WO2013040612A1 - Verfahren zum herstellen einer aluminiumfolie mit integrierten sicherheitsmerkmalen - Google Patents
Verfahren zum herstellen einer aluminiumfolie mit integrierten sicherheitsmerkmalen Download PDFInfo
- Publication number
- WO2013040612A1 WO2013040612A1 PCT/AT2012/000222 AT2012000222W WO2013040612A1 WO 2013040612 A1 WO2013040612 A1 WO 2013040612A1 AT 2012000222 W AT2012000222 W AT 2012000222W WO 2013040612 A1 WO2013040612 A1 WO 2013040612A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aluminum foil
- rolling
- aluminum
- security features
- security feature
- Prior art date
Links
- 239000011888 foil Substances 0.000 title claims abstract description 69
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 68
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000005096 rolling process Methods 0.000 claims abstract description 28
- 238000005097 cold rolling Methods 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 31
- 230000008569 process Effects 0.000 claims description 14
- 230000008859 change Effects 0.000 claims description 7
- 239000010731 rolling oil Substances 0.000 claims description 6
- 230000003746 surface roughness Effects 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000006378 damage Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 230000000717 retained effect Effects 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 abstract description 2
- 238000007517 polishing process Methods 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 description 17
- 230000009467 reduction Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 229940127554 medical product Drugs 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001154582 Zamenis longissimus Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 238000007630 basic procedure Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000009516 primary packaging Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21H—MAKING PARTICULAR METAL OBJECTS BY ROLLING, e.g. SCREWS, WHEELS, RINGS, BARRELS, BALLS
- B21H8/00—Rolling metal of indefinite length in repetitive shapes specially designed for the manufacture of particular objects, e.g. checkered sheets
- B21H8/005—Embossing sheets or rolls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/227—Surface roughening or texturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/40—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B2003/001—Aluminium or its alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/30—Foil or other thin sheet-metal making or treating
- Y10T29/301—Method
- Y10T29/302—Clad or other composite foil or thin metal making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12431—Foil or filament smaller than 6 mils
Definitions
- the invention relates to a method for producing an aluminum foil with integrated security features as well as an aluminum foil produced by this method with integrated security features.
- the invention aims to remedy this situation.
- Aluminum foils is transferred, after which the loose composite of aluminum foils is separated.
- the invention further relates to an aluminum foil with integratedgromerk-paint, which after the
- Aluminum foil are disclosed according to subclaims 7 to 10.
- FIG. 1 shows a pair of work rolls for carrying out the method according to the invention
- FIG. 2 shows a detailed view of a work roll and its surface configuration
- FIG. 3 shows the Striebeck curve for documenting the relevant process parameters in the nip and FIG
- Embodiments for the integrated security feature are described.
- the manufacturing process of the aluminum foil 1 according to the invention with integrated security features 6 initially consists of the sub-processes continuous casting, homogenizing, hot rolling, cold rolling and subsequent annealing above the
- Recrystallization temperature This is followed by the process of film cold rolling.
- the aluminum foil 4 is rolled in several cold rolling passes to a thickness of less than 150 ⁇ , wherein at the same time on both surface sides 4a, 4b of the aluminum foil, a texturing 5a, 5b running in the rolling direction is formed, see FIG. 4b. This in
- Security feature 6 is due to this random texturing to a diffuse reflection of the incident light, so that the area of the security feature 6 appears dull.
- the aluminum foil 4 ⁇ has at its
- Foil rolls belong to the subgroup "flat rolls", and are defined in particular by process end products with a thickness of 20.
- the cold rolling process in this thickness range requires the specific use of surface roughness values for tools in combination with process technology
- Reference symbol 14 from FIG. 2a - "floats" the work roll 11, so that a targeted control of the rolling process and in particular the reduction of the material thickness is no longer possible.
- v, p and n By varying the parameters v, p and n, one can therefore set the range of mixed friction.
- Lubricant plays only a minor role.
- the ratio between boundary friction and fluid friction over the length of the nip depends on the layer thickness of the drawn-in lubricant and the roughness of the work roll and the aluminum foil.
- the mechanisms for influencing the lubricant film thickness 13 are influenced by the hydrodynamic lubricant feed, the entry of lubricant into the roughness valleys IIb and the attachment of lubricant particles, see FIG. 2 B.
- the hydrodynamic lubricant entry 14 takes place primarily in the inlet zone to the nip 9 '.
- the inlet zone forms a wedge-shaped gap 12, wherein the
- Pressure build-up depends on the rolling speed, the viscosity of the lubricant and the geometry of the nip. As soon as the flow condition for the aluminum foils 4 is met, they are plastically deformed and the layer thickness of the lubricant present at this location is transformed into the
- lubricant is introduced into the surface depressions, the so-called roughness valleys IIb, on the work roll 11 and the aluminum foil 4, see FIG. 4c.
- This mechanism can be used for the targeted modification of
- Friction ratios are used, and subsequently serves to produce a changed surface texture due to the resulting fluid friction. This is done by the lack of contact of the work roll and the lack of texturing in the rolling direction.
- Lubricant components such as. B. surface active
- This mechanism is influenced by rolling and rolling stock as well as the chemical composition of the rolling oil 12 and its temperature. Since the Temperature and the composition of the rolling oil 12 with respect to the attachment of lubricant components in
- measured reflectances differs barely measurable, but visually differs significantly from the other surface areas due to the reflective properties, which have a structured surface in the rolling direction due to the partial contact with the work roll.
- Security features 6 is scanned for analysis in multiple passes using optical techniques.
- Fig. 5 shows the representation of a security feature 6 consisting of the word security in conjunction with the in the
- Fig. 6 is a fanciful representation of a
- Security Feature 6 a matte surface, but in the respective adjacent surface areas the structuring 3 is further obtained in the longitudinal direction, whereby the surface appears shiny.
- FIG. 7 shows a representation of a security feature 6.1m recorded by means of scanning electron microscopy
- the area of the security feature is the surface matt, whereas in the adjacent surface areas the
- FIGS. 7a and 7b respectively show that this different effect is caused by the fact that in the area of the
- Security feature 6 the surface is rough, in the adjacent areas, however, is structured in the longitudinal direction.
- Structuring 13 is present.
- Properties of the aluminum foil 4 such as roughness, foldability, elongation, tensile strength and wettability
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
- Laminated Bodies (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2819772A CA2819772C (en) | 2011-09-22 | 2012-08-27 | Process for the manufacture of an aluminum foil with integrated security features |
RU2013122467/02A RU2598413C2 (ru) | 2011-09-22 | 2012-08-27 | Способ изготовления алюминиевой фольги с интегрированными защитными элементами |
CN201280045954.3A CN103889604B (zh) | 2011-09-22 | 2012-08-27 | 用于制造带有集成的安全标志的铝箔的方法 |
KR1020147008212A KR101975313B1 (ko) | 2011-09-22 | 2012-08-27 | 통합된 보안 특징들을 구비한 알루미늄 호일 제조 방법 |
JP2014531043A JP5996653B2 (ja) | 2011-09-22 | 2012-08-27 | 統合されたセキュリティ機能を有するアルミフォイルを製造するための方法 |
US14/346,767 US20140322557A1 (en) | 2011-09-22 | 2012-08-27 | Method for producing an aluminum foil with integrated security features |
MX2014003290A MX348425B (es) | 2011-09-22 | 2012-08-27 | Método para producir una lámina delgada de aluminio con características de seguridad integradas. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11450126.5A EP2572807B1 (de) | 2011-09-22 | 2011-09-22 | Verfahren zum Herstellen einer Aluminiumfolie mit integrierten Sicherheitsmerkmalen |
EP11450126.5 | 2011-09-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013040612A1 true WO2013040612A1 (de) | 2013-03-28 |
Family
ID=46851222
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2012/000222 WO2013040612A1 (de) | 2011-09-22 | 2012-08-27 | Verfahren zum herstellen einer aluminiumfolie mit integrierten sicherheitsmerkmalen |
Country Status (13)
Country | Link |
---|---|
US (1) | US20140322557A1 (de) |
EP (1) | EP2572807B1 (de) |
JP (1) | JP5996653B2 (de) |
KR (1) | KR101975313B1 (de) |
CN (1) | CN103889604B (de) |
CA (1) | CA2819772C (de) |
ES (1) | ES2492520T3 (de) |
HR (1) | HRP20140861T1 (de) |
MX (1) | MX348425B (de) |
PL (1) | PL2572807T3 (de) |
RU (1) | RU2598413C2 (de) |
SI (1) | SI2572807T1 (de) |
WO (1) | WO2013040612A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT512773B1 (de) | 2012-10-29 | 2013-11-15 | Constantia Teich Gmbh | Verfahren zum Herstellen einer Aluminiumfolie mit integrierten Sicherheitsmerkmalen |
EP3238843A1 (de) * | 2016-04-29 | 2017-11-01 | Primetals Technologies Austria GmbH | Verfahren zum walzen eines walzgutes |
CN108856291A (zh) * | 2018-05-17 | 2018-11-23 | 河钢股份有限公司承德分公司 | 一种强度750MPa级极薄花纹板的轧制方法 |
CN113634607B (zh) * | 2021-07-01 | 2023-09-22 | 乳源东阳光优艾希杰精箔有限公司 | 一种铝箔轧机轧制油及其在铝箔制备中的应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS577303A (en) * | 1980-06-17 | 1982-01-14 | Showa Alum Corp | Manufacture of aluminum foil for use of reflector |
US6187455B1 (en) * | 1998-03-24 | 2001-02-13 | Hunter Douglas International N.V. | Decorative roll-patterned strip and process of making same |
WO2003104890A1 (de) * | 2002-06-06 | 2003-12-18 | Teich Aktiengesellschaft | Fälschungssichere metallfolie |
Family Cites Families (28)
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US3938723A (en) * | 1972-01-03 | 1976-02-17 | Slaughter Edward R | Method for rolling thin metal films |
JPS5994505A (ja) * | 1982-11-22 | 1984-05-31 | Toyo Seikan Kaisha Ltd | 水濡れ性のすぐれた包装用アルミニウム箔およびその製造方法 |
SU1084091A1 (ru) * | 1983-02-17 | 1984-04-07 | Запорожский Ордена "Знак Почета" Машиностроительный Институт Им.В.Я.Чубаря | Способ обработки поверхности листа |
JPH07115046B2 (ja) * | 1986-11-20 | 1995-12-13 | 川崎製鉄株式会社 | 模様付金属板 |
JPS63165011A (ja) * | 1986-12-25 | 1988-07-08 | Kawasaki Steel Corp | 模様鋼板及びその製造方法 |
JPS6471502A (en) * | 1987-09-09 | 1989-03-16 | Sumitomo Metal Ind | Manufacture of decorative metal sheet |
US4927070A (en) * | 1989-03-10 | 1990-05-22 | Steven D. Kretchmer | Method for making multi-colored composite laminates |
US4996113A (en) * | 1989-04-24 | 1991-02-26 | Aluminum Company Of America | Brightness enhancement with textured roll |
JPH03281075A (ja) * | 1990-03-28 | 1991-12-11 | Kawasaki Steel Corp | 圧延用ロールの表面加工方法 |
JP2546024B2 (ja) * | 1990-04-13 | 1996-10-23 | 住友金属工業株式会社 | 意匠性金属板製造法とそのための剥離剤 |
US5025547A (en) * | 1990-05-07 | 1991-06-25 | Aluminum Company Of America | Method of providing textures on material by rolling |
US5105638A (en) * | 1990-07-12 | 1992-04-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Method and machine for rolling a metal workpiece at a reduced rolling load |
US5390518A (en) * | 1992-11-10 | 1995-02-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for shining metal sheet surfaces and method for cold-rolling metallic materials |
US5537851A (en) * | 1993-01-05 | 1996-07-23 | Aluminum Company Of America | Sheet product produced by massive reduction in last stand of cold rolling process |
JP3615813B2 (ja) * | 1994-12-28 | 2005-02-02 | 株式会社日立製作所 | 作業ロールクロス圧延機のロール間潤滑油供給システム |
JP3388078B2 (ja) * | 1995-12-28 | 2003-03-17 | 新日本製鐵株式会社 | 冷間圧延用ワークロールおよびその加工方法 |
ES2248837T5 (es) * | 1997-07-17 | 2009-04-16 | ALCAN TECHNOLOGY & MANAGEMENT AG | Utilizacion de un producto laminado de metal con estructura superficial de propagacion de la luz. |
DE19902527B4 (de) * | 1999-01-22 | 2009-06-04 | Hydro Aluminium Deutschland Gmbh | Druckplattenträger und Verfahren zur Herstellung eines Druckplattenträgers oder einer Offsetdruckplatte |
JP4646161B2 (ja) * | 1999-04-02 | 2011-03-09 | ハンター・ダグラス・インターナショナル・エヌ・ブイ | 圧延型押しされたストリップ |
CA2381244C (en) * | 1999-08-09 | 2005-10-18 | Alcan International Limited | Process of producing diffraction gratings on the surfaces of articles |
DE10110323A1 (de) * | 2001-03-03 | 2002-09-05 | Sms Demag Ag | Verfahren zur gezielten Einstellung der Oberflächenstruktur von Walzgut beim Kaltnachwalzen in Dressier-Walzgerüsten |
JP2003205303A (ja) * | 2001-11-06 | 2003-07-22 | Jfe Steel Kk | 金属箔帯の重ね圧延方法 |
EP1344580A1 (de) * | 2002-03-12 | 2003-09-17 | Alcan Technology & Management Ltd. | Verfahren und Anlage zur Herstellung eines Aluminiumbandes mit texturierter Oberfläche |
DE20300435U1 (de) * | 2003-01-13 | 2004-06-03 | Kunststoff-Technik Scherer & Trier Gmbh & Co Kg | Mehrlagiges Dekorband |
JP4713136B2 (ja) * | 2004-11-26 | 2011-06-29 | 日本製箔株式会社 | アルミニウム箔及びその製造方法 |
WO2006058424A1 (en) * | 2004-12-03 | 2006-06-08 | Novelis Inc. | Roll embossing of discrete features |
DE102008019768A1 (de) * | 2008-04-18 | 2009-10-22 | Hydro Aluminium Deutschland Gmbh | Verfahren zur Herstellung eines Bandes für Verpackungszwecke |
WO2010017289A1 (en) * | 2008-08-05 | 2010-02-11 | Alcoa Inc. | Metal sheets and plates having friction-reducing textured surfaces and methods of manufacturing same |
-
2011
- 2011-09-22 PL PL11450126T patent/PL2572807T3/pl unknown
- 2011-09-22 SI SI201130265T patent/SI2572807T1/sl unknown
- 2011-09-22 ES ES11450126.5T patent/ES2492520T3/es active Active
- 2011-09-22 EP EP11450126.5A patent/EP2572807B1/de active Active
-
2012
- 2012-08-27 WO PCT/AT2012/000222 patent/WO2013040612A1/de active Application Filing
- 2012-08-27 CN CN201280045954.3A patent/CN103889604B/zh not_active Expired - Fee Related
- 2012-08-27 MX MX2014003290A patent/MX348425B/es active IP Right Grant
- 2012-08-27 US US14/346,767 patent/US20140322557A1/en not_active Abandoned
- 2012-08-27 JP JP2014531043A patent/JP5996653B2/ja not_active Expired - Fee Related
- 2012-08-27 KR KR1020147008212A patent/KR101975313B1/ko active IP Right Grant
- 2012-08-27 CA CA2819772A patent/CA2819772C/en not_active Expired - Fee Related
- 2012-08-27 RU RU2013122467/02A patent/RU2598413C2/ru active
-
2014
- 2014-09-11 HR HRP20140861AT patent/HRP20140861T1/hr unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS577303A (en) * | 1980-06-17 | 1982-01-14 | Showa Alum Corp | Manufacture of aluminum foil for use of reflector |
US6187455B1 (en) * | 1998-03-24 | 2001-02-13 | Hunter Douglas International N.V. | Decorative roll-patterned strip and process of making same |
WO2003104890A1 (de) * | 2002-06-06 | 2003-12-18 | Teich Aktiengesellschaft | Fälschungssichere metallfolie |
Also Published As
Publication number | Publication date |
---|---|
MX348425B (es) | 2017-06-12 |
CN103889604B (zh) | 2016-12-28 |
SI2572807T1 (sl) | 2014-10-30 |
CA2819772C (en) | 2015-08-11 |
US20140322557A1 (en) | 2014-10-30 |
JP2015502254A (ja) | 2015-01-22 |
MX2014003290A (es) | 2014-12-05 |
RU2598413C2 (ru) | 2016-09-27 |
ES2492520T3 (es) | 2014-09-09 |
KR101975313B1 (ko) | 2019-08-28 |
RU2013122467A (ru) | 2014-11-20 |
PL2572807T3 (pl) | 2014-11-28 |
CN103889604A (zh) | 2014-06-25 |
HRP20140861T1 (hr) | 2014-10-24 |
EP2572807B1 (de) | 2014-06-11 |
KR20140077159A (ko) | 2014-06-23 |
JP5996653B2 (ja) | 2016-09-21 |
EP2572807A1 (de) | 2013-03-27 |
CA2819772A1 (en) | 2013-03-28 |
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