WO2013144400A1 - Procedimiento para la eliminación de tinta impresa en films de plástico - Google Patents
Procedimiento para la eliminación de tinta impresa en films de plástico Download PDFInfo
- Publication number
- WO2013144400A1 WO2013144400A1 PCT/ES2013/070161 ES2013070161W WO2013144400A1 WO 2013144400 A1 WO2013144400 A1 WO 2013144400A1 ES 2013070161 W ES2013070161 W ES 2013070161W WO 2013144400 A1 WO2013144400 A1 WO 2013144400A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plastic film
- ink
- film
- cleaning solution
- printed
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000002985 plastic film Substances 0.000 title claims abstract description 37
- 229920006255 plastic film Polymers 0.000 title claims abstract description 37
- 238000004140 cleaning Methods 0.000 claims abstract description 69
- 239000000049 pigment Substances 0.000 claims abstract description 22
- 238000005406 washing Methods 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 10
- 230000003750 conditioning effect Effects 0.000 claims abstract description 7
- 238000011282 treatment Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920006267 polyester film Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 235000019198 oils Nutrition 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 2
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 23
- 239000000126 substance Substances 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 230000008030 elimination Effects 0.000 description 4
- 238000003379 elimination reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 239000004484 Briquette Substances 0.000 description 3
- 239000011111 cardboard Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 238000009459 flexible packaging Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/044—Cleaning involving contact with liquid using agitated containers in which the liquid and articles or material are placed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/20—Adding fluid, other than for crushing or disintegrating by fluid energy after crushing or disintegrating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/40—Adding fluid, other than for crushing or disintegrating by fluid energy with more than one means for adding fluid to the material being crushed or disintegrated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0286—Cleaning means used for separation
- B29B2017/0289—Washing the materials in liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0032—Pigments, colouring agents or opacifiyng agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/008—Wide strips, e.g. films, webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
- B29L2009/005—Layered products coated
- B29L2009/006—Layered products coated painted
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- the present invention relates to a novel method by which ink printed on a plastic film whose nature can be waived is removed.
- plastic film that can be used in the described process are polyethylene (PE), polypropylene (PP), polyester film (PET) and polyamide (PA).
- the flexible packaging printing process involves applying a liquid ink to a plastic film. Subsequently, by means of a drying process, the solvent used is removed (usually organic compounds or water), which is volatilized. After evaporation, the film is printed with the desired drawing and is ready to be used as packaging for various products. During such printing, it is common to adjust the parameters of the printing machine, as well as adjust the different colors used, to achieve a quality print without imperfections. During this step, most of the waste is generated. During the adjustment of the machine, the plastic film circulates through the printer at speeds that can reach 500 meters per minute. Due to this speed, large quantities of plastic film that do not have the necessary quality to be used in the final packaging applications are generated.
- the invention US 5621939 A relates to a treatment for removing ink from printed paper, whereby the starting material is different. In addition, in this procedure the material is not crushed and is processed directly, introducing the paper into a bath containing the cleaning solution.
- the invention EP1419829 A1 deals with the removal of ink in printed films, but the procedure used is totally different, since the film is treated without being previously pelletized, and the method of separation used, although chemical, is composed of organic solvents and nonionic surfactants.
- the invention CA2101 181 consists of a process of recycling multilayer mixed containers, composed of a layer of polymer, another of a metal (usually aluminum) and another of paper or cardboard.
- Printed ink is usually on the sheet of paper or cardboard, which is removed by water vapor.
- the part of ink that is adhered to the plastic film is separated by dissolving it with a solvent and separating it by density from the metal part and the unprinted film, so that neither the separation principle nor the starting material are the same which in the invention are presented.
- the main advantage of the procedure described here is that by means of an economically viable solution, it is possible to separate the printed ink and obtain the clean ink film, increasing the added value of the product recovered.
- the present invention two products are obtained from the printed film: the pigments that can be reused for this and other applications after a treatment such as that described in patent ES2344778 B1, and the recycled and colorless film in the form of pellets, which can also be reused, being a higher quality product than colored film.
- the present invention therefore relates to a process whereby the ink contained in the plastic film is removed by using different physical-chemical treatments.
- the technical problem of recycling the printed film is solved by obtaining an ink-free product suitable for recycling in any type of application due to its high quality and purity.
- the procedure described here is likely to be used in the printed product already used by the end user, or in printing materials formed by the production losses, in which case the material is usually in the form of jumbos (rolls of material of 1 , 5 m wide and variable thickness) or rolls of smaller size and thickness, as well as scattered material.
- the first stage of the invention consists in conditioning the material.
- the elimination of the cylindrical mandrel where the film is supported which is usually made of cardboard, is carried out in order to make the crushing operation easier. This is achieved by manually or mechanically removing the mandrel from the plastic film reels.
- the second stage of the procedure is the crushing of the rolls of film to a size that can vary from 6 to 14 mm in diameter for later cleaning.
- the film rolls are introduced in a knife shredder that has both mobile and fixed blades.
- STAGE 3 FILM INK ELIMINATION
- the operation of cleaning the printed film is carried out, that is, the step where the plastic film is separated from the printed ink.
- the crushed material from the crusher is introduced into the cleaning system.
- the cleaning system is composed of three tanks, a cleaning tank and two washing tanks.
- suitable cleaning agents are added to the cleaning tank, which cause the separation of the ink from the plastic film.
- the operation is preferably performed under basic conditions.
- This stage is carried out in discontinuous mode in the case of the film, for this, the cleaning tank is loaded with the crushed material from stage 2.
- the amounts of water, cleaning agents and necessary bases are added and agitation is performed of tank contents using blade stirrers with proper configuration. During cleaning, the ink that has been removed from the film is continuously removed.
- stage 4 a stream of water is extracted that contains the cleaning solution and the ink. From this moment, stages are executed in parallel, on the one hand the washing (stage 4) and drying of the film (stage 7) is executed, and on the other hand the recovery of the cleaning solution (stage 5) and the pigment (stage 6).
- the cleaning solution that was generated in step 3 feeds the centrifuge to carry out its recovery.
- the centrifuge operates continuously while the cleaning operation is taking place in the tank of stage 3 and manages to separate the ink that is a solid from the cleaning solution. Therefore, two streams come out of this treatment, one is the ink and the other is the cleaning solution. In this way it is achieved that the process is environmentally and economically more favorable, since the cleaning solution can be reused in the cleaning tank, and the ink can be treated to recover the pigment and be used for various applications after a heat treatment.
- the heat treatment consists of a heat treatment reactor in which heating is available and whose function is to decompose the resin to obtain recycled pigment.
- STEP 7 DRYING THE FILM
- the plastic film must be dried to remove the remaining water content.
- the wet material is passed through a mechanical separation element such as a bnqueadora to eliminate the greater amount of water or a hot air drying is performed.
- FIGURE 1 Shows a diagram of the procedure object of this invention as well as the equipment involved in it.
- FIGURE 2 Shows a detailed diagram of the cleaning system of the ink removal procedure of the printed film.
- the ink removal procedure printed on the plastic film comprises the following stages: STEP 1: MATERIAL CONDITIONING
- the printed input material 1 may be polyethylene (PE), polypropylene (PP), polyester film (PET) or polyamide (PA).
- PE polyethylene
- PP polypropylene
- PET polyester film
- PA polyamide
- the particle size of the impurity-free film 2 should be reduced to a diameter that can vary from 6 to 14 mm, in order to favor the penetration of the cleaning solution. For this, it is introduced in a knife shredder 102 consisting of both fixed and mobile blades. This shredder reduces the size of the film until obtaining a crushed material 3.
- the ink must be removed to the crushed matten 3, so it is introduced into the cleaning system 103 with the cleaning solution 6 consisting of a mixture of surfactants in water, in proportions between 0.1 and 5% by weight, and with a basic pH between 1 1 and 13, where the removal of the ink contained in the film occurs, becoming part of the cleaning solution in an undissolved form.
- the surfactants of the cleaning solution in a preferred embodiment, are hexadecyl-thmethylammonium bromide, dodecyl-trimethylammonium bromide or dodecyl sulfate.
- the cleaning system 103 consists of the system shown in Figure 2, consisting of three tanks.
- the cleaning tank 201 is a stirred tank with blades where the plastic film is put in contact with the cleaning solution 6.
- the other two tanks are washing tanks that are put into operation in the next stage.
- Three streams enter this cleaning system 103, the one containing the crushed material 3, the one containing the cleaning solution 6 and the one that contains clean water 23; and two other currents are described below.
- the current containing the crushed material 3 enters the cleaning system 103 by feeding the cleaning tank 201.
- the cleaning solution 6 that comes from the centrifuge 104 also enters this cleaning tank. It is very important that the blades of the cleaning tank 201 cause great turbulence inside the agitated tank with blades so that the pieces of crushed film do not overlap with each other, and thus increase the effectiveness of the procedure.
- the turbulence also favors the dispersion of the ink detached from the film in the cleaning solution 6.
- the treated plastic film 21 containing cleaning solution and scattered ink remains, and on the other side of the cleaning solution together with the ink removed from film 4, which goes to centrifuge 104.
- the first wash tank 202 is where the film from the cleaning tank 201 is washed with water.
- the second wash tank 203 is where the film from the first wash tank 202, comes into contact with clean water to remove the remains of cleaning solution.
- the treated plastic film 21 is introduced to remove the remains of dispersed ink and cleaning solution.
- the washing liquid 25, which leaves the first washing tank 202 feeds the cleaning tank 201 in order to save water.
- From the first wash tank 202 comes out the washed plastic film 22 containing traces of cleaning solution, and feeds the second wash tank 203.
- This second wash eliminates the last remains of cleaning solution that may remain in the plastic.
- Two streams flow from the second wash tank 203, one containing the clean film free of ink and debris from cleaning solution 8 that feeds the briquette 106; and the other stream which contains the wash water 24 that feeds the first wash tank 202 to save water.
- the cleaning solution together with the ink removed from the film 4 must be continuously regenerated by using a centrifuge 104, at 10,000 revolutions per minute.
- This equipment consists of a centrifugal separator to separate the cleaning solution 6 from the ink 5.
- the cleaning solution 6 is reintroduced into the cleaning system 103 reducing the consumption of cleaning solution that the procedure of not reusing it would have .
- the stream containing the ink 5 feeds a heat treatment reactor of the ink 105, in order to destroy the resin structure and from which the pigment leaves ready to be reused 7.
- the heat treatment reactor operates at a temperature between 170 and 200 ° C.
- a mixture of pigment and oil is introduced into the reactor, where the resin containing the pigment is thermally destroyed.
- vegetable oil such as sunflower oil or flaxseed, can be used as mineral oil from petroleum.
- the reactor operates with vigorous agitation and the average residence time of the pigment is 1 hour.
- the mixture is filtered to separate the pigment from the oil and the oil is reintroduced to the reactor to continue treating more pigment. With this the pigment is free of resin and can be used in various applications.
- the clean film free of ink and debris from cleaning solution 8 is formed by the clean film after the ink 5 has been removed and washed with the cleaning solution 6.
- This plastic is introduced into the Briquette 106, which consists of a drying element that removes as much water as possible by pressing and compacting the material. From the briquette 106, a stream comes out containing a crushed film free of ink and cleaning solution 9 ready to be used in other applications.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Processing Of Solid Wastes (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014011432A MX357125B (es) | 2012-03-26 | 2013-03-13 | Procedimiento para la eliminacion de tinta impresa en films de plastico. |
BR112014023871-5A BR112014023871B1 (pt) | 2012-03-26 | 2013-03-13 | Metodo de remocao de tinta impressa sobre um filme plastico |
US14/388,763 US9616595B2 (en) | 2012-03-26 | 2013-03-13 | Method for removing ink printed on plastic films |
JP2015502389A JP6190446B2 (ja) | 2012-03-26 | 2013-03-13 | プラスチックフィルム上に印刷されたインクの除去方法 |
RU2014142594A RU2630819C2 (ru) | 2012-03-26 | 2013-03-13 | Способ удаления краски, отпечатанной на полимерных пленках |
MA37447A MA37447B1 (fr) | 2012-03-26 | 2013-03-13 | Procédé destiné à éliminer l'encre imprimée sur des films plastiques |
KR1020147029937A KR102023744B1 (ko) | 2012-03-26 | 2013-03-13 | 플라스틱 필름에 프린팅된 잉크의 제거 방법 |
CA2868244A CA2868244C (en) | 2012-03-26 | 2013-03-13 | Method for removing ink printed on plastic films |
IN2109MUN2014 IN2014MN02109A (es) | 2012-03-26 | 2013-03-13 | |
EP13770017.5A EP2832459B1 (en) | 2012-03-26 | 2013-03-13 | Method for removing ink printed on plastic films |
CN201380016951.1A CN104254403A (zh) | 2012-03-26 | 2013-03-13 | 用于移除印刷在塑料膜上的油墨的方法 |
AU2013241643A AU2013241643B2 (en) | 2012-03-26 | 2013-03-13 | Method for removing ink printed on plastic films |
SI201330764T SI2832459T1 (sl) | 2012-03-26 | 2013-03-13 | Postopek za odstranjevanje črnila, natisnjenega na plastičnih folijah |
ZA2014/07763A ZA201407763B (en) | 2012-03-26 | 2014-10-24 | Method for removing ink printed on plastic films |
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ESP201200320 | 2012-03-26 | ||
ES201200320A ES2427019B2 (es) | 2012-03-26 | 2012-03-26 | Procedimiento para la eliminación de tinta impresa en film de plástico |
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WO2013144400A1 true WO2013144400A1 (es) | 2013-10-03 |
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US (1) | US9616595B2 (es) |
EP (1) | EP2832459B1 (es) |
JP (1) | JP6190446B2 (es) |
KR (1) | KR102023744B1 (es) |
CN (1) | CN104254403A (es) |
AU (1) | AU2013241643B2 (es) |
BR (1) | BR112014023871B1 (es) |
CA (1) | CA2868244C (es) |
CL (1) | CL2014002545A1 (es) |
CO (1) | CO7170161A2 (es) |
ES (1) | ES2427019B2 (es) |
IN (1) | IN2014MN02109A (es) |
MA (1) | MA37447B1 (es) |
MX (1) | MX357125B (es) |
PE (1) | PE20142155A1 (es) |
PL (1) | PL2832459T3 (es) |
PT (1) | PT2832459T (es) |
RU (1) | RU2630819C2 (es) |
SI (1) | SI2832459T1 (es) |
WO (1) | WO2013144400A1 (es) |
ZA (1) | ZA201407763B (es) |
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CN106999945B (zh) | 2014-08-19 | 2019-03-12 | 吉欧科技聚合物有限责任公司 | 涂层去除系统 |
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EP3365417A4 (en) | 2015-10-20 | 2019-11-20 | Geo-tech Polymers LLC | RECYCLING OF FIBROUS SURFACE COATINGS |
NL2016719B1 (nl) | 2016-05-02 | 2017-11-10 | Boers Holding B V | Werkwijze voor het reinigen van een bedrukte baan flexibel materiaal, alsmede een inrichting daarvoor. |
CA3032129A1 (en) * | 2016-07-26 | 2018-02-01 | Geo-Tech Polymers, Llc | Method and apparatus for film treatment |
CN107520999A (zh) * | 2016-08-11 | 2017-12-29 | 常州市恒力机械有限公司 | 油墨分离方法以及油墨分离装置 |
CN108724529A (zh) * | 2018-05-29 | 2018-11-02 | 无锡添源环保科技有限公司 | 一种废油墨桶的处置回收方法 |
GB2570019B (en) * | 2018-09-17 | 2021-04-21 | Impact Laboratories Ltd | Plastic recycling process |
CA3148208A1 (en) | 2019-07-26 | 2021-02-04 | Borealis Ag | Method for removing ink or other foreign materials from the surface of an article |
ES2823926B2 (es) * | 2019-11-07 | 2021-10-15 | Univ Alicante | Procedimiento para la eliminacion de adhesivos y/o tintas interlaminares en material plastico laminado |
EP3828228A1 (en) | 2019-11-29 | 2021-06-02 | Borealis AG | Method for removing foreign materials from the surface of an article |
EP4107326A1 (en) | 2020-02-19 | 2022-12-28 | Siegwerk Druckfarben AG & Co. KGaA | Deinking of printed substrates |
EP3885095A1 (de) | 2020-03-23 | 2021-09-29 | Covestro Deutschland AG | Verwendung von mischungen aus wasser und ätherischen öl zur auftrennung von mehrschichtverbunden für das sortenreine recycling der polymer- bzw. metallfolien |
EP4127033A2 (en) | 2020-04-02 | 2023-02-08 | Universiteit Gent | A method to deink plastic material |
WO2021211646A1 (en) | 2020-04-15 | 2021-10-21 | The Procter & Gamble Company | Reducing surface and bulk contamination in plastic |
CN111604357B (zh) * | 2020-05-26 | 2021-11-23 | 聊城市洛溪信息科技有限公司 | 一种锡纸食品餐盒回收再利用处理系统及处理方法 |
EP3932642A1 (en) | 2020-07-03 | 2022-01-05 | Siegwerk Druckfarben AG & Co. KGaA | Delamination primer for deinking |
US11674012B2 (en) | 2020-07-28 | 2023-06-13 | The Procter & Gamble Company | Method for producing recycled polyethylene with virgin-like optical properties |
US20220033613A1 (en) | 2020-07-28 | 2022-02-03 | The Procter & Gamble Company | Method for Producing Recycled High-Density Polyethylene with Natural-Like Optical Properties |
EP4205935A1 (en) * | 2020-08-25 | 2023-07-05 | DIC Corporation | Ink remover used to recycle plastic laminates into recycled materials, ink film peeling method, and separation and recovery method of peeled ink film |
WO2022234296A1 (en) | 2021-05-07 | 2022-11-10 | Sortology Ltd | Recycling plastics |
US20220356322A1 (en) | 2021-05-10 | 2022-11-10 | The Procter & Gamble Company | Method of Separating and Purifying a Mixed Stream of Contaminated Reclaimed Polyethylene and Polypropylene |
US20230007899A1 (en) | 2021-07-08 | 2023-01-12 | The Procter & Gamble Company | Method for Producing Recycled Polyethylene Having Low b* Value |
US11707867B1 (en) * | 2021-07-30 | 2023-07-25 | Csr Worldwide Ok, Inc. | System for handling used packaging film in a food processing facility |
JP2023032031A (ja) | 2021-08-26 | 2023-03-09 | Dic株式会社 | プラスチックフィルム積層体のリサイクル方法、プラスチックフィルム積層体を用いたリサイクルプラスチックの加工用材料及びその製造方法 |
EP4434040A1 (en) | 2021-11-18 | 2024-09-25 | Wisconsin Alumni Research Foundation | Recycling of plastics by solvent-targeted recovery and precipitation ("strap") |
CN118414235A (zh) | 2021-12-17 | 2024-07-30 | 根特大学 | 一种使用胺对塑料材料脱墨和/或分层的方法 |
EP4197733A1 (en) | 2021-12-17 | 2023-06-21 | Universiteit Gent | A method to deink and/or to delaminate plastic material using a mixture comprising an oxidizing inorganic acid and a saturated hydrocarbon |
EP4293084A1 (en) | 2022-06-14 | 2023-12-20 | polycirQ GmbH | Composition and method for deinking a printed polymer substrate |
CN115463887B (zh) * | 2022-09-13 | 2023-12-26 | 江西格林循环产业股份有限公司 | 一种废弃塑料回收加工前期处理系统 |
US20240092992A1 (en) | 2022-09-21 | 2024-03-21 | The Procter & Gamble Company | Method for purifying reclaimed polymers |
DE102022124404A1 (de) | 2022-09-22 | 2024-03-28 | HydroDyn Recycling GmbH | Verfahren zum Reinigen von Kunststoffabfall |
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- 2013-03-13 AU AU2013241643A patent/AU2013241643B2/en active Active
- 2013-03-13 PL PL13770017T patent/PL2832459T3/pl unknown
- 2013-03-13 KR KR1020147029937A patent/KR102023744B1/ko active IP Right Grant
- 2013-03-13 IN IN2109MUN2014 patent/IN2014MN02109A/en unknown
- 2013-03-13 SI SI201330764T patent/SI2832459T1/sl unknown
- 2013-03-13 WO PCT/ES2013/070161 patent/WO2013144400A1/es active Application Filing
- 2013-03-13 MA MA37447A patent/MA37447B1/fr unknown
- 2013-03-13 PE PE2014001471A patent/PE20142155A1/es not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
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MA20150353A1 (fr) | 2015-10-30 |
MX2014011432A (es) | 2015-08-14 |
EP2832459A1 (en) | 2015-02-04 |
BR112014023871B1 (pt) | 2020-11-24 |
BR112014023871A2 (es) | 2017-06-20 |
EP2832459A4 (en) | 2015-11-25 |
CA2868244C (en) | 2019-08-13 |
AU2013241643B2 (en) | 2017-12-14 |
CO7170161A2 (es) | 2015-01-28 |
RU2014142594A (ru) | 2016-05-20 |
ES2427019A1 (es) | 2013-10-28 |
BR112014023871A8 (pt) | 2017-07-25 |
US9616595B2 (en) | 2017-04-11 |
KR102023744B1 (ko) | 2019-09-20 |
JP2015520684A (ja) | 2015-07-23 |
JP6190446B2 (ja) | 2017-08-30 |
SI2832459T1 (sl) | 2017-10-30 |
IN2014MN02109A (es) | 2015-09-04 |
ES2427019B2 (es) | 2014-05-09 |
AU2013241643A1 (en) | 2014-11-13 |
MA37447B1 (fr) | 2016-05-31 |
PL2832459T3 (pl) | 2017-09-29 |
CA2868244A1 (en) | 2013-10-03 |
PT2832459T (pt) | 2017-07-13 |
MX357125B (es) | 2018-06-27 |
RU2630819C2 (ru) | 2017-09-13 |
CL2014002545A1 (es) | 2015-05-29 |
US20150298360A1 (en) | 2015-10-22 |
ZA201407763B (en) | 2016-05-25 |
PE20142155A1 (es) | 2015-01-14 |
KR20150006427A (ko) | 2015-01-16 |
EP2832459B1 (en) | 2017-04-26 |
CN104254403A (zh) | 2014-12-31 |
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