JP2006306849A - Oil-in-water eye makeup cosmetic emulsion - Google Patents

Oil-in-water eye makeup cosmetic emulsion Download PDF

Info

Publication number
JP2006306849A
JP2006306849A JP2006087180A JP2006087180A JP2006306849A JP 2006306849 A JP2006306849 A JP 2006306849A JP 2006087180 A JP2006087180 A JP 2006087180A JP 2006087180 A JP2006087180 A JP 2006087180A JP 2006306849 A JP2006306849 A JP 2006306849A
Authority
JP
Japan
Prior art keywords
oil
water
makeup
film
eye makeup
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2006087180A
Other languages
Japanese (ja)
Inventor
Tatsuya Himeno
Yumiko Yakuta
達也 姫野
由美子 役田
Original Assignee
Kose Corp
株式会社コーセー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2005096554 priority Critical
Application filed by Kose Corp, 株式会社コーセー filed Critical Kose Corp
Priority to JP2006087180A priority patent/JP2006306849A/en
Publication of JP2006306849A publication Critical patent/JP2006306849A/en
Application status is Pending legal-status Critical

Links

Abstract

<P>PROBLEM TO BE SOLVED: To provide an oil-in-water eye makeup cosmetic emulsion having makeup-lasting effects against tears, sweat or the like but enabling the makeup film to be easily removed by water or warm water, providing the uniform makeup film having transparency, and hardly bleeding with time. <P>SOLUTION: The oil-in-water eye makeup cosmetic emulsion is obtained by formulating a liquid crystal formed out of a polyhydric alcohol and an amphipathic material in the oil phase. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention has a long-lasting effect on tears, sweat, etc., but the cosmetic film can be easily removed with water or warm water, and a transparent uniform cosmetic film can be obtained and blurs over time. The present invention relates to an oil-in-water eye make-up cosmetic.

Conventionally, eye makeup cosmetics such as mascara, eye color, eyeliner, and eyebrow have been studied to impart water resistance and oil resistance and improve long lasting. (For example, see Patent Document 1) However, when water resistance and oil resistance are improved, it becomes difficult to remove cosmetics, and a dedicated remover is required.
Recently, due to changes in user preferences, the market for vaginal cosmetics in particular has expanded, and the frequency of use has tended to increase markedly.
In this way, everyone can use eye makeup cosmetics regardless of their inexperienced makeup depth, and when applied to everyday makeup, it is easier to apply than improving water and oil resistance. What can be done and can be dropped easily is now required.
Therefore, the development of cosmetics for candy that can be removed by hot water has been developed. For example, an oil-in-water type is suitable as a cosmetic dosage form that can be removed by warm water, but research has been made on a film-forming agent that forms a wax or film as a component to be blended. (For example, see Patent Documents 2 and 3)

Japanese Patent No. 2844076 JP 2003-137732 A JP-T-2004-522701

  However, when an activator or liquid oil is blended in the cosmetic film in order to easily remove the cosmetic film with water or warm water, it causes bleeding and film non-uniformity. In addition, the transparency of the decorative film may be reduced by adding a large amount of wax to maintain the decorative film. Accordingly, it has been desired to develop an eye makeup cosmetic that can be easily removed with water or warm water, can provide a transparent uniform cosmetic film, and does not blur over time.

  As a result of intensive research to solve the above problems, the present inventors applied a liquid crystal substance composed of a polyhydric alcohol and an amphiphilic substance in the oil phase to form a coating film. Since a rigid structure of liquid crystal is formed in the film, the wax can be reduced as compared with the conventional one, and the transparency of the decorative film is improved. Furthermore, the presence of a polyhydric alcohol and an amphiphilic substance that are easily miscible with water during the formation of a decorative film in the water-resistant coating prevents the film from being partially peeled off by perspiration. It was found that it can be removed by applying force and does not bleed over time, and the present invention has been completed. Furthermore, the curl effect is imparted to the wrinkles, but the formed decorative film has flexibility, so that the wrinkles are not hard and a flexible finish can be obtained.

  In other words, the present invention has a long-lasting effect on tears and sweat by blending a liquid crystal composed of a polyhydric alcohol and an amphiphilic substance in the oil phase, but the cosmetic film can be easily formed with water or warm water. Further, the present invention relates to an oil-in-water eye makeup cosmetic that can be applied to the skin and that can provide a uniform transparent makeup film that does not bleed over time.

  The oil-in-water type eye makeup cosmetic of the present invention has a long-lasting effect on tears and sweat, but the makeup film can be easily removed with water or warm water, and a uniform makeup with a transparent feeling. A film is obtained and does not bleed over time.

Hereinafter, the present invention will be described in detail.
The liquid crystal used in the oil-in-water type eye makeup cosmetic of the present invention is formed of a polyhydric alcohol and an amphiphilic substance, and the shape thereof is layered, hexagonal, rod-shaped, vesicular structure or a mixture thereof. Any of these may be used. As a method for confirming the liquid crystal, for example, when a polarizing microscope is used, there is a method of viewing identifiable birefringence such as flat layered birefringence.

The polyhydric alcohol forming the liquid crystal used in the present invention is a polyhydric alcohol having a saturated or unsaturated linear or branched chain as long as it is a polyhydric alcohol that can be used in ordinary cosmetics and can form liquid crystals. Can be used, specifically 1,3-butylene glycol, 1,4-butylene glycol, 1,2-pentylene glycol, 1,6-hexamethylene glycol, propylene glycol, dipropylene glycol , Glycerin, diglycerin, triglycerin, tetraglycerin and the like are exemplified, and one or more of these can be used. Among these, butylene glycol, pentylene glycol, and glycerin are preferable from the viewpoint of easy removal of the decorative film.
These polyhydric alcohols are preferably 5 to 95% by mass (hereinafter simply referred to as “%”) in the liquid crystal, more preferably 20 to 90%.
Moreover, these polyhydric alcohols may be blended in the outer water phase of the oil-in-water type eye makeup cosmetic of the present invention in addition to the liquid crystal. The polyhydric alcohols blended in the oil phase and the water phase may be the same or different, and one or more can be used.

As the amphiphilic substance forming the liquid crystal used in the present invention, any substance can be used as long as it can form both a hydrophilic group and a lipophilic group in the molecule and form a liquid crystal with a polyhydric alcohol. Can also be used.
If it is normally used for cosmetics, it will not restrict | limit in particular, Any thing can be used. Specifically, selected from lauroyl glutamate, stearoyl glutamate, polyoxyethylene-modified beeswax, macadamian nut fatty acid cholesteryl, lanolin fatty acid cholesteryl, macadamian nut fatty acid phytosteryl, dipentaerythritol fatty acid ester, sucrose fatty acid ester Is preferable in terms of preventing bleeding. For example, commercially available products of lauroyl glutamate include AMITER LG-1600, AMITER LG-OD (H), AMITER LGS-5 (H) (manufactured by Nippon Emulsion Co., Ltd.), and stearoyl glutamate esters as AMITER SG-2000 ( As a commercial product of polyoxyethylene modified beeswax (manufactured by Nippon Emulsion Co., Ltd.), Lisolex BW400 (manufactured by Higher Alcohol Industry Co., Ltd.), as a commercial product of macadamian nut fatty acid cholesteryl, YOFCO MAC (manufactured by Nippon Seika Co., Ltd.), lanolin fatty acid cholesteryl YOFCO CLE-S, YOFCO CLE-H (manufactured by Nippon Seika Co., Ltd.) as products, and YOFCO MAS (manufactured by Nippon Seika Co., Ltd.), dipentaerythritol fat as macadamian nut fatty acid phytosteryl as commercial products Commercially available esters include Cosmol 168AR, Cosmol 168E, Cosmol 168M (Nisshin Oilio Group), and commercially available sucrose fatty acid esters include DK Ester S-L160, Sugar Wax A-10E, Sugar Wax S-10E ( (Daiichi Kogyo Seiyaku Co., Ltd.) and the like. Among these, solid or semi-solid ones are preferable. These amphiphiles can be used alone or in combination of two or more as required.
These amphiphilic substances are preferably 5 to 95% in the liquid crystal, more preferably 10 to 80%.

  The liquid crystal formed with the polyhydric alcohol and the amphiphilic substance of the present invention is blended in the oil phase, preferably 1 to 10%, more preferably 3 to 8% in the cosmetic. Within this range, it is possible to obtain an oil-in-water eye makeup cosmetic that can be easily removed with water or warm water without bleed over time, with a uniform makeup film that has excellent makeup and is transparent. Can do.

  In addition to the above essential components, the oil-in-water makeup cosmetic of the present invention requires water in order to obtain an oil-in-water dosage form. Also, a film-forming component, other oily components, and surface activity Agents and powders are blended.

The film-forming component can be blended in either the inner oil phase or the outer water phase, and is not particularly limited as long as it forms a film when a cosmetic is applied, and any resin component, polymer emulsion, etc. Are also used. Specifically, oil-soluble resin components include terpenic acid resins such as rosin acid pentaerythritol, trimethylsiloxysilicic acid, and candelilla resin (where candelilla resin is separated from candelilla wax with an organic solvent. The resin content obtained by extraction is such that the resin content is preferably 65% or more, more preferably 85% or more.), Alkyl acrylate / dimethicone acrylate copolymer, polyvinyl acetate Resin, polyvinyl isobutyl ether, polyisobutylene, and the like, and one or more of them can be used.
The polymer emulsion is a polymer compound dispersed in an aqueous solvent. Examples of the film-forming polymer emulsion include (meth) alkyl acrylate copolymer emulsion, (meth) acrylic acid / (meth) Alkyl acrylate copolymer emulsion, (meth) alkyl acrylate / styrene copolymer emulsion, vinyl acetate polymer emulsion, vinyl acetate-containing copolymer emulsion, vinyl pyrrolidone / styrene copolymer emulsion, silicone-containing (co) heavy A coalescence emulsion etc. are mentioned, These can use 1 type (s) or 2 or more types.
Examples of the water-soluble resin component include polyvinyl alcohol, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, and the like, and one or more of them can be used.
Among these film-forming components, rosin acid resin, trimethylsiloxysilicic acid, alkyl acrylate / dimethicone acrylate copolymer, and candelilla resin are used as oil-soluble resin components, and acrylic acid esters are used as polymer emulsions. Polymer emulsions and vinyl acetate polymer emulsions are preferred for cosmetics for vases because the cosmetic effect appears remarkably.

  The oily components include hydrocarbons, fats and oils, waxes, oils, waxes, waxes, oils, vegetable oils, synthetic oils and other solid oils, semi-solid oils, liquid oils, volatile oils, etc. , Hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyethylene wax, ethylene / propylene copolymer, paraffin wax, montan wax, Fischer-Tropsch wax, polyisobutylene, polybutene, ceresin wax, ozokerite wax, mole, Oils such as olive oil, castor oil, mink oil, macadamian nut oil, waxes such as beeswax, gay wax, carnauba wax, candelilla wax, jojoba oil, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, Glyceryl tribehenate, cetyl 2-ethylhexanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, neopentyl dioctanoate Esters such as recall, malic acid diisostearyl, stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid and other fatty acids, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, Higher alcohols such as behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, highly polymerized methylphenylpolysiloxane, partially crosslinked organopolysiloxane, partially crosslinked polyether modified methyl Polysiloxane, stearyl-modified organopolysiloxane, oleyl-modified organopolysiloxane, behenyl-modified organopolysiloxane, high degree of polymerization dimethylpoly Silicone such as loxane, alkoxy-modified organopolysiloxane, fluorine-modified organopolysiloxane, fluorine-based oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, etc. Examples include lanolin derivatives, starch fatty acid esters, aluminum isostearate, and oily gelling agents such as 12-hydroxystearic acid. These can be used alone or in combination. The oil component is preferably a solid, semi-solid or volatile oil component.

As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant Etc.
Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone And the like.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.

  As a powder component, if it is a powder used as a powder generally used in cosmetics, a spherical shape, a plate shape, a needle-like shape, a haze shape, a fine particle, a particle size such as a pigment class, a porous material, It is not particularly limited by the particle structure such as non-porous, and examples thereof include inorganic powders, glitter powders, organic powders, pigment powders, metal powders, and composite powders. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, etc. Colored inorganic pigments, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide White body powders such as zirconium oxide, antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, Titanium oxide coated mica, titanium oxide coated bismuth oxychloride Iron oxide mica titanium, bitumen treated mica titanium, carmine treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc. Bright powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, polypropylene resin, silicone Resin, organic polymer resin powder such as urethane resin, organic low molecular weight powder such as zinc stearate and N-acyl lysine, natural organic powder such as silk powder and cellulose powder, Red No. 201, Red 202 , Red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, red 3, red 104, red 106, orange 205, yellow 4 , Yellow 5, green 3, blue 1, etc. zirconium, barium or aluminum lake or other organic pigment powders or metal powders such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide Coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. These powders can be used alone or in combination of two or more. You may use what was compounded. Further, these powders may be subjected to a surface treatment by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, an oil or fat, a hydrocarbon or the like.

  In addition, the oil-in-water makeup cosmetics of the present invention usually contain components such as fibers, water-soluble polymers and sugars, aqueous components such as humectants, antioxidants, ultraviolet absorbers, and ambers. An inhibitor, an antifoaming agent, a cosmetic ingredient, an antiseptic, a fragrance, and the like can be appropriately blended within a range that does not impair the effects of the present invention.

  The fiber is not particularly limited as long as it is generally used in cosmetics, and synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate human silk, and the like. Can be mentioned. These fibers are used after being surface-treated as necessary. Examples of the surface treatment agent include a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, and surfactant.

As the aqueous component, any component that is soluble in water may be used, and examples thereof include plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, and rose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan and other semi-synthetic compounds such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer and sodium polyacrylate can be mentioned. Other moisturizing agents such as protein, mucopolysaccharide, collagen, elastin, keratin and the like can also be contained.
Examples of the antioxidant include α-tocopherol and ascorbic acid. Examples of the beauty component include vitamins, anti-inflammatory agents and herbal medicines. Examples of the preservative include paraoxybenzoic acid ester and phenoxyethanol.
Examples of the ultraviolet absorber include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like.

  Examples of the oil-in-water eye makeup cosmetics of the present invention include mascara, eye color, eyeliner, eyebrow and the like, and can take a creamy or milky form. It is preferable to use mascara, which is a vaginal cosmetic, because the effects of the present invention can be remarkably obtained.

  The oil-in-water eye makeup cosmetics of the present invention, for example, directly add and disperse the oil phase in the liquid crystal to obtain a gel-like liquid crystal oil-in-water emulsion, and then add the remaining water phase to form an oil-in-water emulsion. It can be manufactured by the method.

  EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.

Examples 1 to 5 and Comparative Examples 1 to 3: Mascara (oil-in-water cosmetic for cosmetics)
A mascara having the formulation shown in Table 1 below was prepared, and evaluated for the ease of makeup removal, the persistence of the makeup effect, the uniformity of the makeup film, the transparency of the makeup film, and the lack of bleeding over time by the following methods. The results are also shown in Table 1.

* 1: YOFCO MAS (Nippon Seika Co., Ltd.)
* 2: Candelilla resin E-1 (Nippon Natural Products)
* 3: Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 4: PLEXTOL B-500 (50% solid content) (manufactured by Polymer Latex)
(Production method)
A. Components (1) to (3) are heated and dissolved at 80 ° C. and mixed.
B. Ingredients (4) to (10) are dissolved by heating at 90 ° C., mixed uniformly, and A is added.
C. Components (11) to (19) are heated at 80 ° C. and mixed uniformly.
D. Add C to B and emulsify at 80 ° C.
E. D was cooled to room temperature and filled into a container to obtain mascara (oil-in-water cosmetic for cosmetics).

(Evaluation methods)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Ease of makeup removal b. Persistence of makeup effect c. Uniformity of the cosmetic film d. Transparency of cosmetic film e. No blurring over time Each sample is tested by 20 specialist panels, and each panel is rated according to the following 7 absolute ratings and given a score. Was calculated and determined according to the following four-step criteria.
In addition, about the ease of removal of the makeup | decoration of a, it evaluated whether it could remove easily by removing a wrinkle with water, using a tap water.
In addition, regarding the persistence of the makeup effect of b and the non-bleeding of e over time, each sample was applied to the heel, and the panel was allowed to have a normal life. The degree of bleeding was evaluated. The uniformity of the decorative film of c and the transparency of the decorative film of d were evaluated immediately after each sample was applied to the bag.
In addition, regarding the ease of removing the makeup of a, in addition to the evaluation of the use test, Example 1 and Comparative Example 3 were subjected to the degree of removal when the remover was used in the following removal test.

Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad Four-step criteria (judgment): (Average score)
◎: More than 5 points: Very good ○: More than 3 points, 5 points or less: Good △: More than 1 point, 3 points or less: Slightly poor ×: 1 point or less: Bad

(Removal test)
In Example 1 and Comparative Example 3, a coating film was formed on a glass plate with an applicator having a film thickness of 32 mil (about 0.8 mm), 2.5 mL of the following remover was dropped on the coating film, and cotton was placed thereon. . After leaving for 5 minutes, the coated film was removed by moving in parallel with the coated surface while pressing the cotton. The state of the removed portion was evaluated and determined according to the following criteria. In this test, the area of the dropped part was set to 100, and the ratio of the area of the part that could be completely removed was determined and used as a criterion.
(Criteria)
(Judgment): (Removal area): (Evaluation)
A: 90% or more: Familiarity with remover is good and can be easily removed.
○: 80% or more and less than 90%: The familiarity with the remover can be removed well.
Δ: 60% or more and less than 80%: It fits with the remover but is difficult to remove.
X: Less than 60%: It is difficult to remove.

Removal test remover (component) (%)
(1) 1,3-butylene glycol 20
(2) Liquid paraffin 10
(3) Cyclopentasiloxane 10
(4) Preservative appropriate amount (5) remaining amount of purified water (production method)
A. Components (1) to (4) are dissolved by heating at 70 ° C.
B. Add component (5) and mix uniformly.
C. A and B are filled into a container to obtain a removal test remover.

As is apparent from the results in Table 1, the mascara (oil-in-water type cosmetics for cosmetics) of Examples 1 to 5 of the present invention is more cosmetic than the mascara (comparable product for oil-in-water cosmetics) of Comparative Examples 1-3. It was excellent in all of the ease of dropping, the persistence of the makeup effect, the uniformity of the makeup film, the transparency of the makeup film, and the lack of bleeding over time. In addition to the above evaluation items, the mascara of the present invention has curling power of wrinkles, but the decorative film is not hard and the wrinkles can obtain a flexible finish.
In contrast, Comparative Example 1 in which no polyhydric alcohol was blended in the oil phase was particularly inferior in the ease of makeup removal and the sustainability of the makeup effect. Further, Comparative Example 2 in which no amphiphilic substance was blended was particularly inferior in the ease of makeup removal and the uniformity of the cosmetic film. In Comparative Example 3 in which the wax was increased instead of the liquid crystal, the ease of removing the makeup and the transparency of the decorative film were inferior.
Moreover, when the removal test by a remover was conducted, Example 1 was able to remove 90% or more, and it was judged as ◎, whereas Comparative Example 3 used a remover in the same manner as the use test using water a. Was difficult to remove, and it was judged as x.

Example 6: Oil-in-water emulsion type eyeliner (component) (%)
(1) Stearic acid 1
(2) Cetanol 1
(3) Glycerol monostearate 0.5
(4) Ethylene glycol monostearate 0.5
(5) Polyoxyethylene-modified beeswax * 5 4
(6) Glycerin 1
(7) Ultramarine 1
(8) Red No. 202 1
(9) Purified water remaining amount (10) 1,3-butylene glycol 5
(11) Sodium hydroxide 0.2
(12) Hydrolyzed conchiolin solution 0.1
(13) Methyl paraoxybenzoate 0.1
(14) Vinylpyrrolidone / vinyl acetate copolymer emulsion * 6 10
(15) Mica titanium 10
(16) Fragrance appropriate amount * 5: Lisolex BW400 (manufactured by Higher Alcohol Industry)
* 6: PVP / VAE-735 (solid content 50%) (made by ISP Van Dyke)
(Manufacturing method)
A. Components (1) to (6) are dissolved by heating at 90 ° C., and (7) and (8) are added and mixed uniformly.
B. Components (9) to (16) are dissolved by heating at 80 ° C. and mixed uniformly.
C. Add B to A and emulsify at 80 ° C.
D. Fill the container to make the product.
The oil-in-water emulsion type eyeliner obtained as described above is excellent in terms of ease of makeup removal, durability of makeup effect, uniformity of makeup film, transparency of makeup film, and no bleeding over time. It was.

Example 7: Oil-in-water emulsified eye shadow (component) (%)
(1) Stearic acid 1
(2) Cetanol 1
(3) Polyoxyethylene monooleate (20E.O.)
Sorbitan 0.5
(4) Sorbitan sesquioleate 0.5
(5) Glycerol monostearate 0.5
(6) Rosin acid pentaerythritol 10
(7) Lauroyl glutamate dioctyldodecyl * 7 1
(8) 1,3-butylene glycol 5
(9) Yellow No. 1 1
(10) Red No. 202 1
(11) Purified water remaining amount (12) Dipropylene glycol 5
(13) Carboxyvinyl polymer 0.1
(14) Triethanolamine 0.2
(15) Cosmetic ingredients (camomile extract) 0.1
(16) Preservative (phenoxyethanol) 0.1
(17) Alkyl acrylate copolymer emulsion * 4 10
(18) Titanium oxide-treated synthetic phlogopite 10
(19) Polyethylene terephthalate
Aluminum epoxy laminated powder 1
(20) Polyethylene terephthalate
Polyolefin laminated film powder 1
* 7: AMITER LG-OD (H) (Nippon Emulsion Co., Ltd.)
(Production method)
A. Components (1) to (8) are dissolved by heating at 90 ° C., and (9) and (10) are added and mixed uniformly.
B. Components (11) to (20) are heated and dissolved at 80 ° C. and mixed uniformly.
C. Add B to A and emulsify at 80 ° C.
D. Fill the container to make the product.
The oil-in-water emulsified eye shadow obtained as described above is excellent in terms of ease of makeup removal, durability of makeup effect, uniformity of makeup film, transparency of makeup film, and no blur over time. It was.

Example 8: Oil-in-water emulsified eyebrow (component) (%)
(1) Stearic acid 3
(2) Cetanol 2
(3) Glycerol monostearate 0.5
(4) Ethylene glycol monostearate 0.5
(5) Dipropylene glycol 4
(6) Sucrose fatty acid ester * 3 1
(7) Black iron oxide 1
(8) Purified water remaining amount (9) 1,3-butylene glycol 5
(10) Sodium hydroxide 0.2
(12) Royal jelly extract 0.1
(13) Methyl paraoxybenzoate 0.1
(14) Polyvinyl acetate emulsion * 8 10
* 8: Viniblanc GV-5651 (solid content 36%) (manufactured by Nissin Chemical Industry Co., Ltd.)
(Production method)
A. Components (1) to (6) are heated and dissolved at 90 ° C., and (7) is added and mixed uniformly.
B. Components (8) to (14) are heated and dissolved at 80 ° C. and mixed uniformly.
C. Add B to A and emulsify at 80 ° C.
D. Fill the container to make the product.
The oil-in-water emulsified eyebrow obtained as described above is excellent in terms of ease of makeup removal, durability of makeup effect, uniformity of makeup film, transparency of makeup film, and no bleeding over time. It was a thing. Furthermore, the eyebrows did not become stiff and the finish was flexible.

Example 9: Oil-in-water emulsified mascara (component) (%)
(1) Stearic acid 2
(2) Cetanol 3
(3) Carnauba wax 1
(4) Beeswax 1
(5) Glycerol monostearate 1
(6) Polyoxyethylene monooleate (20E.O.)
Sorbitan 1
(7) Sorbitan sesquioleate 0.5
(8) 1,3-butylene glycol 4
(9) Sucrose fatty acid ester * 3 1
(10) Macadamian nut fatty acid phytosteryl * 1 0.5
(11) Black iron oxide 1
(12) Purified water remaining amount (13) 1,3-butylene glycol 5
(14) Triethanolamine 1.2
(15) Royal jelly extract 0.1
(16) Methyl paraoxybenzoate 0.1
(17) Alkyl acrylate copolymer emulsion * 4 27
(Production method)
A. Components (1) to (7) are heated and dissolved at 90 ° C. and mixed.
B. Ingredients (8) to (10) are heated and dissolved at 80 ° C., mixed uniformly, and added to A.
C. Components (11) to (17) are heated at 80 ° C. and mixed uniformly.
D. Add C to B and emulsify at 80 ° C.
E. D was cooled to room temperature and filled into a container to obtain an oil-in-water mascara.
The oil-in-water emulsified mascara obtained as described above is excellent in terms of ease of makeup removal, durability of the makeup effect, uniformity of the makeup film, transparency of the makeup film, and no bleeding over time. It was a thing. Furthermore, the curl was excellent in curling power, and the wrinkle did not become hard and a flexible finish was obtained.

Claims (6)

  1.   An oil-in-water eye makeup cosmetic comprising a liquid crystal composed of a polyhydric alcohol and an amphiphilic substance in an oil phase.
  2.   The oil-in-water eye makeup cosmetic according to claim 1, further comprising a film-forming resin.
  3.   The oil-in-water eye makeup cosmetic according to claim 1 or 2, wherein a polyhydric alcohol is blended in both the water phase and the oil phase.
  4.   The amphiphile is selected from lauroyl glutamate, stearoyl glutamate, polyoxyethylene-modified beeswax, macadamian nut fatty acid cholesteryl, lanolin fatty acid cholesteryl, macadamian nut fatty acid phytosteryl, dipentaerythritol fatty acid ester, sucrose fatty acid ester The oil-in-water eye makeup cosmetic according to any one of claims 1 to 3, wherein the cosmetic is one or two or more and is solid or semi-solid.
  5.   The oil-in-water eye makeup cosmetic according to any one of claims 1 to 4, wherein the liquid crystal in the oil phase is incorporated in the cosmetic in an amount of 1 to 10% by mass.
  6.   The oil-in-water eye makeup cosmetic according to any one of claims 1 to 5, wherein the oil-in-water eye makeup cosmetic is an oil-in-water cosmetic.
JP2006087180A 2005-03-29 2006-03-28 Oil-in-water eye makeup cosmetic emulsion Pending JP2006306849A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2005096554 2005-03-29
JP2006087180A JP2006306849A (en) 2005-03-29 2006-03-28 Oil-in-water eye makeup cosmetic emulsion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006087180A JP2006306849A (en) 2005-03-29 2006-03-28 Oil-in-water eye makeup cosmetic emulsion

Publications (1)

Publication Number Publication Date
JP2006306849A true JP2006306849A (en) 2006-11-09

Family

ID=37474141

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006087180A Pending JP2006306849A (en) 2005-03-29 2006-03-28 Oil-in-water eye makeup cosmetic emulsion

Country Status (1)

Country Link
JP (1) JP2006306849A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010241729A (en) * 2009-04-06 2010-10-28 Lion Corp Process for producing skin cosmetic
JP2011526902A (en) * 2008-06-30 2011-10-20 イーエルシー マネージメント エルエルシー Re-applicable mascara composition
JP2013544246A (en) * 2010-11-22 2013-12-12 ▲蘇▼州元素集▲化▼学工▲業▼有限公司Suzhou Eleco Chemical Industry Co., Ltd. Dense cleaning composition
WO2014058048A1 (en) 2012-10-12 2014-04-17 株式会社 資生堂 Makeup base cosmetic for skin removable with warm water
KR101472315B1 (en) * 2012-09-05 2014-12-12 코스맥스 주식회사 Eye liner of cream form cosmetic composition comprising hectorit and fine grinding pigment
JP2015074646A (en) * 2013-10-11 2015-04-20 株式会社コーセー Oil-in-water emulsion cosmetic
CN106102710A (en) * 2014-04-17 2016-11-09 雅芳产品公司 The mascara of incremental contribution
KR20170033322A (en) 2014-07-28 2017-03-24 가부시키가이샤 시세이도 Oily cosmetic

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011526902A (en) * 2008-06-30 2011-10-20 イーエルシー マネージメント エルエルシー Re-applicable mascara composition
JP2010241729A (en) * 2009-04-06 2010-10-28 Lion Corp Process for producing skin cosmetic
US9326928B2 (en) 2010-11-22 2016-05-03 Suzhou Eleco Chemical Industry CO., Ltd. Thick cleaning composition
JP2013544246A (en) * 2010-11-22 2013-12-12 ▲蘇▼州元素集▲化▼学工▲業▼有限公司Suzhou Eleco Chemical Industry Co., Ltd. Dense cleaning composition
KR101472315B1 (en) * 2012-09-05 2014-12-12 코스맥스 주식회사 Eye liner of cream form cosmetic composition comprising hectorit and fine grinding pigment
TWI602578B (en) * 2012-10-12 2017-10-21 資生堂股份有限公司 Skin underlayer cosmetic falling off with warm water
WO2014058048A1 (en) 2012-10-12 2014-04-17 株式会社 資生堂 Makeup base cosmetic for skin removable with warm water
US9968542B2 (en) 2012-10-12 2018-05-15 Shiseido Company, Ltd. Makeup base for skin removable with warm water
EP2907499A4 (en) * 2012-10-12 2016-04-06 Shiseido Co Ltd Makeup base cosmetic for skin removable with warm water
RU2635538C2 (en) * 2012-10-12 2017-11-13 Шисейдо Компани, Лтд. Cosmetic basis for skin make-up, removable by warm water
JPWO2014058048A1 (en) * 2012-10-12 2016-09-05 株式会社 資生堂 Skin foundation cosmetics that fall with warm water
JP2015074646A (en) * 2013-10-11 2015-04-20 株式会社コーセー Oil-in-water emulsion cosmetic
EP3131530A4 (en) * 2014-04-17 2017-11-01 Avon Products, Inc. Volumizing mascara compositions
CN106102710A (en) * 2014-04-17 2016-11-09 雅芳产品公司 The mascara of incremental contribution
US10532010B2 (en) 2014-04-17 2020-01-14 Avon Products, Inc. Volumizing mascara compositions
KR20170033322A (en) 2014-07-28 2017-03-24 가부시키가이샤 시세이도 Oily cosmetic

Similar Documents

Publication Publication Date Title
EP1184028B2 (en) Non-transfer cosmetic composition comprising a non-volatile silicone, a non-volatile hydrocarbon oil and an inert particulate phase
EP1112734B1 (en) Non-transfer cosmetic composition comprising a non-volatile silicon compound, and a non-volatile hydrocarbon oil incompatible with the silicone compound
JP3388194B2 (en) Transfer-free cosmetic composition comprising a non-film-forming polymer-particle dispersion in a partially non-volatile liquid fatty phase
DE60012614T2 (en) Anhydrous make-up or skin care products containing fibers and polyols
CN1309365C (en) Transfer-resistant composition structured in rigid form by polymer
DE69831643T2 (en) Abrasion-resistant cosmetic composition comprising a plastic dispersion in a liquid oil phase and a fat-soluble polymer
ES2348234T3 (en) Bicapa cosmetic product, its uses and makeup kit that includes this product.
DE69918030T2 (en) Non-transfer cosmetic compositions containing a dispersion of polymer particles and a special rheology aid
CA2562484C (en) Long-wearing cosmetic compositions with improved shine
CA2264976C (en) Topical composition containing an acid ester or fatty alcohol branched into c24 to c28
CA2301812C (en) Make-up or care composition containing an oxyalkylene group cross-linked organopolysiloxane
EP1470811B1 (en) Composition comprising a dispersion of polymer particles and an ester of a carboxylic acid with a polyol for pigment dispersion
CN104703579B (en) The cosmetic composition for coating keratin fiber comprising hard wax particle
US20080233158A1 (en) Two-coat makeup product, its uses, and makeup kit comprising the product
ES2297346T3 (en) Bicapa cosmetic product, its use and makeup kit containing such product.
CN100427060C (en) Oil-based cosmetic preparation
US20040228890A1 (en) Two-coat cosmetic product, its uses, and makeup kit including the product
JP4563854B2 (en) Oily cosmetics
US20040234612A1 (en) Cosmetic composition comprising at least one polymer particle dispersed in at least one liquid fatty phase and at least one compound plasticizing the polymer
JP5144896B2 (en) Lip cosmetics
AU2005240099A1 (en) Long-wearing cosmetic compositions
FR2873030A1 (en) Cosmetic bicouche product comprising a silicone polymer
JP2003535883A (en) Solid emulsion containing liquid fatty phase structured with polymer
WO2007006536A1 (en) Water-free cosmetic preparation
JP2002128639A (en) Cosmetic