JP2009114099A - Oily cosmetic for eyelash - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an oily cosmetic for eyelashes having good adhesiveness to the eyelashes, sufficient volume effects and curling effects, excellent makeup persistence thereof, affording a uniform and beautiful makeup film without causing bunching, and having excellent softness and pliability of the makeup film in relation to the oily cosmetic for the eyelashes. <P>SOLUTION: The oily cosmetic is characterized by formulating following ingredients (A) to (C): (A) a rosin ester compound that is an ester of rosin with glycerol in which the rosin is disproportionated and/or hydrogenated, (B) one or two or more kinds of oil-soluble resins selected from among any of pentaerythritol rosinate, trimethylsiloxysilicic acid, and an alkyl acrylate methylpolysiloxane ester, and (C) a volatile oil. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to an oily wrinkle cosmetic, and more particularly, an ester of rosin and any one of mono-, di-, and triglycerin, wherein the rosin is disproportionated and / or hydrogenated. By blending a rosin ester compound, a specific oil-soluble resin and a volatile oil agent, it is possible to obtain a uniform and beautiful cosmetic film with good adhesion to wrinkles, sufficient volume effect and curl effect, no bundling The present invention relates to a cosmetic for oily wrinkles that can be made and has excellent flexibility and flexibility of the cosmetic film.

Cosmetics for eyelashes make the eye clearly and beautifully clarified by curling the eyelids upward and making the eyelashes thicker and longer.
Conventionally, these cosmetics for wrinkles are mainly composed of solid oil such as wax, powder, film-forming agent, water-soluble polymer, etc., according to consumer needs, usability, feeling of use, In order to improve functionality, various dosage forms and compounding raw materials have been studied. For example, by blending a specific oil-soluble resin, fumed silicic acid anhydride, an organically modified clay mineral, and an aqueous component, the cosmetic effect and usability of the vaginal cosmetics and the stability over time are improved, and further, the remover There has been a technique (for example, see Patent Document 1) that facilitates the removal. In addition, by blending trimethylylsiloxysilicic acid, a specific acrylic-silicone graft copolymer, low-boiling silicone oil and / or low-boiling isoparaffin, it has excellent water resistance and sebum resistance and uniform coating and use There is a technique that improves the feeling (see, for example, Patent Document 2). Furthermore, there has been a technique for imparting volume feeling and curl flexibility by blending a non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone and a hollow powder (see, for example, Patent Document 3).
On the other hand, use of dimer acid esters and dimer diol esters in combination with lower polyhydric alcohol esters of hydrogenated rosin in cosmetics has been studied (for example, see Patent Document 4).

JP 2004-300092 A Japanese Patent Laid-Open No. 7-196449 JP 2004-315420 A JP 2004-277285 A

However, in oil-in-water cosmetics, it is possible to obtain a long and thick cosmetic effect and long-lasting makeup by adding wax, resin, film-forming agent, and fiber. There was a drawback that the makeup persistence against tears was low, and the eyes were blurred over time. Water-in-oil cosmetics may have inferior film uniformity compared to oil-based types, and it is a technology that combines specific oil-soluble resins, fumed silicic acid anhydride, organically modified clay minerals, and aqueous components. In some cases, sufficient flexibility of the decorative film after drying cannot be obtained. In addition, for oily types, makeup persistence against sweat and tears is obtained, but when oil-soluble resins such as trimethylylsiloxysilicic acid and acrylic-silicone graft copolymers are highly blended, makeup after drying The flexibility of the film was lost, and the curl of the kite, which should have a natural curve, gave a linear and unnatural impression. In addition, although the technology combining non-aqueous polymer dispersion and hollow powder is excellent in flexibility and long-lasting makeup, it has not been sufficient in terms of cosmetic effect such as low adhesion to wrinkles and long and thick wrinkles.
In addition, it has been known that the lower polyhydric alcohol ester of hydrogenated rosin improves the adhesion, but the cosmetic effect obtained by applying it to wrinkles has not been disclosed or suggested.
Therefore, it has good adhesion to wrinkles, sufficient volume effect and curl effect, can obtain a uniform and beautiful makeup film without bundling, and the makeup film after drying is flexible, supple and natural There has been a demand for the development of oily wrinkle cosmetics that can impart curls to wrinkles.

As a result of intensive studies to solve the above-mentioned problems, the present inventors have used a volatile oil agent in an oleaginous cosmetic and used an ester of rosin and any one of mono-, di-, and triglycerides. In order to complete the present invention, it is found that the above problem can be solved by blending a rosin ester compound in which the rosin is disproportionated and / or hydrogenated with a specific oil-soluble resin. It came.
Component (A) can form a flexible film, and component (B) forms a relatively rigid film. By combining both of these and specifying the component (B), it is possible to form a flexible film with a certain degree of solidification force, good adhesion to wrinkles, sufficient volume effect, curl An oily wrinkle cosmetic having an effect and having a uniform and beautiful cosmetic film without bundling and excellent in flexibility and flexibility of the cosmetic film after drying was obtained.

That is, the present invention includes the following components (A) to (C),
(A) an ester of rosin and any one of mono-, di-, and triglycerin, wherein the rosin is disproportionated and / or hydrogenated (B) rosin acid pentaerythritol; The present invention provides an oil-based cosmetic for cosmetics characterized in that it contains one or more oil-soluble resins (C) volatile oils selected from trimethylsiloxysilicic acid and acrylic-silicone graft copolymers. .

  The oily wrinkle cosmetic of the present invention has good adhesion to wrinkles, sufficient volume effect and curl effect, excellent makeup durability, excellent flexibility and flexibility of the cosmetic film, and no bundling The present invention relates to a cosmetic for oily wrinkles from which a uniform and beautiful cosmetic film can be obtained.

  In the present invention, the oily wrinkle cosmetic is a vaginal cosmetic substantially free of water having a continuous phase of an oily component that is a liquid, semi-solid or solid oil agent or oil-soluble compound.

  The rosin of the component (A) used in the oily wrinkle cosmetic composition of the present invention and any one of mono-, di-, and triglycerin esters is any of disproportionated rosin and mono-, di-, or tri. Esters of glycerin, hydrogenated rosin with mono-, di-, triglycerin, disproportionated and hydrogenated rosin with mono-, di-, triglycerin The order of the reaction of disproportionation, hydrogenation, and esterification is not particularly limited.

The method for synthesizing component (A) is not particularly limited. Specifically, rosin is a natural resin that can be taken from pine and contains abietic acid as a main component. By disproportionating the rosin mainly by disproportionation to dehydroabietic acid, dihydroabietic acid, and tetrahydroabietic acid, and mono-, di-, or triglycerides are esterified, A leveled rosin glycerin ester can be obtained.
The ester with hydrogenated rosin is, for example, an ester of dihydroabietic acid or tetrahydroabietic acid that is hydrogenated if it is the main component abietic acid, and mono-, di-, or triglycerides. The hydrogenated rosin glycerin ester can be obtained.
Further, the disproportionated rosin may be esterified with mono-, di-, or triglyceride by hydrogenation reaction, and the disproportionated rosin and any of mono-, di-, tri-glycerin may be used. A product obtained by hydrogenating an ester with can also be used.
The esterification reaction may be a monoester, diester, triester, tetraester or the like.
A hydrogenated ester gum obtained by hydrogenating a glycerin ester of a mixture of mainly dehydroabietic acid and dihydroabietic acid obtained by disproportionating rosin is preferable because it is not sticky and has a long lasting appearance. Examples of commercially available products include Pine Crystal KE-311, KE-100, Ester Gum H, Superester A-75, A-100 (above, manufactured by Arakawa Chemical Industries).

  The component (A) can be used alone or in combination of two or more as required. The amount of the component (A) is not particularly limited, but is preferably 1 to 20% by mass (hereinafter simply indicated by “%”). ˜16% is particularly preferred. If it is in this range, it has good adhesion to wrinkles, sufficient volume effect, curl effect, excellent sustainability, excellent flexibility and flexibility of the cosmetic film, uniform and beautiful cosmetic film without bundling Is obtained.

The specific oil-soluble resin of the component (B) used in the oily cosmetic composition of the present invention is a resin having the property of forming a relatively rigid coating film, such as hydrogenated pentaerythrityl rosin acid, trimethylsiloxysilicate. Acid, acrylic-silicone graft copolymer.
Rosin acid pentaerythritol is an ester of a resin acid obtained from a pine family plant and pentaerythritol, and a commercially available product is ester gum HP (manufactured by Arakawa Chemical Industries).
Trimethylsiloxysilicic acid is a compound having a cross-linked structure with a siloxane structure as the main skeleton, and commercially available products are dissolved in silicone oil as KF7312J (solid content 50% decamethylcyclopentasiloxane solution), KF -9021 (50% decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.), TSF4600 (methyl polysiloxane solution) (manufactured by Toshiba Silicone Co., Ltd.), BY11-018 (30% decamethylcyclopentasiloxane) Siloxane solution) (manufactured by Toray Dow Corning Silicone Co., Ltd.).
The acrylic-silicone graft copolymer is a radical polymer of an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate. KP541 (solid content 60%, solvent: isopropanol), KP545 (solid content 30%, solvent: decamethylcyclopentasiloxane), KP575 (solid content 30), in which an acrylic-silicone graft copolymer is dissolved in a solvent. %, Solvent: decamethylcyclopentasiloxane) (all manufactured by Shin-Etsu Chemical Co., Ltd.).
Among these, rosin acid pentaerythritol is preferable in terms of uniformity of the cosmetic film and makeup durability.
These oil-soluble resins may be blended alone or in combination of two or more.

  The blending amount of the component (B) oil-soluble resin is not particularly limited, but is preferably 0.5 to 20%, particularly preferably 1 to 16%. If it is in this range, it has good adhesion to wrinkles, sufficient volume effect, curl effect, excellent sustainability, excellent flexibility and flexibility of the cosmetic film, uniform and beautiful cosmetic film without bundling Is obtained.

The ratio of the amount of component (A) to component (B) is preferably in the range of 1: 4 to 4: 1 by mass ratio. Within this range, adhesiveness to the wrinkles is good, sufficient volume effect and curl effect are obtained, the cosmetic film is excellent in flexibility and flexibility, and a uniform and beautiful cosmetic film without bundling can be obtained.
The total amount of component (A) and component (B) is not particularly limited, but is preferably 5 to 25%, and more preferably 10 to 20%. When blended in this range, it has good adhesiveness to wrinkles, sufficient volume and curl effects, excellent sustainability, excellent flexibility and flexibility of the cosmetic film, uniform and beautiful cosmetic film without bundling Is obtained.

The film formed by component (A) is weak and flexible, and the film formed by component (B) is strong but fragile. The flexibility of the film formed of each component can be measured by a method described below using a Surfand And Interfacial Cutting Analysis System (hereinafter referred to as SAICAS, manufactured by Daipura Wintes).
Each component is dissolved in a volatile solvent and placed in a glass plate shape. After a coating film is formed using a doctor blade (15.7 mill), it is sufficiently dried to obtain a sample. A BN blade having a blade width of 2 mm, a rake angle of 20 degrees, a blade angle of 60 degrees, and a bald angle of 10 degrees was applied to the surface of the dried coating film, with a horizontal speed of 10 μm / sec, a vertical speed of 0.5 μm / sec, and a shear angle of 45 degrees. The flexibility of the film can be expressed by cutting and measuring the change in the horizontal load value as the depth increases.

  The volatile oil of component (C) used in the oily wrinkle cosmetic of the present invention is not particularly limited as long as it can be used in cosmetics. For example, hydrocarbon oils such as light liquid isoparaffin and isododecane , Silicones such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane can be used, and one or more of these can be used as required. Any volatile oil can be used, but light liquid isoparaffin and cyclic silicone are particularly effective in enhancing the drying of oil-based cosmetics and forming a strong cosmetic coating by volatilization. ,preferable. Examples of commercially available components (C) include IP solvent (made by Idemitsu Petrochemical Co., Ltd.), shell sol (made by Shell Chemical Co., Ltd.), silicon KF994, KF995, KF96A (5CS) (all manufactured by Shin-Etsu Chemical Co., Ltd.), etc. Is mentioned. In addition, a component (C) can also be used as a solvent which melt | dissolves a component (B).

  Although the compounding quantity of a component (C) is not specifically limited, 10 to 70% is preferable and 20 to 60% is still more preferable. Within this range, satisfactory results can be obtained in terms of adhesion to wrinkles, smoothness during use, and uniformity of the decorative film.

In this invention, in addition to the said component, the dextrin fatty acid ester of a component (D) is mix | blended, and the adhesiveness to a wrinkle improves markedly without impairing the softness | flexibility of a decorative film.
As the dextrin fatty acid ester of component (D), an ester of dextrin and preferably a higher fatty acid having 8 to 22 carbon atoms is used. Specifically, dextrin octoate, dextrin laurate, dextrin palmitate, dextrin myristate , Stearic acid dextrin, behenic acid dextrin, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin and the like. Of these, dextrin palmitate is most preferable from the viewpoint of shape stability and usability. Examples of commercially available products of these dextrin fatty acid esters include “Leopard KL”, “Leopard KE”, “Leopard TT”, and “Leopard TL” (above, manufactured by Chiba Flour Mills).
Etc.
Although the compounding quantity of a component (D) is not specifically limited, Preferably it is 0.1 to 10%, More preferably, it is 1 to 5%. If the content is within this range, the adhesiveness of the cosmetic material to the wrinkles can be improved while maintaining the flexibility of the decorative film, and a good product can be obtained in terms of smooth usability and stability over time.
These dextrin fatty acid esters can be used alone or in combination of two or more as required.

  In addition to the above components (A) to (D), the oily wrinkle cosmetic of the present invention is a component that is usually used in cosmetics, for example, an oily component as a base material or an emollient component, a feel adjustment or coloring component. Powder, fiber as a component to obtain a long rush effect, surfactant for powder dispersion and feel adjustment, aqueous component as moisturizer, UV absorber, moisturizer, anti-fading agent, antioxidant, antifoaming agent, Beauty ingredients, preservatives, fragrances, and the like can be appropriately blended within a range not impairing the effects of the present invention.

Oily components other than components (A) to (D) include hydrocarbons, fats and oils, regardless of the origin of animal oils, vegetable oils, synthetic oils, and the properties of solid oils, semisolid oils, liquid oils, etc. Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents.
Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, fisher trops wax, molasses, olive oil, castor oil, mink oil, macadamia Oils such as peanut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearate Polyglyceryl acid, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fat Acid esters, esters such as N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methylphenyl poly Silicones such as siloxane and fluorine-modified organopolysiloxane, fluorine oils such as perfluorodecane, perfluorooctane and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, and sucrose fatty acid esters , Starch fatty acid esters, 12-hydroxystearic acid, oily gelling agents such as calcium stearate, and the like.

  The powder component is not particularly limited by the shape of plates, spindles, needles, etc., the particle size of fumes, fine particles, pigment grades, the particle structure of porous, nonporous, etc. , Glitter powders, organic powders, pigment powders, composite powders, and the like. Specifically, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, Carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silica, silicon carbide, barium sulfate, boron nitride and other inorganic powders, oxy Bismuth chloride, mica titanium, iron oxide treated mica, iron oxide mica titanium, organic pigment treated mica titanium, titanium oxide treated glass powder, iron oxide titanium oxide treated glass powder, aluminum powder and other glittering powders, magnesium stearate, Zinc stearate, N-acyl lysine, Nai Organic powders such as silver, organic tar pigments, pigment powders such as organic rake pigments, fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium dioxide-containing silicon dioxide And composite powders such as zinc oxide-containing silicon dioxide, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc. The above can be used. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. A surface-treated product may be used.

The fiber is not particularly limited as long as it is generally used in cosmetics. For example, synthetic fibers such as nylon, polyester, and polypropylene, artificial fibers such as rayon, natural fibers such as cellulose, and half fibers such as acetate silk. Examples thereof include synthetic fibers and the like, or composite fibers of these.
The length is not particularly limited, but generally 0.1 to 10 mm is preferable, and 0.3 to 7 mm is more preferably used. Generally, the thickness is preferably 0.1 to 20 tex (hereinafter simply referred to as “T”), more preferably 0.3 to 15T. These fibers can be used singly or in combination of different materials, thicknesses and lengths.
The shape of the cross section of the fiber is not particularly limited, and any of a circular shape, an elliptical shape, a polygonal shape, a well shape, a T shape, a Y shape, and the like can be used.
Furthermore, these fibers are used after being colored with a colorant or subjected to a surface treatment, if necessary. Examples of the surface treatment agent include a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, and surfactant.

  For the purpose of improving the dispersibility of the powder, any surfactant that is commonly used in cosmetics can be used as the surfactant. Nonionic surfactants, anionic surfactants, cations Ionic surfactants, amphoteric surfactants and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified Examples thereof include organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.

  The aqueous component may be any component as long as it is soluble in water and water, such as lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol and the like. Glycerols such as glycols, glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, and other semi-synthetic materials such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer and sodium polyacrylate can be mentioned. Other moisturizing agents such as protein, mucopolysaccharide, collagen, elastin, keratin and the like can also be contained. However, since the present invention is an oily wrinkle cosmetic, the water content is preferably 1% or less.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.

  The oily wrinkle cosmetic of the present invention can be applied to mascara, mascara base, mascara topcoat, etc., and examples of the form include cream, gel, liquid, etc. Among them, gel is preferable, and the appearance is transparent. Can be used as cosmetics, translucent and opaque.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Examples 1-9 and Comparative Examples 1-5: Oily mascara (gel)
Oily wrinkle cosmetics having the formulations shown in Table 1 below were prepared, and the finished flexibility, makeup effect, makeup retention, etc. were evaluated by the following methods. The results are also shown in Table 1.

* 1: Pine Crystal KE-311 (Arakawa Chemical Industries)
* 2: Esther gum HP (Arakawa Chemical Industries)
* 3: KF7312J (manufactured by Shin-Etsu Chemical Co., Ltd.) (solid content 50% decamethylcyclopentasiloxane solution)
* 4: KP545 (manufactured by Shin-Etsu Chemical Co., Ltd.) (30% solid content decamethylcyclopentasiloxane solution)
* 5: Leopard TL (Chiba Flour Mills)
* 6: Dimethicone 5% treatment * 7: AEROSIL 200 (Nippon Aerosil Co., Ltd.)
* 8: IP solvent 1620MU (made by Idemitsu Kosan Co., Ltd.)
(Manufacturing method)
A. Ingredients (1) to (5) are heated to about 110 ° C. and mixed uniformly.
B. Add (6) to (14) to A and mix uniformly.
C. B was filled into a container to obtain an oily mascara.

(Evaluation methods)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Flexibility of decorative film b. Uniformity of the decorative film c. Volume effect d. Carl's suppleness e. Makeup persistence For the items a to e, a use test was conducted by 20 specialist panels for each sample. Each panel member gave a rating based on the following absolute rating and assigned a score. The average value of each sample was calculated from the total score of all the panel members, and the determination was made according to the following four criteria. In addition, for the makeup persistence of e, each sample was applied to the eyelid, and after having a normal life on the panel, it was evaluated whether or not it was blotted or dropped by tears or sweat after 6 hours.

Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

4-step criteria (judgment): (average score)
◎: Over 5 points: Very good ○: Over 3.5 points and 5 points or less: Good △: Over 1 point and 3.5 points or less: Slightly defective ×: 1 point or less: Defect

As is apparent from the results in Table 1, the oily mascara of Examples 1 to 9 of the present invention is superior in adhesion to wrinkles as compared with the oily mascara of Comparative Examples 1 to 5, the flexibility of the cosmetic film, It was excellent in all of uniformity, volume effect, curling flexibility, and makeup sustainability.
On the other hand, in the comparative example 1 which mix | blended only a component (A) and does not contain a component (B), and the comparative example 2 which replaced the component (B) of Example 1 with the component (A), Since the adhesiveness was poor and the film strength was weak, a cosmetic effect could not be obtained, and particularly satisfactory in terms of makeup sustainability and volume effect could not be obtained.
In Comparative Example 3 where the component (A) is not blended and in Comparative Example 4 where the component (A) of Example 1 is replaced with the component (B), as seen in conventional cosmetics for oily wrinkles, over time As a result, the decorative film became hard, and satisfactory results were not obtained in terms of the flexibility of the decorative film and the flexibility of the curl.
In Comparative Example 5 using a combination of other oil-soluble resins instead of component (A), compared with Comparative Examples 3 and 4, the uniformity and volume effect of the cosmetic film, and makeup persistence are improved. Compared to the Examples, it was inferior to the flexibility of the decorative film and the flexibility of the curl.

  Furthermore, as for the oily mascara of Example 1 and Comparative Example 5, the flexibility of each decorative film was measured by the measurement method using SAICAS. As a result, Example 1 was more flexible than Comparative Example 5. Was obtained and was consistent with the results of the usage test.

Example 10: Oily mascara (gel)
(Ingredient) (%)
(1) Hydrogenated ester gum * 1 5
(2) Trimethylsiloxysilicate solution * 3 3
(3) Hydrogenated pentaerythrityl rosinate * 2 5
(4) Candelilla wax 3
(5) Beeswax 3
(6) Dextrin fatty acid ester * 5 2
(7) Light liquid isoparaffin * 8 Residual amount (8) Organically modified bentonite 3
(9) Silicone-treated mica titanium * 9 10
(10) Titanium oxide coated glass powder 6
(11) Mica 2
(12) Red iron oxide 3
(13) Yellow iron oxide 3
(14) Methyl ester of paraoxybenzoic acid 0.1
(15) Phenoxyethanol 0.1
(16) Fragrance 0.2
* 9: (Dimethicone / Methicone) Copolymer 2% treatment: FLAMENCO BLUE 620C (manufactured by Engelhard)
(Manufacturing method)
A. Ingredients (1) to (7) are heated and mixed at about 110 ° C. to be uniform.
B. Ingredients (8) to (16) are added to A and mixed uniformly.
C. B was filled into a container to obtain an oily mascara.
The oily mascara obtained as described above was excellent in all of the flexibility of the decorative film, the uniformity of the decorative film, the volume effect, the flexibility of the curl, and the makeup sustainability.

Example 11: Oily mascara (long type, gel)
(Ingredient) (%)
(1) Disproportionated rosin glycerin ester * 10 10
(2) Hydrogenated pentaerythrityl rosinate * 2 5
(3) Candelilla wax 3
(4) Beeswax 2
(5) Dextrin palmitate * 11 1.5
(6) Light liquid isoparaffin * 8 Residual amount (7) Organically modified bentonite 3
(8) Black iron oxide 10
(9) Silicon processing talc * 12 3
(10) Silicon-treated sericite * 12 3
(11) Nylon fiber 2
(12) Methyl ester of paraoxybenzoic acid 0.1
(13) 1,3-butylene glycol 0.2
(14) Sodium hyaluronate 0.1
(15) Fragrance 0.1
* 10: Superester A-75 (Arakawa Chemical Industries)
* 11: Leopard KL (manufactured by Chiba Flour Milling)
* 12: Dimethicone 5% treatment (production method)
A. Ingredients (1) to (6) are heated and mixed at about 110 ° C. to be uniform.
B. Components (7) to (15) and A are combined and mixed uniformly.
C. B was filled in a container to obtain an oily wrinkle cosmetic (long type).
The oily wrinkle cosmetic (long type) obtained as described above has good adhesion to wrinkles, sufficient volume effect and long rush effect, and the uniformity and flexibility of the cosmetic film and curl It was excellent in suppleness and had good makeup persistence.

Example 12: Mascara base (gel)
(Ingredient) (%)
(1) Hydrogenated ester gum * 1 4
(2) Acrylic-silicone graft copolymer * 4 8
(3) Light liquid isoparaffin * 8 Residual amount (4) Hydrogenated polydecene * 13 0.1
(5) Polyoxyethylene (10 mol) hydrogenated castor oil 0.1
(6) Silicon processing talc * 12 30
(7) Titanium oxide 0.5
(8) Calcium carbonate 1
* 13: Silkflo 364NF Polydecene (manufactured by Lipo Chemicals)
(Manufacturing method)
A. Ingredients (1) to (8) are uniformly mixed at about 100 ° C.
B. A was filled into a container to obtain a mascara substrate.
The mascara base obtained as described above was excellent in adhesion to wrinkles, flexibility of the decorative film, uniformity of the decorative film, suppleness of curl, and makeup sustainability.

Example 13: Mascara overcoat (liquid)
(Ingredient) (%)
(1) Hydrogenated ester gum * 1 8
(2) Hydrogenated pentaerythrityl rosinate * 2 5
(3) Decamethylcyclopentasiloxane 76.5
(4) Dextrin fatty acid ester * 5 2
(5) Colored interference fiber * 14 8
(6) Vinyl acetate / vinyl pyrrolidone copolymer 0.1
(7) Trehalose 0.1
(8) Methyl ester of paraoxybenzoic acid 0.2
(9) Fragrance 0.1
* 14: Polyethylene terephthalate and nylon laminated in 51 layers according to JP-A-11-1829, 5 denier, 1 mm, red 102 dyed 0.1% (production method)
A. Ingredients (1) to (9) are uniformly mixed at about 100 ° C.
B. A was filled into a container to obtain a mascara overcoat.
The mascara overcoat obtained as described above was excellent in the adhesion to wrinkles, the flexibility of the decorative film, the uniformity of the decorative film, the flexibility of the curl, and the makeup sustainability.

Claims (4)

The following components (A) to (C);
(A) A rosin ester compound of rosin and mono-, di-, or triglycerin, wherein the rosin is disproportionated and / or hydrogenated (B) hydrogenated rosin acid pentaerythrite An oil-based cosmetic for cosmetics, comprising one or more oil-soluble resins (C) volatile oils selected from lithyl, trimethylsiloxysilicic acid, and an acrylic-silicone graft copolymer.   2. The oily salmon cosmetic according to claim 1, further comprising a component (D) dextrin fatty acid ester.   The ratio of the said component (A) and a component (B) is the range of 1: 4-4: 1 by mass ratio, The oily wrinkle cosmetics of Claim 1 or 2 characterized by the above-mentioned.   The said component (B) is hydrogenated rosin acid pentaerythlit, cosmetics for oily wrinkles according to any one of claims 1 to 3.