感良好。将其与氢化代可可脂巧克力进行对比，具体结果如表1所示。
表1非氢化代可可脂巧克力与氢化代可可脂巧克力对比
| 反式脂肪酸含量 | 操作性 | 硬度 | 风味口感 | |
| 非氢化巧克力 | 0 | 良好 | 适中 | 柔和，纯正 |
| 氢化巧克力 | 0.1-0.3 | 良好 | 质构偏硬 | 柔和 |
实施例2：
生产100kg非氢化代可可脂巧克力配方：非氢化精炼棕榈仁油25kg，非氢化椰子油12kg，白砂糖35kg，可可粉7kg，脱脂奶粉8kg，乳清粉4kg，麦芽糊精3.5kg，大豆蛋白粉2kg，单硬脂酸甘油酯2.5kg，大豆磷脂0.5kg，聚甘油蓖麻醇酯0.2kg，蔗糖脂肪酸酯0.2kg，食用香精香兰素0.1kg。
制备工艺：
1)将白砂糖用粉糖机粉碎成糖粉。
2)将非氢化植物油、蔗糖脂肪酸酯、单硬脂酸甘油酯一起投入融油锅中全部融化，制得油相，并保持在70-90℃备用。
3)将糖粉、可可粉、奶粉、大豆蛋白粉、麦芽糊精、部分油脂混合后输送至二辊碾磨机结合五辊碾磨机，碾磨至15-30微米，然后将碾磨好的混合料输送至具有剪切搅拌功能的混合缸中，加入剩余油脂，剪切，搅拌，直至形成均匀的巧克力浆料，最后加入大豆磷脂，聚甘油蓖麻醇酯，食用香料。
4)将精磨好的物料输送至巧克力保温缸，然后采用浇注机，或者人工浇注，进入冷道冷却，冷道温度3-10℃，冷却成型之后，包装，检验，入库。
成品仓库温度要保持在18-25度，相对湿度≤60％。
通过上述方法得到的巧克力，经测试，其反式脂肪酸含量为0，且其质构不再偏软，操作性很好，无植物油的味道，风味口感良好。将其与氢化代可可脂巧克力进行对比，具体结果如表2所示。
表2非氢化代可可脂巧克力与氢化代可可脂巧克力对比
| 反式脂肪酸含量 | 操作性 | 硬度 | 风味口感 | |
| 非氢化巧克力 | 0 | 良好 | 适中 | 柔和，纯正 |
| 氢化巧克力 | 0.1-0.3 | 良好 | 质构偏硬 | 柔和 |
实施例3：
生产100kg非氢化代可可脂巧克力配方：非氢化精炼棕榈仁油28kg，非氢化椰子油12kg，白砂糖30kg，可可粉9kg，脱脂奶粉7kg，乳清粉3kg，麦芽糊精5kg，大豆蛋白粉2.6kg，单硬脂酸甘油酯2.5kg，大豆磷脂0.45kg，聚甘油蓖麻醇酯0.2kg，蔗糖脂肪酸酯0.2kg，食用香精香兰素0.05kg。
制备工艺：
1)将白砂糖用粉糖机粉碎成糖粉。
2)将非氢化植物油、蔗糖脂肪酸酯、单硬脂酸甘油酯一起投入融油锅中全部融化，制得油相，并保持在70-90℃备用。
3)将糖粉、可可粉、奶粉、大豆蛋白粉、麦芽糊精、部分油脂混合后输送至二辊碾磨机结合五辊碾磨机，碾磨至15-30微米，然后将碾磨好的混合料输送至具有剪切搅拌功能的混合缸中，加入剩余油脂，剪切，搅拌，直至形成均匀的巧克力浆料，最后加入大豆磷脂，聚甘油蓖麻醇酯，食用香料。
4)将精磨好的物料输送至巧克力保温缸，然后采用浇注机，或者人工浇注，进入冷道冷却，冷道温度3-10℃，冷却成型之后，包装，检验，入库。
成品仓库温度要保持在18-25度，相对湿度≤60％。
通过上述方法得到的巧克力，经测试，其反式脂肪酸含量为0，且其质构不再偏软，操作性很好，无植物油的味道，风味口感良好。将其与氢化代可可脂巧克力进行对比，具体结果如表3所示。
表3非氢化代可可脂巧克力与氢化代可可脂巧克力对比
| 反式脂肪酸含量 | 操作性 | 硬度 | 风味口感 | |
| 非氢化巧克力 | 0 | 良好 | 适中 | 柔和，纯正 |
| 氢化巧克力 | 0.1-0.3 | 良好 | 质构偏硬 | 柔和 |
对比例
对比实施例主要是考察乳化剂的协同使用对巧克力产品性能如稳定性、操作性以及硬度等指标的影响。
对比例1：
配方：非氢化精炼棕榈仁油28kg，非氢化椰子油12kg，白砂糖30kg，可可粉9kg，脱脂奶粉7kg，乳清粉3kg，麦芽糊精5kg，大豆蛋白粉2.6kg，单硬脂酸甘油酯0kg，大豆磷脂0.45kg，聚甘油蓖麻醇酯0.2kg，蔗糖脂肪酸酯0.2kg，食用香精香兰素0.05kg。
制备工艺：同实施例1。
对比例2：
配方：非氢化精炼棕榈仁油28kg，非氢化椰子油12kg，白砂糖
30kg，可可粉9kg，脱脂奶粉7kg，乳清粉3kg，麦芽糊精5kg，大豆蛋白粉2.6kg，单硬脂酸甘油酯2.5kg，大豆磷脂0.45kg，聚甘油蓖麻醇酯0.2kg，蔗糖脂肪酸酯0kg，食用香精香兰素0.05kg。
制备工艺：同实施例1。
分别对比由上述三种对比例制得的巧克力产品的稳定性，操作性以及硬度，具体结果如表4所示。
表4对实施例3和对比例1，2制得的巧克力产品性能对比结果
Claims (6)
- 一种采用非氢化代可可脂生产的巧克力，其特征在于：其由以下百分比计的原料组成：非氢化植物油：35-50％；白砂糖：30-50％；可可粉：6-30％；奶粉：5％-40％；麦芽糊精：1-10％；大豆蛋白：2-8％；单硬脂酸甘油酯：1-5％；大豆磷脂：0.2-0.5％；聚甘油蓖麻醇酯：0.1-0.3％；蔗糖脂肪酸酯：0.1-0.3％；食用香精：0.01-0.1％。
- 根据权利要求1所述的一种采用非氢化代可可脂生产的巧克力，其特征在于：所述非氢化植物油为精炼棕榈仁油和椰子油。
- 根据权利要求2所述的一种采用非氢化代可可脂生产的巧克力，其特征在于：所述的精炼棕榈仁油和椰子油，其重量比例为：25-28:10-12。
- 根据权利要求1所述的一种采用非氢化代可可脂生产的巧克力，其特征在于：所述奶粉为脱脂奶粉或乳清粉。
- 权利要求1所述一种非氢化代可可脂巧克力的制备方法，其特征在于：包括如下步骤：1)将白砂糖用粉糖机粉碎成糖粉；2)将非氢化植物油、蔗糖脂肪酸酯、单硬脂酸甘油酯一起投入融油锅中全部融化，制得油相，并保持在70-90℃备用；3)将糖粉、可可粉、奶粉、大豆蛋白粉、麦芽糊精、部分油脂混合后输送至二辊碾磨机结合五辊碾磨机，碾磨至15-30微米，然后将碾磨好的混合料输送至具有剪切搅拌功能的混合缸中，加入剩余油脂，剪切，搅拌，直至形成均匀的巧克力浆料，最后加入大豆磷脂，聚甘油蓖麻醇酯，食用香料；4)将精磨好的物料输送至巧克力保温缸，然后采用浇注机，或者人工浇注，进入冷道冷却，冷道温度3-10℃，冷却成型之后，包装，检验，入库。
- 根据权利要求5所述的制备方法，其特征在于：步骤3)中，混合物在精磨过程中，累计三次紧格精磨，精磨时间8-10小时，加热温度为50-75℃，直至巧克力浆料精磨至15-30微米时，给精磨机松格；然后再加入大豆磷脂，聚甘油蓖麻醇酯，食用香料混合半小时后输送至巧克力保温缸，灌装。
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| CN110140789B (zh) * | 2019-06-03 | 2022-06-03 | 内蒙古田牧实业(集团)股份有限公司 | 一种用于冰淇淋中的软质巧克力的制备方法 |
| CN111758828A (zh) * | 2020-06-10 | 2020-10-13 | 安徽省好朋友食品有限公司 | 一种含有虾青素的功能性巧克力及其制备方法 |
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