WO2013111634A1 - 汚染防止方法 - Google Patents
汚染防止方法 Download PDFInfo
- Publication number
- WO2013111634A1 WO2013111634A1 PCT/JP2013/050521 JP2013050521W WO2013111634A1 WO 2013111634 A1 WO2013111634 A1 WO 2013111634A1 JP 2013050521 W JP2013050521 W JP 2013050521W WO 2013111634 A1 WO2013111634 A1 WO 2013111634A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressure
- adhesive tape
- sensitive adhesive
- antifouling
- adhesive
- Prior art date
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B59/00—Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
- B63B59/04—Preventing hull fouling
- B63B59/045—Preventing hull fouling by wrapping the submerged hull or part of the hull with an impermeable sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B59/00—Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
- B63B59/04—Preventing hull fouling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B73/00—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms
- B63B73/40—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms characterised by joining methods
- B63B73/46—Gluing; Taping; Cold-bonding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
- C09J179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09J179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/306—Applications of adhesives in processes or use of adhesives in the form of films or foils for protecting painted surfaces, e.g. of cars
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/14—Glass
- C09J2400/143—Glass in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
- C09J2433/006—Presence of (meth)acrylic polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
- C09J2475/006—Presence of polyurethane in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2479/00—Presence of polyamine or polyimide
- C09J2479/08—Presence of polyamine or polyimide polyimide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1089—Methods of surface bonding and/or assembly therefor of discrete laminae to single face of additional lamina
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24752—Laterally noncoextensive components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2848—Three or more layers
Definitions
- the present invention relates to a method for preventing contamination of a structure having a surface where contamination should be prevented.
- Underwater structures such as ships, buoys, port facilities, offshore oilfield facilities, cooling water supply channels for power plants, cooling water supply channels for factories, etc.
- Aquatic organisms such as bryozoans, mushrooms, aonori, and attached diatoms grow and adhere, and it is preferable to reduce equipment mechanical performance such as increased fluid resistance and reduced thermal conductivity, and to disperse attached aquatic organisms into water. Is causing no state.
- the work for removing the attached aquatic organisms requires a large amount of labor and enormous time, and suffers an economic loss.
- antifouling paint In order to prevent such damage, antifouling paint has been conventionally applied to underwater structures. However, when the antifouling paint is dried after being applied, about 30% by weight of the organic solvent (VOC) is volatilized, which adversely affects the work environment and the surrounding environment. In spray coating, in addition to discharging VOC into the atmosphere, it is said that 10 to 20% by weight of the paint is scattered around by the wind, which has a great adverse effect on the environment.
- VOC organic solvent
- Patent Document 1 or 2 it has been proposed to prevent adhesion of aquatic organisms by applying an antifouling adhesive tape containing a copper or copper alloy base material to the wetted surface of an underwater structure.
- Patent Document 1 or 2 In the antifouling treatment using such an antifouling adhesive tape, the discharge of VOC into the environment is reduced, there is no change in the quality of the coating film due to changes in the coating environment, and the painter's coating is not applied. While there is an advantage that there is no difference in engineering amount, the following problems may occur.
- Peeling from the joints can be suppressed by increasing the adhesive strength of the antifouling adhesive tape to the wetted surface, but in this case, it becomes extremely difficult to remove and remove the deteriorated antifouling adhesive tape. There is a problem that the workability of the apparatus is significantly reduced.
- the adjacent antifouling adhesive tapes are abutted without gaps, or the ends are overlapped, and the antifouling adhesive tape is expanded or contracted. It is difficult to completely prevent gaps due to construction errors.
- the peeling progresses due to fluid resistance such as water flow or air flow, and the adhesive tape may be peeled off.
- An object of the present invention is to prevent contamination of a structure using an antifouling pressure-sensitive adhesive tape, peeling from the joint of the antifouling pressure-sensitive adhesive tape, attaching aquatic organisms in the gaps between the antifouling pressure-sensitive adhesive tapes, and bending portions. It is to provide a method capable of solving the above-mentioned conventional problems such as workability and peeling of the antifouling adhesive tape.
- a method for preventing contamination of a structure includes the following step 1, and step 2a-1 to step 2a-2 or step 2b.
- Step 1 Antifouling pressure-sensitive adhesive tape having a base material layer (A) and an adhesive layer (A) provided on one side of the substrate layer, and one side easily adhered to the adhesive layer (A) Preparing an easy-adhesive pressure-sensitive adhesive tape having a base material layer (B) and a pressure-sensitive adhesive layer (B) provided on the other surface side, (Step 2a-1) affixing the easily adhesive pressure-sensitive adhesive tape to the surface of a structure having a surface to be prevented from being contaminated; (Step 2a-2) Affixing the antifouling adhesive tape on the affixed adhesive tape so that the longitudinal directions thereof are not parallel to each other; (Step 2b) Two or more antifouling pressure-sensitive adhesive tapes and at least one easy-adhesive pressure-sensitive adhesive tape are placed on the surface of
- the easy-adhesive pressure-sensitive adhesive tape is applied in parallel.
- the easy-adhesive pressure-sensitive adhesive tape is attached in a lattice shape.
- the easy-adhesive pressure-sensitive adhesive tape is affixed so that the longitudinal direction and / or the interval thereof are random.
- the antifouling agent is used such that the longitudinal direction of the easy-adhesive adhesive tape and the longitudinal direction of the antifouling adhesive tape form an angle of 30 ° to 150 °. Apply adhesive tape.
- the step 2b includes affixing the antifouling pressure-sensitive adhesive tape after affixing the easily adhesive pressure-sensitive adhesive tape to the surface to be prevented from being contaminated.
- the antifouling pressure-sensitive adhesive tape is shifted by a predetermined width from the surface of the base layer (B) of the easy-adhesive pressure-sensitive adhesive tape, and the longitudinal direction is made substantially parallel.
- the antifouling pressure-sensitive adhesive tape and the easy-adhesive pressure-sensitive adhesive tape are bonded together so that the antifouling pressure-sensitive adhesive tape does not overlap each other, and the joints are It includes affixing to the surface where the contamination is to be prevented while overlapping and shifting so as to be on the surface of the base material layer (B) of the adhesive pressure-sensitive adhesive tape.
- the step 2b is carried out so that the antifouling pressure-sensitive adhesive tapes do not overlap each other, and the joint is on the surface of the base material layer (B) of the easily adhesive pressure-sensitive adhesive tape.
- the antifouling pressure-sensitive adhesive tape and the easy-adhesive pressure-sensitive adhesive tape are alternately bonded together, and the antifouling pressure-sensitive adhesive tape and the easy-adhesive pressure-sensitive adhesive tape are bonded to the surface to be prevented from being contaminated. Includes pasting.
- the surface on which the contamination is to be prevented has a bent portion, and the easy-adhesive pressure-sensitive adhesive tape is disposed at the tip of the bent portion.
- the antifouling pressure-sensitive adhesive tape has an antifouling layer on the side of the base material layer (A) where the adhesive layer (A) is not provided.
- the surface on which contamination is to be prevented is the surface of an underwater structure.
- an adhesive tape set for the method for preventing contamination of the structure.
- the pressure-sensitive adhesive tape set includes an antifouling pressure-sensitive adhesive tape having a base material layer (A) and a pressure-sensitive adhesive layer (A) provided on one surface side thereof, and one surface of the pressure-sensitive adhesive layer (A).
- An easily adhesive pressure-sensitive adhesive tape having a base material layer (B) that is easily adhesive and an adhesive layer (B) provided on the other surface side is included.
- the antifouling pressure-sensitive adhesive tape is bonded to the surface of the base material layer (B) of the easy-adhesive pressure-sensitive adhesive tape while being shifted by a predetermined width and with the longitudinal direction being substantially parallel. ing.
- the antifouling pressure-sensitive adhesive tape is such that the antifouling pressure-sensitive adhesive tapes do not overlap each other and the joint is on the surface of the base material layer (B) of the easy-adhesive pressure-sensitive adhesive tape.
- the above-mentioned easily adhesive pressure-sensitive adhesive tape are alternately laminated.
- a structure is provided.
- the structure has a surface to be prevented from being contaminated, and has at least part of the surface having a base material layer (A) and an adhesive layer (A) provided on one surface side thereof.
- Adhesive tape has a base material (B) whose one surface is easily adhesive to the adhesive layer (A) and an adhesive layer (B) provided on the other surface side.
- the structure has a surface to be prevented from being contaminated, and at least a part of the surface is provided with the base material layer (A) and an adhesive layer provided on one surface side thereof.
- Two or more antifouling pressure-sensitive adhesive tapes having (A), and one surface is provided on the other surface side of the base material layer (B) which is easily adhesive to the pressure-sensitive adhesive layer (A).
- the structure is an underwater structure.
- the method for preventing contamination of a structure of the present invention by using an easily adhesive pressure-sensitive adhesive tape, the progress of peeling of the antifouling pressure-sensitive adhesive tape is suppressed, so that the problem of peeling off of the antifouling pressure-sensitive adhesive tape is solved. obtain. Moreover, peeling from the joint of the antifouling pressure-sensitive adhesive tape, adhesion of aquatic organisms in the gaps between the antifouling pressure-sensitive adhesive tapes, and workability problems with respect to the bent portion can be solved.
- (A) And (b) is a schematic sectional drawing of the antifouling adhesive tape which can be used with the pollution prevention method of this invention, respectively. It is a schematic sectional drawing of the easily-adhesive adhesive tape which can be used with the contamination prevention method of this invention. It is a figure explaining the sticking method of the easily-adhesive adhesive tape in process 2a-1. It is a figure explaining the sticking method of the easily-adhesive adhesive tape in process 2a-1. It is a figure explaining the sticking method of the easily-adhesive adhesive tape in process 2a-1. It is a figure explaining the sticking method of the easily-adhesive adhesive tape in process 2a-1. It is a figure explaining the sticking method of the easily-adhesive adhesive tape in process 2a-1.
- FIG. 2 is a schematic diagram illustrating one preferred embodiment of step 2b. It is the schematic explaining another preferable embodiment of the process 2b. It is the schematic explaining another preferable embodiment of the process 2b. It is the schematic explaining another preferable embodiment of the process 2b. It is the schematic explaining another preferable embodiment of the process 2b.
- the structure contamination prevention method of the present invention includes the following step 1 and steps 2a-1 to 2a-2 or 2b.
- the structure contamination prevention method of the present invention is an embodiment including Step 1 and Steps 2a-1 and 2a-2 (hereinafter referred to as “first embodiment”), or Step 1 and Step. 2b (hereinafter, referred to as “second embodiment”).
- Step 1 Antifouling pressure-sensitive adhesive tape having a base material layer (A) and an adhesive layer (A) provided on one side of the substrate layer, and one side easily adhered to the adhesive layer (A) Preparing an easy-adhesive pressure-sensitive adhesive tape having a base material layer (B) and a pressure-sensitive adhesive layer (B) provided on the other surface side, (Step 2a-1) affixing the easily adhesive pressure-sensitive adhesive tape to the surface of a structure having a surface to be prevented from being contaminated; (Step 2a-2) Affixing the antifouling adhesive tape on the affixed adhesive tape so that the longitudinal directions thereof are not parallel to each other; (Step 2b) Two or more antifouling pressure-sensitive adhesive tapes and at least one easy-adhesive pressure-sensitive adhesive tape are placed on the surface of a structure having a surface to be prevented from being contaminated, and the antifouling pressure-sensitive adhesive tape Affixing so that the joints are on the surface of the base material layer
- the structure contamination prevention method includes: An antifouling pressure-sensitive adhesive tape having a base material layer (A) and an adhesive layer (A) provided on one side of the base layer, and a group whose one surface is easily adhesive to the adhesive layer (A) Preparing an easily adhesive pressure-sensitive adhesive tape having a material layer (B) and a pressure-sensitive adhesive layer (B) provided on the other surface side (step 1); Affixing the easily adhesive pressure-sensitive adhesive tape to the surface of a structure having a surface to be prevented from being contaminated (step 2a-1), and attaching the antifouling adhesive tape to the affixed easily adhesive pressure-sensitive adhesive tape Affixing the tape so that the longitudinal directions are not parallel to each other (step 2a-2) including.
- the adhesive layer (A) of the antifouling adhesive tape and the adhesive layer (B) of the easy-adhesive adhesive tape and the adhesive force between the surface of the structure are peeled off.
- the antifouling pressure-sensitive adhesive tape can be prevented from peeling off while keeping it to a removable level. Specifically, for example, as shown in FIG.
- step 1 the antifouling pressure-sensitive adhesive tape having the base material layer (A) and the pressure-sensitive adhesive layer (A) provided on one surface thereof, and the one surface easy to the pressure-sensitive adhesive layer (A).
- An easy-adhesive pressure-sensitive adhesive tape having a base material layer (B) that is adhesive and a pressure-sensitive adhesive layer (B) provided on the other surface side is prepared. Note that step 1 is a step common to the first embodiment and the second embodiment, and substantially the same description can be applied to both embodiments.
- FIG. 2A is a schematic cross-sectional view of an antifouling adhesive tape that can be used in a preferred embodiment of the present invention.
- the antifouling pressure-sensitive adhesive tape 100a has a base material layer (A) 10 and an adhesive layer (A) 20 provided on one surface side thereof.
- FIG. 2B is a schematic cross-sectional view of an antifouling pressure-sensitive adhesive tape that can be used in another preferred embodiment of the present invention.
- the antifouling pressure-sensitive adhesive tape 100b further has an antifouling layer 30 on the surface side of the base material layer (A) 10 where the adhesive layer (A) 20 is not provided. Further, any appropriate other layer may be further included.
- a release film may be provided on the surface of the antifouling layer 30 and / or the surface of the adhesive layer (A) 20 of the antifouling adhesive tape.
- the thickness of the antifouling pressure-sensitive adhesive tape is set to any appropriate thickness within a range that does not impair the effects of the present invention, depending on the thickness of each layer included therein.
- the thickness of the antifouling pressure-sensitive adhesive tape is preferably 50 to 5000 ⁇ m.
- the antifouling pressure-sensitive adhesive tape any appropriate shape can be adopted depending on the application.
- the antifouling pressure-sensitive adhesive tape may be a strip-like long article, a strip, a piece, or the like.
- the lengths of the long side and the short side of the antifouling pressure-sensitive adhesive tape any appropriate length can be adopted depending on the application or use environment.
- the material for the base material layer (A) is preferably excellent in water resistance, strength, flexibility and tearability.
- Examples of the material of the base material layer (A) include polyurethane resin, polyurethane acrylic resin, rubber resin, vinyl chloride resin, polyester resin, silicone resin, elastomers, fluororesin, polyamide resin, and polyolefin resin (polyethylene). And polypropylene) and polystyrene resin.
- Such a material of the base material layer (A) may be only one kind or two or more kinds.
- the elongation of the base material layer (A) is preferably 100% or more, more preferably 120% or more, and further preferably 150% or more.
- the antifouling pressure-sensitive adhesive tape can follow the shape of various structures well and can be affixed to a flat surface well. Curved surface portion, 90-degree angle portion, acute angle portion, etc.).
- the elongation of the base material layer (A) is less than 100%, it cannot sufficiently follow the shape of various structures, and unbonded portions of wrinkles and pressure-sensitive adhesives are generated, resulting in poor appearance and poor adhesion. There is a risk.
- the upper limit of the elongation of the base material layer (A) is preferably 2000% or less from the viewpoint of the strength of the base material layer (A).
- the base material layer (A) has a stress at breakage of preferably 10 MPa or more, more preferably 12 MPa or more, and further preferably 15 MPa or more.
- the upper limit of the stress at break of the base material layer (A) is preferably 200 MPa or less from the viewpoint of the handleability of the base material layer (A).
- the elongation and stress at break of the substrate layer (A) can be measured according to JIS 7161, JIS 7162, and JIS 7172.
- the elastic modulus of the base material layer (A) is preferably 4000 MPa or less, more preferably 1000 MPa or less, still more preferably 100 MPa or less, and particularly preferably 50 MPa or less.
- the lower limit of the elastic modulus of the base material layer (A) is preferably 0.1 MPa or more from the viewpoint of the handleability of the base material layer (A).
- the base material layer (A) may contain any appropriate additive as long as the effects of the present invention are not impaired.
- additives include olefin resins, silicone polymers, liquid acrylic copolymers, tackifiers, anti-aging agents, hindered amine light stabilizers, ultraviolet absorbers, antioxidants, and antistatic agents. , Polyethyleneimine, fatty acid amide, fatty acid ester, phosphate ester, lubricant, surfactant, filler and pigment (for example, calcium oxide, magnesium oxide, silica, zinc oxide, titanium oxide, carbon black, etc.).
- the base material layer (A) preferably contains an ultraviolet absorber.
- the base material layer (A) contains the ultraviolet absorber, the weather resistance of the antifouling adhesive tape is improved.
- the base material layer (A) does not contain an ultraviolet absorber, the base material is likely to be deteriorated by sunlight during outdoor use, and it may be difficult to maintain the initial base material strength. And when a base material deteriorates, when peeling off used antifouling adhesive tape from a structure, a base material layer (A) will cut
- the thickness of the base material layer (A) is preferably 20 to 500 ⁇ m.
- the thickness of the base material layer (A) is thinner than 20 ⁇ m, the handling property is deteriorated, the role as a base material cannot be fulfilled, and there is a possibility that it is not practical.
- the thickness of the base material layer (A) is thicker than 500 ⁇ m, it is impossible to sufficiently follow the shape of the structure, the concavities and convexities at the joint portion of the tape become large, and there is a possibility that the dirt is easily attached.
- the base material layer (A) may be pre-coated with a primer in order to improve adhesion with the antifouling layer, A silane coupling agent may be added in advance.
- the adhesion to the base material layer (A) may be low due to the low surface energy that is a characteristic of the silicone resin. If the adhesion between the antifouling layer and the base material layer (A) is low, the antifouling layer exhibiting the antifouling effect peels off from the base material layer (A) due to impact or physical damage during use. The antifouling effect may not be sustained.
- a primer is applied to the surface of the base material layer (A) in advance to improve the adhesion with the antifouling layer, or a silanol group or an alkoxysilane group that reacts with the silicone resin is added to the base material layer (silane coupling agent). It can be introduced into A) and subjected to a condensation reaction with a reactive group on the base material layer (A) at the time of application of the condensation type silicone resin to improve the adhesion.
- silane coupling agent Only one type of silane coupling agent may be used, or two or more types may be used. Specific examples of commercially available silane coupling agents include KBM5103, KBM1003, KBM903, KBM403, and KBM802 manufactured by Shin-Etsu Chemical Co., Ltd.
- the content of the silane coupling agent in the substrate layer (A) is preferably 0.01 to 10% by weight.
- the content rate of the silane coupling agent in a base material layer (A) exceeds 10 weight%, there exists a possibility that a silane coupling agent may become a crosslinking point and a base material layer (A) may become hard.
- the content rate of the silane coupling agent in a base material layer (A) is less than 0.01 weight%, there exists a possibility that sufficient adhesiveness cannot be expressed between a base material layer (A) and an antifouling layer.
- the surface of the base material layer (A) on which the adhesive layer (A) is provided may be subjected to an easy adhesion treatment.
- the easy adhesion treatment By performing the easy adhesion treatment, the adhesive residue at the time of peeling and removal can be suppressed.
- Examples of the easy adhesion treatment include the same treatment as the treatment applied to the surface of the base material layer (B) (details will be described later) of the easy adhesion pressure-sensitive adhesive tape.
- any appropriate adhesive layer can be adopted as the adhesive layer (A) as long as the effects of the present invention are not impaired.
- the material for the adhesive layer (A) include acrylic resin adhesives, epoxy resin adhesives, amino resin adhesives, vinyl resin (vinyl acetate polymers, etc.) adhesives, and curable acrylics. Examples thereof include a resin-based adhesive and a silicone resin-based adhesive. Only one type of material for the adhesive layer (A) may be used, or two or more types may be used.
- the adhesive layer (A) has a 180-degree peel adhesive strength at 23 ° C. and a tensile speed of 300 mm / min, preferably 30 N / 20 mm or less, more preferably 20 N / 20 mm or less, and further preferably 15 N / 20 mm or less.
- a tensile speed of 300 mm / min of the adhesive layer (A) is preferably 5 N / 20 mm or more.
- an adhesive strength it is possible to adhere very firmly to the surface of the base material layer (B) of the easy-adhesive pressure-sensitive adhesive tape described later. Therefore, even if it peels off from the surface of the said structure and receives fluid resistance, it can prevent that peeling progresses beyond an adhesion point with an easily-adhesive adhesive tape.
- the 180 degree peel adhesive strength of the pressure-sensitive adhesive layer (A) can be measured, for example, as follows. That is, the pressure-sensitive adhesive layer (A) is laminated on the base material to prepare a pressure-sensitive adhesive sheet, which is cut into a test piece size of 80 mm ⁇ 20 mm. As the adherend, a plastic FRP plate reinforced by putting a glass cloth in an epoxy resin of 30 mm ⁇ 100 mm ⁇ thickness 2 mm is used. The test piece is attached to the adherend by reciprocating once with a 2 kg roller, and left at 23 ° C. for 30 minutes, and then the initial 180-degree peel adhesive strength is measured at a tensile speed of 300 mm / min.
- the compression elastic modulus of the portion of the pressure-sensitive adhesive layer (A) in contact with seawater is smaller than that of the pressure-sensitive adhesive layer (A) before seawater contact.
- the ratio is preferably 1.1 times or more, more preferably 1.2 times or more, and further preferably 1.5 times or more.
- the compression elastic modulus of the portion of the pressure-sensitive adhesive layer (A) in contact with seawater is 1. of the compression elastic modulus in the pressure-sensitive adhesive layer (A) before seawater contact. If it is 1 or more times, favorable adhesiveness can be expressed also in water.
- the ratio of the compression elastic modulus of the portion of the pressure-sensitive adhesive layer (A) in contact with seawater to the compression elastic modulus of the pressure-sensitive adhesive layer (A) before seawater contact The upper limit is preferably 100 times or less from the viewpoint of handleability.
- the thickness of the adhesive layer (A) is preferably 10 ⁇ m or more. If the thickness of the pressure-sensitive adhesive layer (A) is less than 10 ⁇ m, it is impossible to sufficiently follow the shape of the structure, the adhesion area is reduced, and there is a possibility that sufficient pressure-sensitive adhesive force cannot be expressed.
- the upper limit of the thickness of the pressure-sensitive adhesive layer (A) is preferably 100 ⁇ m or less from the viewpoint of handleability.
- the material for forming such an antifouling layer includes, for example, a resin having a small surface energy such as a fluorine resin, a silicone resin, a melamine resin, and an acrylic resin.
- the antifouling layer preferably further contains an antifouling agent. Only one type of antifouling agent may be used, or two or more types may be used. When the antifouling layer contains an antifouling agent, the antifouling agent moves to the surface of the resin as a matrix and covers the surface, whereby a high antifouling effect can be maintained for a long time.
- the content ratio of the antifouling agent to the resin is preferably 2% by weight or more, more preferably 2 to 200% by weight, further preferably 3 to 150% by weight, particularly preferably 4 to 120% by weight, Most preferably, it is 5 to 100% by weight.
- the content ratio of the antifouling agent to the resin is less than 2% by weight, the antifouling effect of the antifouling layer may not be sufficiently exhibited.
- the content of the antifouling agent with respect to the base resin exceeds 200% by weight, the appearance of the final molded product or the film may be deteriorated, and the antifouling layer cannot be maintained due to a decrease in strength of the antifouling layer. There is a fear.
- any appropriate antifouling agent can be adopted as long as the effects of the present invention are not impaired.
- examples of such an antifouling agent include silicone oil, liquid paraffin, surfactant, wax, petrolatum, animal fats, fatty acids and the like.
- the antifouling agent that can be used in the present invention is preferably at least one selected from silicone oil, liquid paraffin, and surfactant.
- silicone oil for example, KF96L, KF96, KF69, KF99, KF50, KF54, KF410, KF412, KF414, FL manufactured by Shin-Etsu Chemical Co., Ltd., BY16-846, SF8416, SH203 manufactured by Toray Dow Corning Co., Ltd. , SH230, SF8419, FS1265, SH510, SH550, SH710, FZ-2110, FZ-2203.
- surfactant examples include an anionic surfactant, a cationic surfactant, and a nonionic surfactant.
- antifouling agents diatomaceous adhesion inhibitors, agricultural chemicals, pharmaceuticals (such as medetomidine), enzyme activity inhibitors (such as alkylphenols and alkylresorcinol), and biological repellents may be used.
- pharmaceuticals such as medetomidine
- enzyme activity inhibitors such as alkylphenols and alkylresorcinol
- biological repellents may be used.
- the antifouling layer may contain any appropriate other additive as long as the effects of the present invention are not impaired.
- a commercially available coating composition can be used as the antifouling layer forming material.
- examples of the commercially available coating composition include trade names “Peracrine” and “Bioclin” manufactured by China Paint Co., Ltd., and “Everclean” manufactured by NKM Coatings.
- the thickness of the antifouling layer may be any appropriate thickness depending on the application and usage environment.
- the thickness of the antifouling layer is preferably 5 to 500 ⁇ m. When the thickness of the antifouling layer is less than 5 ⁇ m, the period during which the antifouling effect is effective is shortened and may not be practical. If the antifouling layer is thicker than 500 ⁇ m, the antifouling pressure-sensitive adhesive tape becomes thick and increases in weight, so that the handling property is deteriorated, the unevenness of the joint portion of the tape is increased, and there is a possibility that the stain is easily attached.
- ⁇ Anti-fouling adhesive tape can be produced by any appropriate method.
- a separately prepared base material layer (A) and an adhesive layer (A) are bonded together, and an adhesive layer forming material is applied to one surface of the base material layer (A) for adhesion.
- a method for forming the layer (A), a separately prepared base material layer (A) and an adhesive layer (A) are bonded together, and then an antifouling layer forming material is applied onto the base material layer (A) to prevent the antifouling layer.
- the adhesive layer forming material is applied to one surface of the base material layer (A) to form the adhesive layer (A), and the antifouling layer forming material is applied to the other surface of the base material layer (A).
- a method for forming an antifouling layer by coating a base material layer forming material and an adhesive layer forming material is coextruded to form a base material layer (A) / adhesive layer (A) laminate.
- Examples thereof include a method of forming the antifouling layer by applying the forming material on the base material layer (A).
- Examples of the method for applying the antifouling layer forming material on the base material layer include spraying, brushing, roller, curtain flow, roll, dip and the like.
- the antifouling layer-forming material is applied onto the base material layer by these methods, and the antifouling layer is formed, for example, by drying at a temperature from room temperature to 250 ° C. (preferably from room temperature to 180 ° C.). can do.
- FIG. 3 is a schematic cross-sectional view of an easily adhesive pressure-sensitive adhesive tape that can be used in the present invention.
- the easy-adhesive pressure-sensitive adhesive tape 200 includes a base material layer (B) 40 and a pressure-sensitive adhesive layer (B) 50 provided on one surface side thereof.
- a release film may be provided on the surface of the base material layer (B) 40 and / or the surface of the pressure-sensitive adhesive layer (B) 50 of the easily adhesive pressure-sensitive adhesive tape.
- the thickness of the easy-adhesive pressure-sensitive adhesive tape is set to any appropriate thickness within a range that does not impair the effects of the present invention, depending on the thickness of each layer included therein.
- the thickness of the easily adhesive pressure-sensitive adhesive tape is preferably 50 to 5000 ⁇ m.
- the easy-adhesive pressure-sensitive adhesive tape any appropriate shape can be adopted depending on the application.
- the easy-adhesive pressure-sensitive adhesive tape may be a strip-like long article, a strip, a small piece, or the like.
- the lengths of the long side and the short side of the easily adhesive pressure-sensitive adhesive tape any appropriate length can be adopted depending on the application and use environment.
- the easy-adhesive pressure-sensitive adhesive tape only needs to be disposed under the antifouling pressure-sensitive adhesive tape (in the antifouling method of the second embodiment described below, below the joint between the antifouling pressure-sensitive adhesive tapes), and has a large area.
- the tape can be narrower than the antifouling adhesive tape.
- the length of the short side of the easily adhesive pressure-sensitive adhesive tape may be, for example, in the range of 0.5 to 50 cm, preferably 1 to 30 cm.
- the material for the base material layer (B) is preferably excellent in water resistance, strength, flexibility and tearability.
- Examples of the material of the base material layer (B) include polyurethane resin, polyurethane acrylic resin, rubber resin, vinyl chloride resin, polyester resin, silicone resin, elastomers, fluororesin, polyamide resin, and polyolefin resin (polyethylene). , Polypropylene, etc.), polystyrene resin, polyimide resin, polyethylene terephthalate resin, aramid (paper), glass cloth, nylon cloth and the like.
- Such a material of the base material layer (B) may be only one kind or two or more kinds.
- the base material layer (B) has a stress at breakage of preferably 10 MPa or more, more preferably 12 MPa or more, and further preferably 15 MPa or more.
- the base material layer (B) is broken due to the stress that the peeled antifouling adhesive tape receives from the fluid resistance, for example, the breakage. Can be suppressed. As a result, the progress of peeling can be suppressed.
- the breakage of the base material layer (B) at the joint of the antifouling pressure-sensitive adhesive tape for example, the breakage can be suppressed, and as a result, the strength of the joint is reduced. It can be equal to or higher than the strength of the tape.
- the upper limit of the stress at break of the base material layer (B) is preferably 200 MPa or less from the viewpoint of the handleability of the base material layer (B).
- the stress at break of the base material layer (B) can be measured according to JIS 7161, JIS 7162, and JIS 7172.
- the surface of the base material layer (B) on which the adhesive layer (B) is not provided is easily adhesive to the adhesive layer (A) of the antifouling adhesive tape (hereinafter, this surface is referred to as “easily adhesive”). Sometimes referred to as “surface”).
- the adhesive force between the pressure-sensitive adhesive layer (A) and the easy-adhesion surface is larger than the adhesive force between the pressure-sensitive adhesive layer (A) and the surface on which contamination of the structure is to be prevented. Accordingly, the antifouling pressure-sensitive adhesive tape can be very firmly bonded onto the easily adhesive pressure-sensitive adhesive tape.
- the antifouling pressure-sensitive adhesive tape is peeled off and the peeled portion is subjected to fluid resistance, it is difficult to peel and remove the adhesive force between the surface of the structure and the antifouling pressure-sensitive adhesive tape.
- the progress of peeling can be suitably suppressed without increasing to a certain level.
- without increasing the adhesive force between the surface of the structure and the antifouling pressure-sensitive adhesive tape to a level at which peeling and removal are difficult, from the joint of the antifouling pressure-sensitive adhesive tape. can be suitably prevented.
- the adhesive strength of the antifouling pressure-sensitive adhesive tape to the easy-adhesive surface of the easy-adhesive pressure-sensitive adhesive tape (180-degree peel adhesive strength at 23 ° C. and a tensile speed of 300 mm / min) is preferably 15 N / 20 mm or more, more preferably 20 N / 20 mm. That's it.
- This adhesive force can be measured on the same conditions as the 180 degree
- the surface of the base material layer (B) where the adhesive layer (B) is not provided may be subjected to an easy adhesion treatment for making the adhesive layer (A) easily adhesive.
- an easy adhesion treatment for making the adhesive layer (A) easily adhesive.
- Any appropriate chemical surface treatment, physical surface treatment, and combinations thereof may be used as the easy adhesion treatment.
- Specific examples include vapor deposition of metals, oxides, inorganics, etc .; sputtering of oxygen, nitrogen, argon, etc .; plasma treatment; acids such as hydrochloric acid, sulfuric acid, nitric acid, alkalis such as sodium hydroxide, potassium hydroxide, or organic solvents Surface treatment by UV; ozone irradiation; corona discharge treatment; flame treatment; application of coupling agent; roughening treatment by mold shape transfer, sand blasting, stretching and bending; filler to substrate forming material, coupling agent And the like.
- an easy adhesion treatment can be performed on the surface of the base material layer (B) on the side where the adhesive layer (B) is provided for the purpose of suppressing adhesive residue at the time of peeling and removing.
- UV / ozone irradiation, surface treatment with alkali (saponification), or addition of a filler, a coupling agent or the like to the substrate forming material is preferable. It is because both surfaces of the base material layer (B) can be processed simultaneously.
- the thickness of the base material layer (B) is preferably 20 to 500 ⁇ m.
- the thickness of the base material layer (B) is thinner than 20 ⁇ m, the handling property is deteriorated, the role as a base material cannot be fulfilled, and there is a possibility that it is not practical.
- the thickness of the base material layer (B) is thicker than 500 ⁇ m, it may not be possible to sufficiently follow the shape of the structure.
- any appropriate adhesive layer can be adopted as the adhesive layer (B) as long as the effects of the present invention are not impaired.
- the adhesive layer similar to the adhesive layer (A) is mentioned.
- the easy-adhesive pressure-sensitive adhesive tape can be produced by any appropriate method.
- a separately prepared base material layer (B) and an adhesive layer (B) are bonded together, and the adhesive layer (B) forming material is applied to one surface of the base material layer (B).
- coating and forming an adhesion layer (B), the method of coextruding a base material layer (B) formation material and an adhesion layer (B) formation material, etc. are mentioned.
- the base layer (B) may be subjected to easy adhesion treatment before lamination with the pressure-sensitive adhesive layer (B), or may be subjected to easy adhesion treatment after lamination.
- an easily adhesive pressure-sensitive adhesive tape is applied to the surface of a structure having a surface to be prevented from being contaminated.
- it is two or more sheets. Adhering two or more sheets increases the point of adhesion of the antifouling adhesive tape to the easily adhesive pressure-sensitive adhesive tape, so that the progress of peeling can be subdivided and suppressed in stages.
- Two or more easy-adhesive pressure-sensitive adhesive tapes 200 may be affixed in parallel at equal intervals to the surface of the structure 60 (in the illustrated example, a ship) as exemplified in FIGS. 4 (a) and 4 (b).
- 5 may be applied in parallel at unequal intervals as illustrated in FIG. 5, may be applied in a lattice shape as illustrated in FIG. 6, or may be applied over the entire surface as illustrated in FIG.
- FIGS. 8A and 8B the angles and intervals formed by the respective longitudinal directions may be affixed at random.
- the easily adhesive pressure-sensitive adhesive tape is preferably applied with an interval of 0.1 to 5 m, more preferably 0.3 to 3 m. With such an interval, the progress of peeling of the antifouling adhesive tape can be subdivided stepwise and economically prevented.
- the adhesive tape is affixed non-linearly (for example, shown in FIG. 8B), the direction in which the straight line connecting the center points of the short sides extends is the longitudinal direction.
- the structure having a surface to be prevented from being contaminated may be any appropriate structure as long as it has a surface to be prevented from being contaminated.
- Examples of such structures include ships, buoys, harbor facilities, offshore oil field facilities, underwater structures such as cooling water supply channels for power plants, cooling water supply channels for factories, propellers for wind power generation, piers, buildings, automobiles, etc. , Heavy machinery and aircraft, and preferably an underwater structure.
- an antifouling paint or an anticorrosive paint may be applied to the surface where the contamination of the structure is to be prevented.
- step 2a-2 the antifouling adhesive tape is affixed on the easily adhesive pressure-sensitive adhesive tape affixed in step 2a-1 so that the longitudinal directions thereof are not parallel to each other.
- the antifouling pressure-sensitive adhesive tape 100b receives the stress a due to fluid resistance such as water flow or airflow, and the above structure
- the antifouling pressure-sensitive adhesive tape 100b exceeds the adhesion point b with the easy-adhesive pressure-sensitive adhesive tape 200a due to the strong adhesion between the antifouling pressure-sensitive adhesive tape 100b and the easy-adhesion pressure-sensitive adhesive tape 200a. It can prevent peeling.
- the stress by the fluid resistance with respect to the peeling part of the adhesive tape for antifouling is large, there exists a possibility that the adhesive tape for antifouling may peel with the easily-adhesive adhesive tape.
- the antifouling pressure-sensitive adhesive tape is preferably non-parallel to the longitudinal direction of all the easy-adhesive pressure-sensitive adhesive tapes.
- some of the easily adhesive pressure-sensitive adhesive tapes may be attached so that their longitudinal directions are parallel to each other.
- the angle formed by the longitudinal direction of the easily adhesive pressure-sensitive adhesive tape and the longitudinal direction of the antifouling pressure-sensitive adhesive tape is preferably 30 to 150 °, more preferably 45 to 135 °, still more preferably 60 to 120 °, and particularly preferably 80. ° to 100 °.
- the direction of peeling of each adhesive tape is greatly different, so it is preferable that both adhesive tapes are peeled together. Can be prevented.
- the number of adhesion points of the antifouling pressure-sensitive adhesive tape to the easily adhesive pressure-sensitive adhesive tape is preferably 2 or more, more preferably 3 or more.
- the distance between the adhesion points is preferably 0.1 to 5 m, more preferably 0.3 to 3 m. With such an interval, the progress of peeling of the antifouling adhesive tape can be subdivided stepwise and economically prevented.
- a construction liquid containing a surfactant is used from the viewpoint of preventing air bubbles and the like.
- any appropriate construction liquid can be used from the same viewpoint.
- the construction liquid in step 2a-2 it is preferable that the adjacent antifouling pressure-sensitive adhesive tape be applied without overlapping. This is because the construction liquid can be easily extruded from the joint, and as a result, it can be applied with good adhesion.
- Adjacent antifouling adhesive tape is preferably abutted and applied so that there is no gap at the joint, but in the case where it is difficult to affix and affix, it is possible to easily eliminate the construction liquid
- the end portions of the adjacent antifouling pressure-sensitive adhesive tape may be stacked and pasted.
- the overlapping width is preferably 1 cm or less.
- a gap (for example, 1 cm or less) may exist at the joint between the antifouling pressure-sensitive adhesive tapes as long as the effects of the present invention are not impaired.
- the antifouling adhesive tape 100 may be applied so that its longitudinal direction is parallel to the direction in which the stress a due to fluid resistance such as water flow or airflow acts. As shown in FIG. 9 (b), it may be affixed in a direction perpendicular to the direction in which the stress a acts, or may be affixed in a direction that is neither parallel nor orthogonal to the direction in which the stress acts. Good.
- the structure contamination prevention method of the second embodiment of the present invention is as follows.
- An antifouling pressure-sensitive adhesive tape having a base material layer (A) and an adhesive layer (A) provided on one side of the base layer, and a group whose one surface is easily adhesive to the adhesive layer (A)
- At least one piece of the easily adhesive pressure-sensitive adhesive tape is bonded to the surface of the structure having a surface to be prevented from being contaminated so that the antifouling pressure-sensitive adhesive tape does not overlap with each other, and the joint thereof is the easy adhesion.
- the adhesive layer (A) of the antifouling adhesive tape and the adhesive layer (B) of the easy-adhesive adhesive tape and the adhesive force between the surface of the structure are peeled off.
- the pressure-sensitive adhesive layer (A) of the antifouling pressure-sensitive adhesive tape and the base material layer (B) of the easily-adhesive pressure-sensitive adhesive tape can be bonded extremely firmly while being suppressed to the extent that they can be removed. As a result, it is possible to suppress peeling of the antifouling adhesive tape from the joints without deteriorating workability during peeling and removal.
- the easy-adhesive adhesive tape is disposed under the joint between the antifouling adhesive tapes, even if a gap is formed in the joint and aquatic organisms adhere.
- the area that can be attached is small and can be easily removed by peeling the adhesive tape.
- step 1 the antifouling pressure-sensitive adhesive tape having the base material layer (A) and the pressure-sensitive adhesive layer (A) provided on one surface thereof, and the one surface easy to the pressure-sensitive adhesive layer (A).
- An easy-adhesive pressure-sensitive adhesive tape having a base material layer (B) that is adhesive and a pressure-sensitive adhesive layer (B) provided on the other surface side is prepared.
- step 1 the same explanation as step 1 in the first embodiment can be applied.
- step 2b In step 2b, as shown in FIG. 10, two or more antifouling pressure-sensitive adhesive tapes 100 and at least one easy-adhesive pressure-sensitive adhesive tape 200 have a structure 60 having a surface to be prevented from being contaminated.
- the antifouling pressure-sensitive adhesive tape 100 is affixed to the surface of the substrate so that the antifouling pressure-sensitive adhesive tapes 100 do not overlap each other, and the joint is on the surface of the base material layer (B) 40 of the easy-adhesive adhesive tape 200.
- an antifouling pressure-sensitive adhesive tape is applied so as to cover the entire surface to be prevented from being contaminated, but if necessary, only a desired portion (for example, a bent portion described later) of the surface is applied. You may stick so that it may cover.
- step 2b preferably, the adjacent antifouling pressure-sensitive adhesive tape is abutted and stuck so as not to cause a gap at the joint, but the gap (for example, 1 cm) is bonded to the joint as long as the effect of the present invention is not impaired.
- the gap for example, 1 cm
- both end portions of the antifouling pressure-sensitive adhesive tape may overlap each other by 1 cm or more on the easy-adhesive pressure-sensitive adhesive tape. .
- a working solution containing a surfactant is used from the viewpoint of preventing the entrapment of bubbles.
- any appropriate construction liquid can be used from the same viewpoint.
- the antifouling pressure-sensitive adhesive tape is applied without being overlapped, the construction liquid can be easily extruded from the joint, and as a result, it can be applied with good adhesion.
- the antifouling pressure-sensitive adhesive tape is bonded so that the end portions overlap, there is a problem in that there is no escape space for the construction liquid and adhesion can be reduced.
- the structure having a surface to be prevented from being contaminated may be any appropriate structure as long as it has a surface to be prevented from being contaminated.
- Examples of such structures include ships, buoys, harbor facilities, offshore oil field facilities, underwater structures such as cooling water supply channels for power plants, cooling water supply channels for factories, propellers for wind power generation, piers, buildings, automobiles, etc. , Heavy machinery and aircraft, and preferably an underwater structure.
- an antifouling paint or an anticorrosive paint may be applied to the surface where the contamination of the structure is to be prevented.
- the surface to be prevented from being contaminated has a bent portion, it may be difficult to fold and apply the antifouling adhesive tape to a sharp bent portion.
- the antifouling adhesive tape is abutted and applied so that the joint is arranged at the end of the bent part (for example, the ridge line)
- the application work becomes easy, but severe conditions such as a strong water flow hit the joint. There is a risk of peeling due to exposure.
- the easily adhesive pressure-sensitive adhesive tape is disposed at the tip of the bent portion. As a specific example, FIG.
- FIG. 11 shows a schematic diagram for explaining a preferable arrangement state of the antifouling adhesive tape and the easy-adhesive adhesive tape when the surface to be prevented from being contaminated is a bow (FIG. 11A).
- FIG. 11B is a perspective view of the bow, and
- FIG. 11B is a top view).
- positioning state of the antifouling adhesive tape and an easily-adhesive adhesive tape in case the surface where the said contamination should be prevented is a stern is shown in FIG.
- the easy-adhesive adhesive tape 200 is applied to the end of the bent portion, and then the antifouling adhesive tape 100 is abutted and applied so that the joint is at the end.
- the “tip of the bent portion” is a portion of the bent line with respect to the bent portion that is bent linearly, and the portion with the largest curvature with respect to the bent portion of the bent portion.
- FIG. 13 is a schematic diagram illustrating one preferred embodiment (embodiment a) of step 2b.
- the anti-stain adhesive tape 100 is applied after the easy-adhesive adhesive tape 200 is applied to the surface (in the illustrated example, the bottom of the ship) where contamination of the structure 60 is to be prevented.
- an easy-adhesive pressure-sensitive adhesive tape is applied in advance to the joints of the antifouling pressure-sensitive adhesive tape, and then the end portions are arranged on the easy-adhesive pressure-sensitive adhesive tape and do not overlap each other. Affix an antifouling adhesive tape.
- FIG. 14 and FIG. 15 are schematic diagrams for explaining another preferred embodiment (embodiment b) of the step 2b.
- the antifouling pressure-sensitive adhesive tape 100 is preliminarily shifted from the surface of the base layer (B) 40 of the easy-adhesive pressure-sensitive adhesive tape 200 by a predetermined width (a), and the longitudinal direction is substantially parallel.
- two or more sets of the antifouling pressure-sensitive adhesive tape 100 and the easy-adhesive pressure-sensitive adhesive tape 200 are joined so that the antifouling pressure-sensitive adhesive tape 100 does not overlap with each other.
- the shift width a when the antifouling pressure-sensitive adhesive tape is bonded to the surface of the base material layer (B) of the easy-adhesive pressure-sensitive adhesive tape can function as an adhesion allowance for the antifouling pressure-sensitive adhesive tape to be bonded thereon. For example, about 1 to 20 cm, preferably about 5 to 10 cm.
- Embodiment b since the antifouling pressure-sensitive adhesive tape and the easy-adhesive pressure-sensitive adhesive tape are integrated onto the surface of the structure, the alignment of the pressure-sensitive adhesive tape is relatively easy. As a result, since the bonding allowance is small, an easily adhesive pressure-sensitive adhesive tape having a narrower width than that used in the embodiment a can be used.
- the adhesive tape 300 which bonded the antifouling adhesive tape 100 and the easily-adhesive adhesive tape 200 was prepared previously, and this bonded adhesive tape 300 was prepared.
- the antifouling pressure-sensitive adhesive tape 100 and the easy-adhesive pressure-sensitive adhesive tape 200 may be bonded together, and the structure 60 of the bonded pressure-sensitive adhesive tape may be attached. You may perform the sticking to the surface continuously.
- FIG. 16 is a schematic diagram illustrating still another preferred embodiment (embodiment c) of step 2b.
- the antifouling pressure-sensitive adhesive tapes 100 are preliminarily protected so as not to overlap each other and the joints are on the surface of the base material layer (B) 40 of the easy-adhesive pressure-sensitive adhesive tape 200.
- the soiling pressure-sensitive adhesive tape 100 and the easily adhesive pressure-sensitive adhesive tape 200 are alternately bonded, and then the bonded antifouling pressure-sensitive adhesive tape and the easily adhesive pressure-sensitive adhesive tape are bonded to the surface of the structure 60.
- the same number of antifouling adhesive tapes and easy-adhesive adhesive tapes may be alternately bonded, and one of the adhesive tapes is bonded together so that both ends become the same adhesive tape. May be.
- the total number of adhesive tapes to be bonded can be appropriately set according to workability and the like, and is preferably 3 to 8 sheets.
- the antifouling pressure-sensitive adhesive tape and the easily adhesive pressure-sensitive adhesive tape are integrated on the surface of the structure after being integrated as in the case of the embodiment b, the alignment of the pressure-sensitive adhesive tape is relatively easy. As a result, since the bonding allowance is small, an easily adhesive pressure-sensitive adhesive tape having a narrower width than that used in the embodiment a can be used.
- step 2b only one of the above embodiments a to c may be performed or a combination of two or more may be performed depending on the shape, size, etc. of the structure.
- the pressure-sensitive adhesive tape set of the present invention is a pressure-sensitive adhesive tape set for use in the structure contamination prevention method of the second embodiment, and is a base material layer (A) and a pressure-sensitive adhesive layer provided on one surface side thereof.
- An antifouling adhesive tape having (A), a base material layer (B) whose one surface is easily adhesive to the adhesive layer (A), and an adhesive layer provided on the other surface side ( B) and an easily adhesive pressure-sensitive adhesive tape.
- the details of the antifouling pressure-sensitive adhesive tape and the easily adhesive pressure-sensitive adhesive tape are as described in the above section A.
- the adhesive tape set has the antifouling adhesive tape shifted by a predetermined width on the surface of the base material layer (B) of the easy-adhesive adhesive tape, and the longitudinal direction is substantially parallel. It may be in the form of being laminated together.
- the adhesive tape set of such a form can be suitably applied in the embodiment b of the step 2b, and can be provided as a wound body as shown in FIG.
- the pressure-sensitive adhesive tape set is such that the antifouling pressure-sensitive adhesive tapes do not overlap each other, and the joint is on the surface of the base material layer (B) of the easy-adhesive pressure-sensitive adhesive tape.
- the antifouling pressure-sensitive adhesive tape and the easily adhesive pressure-sensitive adhesive tape may be alternately bonded.
- the same number of antifouling adhesive tapes and easy-adhesive adhesive tapes may be bonded together, and either one of the adhesive tapes is bonded together so that both ends are the same adhesive tape. It may be done.
- the total number of adhesive tapes to be bonded can be, for example, 3 to 8.
- the adhesive tape set of such a form can be suitably applied in the embodiment c of the above step 2b, and can be exemplified, for example, in FIG.
- the structure according to one embodiment of the present invention has a surface to be prevented from being contaminated, and at least a part of the surface includes a base material layer (A) and an adhesive layer (on one surface side) A) an antifouling pressure-sensitive adhesive tape comprising a base material (B) whose one surface is easily adhesive to the pressure-sensitive adhesive layer (A) and a pressure-sensitive adhesive layer (B) provided on the other surface side Are attached so that their longitudinal directions are not parallel to each other.
- the details of the antifouling pressure-sensitive adhesive tape and the easy-adhesive pressure-sensitive adhesive tape and the attaching method thereof are the same as described for the structure contamination prevention method of the first embodiment.
- the structure according to another embodiment of the present invention has a surface to be prevented from being contaminated, and at least a part of the surface includes a base material layer (A) and an adhesive layer (on one surface side) A) and two or more antifouling adhesive tapes, and one surface is provided on the other surface side with the base material layer (B) being easily adhesive to the adhesive layer (A).
- At least one easy-adhesive pressure-sensitive adhesive tape having an adhesive layer (B) so that the antifouling pressure-sensitive adhesive tapes do not overlap each other, and the joint is a base material layer (B ) Affixed to be on the surface.
- the details of the antifouling pressure-sensitive adhesive tape, the easy-adhesive pressure-sensitive adhesive tape, and the application method thereof are as described for the structure contamination prevention method of the second embodiment.
- the structure can be any suitable structure as long as it has a surface to be prevented from contamination.
- suitable structures include ships, buoys, harbor facilities, offshore oil field facilities, underwater structures such as cooling water supply channels for power plants, cooling water supply channels for factories, propellers for wind power generation, piers, buildings, automobiles, etc. , Heavy machinery and aircraft.
- the structure is preferably an underwater structure because the effect of the pollution prevention method of the present invention is suitably obtained.
- Example A-1 Anti-fouling adhesive tape
- a reaction vessel equipped with a condenser, a thermometer, and a stirrer as a (meth) acrylic monomer, isobornyl acrylate (trade name “IBXA”, manufactured by Osaka Organic Chemical Industry Co., Ltd.): 71 parts by weight, n -Butyl acrylate (BA, manufactured by Toagosei Co., Ltd.): 19 parts by weight, acrylic acid (AA): 10 parts by weight, poly (oxytetramethylene) glycol having a number average molecular weight of 650 as a polyol (PTMG650, Mitsubishi Chemical Corporation) Manufactured): 68.4 parts by weight, dibutyltin dilaurate (DBTL): 0.01 parts by weight as a catalyst, and hydrogenated xylylene diisocyanate (HXDI, manufactured by Mitsui Chemicals Polyurethane Co., Ltd.): 25.
- DBTL di
- urethane polymer- (meth) acrylic monomer mixture 5 parts by weight were dropped and reacted at 65 ° C. for 5 hours to obtain a urethane polymer- (meth) acrylic monomer mixture. Thereafter, hydroxyethyl acrylate (trade name “Acrix HEA”, manufactured by Toa Gosei Co., Ltd.): 6.1 parts by weight were added and reacted at 65 ° C. for 1 hour, whereby acryloyl group-terminated urethane polymer- (meth) An acrylic monomer mixture was obtained.
- hydroxyethyl acrylate trade name “Acrix HEA”, manufactured by Toa Gosei Co., Ltd.
- the obtained syrup was coated on the surface of a separator (trade name “MRF38”, manufactured by Mitsubishi Plastics, Inc., thickness 38 ⁇ m) with an applicator to form a syrup layer having a thickness of 150 ⁇ m.
- a cover separator (trade name “MRF38”, manufactured by Mitsubishi Plastics Co., Ltd., thickness 38 ⁇ m) is bonded onto this syrup layer with a hand roller, and further irradiated with ultraviolet rays (ultraviolet illuminance: 3.4 mW) by an ultraviolet lamp (BL type). / Cm 2 , cumulative irradiation amount: 2000 mJ / cm 2 ) to obtain a base material layer (A).
- the obtained base material layer (A) was cut into a width of 10 mm and a length of 100 mm, and installed so that the distance between chucks was 50 mm.
- a tensile tester (trade name “Autograph AG-X 200N”, Co., Ltd.) SS test (temperature: 23 ° C., humidity: 65% RH, tensile speed: 200 mm / min) was performed by Shimadzu Corporation. Based on this measured value, the elongation at break and the stress at break were determined and found to be 415% and 27.1 MPa, respectively.
- the elastic modulus was determined from the slope of the initial rise of the obtained SS curve and found to be 4.9 MPa.
- a polyurethane elastomer sheet (manufactured by Seadam, product name “DUS451”, thickness: 150 ⁇ m) was used as the base material layer (B). Easy adhesion treatment is performed by forming a film on the surface of the base material layer (B) by a dipping method using a 0.1 wt% toluene solution of a silane coupling agent (manufactured by Shin-Etsu Chemical Co., Ltd., product name “KBM5103”). It was.
- the release film on one side of was peeled off and bonded as an adhesive layer (B) to one surface of the base material layer (B). This produced the easily-adhesive adhesive tape (1).
- An easy-adhesive adhesive tape (1) was affixed to the water-contacting surface of an FPR ship at intervals of 50 cm so that the longitudinal direction was perpendicular to the traveling direction of the ship (the direction parallel to the water surface).
- the antifouling pressure-sensitive adhesive tape (1) was abutted and pasted onto the surface with no gap so that the longitudinal direction was the traveling direction of the ship.
- the angle formed by the longitudinal direction of each pressure-sensitive adhesive tape was 90 °.
- Example A-2 Anti-fouling adhesive tape
- a polyurethane elastomer sheet manufactured by Seadam, product name “DUS451”, thickness: 150 ⁇ m
- One side of a commercially available pressure-sensitive adhesive product name “HJ9150” manufactured by Nitto Denko Corporation
- a commercially available pressure-sensitive adhesive product name “HJ9150” manufactured by Nitto Denko Corporation
- release film was peeled off and bonded as an adhesive layer (A) to one surface of the base material layer (A).
- an antifouling paint composition (manufactured by China Paint Co., Ltd., product name “Peracrine”) is applied to the other surface of the base material layer (A) so that the thickness after drying becomes 100 ⁇ m.
- An antifouling layer was formed by drying for a minute. This produced the antifouling adhesive tape (2).
- a PET film (product name “Lumirror S10”, thickness: 50 ⁇ m, manufactured by Toray Industries, Inc.) is used as a base material layer (B), and an SiO 2 vapor deposition film (thickness: 15 nm) is formed on one surface of the film. Adhesion treatment was performed. Commercially available pressure-sensitive adhesive was peeled off one side of the release film (manufactured by Nitto Denko Corporation, product name "No.591”), the adhesive layer on the surface SiO 2 deposited film is not formed in the substrate layer (B) (B ). This produced the easily-adhesive adhesive tape (2).
- An easy-adhesive adhesive tape (2) was applied in a grid pattern on the water contact surface of an FPR ship so that the longitudinal direction was an angle of ⁇ 45 ° with respect to the traveling direction of the ship (the direction parallel to the water surface). At this time, the length of the diagonal line of the formed lattice was set to 70 cm. Next, the antifouling adhesive tape (2) was abutted and pasted onto the surface with no gap so that the longitudinal direction was perpendicular to the traveling direction of the ship. At the point where the easily adhesive pressure-sensitive adhesive tape (2) and the antifouling pressure-sensitive adhesive tape (2) intersect, the angle formed by the longitudinal direction of each pressure-sensitive adhesive tape was ⁇ 45 °.
- Example A-3 Anti-fouling adhesive tape
- a polyurethane elastomer sheet manufactured by Nippon Matai Co., Ltd., product name “Esmer URS-PX”, thickness: 150 ⁇ m
- a release film on one side of a commercially available adhesive manufactured by Nitto Denko Corporation, product name “No. 5919” was peeled off and bonded to one surface of the base material layer (A) as an adhesive layer (A).
- an antifouling paint composition (manufactured by China Paint Co., Ltd., product name “Peracrine”) is applied to the other surface of the base material layer (A) so that the thickness after drying becomes 100 ⁇ m.
- An antifouling layer was formed by drying for a minute. This produced the antifouling adhesive tape (3).
- a glass cloth made by Maeda Glass Co., Ltd., product name “EP11”, thickness: 110 ⁇ m was used as the base material layer (B).
- the glass cloth was dipped in a 3 wt% aqueous solution of a silane coupling agent (manufactured by Toray Dow Corning, product name “Z6040”), and then dried at room temperature to form a film on the surface for easy adhesion treatment.
- a release film on one side of a commercially available adhesive manufactured by Nitto Denko Corporation, product name “HJ9150” was peeled off, and bonded to one side of the treated glass cloth as an adhesive layer (B). This produced the easily-adhesive adhesive tape (3).
- An easy-adhesive pressure-sensitive adhesive tape (3) was affixed to the water-contact surface of an FPR ship at 100 cm intervals so that the longitudinal direction forms an angle of 60 degrees counterclockwise with respect to the traveling direction of the ship.
- the antifouling adhesive tape (3) was abutted and pasted onto the surface with no gap so that the longitudinal direction was perpendicular to the traveling direction of the ship.
- the angle formed by the longitudinal direction of each pressure-sensitive adhesive tape was 30 °.
- Example A-4 Anti-fouling adhesive tape
- An antifouling adhesive tape (4) was prepared in the same manner as in Example A-1, except that a commercially available adhesive (manufactured by Nitto Denko Corporation, product name “HJ9150”) was used as the adhesive layer (A).
- An easy-adhesive pressure-sensitive adhesive tape (4) was affixed to the water-contact surface of an FPR ship at 30 cm intervals so that the longitudinal direction forms an angle of 60 degrees counterclockwise with respect to the traveling direction of the ship.
- an antifouling pressure-sensitive adhesive tape (4) was abutted and pasted onto the surface with no gap so that the longitudinal direction was the traveling direction of the ship.
- the angle formed by the longitudinal direction of each pressure-sensitive adhesive tape was 60 °.
- Example A-5 Anti-fouling adhesive tape
- An ether-based urethane resin film manufactured by Fait Plast, product name “EST-001”, thickness: 100 ⁇ m
- a release film on one side of a commercially available adhesive manufactured by Nitto Denko Corporation, product name “No. 591”
- an antifouling paint composition is applied to the other surface of the base material layer (A) so that the thickness after drying becomes 100 ⁇ m.
- a PET film (manufactured by Toray Industries Inc., product name “Lumirror S10”, thickness: 50 ⁇ m) is used as a base material layer (B), and one surface of the film is subjected to surface modification by corona treatment, and the wetting tension of the surface is set to 48 mN. / M.
- a release film on one side of a commercially available adhesive (manufactured by Nitto Denko Corporation, product name “No. 5919”) is peeled off and pasted as an adhesive layer (B) on the surface of the base material layer (B) which has not been subjected to corona treatment. Combined. This produced the easily-adhesive adhesive tape (5).
- Example A-1 an easily adhesive pressure-sensitive adhesive tape (5) and an antifouling pressure-sensitive adhesive tape (5) were affixed to the water contact surface of an FPR ship. Thereafter, when the antifouling pressure-sensitive adhesive tape (5) was forcibly peeled off, the adhesive point with the easy-adhesive pressure-sensitive adhesive tape (5) could be peeled off, but the antifouling pressure-sensitive adhesive tape (5 ) And the easy-adhesive pressure-sensitive adhesive tape (5) were very strong and could not be peeled beyond the adhesion point.
- Example A-6 Anti-fouling adhesive tape
- An ether-based urethane resin film manufactured by Fait Plast, product name “EST-001”, thickness: 200 ⁇ m
- a release film on one side of a commercially available adhesive manufactured by Nitto Denko Corporation, product name “No. 591” was peeled off, and bonded to one surface of the base material layer (A) as an adhesive layer (A).
- an antifouling paint composition (manufactured by Chugoku Paint Co., Ltd., product name “Peracrine”) is applied to the other surface of the base material layer (A) so that the thickness after drying is 100 ⁇ m, and it is at room temperature for 24 hours.
- An antifouling layer was formed by drying. This produced the antifouling adhesive tape (6).
- a PET film manufactured by Toray Industries Inc., product name “Lumirror S10”, thickness: 50 ⁇ m
- the surface was subjected to surface modification, and the wet tension of the surface was set to 47 mN / m.
- a release film on one side of a commercially available adhesive product name “No. 5919” manufactured by Nitto Denko Corporation) is peeled off, and an adhesive layer (B) is applied to the surface of the base material layer (B) which has not been subjected to atmospheric pressure plasma treatment. As pasted together.
- Example A-2 In the same manner as in Example A-2, an easily adhesive pressure-sensitive adhesive tape (6) and an antifouling pressure-sensitive adhesive tape (6) were affixed to the water contact surface of an FPR ship. Thereafter, when the antifouling pressure-sensitive adhesive tape (6) was forcibly peeled off, the adhesive point with the easily adhesive pressure-sensitive adhesive tape (6) could be peeled off. ) And the easy-adhesive pressure-sensitive adhesive tape (6) were very strong and could not be peeled beyond the adhesion point.
- Example A-7 Anti-fouling adhesive tape
- An antifouling adhesive tape (7) was prepared in the same manner as in Example A-1, except that a commercially available adhesive (product name “No. 5919” manufactured by Nitto Denko Corporation) was used as the adhesive layer (A). did.
- Example A-1 an easily adhesive pressure-sensitive adhesive tape (7) and an antifouling pressure-sensitive adhesive tape (7) were affixed to the water contact surface of an FPR ship. After that, when the antifouling pressure-sensitive adhesive tape (7) was forcibly peeled off, the antifouling pressure-sensitive adhesive tape (7) could be peeled up to the adhesion point with the easily adhesive pressure-sensitive adhesive tape (7). ) And the easy-adhesive pressure-sensitive adhesive tape (7) were very strong, and could not be peeled beyond the adhesion point. Moreover, since both sides of the adhesion point of the easily adhesive pressure-sensitive adhesive tape (7) were supported by other adjacent antifouling pressure-sensitive adhesive tapes (7), peeling of the easily adhesive pressure-sensitive adhesive tape (7) did not proceed. It was.
- Example B-1 The antifouling pressure-sensitive adhesive tape (1) and the easily adhesive pressure-sensitive adhesive tape (1) prepared in Example A-1 were used.
- Adhesive adhesive tape (1) is attached to the bottom of a ship made of fiber reinforced plastic, and the antifouling adhesive tape (1) to be applied thereafter is attached at a predetermined interval so that the joint is on the easily adhesive surface. did.
- the antifouling pressure-sensitive adhesive tape (1) was applied in order so as to abut without gaps. At this time, the joint of the antifouling pressure-sensitive adhesive tape (1) was located substantially at the center of the easy-adhesion surface of the easy-adhesion pressure-sensitive adhesive tape (1).
- Example B-2 The antifouling pressure-sensitive adhesive tape (2) and the easily adhesive pressure-sensitive adhesive tape (2) prepared in Example A-2 were used.
- Adhesive adhesive tape (2) is attached to the bottom of a boat with a total length of about 8m, and the antifouling adhesive tape (2) to be applied thereafter is attached at a predetermined interval so that the joint is on the easy adhesive surface. did.
- the antifouling pressure-sensitive adhesive tape (2) was applied in order so as to abut without gaps.
- the easy-adhesive pressure-sensitive adhesive tape (2) was sufficiently deformed so as to follow the curved surface of the ship bottom, and was stuck to the surface of the boat with good adhesion.
- the adhesive force between the easy-adhesive surface of the easy-adhesive adhesive tape (2) and the adhesive layer (A) of the antifouling adhesive tape (2) is the same as that of the adhesive layer (A) of the antifouling adhesive tape (2) and the boat surface.
- the adhesive strength of the adhesive layer (A) was about twice as large as that of the adhesive layer.
- Example B-3 The antifouling pressure-sensitive adhesive tape (3) and the easily adhesive pressure-sensitive adhesive tape (3) prepared in Example A-3 were used.
- An easy-adhesive pressure-sensitive adhesive tape (3) was folded and applied to a steel square column painted with an anticorrosive paint (manufactured by China Paint Co., Ltd., product name “Banno 500”) so as to cover the ridgeline.
- the antifouling pressure-sensitive adhesive tape (3) was attached so as to abut on the ridge line portion.
- the antifouling pressure-sensitive adhesive tape (3) was firmly adhered to the easy-adhesion surface of the easy-adhesive pressure-sensitive adhesive tape (3) at the joint, and no peeling occurred even when a water flow was applied by a high pressure washer manufactured by Kärcher.
- Example B-4 The antifouling pressure-sensitive adhesive tape (4) and the easily adhesive pressure-sensitive adhesive tape (4) prepared in Example A-4 were used. An easy-adhesive adhesive tape (4) was applied so as to cover the tip of the bottom keel part, and an antifouling adhesive tape (4) was attached to both ends so that a joint was placed at the tip. When the construction liquid was used when applying the antifouling pressure-sensitive adhesive tape (4), the construction liquid could be eliminated without any problem from the joint. After that, when the bottom keel part was left in seawater for 2 months, aquatic organisms were observed in the gaps between the joints. However, since the aquatic organisms could be easily removed by peeling and removing the easily adhesive pressure-sensitive adhesive tape (4) and the antifouling pressure-sensitive adhesive tape (4), direct contamination of the ship bottom and generation of deposits that are difficult to remove There was no.
- Example B-5 The antifouling pressure-sensitive adhesive tape (5) and the easily adhesive pressure-sensitive adhesive tape (5) prepared in Example A-5 were used. Adhesive adhesive tape (5) is attached to the bottom of a boat with a total length of about 8m, and the antifouling adhesive tape (5) to be applied thereafter is attached at a predetermined interval so that the joint is on the easy adhesive surface. did. Next, the antifouling pressure-sensitive adhesive tape (5) was applied in order so as to abut without gaps. The easy-adhesive pressure-sensitive adhesive tape (5) was sufficiently deformed so as to follow the curved surface of the ship bottom, and was stuck to the surface of the boat with good adhesion.
- the adhesive force between the easy-adhesive surface of the easy-adhesive adhesive tape (5) and the adhesive layer (A) of the antifouling adhesive tape (5) is the same as that of the adhesive layer (A) of the antifouling adhesive tape (5) and the boat surface.
- the adhesive strength of the adhesive layer (A) was about twice as large as that of the adhesive layer.
- Example B-6 The antifouling pressure-sensitive adhesive tape (6) and the easily adhesive pressure-sensitive adhesive tape (6) prepared in Example A-6 were used. An easily adhesive pressure-sensitive adhesive tape (6) was applied so as to cover the edge portion of the brass propeller. Subsequently, the antifouling pressure-sensitive adhesive tape (6) was abutted and pasted so that the joints were arranged at the edge portions. Thereafter, the propeller was driven in water, but peeling of the antifouling adhesive tape (6) did not occur.
- Example B-1 An antifouling pressure-sensitive adhesive tape (1) was applied to the bottom of a fiber-reinforced plastic ship in the same manner as in Example B-1, except that the easy-adhesive pressure-sensitive adhesive tape (1) was not used. At this time, the paste was applied so that there was no gap, but the stretching stress at the time of sticking relaxed over time, and the antifouling adhesive tape (1) slightly contracted, resulting in a gap at the joint. The generated gap was about 1 to 2 mm, but a large amount of barnacles adhered to the gap in an immersion test in seawater (about one month in the summer from August to September). The antifouling adhesive tape (1) was peeled and removed, but the barnacles penetrated between the surface of the bottom of the ship and the adhesive layer (A) through the gap and adhered with a strong adhesive force. It took a lot of effort.
- Example B-2 The same antifouling adhesive tape (1) as in Example B-1 was applied to a brass propeller so that the joints were arranged at the edges. Thereafter, when the propeller was driven in water, peeling occurred from the joint due to the resistance of rotation and water flow.
- Example B-3 The antifouling pressure-sensitive adhesive tape (4) was applied to the bottom keel portion in the same manner as in Example B-4 except that the easy-adhesive pressure-sensitive adhesive tape (4) was not used and the antifouling pressure-sensitive adhesive tape (4) was laminated. ) was affixed. Thereafter, when the bottom keel part was left in seawater for two months, a part of the antifouling adhesive tape (4) was peeled off. This is presumably because the construction liquid remained in the overlapped portion and the adhesion between the ship bottom surface and the antifouling adhesive tape (4) was lowered.
- the contamination prevention method of the present invention can be suitably applied particularly to prevention of contamination of the wetted surface of an underwater structure.
- Adhesive Tape 100 Antifouling Adhesive Tape 200 Easy Adhesive Adhesive Tape 10 Base Material Layer (A) 20 Adhesive layer (A) 30 Antifouling layer 40 Base material layer (B) 50 Adhesive layer (B) 60 Structure
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Description
(工程1)基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備すること、
(工程2a-1)該易接着性粘着テープを、汚染が防止されるべき表面を有する構造物の該表面に貼付すること、
(工程2a-2)該防汚用粘着テープを、該貼付された易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付すること、
(工程2b)2枚以上の該防汚用粘着テープと少なくとも1枚の該易接着性粘着テープとを、汚染が防止されるべき表面を有する構造物の該表面に、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付すること。
好ましい実施形態においては、上記工程2a-1において、上記易接着性粘着テープを平行に貼付する。
好ましい実施形態においては、上記工程2a-1において、上記易接着性粘着テープを格子状に貼付する。
好ましい実施形態においては、上記工程2a-1において、上記易接着性粘着テープをそれぞれの長手方向および/または間隔がランダムとなるように貼付する。
好ましい実施形態においては、上記工程2a-2において、上記易接着性粘着テープの長手方向と上記防汚用粘着テープの長手方向とが、30°~150°の角度をなすように上記防汚用粘着テープを貼付する。
好ましい実施形態においては、上記工程2bが、上記汚染が防止されるべき表面に上記易接着性粘着テープを貼付した後に、上記防汚用粘着テープを貼付することを含む。
好ましい実施形態においては、上記工程2bが、上記防汚用粘着テープを上記易接着性粘着テープの基材層(B)表面に所定の幅分ずらして、かつ、長手方向を略平行に揃えて貼り合わせること、および、2組以上の貼り合わせられた上記防汚用粘着テープと上記易接着性粘着テープとを、上記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が上記易接着性粘着テープの基材層(B)表面上となるようにずらして重ねながら上記汚染が防止されるべき表面に貼付することを含む。
好ましい実施形態においては、上記工程2bが、上記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が上記易接着性粘着テープの基材層(B)表面上となるように、上記防汚用粘着テープと上記易接着性粘着テープとを交互に貼り合わせること、および、貼り合わせられた上記防汚用粘着テープと上記易接着性粘着テープとを上記汚染が防止されるべき表面に貼付することを含む。
好ましい実施形態においては、上記汚染が防止されるべき表面が屈曲部を有し、該屈曲部の先端に上記易接着性粘着テープが配置される。
好ましい実施形態においては、上記防汚用粘着テープが、基材層(A)の粘着層(A)が設けられていない面側に防汚層を有する。
好ましい実施形態においては、上記汚染が防止されるべき表面が水中構造物の表面である。
本発明の別の局面によれば、上記構造物の汚染防止方法のための粘着テープセットが提供される。該粘着テープセットは、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを含む。
好ましい実施形態においては、上記防汚用粘着テープが、上記易接着性粘着テープの基材層(B)表面上に所定の幅分ずらして、かつ、長手方向を略平行に揃えて貼り合わせられている。
好ましい実施形態においては、上記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が上記易接着性粘着テープの基材層(B)表面上となるように、上記防汚用粘着テープと上記易接着性粘着テープとが交互に貼り合わせられている。
本発明のさらに別の局面によれば、構造物が提供される。該構造物は、汚染が防止されるべき表面を有し、該表面の少なくとも一部に、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープが、一方の面が該粘着層(A)に対して易接着性である基材(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付されている。
別の実施形態によれば、上記構造物は、汚染が防止されるべき表面を有し、該表面の少なくとも一部に、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する2枚以上の防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する少なくとも1枚の易接着性粘着テープとが、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付されている。
好ましい実施形態においては、上記構造物は、水中構造物である。
本発明の構造物の汚染防止方法は、以下の工程1と、工程2a-1~工程2a-2または工程2bとを含む。すなわち、本発明の構造物の汚染防止方法は、工程1と工程2a-1および工程2a-2とを含む実施形態(以下、「第1の実施形態」と称する)、または、工程1と工程2bとを含む実施形態(以下、「第2の実施形態」と称する)であり得る。
(工程1)基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備すること、
(工程2a-1)該易接着性粘着テープを、汚染が防止されるべき表面を有する構造物の該表面に貼付すること、
(工程2a-2)該防汚用粘着テープを、該貼付された易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付すること、
(工程2b)2枚以上の該防汚用粘着テープと少なくとも1枚の該易接着性粘着テープとを、汚染が防止されるべき表面を有する構造物の該表面に、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付すること。
以下、本発明の第1の実施形態および第2の実施形態の構造物の汚染防止方法について詳細に説明する。
本発明の第1の実施形態の構造物の汚染防止方法は、
基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備すること(工程1)、
該易接着性粘着テープを、汚染が防止されるべき表面を有する構造物の該表面に貼付すること(工程2a-1)、および
該防汚用粘着テープを、該貼付された易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付すること(工程2a-2)
を含む。このような汚染防止方法によれば、防汚用粘着テープの粘着層(A)および易接着性粘着テープの粘着層(B)と該構造物の表面との接着力を、各粘着テープを剥離除去可能な程度に抑えつつ、防汚用粘着テープの剥落を防止することができる。具体的には、例えば、図1に示すように、水流、気流等の流体抵抗による応力aを受けて防汚用粘着テープ100bが上記構造物60の表面から剥離した場合、防汚用粘着テープと易接着性粘着テープとが強固に接着していることにより、該剥離が防汚用粘着テープ100bと易接着性粘着テープ200aとの接着点bを超えて進行することを防ぐことができる。また、該接着点bにおいて、防汚用粘着テープ100bが易接着性粘着テープ200aごと剥離しようとしても、防汚用粘着テープと易接着性粘着テープの長手方向が互いに非平行となるように貼付されていることにより、剥離の進行方向が異なるので、周囲の剥離していない部分によって剥離の進行が抑制され得る。なお、第1の実施形態において、「平行」とは0°±3.0°を包含する意味であり、「非平行」とは、0°±3.0°を除く意味である。
工程1においては、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備する。なお、工程1は、第1の実施形態と第2の実施形態において共通の工程であり、両方の実施形態においてほぼ同様の説明が適用され得る。
図2(a)は、本発明の好ましい実施形態において用いられ得る防汚用粘着テープの概略断面図である。防汚用粘着テープ100aは、基材層(A)10とその一方の面側に設けられた粘着層(A)20とを有する。図2(b)は、本発明の別の好ましい実施形態において用いられ得る防汚用粘着テープの概略断面図である。防汚用粘着テープ100bは、基材層(A)10の粘着層(A)20が設けられていない面側に防汚層30をさらに有する。また、任意の適切な他の層をさらに有していてもよい。図示しないが、防汚用粘着テープの防汚層30の表面および/または粘着層(A)20の表面には、剥離フィルムが設けられていてもよい。
図3は、本発明で用いられ得る易接着性粘着テープの概略断面図である。易接着性粘着テープ200は、基材層(B)40とその一方の面側に設けられた粘着層(B)50とを有する。図示しないが、易接着性粘着テープの基材層(B)40の表面および/または粘着層(B)50の表面には、剥離フィルムが設けられていてもよい。
工程2a-1においては、易接着性粘着テープを、汚染が防止されるべき表面を有する構造物の該表面に貼付する。貼付する易接着性粘着テープの数に制限はないが、好ましくは2枚以上である。2枚以上貼付することにより、防汚用粘着テープの易接着性粘着テープとの接着点が増加するので、剥離の進行を段階的に細分して抑制することができる。
工程2a-2においては、防汚用粘着テープを、工程2a-1で貼付された易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付する。易接着性粘着テープ上に防汚用粘着テープを貼付することにより、例えば、図1に示すように、水流、気流等の流体抵抗による応力aを受けて防汚用粘着テープ100bが上記構造物60の表面から剥離した場合に、防汚用粘着テープ100bと易接着性粘着テープ200aとの強固な接着によって、防汚用粘着テープ100bが易接着性粘着テープ200aとの接着点bを超えて剥離することを防止し得る。また、防汚用粘着テープの剥離部分に対する流体抵抗による応力が大きい場合、防汚用粘着テープが易接着性粘着テープごと剥離する可能性がある。しかしながら、このような場合であっても、互いの長手方向を非平行にして各々の剥離の進行方向を相違させることにより、周囲の剥離していない部分が剥離の進行を抑制することができる。具体例としては、図1に示すように、防汚用粘着テープ100bが易接着性粘着テープ200aとの接着点bにおいて易接着性粘着テープ200aごと剥離しようとする場合であっても、防汚用粘着テープ100bに隣接する防汚用粘着テープ100aおよび100cが易接着性粘着テープ200aの該接着点bの両側を押さえるように貼付されているので、該剥離の進行を防止し得る。なお、構造物60の表面に2枚以上の易接着性粘着テープが貼付されている場合、防汚用粘着テープは、好ましくはその全ての易接着性粘着テープと長手方向が互いに非平行となるように貼付されるが、本発明の効果が得られる範囲において、一部の易接着性粘着テープと長手方向が互いに平行となるように貼付されてもよい。
本発明の第2の実施形態の構造物の汚染防止方法は、
基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備すること(工程1)、および
2枚以上の該防汚用粘着テープと少なくとも1枚の該易接着性粘着テープとを、汚染が防止されるべき表面を有する構造物の該表面に、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付すること(工程2b)を含む。このような汚染防止方法によれば、防汚用粘着テープの粘着層(A)および易接着性粘着テープの粘着層(B)と該構造物の表面との接着力を、各粘着テープを剥離除去可能な程度に抑えつつ、防汚用粘着テープの粘着層(A)と易接着性粘着テープの基材層(B)とを極めて強固に接着することができる。その結果、剥離除去時の作業性を低下させることなく、つなぎ目からの防汚用粘着テープの剥離を抑制することができる。また、本発明の汚染防止方法によれば、防汚用粘着テープ間のつなぎ目の下には易接着性粘着テープが配置されているので、該つなぎ目に隙間が生じて水生生物が付着するとしても、付着可能な面積は少なく、また、該粘着テープを剥離することによって、簡単に除去することができる。
工程1においては、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備する。該工程1に関しては、上記第1の実施形態における工程1と同様の説明が適用され得る。
工程2bにおいては、図10に示すように、2枚以上の該防汚用粘着テープ100と少なくとも1枚の該易接着性粘着テープ200とを、汚染が防止されるべき表面を有する構造物60の該表面に、該防汚用粘着テープ100が互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープ200の基材層(B)40の表面上となるように貼付する。代表的には、防汚用粘着テープを該汚染が防止されるべき表面の全面を覆うように貼付するが、必要に応じて、該表面の所望の部位(例えば、後述の屈曲部)のみを覆うように貼付してもよい。
本発明の粘着テープセットは、上記第2の実施形態の構造物の汚染防止方法に用いるための粘着テープセットであって、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを含む。防汚用粘着テープおよび易接着性粘着テープの詳細については、上記A項に記載したとおりである。
本発明の1つの実施形態による構造物は、汚染が防止されるべき表面を有し、該表面の少なくとも一部に、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープが、一方の面が該粘着層(A)に対して易接着性である基材(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付されている。防汚用粘着テープおよび易接着性粘着テープならびにこれらの貼付方法の詳細については、上記第1の実施形態の構造物の汚染防止方法に関して説明したとおりである。
(防汚用粘着テープ)
冷却管、温度計、および攪拌装置を備えた反応容器に、(メタ)アクリル系モノマーとして、イソボルニルアクリレート(商品名「IBXA」、大阪有機化学工業(株)製):71重量部、n-ブチルアクリレート(BA、東亜合成(株)製):19重量部、アクリル酸(AA):10重量部、ポリオールとして数平均分子量650のポリ(オキシテトラメチレン)グリコール(PTMG650、三菱化学(株)製):68.4重量部、触媒としてジラウリン酸ジブチルスズ(DBTL):0.01重量部を投入し、攪拌しながら、水添キシリレンジイソシアネート(HXDI、三井化学ポリウレタン(株)製):25.5重量部を滴下し、65℃で5時間反応させ、ウレタンポリマー-(メタ)アクリル系モノマー混合物を得た。その後、ヒドロキシエチルアクリレート(商品名「アクリックス HEA」、東亜合成(株)製):6.1重量部を投入し、65℃で1時間反応することで、アクリロイル基末端ウレタンポリマー-(メタ)アクリル系モノマー混合物を得た。
得られたアクリロイル基末端ウレタンポリマー-(メタ)アクリル系モノマー混合物に、3-アクリロキシプロピルトリメトキシシラン(KBM-5103、信越化学工業(株)製):1重量部、光重合開始剤としてジフェニル(2,4,6,-トリメトキシベンゾイル)ホスフィンオキシド(商品名「ルシリンTPO」、BASF(株)製):0.25重量部、紫外線吸収剤(商品名「TINUVIN123」、BASF(株)社製):1.25重量部、酸化防止剤(商品名「TINUVIN400」、BASF(株)社製):0.6重量部を添加することにより、シロップを得た。
セパレーター(商品名「MRF38」、三菱樹脂(株)製、厚み38μm)の表面に、得られたシロップをアプリケーターにて塗工し、厚み150μmのシロップ層を形成した。このシロップ層上にカバーセパレータ(商品名「MRF38」、三菱樹脂(株)製、厚み38μm)をハンドローラーにて貼り合わせ、さらに紫外線ランプ(BLタイプ)により紫外線を照射(紫外線照度:3.4mW/cm2、積算照射量:2000mJ/cm2)し、基材層(A)を得た。
ポリウレタンエラストマーシート(シーダム社製、製品名「DUS451」、厚み:150μm)を基材層(B)とした。シランカップリング剤(信越化学工業社製、製品名「KBM5103」)の0.1wt%トルエン溶液を用いたディッピング法によって該基材層(B)表面に成膜することにより、易接着処理を行った。剥離フィルム(厚み=約38μm)/アクリル系粘着剤層(厚み=50μm)/剥離フィルム(厚み=約38μm)の構成を有する市販の粘着剤(日東電工社製、製品名「No.5919」)の片側の剥離フィルムを剥離し、上記基材層(B)の一方の面に粘着層(B)として貼り合わせた。これにより易接着性粘着テープ(1)を作成した。易接着性粘着テープ(1)の構成は、基材層(B)(厚み=150μm)/粘着層(B)(厚み=50μm)であった。
(防汚用粘着テープ)
ポリウレタンエラストマーシート(シーダム社製、製品名「DUS451」、厚み:150μm)を基材層(A)とした。剥離フィルム(厚み=約38μm)/アクリル系粘着剤層(厚み=50μm)/剥離フィルム(厚み=約38μm)の構成を有する市販の粘着剤(日東電工社製、製品名「HJ9150」)の片側の剥離フィルムを剥離し、上記基材層(A)の一方の面に粘着層(A)として貼り合わせた。次いで、上記基材層(A)の他方の面に防汚用塗料組成物(中国塗料社製、製品名「ペラクリン」)を乾燥後の厚みが100μmとなるように塗布し、150℃で10分間乾燥させて防汚層を形成した。これにより、防汚用粘着テープ(2)を作成した。防汚用粘着テープ(2)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=150μm)/粘着層(A)(厚み=50μm)であった。
PETフィルム(東レ社製、製品名「ルミラーS10」、厚み:50μm)を基材層(B)とし、該フィルムの一方の面にSiO2蒸着膜(厚み:15nm)を形成することにより、易接着処理を施した。市販の粘着剤(日東電工社製、製品名「No.591」)の片側の剥離フィルムを剥離し、上記基材層(B)のSiO2蒸着膜が形成されていない面に粘着層(B)として貼り合わせた。これにより易接着性粘着テープ(2)を作成した。易接着性粘着テープ(2)の構成は、基材層(B)(厚み=50μm)/粘着層(B)(厚み=50μm)であった。また、易接着性粘着テープ(2)の幅は50mmであった。
(防汚用粘着テープ)
ポリウレタンエラストマーシート(日本マタイ社製、製品名「エスマーURS-PX」、厚み:150μm)を基材層(A)とした。市販の粘着剤(日東電工社製、製品名「No.5919」)の片側の剥離フィルムを剥離し、上記基材層(A)の一方の面に粘着層(A)として貼り合わせた。次いで、上記基材層(A)の他方の面に防汚用塗料組成物(中国塗料社製、製品名「ペラクリン」)を乾燥後の厚みが100μmとなるように塗布し、150℃で10分間乾燥させて防汚層を形成した。これにより、防汚用粘着テープ(3)を作成した。防汚用粘着テープ(3)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=150μm)/粘着層(A)(厚み=50μm)であった。
ガラスクロス(前田硝子社製、製品名「EP11」、厚み:110μm)を基材層(B)とした。シランカップリング剤(東レダウコーニング社製、製品名「Z6040」)の3wt%水溶液に該ガラスクロスを浸漬し、次いで、常温乾燥して表面に成膜することにより、易接着処理を施した。市販の粘着剤(日東電工社製、製品名「HJ9150」)の片側の剥離フィルムを剥離し、処理後のガラスクロスの一方の面に粘着層(B)として貼り合わせた。これにより易接着性粘着テープ(3)を作成した。易接着性粘着テープ(3)の構成は、基材層(B)(厚み=110μm)/粘着層(B)(厚み=50μm)であった。
(防汚用粘着テープ)
粘着層(A)として市販の粘着剤(日東電工社製、製品名「HJ9150」)を用いたこと以外は実施例A-1と同様にして、防汚用粘着テープ(4)を作成した。防汚用粘着テープ(4)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=150μm)/粘着層(A)(厚み=50μm)であった。
ポリイミドテープ(日東電工社製、製品名「360UL」)のポリイミドフィルム面に窒素ガススパッタリングを行うことにより、易接着処理を行った。具体的には、ガス圧が0.4Pa、窒素ガスの導入量が標準状態において200cc/分、グロ-放電の処理電力が0.4kw、処理時間が5分、処理周波数が13.56MHZのスパッタリング条件で表面をエッチングし、アミド基を導入した。これにより、易接着性粘着テープ(4)を作成した。得られた易接着性粘着テープ(4)の幅は、50mmであった。
(防汚用粘着テープ)
エーテル系ウレタン樹脂フィルム(Fait Plast社製、製品名「EST-001」、厚み:100μm)を基材層(A)とした。市販の粘着剤(日東電工社製、製品名「No.591」)の片側の剥離フィルムを剥離し、上記基材層(A)の一方の面に粘着層(A)として貼り合わせた。次いで、上記基材層(A)の他方の面に防汚用塗料組成物(中国塗料社製、製品名「ペラクリン」)を乾燥後の厚みが100μmとなるように塗布し、150℃で10分間乾燥させて防汚層を形成した。これにより、防汚用粘着テープ(5)を作成した。防汚用粘着テープ(5)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=100μm)/粘着層(A)(厚み=50μm)であった。
PETフィルム(東レ社製、製品名「ルミラーS10」、厚み:50μm)を基材層(B)とし、該フィルムの一方の面にコロナ処理による表面改質を行い、該表面の濡れ張力を48mN/mとした。市販の粘着剤(日東電工社製、製品名「No.5919」)の片側の剥離フィルムを剥離し、上記基材層(B)のコロナ処理を施していない面に粘着層(B)として貼り合わせた。これにより易接着性粘着テープ(5)を作成した。易接着性粘着テープ(5)の構成は、基材層(B)(厚み=50μm)/粘着層(B)(厚み=50μm)であった。また、易接着性粘着テープ(5)の幅は50mmであった。
(防汚用粘着テープ)
エーテル系ウレタン樹脂フィルム(Fait Plast社製、製品名「EST-001」、厚み:200μm)を基材層(A)とした。市販の粘着剤(日東電工社製、製品名「No.591」)の片側の剥離フィルムを剥離し、上記基材層(A)の一方の面に粘着層(A)として貼り合わせた。次いで、上記基材層(A)の他方の面に防汚用塗料組成物(中国塗料社製、製品名「ペラクリン」)を乾燥後の厚みが100μmとなるように塗布し、常温で24時間乾燥させて防汚層を形成した。これにより、防汚用粘着テープ(6)を作成した。防汚用粘着テープ(6)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=200μm)/粘着層(A)(厚み=50μm)であった。
PETフィルム(東レ社製、製品名「ルミラーS10」、厚み:50μm)を基材層(B)とし、該フィルムの一方の面に大気圧プラズマ処理(ヘリウム:酸素=98:2、RF出力300W)による表面改質を行い、該表面の濡れ張力を47mN/mとした。市販の粘着剤(日東電工社製、製品名「No.5919」)の片側の剥離フィルムを剥離し、上記基材層(B)の大気圧プラズマ処理を施していない面に粘着層(B)として貼り合わせた。これにより易接着性粘着テープ(6)を作成した。易接着性粘着テープ(6)の構成は、基材層(B)(厚み=50μm)/粘着層(B)(厚み=50μm)であった。また、易接着性粘着テープ(6)の幅は50mmであった。
(防汚用粘着テープ)
粘着層(A)として市販の粘着剤(日東電工社製、製品名「No.5919」)を用いたこと以外は実施例A-1と同様にして、防汚用粘着テープ(7)を作成した。防汚用粘着テープ(7)の構成は、防汚層(厚み=100μm)/基材層(A)(厚み=150μm)/粘着層(A)(厚み=50μm)であった。
市販の粘着テープ(日東電工社製、製品名「31B」、基材層:PETフィルム、粘着層:アクリル系粘着剤)の基材表面にコロナ処理(12kV、0.5秒相当)を行った。これにより、易接着性粘着テープ(7)を得た。得られた易接着性粘着テープ(7)の幅は30mmであった。
実施例A-1で作成した防汚用粘着テープ(1)および易接着性粘着テープ(1)を用いた。繊維強化プラスチック製の船舶の底部に易接着性粘着テープ(1)を、その後に貼付する防汚用粘着テープ(1)のつなぎ目がその易接着面上となるように所定の間隔を設けて貼付した。次に、防汚用粘着テープ(1)を隙間なく突合わせるように順次貼付した。このとき、防汚用粘着テープ(1)のつなぎ目は、易接着性粘着テープ(1)の易接着面のほぼ中央に位置していた。
実施例A-2で作成した防汚用粘着テープ(2)および易接着性粘着テープ(2)を用いた。全長約8mのボートの船底部に易接着性粘着テープ(2)を、その後に貼付する防汚用粘着テープ(2)のつなぎ目がその易接着面上となるように所定の間隔を設けて貼付した。次に、防汚用粘着テープ(2)を隙間なく突合わせるように順次貼付した。易接着性粘着テープ(2)は、船底部の曲面に沿うように十分に変形し、該ボートの表面に良好な密着性で貼付した。易接着性粘着テープ(2)の易接着面と防汚用粘着テープ(2)の粘着層(A)との接着力は、防汚用粘着テープ(2)の粘着層(A)とボート表面との接着力の約2倍であり、両者を剥離すると粘着層(A)の凝集破壊に至った。
実施例A-3で作成した防汚用粘着テープ(3)および易接着性粘着テープ(3)を用いた。防食塗料(中国塗料社製、製品名「バンノー500」)で塗装された鋼鉄製の四角柱に、その稜線を覆うように易接着性粘着テープ(3)を折り曲げて貼付した。次いで、防汚用粘着テープ(3)を該稜線部で突合わせるように貼付した。防汚用粘着テープ(3)は、つなぎ目において易接着性粘着テープ(3)の易接着面と強固に接着しており、ケルヒャー社製高圧洗浄機による水流を当てても剥離は生じなかった。
実施例A-4で作成した防汚用粘着テープ(4)および易接着性粘着テープ(4)を用いた。易接着性粘着テープ(4)を船底キール部の先端を覆うように貼付し、該先端につなぎ目が配置されるように両側から防汚用粘着テープ(4)を突合わせて貼付した。防汚用粘着テープ(4)を貼付する際に施工液を使用したところ、該つなぎ目から問題なく施工液を排除することができた。その後、該船底キール部を海水中で2ヶ月間放置したところ、該つなぎ目の隙間に水生生物の付着が見られた。しかしながら、易接着性粘着テープ(4)および防汚用粘着テープ(4)を剥離除去することにより該水生生物も容易に除去できたため、船底への直接的な汚染および除去困難な付着物の発生はなかった。
実施例A-5で作成した防汚用粘着テープ(5)および易接着性粘着テープ(5)を用いた。全長約8mのボートの船底部に易接着性粘着テープ(5)を、その後に貼付する防汚用粘着テープ(5)のつなぎ目がその易接着面上となるように所定の間隔を設けて貼付した。次に、防汚用粘着テープ(5)を隙間なく突合わせるように順次貼付した。易接着性粘着テープ(5)は、船底部の曲面に沿うように十分に変形し、該ボートの表面に良好な密着性で貼付した。易接着性粘着テープ(5)の易接着面と防汚用粘着テープ(5)の粘着層(A)との接着力は、防汚用粘着テープ(5)の粘着層(A)とボート表面との接着力の約2倍であり、両者を剥離すると粘着層(A)の凝集破壊に至った。
実施例A-6で作成した防汚用粘着テープ(6)および易接着性粘着テープ(6)を用いた。易接着性粘着テープ(6)を真ちゅう製のプロペラのエッジ部分を覆うように貼付した。次いで、防汚用粘着テープ(6)をエッジ部分につなぎ目が配置されるように突合わせて貼付した。その後、水中で該プロペラを駆動させたが、防汚用粘着テープ(6)の剥離は生じなかった。
易接着性粘着テープ(1)を用いないこと以外は実施例B-1と同様にして、繊維強化プラスチック製の船舶の底部に防汚用粘着テープ(1)を貼付した。このとき、隙間なく突き合わせるように貼付したが、貼付時の延伸応力が経時で緩和し、防汚用粘着テープ(1)が若干収縮したため、つなぎ目に隙間が生じた。生じた隙間は1~2mm程度であったが海水中への浸漬試験(8月から9月の夏季の約1ヶ月)においてフジツボ類が該隙間に大量に付着した。防汚用粘着テープ(1)を剥離除去したが、フジツボ類は該隙間から船舶底部表面と粘着層(A)との間に侵入し、強固な付着力で付着していたので、除去には多大な労力を要した。
実施例B-1と同様の防汚用粘着テープ(1)を真ちゅう製のプロペラに、エッジ部分につなぎ目が配置されるように突合わせて貼付した。その後、水中で該プロペラを駆動させたところ、回転と水流の抵抗のためにつなぎ目から剥離が生じた。
易接着性粘着テープ(4)を用いないこと、および、防汚用粘着テープ(4)を重ね貼りしたこと以外は実施例B-4と同様にして船底キール部に防汚用粘着テープ(4)を貼付した。その後、該船底キール部を海水中で2ヶ月間放置したところ、防汚用粘着テープ(4)の一部が剥離していた。これは、重ね貼りの部分に施工液が残存し、船底表面と防汚用粘着テープ(4)との密着性が低下したためと考えられる。
200 易接着性粘着テープ
10 基材層(A)
20 粘着層(A)
30 防汚層
40 基材層(B)
50 粘着層(B)
60 構造物
Claims (17)
- 以下の工程1と、工程2a-1~工程2a-2または工程2bとを含む、構造物の汚染防止方法、
(工程1)基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを準備すること、
(工程2a-1)該易接着性粘着テープを、汚染が防止されるべき表面を有する構造物の該表面に貼付すること、
(工程2a-2)該防汚用粘着テープを、該貼付された易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付すること、
(工程2b)2枚以上の該防汚用粘着テープと少なくとも1枚の該易接着性粘着テープとを、汚染が防止されるべき表面を有する構造物の該表面に、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付すること。 - 前記工程2a-1において、前記易接着性粘着テープを平行に貼付する、請求項1に記載の構造物の汚染防止方法。
- 前記工程2a-1において、前記易接着性粘着テープを格子状に貼付する、請求項1に記載の構造物の汚染防止方法。
- 前記工程2a-1において、前記易接着性粘着テープをそれぞれの長手方向および/または間隔がランダムとなるように貼付する、請求項1に記載の構造物の汚染防止方法。
- 前記工程2a-2において、前記易接着性粘着テープの長手方向と前記防汚用粘着テープの長手方向とが、30°~150°の角度をなすように前記防汚用粘着テープを貼付する、請求項1から4のいずれか一項に記載の構造物の汚染防止方法。
- 前記工程2bが、
前記汚染が防止されるべき表面に前記易接着性粘着テープを貼付した後に、前記防汚用粘着テープを貼付すること
を含む、請求項1に記載の構造物の汚染防止方法。 - 前記工程2bが、
前記防汚用粘着テープを前記易接着性粘着テープの基材層(B)表面に所定の幅分ずらして、かつ、長手方向を略平行に揃えて貼り合わせること、および
2組以上の貼り合わせられた前記防汚用粘着テープと前記易接着性粘着テープとを、前記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が前記易接着性粘着テープの基材層(B)表面上となるようにずらして重ねながら前記汚染が防止されるべき表面に貼付すること
を含む、請求項1に記載の構造物の汚染防止方法。 - 前記工程2bが、
前記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が前記易接着性粘着テープの基材層(B)表面上となるように、前記防汚用粘着テープと前記易接着性粘着テープとを交互に貼り合わせること、および
貼り合わせられた前記防汚用粘着テープと前記易接着性粘着テープとを前記汚染が防止されるべき表面に貼付すること
を含む、請求項1に記載の構造物の汚染防止方法。 - 前記汚染が防止されるべき表面が屈曲部を有し、該屈曲部の先端に前記易接着性粘着テープが配置される、請求項1または6から8のいずれか一項に記載の構造物の汚染防止方法。
- 前記防汚用粘着テープが、基材層(A)の粘着層(A)が設けられていない面側に防汚層を有する、請求項1から9のいずれか一項に記載の構造物の汚染防止方法。
- 前記汚染が防止されるべき表面が水中構造物の表面である、請求項1から10のいずれか一項に記載の構造物の汚染防止方法。
- 基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープとを含む、請求項1または6から11のいずれか一項に記載の構造物の汚染防止方法のための粘着テープセット。
- 前記防汚用粘着テープが、前記易接着性粘着テープの基材層(B)表面上に所定の幅分ずらして、かつ、長手方向を略平行に揃えて貼り合わせられている、請求項12に記載の粘着テープセット。
- 前記防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が前記易接着性粘着テープの基材層(B)表面上となるように、前記防汚用粘着テープと前記易接着性粘着テープとが交互に貼り合わせられている、請求項12に記載の粘着テープセット。
- 汚染が防止されるべき表面を有し、
該表面の少なくとも一部に、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する防汚用粘着テープが、一方の面が該粘着層(A)に対して易接着性である基材(B)とその他方の面側に設けられた粘着層(B)とを有する易接着性粘着テープ上に、長手方向が互いに非平行となるように貼付されている、構造物。 - 汚染が防止されるべき表面を有し、
該表面の少なくとも一部に、基材層(A)とその一方の面側に設けられた粘着層(A)とを有する2枚以上の防汚用粘着テープと、一方の面が該粘着層(A)に対して易接着性である基材層(B)とその他方の面側に設けられた粘着層(B)とを有する少なくとも1枚の易接着性粘着テープとが、該防汚用粘着テープが互いに重ならないように、かつ、そのつなぎ目が該易接着性粘着テープの基材層(B)表面上となるように貼付されている、構造物。 - 水中構造物である、請求項15または16に記載の構造物。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020147020704A KR20140117436A (ko) | 2012-01-27 | 2013-01-15 | 오염 방지 방법 |
EP13740744.1A EP2808246A4 (en) | 2012-01-27 | 2013-01-15 | METHOD FOR PREVENTING FIGURE |
CN201380006953.2A CN104080695A (zh) | 2012-01-27 | 2013-01-15 | 防污染方法 |
US14/374,627 US20140356587A1 (en) | 2012-01-27 | 2013-01-15 | Method for preventing fouling |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012-015209 | 2012-01-27 | ||
JP2012-015208 | 2012-01-27 | ||
JP2012015208A JP5854859B2 (ja) | 2012-01-27 | 2012-01-27 | 汚染防止方法 |
JP2012015209A JP5854860B2 (ja) | 2012-01-27 | 2012-01-27 | 汚染防止方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013111634A1 true WO2013111634A1 (ja) | 2013-08-01 |
Family
ID=48873355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2013/050521 WO2013111634A1 (ja) | 2012-01-27 | 2013-01-15 | 汚染防止方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20140356587A1 (ja) |
EP (1) | EP2808246A4 (ja) |
KR (1) | KR20140117436A (ja) |
CN (1) | CN104080695A (ja) |
WO (1) | WO2013111634A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150218420A1 (en) * | 2012-09-04 | 2015-08-06 | Nitto Denko Corporation | Anti-fouling adhesive sheet, and anti-fouling treatment method for a structure using said anti-fouling adhesive sheet |
JP2016124994A (ja) * | 2015-01-05 | 2016-07-11 | 日東電工株式会社 | 構造物表面の防汚方法および封止用粘着テープ |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2014200187A1 (en) * | 2013-01-23 | 2014-08-07 | Cgg Services Sa | Fast fastening antifouling tape or substrate useable in marine seismic surveys |
AU2014201059B2 (en) * | 2013-03-04 | 2018-02-08 | Sercel Sas | Antifouling protective skin section for seismic survey equipment and related methods |
NO343005B1 (en) * | 2017-03-30 | 2018-09-24 | Polarcus Dmcc | Antifouling coating tape for marine seismic streamers and a method for its use |
CN113512985A (zh) * | 2019-04-15 | 2021-10-19 | 唐波 | 一种无寄生虫军舰码头 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6362487B2 (ja) | 1984-04-03 | 1988-12-02 | ||
JPH01212692A (ja) * | 1988-02-18 | 1989-08-25 | Nichiban Co Ltd | 海生生物の付着を防止する接水構造物 |
WO2001081167A1 (en) * | 2000-04-27 | 2001-11-01 | Olsen Design Aps | A moorage with a cover for inhibiting the fouling of a vessel |
JP2004189201A (ja) * | 2002-12-10 | 2004-07-08 | Shigematsu:Kk | 壁面保護方法、壁面保護材及びこれにより保護された構造物 |
JP2006526528A (ja) * | 2003-06-02 | 2006-11-24 | レイセオン カンパニー | 防汚テープ及びその適用方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6241280A (ja) * | 1985-08-19 | 1987-02-23 | Nichiban Co Ltd | 水中生物付着防止用粘着シ−ト |
-
2013
- 2013-01-15 CN CN201380006953.2A patent/CN104080695A/zh active Pending
- 2013-01-15 WO PCT/JP2013/050521 patent/WO2013111634A1/ja active Application Filing
- 2013-01-15 EP EP13740744.1A patent/EP2808246A4/en not_active Withdrawn
- 2013-01-15 US US14/374,627 patent/US20140356587A1/en not_active Abandoned
- 2013-01-15 KR KR1020147020704A patent/KR20140117436A/ko not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6362487B2 (ja) | 1984-04-03 | 1988-12-02 | ||
JPH01212692A (ja) * | 1988-02-18 | 1989-08-25 | Nichiban Co Ltd | 海生生物の付着を防止する接水構造物 |
JPH0427076B2 (ja) | 1988-02-18 | 1992-05-08 | Nichiban Kk | |
WO2001081167A1 (en) * | 2000-04-27 | 2001-11-01 | Olsen Design Aps | A moorage with a cover for inhibiting the fouling of a vessel |
JP2004189201A (ja) * | 2002-12-10 | 2004-07-08 | Shigematsu:Kk | 壁面保護方法、壁面保護材及びこれにより保護された構造物 |
JP2006526528A (ja) * | 2003-06-02 | 2006-11-24 | レイセオン カンパニー | 防汚テープ及びその適用方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2808246A4 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150218420A1 (en) * | 2012-09-04 | 2015-08-06 | Nitto Denko Corporation | Anti-fouling adhesive sheet, and anti-fouling treatment method for a structure using said anti-fouling adhesive sheet |
US10066129B2 (en) * | 2012-09-04 | 2018-09-04 | Nitto Denko Corporation | Anti-fouling adhesive sheet, and anti-fouling treatment method for a structure using said anti-fouling adhesive sheet |
JP2016124994A (ja) * | 2015-01-05 | 2016-07-11 | 日東電工株式会社 | 構造物表面の防汚方法および封止用粘着テープ |
WO2016111108A1 (ja) * | 2015-01-05 | 2016-07-14 | 日東電工株式会社 | 構造物表面の防汚方法および封止用粘着テープ |
Also Published As
Publication number | Publication date |
---|---|
EP2808246A4 (en) | 2016-02-24 |
KR20140117436A (ko) | 2014-10-07 |
CN104080695A (zh) | 2014-10-01 |
EP2808246A1 (en) | 2014-12-03 |
US20140356587A1 (en) | 2014-12-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6087766B2 (ja) | 防汚用粘着シートおよびこれを用いた構造物の防汚処理方法 | |
WO2013111634A1 (ja) | 汚染防止方法 | |
KR101994503B1 (ko) | 수생 생물 부착 방지 점착 테이프 | |
WO2013146718A1 (ja) | 水生生物付着防止粘着テープ | |
WO2013103092A1 (ja) | 水生生物付着防止粘着テープ | |
JP5854859B2 (ja) | 汚染防止方法 | |
JP6177820B2 (ja) | 水生生物付着防止粘着テープ | |
JP2013139534A (ja) | 水生生物付着防止粘着テープ | |
JP5854860B2 (ja) | 汚染防止方法 | |
WO2014038477A1 (ja) | 水中構造物の防汚処理方法 | |
JP2014234413A (ja) | 防汚用粘着シート | |
JP2014234414A (ja) | 易接着性粘着シート | |
KR20120049116A (ko) | 수중 방오 코팅시트 및 코팅방법 | |
JP2016023306A (ja) | 水生生物付着防止粘着テープまたはシート | |
WO2013146726A1 (ja) | 水生生物付着防止粘着テープ | |
KR102192734B1 (ko) | 요트선저용 보호필름 | |
WO2013094443A1 (ja) | 水生生物付着防止粘着テープ | |
JP2013139533A (ja) | 水生生物付着防止粘着テープ | |
WO2014208590A1 (ja) | 水生生物付着防止粘着テープ | |
JP2016056218A (ja) | 樹脂組成物、防汚材、防汚層、および積層フィルム | |
JP2015150547A (ja) | 構造物の防汚処理方法 | |
JP2013139535A (ja) | 水生生物付着防止粘着テープ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 13740744 Country of ref document: EP Kind code of ref document: A1 |
|
REEP | Request for entry into the european phase |
Ref document number: 2013740744 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2013740744 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 20147020704 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14374627 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |