WO2013069657A1 - 立方晶窒化硼素焼結体 - Google Patents
立方晶窒化硼素焼結体 Download PDFInfo
- Publication number
- WO2013069657A1 WO2013069657A1 PCT/JP2012/078774 JP2012078774W WO2013069657A1 WO 2013069657 A1 WO2013069657 A1 WO 2013069657A1 JP 2012078774 W JP2012078774 W JP 2012078774W WO 2013069657 A1 WO2013069657 A1 WO 2013069657A1
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- WIPO (PCT)
- Prior art keywords
- boron nitride
- cubic boron
- sintered body
- nitride sintered
- binder phase
- Prior art date
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Definitions
- the present invention relates to a cubic boron nitride sintered body having a high cubic boron nitride content.
- Cubic boron nitride has excellent strength as a tool material that has the second highest hardness and excellent thermal conductivity after diamond and has a lower affinity with iron than diamond.
- many studies have been made on a cubic boron nitride sintered body having a high cubic boron nitride content.
- cubic boron nitride sintered bodies having a high cubic boron nitride content include cubic boron nitride: 88 to 97% by volume, carbides, nitrides, borides of W, Co, and Al, and solid solutions thereof.
- a cubic boron nitride sintered body composed of a binder phase consisting of at least one selected from the above and inevitable impurities: the balance, wherein the binder phase contains B 6 Co 21 W 2 and B 6
- the binder phase contains B 6 Co 21 W 2 and B 6
- the intensity ratio indicating the ratio of Iw to Ib is Iw / Ib.
- a cubic boron nitride sintered body having a 0.10 to 0.40 is known (see, for example, Patent Document 1).
- cubic boron nitride molded body including a polycrystalline lump of cubic boron nitride particles present in an amount of at least 70 volume percent and a binder phase that is a metal in nature (see, for example, Patent Document 2). .).
- the invention of the above-mentioned Patent Document 1 has a problem that it has become unable to sufficiently meet the demands in recent cutting work in terms of fracture resistance and toughness.
- the binder phase which is a metal is easily worn and wear resistance is low.
- the present invention has been made to solve the above problems, and an object of the present invention is to provide a cubic boron nitride sintered body excellent in wear resistance and fracture resistance.
- the inventor has conducted research on a cubic boron nitride sintered body, and as a result of improving the binder phase, the bonding of cubic boron nitride particles becomes stronger, and the toughness of the cubic boron nitride sintered body is improved. I got the knowledge. In addition, it was also found that the wear of the cubic boron nitride sintered body can be suppressed by changing the binder phase of the cubic boron nitride sintered body from a metal to a compound, thereby reducing the wear of the binder phase.
- the gist of the present invention is as follows.
- Cubic boron nitride is composed of 85 to 95% by volume, and a binder phase and inevitable impurities: 5 to 15% by volume, and the binder phase includes Al, V, Cr, Mn, Co, Ni, Nb and Consisting of three or more compounds selected from the group consisting of carbides, nitrides, carbonitrides, oxides and their mutual solid solutions selected from the group consisting of Mo and included in the cubic boron nitride sintered body
- the amount of aluminum element to be added is 0.5 to 5% by mass with respect to the total mass of the cubic boron nitride sintered body, provided that the binder phase does not include simple metals and alloys. Boron sintered body.
- the binder phase is a carbide, nitride, or carbonitride of an element selected from the group consisting of at least one compound of AlN and Al 2 O 3 and V, Cr, Mn, Co, Ni, Nb, and Mo. And a cubic boron nitride sintered body according to (1), which comprises two or more compounds selected from the group consisting of a solid solution and a mutual solid solution thereof.
- the binder phase is selected from the group consisting of at least one compound of AlN and Al 2 O 3 and Co 5.47 N, Cr 2 N, CrN, Cr 3 C 2 , Mo 2 C and VC.
- the amount of tungsten element contained in the cubic boron nitride sintered body is 5% by mass or less based on the total mass of the cubic boron nitride sintered body, according to any one of (1) to (5) Cubic boron nitride sintered body.
- the simple metal and alloy not included in the binder phase are metals in which the single metal is composed of one kind of metal element, and the alloy is a metal composed of two or more kinds of metal elements
- (1) The coated cubic boron nitride sintered body according to any one of (6) to (6).
- At least one metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al, and Si, and at least one oxide or carbide of these metals The coated cubic boron nitride sintered body according to (9), comprising at least one selected from the group consisting of nitrides, borides, and mutual solid solutions thereof.
- the cubic boron nitride sintered body and the coated cubic boron nitride sintered body of the present invention are excellent in wear resistance, fracture resistance and toughness. Therefore, when the cubic boron nitride sintered body and the coated cubic boron nitride sintered body of the present invention are used as a cutting tool or a wear-resistant tool, an effect that the tool life can be extended is obtained.
- the cubic boron nitride sintered body of the present invention has a cubic boron nitride: 85 to 95% by volume with respect to the total mass of the cubic boron nitride sintered body, a binder phase and inevitable impurities: cubic boron nitride sintered.
- the cubic boron nitride sintered body is composed of 5 to 15% by volume with respect to the total mass of the body, and the total of these is 100% by volume.
- the amount of cubic boron nitride exceeds 95% by volume and the binder phase and unavoidable impurities are less than 5% by volume, the cubic boron nitride particles easily fall off.
- cubic boron nitride when the cubic boron nitride is less than 85% by volume and the binder phase and inevitable impurities are more than 15% by volume, the wear resistance of the cubic boron nitride sintered body is lowered. Therefore, cubic boron nitride was set to 85 to 95% by volume, and the binder phase and unavoidable impurities were set to 5 to 15% by volume. Among them, cubic boron nitride: 89 to 95% by volume, and the balance is preferably a binder phase and inevitable impurities.
- the cubic boron nitride and the content (volume%) of the binder phase and inevitable impurities were photographed at 1000 to 5000 times by photographing the cross-sectional structure of the cubic boron nitride sintered body with an SEM (scanning electron microscope).
- the cross-sectional structure photograph can be image-analyzed and obtained from each surface area ratio.
- the binder phase of the present invention is selected from the group consisting of carbides, nitrides, carbonitrides, oxides and their mutual solid solutions of elements selected from Al, V, Cr, Mn, Co, Ni, Nb and Mo. It consists of three or more compounds. Preferably, at least one of AlN (PDF card No. 25-1133) and Al 2 O 3 (PDF card No. 10-0173), V, Cr, Mn, Co, Ni, Nb, Mo carbide, nitriding And two or more selected from the group consisting of solids, carbonitrides and their mutual solid solutions.
- PDF card no. Is a number identifying a substance described in Powder Diffraction File PDF-2 Release 2004 of International Center for Diffraction Data. Since the binder phase of the present invention is composed of these compounds and does not contain simple metals or alloys, the wear of the binder phase can be suppressed.
- the simple metal means a metal composed of one kind of metal element
- the alloy means a metal composed of two or more kinds of metal elements.
- an intermetallic compound in which two or more metal elements are bonded at a certain ratio is a kind of alloy, and the binder phase of the present invention does not include an intermetallic compound. That is, since the entire cubic boron nitride sintered body does not contain a single metal or an alloy, the effect of improving the wear resistance of the cubic boron nitride sintered body can be obtained.
- the binder phase of the present invention is selected from the group consisting of at least one of AlN and Al 2 O 3 and Co 5.47 N, CrN, Cr 2 N, Cr 3 C 2 , Mo 2 C and VC 2 More preferably, it comprises more than seeds, and among them, it is more preferred that the binder phase contains Co 5.47 N and Cr 2 N, and among these, the binder phase comprises Al 2 O 3 , AlN, Co 5.47 N and Cr 2 N. More preferably.
- the cubic boron nitride sintered body of the present invention contains 0.5 to 5% by mass of aluminum element with respect to the total mass of the cubic boron nitride sintered body.
- Aluminum element combines with oxygen adsorbed on the raw material powder, and has the effect of strengthening the bond between cubic boron nitride particles and the binder phase.
- the amount of aluminum element contained in the cubic boron nitride sintered body is less than 0.5% by mass, the action of combining with oxygen is insufficient and the cubic boron nitride particles are likely to fall off.
- the amount of aluminum element contained in the cubic boron nitride sintered body of the present invention is set to 0.5 to 5% by mass with respect to the total mass of the cubic boron nitride sintered body.
- the aluminum element amount is preferably 0.5 to 4% by mass with respect to the total mass of the cubic boron nitride sintered body.
- the amount of aluminum element in the cubic boron nitride sintered body of the present invention can be measured using an EDS (energy dispersive X-ray analyzer) or the like.
- the average particle size of the cubic boron nitride of the present invention is not particularly limited. However, when the average particle size of the cubic boron nitride is less than 0.5 ⁇ m, the surface adsorbed oxygen amount of the cubic boron nitride increases and the average particle size is increased. The sintering reaction tends to be hindered and the sinterability tends to decrease. When the average particle size exceeds 5 ⁇ m, the binder phase tends to aggregate and the thickness of the brittle binder phase is larger than that of cubic boron nitride. Therefore, the average particle size of the cubic boron nitride of the present invention is preferably 0.5 to 5 ⁇ m. Among these, the average particle diameter of cubic boron nitride is more preferably 1 to 3 ⁇ m.
- Examples of impurities inevitably contained in the cubic boron nitride sintered body of the present invention include lithium element mixed from the raw material powder and tungsten element mixed in the mixing step of the raw material powder.
- the total amount of inevitable impurities is generally 5% by mass or less with respect to the total mass of the cubic boron nitride sintered body, and more preferably 3% by mass or less.
- tungsten element is contained in the cubic boron nitride sintered body as a compound such as WC and WB. There is a tendency for the cutting performance of the boron nitride sintered body to decrease.
- the amount of tungsten element contained in the cubic boron nitride sintered body of the present invention is preferably 5% by mass or less with respect to the total mass of the cubic boron nitride sintered body because cutting performance is improved. More preferably, the amount of tungsten element is 3% by mass or less. Most of the tungsten element contained as an inevitable impurity in the cubic boron nitride sintered body of the present invention is derived from a cemented carbide ball used for ball mill mixing.
- the amount of tungsten element contained in the cubic boron nitride sintered body of the present invention is adjusted by adjusting the composition of the cemented carbide ball, the amount of the cemented carbide ball used, the size of the cylinder, and the ball mill mixing time. Can be adjusted.
- the amount of tungsten element contained in the cubic boron nitride sintered body of the present invention can be measured using an EDS (energy dispersive X-ray analyzer) or the like.
- At least one metal selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al and Si, at least one oxide of these metals, carbide Mention may be made of at least one selected from the group consisting of nitrides, borides and their mutual solid solutions. Specific examples include TiN, TiC, TiCN, TiAlN, TiSiN, and CrAlN.
- the coating is preferably either a single layer or a laminate of two or more layers, and is also preferably an alternately laminated film in which thin films having different film thicknesses of 5 to 200 nm are alternately laminated. When the average film thickness is less than 0.5 ⁇ m, the effect of extending the tool life is reduced. When the average film thickness exceeds 15 ⁇ m, the fracture resistance tends to decrease. It is preferably 15 ⁇ m, more preferably 1 to 10 ⁇ m, and most preferably 1.5 to 5 ⁇ m.
- the cubic boron nitride sintered body and the coated cubic boron nitride sintered body of the present invention are excellent in wear resistance, fracture resistance and toughness, they are preferably used as cutting tools and wear resistant tools. More preferably, it is used as a tool, and more preferably, it is used as a cutting tool for sintered metal or a cutting tool for cast iron.
- the cubic boron nitride sintered body of the present invention can be obtained, for example, by the following manufacturing method.
- raw material powders cubic boron nitride powder having an average particle size of 0.5 to 8 ⁇ m, aluminum powder having an average particle size of 5 to 20 ⁇ m, and V, Cr, Mn, Co, Ni, having an average particle size of 0.5 to 5 ⁇ m
- a binder phase forming powder composed of two or more selected from the group consisting of Nb, Mo metal, carbide, nitride, carbonitride, and their mutual solid solution is prepared.
- the average particle diameter of the raw material powder is measured by the Fisher method (Fisher Sub-Sieve Sizer (FSSS)) described in American Society for Testing and Materials (ASTM) standard B330.
- the prepared raw material powders consisted of cubic boron nitride powder: 85 to 95% by volume, aluminum powder: 0.5 to 8% by volume, and binder phase forming powder: 3 to 14.5% by volume. It mix
- the shape of aluminum powder is not specifically limited, In this invention, it can be used even if it is any shape, such as spherical shape, scale shape, and needle shape. Paraffin is added to the blended raw material powder and mixed.
- the obtained mixture is molded and subjected to vacuum heat treatment at a temperature of 700 to 1000 ° C. in a vacuum of 5 ⁇ 10 ⁇ 3 Pa or less to remove organic substances such as paraffin, and then put into an ultrahigh pressure and high temperature generator. It is obtained by sintering under conditions of pressure 6 to 8 GPa, temperature 1700 to 2000 ° C. and holding time 20 to 60 minutes.
- the cubic boron nitride sintered body of the present invention is processed into a predetermined shape by a laser cutting machine or the like to produce a cutting tool or wear-resistant tool provided with the cubic boron nitride sintered body of the present invention. Can do.
- the coated cubic boron nitride sintered body of the present invention can be obtained by forming a film on the surface of the cubic boron nitride sintered body of the present invention by a conventional CVD method or PVD method.
- cBN Cubic boron nitride
- Cr powder having an average particle size of 4.9 ⁇ m
- Cr 2 N powder having an average particle size of 3.0 ⁇ m
- Cr 3 having an average particle size of 2.7 ⁇ m C 2 powder
- VC powder with an average particle size of 2.7 ⁇ m
- Mo 2 C powder with an average particle size of 2.5 ⁇ m
- TiN powder with an average particle size of 1.8 ⁇ m
- WC powder with an average particle size of 2.2 ⁇ m
- Co powder and a scaly aluminum (Al) powder having an average particle size of 20 ⁇ m were prepared and blended in the blending composition shown in Table 1.
- the average particle diameter of the raw material powder was measured by the Fisher method (Fisher Sub-Sieve Sizer (FSSS)) described in American Society for Testing and Materials (ASTM) standard B330.
- the blended raw material powder was placed in a ball mill cylinder together with a cemented carbide ball, an n-hexane solvent and paraffin, and ball mill mixing was performed for 24 hours. After the mixed powder obtained by mixing and pulverizing with a ball mill was compacted, it was deparaffinized under conditions of a pressure of 5 ⁇ 10 ⁇ 3 Pa and a temperature of 750 ° C.
- the compacted body that has been deparaffinized is enclosed in a metal capsule, the metal capsule is placed in an ultra-high pressure and high temperature generator, and sintered under a pressure of 7.0 GPa, a temperature of 1900 ° C., and a holding time of 30 minutes. Cubic boron nitride sintered bodies were obtained.
- the cross-sectional structure of the cubic boron nitride sintered body thus obtained was observed using SEM (HITACHI SEM S-3000H), and the composition was analyzed using EDS (HORIBA EMAX EX-300).
- EDS HORIBA EMAX EX-300.
- the cBN content (% by volume) and the binder phase content (% by volume) were determined from the respective surface areas.
- the amount of aluminum (Al) element (mass%) and the amount of tungsten (W) element (mass%) contained in the entire cubic boron nitride sintered body were quantitatively analyzed by EDS.
- the cubic boron nitride sintered body is cut into a predetermined shape with a laser cutting machine, brazed to a cemented carbide base material, and subjected to grinding finish processing to form an ISO standard CNGA120408 cutting insert
- the cutting tool was obtained.
- the following cutting tests (1) and (2) were performed using these cutting inserts. The results are shown in Table 3.
- Cutting test (1) Perimeter continuous wet cutting (turning), Work material: Carburized and quenched sintered metal (chemical component C: 0.2 to 1.0 mass%, Fe: remainder, other: 1 mass% or less (equivalent to the former JIS standard SMF4040), HRA 63 to 65), Work material shape: Cylinder ⁇ 45mm ⁇ 85mm, Cutting speed: 250 m / min, Cutting depth: 0.2 mm, Feed: 0.1 mm / rev, Insert shape: CNGA120408, Holder: DCLNR2525M12, Evaluation: Cutting time until the corner wear amount VBc reaches 0.15 mm or cutting time until a defect.
- Cutting test (2) Peripheral intermittent wet cutting (turning), Work material: Sintered metal (Chemical component C: 0.2 to 1.0 mass%, Fe: remainder, others: 1 mass% or less (equivalent to the former JIS standard SMF4040), HRB 77 to 80), Work material shape: Gear shape ⁇ 45mm (tooth height 8mm) x 30mm, Cutting speed: 300 m / min, Cutting depth: 0.2 mm, Feed: 0.1 mm / rev, Insert shape: CNGA120408, Holder: DCLNR2525M12, Evaluation: Cutting time until the corner wear amount VBc reaches 0.15 mm or cutting time until a defect.
- the cubic boron nitride sintered body of the present invention is superior in wear resistance and fracture resistance, and therefore has a longer tool life than the comparative cubic boron nitride sintered body.
- Example 2 The raw material powder of Example 1 was blended in the blending composition shown in Table 4, and a cubic boron nitride sintered body was produced by the same production method as in Example 1.
- the obtained cubic boron nitride sintered body was subjected to various measurements by the same measurement method as in Example 1. The results are shown in Table 5.
- a cubic boron nitride sintered body was processed in the same manner as in Example 1 to obtain a cutting tool having an ISO standard CNGA120408 cutting insert shape. Using these cutting inserts, cutting tests (1) and (2) under the same test conditions as in Example 1 were performed. The results are shown in Table 6.
- Example 3 The raw material powder of Example 1 was blended in the blending composition shown in Table 7, and a cubic boron nitride sintered body was produced by the same production method as in Example 1.
- a cubic boron nitride sintered body was processed in the same manner as in Example 1 to obtain a cutting tool having an ISO standard CNGA120408 cutting insert shape. Using these cutting inserts, cutting tests (1) and (2) under the same test conditions as in Example 1 were performed. The results are shown in Table 9.
- Example 4 The surface of Invention 1 of Example 1 was coated using a PVD apparatus.
- Inventive product 17 was obtained by forming a TiN film having an average film thickness of 3 ⁇ m on the surface of Invention product 1
- Invented product 18 was formed by forming a TiAlN film having an average film thickness of 3 ⁇ m on the surface of Invention product 1.
- the inventive products 17 and 18 were subjected to the same cutting tests (1) and (2) as in Example 1. The results are shown in Table 10.
- Inventive products 17 and 18 with a coating formed could have a longer tool life than Invention 1 without a coating.
- a cubic boron nitride sintered body and a coated cubic boron nitride sintered body excellent in wear resistance, fracture resistance and toughness can be provided.
- the cubic boron nitride sintered body and the coated cubic boron nitride sintered body of the present invention are used as a cutting tool or a wear-resistant tool, an effect that the tool life can be extended is obtained.
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Abstract
Description
(1)立方晶窒化硼素:85~95体積%と、結合相および不可避的不純物:5~15体積%とから構成され、結合相は、Al、V、Cr、Mn、Co、Ni、NbおよびMoから成る群より選択された元素の炭化物、窒化物、炭窒化物、酸化物およびこれらの相互固溶体から成る群より選択された3種以上の化合物からなり、立方晶窒化硼素焼結体に含まれるアルミニウム元素量は立方晶窒化硼素焼結体の全質量に対して0.5~5質量%であり、但し、結合相中に金属単体および合金は含まれないことを特徴とする立方晶窒化硼素焼結体。
(2)結合相は、AlNおよびAl2O3の少なくとも1種の化合物と、V、Cr、Mn、Co、Ni、NbおよびMoから成る群より選択された元素の炭化物、窒化物、炭窒化物およびこれらの相互固溶体から成る群より選択された2種以上の化合物とからなる(1)に記載の立方晶窒化硼素焼結体。
(3)結合相は、AlNおよびAl2O3の少なくとも1種の化合物と、Co5.47N、Cr2N、CrN、Cr3C2、Mo2CおよびVCから成る群より選択された2種以上の化合物とからなる(1)または(2)に記載の立方晶窒化硼素焼結体。
(4)結合相は、少なくともCo5.47NおよびCr2Nを含有する(1)~(3)のいずれかに記載の立方晶窒化硼素焼結体。
(5)結合相は、Al2O3、AlN、Co5.47NおよびCr2Nからなる(1)~(4)のいずれかに記載の立方晶窒化硼素焼結体。
(6)立方晶窒化硼素焼結体に含まれるタングステン元素量は、立方晶窒化硼素焼結体の全質量に対して5質量%以下である(1)~(5)のいずれかに記載の立方晶窒化硼素焼結体。
(7)結合相中に含まれない金属単体および合金は、金属単体が1種の金属元素から構成される金属であり、合金が2種以上の金属元素から構成される金属である(1)~(6)のいずれかに記載の被覆立方晶窒化硼素焼結体。
(8)切削工具または耐摩耗工具として使用される(1)~(7)のいずれかに記載の立方晶窒化硼素焼結体。
(9)(1)~(7)のいずれかに記載の立方晶窒化硼素焼結体の表面に被膜を形成した被覆立方晶窒化硼素焼結体。
(10)被膜がTi、Zr、Hf、V、Nb、Ta、Cr、Mo、W、AlおよびSiから成る群より選択された少なくとも1種の金属、これら金属の少なくとも1種の酸化物、炭化物、窒化物、硼化物およびこれらの相互固溶体から成る群より選択された少なくとも1種からなる(9)に記載の被覆立方晶窒化硼素焼結体。
(11)被膜がTiN、TiC、TiCN、TiAlN、TiSiNおよびCrAlNから成る群より選択された少なくとも1種からなる(9)または(10)に記載の被覆立方晶窒化硼素焼結体。
(12)被膜の平均膜厚が、0.5~15μmである(9)~(11)のいずれかに記載の被覆立方晶窒化硼素焼結体。
(13)切削工具または耐摩耗工具として使用される(9)~(12)のいずれかに記載の被覆立方晶窒化硼素焼結体。
平均粒径2μmの立方晶窒化硼素(以下、cBNと表す。)粉末、平均粒径4.9μmのCr粉末、平均粒径3.0μmのCr2N粉末、平均粒径2.7μmのCr3C2粉末、平均粒径2.7μmのVC粉末、平均粒径2.5μmのMo2C粉末、平均粒径1.8μmのTiN粉末、平均粒径2.2μmのWC粉末、平均粒径0.9μmのCo粉末、平均粒径20μmの鱗片状アルミニウム(Al)粉末を用意して、表1に示す配合組成に配合した。なお、原料粉末の平均粒径は米国材料試験協会(ASTM)規格B330に記載のフィッシャー法(Fisher Sub-Sieve Sizer(FSSS))により測定した。配合した原料粉末を超硬合金製ボールとn-ヘキサン溶媒とパラフィンとともにボールミル用のシリンダーに入れてボールミル混合を24時間行った。ボールミルで混合粉砕して得られた混合粉末を圧粉成型した後、圧力5×10-3Pa、温度750℃の条件で脱パラフィン処理をした。脱パラフィン処理をした圧粉成型体を金属カプセルに封入し、金属カプセルを超高圧高温発生装置に入れて、圧力7.0GPa、温度1900℃、保持時間30分の条件で焼結して、発明品および比較品の立方晶窒化硼素焼結体を得た。
外周連続湿式切削(旋削)、
被削材:浸炭焼入れした焼結金属(化学成分 C:0.2~1.0質量%,Fe:残部,その他:1質量%以下(旧JIS規格SMF4040相当)、HRA63~65)、
被削材形状:円柱φ45mm×85mm、
切削速度:250m/min、
切込み量:0.2mm、
送り:0.1mm/rev、
インサート形状:CNGA120408、
ホルダー:DCLNR2525M12、
評価:コーナ摩耗量VBcが0.15mmに達するまでの切削時間あるいは欠損までの切削時間。
外周断続湿式切削(旋削)、
被削材:焼結金属(化学成分 C:0.2~1.0質量%,Fe:残部,その他:1質量%以下(旧JIS規格SMF4040相当)、HRB77~80)、
被削材形状:ギア形状φ45mm(歯高8mm)×30mm、
切削速度:300m/min、
切込み量:0.2mm、
送り:0.1mm/rev、
インサート形状:CNGA120408、
ホルダー:DCLNR2525M12、
評価:コーナ摩耗量VBcが0.15mmに達するまでの切削時間あるいは欠損までの切削時間。
実施例1の原料粉末を表4に示す配合組成に配合し、実施例1と同様の製造方法により立方晶窒化硼素焼結体を作製した。
実施例1の原料粉末を表7に示す配合組成に配合し、実施例1と同様の製造方法により立方晶窒化硼素焼結体を作製した。
実施例1の発明品1の表面にPVD装置を用いて被覆処理を行った。発明品1の表面に平均膜厚3μmのTiN膜を形成したものを発明品17、発明品1の表面に平均膜厚3μmのTiAlN膜を形成したものを発明品18とした。発明品17、18について実施例1と同じ切削試験(1)および(2)を行った。それらの結果を表10に示す。
Claims (13)
- 立方晶窒化硼素:85~95体積%と、結合相および不可避的不純物:5~15体積%とから構成され、結合相は、Al、V、Cr、Mn、Co、Ni、NbおよびMoから成る群より選択された元素の炭化物、窒化物、炭窒化物、酸化物およびこれらの相互固溶体から成る群より選択された3種以上の化合物とからなり、立方晶窒化硼素焼結体に含まれるアルミニウム元素量は立方晶窒化硼素焼結体の全質量に対して0.5~5質量%であり、但し、結合相中に金属単体および合金は含まれないことを特徴とする立方晶窒化硼素焼結体。
- 結合相は、AlNおよびAl2O3の少なくとも1種の化合物と、V、Cr、Mn、Co、Ni、NbおよびMoから成る群より選択された元素の炭化物、窒化物、炭窒化物およびこれらの相互固溶体から成る群より選択された2種以上の化合物とからなる請求項1に記載の立方晶窒化硼素焼結体。
- 結合相は、AlNおよびAl2O3の少なくとも1種の化合物と、Co5.47N、Cr2N、CrN、Cr3C2、Mo2CおよびVCから成る群より選択された2種以上の化合物とからなる請求項1または2に記載の立方晶窒化硼素焼結体。
- 結合相は、少なくともCo5.47NおよびCr2Nを含有する請求項1~3のいずれか1項に記載の立方晶窒化硼素焼結体。
- 結合相は、Al2O3とAlNとCo5.47NとCr2Nとからなる請求項1~4のいずれか1項に記載の立方晶窒化硼素焼結体。
- 立方晶窒化硼素焼結体に含まれるタングステン元素量は、立方晶窒化硼素焼結体の全質量に対して5質量%以下である請求項1~5のいずれか1項に記載の立方晶窒化硼素焼結体。
- 結合相中に含まれない金属単体および合金は、金属単体が1種の金属元素から構成される金属であり、合金が2種以上の金属元素から構成される金属である請求項1~6のいずれか1項に記載の被覆立方晶窒化硼素焼結体。
- 切削工具または耐摩耗工具として使用される請求項1~7のいずれか1項に記載の立方晶窒化硼素焼結体。
- 請求項1~7のいずれか1項に記載の立方晶窒化硼素焼結体の表面に被膜を形成した被覆立方晶窒化硼素焼結体。
- 被膜がTi、Zr、Hf、V、Nb、Ta、Cr、Mo、W、AlおよびSiから成る群より選択された少なくとも1種の金属、これら金属の少なくとも1種の酸化物、炭化物、窒化物、硼化物およびこれらの相互固溶体から成る群より選択された少なくとも1種からなる請求項9に記載の被覆立方晶窒化硼素焼結体。
- 被膜がTiN、TiC、TiCN、TiAlN、TiSiNおよびCrAlNから成る群より選択された少なくとも1種からなる請求項9または10に記載の被覆立方晶窒化硼素焼結体。
- 被膜の平均膜厚が、0.5~15μmである請求項9~11のいずれか1項に記載の被覆立方晶窒化硼素焼結体。
- 切削工具または耐摩耗工具として使用される請求項9~12のいずれか1項に記載の被覆立方晶窒化硼素焼結体。
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