WO2016090868A1 - 电化学储能装置 - Google Patents
电化学储能装置 Download PDFInfo
- Publication number
- WO2016090868A1 WO2016090868A1 PCT/CN2015/080758 CN2015080758W WO2016090868A1 WO 2016090868 A1 WO2016090868 A1 WO 2016090868A1 CN 2015080758 W CN2015080758 W CN 2015080758W WO 2016090868 A1 WO2016090868 A1 WO 2016090868A1
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- storage device
- energy storage
- electrochemical energy
- adhesive
- battery core
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to the field of electrochemical technology, and in particular to an electrochemical energy storage device.
- Lithium-ion secondary batteries have advantages such as high voltage, small volume, light weight, high specific capacity, no memory effect, no pollution, small self-discharge and long cycle life, making them suitable for communication, electrical appliances, electronic information, power equipment, and
- the application in the field of energy storage has been unprecedentedly developed, and with the rapid development of society, people have put forward higher requirements on the energy density, charge and discharge speed, cycle life and safety performance of lithium ion secondary batteries.
- the drop test is a more stringent safety test for lithium ion secondary batteries.
- Lithium-ion secondary batteries are extremely prone to problems such as top sealing, liquid leakage, wrinkling of the separator, internal short circuit, and pull of the ear.
- the problem of the top seal punching, liquid leakage, and tab tearing is solved by using a tape to bind the battery core or increase the size of the top sealing region, but the energy density of the lithium ion secondary battery is lowered by this method, and The problem of shrinkage, wrinkling, and internal short circuit of the separator which occurs when the lithium ion secondary battery is dropped cannot be solved.
- an object of the present invention is to provide an electrochemical energy storage device capable of achieving a fixed connection between a battery core and a package shell, and solving the occurrence of a drop test.
- Various problems can avoid the problem that the core is difficult to enter due to the viscosity on both sides of the rubber material, and also has good cycle performance and large rate charge and discharge performance.
- the present invention provides an electrochemical energy storage device comprising: a battery core, an electrolyte, and a package.
- the battery core includes a positive electrode sheet, a negative electrode sheet, and a positive electrode sheet, and a negative electrode. a separator between the pole pieces; an electrolyte impregnated cell; the package encloses the cell and contains the electrolyte.
- the electrochemical energy storage device further includes: a glue material between the battery core and the package shell.
- the glue material includes: an adhesive layer and a protective layer.
- the adhesive layer is directly or indirectly bonded on the outer surface of the battery core, and one side away from the battery core is an adhesive surface; the protective layer is disposed on the adhesive surface of the adhesive layer, and the protective layer dissolves or swells wholly or partially Dispersed in the electrolyte to expose the adhesive side of the adhesive layer, and the adhesive layer bonds the cell and the package together.
- the protective layer is a polar molecule containing one or more of -F, -CO-NH-, -NH-CO-NH-, and -NH-CO-O-.
- the adhesive layer of the rubber of the present invention does not adhere to the package before the protective layer is completely or partially dissolved or swelled and dispersed in the electrolyte, thereby preventing the electricity from being sticky on both sides of the rubber.
- the problem of the core being difficult to enter the shell.
- the protective layer of the rubber material of the invention is a polar molecule, and is easy to form a network structure, so that the excess electrolyte in the electrochemical energy storage device can be absorbed to improve the liquid rising phenomenon, and at the same time, after long-term circulation, the electrochemical storage
- the electrolyte in the device can be gradually reduced due to decomposition.
- the electrolyte absorbed by the protective layer is gradually released into the electrochemical energy storage device due to the difference in concentration, so as to improve the long-term cycle performance of the electrochemical energy storage device.
- the protective layer of the rubber material of the present invention can be viscous after being completely or partially dissolved or swelled and dispersed in the electrolyte, and can be separated into the electrochemical energy storage device as the electrolyte diffuses, thereby providing the separator and the pole piece. Bonding prevents the separator from shrinking after the electrochemical energy storage device falls, and at the same time, it can also inhibit the deformation of the pole piece after long-term circulation due to expansion.
- the protective layer of the present invention has a large molecular polarity, which is favorable for ionization of the lithium salt, thereby improving the ion-conducting ability of the electrolyte, and is beneficial to the performance of the large-capacity charge-discharge performance of the electrochemical energy storage device.
- FIG. 1 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with an embodiment of the present invention
- FIG. 2 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with another embodiment of the present invention.
- FIG. 3 is a schematic structural view of an embodiment of a rubber material of an electrochemical energy storage device according to the present invention.
- Fig. 4 is a structural view showing another embodiment of the electrochemical energy storage device according to the present invention, which is schematically exaggerated in section, taken along line A-A of Fig. 1.
- an electrochemical energy storage device comprising: a cell 1, an electrolyte, and a package 2 .
- the battery cell 1 includes a positive electrode sheet, a negative electrode sheet, and a separator interposed between the positive electrode sheet and the negative electrode sheet; the electrolyte is impregnated with the battery core 1; and the package 2 encloses the battery core 1 and houses the electrolyte.
- the electrochemical energy storage device further includes a glue material 3 between the battery core 1 and the package body 2.
- the glue 3 includes an adhesive layer 31 and a protective layer 32.
- the adhesive layer 31 is directly or indirectly bonded on the outer surface of the battery core 1, and one side away from the battery core 1 is an adhesive surface; the protective layer 32 is disposed on the adhesive surface of the adhesive layer 31, and the protective layer 32 is entirely Or partially dissolved or swollen and dispersed in the electrolytic solution to expose the adhesive face of the adhesive layer 31, and the adhesive layer 31 bonds the battery core 1 and the package can 2 together.
- the protective layer 32 is a polar molecule containing one or more of -F, -CO-NH-, -NH-CO-NH-, and -NH-CO-O-.
- the package can be pressed or heated from the outside so that the adhesive layer 31 is made.
- the cell 1 and the package 2 are bonded together.
- the protective layer 32 may be selected from a fluorine-containing polyolefin having polarity, a fluorine-containing polyester having polarity, a fluorine rubber having polarity, a polyamide, and a polyurethane. One or several.
- the polar fluorine-containing polyolefin may be selected from the group consisting of polyvinylidene fluoride (PVDF), polyacrylic acid modified polyvinylidene fluoride, and fluorine-containing polypropylene ( FPP), Vinylidene fluoride and hexafluoropropylene copolymer (fluororubber 26), tetrafluoroethylene and hydropropylene copolymer (fluororubber TP), fluoroolefin-vinyl ether copolymer (FEVE), vinylidene fluoride-tetrafluoroethylene- One or more of a hexafluoropropylene copolymer (VDF-TFE-HEP) and a tetrafluoropropene rubber.
- PVDF polyvinylidene fluoride
- FPP fluorine-containing polypropylene
- FPP fluorine-containing polypropylene
- FPP Vinylidene fluoride and
- the polar fluorine-containing polyester may be selected from the group consisting of fluorine-containing polyurethane, fluorine-containing linear polybutylene isophthalate (FPBI), and fluorine-containing linearity.
- FPBI fluorine-containing linear polybutylene isophthalate
- HBFP fluorine-containing polyhydroxy hyperbranched polyester
- the polar fluororubber may be selected from one or more of a hydroxynitrosofluororubber and a fluorocarbon rubber.
- the polyamide may be selected from one or more of polyphosphonium diamide, polyundecamide, and polydodecanamide.
- the polyurethane may be formed by reacting a double bond polyol, a diisocyanate, and a chain extender.
- the double bond polyol may be selected from one or more of polyhexylene glycol, polypropylene glycol, polytetramethylene ether glycol, and polycaprolactone;
- the diisocyanate may be selected from diphenyl One or more of methane diisocyanate, lysine diisocyanate, hydrogenated xylene diisocyanate, and 2,4,6-triisopropylphenyl diisocyanate;
- the chain extender may be selected from its own diamine, One or more of butanediamine, propylenediamine, and xylenediamine.
- the polyurethane may be a fluorine-containing polyurethane.
- the electrochemical energy storage device may be selected from one of a lithium secondary battery, a lithium ion secondary battery, a super capacitor, a fuel battery, and a solar battery.
- the battery cell 1 may be a wound cell, a laminated cell or a stacked roll cell.
- the glue 3 can be placed at any position between the cell 1 and the package 2.
- the glue 3 can be adhesively disposed at the winding end 11 of the wound cell 1 or any position of the surface of the cell 1 facing the package 2, and the glue 3 can be simultaneously bonded to be perpendicular to the electricity.
- the top and bottom of the core 1 in the width direction of the core 1 can also be attached to any one of the edges and corners of the cell 1, or at the same time.
- the area of the rubber material 3 does not exceed the surface area of the battery core 1, and the shape of the rubber material 3 may be one or more of a rectangular shape, a circular shape, a diamond shape, a triangular shape, a ring shape, a back shape, and a porous shape.
- the package 2 may be selected from a soft package or a hard package.
- Packaging shell In the electrochemical energy storage device according to the present invention, the package 2 may be selected from a soft package or a hard package. Packaging shell.
- the electrochemical energy storage device may further include: a viscous adhesive tape 4 on one or both sides, located in the battery core 1 and the glue material 3
- the adhesive surface of the adhesive tape 4 is adhesively disposed on the outer surface of the battery core 1 and the other surface is adhesively coupled to the adhesive material 3 such that the adhesive material 3 is indirectly bonded to the outer surface of the battery core 1.
- the substrate of the adhesive tape 4 may be selected from the group consisting of polyethylene terephthalate (PET), oriented polypropylene (PP), and polyimide (PI).
- PET polyethylene terephthalate
- PP oriented polypropylene
- PI polyimide
- One or more of the adhesive sheets 4; the adhesive of the adhesive tape 4 may be selected from one or more of an acrylic resin, a thermosetting polyurethane adhesive, an organic silicone, a natural rubber, and a synthetic rubber.
- the thickness of the adhesive tape 4 may be from 3 ⁇ m to 20 ⁇ m.
- the adhesive layer 31 may have a thickness of from 3 ⁇ m to 40 ⁇ m.
- the adhesive layer 31 may be selected from one or more of a temperature sensitive adhesive and a pressure sensitive adhesive.
- the temperature sensitive adhesive may be selected from the group consisting of terpene resins, petroleum resins, naphthenic oils, polyolefins, polyvinyl butyral, polyamides, and ethylene-acetic acid.
- terpene resins petroleum resins, naphthenic oils, polyolefins, polyvinyl butyral, polyamides, and ethylene-acetic acid.
- EVA ethylene copolymer
- SIS styrene-isoprene-styrene block copolymer
- polyester wherein naphthenic oil cannot be used alone.
- the pressure sensitive adhesive may be selected from the group consisting of ethylene-butylene-polystyrene linear triblock copolymer (SEBS), styrene-butadiene block copolymer. (SEPS), one or more of epoxidized styrene-isoprene-styrene block copolymer (ESIS), acrylic resin glue, thermosetting polyurethane glue, silicone rubber, natural rubber, and synthetic rubber.
- SEBS ethylene-butylene-polystyrene linear triblock copolymer
- SEPS styrene-butadiene block copolymer
- ESIS epoxidized styrene-isoprene-styrene block copolymer
- acrylic resin glue thermosetting polyurethane glue
- silicone rubber silicone rubber
- natural rubber natural rubber
- the adhesive layer 31 may have fluidity.
- the adhesive layer 31 may further include an inorganic additive which may be selected from one or more of Al 2 O 3 and SiO 2 .
- the protective layer 32 may have a thickness of 2 ⁇ m to 20 ⁇ m.
- the use of the inorganic additive can effectively control the viscosity of the adhesive layer 31, so that the adhesive material 3 does not flow to the package side of the battery cell 1 under the action of pressure or heating.
- the problem of poor packaging caused by the irregular flow of the glue material 3 is solved.
- LiCoO 2 , conductive carbon, and polyvinylidene fluoride were dispersed in N-methylpyrrolidone in a weight ratio of 96:1:3 to prepare a positive electrode slurry, which was then subjected to coating compaction to prepare a positive electrode sheet having a thickness of 100 ⁇ m.
- Graphite, conductive carbon, sodium carboxymethylcellulose, styrene-butadiene rubber were dispersed in deionized water at a weight ratio of 97:1:1:1 to prepare a negative electrode slurry, which was then compacted by coating to prepare a negative electrode having a thickness of 90 ⁇ m. sheet.
- the EC, PC, DEC, and EMC were formulated into a non-aqueous organic solvent at a weight ratio of 20:20:50:10, and 1 mol/L of LiPF 6 was added as a lithium salt to complete the preparation of the electrolyte.
- the prepared positive electrode sheet, PP separator, and negative electrode sheet were sequentially wound to prepare a wound cell having a thickness of 3.5 mm, a width of 48 mm, and a length of 80 mm.
- the length of the glue is 75mm and the width is 8mm;
- the adhesive layer is a mixture of polybutene (PB) and terpene resin, and has a thickness of 20 ⁇ m;
- the protective layer is PVDF and has a thickness of 3 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the protective layer is PVDF and has a thickness of 20 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the protective layer is FPP and has a thickness of 3 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the protective layer is FPBI and has a thickness of 3 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the length of the glue is 75mm and the width is 8mm;
- the adhesive layer is a mixture of polybutene (PB) and terpene resin, and has a thickness of 20 ⁇ m;
- the protective layer is FPBI and has a thickness of 3 ⁇ m.
- the length of the green rubber is 75mm and the width is 8mm.
- the green rubber is made of polyethylene terephthalate (PET), the acrylic resin is used as the adhesive, and the acrylic resin is coated with poly(ethylene terephthalate).
- PET polyethylene glycol ester
- the thickness of the polyethylene terephthalate (PET) was 7 ⁇ m, and the thickness of the acrylic resin gel was 8 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the adhesive layer was a mixture of SIS and terpene resin and had a thickness of 20 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 7, except for the following:
- the adhesive layer is a mixture of SIS and a terpene resin, and an Al 2 O 3 inorganic additive is added to the adhesive layer to a thickness of 40 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- a surface pressure of 0.6 MPa was applied to adhere the adhesive surface of the adhesive layer to the inner surface of the package to complete the preparation of the lithium ion secondary battery.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- a surface pressure of 0.8 MPa was applied to bond the adhesive side of the adhesive layer to the inner surface of the package to complete the preparation of the lithium ion secondary battery.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the length of the glue is 75mm and the width is 11mm;
- the adhesive layer was a mixture of polybutene (PB) and petroleum resin and had a thickness of 10 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the length of the glue is 75mm and the width is 11mm;
- the adhesive layer is a mixture of SEBS and polystyrene (PS), and has a thickness of 30 ⁇ m;
- the protective layer is PVDF and has a thickness of 5 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the prepared positive electrode sheet, PP separator, and negative electrode sheet were sequentially laminated to prepare a laminated battery core having a thickness of 3.5 mm, a width of 48 mm, and a length of 80 mm.
- the adhesive layer was a mixture of polyisoprene (PI) and naphthenic oil and had a thickness of 20 ⁇ m.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the length of the glue is 75mm and the width is 8mm;
- the adhesive layer is a mixture of polyisoprene (PI) and naphthenic oil, and has a thickness of 20 ⁇ m;
- the protective layer is PVDF and has a thickness of 3 ⁇ m.
- the length of the glue is 30mm and the width is 8mm;
- the adhesive layer is a mixture of polyisoprene (PI) and naphthenic oil, and has a thickness of 20 ⁇ m;
- the protective layer is PVDF and has a thickness of 3 ⁇ m.
- the adhesive tape is a green glue with a length of 75mm and a width of 8mm.
- the green glue is made of polyethylene terephthalate (PET) as the base material, the acrylic resin is used as the adhesive, and the acrylic resin is coated on the poly.
- PET polyethylene terephthalate
- PET polyethylene terephthalate
- acrylic resin paste has a thickness of 8 ⁇ m.
- Adhesive paper is adhered to the surface of the winding type of the winding core, and then the adhesive layer of the first adhesive is bonded to the corresponding green rubber at the end of the battery core, and is perpendicular to the width direction of the battery core and bypassed
- the bottom of the cell is pasted with two second glues in the form of a glue, and a second glue in the form of a glue is pasted perpendicular to the width of the cell and around the top of the cell, and then the glue is applied.
- the battery core is placed in the packaging shell, and the electrolyte is injected.
- a surface pressure of 1 MPa is applied on the outer surface of the corresponding packaging shell at the battery core bonding adhesive to make the adhesive surface of the adhesive layer and the packaging shell.
- the inner surface is bonded to complete the preparation of the lithium ion secondary battery.
- a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
- the rubber material is acrylic double-sided tape, the length is 75mm, the width is 11mm, the thickness is 20 ⁇ m, the acrylic double-sided tape is based on polyethylene terephthalate (PET), and the acrylic resin is used as the adhesive.
- the acrylic resin was coated on both sides of polyethylene terephthalate (PET), the thickness of polyethylene terephthalate (PET) was 6 ⁇ m, and the thickness of the acrylic resin was 7 ⁇ m.
- the lithium ion secondary battery is fixed in a drop test fixture with a double-sided tape, and the initial voltage of the lithium ion secondary battery is tested and recorded as V 0 , and the six faces of the jig are sequentially numbered 1, 2, 3, 4, 5, 6.
- the four corners of the fixture are numbered C1, C2, C3, and C4.
- the fixture was placed on a 1.5 m high test bench, and the lithium ion secondary batteries were sequentially dropped in the order of number 1-6, and then the lithium ion secondary batteries were sequentially dropped in the order of number C1-C4, and the cycle was repeated.
- the drop test was completed, and after standing for 1 h, the final voltage of the test lithium ion secondary battery was recorded as V 1 .
- the lithium ion secondary battery was placed in an incubator at 25 ° C, and charged at a constant current of 0.5 C.
- the cut-off voltage was 4.35 V, and then charged at a constant voltage of 4.35 V.
- the off current was 0.025 C, and after standing for 3 min, 0.5. C constant current discharge, the cut-off voltage is 3.0V, this is a charge and discharge cycle process, repeating the above charging and discharging process 800 times to observe whether a short circuit occurs.
- Each group was tested for 50 lithium ion secondary batteries, and then the pass rate of the lithium ion secondary battery was calculated.
- the initial thickness of the lithium ion secondary battery before the cycle is measured by the thickness gauge as D 1
- the thickness after 800 cycles is recorded as D 2
- D 2 /D 1 -1 can represent the deformation rate of the lithium ion secondary battery.
- the deformation rate of ⁇ 8% is considered to be that the lithium ion secondary battery has no deformation, and the pass rate of the lithium ion secondary battery without deformation is calculated.
- the lithium ion secondary battery was placed in an incubator at 25 ° C, and charged at a constant current of 0.7 C.
- the cut-off voltage was 4.35 V, and then charged at a constant voltage of 4.35 V.
- the off current was 0.025 C, and after standing for 3 min, 1 C was used. Constant current discharge, the cut-off voltage is 3.0V, this is a charge-discharge cycle process, repeating the cycle until The capacity of the lithium ion secondary battery is attenuated to ⁇ 80%, and the number of cycles is recorded.
- the appearance of the lithium ion secondary battery was visually observed for the presence or absence of significant electrolyte liquid rising, and the number of lithium ion secondary batteries without liquid rising was recorded as P 0 , and the detected The total number of lithium ion secondary batteries is P, and the liquid-free passage rate of the lithium ion secondary battery is P 0 /P.
- Table 1 gives the parameters of Examples 1-15 and Comparative Example 1.
- Table 2 gives the performance test results of Examples 1-15 and Comparative Example 1.
- the lithium ion secondary battery of the present invention has a higher drop test pass rate, no short circuit pass rate after higher cycle, and no higher cycle. Deformation pass rate and high no-liquid passage rate, and have a high number of large-rate discharge cycles.
- Comparative Example 1 uses a common acrylic double-sided tape, and both surfaces thereof have adhesiveness at normal temperature, which makes it difficult to adjust the position of the cell after bonding the double-sided tape to the package, and The bonding strength of the double-sided tape is small. In order to achieve better bonding strength, the width of the double-sided tape must be increased to increase the bonding area, thereby improving the bonding strength.
- the protective layer of the present invention is a polar molecule, is easy to form a network structure, can absorb an electrolyte, and when the electrolyte in the lithium ion secondary battery is gradually reduced due to decomposition, the electrolyte absorbed by the protective layer is also poor in concentration due to the concentration. It will be gradually released; the protective layer can be viscous after being dissolved or swelled in the electrolyte in whole or in part, and can be adhered to the inside of the lithium ion secondary battery as the electrolyte diffuses, so that the separator and the pole piece can be bonded.
- the separator Prevent the separator from shrinking after the lithium ion secondary battery falls, without additionally adding a rubber around the head and tail; Since the molecular polarity of the protective layer is large, the ionization of the lithium salt is facilitated, thereby improving the ion conductivity of the electrolyte, which is advantageous for the large-rate charge and discharge performance of the lithium ion secondary battery.
- Example 1-2 It can be seen from Example 1-2 that as the thickness of the protective layer increases, the amount of the protective layer dissolved or swelled and dispersed in the electrolytic solution increases, and the amount between the positive electrode sheet and the negative electrode sheet becomes large, and the positive electrode sheet and the positive electrode sheet can be enhanced. The adhesion between the negative electrode sheets, so the pass rate of the lithium ion secondary battery without deformation after the cycle is improved.
- Example 5 It can be seen from Example 5 that the change in the position of the glue material does not affect the performance of the lithium ion secondary battery.
- Example 8 it can be seen from Example 8 that when the adhesive layer contains an inorganic additive, the lithium ion secondary battery has better performance even if the thickness of the adhesive layer is large, because the inorganic additive can effectively control the adhesive layer.
- the viscosity of the glue does not flow to the package edge of the battery under the action of pressure or heating, which solves the problem of poor packaging caused by irregular flow of the rubber material and improves the width of the overflow.
- the surface of the cell is pasted with the green glue, and the adhesive is placed on the surface of the cell at the end of the cell, and when the thickness of the bonding layer is When the thickness of the protective layer is increased, it is advantageous to increase the adhesion between the battery core and the package shell, and improve the pass-through rate of the lithium ion secondary battery after the cycle.
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Abstract
Description
Claims (26)
- 一种电化学储能装置,包括:电芯(1),包括正极片、负极片以及间隔于正极片、负极片之间的隔离膜;电解液,浸渍电芯(1);以及包装壳(2),封装电芯(1)并容纳电解液;其特征在于,所述电化学储能装置还包括:胶材(3),位于电芯(1)和包装壳(2)之间,包括:粘性层(31),直接或间接地粘结设置于电芯(1)的外表面上,且其远离电芯(1)的一面为胶粘面;保护层(32),设置于粘性层(31)的胶粘面上,保护层(32)全部或部分地溶解或溶胀分散于电解液中,以露出粘性层(31)的胶粘面,进而粘性层(31)将电芯(1)和包装壳(2)粘结在一起;保护层(32)为极性分子,所述极性分子中包含-F、-CO-NH-、-NH-CO-NH-、以及-NH-CO-O-中的一种或几种。
- 根据权利要求1所述的电化学储能装置,其特征在于,保护层(32)选自具有极性的含氟聚烯烃、具有极性的含氟聚酯、具有极性的氟橡胶、聚酰胺以及聚氨酯中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述具有极性的含氟聚烯烃选自聚偏氟乙烯、聚丙烯酸改性的聚偏氟乙烯、含氟聚丙烯、偏二氟乙烯和六氟丙烯共聚物、四氟乙烯和碳氢丙烯共聚物、氟烯烃-乙烯基醚共聚物、偏二氟乙烯-四氟乙烯-六氟丙烯共聚物、以及四丙氟橡胶中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述具有极性的含氟聚酯选自含氟线性聚间苯二甲酸丁二醇酯、含氟线性聚对苯二甲酸丁 二醇酯、端羟基含氟聚酯聚硅氧烷、以及含氟多羟基超支化聚酯中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述具有极性的氟橡胶选自羟基亚硝基氟橡胶、以及偏氟醚橡胶中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述聚酰胺选自聚癸二酸癸二胺、聚十一酰胺、以及聚十二酰胺中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述聚氨酯由双键多元醇、二异氰酸酯以及增链剂反应生成。
- 根据权利要求7所述的电化学储能装置,其特征在于,所述双键多元醇选自聚己二醇、聚丙二醇、聚四亚甲基醚二醇、以及聚己内脂二醇中的一种或几种。
- 根据权利要求7所述的电化学储能装置,其特征在于,所述二异氰酸酯选自二苯甲烷二异氰酸酯、赖氨酸二异氰酸酯、氢化二甲苯二异氰酸酯、以及2,4,6-三异丙基苯基二异氰酸酯中的一种或几种。
- 根据权利要求7所述的电化学储能装置,其特征在于,所述增链剂选自己二胺、丁二胺、丙二胺、以及二甲苯二胺中的一种或几种。
- 根据权利要求2所述的电化学储能装置,其特征在于,所述聚氨酯为含氟聚氨酯。
- 根据权利要求1所述的电化学储能装置,其特征在于,粘性层(31)选自温敏胶、以及压敏胶中的一种或几种。
- 根据权利要求12所述的电化学储能装置,其特征在于,所述温敏胶 选自萜烯树脂、石油树脂、环烷油、聚烯烃、聚乙烯醇缩丁醛、聚酰胺类、乙烯-醋酸乙烯共聚物、苯乙烯-异戊二烯-苯乙烯嵌段共聚物、以及聚酯类中的一种或几种,其中环烷油不能单独使用。
- 根据权利要求12所述的电化学储能装置,其特征在于,所述压敏胶选自乙烯-丁烯-聚苯乙烯线性三嵌段共聚物、苯乙烯-丁二烯嵌段共聚物、环氧化苯乙烯-异戊二烯-苯乙烯嵌段共聚物、丙烯酸树脂胶、热固性聚氨酯胶、有机硅胶、天然橡胶、以及合成橡胶中的一种或几种。
- 根据权利要求1所述的电化学储能装置,其特征在于,粘性层(31)具有流动性。
- 根据权利要求1所述的电化学储能装置,其特征在于,粘性层(31)还包括无机添加剂。
- 根据权利要求16所述的电化学储能装置,其特征在于,所述无机添加剂选自Al2O3、以及SiO2中的一种或几种。
- 根据权利要求1所述的电化学储能装置,其特征在于,所述电化学储能装置还包括:单面或双面具有粘性的胶纸(4),位于电芯(1)和胶材(3)之间,其胶粘面粘结设置于电芯(1)的外表面上而另一面与胶材(3)粘结连接,以使胶材(3)间接地粘结设置于电芯(1)的外表面上。
- 根据权利要求18所述的电化学储能装置,其特征在于,胶纸(4)的基材选自聚对苯二甲酸乙二醇酯、取向聚丙烯、以及聚酰亚胺中的一种或几种。
- 根据权利要求18所述的电化学储能装置,其特征在于,胶纸(4)的胶黏剂选自丙烯酸树脂胶、热固性聚氨酯胶、有机硅胶、天然橡胶、以及合 成橡胶中的一种或几种。
- 根据权利要求18所述的电化学储能装置,其特征在于,胶纸(4)的厚度为3μm~20μm。
- 根据权利要求1所述的电化学储能装置,其特征在于,粘性层(31)的厚度为3μm~40μm。
- 根据权利要求1所述的电化学储能装置,其特征在于,保护层(32)的厚度为2μm~20μm。
- 根据权利要求1所述的电化学储能装置,其特征在于,所述电化学储能装置选自锂离子二次电池、超级电容器、燃料电池、太阳能电池中的一种。
- 根据权利要求1所述的电化学储能装置,其特征在于,电芯(1)为卷绕式电芯、叠片式电芯或叠加卷式电芯。
- 根据权利要求1所述的电化学储能装置,其特征在于,包装壳(2)选自软包装壳或硬包装壳。
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US20170263983A1 (en) | 2017-09-14 |
EP3232501A1 (en) | 2017-10-18 |
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