WO2017094600A1 - Composition répulsive pulvérulente pour lutter contre les insectes nuisibles et son procédé de fabrication - Google Patents

Composition répulsive pulvérulente pour lutter contre les insectes nuisibles et son procédé de fabrication Download PDF

Info

Publication number
WO2017094600A1
WO2017094600A1 PCT/JP2016/084905 JP2016084905W WO2017094600A1 WO 2017094600 A1 WO2017094600 A1 WO 2017094600A1 JP 2016084905 W JP2016084905 W JP 2016084905W WO 2017094600 A1 WO2017094600 A1 WO 2017094600A1
Authority
WO
WIPO (PCT)
Prior art keywords
pest repellent
repellent composition
powdery
active ingredient
oil absorbent
Prior art date
Application number
PCT/JP2016/084905
Other languages
English (en)
Japanese (ja)
Inventor
市村　由美子
浅井　洋
中山　幸治
Original Assignee
大日本除蟲菊株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大日本除蟲菊株式会社 filed Critical 大日本除蟲菊株式会社
Priority to CN201680064957.XA priority Critical patent/CN108347930A/zh
Priority to JP2017553814A priority patent/JP6449484B2/ja
Publication of WO2017094600A1 publication Critical patent/WO2017094600A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring

Definitions

  • the present invention relates to a powdery pest repellent composition for protecting human bodies and animals from pests such as mosquitoes, gnats, sand flies, house dust mites, bedbugs, and the like, and a method for producing the same.
  • Patent Literature 1 and Patent Literature 2 are known as conventional aerosol type pest repellent products.
  • the pest repellent composition of Patent Document 1 is a mixture of inorganic powder or organic powder and anhydrous silicic acid in a specific ratio, which is filled in an aerosol container together with pest repellent components, alcohol, and propellant.
  • a pest repellent is supported on silicic anhydride porous fine particles, and this is filled in an aerosol container together with synthetic resin fine particles, alcohol and a propellant.
  • a wet tissue type product as in Patent Document 3 has also been developed.
  • the pest repellent of Patent Document 3 is obtained by impregnating a nonwoven fabric with a silicate compound, a pest repellent component, and alcohol.
  • aerosol-type pest repellent products such as Patent Document 1 and Patent Document 2 atomize the pest repellent component and spray it onto the skin surface, which easily causes uneven coating on the coated surface. As a result, a slight portion where the drug does not adhere to the skin may occur, and this small portion may lead to mosquito biting and blood sucking behavior.
  • the nasal mucosa may be irritated by the scattering of a pest repellent composition (medicine) containing alcohol and a pest repellent component, and improvement is required in terms of usability.
  • the present invention has been made in view of the above problems, focusing on the powder type as the product form of the pest repellent composition, and of course has excellent pest repellent effect and safety to human bodies and animals.
  • Another object of the present invention is to provide an alcohol-free powdery pest repellent composition that is satisfactory in terms of usability and sustainability, and a method for producing the same.
  • the characteristic constitution of the powdery pest repellent composition according to the present invention for solving the above problems is as follows: A pest repellent containing at least one selected from the group consisting of diet, 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester, and icaridin, An irritation relaxation agent comprising a glycol solvent as an active ingredient; A water retention agent containing talc as an active ingredient; An oil absorbent containing a silicate compound as an active ingredient; A powdery pest repellent composition comprising: The ratio (a: b) of the blending amount (a) of the moisture retention agent and the blending amount (b) of the oil absorbent is 3: 1 to 20: 1 by weight.
  • the powdery pest repellent composition of this configuration contains a water retention agent containing talc as an active ingredient and an oil absorbent containing a silicate compound as an active ingredient in the above-mentioned appropriate blending ratio.
  • oil such as sebum is moderately absorbed by the silicic acid compound, while talc retains moisture moderately, reducing the stickiness and moist feeling can get.
  • talc and silicic acid compounds are stable substances, there is no possibility of weakening the effect of the pest repellent, and coupled with the effect of the stimulant mitigating agent, the product has a low irritant and high repellent effect.
  • the glycol solvent is preferably 1,3-butylene glycol.
  • the powdery insect pest repellent composition of this configuration by using 1,3-butylene glycol as the glycol solvent, it is possible to particularly enhance the stimulus mitigating effect while realizing an excellent feeling of use.
  • the talc preferably has an apparent specific gravity of 0.4 to 0.6 g / cc measured according to JIS K5101.
  • the talc preferably has an average particle size of 20 ⁇ m or more.
  • the powdery insect pest repellent composition of this configuration when the average particle size of talc is 20 ⁇ m or more, talc is reliably attached to the skin and a moist feeling can be obtained.
  • the silicic acid compound is preferably anhydrous silicic acid.
  • the use of silicic anhydride as the silicic acid compound makes the oil absorption particularly good, and is an effective product that can reduce the feeling of stickiness for people with a lot of sebum It becomes.
  • the silicic acid compound preferably has a specific surface area of 5 to 100 m 2 / g.
  • the specific surface area of the silicate compound is in the above-mentioned appropriate range, oil such as sebum can be efficiently absorbed.
  • a mixing step of mixing an irritation reducing agent An absorption step of absorbing the mixture obtained by the mixing step into an oil absorbent containing a silicate compound as an active ingredient;
  • a method for producing a powdery pest repellent composition comprising: The ratio (a: b) of the amount (a) of the water retaining agent in the addition step and the amount (b) of the oil absorbent used in the absorption step is 3: 1 to 20: 1 by weight.
  • the same excellent effects as those of the powdery pest repellent composition described above are exhibited.
  • the amount of water retention agent containing talc as an active ingredient in the addition step and the amount of oil absorbent containing silicate compound as the active ingredient in the absorption step are set to the appropriate weight ratio described above.
  • the powdered pest repellent composition obtained through the subsequent stirring step is such that when the user applies it to the skin, oils such as sebum are appropriately absorbed by the silicate compound, while talc retains moisture appropriately. This provides a moist feel while suppressing stickiness.
  • talc and silicic acid compounds are stable substances, there is no risk of weakening the effect of the pest repellent, and in combination with the effect of the stimulant mitigating agent, it is possible to produce a product with a high repellent effect while being mild. .
  • the powdery pest repellent composition of the present invention contains (1) a pest repellent, (2) a stimulus mitigating agent, (3) a water retention agent, and (4) an oil absorbent as basic components.
  • the powdery pest repellent composition of the present invention does not contain alcohols such as ethanol, isopropanol, and propanol.
  • alcohols such as ethanol, isopropanol, and propanol.
  • Pest repellent is a substance having a repellent action and a blood sucking inhibitory action against pests.
  • pest repellents include diet, 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester, icaridin, picaridin, citronellal, citronellol, citral, linalool, terpineol, menthol, p-menthane-3,
  • Examples include synthetic compounds such as 8-diol, ⁇ -pinene, camphor, geraniol, and caran-3,4-diol.
  • Natural products such as cinnamon bark, citronella, lemongrass, clover, bergamot, laurel and eucalyptus can also be used. Natural products can be used in the form of essential oils or extracts.
  • diet 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester, and icaridin are preferably used. Diet has a long track record of use. 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester has a repellent effect equivalent to that of diet, but is safer to the human body than diet. Icaridine has a high insect repellent effect and high safety.
  • Each of the above-mentioned pest repellents may be used alone or as a mixture of two or more.
  • the compounding amount of the pest repellent is 1 to 15% by weight, preferably 3 to 14% by weight, more preferably 6 to 12% by weight based on the total amount of the powdery pest repellent composition. If the blending amount is less than 1% by weight, a sufficient pest repellent action may not be obtained. If the blending amount is more than 15% by weight, the irritation may become too strong.
  • An irritation mitigating agent is a substance added to alleviate skin irritation caused by a pest repellent.
  • a glycol solvent is used as the stimulant mitigating agent.
  • the glycol solvent is preferably a C 3 to C 6 glycol, and examples thereof include diethylene glycol, propylene glycol, dipropylene glycol, and 1,3-butylene glycol. Of these, 1,3-butylene glycol having a high stimulus mitigating action is more preferably used.
  • C 3 -C 6 glycols such as 1,3-butylene glycol are difficult to be absorbed from the skin per se, which is effective in reducing the percutaneous absorption of pest repellents.
  • the glycol solvents listed above may be used singly or as a mixture of two or more.
  • the amount of the stimulant mitigating agent is 1 to 15% by weight, preferably 5 to 10% by weight, more preferably 6 to 8% by weight, based on the total amount of the powdery pest repellent composition.
  • the blending amount is less than 1% by weight, there is a possibility that the stimulation of the pest repellent cannot be sufficiently mitigated.
  • the blending amount is more than 15% by weight, the feeling of stickiness is increased by a large amount of glycol solvent, and the feeling of use may be deteriorated.
  • the moisture retention agent is a substance added to give a moist feel (so-called moist feeling).
  • talc is used as the moisture retaining agent.
  • Talc preferably has an apparent specific gravity of 0.4 to 0.6 g / cc measured according to JIS K5101. When the apparent specific gravity is less than 0.4 g / cc, the sticky feeling is felt stronger than the moist feeling, and the feeling of use may be deteriorated. When the apparent specific gravity exceeds 0.6 g / cc, the smoothness becomes stronger and the powder may fall off.
  • the average particle diameter of a talc is 20 micrometers or more.
  • talc By setting the average particle size to 20 ⁇ m or more, talc can reliably adhere to the skin and a moist feeling can be obtained.
  • the average particle size is less than 20 ⁇ m, a so-called white residue may be generated in which the pest repellent composition stands out in white when applied to the skin.
  • talc can also be used in the state mixed with other inorganic powders, such as kaolin and bentonite.
  • the amount of the water retaining agent is 50 to 90% by weight, preferably 55 to 85% by weight, more preferably 63 to 83.5% by weight, based on the total amount of the powdery pest repellent composition.
  • the blending amount is less than 50% by weight, moisture cannot be sufficiently retained, and there is a possibility that powder falling off may occur.
  • the blending amount is more than 90% by weight, the sticky feeling becomes stronger than the moist feeling, and the feeling of use may be deteriorated.
  • Oil absorbent is a substance added to absorb oil such as sebum.
  • a silicate compound is used as the oil absorbent.
  • the silicate compound include anhydrous silicic acid, calcium silicate, hydrophobic silica, diatomaceous earth and the like. Of these, silicic anhydride having a high oil absorption effect is more preferably used.
  • the silicic acid compound preferably has a specific surface area of 5 to 100 m 2 / g. When the specific surface area is less than 5 m 2 / g, the oil absorption capacity is insufficient and stickiness tends to occur. When the specific surface area exceeds 100 m 2 / g, the smoothness becomes stronger and the powder may fall off.
  • the silicic acid compounds listed above may be used alone or as a mixture of two or more.
  • the blending amount of the oil absorbent is 1 to 50% by weight, preferably 3 to 30% by weight, more preferably 4.5 to 21% by weight, based on the total amount of the powdery pest repellent composition. If the blending amount is less than 1% by weight, the oil absorption capacity is insufficient, and stickiness tends to occur. When the blending amount is more than 50% by weight, the oil absorption capacity becomes excessive, the weight is felt, and the usability may be deteriorated.
  • the powdery pest repellent composition of the present invention is prepared from the above-mentioned (1) pest repellent, (2) irritation mitigating agent, (3) moisture retention agent, and (4) oil absorbent as raw materials. Can be manufactured.
  • pest repellent and stimulant mitigating agent are mixed (mixing process).
  • the mixture obtained by the mixing step is absorbed by the oil absorbent (absorption step).
  • a water retention agent is added to the oil absorbent that has completed the absorption process (addition process).
  • the mixture of each component obtained by the addition process is stirred (stirring process). Thereby, the powdery pest repellent composition of the present invention is completed.
  • the present inventors conducted trial and error, and while ensuring the pest repellent effect and safety to the human body and animals, the feeling of use and lasting In order to obtain a product with excellent properties, it has been found that it is particularly important to set an appropriate ratio between the amount of the water retaining agent and the amount of the oil absorbent, among the above components. . Specifically, when the blending amount (addition amount) of the moisture retention agent is a and the blending amount (use amount) of the oil absorbent is b, the ratio between the blending amount of the moisture retention agent and the blending amount of the oil absorption agent.
  • the weight ratio is set so that (a: b) is 3: 1 to 20: 1, preferably 3: 1 to 19: 1.
  • the blending ratio is less than 3: 1, that is, when the blending amount of the moisture retaining agent is too small than the blending amount of the oil absorbent, moisture cannot be retained sufficiently, and there is a possibility that powder falling may occur.
  • the blending ratio is larger than 20: 1, that is, when the blending amount of the moisture retaining agent is too much than the blending amount of the oil absorbent, the sticky feeling is felt more strongly than the moist feeling, and the feeling of use is increased. May get worse.
  • the blending ratio is set within the above-mentioned range, when the user applies the powdery pest repellent composition to the skin, oil such as sebum is appropriately absorbed by the silicate compound, while talc retains moisture appropriately. By doing so, a moist feel can be obtained while suppressing stickiness.
  • talc and silicic acid compounds are stable substances, there is no possibility of weakening the effect of the pest repellent, and coupled with the effect of the stimulant mitigating agent, the product has a low irritant and high repellent effect.
  • the powdery pest repellent composition of the present invention may contain other components as long as they do not inhibit the effects of the pest repellent, the stimulus mitigating agent, the water retention agent, and the oil absorbent.
  • examples of such components include ultraviolet absorbers, ultraviolet scattering agents, brighteners, other powders, flame retardants, antiperspirants, moisturizers, surfactants, dispersants, fragrances and the like.
  • Examples of the ultraviolet absorber and ultraviolet scattering agent include paraaminobenzoic acid, amylsalicynate, octylcinnamate, octyl methoxycinnamate, 2,4-dihydroxybenzophenone, titanium oxide, and zinc oxide.
  • Anti-inflammatory agents include dipotassium glycyrrhizinate, allantoin, alkyltrimethylammonium chloride, tocopherol acetate, camphor and the like.
  • Examples of the antiperspirant include aluminum sulfate, chlorohydroxyaluminum, and zinc phenolsulfonate.
  • the brightener examples include films (for example, a film obtained by vapor-depositing aluminum on polyethylene terephthalate, a film obtained by vapor-depositing gold on polyethylene terephthalate, a laminated film of polyethylene terephthalate and polyolefin, a laminated film of polyethylene terephthalate and polymethyl methacrylate, and polyethylene terephthalate.
  • films for example, a film obtained by vapor-depositing aluminum on polyethylene terephthalate, a film obtained by vapor-depositing gold on polyethylene terephthalate, a laminated film of polyethylene terephthalate and polyolefin, a laminated film of polyethylene terephthalate and polymethyl methacrylate, and polyethylene terephthalate.
  • Mineral fragments of laminated film with polyethylene natural mica powder such as muscovite powder and phlogopite powder, synthetic mica powder obtained by melting natural mica powder and removing impurities, and mica titanium mixed with titanium oxide and other minerals such as titanium mica And polyalcohol esters such as ethylene glycol monostearate, ethylene glycol distearate and triethylene glycol distearate, and agar capsules containing a dye.
  • organic powders such as modified starch and silk fiber powder, can also be mix
  • the thus obtained powdery pest repellent composition of the present invention has a high repellent effect on pests (especially mosquitoes, gnats, sand flies, house dust mites, bedbugs, etc.), but also human bodies and animals. It is excellent in safety and is a pest repellent product that is satisfactory in terms of usability and sustainability. And since no alcohol is used in the powdery pest repellent composition of the present invention, it can be used with peace of mind even for those who are sensitive to alcohol.
  • the powdery pest repellent composition (Examples 1 to 4) was prepared by variously changing the composition of the pest repellent, the stimulant mitigating agent, the water retention agent, and the oil absorbent. 11, Comparative Examples 1 to 3) were prepared, and a pest repellent effect confirmation test (initial, after a certain period of time) and a sensory test (stickiness, moist feeling) were performed using each composition.
  • ⁇ Preparation of powdery pest repellent composition First, a mixture of a pest repellent and a stimulant mitigant was prepared, and this mixture was absorbed into an oil absorbent. Further, a water retaining agent was further added and thoroughly mixed to obtain powdery pest repellent compositions according to Examples 1 to 11 and Comparative Examples 1 to 3. Table 1 shows the composition (unit: parts by weight) of the pest repellent, the stimulus mitigating agent, the water retention agent, and the oil absorbent in each of the examples and comparative examples.
  • ⁇ Pest repellent effect confirmation test 20 female adult mosquitoes were released into a box having an opening that can be sealed, and the powdery pest repellent compositions (2 g each) according to Examples 1 to 11 and Comparative Examples 1 to 3 were applied to the box from the opening. One arm of each subject was inserted, and the number (n 1 ) of the squid that adhered to one arm of the subject was counted. In addition, as a blank, one arm of a subject who did not apply the powdery pest repellent composition was inserted into a box under the same conditions, and the number (n 0 ) of the squid that adhered to the one arm of the subject was counted in the same manner.
  • the repellent rate of Culex pipiens was calculated as (n 0 -n 1 ) / n 0 [%].
  • the repellent rate was calculated immediately after the start of use of the powdery pest repellent composition (immediately after the start of the test) and 4 hours after the start of use.
  • Table 2 shows the results of the insect pest repellent effect confirmation test.
  • the powdery pest repellent compositions according to Examples 1 to 11 are highly evaluated in terms of both “stickiness” and “moistness” as a whole (ie, less sticky feeling, However, the powdery insect pest repellent compositions according to Comparative Examples 1 to 3 cannot achieve both “stickiness” and “moistness”, and the evaluation points themselves are low. It was.
  • the powdery pest repellent composition of the present invention has excellent usability and sustainability, and does not contain any alcohol, so it is useful as a pest repellent product that is easy to use even for people who are sensitive to irritation. Became clear.
  • the powdery pest repellent composition of the present invention can be used as a pest repellent product for humans and pets.
  • Other uses include, for example, insecticidal, acaricidal, bactericidal, antibacterial, deodorizing, and deodorizing. It is also possible to use it for purposes.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Toxicology (AREA)
  • Insects & Arthropods (AREA)
  • Birds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicinal Preparation (AREA)

Abstract

En identifiant un répulsif pour lutter contre les insectes nuisibles sous la forme d'un produit pulvérulent, la présente invention concerne une composition répulsive pulvérulente sans alcool pour lutter contre les insectes nuisibles qui possède un excellent effet répulsif contre les insectes nuisibles et qui est très sûre pour les êtres humains et les animaux et qui, par ailleurs, donne une bonne satisfaction d'utilisation et présente une longue persistance. La composition répulsive pulvérulente pour lutter contre les insectes nuisibles comprend un répulsif d'insectes nuisibles comprenant, comme principe actif, au moins un élément sélectionné dans le groupe constitué du DEET, du 3-(N-N-butyl-N-acétyl)aminopropionate d'éthyle et de l'icaridine, un agent atténuateur d'irritation comprenant un solvant de type glycol comme principe actif, un agent rétenteur d'humidité comprenant du talc comme principe actif et un absorbant d'huile comprenant un composé d'acide silicique comme principe actif, le rapport (a/b) en poids de la teneur (a) de l'agent rétenteur d'humidité à la teneur (b) de l'absorbant d'huile est de 3/1 à 20/1.
PCT/JP2016/084905 2015-11-30 2016-11-25 Composition répulsive pulvérulente pour lutter contre les insectes nuisibles et son procédé de fabrication WO2017094600A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201680064957.XA CN108347930A (zh) 2015-11-30 2016-11-25 粉末状驱虫组合物及其制造方法
JP2017553814A JP6449484B2 (ja) 2015-11-30 2016-11-25 パウダー状害虫忌避組成物、及びその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015232906 2015-11-30
JP2015-232906 2015-11-30

Publications (1)

Publication Number Publication Date
WO2017094600A1 true WO2017094600A1 (fr) 2017-06-08

Family

ID=58796654

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2016/084905 WO2017094600A1 (fr) 2015-11-30 2016-11-25 Composition répulsive pulvérulente pour lutter contre les insectes nuisibles et son procédé de fabrication

Country Status (4)

Country Link
JP (1) JP6449484B2 (fr)
CN (1) CN108347930A (fr)
TW (1) TWI662895B (fr)
WO (1) WO2017094600A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3738993A1 (fr) 2019-05-10 2020-11-18 Henkel AG & Co. KGaA Libération retardée d'un composé insectifuge
DE102020132182A1 (de) 2020-12-03 2022-06-09 Henkel Ag & Co. Kgaa Verwendung von hydrazonen als insektenabwehrmittel

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019198505A1 (fr) * 2018-04-09 2019-10-17 大日本除蟲菊株式会社 Répulsif pour insectes nuisibles et produit repoussant les insectes nuisibles
JP7198290B2 (ja) * 2018-12-26 2022-12-28 大日本除蟲菊株式会社 消臭組成物、及び消臭方法、並びに悪臭害虫防除用組成物、及び悪臭害虫防除方法
LT3763212T (lt) * 2019-07-11 2021-12-27 Sanderstrothmann Gmbh Nariuotakojų repelentinė kompozicija

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53142528A (en) * 1977-05-19 1978-12-12 Kao Corp Repellant for noxious insect
JP2007063185A (ja) * 2005-08-31 2007-03-15 Dainippon Jochugiku Co Ltd パウダー状害虫忌避組成物
JP2009126804A (ja) * 2007-11-21 2009-06-11 Dainippon Jochugiku Co Ltd 人体用害虫忌避剤
JP2014012104A (ja) * 2012-07-05 2014-01-23 Ginza Rosso:Kk 泡立て方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11302102A (ja) * 1998-04-23 1999-11-02 Dainippon Jochugiku Co Ltd 害虫忌避組成物
JP4340015B2 (ja) * 2000-01-17 2009-10-07 アース製薬株式会社 害虫忌避剤
CN102808361B (zh) * 2011-06-02 2015-07-15 金红叶纸业集团有限公司 具有驱蚊功能的生活用纸及其制造方法
JP2014001204A (ja) * 2012-05-23 2014-01-09 Kumamoto Univ 腫瘍細胞選択的抗がん剤
CN108130225B (zh) * 2016-12-01 2020-09-15 广州蓝月亮实业有限公司 一种清洁组合物、清洁剂及其制备方法和应用

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53142528A (en) * 1977-05-19 1978-12-12 Kao Corp Repellant for noxious insect
JP2007063185A (ja) * 2005-08-31 2007-03-15 Dainippon Jochugiku Co Ltd パウダー状害虫忌避組成物
JP2009126804A (ja) * 2007-11-21 2009-06-11 Dainippon Jochugiku Co Ltd 人体用害虫忌避剤
JP2014012104A (ja) * 2012-07-05 2014-01-23 Ginza Rosso:Kk 泡立て方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"MS-T Han'yo Talc Series (Kosu Mitsudo Talc", 13 April 2009 (2009-04-13), Retrieved from the Internet <URL:https://www.ipros.jp/product/detail/print/?objectId=121914&hub=45+google> [retrieved on 20161221] *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3738993A1 (fr) 2019-05-10 2020-11-18 Henkel AG & Co. KGaA Libération retardée d'un composé insectifuge
DE102020132182A1 (de) 2020-12-03 2022-06-09 Henkel Ag & Co. Kgaa Verwendung von hydrazonen als insektenabwehrmittel

Also Published As

Publication number Publication date
JPWO2017094600A1 (ja) 2018-06-21
TW201720301A (zh) 2017-06-16
TWI662895B (zh) 2019-06-21
CN108347930A (zh) 2018-07-31
JP6449484B2 (ja) 2019-01-09

Similar Documents

Publication Publication Date Title
JP6449484B2 (ja) パウダー状害虫忌避組成物、及びその製造方法
US6258857B1 (en) Internal liquid composition contained as internal liquid in a releasing container and releasing container product
EP1745772B1 (fr) Insectifuges avec action fortifiée
US20050255065A1 (en) Aluminium and hexamethylenetetramine complex and the applications thereof
DE102006040535A1 (de) Aerosolzubereitung umfassend Peloide
JP2009001501A (ja) 人体用害虫忌避剤
DE2354476A1 (de) Desodorans
JP2899885B2 (ja) 消臭剤
WO2023136347A1 (fr) Répulsif pour animaux nuisibles destiné à être utilisé sur le corps humain
JP2000053923A (ja) 殺ダニ効果を持つ床用艶出し剤
JP5071953B2 (ja) パウダー状害虫忌避組成物
DE1492006C3 (de) Aus Druckzerstäuberdose aussprühbares Mittel zur Pflege und Behandlung von behaarten Tieren
JP2000281511A (ja) 殺ダニ剤及び殺ダニスプレー
JP6214135B2 (ja) 人体用害虫忌避エアゾール剤、及びこれを用いた害虫忌避並びに冷感の付与方法。
EP4185113A1 (fr) Agent désinfectant, toléré par la peau, nourrissant et relipidant, destiné à être appliqué sur la peau
JP3405833B2 (ja) 人体用害虫忌避組成物
JP4868743B2 (ja) 人体用害虫忌避エアゾール
EP1997380B1 (fr) Insectifuge et parfum
JPH01245058A (ja) 樹脂組成物
JP2000281509A (ja) 蒸散性殺ダニ剤
DE10239101B4 (de) Pflaster zur Verabreichung von Deodorantien
JP4145986B2 (ja) 害虫忌避組成物
DE10303553B4 (de) Antitranspiranter Wirkstoff und dessen Verwendung
JPH0978057A (ja) エアゾール組成物及びその製造方法、並びにそれを用いたエアゾール製品
JPH11302102A (ja) 害虫忌避組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16870537

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2017553814

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16870537

Country of ref document: EP

Kind code of ref document: A1