WO2017140083A1 - 配向膜厚度均一性的优化方法及液晶显示面板 - Google Patents

配向膜厚度均一性的优化方法及液晶显示面板 Download PDF

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Publication number
WO2017140083A1
WO2017140083A1 PCT/CN2016/089745 CN2016089745W WO2017140083A1 WO 2017140083 A1 WO2017140083 A1 WO 2017140083A1 CN 2016089745 W CN2016089745 W CN 2016089745W WO 2017140083 A1 WO2017140083 A1 WO 2017140083A1
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region
layer
photoresist
passivation layer
ito film
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PCT/CN2016/089745
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English (en)
French (fr)
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豆婷
李强
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深圳市华星光电技术有限公司
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Priority to US15/128,968 priority Critical patent/US20180120601A1/en
Publication of WO2017140083A1 publication Critical patent/WO2017140083A1/zh

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/13378Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
    • G02F1/133788Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
    • GPHYSICS
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    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • GPHYSICS
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    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
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    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
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    • G02F1/1368Active matrix addressed cells in which the switching element is a three-electrode device
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    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/26Phase shift masks [PSM]; PSM blanks; Preparation thereof
    • G03F1/32Attenuating PSM [att-PSM], e.g. halftone PSM or PSM having semi-transparent phase shift portion; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/16Coating processes; Apparatus therefor
    • GPHYSICS
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    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1259Multistep manufacturing methods
    • H01L27/1288Multistep manufacturing methods employing particular masking sequences or specially adapted masks, e.g. half-tone mask
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1259Multistep manufacturing methods
    • H01L27/1296Multistep manufacturing methods adapted to increase the uniformity of device parameters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/133345Insulating layers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/13378Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
    • G02F1/133792Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by etching
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/136231Active matrix addressed cells for reducing the number of lithographic steps
    • G02F1/136236Active matrix addressed cells for reducing the number of lithographic steps using a grey or half tone lithographic process
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/13625Patterning using multi-mask exposure

Definitions

  • the invention relates to the field of liquid crystal display technology, in particular to an optimization method for uniformity of alignment film thickness and a liquid crystal display panel obtained by the optimization method.
  • touch display panels have been widely used in smart electronic products such as smart phones and tablet computers, bringing a more convenient experience for human-computer interaction.
  • the main structure of the liquid crystal display panel includes a color filter substrate (CF), a thin film transistor array substrate (TFT Array Substrate, Thin Film Transistor Array Substrate), and a liquid crystal disposed between the color filter substrate and the thin film transistor array substrate.
  • CF color filter substrate
  • TFT Array Substrate thin film transistor array substrate
  • TFT Array Substrate Thin Film Transistor Array Substrate
  • a liquid crystal disposed between the color filter substrate and the thin film transistor array substrate.
  • PS Liquid Crystal Layer and Spacer
  • Sealant Sealant Frame
  • a transparent ITO film layer 500 for controlling the deflection of the liquid crystal in the liquid crystal cell is provided on the passivation layer 100 (PV, Passivation) on the side of the thin film transistor array substrate 2.
  • the ITO film is as shown in FIG.
  • the layer is not a full-surface layer deposited on the passivation layer, but a patterned pattern obtained by an etching process, so that the same ITO film layer 500 as shown in FIG. 1 is not continuously disposed, but There is a certain interval between them.
  • the alignment film 600 coated on the non-ITO layer region (that is, coated on the passivation layer 100) has a thickness H1
  • the alignment film 600 coated on the ITO film layer 500 has a thickness H2.
  • the difference ⁇ H H1-H2, which may be referred to as the deviation of the alignment film thickness (ie, the thickness of the alignment film coated on the ITO layer and the thickness of the alignment film coated on the non-ITO layer region) difference).
  • the gap of the alignment film is mainly affected by the thickness of the ITO layer, and the thickness of the ITO layer causes the alignment film to have different thicknesses in different regions.
  • the thickness of the ITO film layer is in order with 4(b)-1 to (b)-3 are schematic views showing the occurrence of a gap after the alignment film is coated on the ITO film layer in Figs. 4(a)-1 to (a)-3.
  • the larger the thickness of the ITO film layer the larger the difference ⁇ H of the alignment film.
  • the thickness uniformity of the alignment film has an important influence on the display effect of the liquid crystal display panel, so it is necessary to improve and optimize the existing related technology to solve the above structure.
  • the thickness of the alignment film present is inconsistent and there is a problem of a gap.
  • the invention provides an optimized method for uniformity of alignment film thickness, wherein the alignment film is used for a liquid crystal display panel, and the optimization method comprises the following steps:
  • the thin film transistor array substrate is divided into different regions, and the halftone mask exposure and the common mask exposure are respectively performed on the photoresists in different regions.
  • the thin film transistor array substrate is divided into a first region and a second region, and the photoresist in the first region is subjected to halftone mask exposure, and the photoresist in the second region is subjected to normal mask exposure.
  • the halftone mask exposure of the photoresist in the first region is performed by using a halftone mask to incompletely expose the photoresist of the first region, and the first region will correspondingly form an ITO film layer
  • the common mask exposure of the photoresist in the second region is to completely expose the photoresist of the second region by using a common mask, and the second region will correspondingly form a contact hole.
  • the photoresist in the first region is formed into a plurality of intervals. a groove is formed in the second region to form an opening penetrating the photoresist.
  • etching the photoresist and the passivation layer after the development is performed by etching the photoresist in the first region and the passivation layer under the first region to form the passivation layer in the first region
  • a plurality of spaced-apart grooves are formed to simultaneously etch the passivation layer of the second region to form a contact hole penetrating through the passivation layer of the second region.
  • removing the photoresist after etching is to remove all of the photoresist on the passivation layer with an organic solution.
  • depositing the ITO film layer after removing the photoresist is to deposit an ITO film layer on the upper surface of the passivation layer.
  • the ITO film layer is etched to obtain an upper surface of the ITO film layer in the first region and in the first region.
  • the upper surface of the passivation layer is in the same plane of the thin film transistor array substrate.
  • the alignment film is coated on the upper surface of the ITO film layer and the passivation layer The surface of the alignment film is planar.
  • the lower surface of the alignment film in the first region is a flat surface.
  • the material of the passivation layer is SiNx.
  • a liquid crystal display panel obtained by the above optimized process comprises a color film substrate and a thin film transistor array substrate disposed opposite to each other, and a liquid crystal layer disposed between the color film substrate and the thin film transistor array substrate;
  • the upper surface of the thin film transistor array substrate is sequentially provided with a passivation layer and an ITO film layer, and an upper surface of the passivation layer is in the same plane as an upper surface of the ITO film layer, and the upper surface of the passivation layer is The upper surface of the ITO film layer is coated with an alignment film.
  • the effect of the ITO film layer and the upper surface of the passivation layer being in the same plane is achieved by using a halftone mask process, so that the entire surface of the alignment film is coated on the ITO film layer and the passivation layer at the corresponding positions.
  • the surface is uniform, the thickness is uniform and the uniformity is good, and there is no problem that the thickness of the alignment film is broken due to a gap between the ITO film layer and the passivation layer.
  • the optimization method of the present invention does not add other process processes, thereby optimizing the thickness uniformity of the alignment film while ensuring that the process steps are not complicated and complicated, thereby contributing to improving the display quality of the liquid crystal display panel.
  • FIG. 1 is a schematic cross-sectional structural view of a liquid crystal display panel in the prior art.
  • FIG. 2 is a schematic view showing the distribution of an ITO film layer on one side of a thin film transistor array substrate in the prior art.
  • Fig. 3 is a partially enlarged schematic view showing a portion A in Fig. 1.
  • FIGS. 4(a)-1 to (a)-3 are schematic views of prior art in which ITO film layers of different thicknesses are provided on a passivation layer.
  • FIGS. 4(b)-1 to (b)-3 are schematic views showing the occurrence of a gap after coating the alignment film on the ITO film layers of different thicknesses in Figs. 4(a)-1 to (a)-3.
  • FIG. 13 are process flows of a method for optimizing uniformity of alignment film thickness according to an embodiment of the present invention.
  • FIG. 14 is a schematic structural view of a liquid crystal display panel according to Embodiment 2 of the present invention.
  • This embodiment provides an optimization method for uniformity of alignment film thickness, wherein the alignment film is used for a thin film transistor array substrate, and the optimization method includes the following steps:
  • a thin film transistor array substrate (not shown) on which a passivation layer 100 is deposited is provided, and the material of the passivation layer is SiNx.
  • a photoresist 200 is coated on the passivation layer 100.
  • the halftone mask exposure and the common mask exposure are respectively performed on different regions of the photoresist, specifically, as shown in FIG. 7, the thin film transistor array substrate is divided into the first region 91 and the second region 92, and a halftone mask is used.
  • the photoresist 200 in the first region 91 is incompletely exposed, and the first region will correspondingly form an ITO film layer; the photoresist 200 in the second region 92 is completely exposed using a common mask, and the second region will correspond A contact hole and an ITO film layer formed in the contact hole are formed.
  • the photoresist after the halftone mask exposure and the ordinary mask exposure is developed, specifically, the first region 91 is developed, since the first region 91 is incompletely exposed, The first region is only partially removed, so that the photoresist in the first region is recessed toward the interior thereof to form a plurality of spaced grooves; the second region 92 is developed, since the second region 92 is completely exposed, Therefore, the photoresist of the second region is completely removed after development, so that the second region forms an opening through the photoresist.
  • FIG. 9(a) shows the photoresist and the etching state of the passivation layer during the etching process.
  • FIG. 9(b) is a schematic view showing the structure of the photoresist and the passivation layer after the etching process is completed, thereby clearly showing the state of change of the photoresist and the passivation layer during the etching process.
  • the photoresist 200 in the first region 91 and the passivation layer 100 under it are etched.
  • the photoresist under the groove is thinner than the photoresist at other positions, so as shown in FIG.
  • the portion of the photoresist is first etched away, so that A portion of the passivation layer in one region is exposed, while the photoresist at other locations is also etched and thinned as the etching process proceeds; then, as the etching proceeds, as shown in Figure 9(b) As shown, a portion of the exposed passivation layer will continue to be etched, and the etch etch will cause the upper surface of the passivation layer to be recessed toward the interior thereof to form a plurality of spaced grooves 300, while the photoresist in the first region is The etching process continues to be etched and made thinner.
  • the second region 92 forms an opening through the photoresist after development, the portion of the passivation layer under the photoresist of the second region 92 is exposed, so when the second region after development is etched, it is actually The partially exposed passivation layer 100 in the second region 92 is etched and etched to form a contact hole 400 penetrating through the passivation layer 100 for contacting the drain electrode with the ITO film layer; At the same time, the photoresist in the second region is also etched and thinned as the etching process proceeds.
  • the photoresist is removed using an organic solution; in fact, the purpose of this step is to remove the photoresist, so that in addition to the use of the organic solution as the photoresist removal liquid, other common in the prior art can be employed.
  • the treatment method for example, uses a plasma treatment technique to ash the photoresist, thereby removing the photoresist.
  • an ITO film layer 500 is deposited on the passivation layer after the photoresist is removed, and an ITO film layer is deposited on the upper surface, the recess, and the opening of the passivation layer.
  • the ITO film layer 500 is etched by a yellow light process to remove the ITO film layer on the upper surface of the passivation layer, and the ITO film layer in the recess 300 of the passivation layer is left to be located first.
  • the upper surface of the passivation layer 100 of the region 91 is on the same level as the upper surface of the ITO film layer 500.
  • a surface of the ITO film layer 500 which has been completely etched and a partially exposed passivation layer 100 are coated with a full-face alignment film 600 whose upper surface is a flat surface. Since the upper surface of the passivation layer in the first region is at the same level as the upper surface of the ITO film layer, when the alignment film is coated in the first region, the lower surface of the alignment film is also a flat plane, thereby ensuring alignment The thickness of the film is uniform.
  • the effect of the ITO film layer and the upper surface of the passivation layer being in the same plane is achieved by using a halftone mask process, so that the uniformity of thickness of the alignment film during coating is good, and ITO is not present.
  • the gap between the film layer and the passivation layer causes a problem of a gap in the thickness of the alignment film.
  • no other process steps are added in the optimization method, so that an alignment film with good thickness uniformity is obtained under the premise that the process flow is not complicated.
  • the embodiment provides a liquid crystal display panel prepared by the above optimization method.
  • the liquid crystal display panel includes a color film substrate 1 and a thin film transistor array substrate 2 disposed opposite to each other, and a color filter substrate and a thin film transistor.
  • the liquid crystal layer 3 between the array substrates.
  • the color film substrate ITO film layer 700 and the color film substrate alignment film 800 are disposed on the lower surface of the color filter substrate 1; the passivation layer 100 and the ITO film layer 500 are sequentially disposed on the upper surface of the thin film transistor array substrate 2, and the thin film transistor is provided.
  • the array substrate may be divided into a first region 91 on the right side and a second region 92 on the left side, in which a contact hole 400 penetrating through the passivation layer is formed, and an ITO film located in the second region
  • the layer 500 is deposited on the contact hole 400 such that the ITO film layer is in contact with the drain (not shown);
  • a plurality of spaced grooves 300 recessed toward the inside of the passivation layer 100 itself are provided in the first region 91, and the ITO film layer 500 located in the first region is disposed in the grooves 300, and in the first region 91
  • the upper surface of the passivation layer 100 is flat with the upper surface of the ITO film layer 500, and the two are in the same horizontal plane.
  • An alignment film 600 is further coated on the upper surface of the passivation layer 100 and the ITO film layer 500 of the first region 91.
  • the upper surface of the alignment film is a flat surface. Since the upper surface of the ITO film layer located in the first region is at the same level as the upper surface of the passivation layer, the lower surface of the alignment film located in the first region is also planar.
  • the thin film transistor array substrate and the liquid crystal display panel may further include other conventional functional structures, which are not repeatedly described in the present invention.

Abstract

一种配向膜(600)厚度均一性的优化方法,包括以下步骤:提供沉积有钝化层(100)的薄膜晶体管阵列基板(2);在钝化层(100)上涂布光阻(200);将薄膜晶体管阵列基板(2)划分为不同区域,对处于不同区域的光阻(200)分别进行半色调掩膜曝光和普通掩膜曝光、显影、刻蚀;刻蚀后,去除光阻(200)、沉积ITO膜层(500);对ITO膜层(500)进行刻蚀,得到ITO膜层(500)上表面与钝化层(100)上表面处于同一平面的薄膜晶体管阵列基板(2);在ITO膜层(500)上表面和钝化层(100)上表面涂布配向膜(600)。由于ITO膜层(500)上表面与钝化层(100)上表面处于同一平面,使得涂布在其上方的整面配向膜(600)厚度均一,因而有助于提高液晶显示面板的显示品质。

Description

配向膜厚度均一性的优化方法及液晶显示面板 技术领域
本发明涉及液晶显示技术领域,具体是一种配向膜厚度均一性的优化方法以及利用该优化方法得到的液晶显示面板。
背景技术
随着触控技术和显示技术的发展,触控显示面板已经被广泛应用于智能手机、平板电脑等智能电子产品中,为人机交互带来更便捷地体验。
通常地,液晶显示面板的主要结构包括彩膜基板(CF,Color Filter)、薄膜晶体管阵列基板(TFT Array Substrate,Thin Film Transistor Array Substrate)、设置在彩膜基板和薄膜晶体管阵列基板之间的液晶层(Liquid Crystal Layer)和间隔物(PS,Photo Spacer)、以及密封胶框(Sealant)。其中,在彩膜基板的下表面、薄膜晶体管阵列基板的上表面均涂布了一层配向膜(PI),作用是使液晶分子按照一定的方向和角度排列,因此配向膜对于液晶显示面板而言是必不可少的,而且配向膜的厚度是否均一会对液晶显示面板的光学品质产生一定影响。
如图1所示,在薄膜晶体管阵列基板2一侧的钝化层100(PV,Passivation)上设有用于控制液晶盒内液晶产生偏转的透明ITO膜层500,结合图2可知,该ITO膜层并不是沉积在钝化层上的一整面图层,而是通过刻蚀工艺得到的图案化图形,因此才会有如图1所示的同一ITO膜层500并不是连续设置,而是之间有一定间隔。故在薄膜晶体管阵列基板2上表面涂布整面配向膜600时,部分配向膜是覆盖在ITO膜层上的,同时也有部分配向膜是覆盖在处于ITO膜层间隔处的钝化层100上的,这就导致了配向膜的厚度不一致的问题。
如图3所示,涂布于非ITO层区域(即涂布于钝化层100)上的配向膜600厚度为H1,涂布于ITO膜层500上的配向膜600厚度为H2,二者之间的差值△H=H1-H2,该差值可称为配向膜厚度的断差(即涂布于ITO层上的配向膜厚度与涂布于非ITO层区域上的配向膜厚度之差)。配向膜的断差主要是受到ITO层厚度的影响,ITO层厚度导致了配向膜在不同区域有不同的厚度。图4(a)-1至(a)-3中,ITO膜层的厚度依次为
Figure PCTCN2016089745-appb-000001
Figure PCTCN2016089745-appb-000002
图4(b)-1至(b)-3是在图4(a)-1至(a)-3中ITO膜层上涂布配向膜后,产生断差的示意图。从这些图的对比可以看出,ITO膜层的厚度越大,配向膜的断差△H越大。考虑到配向膜在液晶显示面板中所起到的作用可知,配向膜的厚度一 致性对于液晶显示面板的显示效果有着重要影响,因此实有必要对现有相关技术进行改进和优化以解决上述结构中存在的配向膜厚度不一致、出现断差的问题。
发明内容
为克服现有技术的不足,本发明的目的在于提供一种。
本发明提供一种配向膜厚度均一性的优化方法,所述配向膜用于液晶显示面板,所述优化方法包括以下步骤:
提供沉积有钝化层的薄膜晶体管阵列基板;在所述钝化层上涂布光阻;将所述薄膜晶体管阵列基板划分为不同区域,对处于不同区域的光阻分别进行半色调掩膜曝光和普通掩膜曝光;对进行半色调掩膜曝光和普通掩膜曝光后的所述光阻进行显影;对显影后的所述光阻和钝化层进行刻蚀;刻蚀后,去除所述光阻;去除所述光阻后,沉积ITO膜层;对所述ITO膜层进行刻蚀,得到ITO膜层上表面与钝化层上表面处于同一平面的薄膜晶体管阵列基板;在所述ITO膜层上表面和所述钝化层上表面涂布配向膜。
作为一种实施方式,在本发明所述优化方法中,将所述薄膜晶体管阵列基板划分为不同区域,对处于不同区域的光阻分别进行半色调掩膜曝光和普通掩膜曝光是将所述薄膜晶体管阵列基板划分为第一区域和第二区域,对处于第一区域的所述光阻进行半色调掩膜曝光,对处于第二区域的所述光阻进行普通掩膜曝光。进一步地,对处于第一区域的所述光阻进行半色调掩膜曝光是采用半色调掩膜对第一区域的所述光阻进行不完全曝光,第一区域将对应形成ITO膜层,对处于第二区域的所述光阻进行普通掩膜曝光是采用普通掩膜对第二区域的所述光阻进行完全曝光,第二区域将对应形成接触孔。作为一种实施方式,在本发明所述优化方法中,对进行半色调掩膜曝光和普通掩膜曝光后的所述光阻进行显影后,使处于所述第一区域的光阻形成若干间隔设置的凹槽,所述第二区域内形成贯穿于所述光阻的开孔。
进一步地,对显影后的所述光阻和钝化层进行刻蚀是对处于第一区域的光阻及其下方的钝化层进行刻蚀,使处于第一区域的所述钝化层形成若干间隔设置的凹槽,同时对所述第二区域的所述钝化层进行刻蚀,形成贯穿于所述第二区域的钝化层的接触孔。
进一步地,刻蚀后去除所述光阻是采用有机溶液除去所述钝化层上的全部所述光阻。
进一步地,去除所述光阻后沉积ITO膜层是在钝化层的上表面沉积形成ITO膜层。
作为一种实施方式,在本发明所述优化方法中,对所述ITO膜层进行刻蚀,得到处于所述第一区域中的所述ITO膜层上表面与处于所述第一区域中的所述钝化层上表面处于同一平面的薄膜晶体管阵列基板。
进一步地,所述配向膜整面涂布在所述ITO膜层上表面和所述钝化层上表 面,使所述配向膜上表面为平面。
进一步地,处于所述第一区域内的所述配向膜下表面为平面。
优选地,所述钝化层的材料为SiNx。
一种采用上述优化工艺方法得到的液晶显示面板,包括相对设置的彩膜基板和薄膜晶体管阵列基板、以及设置于所述彩膜基板和所述薄膜晶体管阵列基板之间的液晶层;其中,在所述薄膜晶体管阵列基板上表面依次设有钝化层和ITO膜层,且所述钝化层的上表面与所述ITO膜层的上表面处于同一平面,在所述钝化层上表面和所述ITO膜层上表面涂布有配向膜。
与现有技术相比,本发明的有益效果如下:
在本发明中,通过利用半色调掩膜工艺实现ITO膜层与钝化层的上表面处于同一平面的效果,从而使配向膜整面涂布在相应位置ITO膜层与钝化层呢个上表面时,其厚度一致、均一性良好,不会出现因ITO膜层与钝化层之间有断差而导致配向膜厚度出现断差的问题。此外,本发明的优化方法并未增加其它的制程过程,从而在保证工艺步骤不繁琐复杂的同时,使配向膜厚度均一性得到优化,进而有助于提高液晶显示面板的显示品质。
附图说明
图1是现有技术中液晶显示面板的剖面结构示意图。
图2是现有技术中薄膜晶体管阵列基板一侧设置ITO膜层的分布示意图。
图3是图1中A处的局部放大示意图。
图4(a)-1至(a)-3是现有技术中在钝化层上设置不同厚度ITO膜层的示意图。
图4(b)-1至(b)-3是在图4(a)-1至(a)-3中不同厚度ITO膜层上涂布配向膜后产生断差的示意图。
图5至图13是本发明实施例一配向膜厚度均一性优化方法的工艺流程。
图14是本发明实施例二液晶显示面板的结构示意图。
具体实施方式
实施例一
本实施例提供一种配向膜厚度均一性的优化方法,所述配向膜用于薄膜晶体管阵列基板,所述优化方法包括以下步骤:
如图5所示,提供一沉积有钝化层100的薄膜晶体管阵列基板(图未示),该钝化层的材料为SiNx。
如图6所示,在该钝化层100上涂布光阻200。
对光阻的不同区域分别进行半色调掩膜曝光和普通掩膜曝光,具体为:如图7所示,将薄膜晶体管阵列基板划分为第一区域91和第二区域92,使用半色调掩膜对处于第一区域91的光阻200进行不完全曝光,该第一区域将对应形成ITO膜层;使用普通光罩对处于第二区域92的光阻200进行完全曝光,该第二区域将对应形成接触孔以及形成于接触孔中的ITO膜层。
如图8所示,对进行半色调掩膜曝光和普通掩膜曝光后的光阻进行显影,具体为:对第一区域91进行显影,由于该第一区域91为不完全曝光,因此显影后使该第一区域仅除去部分光阻,从而使处于第一区域的光阻朝向自身内部凹陷形成若干间隔设置的凹槽;对第二区域92进行显影,由于对第二区域92为完全曝光,因此显影后该第二区域的光阻全部被除去,从而使第二区域形成贯穿光阻的开孔。
接着,对显影后的光阻和钝化层进行刻蚀,该刻蚀过程是一个连续的过程,图9(a)所示为刻蚀工艺过程中的光阻和钝化层的刻蚀状态,图9(b)所示为刻蚀工艺完成后光阻和钝化层的结构示意图,从而清楚地显示刻蚀工艺过程中光阻和钝化层的变化状态。
具体为:对处于第一区域91的光阻200及其下方的钝化层100进行刻蚀。首先,由于形成有若干凹槽,使得位于凹槽下方的光阻较其它位置的光阻更薄,因此如图9(a)所示,该部分光阻最先被刻蚀掉,使处于第一区域中的部分钝化层暴露,与此同时其它位置的光阻也随着刻蚀工艺过程的进行而被刻蚀、变薄;然后,随着刻蚀的进行,如图9(b)所示,部分已经暴露的钝化层会继续被刻蚀,刻蚀刻蚀使钝化层上表面朝向自身内部凹陷形成若干间隔设置的凹槽300,与此同时处于第一区域内的光阻随着刻蚀工艺的进行会继续被刻蚀、变得更薄。
由于第二区域92在显影后形成贯穿光阻的开孔,使位于该第二区域92光阻下方的钝化层部分暴露,因此对显影后的第二区域进行刻蚀时,实际上是对处于第二区域92中部分暴露的钝化层100进行刻蚀刻蚀,刻蚀后形成贯穿于钝化层100的接触孔400,该接触孔用于使漏极与ITO膜层相接触;与此同时,处于第二区域内的光阻也随着刻蚀工艺的进行而被刻蚀、不断变薄。
如图10所示,使用有机溶液将光阻除去;实际上,本步骤的目的在于将光阻除去即可,因此除了使用有机溶液作为光阻去除液,还可以采用其它现有技术中常见的处理方法,例如采用等离子处理技术使光阻灰化,进而将光阻除去。
如图11所示,在除去光阻后的钝化层上沉积形成ITO膜层500,使钝化层的上表面、凹槽、开孔中均沉积有ITO膜层。
如图12所示,采用黄光制程对ITO膜层500进行刻蚀,除去位于钝化层上表面的ITO膜层,保留位于钝化层的凹槽300中的ITO膜层,使位于第一区域91的钝化层100上表面与ITO膜层500上表面处于同一水平面上。
如图13所示,在上述已经完成刻蚀的ITO膜层500表面、部分暴露的钝化层100表面涂布一整面的配向膜600,该配向膜600的上表面为平面。由于在第一区域中的钝化层上表面与ITO膜层上表面处于同一水平面,因此在该第一区域内涂布配向膜时,配向膜的下表面也是平整的平面,由此保证了配向膜的厚度均一性。
在本实施例的优化方法中,利用半色调掩膜工艺实现ITO膜层与钝化层的上表面处于同一平面的效果,使得配向膜在涂布时,厚度均一性良好,不会出现因ITO膜层与钝化层之间的断差而导致配向膜厚度出现断差的问题。此外,该优化方法中并未增加其它的工艺步骤,从而在保证了工艺流程并未复杂化的前提下,得到了厚度均一性良好的配向膜。
实施例二
本实施例提供一种利用上述优化方法制得的液晶显示面板,如图14所示,液晶显示面板包括相对设置的彩膜基板1和薄膜晶体管阵列基板2、以及设置于彩膜基板和薄膜晶体管阵列基板之间的液晶层3。
其中,在彩膜基板1的下表面设有彩膜基板ITO膜层700和彩膜基板配向膜800;在薄膜晶体管阵列基板2上表面依次设有钝化层100和ITO膜层500,薄膜晶体管阵列基板可划分为位于右侧的第一区域91和位于左侧的第二区域92,在第二区域92中形成有贯穿于钝化层的接触孔400,位于该第二区域内的ITO膜层500沉积在接触孔400上,从而使ITO膜层与漏极(图未示)相接触;
在第一区域91中设有朝向钝化层100自身内部凹陷的若干间隔的凹槽300,位于该第一区域内的ITO膜层500设置在这些凹槽300中,且在第一区域91的钝化层100上表面与ITO膜层500上表面持平,二者处于同一水平面。在第一区域91的钝化层100和ITO膜层500上表面还涂布有配向膜600。该配向膜的上表面为平面,由于位于第一区域内的ITO膜层上表面与钝化层上表面处于同一水平面,故该配向膜位于第一区域内的下表面也为平面。
可以理解的是,以上仅对薄膜晶体管阵列基板以及液晶显示面板的主体结构进行了说明,薄膜晶体管阵列基板以及液晶显示面板还可以包括其它常规的功能结构,在本发明中不再一一赘述。
以上所述为本发明的具体实施方式,其目的是为了清楚说明本发明而作的举例,并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。

Claims (12)

  1. 一种配向膜厚度均一性的优化方法,所述配向膜用于液晶显示面板,其中:所述优化方法包括以下步骤:
    提供沉积有钝化层的薄膜晶体管阵列基板;在所述钝化层上涂布光阻;将所述薄膜晶体管阵列基板划分为不同区域,对处于不同区域的光阻分别进行半色调掩膜曝光和普通掩膜曝光;对进行半色调掩膜曝光和普通掩膜曝光后的所述光阻进行显影;对显影后的所述光阻和钝化层进行刻蚀;刻蚀后,去除所述光阻;去除所述光阻后,沉积ITO膜层;对所述ITO膜层进行刻蚀,得到ITO膜层上表面与钝化层上表面处于同一平面的薄膜晶体管阵列基板;在所述ITO膜层上表面和所述钝化层上表面涂布配向膜。
  2. 如权利要求1所述的优化方法,其中:将所述薄膜晶体管阵列基板划分为不同区域,对处于不同区域的光阻分别进行半色调掩膜曝光和普通掩膜曝光是将所述薄膜晶体管阵列基板划分为第一区域和第二区域,对处于第一区域的所述光阻进行半色调掩膜曝光,对处于第二区域的所述光阻进行普通掩膜曝光。
  3. 如权利要求2所述的优化方法,其中:对处于第一区域的所述光阻进行半色调掩膜曝光是采用半色调掩膜对第一区域的所述光阻进行不完全曝光,第一区域将对应形成ITO膜层,对处于第二区域的所述光阻进行普通掩膜曝光是采用普通掩膜对第二区域的所述光阻进行完全曝光,第二区域将对应形成接触孔。
  4. 如权利要求3所述的优化方法,其中:对进行半色调掩膜曝光和普通掩膜曝光后的所述光阻进行显影后,使处于所述第一区域的光阻形成若干间隔设置的凹槽,所述第二区域内形成贯穿于所述光阻的开孔。
  5. 如权利要求4所述的优化方法,其中:对显影后的所述光阻和钝化层进行刻蚀是对处于第一区域的光阻及其下方的钝化层进行刻蚀,使处于第一区域的所述钝化层形成若干间隔设置的凹槽,同时对第二区域的所述钝化层进行刻蚀,形成贯穿于第二区域的所述钝化层的接触孔。
  6. 如权利要求2所述的优化方法,其中:对所述ITO膜层进行刻蚀,得到处于所述第一区域中的所述ITO膜层上表面与处于所述第一区域中的所述钝化层上表面处于同一平面的薄膜晶体管阵列基板。
  7. 如权利要求3所述的优化方法,其中:对所述ITO膜层进行刻蚀,得 到处于所述第一区域中的所述ITO膜层上表面与处于所述第一区域中的所述钝化层上表面处于同一平面的薄膜晶体管阵列基板。
  8. 如权利要求4所述的优化方法,其中:对所述ITO膜层进行刻蚀,得到处于所述第一区域中的所述ITO膜层上表面与处于所述第一区域中的所述钝化层上表面处于同一平面的薄膜晶体管阵列基板。
  9. 如权利要求6所述的优化方法,其中:处于所述第一区域内的所述配向膜下表面为平面。
  10. 如权利要求1所述的优化方法,其中:去除所述光阻后沉积ITO膜层是在钝化层的上表面沉积形成ITO膜层。
  11. 如权利要求1所述的优化方法,其中:所述配向膜整面涂布在所述ITO膜层上表面和所述钝化层上表面,使所述配向膜上表面为平面。
  12. 一种液晶显示面板,所述液晶显示面板包括相对设置的彩膜基板和薄膜晶体管阵列基板、以及设置于所述彩膜基板和所述薄膜晶体管阵列基板之间的液晶层;其中:在所述薄膜晶体管阵列基板上表面依次设有钝化层和ITO膜层,且所述钝化层的上表面与所述ITO膜层的上表面处于同一平面,在所述钝化层上表面和所述ITO膜层上表面涂布有配向膜。
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