WO2012133293A1 - Produit cosmétique pour cils - Google Patents

Produit cosmétique pour cils Download PDF

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Publication number
WO2012133293A1
WO2012133293A1 PCT/JP2012/057733 JP2012057733W WO2012133293A1 WO 2012133293 A1 WO2012133293 A1 WO 2012133293A1 JP 2012057733 W JP2012057733 W JP 2012057733W WO 2012133293 A1 WO2012133293 A1 WO 2012133293A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
cosmetic
ester
dextrin
effect
Prior art date
Application number
PCT/JP2012/057733
Other languages
English (en)
Japanese (ja)
Inventor
孝広 岸菜
井手　信之
Original Assignee
株式会社 資生堂
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Priority to JP2013507557A priority Critical patent/JP6113654B2/ja
Publication of WO2012133293A1 publication Critical patent/WO2012133293A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides

Definitions

  • the present invention relates to cosmetics for wrinkles. More specifically, the transparency in the state of the base is high, and when a coloring material or colored fiber is blended, the gloss effect and long effect of wrinkles are excellent, and the stability is good. It relates to cosmetics for vaginal.
  • the effects required for cosmetics for eyelashes are the long effect that makes the eyelids look longer, the volume increase effect that makes the eyelids thicker and the eyes clearer, the curl effect that makes the eyeglasses curl and make the eyes look larger, and the coloring that colors the eyelids
  • the effect and the persistence of each makeup effect were the main ones.
  • Recently, in addition to the conventional makeup effect there is a demand for a fresh gloss effect that gives the impression of being wet.
  • vaginal cosmetics In conventional vaginal cosmetics, a large amount of oily wax is blended to impart a solidifying power, and a vaginal cosmetic having a long effect and curling power is produced by blending a silicone-modified polysaccharide compound. Therefore, the base is not transparent but exhibits a base color derived from wax, which tends to inhibit the blackness and glossiness of the mascara, resulting in a matte finish.
  • an oily base is known that uses dextrin palmitic acid ester and Benton, which is an organically modified clay mineral, and is thickened with a small amount of water (Patent Document 1). There was a tendency to become creamy and to impair blackness.
  • a spinnable composition containing a silicone-modified polysaccharide compound and a lysine derivative-modified silicone has been developed as a highly transparent base that suppresses the whiteness of the base (Patent Document 2).
  • the stability of this composition is highly dependent on temperature, and there is a problem with stability at low and high temperatures.
  • blended the clay mineral with this base and made it the emulsification type base had the problem that stability was impaired, but transparency was impaired.
  • a highly transparent gloss base containing a high-viscosity oil agent and a specific water-soluble polymer is also known (Patent Document 3), but the long effect is insufficient and the fiber gloss is not satisfactory.
  • the present invention has a high transparency in the state of a base, and when blended with a coloring material or a colored fiber, it has an excellent gloss and long effect, and has excellent stability.
  • the purpose is to provide.
  • the present inventors have used a dextrin (palmitic acid / 2-ethylhexanoic acid) ester and a sucrose fatty acid ester having a small solidification power as an oil gelling agent in combination, and a nonionic surfactant together with a silicone-modified polysaccharide compound.
  • a dextrin palmitic acid / 2-ethylhexanoic acid
  • sucrose fatty acid ester having a small solidification power as an oil gelling agent in combination
  • a nonionic surfactant together with a silicone-modified polysaccharide compound.
  • the present invention comprises (a) 0.1-35% by mass of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, (b) 1-13% by mass of sucrose fatty acid ester, and (c) a nonionic interface.
  • a vaginal cosmetic comprising 0.1-10% by mass of an activator and (d) 0.1-13% by mass of tri (trimethylsiloxy) silylpropyl carbamate pullulan.
  • the present invention provides a vaginal cosmetic that is highly transparent in the state of a base, imparts an excellent luster and long effect when blended with coloring materials and colored fibers, and has good stability. be able to. Furthermore, the vaginal cosmetic of the present invention can exhibit excellent curling power and high stability by further containing dextrin palmitate.
  • a dextrin (palmitic acid / 2-ethylhexanoic acid) ester which is an oil gelling agent, and a sucrose fatty acid ester having a low solidification power are used in combination to form an oily base containing a silicone-modified polysaccharide compound.
  • transparency and curl effect are sufficient, temperature stability is excellent, and the spread is uniform and the finish is uniform.
  • the gloss of the base is significantly larger than that of the oily type with a high wax content.
  • the dextrin (palmitic acid / 2-ethylhexanoic acid) ester used in the present invention has a lower solidification power than oil (e) dextrin palmitic acid ester.
  • the blending amount of dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1-35% by mass, preferably 1-30% by mass, more preferably 10%, based on the total amount of cosmetics for candy. -25% by weight.
  • the blending amount of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is less than 0.1% by mass, the appearance of the base becomes whitish, resulting in poor transparency and further poor long effect.
  • the said compounding quantity exceeds 35 mass%, it may be inferior to a long effect, or a feeling of vomit and a stability may worsen.
  • sucrose fatty acid ester used in the present invention is a saturated fatty acid having 8 to 18 carbon atoms or an unsaturated fatty acid having 16 to 22 carbon atoms.
  • a compound in which the mass% or more is a polyester body having a diester body or more and the rising melting point is 20 ° C. or less is desirable.
  • Specific examples of such sucrose fatty acid esters include sucrose caprylate, sucrose caprate, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose Examples thereof include sugar oleate and sucrose erucate, and one or more of these can be used. Of these, sucrose oleate and sucrose erucate are particularly preferred.
  • the proportion of the polyester containing the diester is desirably 100% by mass, but is desirably at least 95% by mass, preferably 97% by mass or more.
  • sucrose fatty acid esters include sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.).
  • the amount of sucrose fatty acid ester used in the present invention is 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass.
  • the stability at high temperature (50 ° C.) is deteriorated (too soft), and when it exceeds 13% by mass, the stability at low temperature (0 ° C.) is deteriorated ( Too hard).
  • the (c) nonionic surfactant used in the present invention is preferably a lipophilic nonionic surfactant.
  • KF6017 Shin-Etsu
  • Emalex RWIS a hydrogenated castor oil with triisostearic acid PEG-20 320 (manufactured by Nippon Emulsion Co., Ltd.).
  • polyethylene glycol (10) dimethicone is particularly preferred. By using polyethylene glycol (10) dimethicone, a more transparent gel can be produced.
  • the amount of the (c) nonionic surfactant is 0.1-10% by mass, preferably 0.5-7% by mass, and most preferably 1-5% by mass. .
  • (D) Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan The tri (trimethylsiloxy) silylpropylcarbamic acid pullulan used in the present invention is represented by the following formula (1).
  • PL represents a glucose residue of pullulan.
  • the bonding ratio of the silicone compound to the reactive functional group of pullulan varies depending on the type, but usually the silicone per unit sugar constituting the pullulan.
  • the average number of bonds (substitution degree) of the compound is preferably 0.5 to 3.0.
  • the degree of substitution is calculated from the Si content (% by mass) in the compound.
  • Examples of commercially available pullulan tri (trimethylsiloxy) silylpropylcarbamate include TSPL-30-D5 (manufactured by Shin-Etsu Chemical Co., Ltd., 30 wt% decamethylcyclopentasiloxane solution).
  • a preferred blending amount of tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is 0.1-13% by mass, preferably 0.3-10% by mass, and most preferably 1-7% by mass. .
  • (E) Dextrin palmitate in the present invention, by further including (e) dextrin palmitate, it is excellent in curling effect and further improved in high temperature stability.
  • dextrin palmitate for example, Leo Pearl KL (manufactured by Chiba Flour Milling Co., Ltd.) can be used as a commercial product.
  • the content of dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, more preferably 1-8% by mass, based on the total amount of cosmetics for vaginal use. .
  • the blending amount of dextrin palmitate exceeds 13% by mass, lumps may be formed and the long effect may be impaired.
  • a mascara containing a coloring material / colored fiber if the amount of the component (e) is too small relative to the component (a), the coloring material / fiber may precipitate at a temperature of 45 ° C. or higher.
  • blackness may be impaired, and it may lack fresh luster and smoothness.
  • the vaginal cosmetics of the present invention need general components that can be blended in cosmetics within the qualitative and quantitative ranges that do not impair the intended effects of the present invention. Can be added accordingly. Specifically, for example, powder, resin, oil, drug, emulsifier, thickener, clay mineral, preservative, moisturizer, alcohol, polyhydric alcohol, water-soluble polymer, drug, antioxidant, UV absorber , UV scattering agents, coating agents, fragrances and the like can be blended.
  • the vaginal cosmetic according to the present invention is preferably an oily cosmetic that does not contain water.
  • the vaginal cosmetic of the present invention can be used as a mascara cosmetic by blending color materials such as pigments and colored fibers. Further, when a coloring material such as a pigment or a colored fiber is not blended, it can be used as a highly transparent mascara base cosmetic.
  • These mascara cosmetics and mascara base cosmetics can be prepared according to conventional methods.
  • the average score value is 4.0 or more and 5.0 points or less.
  • the average score value is 3.0 or more and less than 4.0 points.
  • the average score value is 2.0 or more and less than 3.0 points.
  • the average score is 1.0 or more and less than 2.0
  • the mascara cosmetic of Example 1 containing all of the components (a) to (d) has an effect of imparting a glossy black color to the cocoon, a long effect of making the cocoon look long, and a low temperature (0 ° C.) and a high temperature (50 ° C.). ) was excellent in stability.
  • the cosmetic (Comparative Example 1) obtained by removing only the component (a) from the cosmetic of Example 1 exhibited sufficient whiteness even after blending the black fibers because it exhibited the whiteness of the base.
  • the long effect was inferior.
  • the effect of imparting a glossy blackness and the long effect were improved by blending the component (a) in an amount of 1-40% by mass (Example 2-4, Comparative Example 2).
  • the composition of Comparative Example 2 containing 40% by mass was inferior in the long effect.
  • the composition of Comparative Example 2 has a high stability at 0 ° C., and the stability at 50 ° C. is such that some separation is observed after storage for 1 month, so that the stability can be judged to be generally good. . Therefore, in the vaginal cosmetic of the present invention, (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1 to 35% by mass, preferably 1 to 30% by mass, more preferably 10 to 25%. It was shown that the inclusion of the mass% is excellent in the effect of imparting a glossy blackness to the wrinkles and the long effect of making the wrinkles look longer.
  • the cosmetic for salmon of the present invention contains (b) sucrose fatty acid ester in an amount of 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass, and thus has high stability. It was shown that cosmetics can be obtained.
  • the cosmetic (Comparative Example 5) obtained by removing only the component (c) from the cosmetic of Example 1 has a low viscosity due to insufficient gel formation and is inferior in the long effect.
  • the long effect was improved in the cosmetic containing 0.5% by mass (Example 7) and 10% by mass (Example 8) of component (c), but the cosmetic of Comparative Example 6 containing 15% by mass. Inferior results.
  • the cosmetic of Comparative Example 6 also had a sticky feeling and was inferior in usability. Therefore, the vaginal cosmetic of the present invention contains (c) a nonionic surfactant in an amount of 0.1-10% by mass, preferably 5-7% by mass, more preferably 1-15% by mass. It was shown that the effect is excellent.
  • the vaginal cosmetic of the present invention further comprises (e) dextrin palmitate, which is excellent in curling effect and further improved in high temperature stability.
  • cosmetics formulated with 5% by mass (Example 1) and 10% by mass (Example 12) were very excellent in curling power and stability, but were formulated with 15% by mass.
  • the cosmetic of Comparative Example 9 was found to have lumps and was inferior in the effect of imparting gloss and the long effect. Therefore, it is considered that the suitable amount of (e) dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, and more preferably 1-8% by mass.
  • the glossy effect, transparency, or glossy black was excellent in all of the long effect, low temperature / high temperature stability, and curling force.
  • Formulation example Compounding ingredients Compounding amount (% by mass) Dextrin (palmitic acid / 2-ethylhexanoic acid) ester * 1 20 Sucrose fatty acid ester * 2 5 Polyethylene glycol (10) dimethicone * 3 4 Decamethylcyclopentasiloxane 10.5 Trimethylsiloxysilicic acid 5 Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan * 4 4.5 Dextrin palmitate * 5 5 Fragrance Appropriate amount of white fiber 3 Light isoparaffin remaining amount (result) The obtained mascara base cosmetic was evaluated as having a long effect of “ ⁇ ”, a curling power of “ ⁇ ”, a gloss of “ ⁇ ”, a blackness (or transparency) of “ ⁇ ” (whitening), and a stability ( 50 ° C.) was “ ⁇ ”.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne un produit cosmétique pour cils qui présente une transparence élevée lorsqu'il est sous la forme d'une base, qui présente un effet brillant et un effet d'allongement des cils excellents lorsqu'une substance colorante ou des fibres colorées sont mélangées au cosmétique, et qui présente une bonne stabilité. La présente invention concerne un produit cosmétique pour cils dans lequel les substances suivantes sont mélangées : (a) 0,1 à 35 % en masse d'une dextrine (ester d'acide palmitique/d'acide 2-éthylhexanoïque), (b) 1 à 13 % en masse d'un ester d'acide gras de saccharose, (c) 0,1 à 10 % en masse d'un tensio-actif non ionique et (d) 0,1 à 13 % en masse d'un acide tri(triméthylsiloxy)silylpropylcarbamique-pullulan.
PCT/JP2012/057733 2011-03-29 2012-03-26 Produit cosmétique pour cils WO2012133293A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2013507557A JP6113654B2 (ja) 2011-03-29 2012-03-26 睫用化粧料

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-071493 2011-03-29
JP2011071493 2011-03-29

Publications (1)

Publication Number Publication Date
WO2012133293A1 true WO2012133293A1 (fr) 2012-10-04

Family

ID=46931011

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/057733 WO2012133293A1 (fr) 2011-03-29 2012-03-26 Produit cosmétique pour cils

Country Status (3)

Country Link
JP (1) JP6113654B2 (fr)
TW (1) TW201244751A (fr)
WO (1) WO2012133293A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013079211A (ja) * 2011-10-04 2013-05-02 Shiseido Co Ltd 睫毛用化粧料
WO2014181747A1 (fr) * 2013-05-09 2014-11-13 信越化学工業株式会社 Agent épaississant à base d'huile, composition épaississante à base d'huile, et préparation cosmétique
US20170224608A1 (en) * 2014-07-28 2017-08-10 Shiseido Company, Ltd. Oily cosmetic
JP2018530544A (ja) * 2015-09-30 2018-10-18 アモーレパシフィック コーポレーション 透明な液状油分散剤形のアイメイクアップ組成物
WO2021187306A1 (fr) 2020-03-18 2021-09-23 信越化学工業株式会社 Composition cosmétique
WO2023068123A1 (fr) 2021-10-22 2023-04-27 信越化学工業株式会社 Pullulane modifié au silicone, composition comprenant ledit pullulane modifié, et produit cosmétique

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Publication number Priority date Publication date Assignee Title
JP2004244333A (ja) * 2003-02-12 2004-09-02 Noevir Co Ltd 油性化粧料
WO2006022395A1 (fr) * 2004-08-24 2006-03-02 Shiseido Company, Ltd. Préparation cosmétique huileuse
JP2010083843A (ja) * 2008-10-02 2010-04-15 Shiseido Co Ltd マスカラ化粧料
JP2011046656A (ja) * 2009-08-27 2011-03-10 Shiseido Co Ltd マスカラ下地化粧料

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JPS6366107A (ja) * 1986-09-05 1988-03-24 Kanebo Ltd 乳化型化粧料
JP2004131457A (ja) * 2002-10-07 2004-04-30 Takashi Yokota 透明性基剤及びそれを配合した化粧料
JP6169841B2 (ja) * 2012-07-18 2017-07-26 株式会社 資生堂 半固形化粧料
JP6024587B2 (ja) * 2013-05-13 2016-11-16 信越化学工業株式会社 油性化粧料

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004244333A (ja) * 2003-02-12 2004-09-02 Noevir Co Ltd 油性化粧料
WO2006022395A1 (fr) * 2004-08-24 2006-03-02 Shiseido Company, Ltd. Préparation cosmétique huileuse
JP2010083843A (ja) * 2008-10-02 2010-04-15 Shiseido Co Ltd マスカラ化粧料
JP2011046656A (ja) * 2009-08-27 2011-03-10 Shiseido Co Ltd マスカラ下地化粧料

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013079211A (ja) * 2011-10-04 2013-05-02 Shiseido Co Ltd 睫毛用化粧料
WO2014181747A1 (fr) * 2013-05-09 2014-11-13 信越化学工業株式会社 Agent épaississant à base d'huile, composition épaississante à base d'huile, et préparation cosmétique
JP2014218468A (ja) * 2013-05-09 2014-11-20 信越化学工業株式会社 油性増粘剤、増粘油性組成物及び化粧料
CN105209009A (zh) * 2013-05-09 2015-12-30 信越化学工业株式会社 油性增稠剂、增稠油性组合物和化妆料
KR20160005060A (ko) * 2013-05-09 2016-01-13 신에쓰 가가꾸 고교 가부시끼가이샤 유성 증점제, 증점 유성 조성물 및 화장료
US20160113860A1 (en) * 2013-05-09 2016-04-28 Shin-Etsu Chemical Co., Ltd. Oil-based thickening agent, oil-based thickening composition, and cosmetic preparation
KR102234753B1 (ko) 2013-05-09 2021-04-02 신에쓰 가가꾸 고교 가부시끼가이샤 유성 증점제, 증점 유성 조성물 및 화장료
US20170224608A1 (en) * 2014-07-28 2017-08-10 Shiseido Company, Ltd. Oily cosmetic
US10639268B2 (en) * 2014-07-28 2020-05-05 Shiseido Company, Ltd. Oily cosmetic
JP2018530544A (ja) * 2015-09-30 2018-10-18 アモーレパシフィック コーポレーション 透明な液状油分散剤形のアイメイクアップ組成物
WO2021187306A1 (fr) 2020-03-18 2021-09-23 信越化学工業株式会社 Composition cosmétique
WO2023068123A1 (fr) 2021-10-22 2023-04-27 信越化学工業株式会社 Pullulane modifié au silicone, composition comprenant ledit pullulane modifié, et produit cosmétique

Also Published As

Publication number Publication date
TW201244751A (en) 2012-11-16
JP6113654B2 (ja) 2017-04-12
JPWO2012133293A1 (ja) 2014-07-28

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