JP5947065B2 - Oily salmon cosmetic - Google Patents

Description

  The present invention relates to an oil-based cosmetic for cosmetics, and more specifically, by blending a high-viscosity dimethiconol, N-acyl lysine and a film-forming organic silicone resin, it has a smooth spread and excellent volume effect. The present invention relates to a cosmetic for oily wrinkles that has a uniform gloss and a long lasting makeup.

  Cosmetics for wrinkles such as mascara are cosmetics that have effects such as making the wrinkles look longer (long effect), making the wrinkles thicker (volume effect), curling the wrinkles and keeping them for a long time (curl keeping effect). However, in addition to these conventional effects, there is a demand for usability such as smooth extension and easy application, and finished quality such as a beautiful film and a glossy feeling.

  There are various types of vaginal cosmetics (oil-in-water type, water-in-oil type, oil-based type, water-based type, etc.) depending on the feeling of use and functions. Even in the case of oily wrinkle cosmetics, various studies have been made in order to produce a volume effect, a glossy feeling, and the like while improving usability and a long-lasting effect. For example, by blending a confetti-shaped silicone resin powder, a volatile oil, and an oily gelling agent, the volume is given to the cocoon, the transparency of the base material is high, and the original color is not impaired (see Patent Document 1) ), A pigment, a candelilla resin, a dextrin fatty acid ester, a specific 1,2-alkanediol, a technique for enhancing curl retention and volume effect of cocoons (see Patent Document 2), and a specific rosin ester compound A technique for obtaining a uniform and beautiful decorative film by blending an oil-soluble resin and a volatile oil (see Patent Document 3) has also been studied.

  On the other hand, organosilicone resins are often used in vaginal cosmetics because they are easy to control the hardness of the coating and have little stickiness. was difficult. In view of this, a technique for improving the longevity of cosmetics without transferring color by combining an organosiloxane resin, a fluid diorganopolysiloxane polymer, and a volatile carrier has been studied (see Patent Document 4).

JP 2009-149525 A JP 2008-63259 A JP 2009-1114099 A JP 2000-501074 gazette

However, although the techniques of Patent Documents 1 to 3 are excellent in volume effect, there are cases where the usability such as smooth extension and spread is lacking, and since the uniformity of the film is inferior, the gloss feeling is not satisfactory. Further, according to the technique of Patent Document 4, depending on the viscosity and structure of the diorganopolysiloxane polymer, the stickiness is high and the usability is poor, the adhesiveness to wrinkles is weak, and the production of the volume effect is difficult.
Therefore, there has been a demand for a vaginal cosmetic that is excellent in volume effect, has a glossy feeling with a uniform cosmetic film, and has a long-lasting makeup while being light and easy to use. An object of the present invention is to provide such a cosmetic for oily wrinkles.

  As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that in oil-based cosmetics, dimethiconol, N-acyllysine and a film-forming organic material having a viscosity at 25 ° C. of not less than 100,000 mPa · s. It has been found that the above problems can be solved by blending with a silicone resin, and the present invention has been completed.

That is, the present invention
(1) The following components (A) to (C);
(A) A cosmetic for oil-based candy characterized by blending dimethiconol (B) N-acyl lysine (C) film-forming organic silicone resin having a viscosity at 25 ° C. of 100,000 mPa · s or more,
(2) The amount of the component (A) is 0.1 to 5% by mass, the amount of the component (B) is 0.1 to 5% by mass, and the amount of the component (C) is 10 to 25% by mass. % Cosmetics for oily wrinkles according to (1),
(3) The blending mass ratio (C) / (total oil-soluble resin component) between the component (C) and the total oil-soluble resin component in the cosmetic is 0.5 to 1 (1) Or it is related with the cosmetics for oil-based wrinkles as described in (2).

  The oily wrinkle cosmetic of the present invention is excellent in smoothness at the time of application, and is excellent in volume effect, glossiness and long-lasting makeup.

Hereinafter, the present invention will be described in detail.
The component (A) dimethiconol used in the present invention is a gum-like highly polymerized dimethicone having both ends modified with hydroxyl groups and having no crosslinked structure. Compared to highly polymerized dimethicone having no hydroxyl group, it has a good adhesion to wrinkles, and is a component capable of effectively obtaining a smooth feeling of use peculiar to a silicone compound because the modified sites are at both ends. In addition, if the viscosity at 25 ° C. is 100,000 mPa · s or more, the effect is sufficiently exerted, but the range of 500,000 mPa · s to 30 million mPa · s is preferable, particularly 1,000,000 mPa · s. A range of ˜20 million mPa · s is preferred.

The viscosity of component (A) can be calculated as follows.
A toluene solution of dimethiconol having a concentration of 1 g / 100 mL is prepared, and the specific viscosity ηsp (25 ° C.) is determined by the following formula (1). Next, the intrinsic viscosity [η] is obtained by substituting into the Huggins relational expression shown in the following formula (2). Furthermore, [η] is represented by the following formula (3). Substituting it into the Kololov equation, the molecular weight M is determined. Lastly, M is an A.I. J. et al. Substituting into the Barry equation, the viscosity η of dimethiconol is determined.
ηsp = (η / η0) −1 (1)
(However, η0: the viscosity of toluene, η: the viscosity of the solution was measured in accordance with the cosmetic raw material standard general test method viscosity measurement method No. 1)
ηsp = [η] + K ′ [η] ² (2)
(However, the K ′: Huggins constant is the one described in Nakamuta, Nikka, 77 588 [1956].)
[Η] = 0.215 × 10 ⁻⁴ M ^0.65 (3)
log η = 1.00 + 0.0123 M ^0.5 (4)

  Commercially available products of component (A) include those dissolved in silicone oil, Dow Corning 1501 Fluid (15% decamethylcyclopentasiloxane solution), Dow Corning 1503 Fluid (12% dimethylpolysiloxane solution) (any Also manufactured by Toray Dow Corning Silicone Co., Ltd.), XF49-C2520 (15% decamethylcyclopentasiloxane solution) (made by Momentive Performance Materials Japan GK), hydrocarbon oil, XF49-C2497 (35% hydrogenated polyisobutene solution), XF49-C2070 (20% hydrogenated polyisobutene solution) (both manufactured by Momentive Performance Materials Japan GK), etc. It can be used in combination on.

  Although the compounding quantity of the component (A) in this invention is not specifically limited, The range of 0.1-5 mass% (henceforth "%" only) is preferable, and also the range of 0.3-3% Is preferred. If it is this range, it will be excellent in smooth extension spreading, and the good thing excellent in volume effect, glossiness, and long-lasting makeup can be obtained.

  Component (B) N-acyl lysine used in the present invention is an acyl lysine powder represented by the following general formulas (1) to (3). In addition, the adhesiveness of the cosmetic can be increased to give a volume effect without damaging the gloss and the makeup.

(In the general formulas (1) and (2), RCO represents an aliphatic acyl group having 8 to 22 carbon atoms. In the general formula (3), R'CO and R " CO represents an aliphatic acyl group having 1 to 22 carbon atoms and 9 to 44 in total.

  In the general formulas (1) and (2), for example, after preliminarily protecting the α-position or ε-position amino group of lysine, a fatty acid chloride is dropped into an alkaline aqueous solution of lysine to selectively select the α-position. Is obtained by acylating the ε position. Moreover, General formula (3) is obtained by acylating with a fatty-acid chloride, for example, without protecting the amino group of lysine. By selecting an acyl group, it is possible to adjust the hydrophilicity, hydrophobicity, adhesion, etc. of N-acyllysine.

Examples of N-acyl lysine of component (B) include Nα-hexanoyl lysine, Nα-oleyl lysine, Nα-lauroyl lysine, Nα-myristoyl lysine, Nα-stearoyl lysine, Nε-lauroyl lysine, Nε-stearoyl lysine, Nα. -N (epsilon) -dilauroyl lysine etc. are mentioned, These can be used 1 type, or 2 or more types.
The shape of the N-acyl lysine of component (B) is preferably flaky or plate-like, and the average particle size is preferably 1 to 30 μm from the viewpoint of a feeling of close contact with the skin. Examples of such component (B) include Nα-lauroyllysine commercially available as Amihope LL (manufactured by Ajinomoto Co., Inc.).

  Although the compounding quantity of the component (B) in this invention is not specifically limited, 0.1 to 5% is preferable and 0.5 to 3% is especially preferable. When used in this range, a smooth stretch spread and volume effect can be obtained, and a cosmetic with excellent gloss can be obtained.

The organic silicone resin of component (C) used in the present invention is soluble in an oil such as silicone oil or volatile hydrocarbon oil, and is usually used in cosmetics and has a film-forming property. Any of these can be used, for example, trimethylsiloxysilicic acid, polymethylsilsesquioxane, acrylic-silicone graft copolymer, long-chain alkyl-modified acrylic-silicone graft copolymer, polyvinylpyrrolidone-modified methyl Polysiloxane etc. are mentioned, These can be used 1 type, or 2 or more types.
Specifically, as commercially available products of trimethylsiloxysilicic acid, KF-7312J (50% decamethylcyclopentasiloxane solution), KF-9021 (50% decamethylcyclopentasiloxane solution) are those dissolved in silicone oil. (All are manufactured by Shin-Etsu Chemical Co., Ltd.), SS4267 (35% dimethylpolysiloxane solution) (Momentive Performance Materials Japan GK), BY11-018 (30% decamethylcyclopentasiloxane solution) (Toray Dow) Corning Silicone Co., Ltd.). The acrylic-silicone graft copolymer is a radical copolymer of an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate. Commercially available products are those dissolved in a solvent, KP541 (60% isopropanol solution), KP545 (30% decamethylcyclopentasiloxane solution), KP575 (30% decamethylcyclopentasiloxane solution) (all manufactured by Shin-Etsu Chemical Co., Ltd.) ) And the like.

  Although the compounding quantity of the component (C) in this invention is not specifically limited, 10 to 30% is preferable as solid content, and 15 to 25% is especially preferable. If it is this range, it will be excellent in a volume effect and a glossy feeling, without impairing the curl effect, long effect, makeup lasting effect, etc. which the cosmetics for wrinkles originally have.

  In addition to the organosilicone resin of component (C), the oily wrinkle cosmetic of the present invention can be blended with other oil-soluble resins as necessary. The blending mass ratio (C) / (total oil-soluble resin component) with the total oil-soluble resin component is preferably 0.5 to 1, and more preferably 0.8 to 1. The other oil-soluble resin herein is not particularly limited as long as it can be used in cosmetics, but other than component (C), terpene resins such as candelilla resin and pentaerythritol rosin acid, polyvinyl isobutyl ether, etc. Examples thereof include hydrocarbon resins. By increasing the ratio of the organosilicone resin in the total oil-soluble resin component, a smoother feeling of spreading and spreading can be obtained, and if outside this range, a high volume effect can be obtained, but smooth spreading and spreading are possible. In some cases, it may be extremely inferior.

  In addition to the above-described components, the oily wrinkle cosmetic composition of the present invention is an oily component other than components (A) and (C) and component (B), as long as the effects of the present invention are not impaired. Other ingredients commonly used in cosmetics such as powder components, fibers, surfactants, UV absorbers, moisturizers, antioxidants, beauty ingredients, preservatives, anti-fading agents, and perfumes. Can do.

  As oil components, in addition to essential components (A) and (C), volatile oils, hydrocarbons, regardless of the origin of animal oils, vegetable oils, synthetic oils, and the properties of solid oils, semi-solid oils, liquid oils, etc. , Oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, oil-soluble resins, etc. . Among these, volatile oils are used as solvents for oily vaginal cosmetics, and specifically include hydrocarbon oils such as light liquid isoparaffin and isododecane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, and low polymerization dimethyl. Examples thereof include silicone oils such as polysiloxane and methyltrimethicone. Other oil components include hydrocarbons such as liquid paraffin, squalane, petrolatum, polybutene, hydrogenated polyisobutene, paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, Oils such as olive oil, castor oil, mink oil, macadamian nut oil, waxes such as beeswax, carnauba wax, candelilla wax, gallow, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyl myristate Dodecyl, glyceryl trioctanoate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L-glutamate di (cholesteryl)・ Behenyl octyldodecyl), esters such as jojoba oil, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl Alcohols, higher alcohols such as behenyl alcohol, high degree of polymerization dimethylpolysiloxane, methylphenylpolysiloxane, partially crosslinked organopolysiloxane, silicones such as fluorine-modified polysiloxane, perfluorodecane, perfluorooctane, perfluoropolysiloxane, etc. Fluorinated oils, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, dextrin fatty acid ester, sucrose fatty acid ester, 12 Hydroxystearic acid, starch fatty acid esters, aluminum isostearate, oily gelling agents such as calcium stearate.

  As the powder component, in addition to the essential component (B), a spherical shape, a plate shape, a needle shape, a particle shape such as a fumes, a fine particle, and a pigment grade, a particle structure such as a porous material and a nonporous material, etc. Without being limited, inorganic powders, glitter powders, organic powders, pigment powders, metal powders, composite powders and the like can be mentioned. Specific examples include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as yellow iron oxide, bengara, chromium oxide, chromium hydroxide, bitumen and ultramarine, muscovite, gold Mica, red mica, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicon oxide, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth, White body powder such as aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium oxide coated mica, titanium oxide coated bismuth oxychloride , Titanium oxide coated synthetic phlogopite, glass powder, acid Titanium-coated glass powder, iron oxide-coated glass powder, Bengala-coated mica titanium, Japanese monkey-coated mica titanium, carmine-coated mica titanium, carmine-conjugate-coated mica titanium, chromium oxide-coated mica titanium, bismuth oxychloride, fish scale foil, iron oxide-coated mica Organic pigment coated mica titanium, multilayer coated mica titanium, silicic acid / titanium oxide coated mica, Bengala coated silicic acid, titanium oxide coated silicic acid, titanium oxide coated aluminum oxide and other pearlescent agents and polyethylene terephthalate / aluminum / epoxy laminates Powder, glittering powders of laminating agent such as powder of polyethylene terephthalate / polyolefin laminated film, powder of polyethylene terephthalate / polymethyl methacrylate, polyamide resin, polyethylene resin, polyacrylic resin, polyester Fatty resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, organic polymer resin powder such as polypropylene resin, silicone resin and urethane resin, organic low resin such as zinc stearate Natural organic powders such as molecular powder, starch, silk powder, cellulose powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404 Organic dye powder such as yellow 401, red 3, yellow 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc. zirconium, barium or aluminum lake Organic pigment powder such as aluminum powder, metal powder such as aluminum powder, gold powder, silver powder, etc., fine titanium oxide coated mica titanium, fine zinc oxide coated cloud Examples include composite powders such as mother titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide. These powders can be used alone or in combination of two or more. You may use what you did. These powders are one or two of fluorine compounds, silicone compounds, metal soaps, lecithins, hydrogenated lecithins, collagens, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants and the like. Surface treatment may be performed using the above.

  The fiber is not particularly limited as long as it is generally used in cosmetics. For example, synthetic fibers such as nylon, polyester, and polypropylene, artificial fibers such as rayon, natural fibers such as cellulose, and half fibers such as acetate silk. Examples thereof include synthetic fibers and the like, or composite fibers of these. The length is not particularly limited, but generally 0.1 to 10 mm is preferable, and 0.3 to 7 mm is more preferably used. Generally, the thickness is preferably 0.1 to 20 tex (hereinafter simply referred to as “T”), more preferably 0.3 to 15T. These fibers can be used singly or in combination of different materials, thicknesses and lengths. The shape of the cross section of the fiber is not particularly limited, and any of a circular shape, an elliptical shape, a polygonal shape, a well shape, a T shape, a Y shape, and the like can be used. Furthermore, these fibers are used after being colored with a colorant or subjected to a surface treatment, if necessary. Examples of the surface treatment agent include fluorine compounds, silicone oils, powders, oil agents, gelling agents, emulsion polymers, and surfactants.

  Examples of the surfactant include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Examples of nonionic surfactants include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, and propylene glycol fatty acid esters. And its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxy Ethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene glycol adduct of lanolin, polyoxyalkyl N'arukiru co-modified organopolysiloxane, polyether-modified organopolysiloxane and the like. Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts. Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin.

Examples of the ultraviolet absorber include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like.
As the moisturizing agent, an aqueous component used for the purpose of imparting a moisture effect is used, which is water and a water-soluble component. In addition to water, for example, proteins, mucopolysaccharides, collagen, elastin, keratin and the like Sugars, propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol and other glycols, glycerol, diglycerin, polyglycerin and other glycerols, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, rose, etc. Plant extracts.
Examples of the antioxidant include α-tocopherol and ascorbic acid. Examples of the beauty component include vitamins, anti-inflammatory agents, herbal medicines and the like. Examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol 1,3-butylene glycol, 1,2-pentanediol and the like.

  Examples of the oily wrinkle cosmetic of the present invention include mascara, mascara overcoat, mascara base, and the like, and mascara and mascara overcoat are more preferable. In addition, the oily component only needs to form a continuous phase, and examples of its form include cream, gel, liquid, etc. Even if it is a non-aqueous type that does not contain an aqueous phase, It may be a water-in-oil type dispersed or emulsified therein.

  The method for producing the vaginal cosmetic of the present invention is not particularly limited. For example, an oily component containing components (A) and (C) and a powder containing component (B) are heated and mixed at about 110 ° C. The kneaded product can be obtained by kneading and filling the container.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Examples 1 to 8 and Comparative Examples 1 to 6: Cosmetics for oily wrinkles (gel form)
An oily wrinkle cosmetic with the formulation shown in Table 1 below was prepared, and a. Usability (smooth spread) b. Volume effect, c. Glossy d. Table 1 also shows the results of evaluating the makeup holding by the following evaluation method.

* 1: Leopard TL (Chiba Flour Mills)
* 2: Synthetic wax P-200 (Nippon Natural Products)
* 3: SH200-1,000,000CS (manufactured by Toray Dow Corning)
* 4: BENTONE 38V BC (Made by Elementis)
* 5: High filler K-5 (Matsumura Sangyo Co., Ltd.)
* 6: Amihope LL (Ajinomoto Co., Inc.)
* 7: PDM-10L (Topy Industries, Ltd.)
* 8: KF-9021 (Shin-Etsu Chemical Co., Ltd.) solid content 50%
* 9: Candelilla resin E-1 (Nippon Natural Products)
* 10: Ester gum HP (Arakawa Chemical Industries)
(Production method)
A. Components (1) to (5) and (17) to (19) are heated to about 110 ° C. and mixed uniformly.
B. Add (6) to (16) to A and mix uniformly.
C. B was filled in a container to obtain an oily wrinkle cosmetic.

(Evaluation method)
About the following item, the use test by 20 expert panels was done about each sample. Each sample is applied to a bowl once, and each panel member evaluates to 7 levels according to the following absolute evaluation criteria, gives a score, calculates the average value from the total score of all the panels, and uses the following criteria. Judged.
<Evaluation item>
a. Usability (smooth and spreading)
b. Volume effect c. Glossy d. Makeup
<Fabric absolute evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad
<Criteria>
(Judgment): (Average score)
◎: Over 5 points: Very good ○: Over 3.5 points and 5 points or less: Good △: Over 1 point and 3.5 points or less: Slightly poor ×: 1 point or less: Defect

As is apparent from the results in Table 1, the oily mascara of Examples 1 to 8 of the present invention is superior in all of smooth extension spread, volume effect, glossiness, and longevity compared to the oily mascara of Comparative Examples 1 to 6. It was.
On the other hand, in the comparative example 1 which does not contain a component (A), since the adhesiveness with respect to soot was weak, the volume effect fell remarkably and the glossiness was also inferior. In Comparative Example 2 where the component (A) was not in a specific viscosity range, the volume effect was inferior. In Comparative Example 3 in which a high-viscosity dimethylpolysiloxane was blended in place of the component (A), the adhesion to wrinkles was weak, so that the volume effect was remarkably lowered and the longevity was inferior.
In the comparative example 4 which mix | blended the talc conventionally used instead of a component (B), sufficient effect in a volume effect and a glossiness was not able to be acquired. Even in Comparative Example 5 in which synthetic phlogopite, which is a plate-like powder, was blended in place of component (B), the adhesion to wrinkles was weak, the volume effect was remarkably lowered, and the longevity of the makeup was also inferior.
In Comparative Example 6 in which another oil-soluble resin was blended in place of the component (C), the mascara liquid adhered to the soot due to the adhesive force derived from the resin, but the stickiness was strong and good usability was not obtained.

Example 9: Oily salmon cosmetic (gel)
(Ingredient) (%)
(1) Hydrogenated rosin acid pentaerythrityl * 10 2
(2) Trimethylsiloxysilicate solution * 11 44
(3) Hydrogenated glyceryl abietate * 12 2
(4) Carnauba 5
(5) Dimethiconol (10 million mPa · s) 3
(6) Dextrin palmitate * 1 2
(7) Light liquid isoparaffin remaining amount (8) Organically modified bentonite 3
(9) Fluorine compound-treated mica titanium * 13 5
(10) Fluorine compound-treated talc * 14 10
(11) Fluorine compound-treated iron oxide * 15 5
(12) N-lauroyl-L-lysine * 5 0.5
(13) Methyl ester of paraoxybenzoic acid 0.1
(14) Phenoxyethanol 0.1
(15) Purified water 1
* 11: KF-7312J (Shin-Etsu Chemical Co., Ltd.) resin content 50%
* 12: Pine Crystal KE-311 (Arakawa Chemical Industries)
* 13: Fluoroalkylalkoxysilane 3% treatment * 14: Fluoroalkylalkoxysilane 7% treatment * 15: Fluoroalkylalkoxysilane 5% treatment

(Production method)
A. Ingredients (1) to (4) are heated and mixed at about 110 ° C. to make it uniform.
B. Ingredients (5) to (15) are added to A and mixed uniformly.
C. B was filled in a container to obtain an oily wrinkle cosmetic.
(Evaluation)
The oily wrinkle cosmetic obtained as described above was excellent in all of smooth spreading, volume effect, glossiness, and longevity.

Example 10: Oily wrinkle cosmetic (long type, gel)
(Ingredient) (%)
(1) Disproportionated rosin glycerin ester * 16 3
(2) Hydrogenated glyceryl abietate * 12 1
(3) Trimethylsiloxysilicic acid solution * 17 20
(4) Beeswax 2
(5) Dimethiconol (20 million mPa · s) 3
(6) Dextrin palmitate * 18 1.5
(7) Light liquid isoparaffin remaining amount (8) Organically modified bentonite * 4 3
(9) Titanium / titanium oxide sintered product * 19 5
(10) Black titanium oxide * 20 5
(11) N-lauroyl-L-lysine * 5 3
(12) Talc 5
(13) Colored interference fiber * 21 1
(14) Nylon fiber * 22 1
(15) Methyl ester of paraoxybenzoic acid 0.1
(16) 1,3-butylene glycol 0.2
(17) Fragrance 0.1
* 16: Superester A-75 (Arakawa Chemical Industries)
* 17: SS4267 (Momentive Performance Materials Japan GK) resin content 35%
* 18: Leo Pearl KL (Chiba Flour Mills)
* 19: TILACK D (Ako Kasei Co., Ltd.)
* 20: Titanium black 12S (Gemco)
* 21: Polyethylene terephthalate, nylon laminated in 51 layers according to JP-A-11-1829, 5 denier, 1 mm, dyed with red No. 102 0.1% * 22: Nylon fiber 20D-2MM (manufactured by Chubu Pile Co., Ltd.) )

(Production method)
A. Ingredients (1) to (7) are heated and mixed at about 110 ° C. to be uniform.
B. Components (8) to (17) and A are combined and mixed uniformly.
C. B was filled in a container to obtain an oily wrinkle cosmetic (long type).
(Evaluation)
The oily mascara (long type) obtained as described above was excellent in all of smooth spreading, volume effect, glossiness, and longevity.

Example 11: Base cosmetic for oily wrinkles (gel)
(Ingredient) (%)
(1) Hydrogenated glyceryl abietate * 12 2
(2) Acrylic-silicone graft copolymer * 23 60
(3) Decamethylcyclopentasiloxane Residual amount (4) Dimethiconol (100,000 mPa · s) 3
(5) Polyoxyethylene (10 mol) hydrogenated castor oil 0.1
(6) Talc 3
(7) N-lauroyl-L-lysine * 5 5
(8) Titanium oxide 0.5
(9) Calcium carbonate 1
* 23: KP545 (Shin-Etsu Chemical Co., Ltd.) resin content 30%

(Production method)
A. Ingredients (1) to (9) are uniformly mixed at about 100 ° C.
B. A was filled in a container to obtain a base cosmetic for oily wrinkles.
(Evaluation)
The oily wrinkle base cosmetic obtained as described above was excellent in all of smooth spreading, volume effect, glossiness, and longevity.

Example 12: Mascara overcoat (liquid)
(Ingredient) (%)
(1) Polyisobutylene (molecular weight 100,000) 2
(2) Pentaerythritol rosinate * 9 1
(3) Trimethylsiloxysilicate solution * 11 38
(4) Dimethiconol (1 million mPa · s) 3
(5) Light liquid isoparaffin remaining amount (6) (palmitic acid / octanoic acid) dextrin * 24 5
(7) N-lauroyl-L-lysine * 52
(8) Fluorine compound-treated titanium oxide coated glass powder * 25 10
(9) Hydrogenated polydecene * 26 1
(10) Vinyl acetate / vinyl pyrrolidone copolymer 0.1
(11) Methyl ester of paraoxybenzoic acid 0.2
(12) Fragrance 0.1
(13) Polyethylene terephthalate
Aluminum / epoxy laminated powder 5
(14) Polyethylene terephthalate
Polymethylmethacrylate laminated film powder 3
* 24: Leopard TT (Chiba Flour Mills)
* 25: Treatment with 3% fluoroalkylalkoxysilane * 26: Silkflo 364NF Polydecene (manufactured by Lipo Chemicals)

(Production method)
A. Ingredients (1) to (12) are uniformly mixed at about 100 ° C.
B. Ingredients (13) to (14) are uniformly mixed with A.
C. B was filled into a container to obtain a mascara overcoat.
(Evaluation)
The mascara overcoat obtained as described above was excellent in all of smooth spreading, volume effect, gloss, and makeup.

Claims (3)

The following components (A) to (C);
(A) Dimethiconol (B) N-acyl lysine (C) trimethylsiloxysilicic acid, polymethylsilsesquioxane, acrylic-silicone graft copolymer, long-chain alkyl-modified acrylic having a viscosity at 25 ° C. of 100,000 mPa · s or more -An oily vaginal cosmetic comprising a silicone graft copolymer and an organic silicone resin selected from the group consisting of polyvinylpyrrolidone-modified methylpolysiloxane .   The amount of the component (A) is 0.1 to 5% by mass, the amount of the component (B) is 0.1 to 5% by mass, and the amount of the component (C) is 10 to 25% by mass. The oily wrinkle cosmetic according to claim 1. The blending mass ratio (C) / (total oil-soluble resin component) of the component (C) and the total oil-soluble resin component in the cosmetic is 0.5 to 1, characterized in that The cosmetics for oily wrinkles described.