WO2016104236A1 - ポリフェニレンサルファイドモノフィラメントおよびその製造方法、ならびにパッケージ - Google Patents
ポリフェニレンサルファイドモノフィラメントおよびその製造方法、ならびにパッケージ Download PDFInfo
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- WO2016104236A1 WO2016104236A1 PCT/JP2015/085014 JP2015085014W WO2016104236A1 WO 2016104236 A1 WO2016104236 A1 WO 2016104236A1 JP 2015085014 W JP2015085014 W JP 2015085014W WO 2016104236 A1 WO2016104236 A1 WO 2016104236A1
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- variation
- monofilament
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- polyphenylene sulfide
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/76—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products
- D01F6/765—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products from polyarylene sulfides
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/76—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D7/00—Collecting the newly-spun products
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
Definitions
- the present invention relates to a polyphenylene sulfide (hereinafter abbreviated as PPS) monofilament and its package, and more particularly to a PPS monofilament suitable for high precision filter applications.
- PPS polyphenylene sulfide
- PPS is widely used as a metal substitute material and a material that can withstand extreme environments because it is excellent in heat resistance, chemical resistance, electrical insulation, etc., and has excellent mechanical strength and moldability.
- PPS fibers have also been proposed to be used for industrial materials such as filters, brush bristle materials, paper-making dryer canvases, and electrical insulating papers by utilizing these characteristics.
- Patent Document 1 proposes a method for stably producing PPS fibers with few fineness spots.
- Patent Document 2 proposes a method in which a multifilament is once manufactured and then separated in order to manufacture a monofilament with high productivity and low cost.
- the entanglement process in the multifilament manufacturing process performs stretching and heat setting in a state where the single yarns are entangled with each other.
- fineness spots in the fiber axis direction are generated, and it is difficult to obtain a uniform monofilament.
- Patent Document 3 proposes a method in which a small amount of polyalkylene terephthalate is added in order to obtain a PPS monofilament with good dimensional stability.
- this method since polyalkylene terephthalate is added, heat resistance and chemical resistance are deteriorated, and the uniformity of physical properties in the longitudinal direction is lost due to blend spots, so that it cannot be applied to a high-precision filter. was there.
- Patent Document 4 proposes a PPS monofilament excellent in fineness uniformity for the purpose of improving filter performance.
- a filter with a certain degree of accuracy
- it has been found that it is not possible to cope with the high precision of filters that have increased dramatically in recent years. This is because in order to increase the precision of the filter, it is necessary to suppress tension variation during filter weaving, and no solution has been suggested for this point.
- a PPS monofilament suitable for a high precision filter having an extremely small aperture variation rate has not been obtained so far, and a PPS monofilament suitable for a high precision filter is strongly desired.
- An object of the present invention is to provide a PPS monofilament that is most suitable for a high-precision filter having a very small aperture fluctuation rate.
- the present invention takes the following forms.
- the PPS used in the present invention has a basic repeating structural unit composed of p-phenylene sulfide.
- Other copolymer structural units may be contained.
- the copolymer structural unit include aromatic sulfides such as m-phenylene sulfide and biphenylene sulfide, alkyl substitution products thereof, halogen substitution products, and the like.
- other polymers may be added by mixed spinning or composite spinning. Examples of other polymers include polyester, polyamide, polyolefin, and polyimide.
- the copolymer component amount and polymer addition amount are preferably 3 wt% or less. Within this range, good heat resistance and chemical resistance can be maintained. More preferably, it is 1 wt% or less, and more preferably not added.
- additives such as an antioxidant, a heat-resistant agent, a heat deterioration preventing agent and a weathering agent can be added.
- the amount added is preferably 1 wt% or less. By setting it to 1 wt% or less, good spinnability can be obtained. A more preferable range is 0.5 wt% or less.
- PPS polymerized by a quench method with a small amount of low molecular weight as the PPS used in the present invention.
- a polymer having a small amount of low molecular weight it is possible to suppress the base stain during spinning, and to stably obtain the PPS monofilament of the present invention.
- Continuous thermal shrinkage stress in the fiber axis direction is a continuous measurement in the fiber axis direction of the shrinkage stress that occurs when heat treatment is performed while running the fiber. It is obtained by running a yarn in between, performing dry heat treatment between the rollers, and continuously measuring the contraction stress (cN) with a tension measuring device installed behind the rollers. The variation is obtained by dividing the standard deviation of the continuous heat shrinkage stress by the average value. Specifically, the measurement frequency is 6 times per 1 cm, 1000 data is collected with the average value as 1 data, and the average value and the standard deviation are calculated from the obtained 1000 data. Used to calculate continuous heat shrinkage stress variation. The average value and the standard deviation are automatically calculated by using “continuous heat shrinkage measuring instrument FTA-500” manufactured by Toray Engineering.
- One preferable means for reducing the continuous heat shrinkage stress variation in the fiber axis direction to 5% or less is to suppress stretching tension variation in the stretching step.
- the variation of the die surface temperature is preferably 3 ° C. or less, and more preferably 1.5 ° C. or less.
- the variation in the base surface temperature is the difference between the maximum temperature and the minimum temperature of a total of five points of any 4 points 5 mm from the center of the base and the outermost periphery of the base. It has been clarified by intensive investigation that the temperature of the die surface is 3 ° C. or less, the polymer temperature to be discharged becomes uniform, the discharge and cooling are stable, and the stretching tension in the subsequent stretching process is stabilized.
- a method of suppressing the variation in the base surface temperature a method of keeping the temperature below the base surface with a heater may be mentioned.
- the temperature of the sub-surface heater is preferably in the range of spinning temperature ⁇ 20 ° C, more preferably in the range of spinning temperature ⁇ 10 ° C.
- the fineness uniformity of the PPS monofilament is expressed by Wooster spots (U% Nomal value), and U% for obtaining a very high precision filter as a problem is 1.2% or less, preferably 1.0% or less, more preferably 0. .9% or less.
- the lower limit is 0% or more.
- the cooling process of the polymer discharged from the die is extremely important.
- Cooling with a gas has a lower resistance to the polymer than cooling with a liquid, and is advantageous in ensuring fineness uniformity.
- the temperature of the cooling air is preferably 5 ° C. or higher and 20 ° C. or lower, more preferably 5 ° C. or higher and 10 ° C. or lower.
- the cooling start distance is preferably 100 mm or less, more preferably 80 mm or less from the die surface. By setting the cooling start distance to 100 mm or less, the solidification point of the polymer discharged from the die is stabilized, leading to improvement in fineness uniformity.
- the winding shape of the PPS monofilament is also extremely important, and the package is preferably a drum shape.
- the drum shape By adopting the drum shape, it is possible to suppress a sink-like defect called “Pernbique” that occurs in the Pann shape.
- the fineness of the PPS monofilament of the present invention is preferably 6 to 33 dtex, more preferably 6 to 22 dtex. By setting it to 6 to 33 dtex, pressure loss due to filtration can be suppressed when the density of the filter is increased.
- the strength of the PPS monofilament of the present invention is preferably 3.0 cN / dtex or more, and more preferably 3.5 cN / dtex or more. By setting the strength to 3.0 cN / dtex or more, the durability of the filter can be improved.
- the hot water dimensional change rate of the PPS monofilament of the present invention is preferably 10% or less, more preferably 6% or less.
- the hot water dimensional change rate is preferably 10% or less, more preferably 6% or less.
- the PPS monofilament production method of the present invention preferably uses a one-step method in which the monofilament is directly spun.
- the one-step method it is possible to suppress stretching tension variation that affects continuous heat shrinkage stress variation. Productivity is also greatly improved.
- a method for producing the PPS monofilament of the present invention there is a method of obtaining a monofilament through a splitting step after obtaining a multifilament once. It is preferable to use a one-step method in which a monofilament is directly spun.
- the PPS resin used in the present invention is as described above.
- the PPS resin used for spinning is preferably 0.15 wt% or less, more preferably 0.1 wt% or less, using a dryer.
- melt spinning known methods can be used for melt extrusion of the PPS resin.
- the extruded polymer is measured by a known measuring device such as a gear pump via a pipe, and after passing through a filter for removing foreign matter, it is guided to a die.
- the polymer temperature at this time is preferably 300 to 330 ° C, more preferably 310 to 320 ° C.
- the hole diameter D of the die hole is preferably set to 0.10 mm or more and 0.50 mm or less, and the land length L of the die hole (the straight pipe having the same diameter as the die hole) L / D divided by the hole diameter D is preferably 1.0 or more and 8.0 or less. Further, the number of holes per die is preferably 4 or more from the viewpoint of productivity, and 8 or less from the viewpoint of yarn cooling.
- the base surface temperature and the cooling of the yarn discharged from the base are as described above.
- the cooled and solidified yarn is taken up by the heated first roller and continuously stretched between the first roller and the second roller as described above.
- a one-sided type, a separate roller type, and a Nelson type can be used, but it is preferable to use a Nelson type from the viewpoint of stability of yarn heating and speed fixing.
- the take-up speed of the first roller is preferably 300 to 1000 m / min, more preferably 400 to 800 m / min.
- the heating temperature of the first roller is preferably a glass transition temperature of the polymer of ⁇ 10 ° C. or higher and Tg + 20 ° C. or lower. By setting it as this range, it will become extending
- the heating temperature of the second roller is preferably 140 ° C. or higher and 250 ° C. or lower. By setting the temperature to 140 ° C. or higher, the strength and dimensional stability can be improved.
- the package shape is preferably a drum shape as described above.
- the PPS monofilament thus obtained is warped by a warping machine so as to have a desired opening, and after being driven in by a rapier loom or a water jet loom, it is cut into an arbitrary shape and becomes a filter.
- this filter it is used as, for example, an injection filter of an automobile engine or a filter in a medical field.
- Opening fluctuation rate Warp the PPS monofilament to 380 pieces / inch (2.54 cm) with a warping machine, and 380 pieces / inch (2.54 cm) with a rapier loom (the opening is square) Weaving so that This trial fabric was observed with a scanning electron microscope (Nikon ESEM-2700) at a magnification of 1000 times, and the distance between fibers at any 20 openings (the widest part of each opening) Each was measured on the order of 0.1 ⁇ m.
- Example 1 E2280 (glass transition point; 93 ° C., quenching method) manufactured by Toray Industries, Inc. was used as the PPS polymer pellet, and the pellet with the low molecular weight adjusted to 0.1% or less with a dryer was spin temperature of 320 ° C., single pore Melt spinning was performed at a discharge rate of 4.25 g / min. The polymer temperature at that time was 313 ° C.
- the spinning machine a one-step direct drawing spinning machine shown in FIG. 1 was used. For spinning, a round hole mouthpiece (1) having 8 holes, a hole diameter (D) of the mouthpiece hole of 0.40 mm, and an L / D of 6.0 is used. The base surface temperature variation was 0.8 ° C.
- the polymer discharged from the die is 50 mm from the die surface, cooled by a cooling air blowing device (5) from a cooling air blowing device (5), and supplied by a lubricating roller (7), and then heated to 100 ° C.
- the film was drawn at 625 m / min and stretched 4.00 times between the second rollers (9) continuously heated to 200 ° C.
- the stretching tension variation at this time was 11.5%.
- the drawn yarn was wound on a drum-shaped fiber package (11) using a microcam traverse type winder (10) as it was, and then woven by a rapier loom.
- Table 1 shows the raw yarn characteristics of the obtained PPS monofilament and the results of weaving evaluation (opening fluctuation rate).
- Example 2 A PPS monofilament was obtained in the same manner as in Example 1 except that the heat retaining method of the base surface was changed from heated steam to air heating. Table 1 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilaments thus obtained.
- the base surface temperature variation was slightly increased to 1.3 ° C., but the stretching tension variation was 13.8%, and the continuous heat shrink stress variation was 2.9%. , U% was 0.85%. Further, a good woven fabric having an opening variation rate of 1.8% was obtained.
- Example 3 A PPS monofilament was obtained in the same manner as in Example 2 except that the cooling air temperature was 5 ° C. Table 1 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilaments thus obtained.
- Example 4 A PPS monofilament was obtained in the same manner as in Example 2 except that the cooling start distance was 100 mm. Table 1 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilaments thus obtained.
- Example 1 A PPS monofilament was obtained in the same manner as in Example 1 except that the temperature at the base surface was 290 ° C. Table 2 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilament thus obtained.
- Example 2 A PPS monofilament was obtained in the same manner as in Example 1 except that the cooling start distance was 15 mm. Table 2 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilament thus obtained.
- Example 3 A PPS monofilament was obtained in the same manner as in Example 1 except that the cooling start distance was 200 mm. Table 2 shows the raw yarn characteristics and weaving evaluation results of the PPS monofilament thus obtained.
- E2280 manufactured by Toray Industries, Inc. was used as a PPS polymer pellet, and a pellet whose low boiling point was adjusted to 1.0% or less with a dryer was melt-spun at a spinning temperature of 320 ° C. and a single-hole discharge rate of 4.25 g / min. .
- a round hole die having 8 holes, the diameter (D) of the die hole being 0.4 mm, and L / D being 6 is used, and the die surface is kept warm by heating steam at 330 ° C.
- the variation in surface temperature was 0.9 ° C.
- the polymer discharged from the die was cooled by cooling air of 10 ° C. at 50 mm from the die surface, and after refueling, the polymer was taken up by a non-heated first roller rotating at a constant speed of 625 m / min to obtain an undrawn yarn.
- the undrawn yarn was drawn 4.00 times between a first roller heated to 100 ° C. and a second roll heated to 200 ° C. with a drawing machine.
- the stretching tension variation at this time was 24.5%.
- the drawn yarn was wound around a fiber package having a pan shape and then woven with a rapier loom.
- Table 2 shows the yarn characteristics and weaving evaluation results of the obtained PPS monofilament.
- Table 2 shows the raw yarn characteristics and weaving evaluation results of the obtained PPS monofilament (split yarn).
- the fiber splitting machine there are many guides in the process until winding up as a PPS monofilament (split yarn), and the yarn is easily scratched during the process, and the continuous heat shrinkage stress variation of the split yarn is 6. 1%. Further, during the multifilament manufacturing process, heat setting is performed in a state of being entangled by the entanglement process, so that the heat setting tends to be uneven among the single yarns, and the U% of the split yarn is 1.53%. Further, the opening fluctuation rate was 6.5%, and furthermore, by using a panic shape, sink-like spots were generated and the quality of the fabric was lowered, and a satisfactory fabric could not be obtained.
- the PPS monofilaments obtained in the examples of the present invention have a fineness uniformity (U%), small variation in continuous heat shrinkage stress, and can obtain a woven fabric with a very small opening variation rate. A high-precision filter can be obtained.
- the PPS monofilament obtained in the comparative example could not reduce both fineness uniformity (U%) and continuous heat shrinkage stress variation, and a high-precision filter could not be obtained.
- the extremely high-precision filter produced by using the PPS monofilament obtained by the present invention is suitably used in the production site of chemical, electrical / electronic, automobile, food, precision equipment, medicine / medical and the like.
- Base 2 Heating steam generator 3: Heater under base 4: Cooling air 5: Cooling air blowing device 6: Thread 7: Oil supply roller 8: First roller 9: Second roller 10: Winder 11: Package
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Abstract
Description
(1)繊維軸方向の連続熱収縮応力バラツキが5%以下、繊度均一性(U% Nomal値)が1.2%以下であるポリフェニレンサルファイドモノフィラメント。
(2)上記(1)記載のポリフェニレンサルファイドモノフィラメントが巻き取られたドラム形状のパッケージ。
(3)ポリフェニレンサルファイド樹脂を溶融し、紡糸口金から吐出した各フィラメントを冷却装置で冷却後、油剤を付与し、加熱された引取ローラーで引き取り、引取ローラーと加熱延伸ローラーとの間で延伸し、ドラム状に巻き取る製造方法において、(a)紡糸口金面の中心部と外周部の温度バラツキを3℃以下とし、(b)紡糸口金から100mm以下の距離で、5℃以上20℃以下の冷却風で各フィラメントを冷却することを特徴とするポリフェニレンサルファイドモノフィラメントの製造方法。
(連続熱収縮応力バラツキ)=(標準偏差)/(平均値)×100
本発明では、この繊維軸方向の連続熱収縮応力バラツキがフィルター製織時の張力バラツキに影響していることを見出した。連続熱収縮応力が安定していれば、製織時の張力バラツキは小さくなり、高精密なフィルターを得ることができる。このために必要な連続熱収縮応力バラツキは5%以下であり、3%以下がより好ましい。下限値は0%以上である。
また第1ローラーの加熱温度はポリマーのガラス転移温度-10℃以上、Tg+20℃以下であることが好ましい。この範囲とすることで、PPSの流動性が十分な状態での延伸となり、延伸張力のバラツキを抑制することができる。
整経機にてPPSモノフィラメントを380本/インチ(2.54cm)となるように整経し、レピア織機にて380本/インチ(2.54cm)(開口部が正方形となるように)となるように製織した。この試織反を走査型電子顕微鏡(Nikon社製ESEM-2700)により倍率1000倍で観察し、任意の20ヶ所の各開口部の繊維間距離(各開口部の中で最も距離の広い部分をそれぞれ測定)を0.1μmオーダーで測定した。開口変動率は次式で算出した。
(開口変動率)=(標準偏差)/(平均値)×100
なお、開口変動率は高精密なフィルターの指標である3%以下を合格とした。
連続熱収縮応力の測定には、東レエンジニアリング社製「連続熱収縮測定器 FTA-500」を用いた。測定方法は、糸給糸ローラーと糸引き出しローラーのローラー間に5m/minで糸条を走行させ、このローラー間で乾熱処理を施し(温度:100℃、ユニット長:10cm)、熱による応力(cN)をその後方にある張力測定器で連続的に測定した。測定頻度は1cm当たり6回とし、その平均値を1データとして1000個のデータを採取する。得られた1000個のデータから、平均値、標準偏差を算出し、次式を用いて連続熱収縮応力バラツキを算出する。平均値、標準偏差は該測定器により自動で計算される)
(連続熱収縮応力バラツキ)=(標準偏差)/(平均値)×100 。
Zellweger Uster社製、USTER TESTER 5を用いて、給糸速度800m/min、測定タイプNomalモード、使用スロットルAUTO、ツイスターなしで1分間測定し、得られた値をウースター斑(U%)とした。
熱電対を用いて、口金中心部と口金最外周から5mmの任意の4点の合計5点の温度を測定。最高温度と最低温度の差を口金面温度バラツキとした。
東レエンジニアリング製TTM-101張力計を用いて、第1、第2ローラー間で第2ローラーから約20cmの箇所の延伸張力を1分間測定し、0.1秒間隔で値を抽出、標準偏差と平均値を算出し、次式より算出した。
(延伸張力バラツキ)=(標準偏差)/(平均値)×100 。
JIS L 1013(2010)8.3.1 A法に準じて算出した。
JIS L 1013(2010)8.5.1に準じて測定した。
JIS L 1013(2010)8.18.1 A法に準じて測定した。
PPSポリマーペレットとして東レ(株)製E2280(ガラス転移点;93℃、クエンチ法)を用い、乾燥機にて低分子量物を0.1%以下に調整したペレットを、紡糸温度320℃、単孔吐出量4.25g/minで溶融紡糸した。その際のポリマー温度は313℃であった。紡糸機は、図1に示す1工程法の直接延伸紡糸機を用いた。紡糸には孔数8個、口金孔の孔径(D)が0.40mm、L/Dが6.0の丸孔の口金(1)を使用し、その際、口金面は330℃の加熱蒸気にて保温し、口金面温度のバラツキは0.8℃であった。口金から吐出したポリマーは口金面より50mmで、冷却風吹き出し装置(5)から10℃の冷却風(4)により冷却し、給油ローラー(7)で給油後、100℃に加熱した第1ローラー(8)にて、625m/minで引き取り、連続して200℃に加熱した第2ローラー(9)間で4.00倍に延伸を行った。この際の延伸張力バラツキは11.5%であった。延伸後の糸条は、そのままマイクロカムトラバース型の巻取り機(10)を用いてドラム形状の繊維パッケージ(11)に巻き取った後、レピア織機により製織した。
口金面の保温方法を加熱蒸気から空気加熱とすること以外は実施例1と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表1に示す。
冷却風温度を5℃とすること以外は実施例2と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表1に示す。
冷却開始距離を100mmとすること以外は実施例2と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表1に示す。
口金面の保温温度を290℃とすること以外は実施例1と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表2に示す。
冷却開始距離を15mmとすること以外は実施例1と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表2に示す。
冷却開始距離を200mmとすること以外は実施例1と同様の方法でPPSモノフィラメントを得た。こうして得られたPPSモノフィラメントの原糸特性と製織評価結果を表2に示す。
PPSポリマーペレットとして東レ(株)製E2280を用い、乾燥機にて低沸点物を1.0%以下に調整したペレットを、紡糸温度320℃、単孔吐出量4.25g/minで溶融紡糸した。紡糸には孔数8個、口金孔の孔径(D)が0.4mm、L/Dが6の丸孔の口金を使用し、その際、口金面は330℃の加熱蒸気により保温し、口金面温度のバラツキは0.9℃であった。口金から吐出したポリマーは口金面より50mmで10℃の冷却風により冷却し、給油後、625m/minで一定回転する非加熱の第1ローラーで引き取り、未延伸糸を得た。
ポリマーの冷却後、8本の糸条を1本に収束させて、給油、延伸、巻取りを行うこと以外は実施例1と同様の方法でPPSマルチフィラメントを得た。その際、口金面温度のバラツキは1.0℃、延伸張力バラツキは12.0%と実施例1と比較してやや大きかった。こうして得られたPPSマルチフィラメントを分繊機で分繊した。分繊後の糸条は、パーン形状の繊維パッケージに巻き取った後、レピア織機により製織した。
2:加熱蒸気発生装置
3:口金下ヒーター
4:冷却風
5:冷却風吹き出し装置
6:糸条
7:給油ローラー
8:第1ローラー
9:第2ローラー
10:巻取り機
11:パッケージ
Claims (3)
- 繊維軸方向の連続熱収縮応力バラツキが5%以下、繊度均一性(U% Nomal値)が1.2%以下であるポリフェニレンサルファイドモノフィラメント。
- 請求項1に記載のポリフェニレンサルファイドモノフィラメントが巻き取られたドラム形状のパッケージ。
- ポリフェニレンサルファイド樹脂を溶融し、紡糸口金から吐出した各フィラメントを冷却装置で冷却後、油剤を付与し、加熱された引取ローラーで引き取り、引取ローラーと加熱延伸ローラーとの間で延伸し、ドラム状に巻き取る製造方法において、(a)紡糸口金面の中心部と外周部の温度バラツキを3℃以下とし、(b)紡糸口金から100mm以下の距離で、5℃以上20℃以下の冷却風で各フィラメントを冷却することを特徴とするポリフェニレンサルファイドモノフィラメントの製造方法。
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Cited By (5)
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---|---|---|---|---|
CN108774752A (zh) * | 2018-08-17 | 2018-11-09 | 安徽和邦纺织科技有限公司 | 一种用于纺丝机的均风装置 |
KR102183246B1 (ko) * | 2019-06-27 | 2020-11-26 | 주식회사 휴비스 | 폴리페닐렌 설파이드 복합 멀티필라멘트 및 그의 제조방법 |
JP2021055212A (ja) * | 2019-09-30 | 2021-04-08 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントとその製造方法及びそのパッケージ |
JP2021161572A (ja) * | 2020-03-31 | 2021-10-11 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントからなる繊維パッケージ及びその製造方法 |
WO2022211116A1 (ja) | 2021-03-31 | 2022-10-06 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントとその製造方法及び繊維パッケージ |
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KR101973771B1 (ko) * | 2017-12-27 | 2019-04-30 | 주식회사 휴비스 | 폴리페닐렌 설파이드 필라멘트 섬유 제조방법 및 이에 의한 섬유 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5160721A (en) * | 1974-11-21 | 1976-05-26 | Toray Industries | Goseisenino yojuboshihoho |
JPH01239109A (ja) * | 1988-03-15 | 1989-09-25 | Teijin Ltd | ポリフェニレンサルファイド繊維、その製造法及び該繊維の仮撚加工糸 |
JPH0649707A (ja) * | 1992-06-01 | 1994-02-22 | Toray Ind Inc | 液晶形成性ポリエステルの溶融紡糸方法 |
JPH08269832A (ja) * | 1995-03-31 | 1996-10-15 | Toray Ind Inc | 異繊度低収縮ポリエステル混繊糸 |
JP2000178829A (ja) * | 1998-12-15 | 2000-06-27 | Toyobo Co Ltd | ポリフェニレンサルファイド繊維及びその製造方法 |
JP2003253521A (ja) * | 2002-03-04 | 2003-09-10 | Toyobo Co Ltd | 紡糸口金及びこれを用いた合成繊維の製造方法 |
JP2006257619A (ja) * | 2005-02-16 | 2006-09-28 | Toray Ind Inc | ポリフェニレンスルフィド・ナノファイバーから成る乾式不織布 |
JP2012136797A (ja) * | 2010-12-27 | 2012-07-19 | Toray Ind Inc | ポリフェニレンサルファイド繊維の製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1060734A (ja) | 1996-08-14 | 1998-03-03 | Toray Ind Inc | ポリフェニレンサルファイド繊維の製造方法 |
JP2002038330A (ja) * | 2000-07-27 | 2002-02-06 | Toray Ind Inc | スクリーン紗用ポリエステルモノフィラメントの製造方法 |
JP4844515B2 (ja) * | 2007-09-14 | 2011-12-28 | 東レ株式会社 | 細繊度ポリフェニレンスルフィドモノフィラメントおよびその製造方法 |
JP5251490B2 (ja) * | 2008-01-09 | 2013-07-31 | 東レ株式会社 | ポリフェニレンサルファイド繊維およびその製造方法 |
JP2011106060A (ja) | 2009-11-18 | 2011-06-02 | Toray Ind Inc | ポリアリーレンスルフィド繊維 |
JP2013133576A (ja) * | 2011-12-27 | 2013-07-08 | Toray Ind Inc | 液晶ポリエステルマルチフィラメント |
-
2015
- 2015-12-15 KR KR1020177009807A patent/KR20170100480A/ko unknown
- 2015-12-15 US US15/536,264 patent/US10106917B2/en not_active Expired - Fee Related
- 2015-12-15 EP EP15872805.5A patent/EP3239366B1/en active Active
- 2015-12-15 JP JP2016501263A patent/JPWO2016104236A1/ja active Pending
- 2015-12-15 WO PCT/JP2015/085014 patent/WO2016104236A1/ja active Application Filing
- 2015-12-15 CN CN201580058403.4A patent/CN107075743B/zh active Active
- 2015-12-21 TW TW104142963A patent/TW201630649A/zh unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5160721A (en) * | 1974-11-21 | 1976-05-26 | Toray Industries | Goseisenino yojuboshihoho |
JPH01239109A (ja) * | 1988-03-15 | 1989-09-25 | Teijin Ltd | ポリフェニレンサルファイド繊維、その製造法及び該繊維の仮撚加工糸 |
JPH0649707A (ja) * | 1992-06-01 | 1994-02-22 | Toray Ind Inc | 液晶形成性ポリエステルの溶融紡糸方法 |
JPH08269832A (ja) * | 1995-03-31 | 1996-10-15 | Toray Ind Inc | 異繊度低収縮ポリエステル混繊糸 |
JP2000178829A (ja) * | 1998-12-15 | 2000-06-27 | Toyobo Co Ltd | ポリフェニレンサルファイド繊維及びその製造方法 |
JP2003253521A (ja) * | 2002-03-04 | 2003-09-10 | Toyobo Co Ltd | 紡糸口金及びこれを用いた合成繊維の製造方法 |
JP2006257619A (ja) * | 2005-02-16 | 2006-09-28 | Toray Ind Inc | ポリフェニレンスルフィド・ナノファイバーから成る乾式不織布 |
JP2012136797A (ja) * | 2010-12-27 | 2012-07-19 | Toray Ind Inc | ポリフェニレンサルファイド繊維の製造方法 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108774752A (zh) * | 2018-08-17 | 2018-11-09 | 安徽和邦纺织科技有限公司 | 一种用于纺丝机的均风装置 |
KR102183246B1 (ko) * | 2019-06-27 | 2020-11-26 | 주식회사 휴비스 | 폴리페닐렌 설파이드 복합 멀티필라멘트 및 그의 제조방법 |
JP2021055212A (ja) * | 2019-09-30 | 2021-04-08 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントとその製造方法及びそのパッケージ |
JP7402648B2 (ja) | 2019-09-30 | 2023-12-21 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントとその製造方法及びそのパッケージ |
JP2021161572A (ja) * | 2020-03-31 | 2021-10-11 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントからなる繊維パッケージ及びその製造方法 |
JP7453832B2 (ja) | 2020-03-31 | 2024-03-21 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントからなる繊維パッケージ及びその製造方法 |
WO2022211116A1 (ja) | 2021-03-31 | 2022-10-06 | Kbセーレン株式会社 | ポリフェニレンスルフィドモノフィラメントとその製造方法及び繊維パッケージ |
CN115413302A (zh) * | 2021-03-31 | 2022-11-29 | Kb世联株式会社 | 聚苯硫醚单丝及其制造方法、以及纤维卷装体 |
KR20220158749A (ko) | 2021-03-31 | 2022-12-01 | 케이비 세렌 가부시키가이샤 | 폴리페닐렌설파이드 모노필라멘트와 그 제조방법 및 섬유 패키지 |
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KR20170100480A (ko) | 2017-09-04 |
JPWO2016104236A1 (ja) | 2017-09-28 |
US20170342600A1 (en) | 2017-11-30 |
CN107075743B (zh) | 2020-06-23 |
CN107075743A (zh) | 2017-08-18 |
EP3239366B1 (en) | 2021-03-17 |
TW201630649A (zh) | 2016-09-01 |
EP3239366A4 (en) | 2018-07-04 |
US10106917B2 (en) | 2018-10-23 |
EP3239366A1 (en) | 2017-11-01 |
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