WO2012169481A1 - Adhésif aqueux, et structure stratifiée - Google Patents

Adhésif aqueux, et structure stratifiée Download PDF

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Publication number
WO2012169481A1
WO2012169481A1 PCT/JP2012/064425 JP2012064425W WO2012169481A1 WO 2012169481 A1 WO2012169481 A1 WO 2012169481A1 JP 2012064425 W JP2012064425 W JP 2012064425W WO 2012169481 A1 WO2012169481 A1 WO 2012169481A1
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WO
WIPO (PCT)
Prior art keywords
copolymer
polymer
ethylene
water
aqueous emulsion
Prior art date
Application number
PCT/JP2012/064425
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English (en)
Japanese (ja)
Inventor
肥後　睦子
晶文 熊野
礼 吉田
Original Assignee
住友化学株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友化学株式会社 filed Critical 住友化学株式会社
Publication of WO2012169481A1 publication Critical patent/WO2012169481A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/026—Knitted fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/06—Polymers of vinyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/748—Releasability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00—Packaging equipment or accessories not otherwise provided for
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles

Definitions

  • the polymer comprises a structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms, an ⁇ -olefin having 2 to 20 carbon atoms different from the ⁇ -olefin having 2 to 20 carbon atoms, ⁇ , ⁇ - [1] to [4] are copolymers having structural units derived from one or more monomers selected from the group consisting of unsaturated carboxylic acid esters, ⁇ , ⁇ -unsaturated carboxylic acid anhydrides, and vinyl acetate.
  • the water-based adhesive as described in any one of.
  • the water-based adhesive according to any one of [1] to [6], which is a copolymer having [8]
  • the polymer is (A) Ethylene-propylene copolymer, propylene-1-butene copolymer, ethylene-1-butene copolymer, ethylene-1-octene copolymer, ethylene-1-hexene copolymer, ethylene-propylene- An ⁇ -olefin copolymer such as 1-butene copolymer or a modified product thereof; or a mixture of two or more of these, (B) Ethylene-propylene copolymer, propylene-1-butene copolymer, ethylene-1-butene copolymer, ethylene-1-octene copolymer, ethylene-1-hexene copolymer, ethylene-propylene- An ⁇ -olefin copolymer such as 1-butene copolymer or a maleic anhydride modified
  • it contains a terpene resin selected from the group consisting of a terpene polymer, a terpene phenol, a ⁇ -pinene polymer, an aromatic modified terpene polymer, an ⁇ -pinene polymer, and a terpene hydrogenated resin.
  • a terpene resin selected from the group consisting of a polyurethane resin and a terpene polymer, terpene phenol, ⁇ -pinene polymer, aromatic modified terpene polymer, ⁇ -pinene polymer, terpene hydrogenated resin
  • the water-based adhesive according to any one of [1] to [10] comprising: [14] The aqueous adhesive according to any one of [1] to [10], further comprising a polyurethane resin and terpene phenol or a water-insoluble polyurethane resin and terpene phenol.
  • MDI diphenylmethane diisocyanate
  • TDI tolylene diisocyanate
  • HDI hexamethylene diisocyanate
  • XDI xylene diisocyanate
  • oligomers or polymers thereof [1] The water-based adhesive according to any one of [14].
  • the aqueous adhesive according to any one of [1] to [17], wherein the aqueous adhesive contains a dispersoid having a particle size (number basis) of 0.01 to 1.0 ⁇ m.
  • the surfactant contains 0.1 to 50 parts by weight, 0.1 to 20 parts by weight, or 0.1 to 10 parts by weight with respect to 100 parts by weight of the total resin constituting the aqueous emulsion.
  • the water-based adhesive according to any one of [18] to [18].
  • the surfactant is a surfactant represented by the formula (A) and a surfactant represented by the formula (B) in a mass ratio of 1 to 99:99 to 1, 5 to 95.
  • a first substrate made of polyolefin, an adhesive layer containing a polymer having one or more structural units derived from ⁇ -olefin having 2 to 20 carbon atoms, and a second substrate made of cotton-containing fibers A laminated structure laminated in this order.
  • the adhesive layer is a layer formed from the aqueous adhesive according to any one of [1] to [21].
  • an aqueous adhesive capable of firmly bonding adherends, particularly, polyolefin and cotton-containing fibers.
  • the aqueous adhesive of the present invention contains a polymer having at least one type of structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms.
  • This water-based adhesive can be used as an adhesive between adherends made of various materials, and is particularly suitable for adhesion between polyolefin and cotton-containing fibers.
  • the laminated structure of the present invention includes a first base material made of polyolefin, an adhesive layer containing a polymer having one or more types of structural units derived from ⁇ -olefin having 2 to 20 carbon atoms, and a second base made of cotton-containing fibers. Are laminated in this order.
  • the adhesive layer is sandwiched between substrates made of various materials, in particular, between the laminated structures of polyolefin and cotton-containing fibers.
  • the adhesive layer is a layer obtained by an adhesive, particularly a water-based adhesive, and is a layer formed by evaporation of water and a solvent when contained in the adhesive.
  • the polyolefin (hereinafter sometimes referred to as “first base material”) is a thermoplastic resin obtained by polymerizing an olefin.
  • first base material a thermoplastic resin obtained by polymerizing an olefin.
  • a structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms is used. Examples thereof include homopolymers and copolymers having more than one type.
  • Examples of the ⁇ -olefin having 2 to 20 carbon atoms include ethylene (C2), propylene (C3), 1-butene (C4), 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-octene, Nonene, 1-decene, 1-undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene, 1-eicosene, vinylcyclohexane, etc. Can be mentioned. Preferred are ethylene, propylene and the like. Examples of the polymer having a structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms include those described later.
  • polyethylene has various properties such as high-density polyethylene, low-density polyethylene, ultra-low-density polyethylene, linear low-density polyethylene, and ultra-high-molecular-weight polyethylene depending on the molecular weight.
  • Polyethylene as a body includes any of these.
  • Polypropylene is a thermoplastic resin obtained by polymerizing propylene. Due to the difference in stereoregularity, there are polypropylenes with different isotactic (isotactic), syndiotactic, and atactic stereoregularity. These polypropylenes include any of these.
  • the cotton-containing fiber may be 100% cotton fiber, or a mixed fiber of cotton and other natural fibers and / or chemical fibers. There may be.
  • Other natural fibers include wool, silk, hemp and the like.
  • Chemical fibers include synthetic fibers (for example, polyamide fibers such as polyester and nylon), semi-synthetic fibers (cellulose fibers such as acetate, protein fibers such as promix), regenerated fibers (rayon, cupra, polynosic, etc.) Cellulosic fibers), inorganic fibers (carbon fibers, glass fibers) and the like.
  • Examples of the form of the polyolefin and cotton-containing fiber that are the adherend of the aqueous adhesive of the present invention include various forms such as fiber, woven fabric, knitted fabric, nonwoven fabric, knitted fabric, felt, film, block, and foam. .
  • the water-based adhesive of the present invention exhibits functions such as an adhesive, an adhesive, an adhesive modifier, a heat sealant, a paint, a primer for paint, an ink binder, an adhesive, and an emulsion modifier. It is used as an adhesive for bonding polyolefin and cotton-containing fibers used in films and sheets, structural materials, building materials, automobile parts, electrical / electronic products, packaging materials, clothing, shoes, and the like.
  • polyolefin materials and cotton which are constituent materials of the hood, insole, outer bottom, etc., in footwear including men's shoes and women's shoes such as sports shoes, town shoes, business shoes, and industrial work shoes, etc. It is suitably used as an adhesive for bonding between the contained fiber materials.
  • the size, thickness, shape and the like of the polyolefin and the cotton-containing fiber can be appropriately adjusted according to the purpose of use of the laminated structure.
  • the surfaces of the polyolefin and cotton-containing fibers may be smooth or may have irregularities.
  • attachment such as an adhesive agent, on the surface of a 1st base material and / or a 2nd base material.
  • the primer treatment include blast treatment, chemical treatment, degreasing, flame treatment, oxidation treatment, steam treatment, corona discharge treatment, ultraviolet irradiation treatment, plasma treatment, ion treatment, anchor layer formation, and the like.
  • the adhesive contains a polymer having at least one type of structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms.
  • the polymer contained in the aqueous adhesive of the present invention has at least one type of structural unit derived from an ⁇ -olefin having 2 to 20 carbon atoms.
  • Examples of the ⁇ -olefin having 2 to 20 carbon atoms are the same as those described above.
  • Preferred are ethylene, propylene, 1-butene and the like.
  • a melting peak is observed by a differential scanning calorimetry (DSC) in the temperature range of ⁇ 100 to 200 ° C., a crystal melting peak with a crystal melting heat of 1 J / g or more or a crystal with a crystallization heat of 1 J / g or more. This means that a chemical peak is observed.
  • DSC differential scanning calorimetry
  • the ⁇ -olefin polymer may be a copolymer of ethylene and one or more ⁇ -olefins having 3 to 20 carbon atoms, a modified product of this copolymer, or a mixture thereof. preferable.
  • Examples of unsaturated carboxylic acids or anhydrides include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, itaconic anhydride, fumaric acid, crotonic acid, and unsaturated dicarboxylic acid half esters and half amides. Is mentioned. Of these, acrylic acid, methacrylic acid, maleic acid, and maleic anhydride are preferable, and acrylic acid and maleic anhydride are particularly preferable.
  • Examples of the metal salt of ⁇ , ⁇ -unsaturated carboxylic acid include sodium salt and magnesium salt of (meth) acrylic acid.
  • Examples of ⁇ , ⁇ -unsaturated carboxylic acid esters include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, glycidyl (meth) acrylate, 2-hydroxyethyl acrylate, Examples include esterified products of methacrylic acid and alcohol. Of these, methyl (meth) acrylate and ethyl (meth) acrylate are preferred.
  • vinyl aromatic compound examples include styrene, ⁇ -methylstyrene, p-methylstyrene, vinylxylene, monochlorostyrene, dichlorostyrene, monobromostyrene, dibromostyrene, fluorostyrene, p-tert-butylstyrene, ethylstyrene, Examples include vinyl naphthalene.
  • Examples of the alicyclic conjugated polyene compound include 2-methyl-1,3-cyclopentadiene, 2-methyl-1,3-cyclohexadiene, 2,3-dimethyl-1,3-cyclopentadiene, 2,3- Dimethyl-1,3-cyclohexadiene, 2-chloro-1,3-butadiene, 2,3-dichloro-1,3-butadiene, 1-fluoro-1,3-butadiene, 2-chloro-1,3-pentadiene 2-chloro-1,3-cyclopentadiene, 2-chloro-1,3-cyclohexadiene, and the like.
  • Ether and alpha is a copolymer having a structural unit derived from one or more monomers selected from the group consisting of ⁇ - unsaturated carboxylic acid.
  • the content of the polymer can be appropriately adjusted depending on, for example, the type of polymer used, the purpose of use, the performance to be obtained, and the like.
  • it is preferably 1 to 60% by weight with respect to the total amount of the water-based adhesive. %, More preferably 3 to 60% by weight, 3 to 50% by weight, still more preferably 5 to 55% by weight.
  • anionic groups such as a sulfonyl group and a carboxyl group are preferable, and a sulfonyl group is more preferable. This is because there is a tendency to further improve the water resistance of an aqueous emulsion obtained by emulsion polymerization of monomers.
  • the anionic group is preferably neutralized by a neutralizing agent.
  • the neutralizing agent include tertiary amine compounds such as triethylamine and trietalamine; inorganic alkali compounds such as sodium hydroxide; ammonia and the like.
  • aqueous emulsion was produced in the same manner as ⁇ Aqueous emulsion production example 1> except that 100 parts of the polymer (B-4-2) [BONDINE AX8390 (manufactured by ARKEMA)] was used as the copolymer.
  • the obtained aqueous emulsion (E-9) had a particle size (on a number basis) of 0.11 ⁇ m and a nonvolatile content concentration of 42%.
  • the mixture was kneaded at 300 rpm for 3 minutes (shear rate 1173 sec- 1 ). After kneading, the content was taken out and stirred and dispersed in a container containing warm water of about 70 ° C. to obtain an aqueous emulsion (E-35) having a volume-based median diameter of dispersoid of 0.43 ⁇ m.
  • aqueous emulsion (E-44) was obtained by blending a polyurethane emulsion (SBU, Dispacol U-54) and isocyanate (SBU, Desmodur N3300) at a nonvolatile content ratio of 100 parts: 5 parts. It was.
  • SBU polyurethane emulsion
  • SBU Desmodur N3300

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention a pour objectif de fournir : un adhésif aqueux doté d'excellentes propriétés d'adhérence et destiné à mettre en adhésion une polyoléfine et une fibre contenant du coton; et une structure stratifiée de polyoléfine / couche adhésive / fibre contenant du coton. De préférence, l'adhésif aqueux destiné à mettre en adhésion la polyoléfine et la fibre contenant du coton, contient un polymère possédant une ou plusieurs sortes d'unité structurale dérivée d'une α-oléfine de 2 à 20 atomes de carbone, et contient en outre de l'eau et un agent tensio-actif représenté par la formule (I). (Dans la formule : X représente un atome d'hydrogène, ou -SO3M (M est un atome d'hydrogène, NH4, ou un métal alcalin); n représente un entier de 1 à 3; et m représente un entier de 1 à 100.)
PCT/JP2012/064425 2011-06-10 2012-06-05 Adhésif aqueux, et structure stratifiée WO2012169481A1 (fr)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2011130397 2011-06-10
JP2011-130400 2011-06-10
JP2011-130397 2011-06-10
JP2011130400 2011-06-10
JP2011288246 2011-12-28
JP2011-288246 2011-12-28
JP2011288250 2011-12-28
JP2011-288250 2011-12-28

Publications (1)

Publication Number Publication Date
WO2012169481A1 true WO2012169481A1 (fr) 2012-12-13

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TW (1) TW201307499A (fr)
WO (1) WO2012169481A1 (fr)

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JPH02127491A (ja) * 1988-11-04 1990-05-16 Dai Ichi Kogyo Seiyaku Co Ltd 水系接着剤組成物
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JP2009235289A (ja) * 2008-03-28 2009-10-15 Unitika Ltd 水性分散体および積層体
WO2009125672A1 (fr) * 2008-04-07 2009-10-15 日東電工株式会社 Composition adhésive, film de protection superficiel, et film de protection d'une surface en verre mère pour écran plat
JP2009538951A (ja) * 2006-06-01 2009-11-12 サイテック サーフェース スペシャリティーズ、エス．エイ． 感圧接着剤
JP2010209282A (ja) * 2009-03-12 2010-09-24 Chuo Rika Kogyo Corp 接着剤エマルジョン組成物

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53134833A (en) * 1977-04-28 1978-11-24 Ito Katsuaki Waterrbase adhesives
JPS60203683A (ja) * 1984-02-20 1985-10-15 Sumitomo Chem Co Ltd 接着剤
JPH02127491A (ja) * 1988-11-04 1990-05-16 Dai Ichi Kogyo Seiyaku Co Ltd 水系接着剤組成物
JPH04202393A (ja) * 1990-11-29 1992-07-23 Sekisui Chem Co Ltd 接着剤組成物
JPH08507818A (ja) * 1993-03-18 1996-08-20 エイチ・ビー・フラー・ライセンシング・アンド・ファイナンシング・インコーポレーテッド 貼合わせ用分散剤
JPH0782540A (ja) * 1993-09-13 1995-03-28 Sumitomo Chem Co Ltd 耐水性接着剤
JPH0912999A (ja) * 1995-07-04 1997-01-14 Shoei Kagaku Kogyo Kk 水系接着剤組成物
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