WO2012133293A1 - Eyelash cosmetic - Google Patents
Eyelash cosmetic Download PDFInfo
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- WO2012133293A1 WO2012133293A1 PCT/JP2012/057733 JP2012057733W WO2012133293A1 WO 2012133293 A1 WO2012133293 A1 WO 2012133293A1 JP 2012057733 W JP2012057733 W JP 2012057733W WO 2012133293 A1 WO2012133293 A1 WO 2012133293A1
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- ester
- dextrin
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
Definitions
- the present invention relates to cosmetics for wrinkles. More specifically, the transparency in the state of the base is high, and when a coloring material or colored fiber is blended, the gloss effect and long effect of wrinkles are excellent, and the stability is good. It relates to cosmetics for vaginal.
- the effects required for cosmetics for eyelashes are the long effect that makes the eyelids look longer, the volume increase effect that makes the eyelids thicker and the eyes clearer, the curl effect that makes the eyeglasses curl and make the eyes look larger, and the coloring that colors the eyelids
- the effect and the persistence of each makeup effect were the main ones.
- Recently, in addition to the conventional makeup effect there is a demand for a fresh gloss effect that gives the impression of being wet.
- vaginal cosmetics In conventional vaginal cosmetics, a large amount of oily wax is blended to impart a solidifying power, and a vaginal cosmetic having a long effect and curling power is produced by blending a silicone-modified polysaccharide compound. Therefore, the base is not transparent but exhibits a base color derived from wax, which tends to inhibit the blackness and glossiness of the mascara, resulting in a matte finish.
- an oily base is known that uses dextrin palmitic acid ester and Benton, which is an organically modified clay mineral, and is thickened with a small amount of water (Patent Document 1). There was a tendency to become creamy and to impair blackness.
- a spinnable composition containing a silicone-modified polysaccharide compound and a lysine derivative-modified silicone has been developed as a highly transparent base that suppresses the whiteness of the base (Patent Document 2).
- the stability of this composition is highly dependent on temperature, and there is a problem with stability at low and high temperatures.
- blended the clay mineral with this base and made it the emulsification type base had the problem that stability was impaired, but transparency was impaired.
- a highly transparent gloss base containing a high-viscosity oil agent and a specific water-soluble polymer is also known (Patent Document 3), but the long effect is insufficient and the fiber gloss is not satisfactory.
- the present invention has a high transparency in the state of a base, and when blended with a coloring material or a colored fiber, it has an excellent gloss and long effect, and has excellent stability.
- the purpose is to provide.
- the present inventors have used a dextrin (palmitic acid / 2-ethylhexanoic acid) ester and a sucrose fatty acid ester having a small solidification power as an oil gelling agent in combination, and a nonionic surfactant together with a silicone-modified polysaccharide compound.
- a dextrin palmitic acid / 2-ethylhexanoic acid
- sucrose fatty acid ester having a small solidification power as an oil gelling agent in combination
- a nonionic surfactant together with a silicone-modified polysaccharide compound.
- the present invention comprises (a) 0.1-35% by mass of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, (b) 1-13% by mass of sucrose fatty acid ester, and (c) a nonionic interface.
- a vaginal cosmetic comprising 0.1-10% by mass of an activator and (d) 0.1-13% by mass of tri (trimethylsiloxy) silylpropyl carbamate pullulan.
- the present invention provides a vaginal cosmetic that is highly transparent in the state of a base, imparts an excellent luster and long effect when blended with coloring materials and colored fibers, and has good stability. be able to. Furthermore, the vaginal cosmetic of the present invention can exhibit excellent curling power and high stability by further containing dextrin palmitate.
- a dextrin (palmitic acid / 2-ethylhexanoic acid) ester which is an oil gelling agent, and a sucrose fatty acid ester having a low solidification power are used in combination to form an oily base containing a silicone-modified polysaccharide compound.
- transparency and curl effect are sufficient, temperature stability is excellent, and the spread is uniform and the finish is uniform.
- the gloss of the base is significantly larger than that of the oily type with a high wax content.
- the dextrin (palmitic acid / 2-ethylhexanoic acid) ester used in the present invention has a lower solidification power than oil (e) dextrin palmitic acid ester.
- the blending amount of dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1-35% by mass, preferably 1-30% by mass, more preferably 10%, based on the total amount of cosmetics for candy. -25% by weight.
- the blending amount of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is less than 0.1% by mass, the appearance of the base becomes whitish, resulting in poor transparency and further poor long effect.
- the said compounding quantity exceeds 35 mass%, it may be inferior to a long effect, or a feeling of vomit and a stability may worsen.
- sucrose fatty acid ester used in the present invention is a saturated fatty acid having 8 to 18 carbon atoms or an unsaturated fatty acid having 16 to 22 carbon atoms.
- a compound in which the mass% or more is a polyester body having a diester body or more and the rising melting point is 20 ° C. or less is desirable.
- Specific examples of such sucrose fatty acid esters include sucrose caprylate, sucrose caprate, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose Examples thereof include sugar oleate and sucrose erucate, and one or more of these can be used. Of these, sucrose oleate and sucrose erucate are particularly preferred.
- the proportion of the polyester containing the diester is desirably 100% by mass, but is desirably at least 95% by mass, preferably 97% by mass or more.
- sucrose fatty acid esters include sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.).
- the amount of sucrose fatty acid ester used in the present invention is 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass.
- the stability at high temperature (50 ° C.) is deteriorated (too soft), and when it exceeds 13% by mass, the stability at low temperature (0 ° C.) is deteriorated ( Too hard).
- the (c) nonionic surfactant used in the present invention is preferably a lipophilic nonionic surfactant.
- KF6017 Shin-Etsu
- Emalex RWIS a hydrogenated castor oil with triisostearic acid PEG-20 320 (manufactured by Nippon Emulsion Co., Ltd.).
- polyethylene glycol (10) dimethicone is particularly preferred. By using polyethylene glycol (10) dimethicone, a more transparent gel can be produced.
- the amount of the (c) nonionic surfactant is 0.1-10% by mass, preferably 0.5-7% by mass, and most preferably 1-5% by mass. .
- (D) Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan The tri (trimethylsiloxy) silylpropylcarbamic acid pullulan used in the present invention is represented by the following formula (1).
- PL represents a glucose residue of pullulan.
- the bonding ratio of the silicone compound to the reactive functional group of pullulan varies depending on the type, but usually the silicone per unit sugar constituting the pullulan.
- the average number of bonds (substitution degree) of the compound is preferably 0.5 to 3.0.
- the degree of substitution is calculated from the Si content (% by mass) in the compound.
- Examples of commercially available pullulan tri (trimethylsiloxy) silylpropylcarbamate include TSPL-30-D5 (manufactured by Shin-Etsu Chemical Co., Ltd., 30 wt% decamethylcyclopentasiloxane solution).
- a preferred blending amount of tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is 0.1-13% by mass, preferably 0.3-10% by mass, and most preferably 1-7% by mass. .
- (E) Dextrin palmitate in the present invention, by further including (e) dextrin palmitate, it is excellent in curling effect and further improved in high temperature stability.
- dextrin palmitate for example, Leo Pearl KL (manufactured by Chiba Flour Milling Co., Ltd.) can be used as a commercial product.
- the content of dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, more preferably 1-8% by mass, based on the total amount of cosmetics for vaginal use. .
- the blending amount of dextrin palmitate exceeds 13% by mass, lumps may be formed and the long effect may be impaired.
- a mascara containing a coloring material / colored fiber if the amount of the component (e) is too small relative to the component (a), the coloring material / fiber may precipitate at a temperature of 45 ° C. or higher.
- blackness may be impaired, and it may lack fresh luster and smoothness.
- the vaginal cosmetics of the present invention need general components that can be blended in cosmetics within the qualitative and quantitative ranges that do not impair the intended effects of the present invention. Can be added accordingly. Specifically, for example, powder, resin, oil, drug, emulsifier, thickener, clay mineral, preservative, moisturizer, alcohol, polyhydric alcohol, water-soluble polymer, drug, antioxidant, UV absorber , UV scattering agents, coating agents, fragrances and the like can be blended.
- the vaginal cosmetic according to the present invention is preferably an oily cosmetic that does not contain water.
- the vaginal cosmetic of the present invention can be used as a mascara cosmetic by blending color materials such as pigments and colored fibers. Further, when a coloring material such as a pigment or a colored fiber is not blended, it can be used as a highly transparent mascara base cosmetic.
- These mascara cosmetics and mascara base cosmetics can be prepared according to conventional methods.
- the average score value is 4.0 or more and 5.0 points or less.
- the average score value is 3.0 or more and less than 4.0 points.
- the average score value is 2.0 or more and less than 3.0 points.
- the average score is 1.0 or more and less than 2.0
- the mascara cosmetic of Example 1 containing all of the components (a) to (d) has an effect of imparting a glossy black color to the cocoon, a long effect of making the cocoon look long, and a low temperature (0 ° C.) and a high temperature (50 ° C.). ) was excellent in stability.
- the cosmetic (Comparative Example 1) obtained by removing only the component (a) from the cosmetic of Example 1 exhibited sufficient whiteness even after blending the black fibers because it exhibited the whiteness of the base.
- the long effect was inferior.
- the effect of imparting a glossy blackness and the long effect were improved by blending the component (a) in an amount of 1-40% by mass (Example 2-4, Comparative Example 2).
- the composition of Comparative Example 2 containing 40% by mass was inferior in the long effect.
- the composition of Comparative Example 2 has a high stability at 0 ° C., and the stability at 50 ° C. is such that some separation is observed after storage for 1 month, so that the stability can be judged to be generally good. . Therefore, in the vaginal cosmetic of the present invention, (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1 to 35% by mass, preferably 1 to 30% by mass, more preferably 10 to 25%. It was shown that the inclusion of the mass% is excellent in the effect of imparting a glossy blackness to the wrinkles and the long effect of making the wrinkles look longer.
- the cosmetic for salmon of the present invention contains (b) sucrose fatty acid ester in an amount of 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass, and thus has high stability. It was shown that cosmetics can be obtained.
- the cosmetic (Comparative Example 5) obtained by removing only the component (c) from the cosmetic of Example 1 has a low viscosity due to insufficient gel formation and is inferior in the long effect.
- the long effect was improved in the cosmetic containing 0.5% by mass (Example 7) and 10% by mass (Example 8) of component (c), but the cosmetic of Comparative Example 6 containing 15% by mass. Inferior results.
- the cosmetic of Comparative Example 6 also had a sticky feeling and was inferior in usability. Therefore, the vaginal cosmetic of the present invention contains (c) a nonionic surfactant in an amount of 0.1-10% by mass, preferably 5-7% by mass, more preferably 1-15% by mass. It was shown that the effect is excellent.
- the vaginal cosmetic of the present invention further comprises (e) dextrin palmitate, which is excellent in curling effect and further improved in high temperature stability.
- cosmetics formulated with 5% by mass (Example 1) and 10% by mass (Example 12) were very excellent in curling power and stability, but were formulated with 15% by mass.
- the cosmetic of Comparative Example 9 was found to have lumps and was inferior in the effect of imparting gloss and the long effect. Therefore, it is considered that the suitable amount of (e) dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, and more preferably 1-8% by mass.
- the glossy effect, transparency, or glossy black was excellent in all of the long effect, low temperature / high temperature stability, and curling force.
- Formulation example Compounding ingredients Compounding amount (% by mass) Dextrin (palmitic acid / 2-ethylhexanoic acid) ester * 1 20 Sucrose fatty acid ester * 2 5 Polyethylene glycol (10) dimethicone * 3 4 Decamethylcyclopentasiloxane 10.5 Trimethylsiloxysilicic acid 5 Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan * 4 4.5 Dextrin palmitate * 5 5 Fragrance Appropriate amount of white fiber 3 Light isoparaffin remaining amount (result) The obtained mascara base cosmetic was evaluated as having a long effect of “ ⁇ ”, a curling power of “ ⁇ ”, a gloss of “ ⁇ ”, a blackness (or transparency) of “ ⁇ ” (whitening), and a stability ( 50 ° C.) was “ ⁇ ”.
Abstract
[Problem] To provide an eyelash cosmetic which has high transparency when in the form of a base, which exhibits an excellent eyelash gloss effect and lengthening effect when a coloring material or colored fibers are blended in the cosmetic, and which has good stability. [Solution] An eyelash cosmetic in which the following are combined: (a) 0.1 to 35 mass % of a dextrin (palmitic acid/2-ethylhexanoic acid) ester, (b) 1 to 13 mass % of a sucrose fatty acid ester, (c) 0.1 to 10 mass % of a non-ionic surfactant and (d) 0.1 to 13 mass % of tri(trimethylsiloxy)silylpropylcarbamic acid-pullulan.
Description
本出願は、２０１１年３月２９日付け出願の日本国特許出願２０１１－７１４９３号の優先権を主張しており、ここに折り込まれるものである。
This application claims the priority of Japanese Patent Application No. 2011-71493 filed on March 29, 2011, and is incorporated herein.
本発明は睫用化粧料に関し、さらに詳しくは、基剤の状態での透明性が高く、色材や着色繊維を配合した際には睫のツヤ効果およびロング効果に優れ、安定性が良好な睫用化粧料に関する。
The present invention relates to cosmetics for wrinkles. More specifically, the transparency in the state of the base is high, and when a coloring material or colored fiber is blended, the gloss effect and long effect of wrinkles are excellent, and the stability is good. It relates to cosmetics for vaginal.
従来、睫用化粧料に求められる効果は、睫を長く見せるロング効果、睫を太くして目元をはっきりさせるボリュームアップ効果、睫をカールさせて目を大きく見せるカール効果、睫に彩りを与える着色効果と、各々の化粧効果の持続性が主たるものであった。
これに対し、最近は前記従来の化粧効果に加えて、水に濡れているような印象を与えるみずみずしいツヤ効果が求められている。しかしながら、みずみずしいツヤ効果のある睫用化粧料とするには、まず、基剤の白目立ちを抑えた透明性の高い基剤を開発する必要がある。
従来の睫用化粧料では、油性のワックスを多量に配合して固化力を付与すると共に、シリコーン化多糖化合物を配合によってロング効果やカール力のある睫用化粧料を作製していた。そのため、基剤は透明でなくワックスに由来する基剤色を呈することなり、マスカラの黒さとツヤ感が阻害され、仕上がりがマットになる傾向があった。また、デキストリンパルミチン酸エステルと有機変性粘土鉱物であるベントンを併用し、少量の水で増粘させた油性基剤も知られているが（特許文献１）、ベントン由来の基剤色のためにクリーム色となり、黒さを損なう傾向があった。
そこで、基剤の白目立ちを抑えた透明性の高い基剤として、シリコーン化多糖化合物とリジン誘導体変性シリコーンとを含む曳糸性組成物が開発されている（特許文献２）。しかしながら、この組成物の安定性は温度に大きく依存性しており、低温や高温での安定性に問題があった。そして、この基剤に粘土鉱物を配合して乳化系基剤としたものでは、安定性は改善されるが透明性が損なわれるという問題があった。
また、高粘度油剤と特定の水溶性高分子を含む透明性の高いツヤ基剤も知られているが（特許文献３）、ロング効果が不十分で繊維のツキも満足できるものではなかった。 Conventionally, the effects required for cosmetics for eyelashes are the long effect that makes the eyelids look longer, the volume increase effect that makes the eyelids thicker and the eyes clearer, the curl effect that makes the eyeglasses curl and make the eyes look larger, and the coloring that colors the eyelids The effect and the persistence of each makeup effect were the main ones.
On the other hand, recently, in addition to the conventional makeup effect, there is a demand for a fresh gloss effect that gives the impression of being wet. However, in order to make a vaginal cosmetic with a fresh gloss effect, it is first necessary to develop a highly transparent base that suppresses the whiteness of the base.
In conventional vaginal cosmetics, a large amount of oily wax is blended to impart a solidifying power, and a vaginal cosmetic having a long effect and curling power is produced by blending a silicone-modified polysaccharide compound. Therefore, the base is not transparent but exhibits a base color derived from wax, which tends to inhibit the blackness and glossiness of the mascara, resulting in a matte finish. In addition, although an oily base is known that uses dextrin palmitic acid ester and Benton, which is an organically modified clay mineral, and is thickened with a small amount of water (Patent Document 1). There was a tendency to become creamy and to impair blackness.
Therefore, a spinnable composition containing a silicone-modified polysaccharide compound and a lysine derivative-modified silicone has been developed as a highly transparent base that suppresses the whiteness of the base (Patent Document 2). However, the stability of this composition is highly dependent on temperature, and there is a problem with stability at low and high temperatures. And what mix | blended the clay mineral with this base and made it the emulsification type base had the problem that stability was impaired, but transparency was impaired.
Further, a highly transparent gloss base containing a high-viscosity oil agent and a specific water-soluble polymer is also known (Patent Document 3), but the long effect is insufficient and the fiber gloss is not satisfactory.
これに対し、最近は前記従来の化粧効果に加えて、水に濡れているような印象を与えるみずみずしいツヤ効果が求められている。しかしながら、みずみずしいツヤ効果のある睫用化粧料とするには、まず、基剤の白目立ちを抑えた透明性の高い基剤を開発する必要がある。
従来の睫用化粧料では、油性のワックスを多量に配合して固化力を付与すると共に、シリコーン化多糖化合物を配合によってロング効果やカール力のある睫用化粧料を作製していた。そのため、基剤は透明でなくワックスに由来する基剤色を呈することなり、マスカラの黒さとツヤ感が阻害され、仕上がりがマットになる傾向があった。また、デキストリンパルミチン酸エステルと有機変性粘土鉱物であるベントンを併用し、少量の水で増粘させた油性基剤も知られているが（特許文献１）、ベントン由来の基剤色のためにクリーム色となり、黒さを損なう傾向があった。
そこで、基剤の白目立ちを抑えた透明性の高い基剤として、シリコーン化多糖化合物とリジン誘導体変性シリコーンとを含む曳糸性組成物が開発されている（特許文献２）。しかしながら、この組成物の安定性は温度に大きく依存性しており、低温や高温での安定性に問題があった。そして、この基剤に粘土鉱物を配合して乳化系基剤としたものでは、安定性は改善されるが透明性が損なわれるという問題があった。
また、高粘度油剤と特定の水溶性高分子を含む透明性の高いツヤ基剤も知られているが（特許文献３）、ロング効果が不十分で繊維のツキも満足できるものではなかった。 Conventionally, the effects required for cosmetics for eyelashes are the long effect that makes the eyelids look longer, the volume increase effect that makes the eyelids thicker and the eyes clearer, the curl effect that makes the eyeglasses curl and make the eyes look larger, and the coloring that colors the eyelids The effect and the persistence of each makeup effect were the main ones.
On the other hand, recently, in addition to the conventional makeup effect, there is a demand for a fresh gloss effect that gives the impression of being wet. However, in order to make a vaginal cosmetic with a fresh gloss effect, it is first necessary to develop a highly transparent base that suppresses the whiteness of the base.
In conventional vaginal cosmetics, a large amount of oily wax is blended to impart a solidifying power, and a vaginal cosmetic having a long effect and curling power is produced by blending a silicone-modified polysaccharide compound. Therefore, the base is not transparent but exhibits a base color derived from wax, which tends to inhibit the blackness and glossiness of the mascara, resulting in a matte finish. In addition, although an oily base is known that uses dextrin palmitic acid ester and Benton, which is an organically modified clay mineral, and is thickened with a small amount of water (Patent Document 1). There was a tendency to become creamy and to impair blackness.
Therefore, a spinnable composition containing a silicone-modified polysaccharide compound and a lysine derivative-modified silicone has been developed as a highly transparent base that suppresses the whiteness of the base (Patent Document 2). However, the stability of this composition is highly dependent on temperature, and there is a problem with stability at low and high temperatures. And what mix | blended the clay mineral with this base and made it the emulsification type base had the problem that stability was impaired, but transparency was impaired.
Further, a highly transparent gloss base containing a high-viscosity oil agent and a specific water-soluble polymer is also known (Patent Document 3), but the long effect is insufficient and the fiber gloss is not satisfactory.
本発明は、上記事情に鑑み、基剤の状態での透明性が高く、色材や着色繊維を配合した際には睫のツヤ効果およびロング効果に優れ、安定性も良好な睫用化粧料を提供することを目的とする。
In view of the above circumstances, the present invention has a high transparency in the state of a base, and when blended with a coloring material or a colored fiber, it has an excellent gloss and long effect, and has excellent stability. The purpose is to provide.
本発明者らは、油ゲル化剤としてデキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと固化力の小さいショ糖脂肪酸エステルを併用し、シリコーン化多糖化合物とともに非イオン性界面活性剤を用いて油性基剤とすることで、これまでになく透明で、色材や着色繊維配合後には優れたツヤ効果およびロング効果を発現し、安定性も良好で、のびもよく均一な仕上がりとなる睫用化粧料が得られることを見出し、本発明に至った。
The present inventors have used a dextrin (palmitic acid / 2-ethylhexanoic acid) ester and a sucrose fatty acid ester having a small solidification power as an oil gelling agent in combination, and a nonionic surfactant together with a silicone-modified polysaccharide compound. By using an oily base, it is more transparent than ever before, and after blending with coloring materials and colored fibers, it exhibits excellent luster and long effects, has good stability, spreads well and has a uniform finish The inventors have found that a cosmetic can be obtained and have reached the present invention.
本発明は、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルを０．１－３５質量％と、（ｂ）ショ糖脂肪酸エステルを１－１３質量％と、（ｃ）非イオン界面活性剤を０．１－１０質量％と、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランを０．１－１３質量％と、を含有することを特徴とする睫用化粧料である。
The present invention comprises (a) 0.1-35% by mass of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, (b) 1-13% by mass of sucrose fatty acid ester, and (c) a nonionic interface. A vaginal cosmetic comprising 0.1-10% by mass of an activator and (d) 0.1-13% by mass of tri (trimethylsiloxy) silylpropyl carbamate pullulan.
本発明により、基剤の状態での透明性が高く、色材や着色繊維を配合した際には睫に優れたツヤとロング効果を付与し、安定性も良好な睫用化粧料を提供することができる。さらに、本発明の睫用化粧料は、デキストリンパルミチン酸エステルをさらに含むことで、優れたカール力と高い安定性を発現することができる。
The present invention provides a vaginal cosmetic that is highly transparent in the state of a base, imparts an excellent luster and long effect when blended with coloring materials and colored fibers, and has good stability. be able to. Furthermore, the vaginal cosmetic of the present invention can exhibit excellent curling power and high stability by further containing dextrin palmitate.
以下に、本発明の実施の形態について説明するが、本発明はこれらに限定されるものではない。
本発明においては、油ゲル化剤であるデキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと固化力の小さいショ糖脂肪酸エステルを併用し、シリコーン化多糖化合物を配合した油性基剤とすることで、透明性、カール効果も十分で温度安定性に優れ、かつのびもよく均一な仕上がりとなる。また基剤のツヤもワックス高配合の油性タイプのものと比較して有意に大きくなる。
その基剤にファイバーを配合したときは、まつ毛一本一本が均一に仕上がり、すらりと細く長いまつ毛に仕上がるマスカラを実現することができる。 Embodiments of the present invention will be described below, but the present invention is not limited to these.
In the present invention, a dextrin (palmitic acid / 2-ethylhexanoic acid) ester, which is an oil gelling agent, and a sucrose fatty acid ester having a low solidification power are used in combination to form an oily base containing a silicone-modified polysaccharide compound. Also, transparency and curl effect are sufficient, temperature stability is excellent, and the spread is uniform and the finish is uniform. Also, the gloss of the base is significantly larger than that of the oily type with a high wax content.
When fibers are blended in the base, each eyelash is finished evenly, and a mascara that can be finished into slender, thin, long eyelashes can be realized.
本発明においては、油ゲル化剤であるデキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと固化力の小さいショ糖脂肪酸エステルを併用し、シリコーン化多糖化合物を配合した油性基剤とすることで、透明性、カール効果も十分で温度安定性に優れ、かつのびもよく均一な仕上がりとなる。また基剤のツヤもワックス高配合の油性タイプのものと比較して有意に大きくなる。
その基剤にファイバーを配合したときは、まつ毛一本一本が均一に仕上がり、すらりと細く長いまつ毛に仕上がるマスカラを実現することができる。 Embodiments of the present invention will be described below, but the present invention is not limited to these.
In the present invention, a dextrin (palmitic acid / 2-ethylhexanoic acid) ester, which is an oil gelling agent, and a sucrose fatty acid ester having a low solidification power are used in combination to form an oily base containing a silicone-modified polysaccharide compound. Also, transparency and curl effect are sufficient, temperature stability is excellent, and the spread is uniform and the finish is uniform. Also, the gloss of the base is significantly larger than that of the oily type with a high wax content.
When fibers are blended in the base, each eyelash is finished evenly, and a mascara that can be finished into slender, thin, long eyelashes can be realized.
（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステル
本発明に用いられるデキストリン（パルミチン酸／２－エチルヘキサン酸）エステルは、油分の固化力は（ｅ）デキストリンパルミチン酸エステルよりも低いが、（ｂ）ショ糖脂肪酸エステルと組み合わせることで、透明でロング効果に優れる睫用化粧料を作製することができる。（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの市販品としては、例えばレオパール ＴＴ（千葉製粉株式会社製）を用いることが出来る。 (A) Dextrin (palmitic acid / 2-ethylhexanoic acid) ester The dextrin (palmitic acid / 2-ethylhexanoic acid) ester used in the present invention has a lower solidification power than oil (e) dextrin palmitic acid ester. (B) By combining with a sucrose fatty acid ester, it is possible to produce a vaginal cosmetic that is transparent and has an excellent long effect. (A) As a commercially available product of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, for example, Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.) can be used.
本発明に用いられるデキストリン（パルミチン酸／２－エチルヘキサン酸）エステルは、油分の固化力は（ｅ）デキストリンパルミチン酸エステルよりも低いが、（ｂ）ショ糖脂肪酸エステルと組み合わせることで、透明でロング効果に優れる睫用化粧料を作製することができる。（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの市販品としては、例えばレオパール ＴＴ（千葉製粉株式会社製）を用いることが出来る。 (A) Dextrin (palmitic acid / 2-ethylhexanoic acid) ester The dextrin (palmitic acid / 2-ethylhexanoic acid) ester used in the present invention has a lower solidification power than oil (e) dextrin palmitic acid ester. (B) By combining with a sucrose fatty acid ester, it is possible to produce a vaginal cosmetic that is transparent and has an excellent long effect. (A) As a commercially available product of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, for example, Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.) can be used.
（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの配合量は、睫用化粧料全量の０．１－３５質量％であり、好ましくは１－３０質量％であり、より好ましくは１０－２５質量％である。（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの配合量が０．１質量％未満では、基剤外観が白っぽくなるので透明性に劣り、さらにロング効果にも劣る。また、当該配合量が３５質量％を越えた場合にも、ロング効果に劣ったり、ボソボソ感が出て安定性が悪くなることがある。
デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの市販品としては、例えば、レオパールＴＴ（千葉製粉株式会社製）が挙げられる。 (A) The blending amount of dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1-35% by mass, preferably 1-30% by mass, more preferably 10%, based on the total amount of cosmetics for candy. -25% by weight. When the blending amount of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is less than 0.1% by mass, the appearance of the base becomes whitish, resulting in poor transparency and further poor long effect. Moreover, when the said compounding quantity exceeds 35 mass%, it may be inferior to a long effect, or a feeling of vomit and a stability may worsen.
As a commercially available product of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, for example, Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.) can be mentioned.
デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルの市販品としては、例えば、レオパールＴＴ（千葉製粉株式会社製）が挙げられる。 (A) The blending amount of dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1-35% by mass, preferably 1-30% by mass, more preferably 10%, based on the total amount of cosmetics for candy. -25% by weight. When the blending amount of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is less than 0.1% by mass, the appearance of the base becomes whitish, resulting in poor transparency and further poor long effect. Moreover, when the said compounding quantity exceeds 35 mass%, it may be inferior to a long effect, or a feeling of vomit and a stability may worsen.
As a commercially available product of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, for example, Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.) can be mentioned.
（ｂ）ショ糖脂肪酸エステル
本発明に用いられるショ糖脂肪酸エステルは、構成脂肪酸の少なくとも５０質量％以上が炭素数８～１８の飽和脂肪酸又は炭素数１６～２２の不飽和脂肪酸であり、その９５質量％以上がジエステル体以上のポリエステル体であり、かつ上昇融点が２０℃以下である化合物が望ましい。このようなショ糖脂肪酸エステルの具体例としては、ショ糖カプリル酸エステル、ショ糖カプリン酸エステル、ショ糖ラウリン酸エステル、ショ糖ミリスチン酸エステル、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ショ糖オレイン酸エステル、ショ糖エルカ酸エステルを挙げることができ、これらの１種または２種以上を用いることができる。これらのうち特に好ましいのは、ショ糖オレイン酸エステルおよびショ糖エルカ酸エステルである。ジエステルを含むポリエステルの割合については、１００質量％であることが望ましいが、少なくとも９５質量％以上、好ましくは９７質量％以上であることが望ましい。
ショ糖脂肪酸エステルの市販品としては、例えば、シュガーワックスＡ－１０Ｅ（第一工業製薬株式会社製）が挙げられる。 (B) Sucrose fatty acid ester The sucrose fatty acid ester used in the present invention is a saturated fatty acid having 8 to 18 carbon atoms or an unsaturated fatty acid having 16 to 22 carbon atoms. A compound in which the mass% or more is a polyester body having a diester body or more and the rising melting point is 20 ° C. or less is desirable. Specific examples of such sucrose fatty acid esters include sucrose caprylate, sucrose caprate, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose Examples thereof include sugar oleate and sucrose erucate, and one or more of these can be used. Of these, sucrose oleate and sucrose erucate are particularly preferred. The proportion of the polyester containing the diester is desirably 100% by mass, but is desirably at least 95% by mass, preferably 97% by mass or more.
Examples of commercially available sucrose fatty acid esters include sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.).
本発明に用いられるショ糖脂肪酸エステルは、構成脂肪酸の少なくとも５０質量％以上が炭素数８～１８の飽和脂肪酸又は炭素数１６～２２の不飽和脂肪酸であり、その９５質量％以上がジエステル体以上のポリエステル体であり、かつ上昇融点が２０℃以下である化合物が望ましい。このようなショ糖脂肪酸エステルの具体例としては、ショ糖カプリル酸エステル、ショ糖カプリン酸エステル、ショ糖ラウリン酸エステル、ショ糖ミリスチン酸エステル、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ショ糖オレイン酸エステル、ショ糖エルカ酸エステルを挙げることができ、これらの１種または２種以上を用いることができる。これらのうち特に好ましいのは、ショ糖オレイン酸エステルおよびショ糖エルカ酸エステルである。ジエステルを含むポリエステルの割合については、１００質量％であることが望ましいが、少なくとも９５質量％以上、好ましくは９７質量％以上であることが望ましい。
ショ糖脂肪酸エステルの市販品としては、例えば、シュガーワックスＡ－１０Ｅ（第一工業製薬株式会社製）が挙げられる。 (B) Sucrose fatty acid ester The sucrose fatty acid ester used in the present invention is a saturated fatty acid having 8 to 18 carbon atoms or an unsaturated fatty acid having 16 to 22 carbon atoms. A compound in which the mass% or more is a polyester body having a diester body or more and the rising melting point is 20 ° C. or less is desirable. Specific examples of such sucrose fatty acid esters include sucrose caprylate, sucrose caprate, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose Examples thereof include sugar oleate and sucrose erucate, and one or more of these can be used. Of these, sucrose oleate and sucrose erucate are particularly preferred. The proportion of the polyester containing the diester is desirably 100% by mass, but is desirably at least 95% by mass, preferably 97% by mass or more.
Examples of commercially available sucrose fatty acid esters include sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.).
本発明に用いられるショ糖脂肪酸エステルの配合量は、１－１３質量％であり、好ましくは１－１０質量％であり、より好ましくは３－８質量％である。ショ糖脂肪酸エステルの配合量が１質量％未満では高温（５０℃）での安定性が悪くなり（柔らかくなりすぎ）、１３質量％を超えると低温（０℃）での安定性が悪くなる（硬くなりすぎる）。
The amount of sucrose fatty acid ester used in the present invention is 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass. When the blending amount of sucrose fatty acid ester is less than 1% by mass, the stability at high temperature (50 ° C.) is deteriorated (too soft), and when it exceeds 13% by mass, the stability at low temperature (0 ° C.) is deteriorated ( Too hard).
（ｃ）非イオン界面活性剤
本発明で用いられる（ｃ）非イオン界面活性剤としては、親油性非イオン界面活性剤が好ましく、例えば市販品として、ポリエチレングリコール（１０）ジメチコンであるＫＦ６０１７（信越化学工業社製）、トリイソステアリン酸ＰＥＧ－２０水添ヒマシ油であるエマレックスＲＷＩＳ
３２０（日本エマルジョン社製）が挙げられる。このうち特に、ポリエチレングリコール（１０）ジメチコンが好ましい。ポリエチレングリコール（１０）ジメチコンを用いることで、より透明性の高いゲルをつくることができる。 (C) Nonionic surfactant The (c) nonionic surfactant used in the present invention is preferably a lipophilic nonionic surfactant. For example, as a commercial product, KF6017 (Shin-Etsu) which is polyethylene glycol (10) dimethicone. Emalex RWIS, a hydrogenated castor oil with triisostearic acid PEG-20
320 (manufactured by Nippon Emulsion Co., Ltd.). Of these, polyethylene glycol (10) dimethicone is particularly preferred. By using polyethylene glycol (10) dimethicone, a more transparent gel can be produced.
本発明で用いられる（ｃ）非イオン界面活性剤としては、親油性非イオン界面活性剤が好ましく、例えば市販品として、ポリエチレングリコール（１０）ジメチコンであるＫＦ６０１７（信越化学工業社製）、トリイソステアリン酸ＰＥＧ－２０水添ヒマシ油であるエマレックスＲＷＩＳ
３２０（日本エマルジョン社製）が挙げられる。このうち特に、ポリエチレングリコール（１０）ジメチコンが好ましい。ポリエチレングリコール（１０）ジメチコンを用いることで、より透明性の高いゲルをつくることができる。 (C) Nonionic surfactant The (c) nonionic surfactant used in the present invention is preferably a lipophilic nonionic surfactant. For example, as a commercial product, KF6017 (Shin-Etsu) which is polyethylene glycol (10) dimethicone. Emalex RWIS, a hydrogenated castor oil with triisostearic acid PEG-20
320 (manufactured by Nippon Emulsion Co., Ltd.). Of these, polyethylene glycol (10) dimethicone is particularly preferred. By using polyethylene glycol (10) dimethicone, a more transparent gel can be produced.
本発明において、上記（ｃ）非イオン界面活性剤の配合量は、０．１－１０質量％であり、好ましくは０．５－７質量％であり、最も好ましくは１－５質量％である。（ｃ）非イオン界面活性剤の配合量が０．１質量％未満ではゲルの形成が不十分となるため当該化粧料の粘性が不足し、１０質量％を越えるとマスカラとして塗布した後にべたつきを生じる場合があるからである。
In the present invention, the amount of the (c) nonionic surfactant is 0.1-10% by mass, preferably 0.5-7% by mass, and most preferably 1-5% by mass. . (C) If the blending amount of the nonionic surfactant is less than 0.1% by mass, gel formation becomes insufficient, so that the viscosity of the cosmetic is insufficient, and if it exceeds 10% by mass, it becomes sticky after being applied as a mascara. This is because it may occur.
（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルラン
本発明において用いられるトリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランは下記式（１）で示されるものである。なお、式（１）中、ＰＬはプルランのグルコース残基を表す。 (D) Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan The tri (trimethylsiloxy) silylpropylcarbamic acid pullulan used in the present invention is represented by the following formula (1). In formula (1), PL represents a glucose residue of pullulan.
本発明において用いられるトリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランは下記式（１）で示されるものである。なお、式（１）中、ＰＬはプルランのグルコース残基を表す。 (D) Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan The tri (trimethylsiloxy) silylpropylcarbamic acid pullulan used in the present invention is represented by the following formula (1). In formula (1), PL represents a glucose residue of pullulan.
なお、本発明の（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランにおいて、プルランの反応性官能基に対するシリコーン化合物の結合割合はその種類によって異なるが、通常、プルランの構成糖１単位当たりのシリコーン化合物の平均結合数（置換度）が０．５～３．０であることが好適である。なお、本発明において置換度は化合物中のＳｉ含有量（質量％）から換算したものである。
なお、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの配合の際には、低分子量シリコーン油や軽質イソパラフィンに溶解して配合すると、配合のし易さや使用感等を高めることができる。 In addition, in the (d) pullulan tri (trimethylsiloxy) silylpropylcarbamate according to the present invention, the bonding ratio of the silicone compound to the reactive functional group of pullulan varies depending on the type, but usually the silicone per unit sugar constituting the pullulan. The average number of bonds (substitution degree) of the compound is preferably 0.5 to 3.0. In the present invention, the degree of substitution is calculated from the Si content (% by mass) in the compound.
In addition, when blending (d) tri (trimethylsiloxy) silylpropylcarbamic acid pullulan, blending by dissolving in low molecular weight silicone oil or light isoparaffin can enhance blending ease and usability.
なお、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの配合の際には、低分子量シリコーン油や軽質イソパラフィンに溶解して配合すると、配合のし易さや使用感等を高めることができる。 In addition, in the (d) pullulan tri (trimethylsiloxy) silylpropylcarbamate according to the present invention, the bonding ratio of the silicone compound to the reactive functional group of pullulan varies depending on the type, but usually the silicone per unit sugar constituting the pullulan. The average number of bonds (substitution degree) of the compound is preferably 0.5 to 3.0. In the present invention, the degree of substitution is calculated from the Si content (% by mass) in the compound.
In addition, when blending (d) tri (trimethylsiloxy) silylpropylcarbamic acid pullulan, blending by dissolving in low molecular weight silicone oil or light isoparaffin can enhance blending ease and usability.
（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの市販品としては、例えばＴＳＰＬ－３０－Ｄ５（信越化学工業社製、３０ｗｔ％デカメチルシクロペンタシロキサン溶液）が挙げられる。
(D) Examples of commercially available pullulan tri (trimethylsiloxy) silylpropylcarbamate include TSPL-30-D5 (manufactured by Shin-Etsu Chemical Co., Ltd., 30 wt% decamethylcyclopentasiloxane solution).
（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの好ましい配合量は０．１－１３質量％であり、好ましくは０．３－１０質量％であり、最も好ましくは１－７質量％である。（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの配合量が０．１質量％より少ないと、睫へのツキが悪くなる。また、当該配合量が１３質量％より多いと、曳糸性が強すぎて操作性が悪くなるうえにペタペタとした質感が強くなり、乾きの遅さや二次付着などが生じる場合がある。
(D) A preferred blending amount of tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is 0.1-13% by mass, preferably 0.3-10% by mass, and most preferably 1-7% by mass. . (D) If the blending amount of tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is less than 0.1% by mass, the tackiness of the wrinkles becomes worse. On the other hand, when the blending amount is more than 13% by mass, the spinnability is too strong and the operability is deteriorated, and the texture of the peta-peta becomes strong, which may cause slow drying and secondary adhesion.
（ｅ）デキストリンパルミチン酸エステル
本発明においては、（ｅ）デキストリンパルミチン酸エステルをさらに含むことで、カール効果に優れ、さらに高温安定性の向上が期待される。
（ｅ）デキストリンパルミチン酸エステルは、例えば市販品として、レオパール ＫＬ（千葉製粉株式会社製）を用いることが出来る。 (E) Dextrin palmitate In the present invention, by further including (e) dextrin palmitate, it is excellent in curling effect and further improved in high temperature stability.
(E) As dextrin palmitate, for example, Leo Pearl KL (manufactured by Chiba Flour Milling Co., Ltd.) can be used as a commercial product.
本発明においては、（ｅ）デキストリンパルミチン酸エステルをさらに含むことで、カール効果に優れ、さらに高温安定性の向上が期待される。
（ｅ）デキストリンパルミチン酸エステルは、例えば市販品として、レオパール ＫＬ（千葉製粉株式会社製）を用いることが出来る。 (E) Dextrin palmitate In the present invention, by further including (e) dextrin palmitate, it is excellent in curling effect and further improved in high temperature stability.
(E) As dextrin palmitate, for example, Leo Pearl KL (manufactured by Chiba Flour Milling Co., Ltd.) can be used as a commercial product.
（ｅ）デキストリンパルミチン酸エステルの含有量は、睫用化粧料全量の０．１－１３質量％であり、好ましくは０．１－１０質量％であり、より好ましくは１－８質量％である。（ｅ）デキストリンパルミチン酸エステルの配合量が１３質量％を越えるとダマができるようになり、ロング効果が損なわれる場合がある。
(E) The content of dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, more preferably 1-8% by mass, based on the total amount of cosmetics for vaginal use. . (E) When the blending amount of dextrin palmitate exceeds 13% by mass, lumps may be formed and the long effect may be impaired.
成分（ｅ）の配合による前記効果を得るためには、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと（ｅ）デキストリンパルミチン酸エステルの配合割合は、（ａ）：（ｅ）＝１：０．１～１：１（質量比）であることが好ましい。色材・着色繊維を配合したマスカラにおいて、成分（ａ）に対して成分（ｅ）が少なすぎると、４５℃以上の温度下で当該色材・繊維が沈殿する場合があり、また、成分（ａ）成分に対して成分（ｅ）が多すぎると、黒さが損なわれたり、みずみずしいツヤやなめらかさに欠く場合がある。
In order to obtain the above-described effect by the blending of component (e), the blending ratio of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester and (e) dextrin palmitic acid ester is: (a): (e) = 1: 0.1 to 1: 1 (mass ratio) is preferable. In a mascara containing a coloring material / colored fiber, if the amount of the component (e) is too small relative to the component (a), the coloring material / fiber may precipitate at a temperature of 45 ° C. or higher. When there are too many components (e) with respect to a) component, blackness may be impaired, and it may lack fresh luster and smoothness.
本発明の睫用化粧料においては、上記必須成分の他に、本発明の所期の効果を損なわない質的・量的範囲内で、化粧料に配合され得る一般的な成分を、必要に応じて添加することができる。具体的には、例えば、粉末や樹脂や油分、薬剤、乳化剤、増粘剤、粘土鉱物、防腐剤、保湿剤、アルコール、多価アルコール、水溶性高分子、薬剤、酸化防止剤、紫外線吸収剤、紫外線散乱剤、皮膜剤、香料等を配合することができる。
なお、本発明による睫用化粧料は、水を含まない油性化粧料であることが好ましい。 In addition to the above essential components, the vaginal cosmetics of the present invention need general components that can be blended in cosmetics within the qualitative and quantitative ranges that do not impair the intended effects of the present invention. Can be added accordingly. Specifically, for example, powder, resin, oil, drug, emulsifier, thickener, clay mineral, preservative, moisturizer, alcohol, polyhydric alcohol, water-soluble polymer, drug, antioxidant, UV absorber , UV scattering agents, coating agents, fragrances and the like can be blended.
The vaginal cosmetic according to the present invention is preferably an oily cosmetic that does not contain water.
なお、本発明による睫用化粧料は、水を含まない油性化粧料であることが好ましい。 In addition to the above essential components, the vaginal cosmetics of the present invention need general components that can be blended in cosmetics within the qualitative and quantitative ranges that do not impair the intended effects of the present invention. Can be added accordingly. Specifically, for example, powder, resin, oil, drug, emulsifier, thickener, clay mineral, preservative, moisturizer, alcohol, polyhydric alcohol, water-soluble polymer, drug, antioxidant, UV absorber , UV scattering agents, coating agents, fragrances and the like can be blended.
The vaginal cosmetic according to the present invention is preferably an oily cosmetic that does not contain water.
本発明の睫用化粧料は、顔料などの色材や着色繊維を配合してマスカラ化粧料として用いることができる。また、顔料などの色材や着色繊維を配合しない場合には、透明性の高いマスカラ下地化粧料として用いることができる。これらのマスカラ化粧料及びマスカラ下地化粧料は、常法に従って作製することができる。
The vaginal cosmetic of the present invention can be used as a mascara cosmetic by blending color materials such as pigments and colored fibers. Further, when a coloring material such as a pigment or a colored fiber is not blended, it can be used as a highly transparent mascara base cosmetic. These mascara cosmetics and mascara base cosmetics can be prepared according to conventional methods.
以下、実施例を挙げて本発明をさらに詳しく説明するが、本発明はこれらの実施例により限定されるものではない。なお、配合量については特に断りのない限り質量％を示す。
実施例の説明に先立ち、本発明で用いた試験方法について説明する。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in more detail, this invention is not limited by these Examples. In addition, unless otherwise indicated about a compounding quantity, the mass% is shown.
Prior to the description of the examples, the test method used in the present invention will be described.
実施例の説明に先立ち、本発明で用いた試験方法について説明する。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in more detail, this invention is not limited by these Examples. In addition, unless otherwise indicated about a compounding quantity, the mass% is shown.
Prior to the description of the examples, the test method used in the present invention will be described.
（１）使用性（ロング効果、カール力、ツヤ、黒さ（又は透明性））の評価試験
下記処方のマスカラ化粧料及びマスカラ下地化粧料を常法に従って作製し、専門パネル１０名による実使用性試験を行った。専門パネルに当該化粧料を使用してもらい、ツヤ、黒さ（実施例２２、２３においては透明性）、ロング効果、およびカール力について、下記に示す５段階評価によるスコア（点数）をつけてもらった。パネル１０名によるスコアの平均値を評価項目ごとに計算し、下記の基準に従って当該平均値から各項目の使用性を評価した。 (1) Evaluation test of usability (long effect, curling power, gloss, blackness (or transparency)) Mascara cosmetics and mascara base cosmetics with the following prescriptions are prepared according to conventional methods and used by 10 professional panels A sex test was performed. Have the professional panel use the cosmetic, and give the score (score) based on the following five-level evaluation for gloss, blackness (transparency in Examples 22 and 23), long effect, and curl strength. received. The average value of the score by 10 panelists was calculated for each evaluation item, and the usability of each item was evaluated from the average value according to the following criteria.
下記処方のマスカラ化粧料及びマスカラ下地化粧料を常法に従って作製し、専門パネル１０名による実使用性試験を行った。専門パネルに当該化粧料を使用してもらい、ツヤ、黒さ（実施例２２、２３においては透明性）、ロング効果、およびカール力について、下記に示す５段階評価によるスコア（点数）をつけてもらった。パネル１０名によるスコアの平均値を評価項目ごとに計算し、下記の基準に従って当該平均値から各項目の使用性を評価した。 (1) Evaluation test of usability (long effect, curling power, gloss, blackness (or transparency)) Mascara cosmetics and mascara base cosmetics with the following prescriptions are prepared according to conventional methods and used by 10 professional panels A sex test was performed. Have the professional panel use the cosmetic, and give the score (score) based on the following five-level evaluation for gloss, blackness (transparency in Examples 22 and 23), long effect, and curl strength. received. The average value of the score by 10 panelists was calculated for each evaluation item, and the usability of each item was evaluated from the average value according to the following criteria.
＜５段階評価によるスコア＞
５点：非常に優れている。
４点：優れている。
３点：普通。
２点：劣る。
１点：非常に劣る。 <Score based on 5-level evaluation>
5 points: Excellent.
4 points: Excellent.
3 points: Normal.
2 points: Inferior.
1 point: Very inferior.
５点：非常に優れている。
４点：優れている。
３点：普通。
２点：劣る。
１点：非常に劣る。 <Score based on 5-level evaluation>
5 points: Excellent.
4 points: Excellent.
3 points: Normal.
2 points: Inferior.
1 point: Very inferior.
＜項目ごとの評価基準＞
◎：スコアの平均値が４．０以上５．０点以下
○：スコアの平均値が３．０以上４．０点未満
△：スコアの平均値が２．０以上３．０点未満
×：スコアの平均値が１．０以上２．０点未満 <Evaluation criteria for each item>
A: The average score value is 4.0 or more and 5.0 points or less. ○: The average score value is 3.0 or more and less than 4.0 points. Δ: The average score value is 2.0 or more and less than 3.0 points. The average score is 1.0 or more and less than 2.0
◎：スコアの平均値が４．０以上５．０点以下
○：スコアの平均値が３．０以上４．０点未満
△：スコアの平均値が２．０以上３．０点未満
×：スコアの平均値が１．０以上２．０点未満 <Evaluation criteria for each item>
A: The average score value is 4.0 or more and 5.0 points or less. ○: The average score value is 3.0 or more and less than 4.0 points. Δ: The average score value is 2.0 or more and less than 3.0 points. The average score is 1.0 or more and less than 2.0
（２）安定性の評価試験
下記処方のマスカラ化粧料及びマスカラ下地化粧料について、５０℃または０℃
で１ヶ月間保存した後の状態を、下記評価基準に従って目視にて評価した。
＜安定性の評価基準＞
◎：非常に安定
○：安定
△：やや分離がみられる
×：分離している (2) Stability evaluation test
For mascara cosmetics and mascara base cosmetics with the following prescriptions, 50 ° C or 0 ° C
The condition after storage for 1 month was evaluated visually according to the following evaluation criteria.
<Stability evaluation criteria>
◎: Very stable ○: Stable △: Slightly separated ×: Separated
下記処方のマスカラ化粧料及びマスカラ下地化粧料について、５０℃または０℃
で１ヶ月間保存した後の状態を、下記評価基準に従って目視にて評価した。
＜安定性の評価基準＞
◎：非常に安定
○：安定
△：やや分離がみられる
×：分離している (2) Stability evaluation test
For mascara cosmetics and mascara base cosmetics with the following prescriptions, 50 ° C or 0 ° C
The condition after storage for 1 month was evaluated visually according to the following evaluation criteria.
<Stability evaluation criteria>
◎: Very stable ○: Stable △: Slightly separated ×: Separated
次に、本願実施例および処方例に用いた化合物を示す。
※１：レオパール ＴＴ（千葉製粉株式会社製）
※２：シュガーワックスＡ－１０Ｅ（第一工業製薬株式会社製）
※３：ＫＦ６０１７（信越化学工業社製）
※４：ＴＳＰＬ－３０－Ｄ５（トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルラン（３０質量％）－デカメチルシクロペンタシロキサン（７０質量％）溶液、信越化学工業社製、実分としての値）
※５：レオパール ＫＬ（千葉製粉株式会社製） Next, compounds used in Examples and Formulation Examples of the present application are shown.
* 1: Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.)
* 2: Sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 3: KF6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: TSPL-30-D5 (Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan (30% by mass) -decamethylcyclopentasiloxane (70% by mass) solution, manufactured by Shin-Etsu Chemical Co., Ltd., actual value)
* 5: Leopard KL (manufactured by Chiba Flour Milling Co., Ltd.)
※１：レオパール ＴＴ（千葉製粉株式会社製）
※２：シュガーワックスＡ－１０Ｅ（第一工業製薬株式会社製）
※３：ＫＦ６０１７（信越化学工業社製）
※４：ＴＳＰＬ－３０－Ｄ５（トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルラン（３０質量％）－デカメチルシクロペンタシロキサン（７０質量％）溶液、信越化学工業社製、実分としての値）
※５：レオパール ＫＬ（千葉製粉株式会社製） Next, compounds used in Examples and Formulation Examples of the present application are shown.
* 1: Leopard TT (manufactured by Chiba Flour Milling Co., Ltd.)
* 2: Sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 3: KF6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: TSPL-30-D5 (Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan (30% by mass) -decamethylcyclopentasiloxane (70% by mass) solution, manufactured by Shin-Etsu Chemical Co., Ltd., actual value)
* 5: Leopard KL (manufactured by Chiba Flour Milling Co., Ltd.)
＜成分（ａ）及び（ｂ）の検討＞
下表１に示す処方のマスカラ化粧料を作製し、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステル、および（ｂ）ショ糖脂肪酸エステルの効果および配合量について検討した。 <Examination of components (a) and (b)>
Mascara cosmetics having the formulations shown in Table 1 below were prepared, and the effects and blending amounts of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester and (b) sucrose fatty acid ester were examined.
下表１に示す処方のマスカラ化粧料を作製し、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステル、および（ｂ）ショ糖脂肪酸エステルの効果および配合量について検討した。 <Examination of components (a) and (b)>
Mascara cosmetics having the formulations shown in Table 1 below were prepared, and the effects and blending amounts of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester and (b) sucrose fatty acid ester were examined.
（表１）
(Table 1)
成分（ａ）－（ｄ）をすべて含む実施例１のマスカラ化粧料は、睫にツヤのある黒さを付与する効果、睫を長く見せるロング効果、ならびに低温（０℃）および高温（５０℃）での安定性に優れていた。これに対し、実施例１の化粧料から成分（ａ）のみを除いた化粧料（比較例１）は、基剤の白目立ちを呈していたので黒繊維配合後も十分な黒さを発現することができず、さらにはロング効果にも劣っていた。当該ツヤのある黒さを付与する効果およびロング効果は、成分（ａ）を１－４０質量％配合することで改善されたが（実施例２－４、比較例２）、成分（ａ）を４０質量％含む比較例２の組成物はロング効果に劣るものであった。なお、比較例２の組成物は、０℃での安定性は高く、５０℃での安定性についても1ヶ月間保存後にやや分離が認められる程度であるから、安定性は概ね良好と判断できる。
よって、本発明の睫用化粧料においては、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルを０．１－３５質量％、好ましくは１～３０質量％、さらに好ましくは１０～２５質量％含むことで、睫にツヤのある黒さを付与する効果および睫を長く見せるロング効果に優れることが示された。 The mascara cosmetic of Example 1 containing all of the components (a) to (d) has an effect of imparting a glossy black color to the cocoon, a long effect of making the cocoon look long, and a low temperature (0 ° C.) and a high temperature (50 ° C.). ) Was excellent in stability. On the other hand, the cosmetic (Comparative Example 1) obtained by removing only the component (a) from the cosmetic of Example 1 exhibited sufficient whiteness even after blending the black fibers because it exhibited the whiteness of the base. In addition, the long effect was inferior. The effect of imparting a glossy blackness and the long effect were improved by blending the component (a) in an amount of 1-40% by mass (Example 2-4, Comparative Example 2). The composition of Comparative Example 2 containing 40% by mass was inferior in the long effect. The composition of Comparative Example 2 has a high stability at 0 ° C., and the stability at 50 ° C. is such that some separation is observed after storage for 1 month, so that the stability can be judged to be generally good. .
Therefore, in the vaginal cosmetic of the present invention, (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1 to 35% by mass, preferably 1 to 30% by mass, more preferably 10 to 25%. It was shown that the inclusion of the mass% is excellent in the effect of imparting a glossy blackness to the wrinkles and the long effect of making the wrinkles look longer.
よって、本発明の睫用化粧料においては、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルを０．１－３５質量％、好ましくは１～３０質量％、さらに好ましくは１０～２５質量％含むことで、睫にツヤのある黒さを付与する効果および睫を長く見せるロング効果に優れることが示された。 The mascara cosmetic of Example 1 containing all of the components (a) to (d) has an effect of imparting a glossy black color to the cocoon, a long effect of making the cocoon look long, and a low temperature (0 ° C.) and a high temperature (50 ° C.). ) Was excellent in stability. On the other hand, the cosmetic (Comparative Example 1) obtained by removing only the component (a) from the cosmetic of Example 1 exhibited sufficient whiteness even after blending the black fibers because it exhibited the whiteness of the base. In addition, the long effect was inferior. The effect of imparting a glossy blackness and the long effect were improved by blending the component (a) in an amount of 1-40% by mass (Example 2-4, Comparative Example 2). The composition of Comparative Example 2 containing 40% by mass was inferior in the long effect. The composition of Comparative Example 2 has a high stability at 0 ° C., and the stability at 50 ° C. is such that some separation is observed after storage for 1 month, so that the stability can be judged to be generally good. .
Therefore, in the vaginal cosmetic of the present invention, (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester is 0.1 to 35% by mass, preferably 1 to 30% by mass, more preferably 10 to 25%. It was shown that the inclusion of the mass% is excellent in the effect of imparting a glossy blackness to the wrinkles and the long effect of making the wrinkles look longer.
次に、実施例１の化粧料から成分（ｂ）のみを除いた化粧料（比較例３）を作製したところ、低温（０℃）での安定性は優れていたが高温安定性が非常に低く、５０℃で１ヶ月間保存後には完全に分離してしまった。当該高温安定性は、成分（ｂ）を１質量％（実施例５）、１２質量％（実施例６）配合することで格段に改善されたが、１５質量％配合した化粧料（比較例４）では５０℃で１ヶ月保存後に分離が観察された。
よって、本発明の睫用化粧料においては、（ｂ）ショ糖脂肪酸エステルを１－１３質量％、好ましくは１－１０質量％、さらに好ましくは３－８質量％含むことで、安定性の高い化粧料が得られることが示された。 Next, a cosmetic (Comparative Example 3) obtained by removing only the component (b) from the cosmetic of Example 1 was prepared. The stability at low temperature (0 ° C.) was excellent, but the high temperature stability was very high. It was low and completely separated after 1 month storage at 50 ° C. The high temperature stability was markedly improved by blending 1% by mass (Example 5) and 12% by mass (Example 6) of the component (b), but the cosmetic (Comparative Example 4) blended by 15% by mass. ), Separation was observed after storage at 50 ° C. for 1 month.
Therefore, the cosmetic for salmon of the present invention contains (b) sucrose fatty acid ester in an amount of 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass, and thus has high stability. It was shown that cosmetics can be obtained.
よって、本発明の睫用化粧料においては、（ｂ）ショ糖脂肪酸エステルを１－１３質量％、好ましくは１－１０質量％、さらに好ましくは３－８質量％含むことで、安定性の高い化粧料が得られることが示された。 Next, a cosmetic (Comparative Example 3) obtained by removing only the component (b) from the cosmetic of Example 1 was prepared. The stability at low temperature (0 ° C.) was excellent, but the high temperature stability was very high. It was low and completely separated after 1 month storage at 50 ° C. The high temperature stability was markedly improved by blending 1% by mass (Example 5) and 12% by mass (Example 6) of the component (b), but the cosmetic (Comparative Example 4) blended by 15% by mass. ), Separation was observed after storage at 50 ° C. for 1 month.
Therefore, the cosmetic for salmon of the present invention contains (b) sucrose fatty acid ester in an amount of 1-13% by mass, preferably 1-10% by mass, more preferably 3-8% by mass, and thus has high stability. It was shown that cosmetics can be obtained.
＜成分（ｃ）及び（ｄ）の検討＞
続いて、成分（ｃ）非イオン界面活性剤、および（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの効果および配合量について検討を行った。 <Examination of components (c) and (d)>
Subsequently, the effects and blending amounts of the component (c) nonionic surfactant and (d) tri (trimethylsiloxy) silylpropylcarbamate pullulan were examined.
続いて、成分（ｃ）非イオン界面活性剤、および（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランの効果および配合量について検討を行った。 <Examination of components (c) and (d)>
Subsequently, the effects and blending amounts of the component (c) nonionic surfactant and (d) tri (trimethylsiloxy) silylpropylcarbamate pullulan were examined.
（表２）
(Table 2)
実施例１の化粧料から成分（ｃ）のみを除いた化粧料（比較例５）では、ゲルの形成が不十分なため粘性が低く、ロング効果に劣ることが明らかとなった。当該ロング効果は、成分（ｃ）を０．５質量％（実施例７）、１０質量％（実施例８）配合した化粧料では改善されたが、１５質量％配合した比較例６の化粧料では劣る結果となった。比較例６の化粧料ではべたつき感も感じられ、使用性に劣るものであった。
よって、本発明の睫用化粧料においては、（ｃ）非イオン界面活性剤を０．１－１０質量％、好ましくは５－７質量％、さらに好ましくは１－１５質量％含むことにより、ロング効果に優れることが示された。 It was revealed that the cosmetic (Comparative Example 5) obtained by removing only the component (c) from the cosmetic of Example 1 has a low viscosity due to insufficient gel formation and is inferior in the long effect. The long effect was improved in the cosmetic containing 0.5% by mass (Example 7) and 10% by mass (Example 8) of component (c), but the cosmetic of Comparative Example 6 containing 15% by mass. Inferior results. The cosmetic of Comparative Example 6 also had a sticky feeling and was inferior in usability.
Therefore, the vaginal cosmetic of the present invention contains (c) a nonionic surfactant in an amount of 0.1-10% by mass, preferably 5-7% by mass, more preferably 1-15% by mass. It was shown that the effect is excellent.
よって、本発明の睫用化粧料においては、（ｃ）非イオン界面活性剤を０．１－１０質量％、好ましくは５－７質量％、さらに好ましくは１－１５質量％含むことにより、ロング効果に優れることが示された。 It was revealed that the cosmetic (Comparative Example 5) obtained by removing only the component (c) from the cosmetic of Example 1 has a low viscosity due to insufficient gel formation and is inferior in the long effect. The long effect was improved in the cosmetic containing 0.5% by mass (Example 7) and 10% by mass (Example 8) of component (c), but the cosmetic of Comparative Example 6 containing 15% by mass. Inferior results. The cosmetic of Comparative Example 6 also had a sticky feeling and was inferior in usability.
Therefore, the vaginal cosmetic of the present invention contains (c) a nonionic surfactant in an amount of 0.1-10% by mass, preferably 5-7% by mass, more preferably 1-15% by mass. It was shown that the effect is excellent.
次に、実施例１の化粧料から成分（ｄ）のみを除いた化粧料（比較例７）を作製したところ、当該化粧料は睫への付着が非常に悪く、ロング効果はほとんど得られなかった。当該ロング効果は、成分（ｄ）を０．３質量％（実施例９）、７質量％（実施例１０）配合することで格段に改善されたが、１５質量％配合した化粧料（比較例８）では組成物が緩くて曳糸性が強くなり、ロング効果に劣る結果となった。
よって、本発明の睫用化粧料においては、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランを０．１－１３質量％、好ましくは０．３－１０質量％、さらに好ましくは１－７質量％含むことで、ロング効果に優れることが示された。 Next, when a cosmetic (Comparative Example 7) in which only the component (d) was removed from the cosmetic of Example 1, the cosmetic was very poorly adhered to wrinkles, and a long effect was hardly obtained. It was. The long effect was markedly improved by blending 0.3% by mass (Example 9) and 7% by mass (Example 10) of component (d), but a cosmetic (comparative example) blended by 15% by mass. In 8), the composition was loose and the spinnability became strong, resulting in inferior long effect.
Therefore, in the vaginal cosmetic of the present invention, (d) tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is 0.1-13% by mass, preferably 0.3-10% by mass, more preferably 1-7. It was shown that the long effect was excellent by including the mass%.
よって、本発明の睫用化粧料においては、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランを０．１－１３質量％、好ましくは０．３－１０質量％、さらに好ましくは１－７質量％含むことで、ロング効果に優れることが示された。 Next, when a cosmetic (Comparative Example 7) in which only the component (d) was removed from the cosmetic of Example 1, the cosmetic was very poorly adhered to wrinkles, and a long effect was hardly obtained. It was. The long effect was markedly improved by blending 0.3% by mass (Example 9) and 7% by mass (Example 10) of component (d), but a cosmetic (comparative example) blended by 15% by mass. In 8), the composition was loose and the spinnability became strong, resulting in inferior long effect.
Therefore, in the vaginal cosmetic of the present invention, (d) tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is 0.1-13% by mass, preferably 0.3-10% by mass, more preferably 1-7. It was shown that the long effect was excellent by including the mass%.
＜成分（ｅ）の検討＞
次に、成分（ｅ）についても検討を行った。 <Examination of component (e)>
Next, the component (e) was also examined.
次に、成分（ｅ）についても検討を行った。 <Examination of component (e)>
Next, the component (e) was also examined.
（表３）
(Table 3)
実施例１の化粧料から成分（ｅ）のみを除いた化粧料（比較例１１）では、低温安定性は高く、高温安定性も概ね良好であったが、カール力が劣る結果となった。よって、本発明の睫用化粧料においては、（ｅ）デキストリンパルミチン酸エステルをさらに含むことで、カール効果に優れ、さらに高温安定性が向上することが明らかとなった。
成分（ｅ）の配合量について検討したところ、５質量％（実施例１）、１０質量％（実施例１２）配合した化粧料ではカール力および安定性に非常に優れるが、１５質量％配合した比較例９の化粧料ではダマが認められ、ツヤを付与する効果およびロング効果に劣っていた。よって、（ｅ）デキストリンパルミチン酸エステルの好適な配合量は、０．１－１３質量％、好ましくは０．１－１０質量％、さらに好ましくは１－８質量％と考えられる。 The cosmetic obtained by removing only the component (e) from the cosmetic of Example 1 (Comparative Example 11) had high low-temperature stability and generally good high-temperature stability, but the curling force was poor. Therefore, it was clarified that the vaginal cosmetic of the present invention further comprises (e) dextrin palmitate, which is excellent in curling effect and further improved in high temperature stability.
When the amount of component (e) was examined, cosmetics formulated with 5% by mass (Example 1) and 10% by mass (Example 12) were very excellent in curling power and stability, but were formulated with 15% by mass. The cosmetic of Comparative Example 9 was found to have lumps and was inferior in the effect of imparting gloss and the long effect. Therefore, it is considered that the suitable amount of (e) dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, and more preferably 1-8% by mass.
成分（ｅ）の配合量について検討したところ、５質量％（実施例１）、１０質量％（実施例１２）配合した化粧料ではカール力および安定性に非常に優れるが、１５質量％配合した比較例９の化粧料ではダマが認められ、ツヤを付与する効果およびロング効果に劣っていた。よって、（ｅ）デキストリンパルミチン酸エステルの好適な配合量は、０．１－１３質量％、好ましくは０．１－１０質量％、さらに好ましくは１－８質量％と考えられる。 The cosmetic obtained by removing only the component (e) from the cosmetic of Example 1 (Comparative Example 11) had high low-temperature stability and generally good high-temperature stability, but the curling force was poor. Therefore, it was clarified that the vaginal cosmetic of the present invention further comprises (e) dextrin palmitate, which is excellent in curling effect and further improved in high temperature stability.
When the amount of component (e) was examined, cosmetics formulated with 5% by mass (Example 1) and 10% by mass (Example 12) were very excellent in curling power and stability, but were formulated with 15% by mass. The cosmetic of Comparative Example 9 was found to have lumps and was inferior in the effect of imparting gloss and the long effect. Therefore, it is considered that the suitable amount of (e) dextrin palmitate is 0.1-13% by mass, preferably 0.1-10% by mass, and more preferably 1-8% by mass.
さらに、成分（ａ）と（ｅ）の配合量比（質量比）に注目すると、（ａ）：（ｅ）＝１：０．１７（実施例４）～（ａ）：（ｅ）＝１：５（実施例２）の範囲において、本発明の効果（ツヤのある黒さ（実施例１３、１４では透明性）を付与する効果、睫を長く見せるロング効果、安定性）が得られることがわかる。しかしながら、実施例２の化粧料は、他実施例の化粧料（（ａ）：（ｅ）＝１：０．１７（実施例４）～（ａ）：（ｅ）＝１：１（実施例３））と比べると、なめらかさに劣る傾向が感じられた。
よって、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと（ｅ）デキストリンパルミチン酸エステルの配合割合は、（ａ）：（ｅ）＝１：０．１～１：１（質量比）であることが好ましいと考えられる。 Further, focusing on the blending ratio (mass ratio) of the components (a) and (e), (a) :( e) = 1: 0.17 (Example 4) to (a) :( e) = 1 : Within the range of 5 (Example 2), the effects of the present invention (the effect of imparting glossy blackness (transparency in Examples 13 and 14), the long effect of making wrinkles look longer, and stability) can be obtained. I understand. However, the cosmetics of Example 2 are the same as those of other examples ((a) :( e) = 1: 0.17 (Example 4) to (a) :( e) = 1: 1 (Examples)). Compared with 3)), a tendency to be less smooth was felt.
Therefore, the blending ratio of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester and (e) dextrin palmitic acid ester is (a) :( e) = 1: 0.1 to 1: 1 (mass ratio) ) Is considered preferable.
よって、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルと（ｅ）デキストリンパルミチン酸エステルの配合割合は、（ａ）：（ｅ）＝１：０．１～１：１（質量比）であることが好ましいと考えられる。 Further, focusing on the blending ratio (mass ratio) of the components (a) and (e), (a) :( e) = 1: 0.17 (Example 4) to (a) :( e) = 1 : Within the range of 5 (Example 2), the effects of the present invention (the effect of imparting glossy blackness (transparency in Examples 13 and 14), the long effect of making wrinkles look longer, and stability) can be obtained. I understand. However, the cosmetics of Example 2 are the same as those of other examples ((a) :( e) = 1: 0.17 (Example 4) to (a) :( e) = 1: 1 (Examples)). Compared with 3)), a tendency to be less smooth was felt.
Therefore, the blending ratio of (a) dextrin (palmitic acid / 2-ethylhexanoic acid) ester and (e) dextrin palmitic acid ester is (a) :( e) = 1: 0.1 to 1: 1 (mass ratio) ) Is considered preferable.
また、着色顔料を配合せずに（実施例１３）、または、着色顔料と着色繊維を配合せずに（実施例１４）作製したマスカラ下地化粧料では、ツヤ効果、透明性又はツヤのある黒さ、ロング効果、低温・高温安定性、及びカール力のすべてにおいて優れていた。
Moreover, in the mascara base cosmetic prepared without blending the color pigment (Example 13) or without blending the color pigment and the colored fiber (Example 14), the glossy effect, transparency, or glossy black In addition, it was excellent in all of the long effect, low temperature / high temperature stability, and curling force.
以上の結果より、（ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルを０．１－３５質量％と、（ｂ）ショ糖脂肪酸エステルを１－１３質量％と、（ｃ）非イオン界面活性剤を０．１－１０質量％と、（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランを０．１－１３質量％配合することにより、基剤の状態では透明性が非常に高く、色材や着色繊維を配合した際には睫のツヤ効果およびロング効果に優れ、安定性が良好な睫用化粧料が作製できることが明らかとなった。さらに、０．１－１５質量％の（ｅ）デキストリンパルミチン酸エステルを追加することで、高温安定性が改善され、優れたカール効果も付与されることが示された。
From the above results, (a) 0.1-35% by mass of dextrin (palmitic acid / 2-ethylhexanoic acid) ester, (b) 1-13% by mass of sucrose fatty acid ester, (c) nonionic By blending 0.1-10% by mass of surfactant and 0.1-13% by mass of (d) tri (trimethylsiloxy) silylpropylcarbamic acid pullulan, transparency in the base state is very high. It has been clarified that when a coloring material or colored fiber is blended, it is possible to produce a vaginal cosmetic that is excellent in wrinkle and long effects of wrinkles and has good stability. Furthermore, it was shown that the addition of 0.1-15% by mass of (e) dextrin palmitate improves the high-temperature stability and provides an excellent curling effect.
以下に、本発明の睫用化粧料の好適な例を示すが、本発明は以下の処方例に限定されるものではない。
処方例（マスカラ下地化粧料）
配合成分 配合量（質量％）
デキストリン（パルミチン酸／２－エチルヘキサン酸）エステル※１
２０
ショ糖脂肪酸エステル※２ ５
ポリエチレングリコール（１０）ジメチコン※３ ４
デカメチルシクロペンタシロキサン １０．５
トリメチルシロキシケイ酸 ５
トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルラン※４
４．５
デキストリンパルチミン酸エステル※５ ５
香料 適量
白繊維 ３
軽質イソパラフィン 残量
（結果）
得られたマスカラ下地化粧料の評価は、ロング効果が「◎」、カール力が「◎」、ツヤが「◎」、黒さ（又は透明性）が「△」（白くなる）、安定性（５０℃）が「◎」であった。 Although the suitable example of the cosmetics for candy of this invention is shown below, this invention is not limited to the following formulation examples.
Formulation example (mascara base cosmetic)
Compounding ingredients Compounding amount (% by mass)
Dextrin (palmitic acid / 2-ethylhexanoic acid) ester * 1
20
Sucrose fatty acid ester * 2 5
Polyethylene glycol (10) dimethicone * 3 4
Decamethylcyclopentasiloxane 10.5
Trimethylsiloxysilicic acid 5
Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan * 4
4.5
Dextrin palmitate * 5 5
Fragrance Appropriate amount of white fiber 3
Light isoparaffin remaining amount (result)
The obtained mascara base cosmetic was evaluated as having a long effect of “◎”, a curling power of “◎”, a gloss of “◎”, a blackness (or transparency) of “△” (whitening), and a stability ( 50 ° C.) was “◎”.
処方例（マスカラ下地化粧料）
配合成分 配合量（質量％）
デキストリン（パルミチン酸／２－エチルヘキサン酸）エステル※１
２０
ショ糖脂肪酸エステル※２ ５
ポリエチレングリコール（１０）ジメチコン※３ ４
デカメチルシクロペンタシロキサン １０．５
トリメチルシロキシケイ酸 ５
トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルラン※４
４．５
デキストリンパルチミン酸エステル※５ ５
香料 適量
白繊維 ３
軽質イソパラフィン 残量
（結果）
得られたマスカラ下地化粧料の評価は、ロング効果が「◎」、カール力が「◎」、ツヤが「◎」、黒さ（又は透明性）が「△」（白くなる）、安定性（５０℃）が「◎」であった。 Although the suitable example of the cosmetics for candy of this invention is shown below, this invention is not limited to the following formulation examples.
Formulation example (mascara base cosmetic)
Compounding ingredients Compounding amount (% by mass)
Dextrin (palmitic acid / 2-ethylhexanoic acid) ester * 1
20
Sucrose fatty acid ester * 2 5
Polyethylene glycol (10) dimethicone * 3 4
Decamethylcyclopentasiloxane 10.5
Trimethylsiloxysilicic acid 5
Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan * 4
4.5
Dextrin palmitate * 5 5
Fragrance Appropriate amount of white fiber 3
Light isoparaffin remaining amount (result)
The obtained mascara base cosmetic was evaluated as having a long effect of “◎”, a curling power of “◎”, a gloss of “◎”, a blackness (or transparency) of “△” (whitening), and a stability ( 50 ° C.) was “◎”.
Claims (3)
- （ａ）デキストリン（パルミチン酸／２－エチルヘキサン酸）エステルを０．１－３５質量％と、
（ｂ）ショ糖脂肪酸エステルを１－１３質量％と、
（ｃ）非イオン界面活性剤を０．１－１０質量％と、
（ｄ）トリ（トリメチルシロキシ）シリルプロピルカルバミド酸プルランを０．１－１３質量％と、
を含有することを特徴とする睫用化粧料。 (A) 0.1-35% by mass of dextrin (palmitic acid / 2-ethylhexanoic acid) ester,
(B) 1-13% by mass of sucrose fatty acid ester,
(C) 0.1-10% by weight of nonionic surfactant,
(D) 0.1-13% by mass of pullulan tri (trimethylsiloxy) silylpropylcarbamate,
A vaginal cosmetic, comprising: - さらに（ｅ）デキストリンパルミチン酸エステル０．１－１３質量％を含有することを特徴とする請求項１記載の睫用化粧料。 The vaginal cosmetic according to claim 1, further comprising (e) 0.1-13% by mass of a dextrin palmitate ester.
- （ａ）成分と（ｅ）成分の配合割合が、（ａ）：（ｅ）＝１：０．１～１：１（質量比）であることを特徴とする請求項２に記載の睫用化粧料。 The combination of (a) component and (e) component is (a) :( e) = 1: 0.1-1: 1 (mass ratio) Cosmetics.
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| JP2013507557A JP6113654B2 (en) | 2011-03-29 | 2012-03-26 | Cosmetic for salmon |
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|---|---|---|---|
| JP2011-071493 | 2011-03-29 | ||
| JP2011071493 | 2011-03-29 |
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|---|---|---|---|
| PCT/JP2012/057733 WO2012133293A1 (en) | 2011-03-29 | 2012-03-26 | Eyelash cosmetic |
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| JP (1) | JP6113654B2 (en) |
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| Publication number | Publication date |
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| JP6113654B2 (en) | 2017-04-12 |
| TW201244751A (en) | 2012-11-16 |
| JPWO2012133293A1 (en) | 2014-07-28 |
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