JP5203622B2 - Oily cosmetics - Google Patents
Oily cosmetics Download PDFInfo
- Publication number
- JP5203622B2 JP5203622B2 JP2007092081A JP2007092081A JP5203622B2 JP 5203622 B2 JP5203622 B2 JP 5203622B2 JP 2007092081 A JP2007092081 A JP 2007092081A JP 2007092081 A JP2007092081 A JP 2007092081A JP 5203622 B2 JP5203622 B2 JP 5203622B2
- Authority
- JP
- Japan
- Prior art keywords
- wax
- component
- oily
- fatty acid
- feeling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000002537 cosmetic Substances 0.000 title claims description 46
- -1 fatty acid ester Chemical class 0.000 claims description 44
- 239000001993 wax Substances 0.000 claims description 39
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 18
- 239000000194 fatty acid Substances 0.000 claims description 18
- 229930195729 fatty acid Natural products 0.000 claims description 18
- 229920001155 polypropylene Polymers 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
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- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims description 4
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- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
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- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 2
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- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Cosmetics (AREA)
Description
本発明は、特定のプロピレン重合体と炭化水素ワックスとポリグリセリン脂肪酸エステルを含有する油性化粧料に関し、詳細には、該プロピレン重合体を配合することにより、炭化水素ワックスとポリグリセリン脂肪酸エステルで形成されるワックスオイルゲルの温度依存性(温度変化による形状変化)を小さくすることが可能であるため、高温の形状保持性に優れながらも、柔らかな使用感であり、更には、肌及び唇へのフィット感、化粧膜のツヤ感、発色の持続性に優れた油性化粧料を提供するものである。 The present invention relates to an oily cosmetic containing a specific propylene polymer, a hydrocarbon wax, and a polyglycerin fatty acid ester, and more specifically, formed from a hydrocarbon wax and a polyglycerin fatty acid ester by blending the propylene polymer. It is possible to reduce the temperature dependence of the wax oil gel (shape change due to temperature change), so it is excellent in high-temperature shape retention, but has a soft feeling of use, and further to the skin and lips. It is an object of the present invention to provide an oily cosmetic with excellent fit, glossiness of the cosmetic film, and sustainability of color development.
油性化粧料は、液状油の特性であるツヤ感やエモリエント効果に優れるため、アイクリームや口紅、ファンデーション等の用途に幅広く応用されている。従来から、これらの油性化粧料では、油剤と、油性ゲル化剤やワックス類との組合せを主体として、使用性の向上や成型性の付与がなされてきた。しかしながら、固形油や半固形油を配合した場合は、温度依存性(温度変化による形状変化)が大きく、低温では油性化粧料がより固くなることで、使用感が重くなったり、とれや肌への塗布性が悪くなったりし、逆に、高温では油性化粧料の軟化により、使用時のべたつき感や、形状安定性の不良等の欠点を有していた。高温での形状保持は、日常携帯品の機能として必須であり、これを実現するためにワックス類を多量に配合すると、使用時は固い感触となり、仕上がりのツヤ感も低減する。そこで、これらを解消するために、温度変化に対する安定性や形状保持性を改良する技術(例えば特許文献1〜3参照)が報告されている。 Oily cosmetics are widely applied to uses such as eye cream, lipstick, and foundation because they are excellent in the gloss and emollient effects that are characteristics of liquid oils. Conventionally, in these oily cosmetics, usability has been improved and moldability has been imparted mainly by a combination of an oil agent, an oily gelling agent and waxes. However, when blended with solid oil or semi-solid oil, the temperature dependency (change in shape due to temperature change) is large, and the oily cosmetic becomes harder at low temperatures, which increases the feeling of use and helps to remove skin and skin. On the other hand, at high temperatures, the oily cosmetics were softened, resulting in problems such as stickiness during use and poor shape stability. Maintaining the shape at high temperature is indispensable as a function of everyday portable goods. When a large amount of waxes are blended to realize this, it becomes hard to use and reduces the glossiness of the finished product. In order to solve these problems, techniques for improving stability against temperature change and shape retention (for example, see Patent Documents 1 to 3) have been reported.
しかしながら、従来のワックス類と油剤の組合せでは、ワックスオイルゲルにより形状を保持する油性化粧料の温度依存性を著しく低下させることは困難であり、高温における形状保持性と、使用感とを満足することはできなかった。また、最近の油性化粧料には、化粧膜のツヤ感等の従来機能に加えて、化粧の持続性等の高度な機能と、使用中の心地よさや膜感の向上等の良質な感触とを兼ね備えた品質が求められている。このため、高温の形状保持性に優れながらも、柔らかな使用感であり、更には、肌及び唇へのフィット感、化粧膜のツヤ感、発色の持続性に優れた化粧料の開発が望まれていた。 However, with the combination of conventional waxes and oils, it is difficult to remarkably reduce the temperature dependency of the oily cosmetic that retains the shape with the wax oil gel, and satisfies the shape retention at high temperatures and the feeling of use. I couldn't. In addition to the conventional functions such as the glossiness of the cosmetic film, recent oily cosmetics have advanced functions such as the sustainability of makeup, and a high-quality feel such as improved comfort and film feeling during use. Quality that combines is required. For this reason, it is hoped to develop cosmetics that are excellent in high-temperature shape retention but have a soft feeling of use, and also have a feeling of fitting to the skin and lips, a glossy appearance of the cosmetic film, and a long-lasting color development. It was rare.
上記実情に鑑み、発明者らは鋭意検討の結果、高分子量の特定のプロピレン重合体を、炭化水素ワックスとポリグリセリン脂肪酸エステルで構成される油性化粧料に配合することにより、油性化粧料の温度依存性を低減させることが可能であることを見出し、高温の形状保持性に優れながらも、柔らかな使用感があり、肌及び唇へのフィット感、化粧膜のツヤ感、発色の持続性に優れた化粧料を完成した。 In view of the above circumstances, as a result of intensive studies, the inventors have formulated a specific propylene polymer having a high molecular weight into an oily cosmetic composed of a hydrocarbon wax and a polyglycerin fatty acid ester, so that the temperature of the oily cosmetic is increased. It was found that it was possible to reduce the dependence, and while maintaining excellent shape retention at high temperatures, there was a soft feeling of use, a feeling of fitting to the skin and lips, a glossy feeling of the cosmetic film, and a long-lasting color development An excellent cosmetic was completed.
即ち、本発明は、次の成分(A)〜(C);
(A)重量平均分子量(Mw)が25000〜100000、融点が60℃〜100℃であるプロピレン重合体
(B)炭化水素ワックス
(C)ポリグリセリン脂肪酸エステル
を含有することを特徴とする油性化粧料を提供するものであり、また、当該ピレン重合体の分子量分布(Mw/Mn)が4.0以下である油性化粧料に関するものである。さらに、本発明は、前記成分(A)プロピレン重合体と成分(B)炭化水素ワックスの配合比率(A)/(B)が0.001〜1である油性化粧料を提供するものである。
That is, the present invention includes the following components (A) to (C);
(A) Oily cosmetic comprising a propylene polymer (B) hydrocarbon wax (C) polyglycerin fatty acid ester having a weight average molecular weight (Mw) of 25,000 to 100,000 and a melting point of 60 ° C to 100 ° C And a molecular weight distribution (Mw / Mn) of the pyrene polymer is about 4.0 or less. Furthermore, this invention provides the oil-based cosmetics whose compounding ratio (A) / (B) of the said component (A) propylene polymer and component (B) hydrocarbon wax is 0.001-1.
本発明の油性化粧料は、高温の形状保持性に優れながらも、柔らかな使用感であり、更には、肌及び唇へのフィット感、化粧膜のツヤ感、発色の持続性を有するものである。 The oily cosmetic of the present invention has a soft feeling of use while having excellent shape retention at high temperatures, and further has a feeling of fitting to the skin and lips, a glossy feeling of the cosmetic film, and color development. is there.
以下、本発明について詳細に説明する。
本発明に用いられる成分(A)のプロピレン重合体は、透明感のある固形物であり、容易に融解、あるいは汎用の化粧料油分と相溶することで配合が可能であり、本発明においては、成分(B)と成分(C)のオイルゲルと相互作用することにより、油性化粧料の温度依存性に寄与するものである。
Hereinafter, the present invention will be described in detail.
The propylene polymer of the component (A) used in the present invention is a transparent solid, which can be easily melted or compounded by being compatible with general-purpose cosmetic oils. By interacting with the oil gel of component (B) and component (C), it contributes to the temperature dependence of the oily cosmetic.
本発明に用いられる成分(A)の重量平均分子量(Mw)の範囲は、25000〜100000であり、好ましい範囲としては、25000〜40000である。Mwが25000未満では、べたつきが発生することがあり、また、100000を超えると、柔らかな使用感に劣ることがある。重量平均分子量(Mw)の算出は、GPC測定装置(カラム:TOSO GMHHR−H(S)HT、検出器:液体クロマトグラム用RI検出器 WATERS 150C)を用い、詳細な測定条件は、溶媒として1,2,4−トリクロロベンゼン、測定温度は145℃、流速は1.0ミリリットル/分、試料濃度:2.2mg/ミリリットル、注入量は160マイクロリットル、さらに、検量線はUniversal Calibration、解析プログラム:HT−GPC(Ver.1.0)とする。 The range of the weight average molecular weight (Mw) of the component (A) used for this invention is 25000-100,000, As a preferable range, it is 25000-40000. If Mw is less than 25,000, stickiness may occur, and if it exceeds 100,000, the soft feeling may be inferior. The weight average molecular weight (Mw) was calculated using a GPC measurement apparatus (column: TOSO GMHHR-H (S) HT, detector: RI detector for liquid chromatogram WATERS 150C), and the detailed measurement conditions were 1 as a solvent. , 2,4-trichlorobenzene, measurement temperature is 145 ° C., flow rate is 1.0 ml / min, sample concentration: 2.2 mg / ml, injection amount is 160 microliters, calibration curve is Universal Calibration, analysis program: HT-GPC (Ver. 1.0).
本発明に用いられる成分(A)の融点の範囲は、60℃〜100℃の範囲にあり、好ましい範囲としては、70℃〜90℃である。融点の測定は、示差走査型熱量計(DSC)を用い、試料を窒素雰囲気下−10℃で5分間保持した後、10℃/分で昇温させることにより得られた融解吸熱カーブの最も高温側に観測されるピークのピークトップとして定義される融点(Tm)とする。 The melting point range of the component (A) used in the present invention is in the range of 60 ° C to 100 ° C, and a preferred range is 70 ° C to 90 ° C. The melting point was measured by using a differential scanning calorimeter (DSC), holding the sample at −10 ° C. for 5 minutes in a nitrogen atmosphere, and then raising the temperature at 10 ° C./min. The melting point (Tm) is defined as the peak top of the peak observed on the side.
また、本発明に用いられる成分(A)は、GPC法により測定した分子量分布(Mw/Mn)が4以下であることが好ましく、より好ましくは3.5以下、特に好ましくは3.0以下である。分子量分布(Mw/Mn)が4を超えると、べたつきが発生することがある。 The component (A) used in the present invention preferably has a molecular weight distribution (Mw / Mn) measured by GPC method of 4 or less, more preferably 3.5 or less, particularly preferably 3.0 or less. is there. If the molecular weight distribution (Mw / Mn) exceeds 4, stickiness may occur.
本発明に用いられる成分(A)の重合方法は特に制限されず、スラリー重合法、気相重合法、塊状重合法、溶液重合法、懸濁重合法等のいずれの方法を用いてもよいが、分子量分布の観点から、メタロセン錯体を用いて合成する方法が好ましく、例えば、国際公開WO2003/091289号公報に記載された方法に基づいて製造することができる。 The polymerization method of component (A) used in the present invention is not particularly limited, and any method such as a slurry polymerization method, a gas phase polymerization method, a bulk polymerization method, a solution polymerization method, and a suspension polymerization method may be used. From the viewpoint of molecular weight distribution, a method of synthesizing using a metallocene complex is preferable, and for example, it can be produced based on the method described in International Publication WO2003 / 091289.
また、成分(A)のプロピレン重合体は、前記以外の特性を有するものである。即ち、テトラリン溶媒中135℃にて測定した極限粘度[η]が0.01〜0.5デシリットル/gであり、この極限粘度[η]は、好ましくは0.1〜0.5デシリットル/g、特に好ましくは0.2〜0.4デシリットル/gである。極限粘度[η]が0.01デシリットル/g未満では、十分なフィット性が得られないことがあり、また0.5デシリットル/gを超えると、塗布時の滑らかさに劣ることがある。 The propylene polymer of component (A) has properties other than those described above. That is, the intrinsic viscosity [η] measured at 135 ° C. in a tetralin solvent is 0.01 to 0.5 deciliter / g, and this intrinsic viscosity [η] is preferably 0.1 to 0.5 deciliter / g. Particularly preferred is 0.2 to 0.4 deciliter / g. If the intrinsic viscosity [η] is less than 0.01 deciliter / g, sufficient fit may not be obtained, and if it exceeds 0.5 deciliter / g, the smoothness during application may be inferior.
本発明における成分(A)の化粧料中の配合量は、本発明の効果が奏される限り特に制限はないが、0.1〜5質量%(以下、単に「%」と略す)の範囲が好ましい。 The amount of the component (A) in the cosmetic according to the present invention is not particularly limited as long as the effect of the present invention is exhibited, but it is in the range of 0.1 to 5% by mass (hereinafter simply referred to as “%”). Is preferred.
本発明に用いられる成分(B)の炭化水素ワックスは、合成炭化水素ワックス及び天然より抽出し、精製される炭化水素ワックスである。その融点は、油性化粧料の、特に高温での形状を保持するために40℃以上が好ましい。具体的には、ポリエチレンワックス、エチレン・プロピレンコポリマー、フィッシャートロプシュワックス、マイクロクリスタリンワックス、オゾケライトワックス、パラフィンワックス、セレシンワックス等が挙げられ、中でもポリエチレンワックス、エチレン・プロピレンコポリマー、フィッシャートロプシュワックス、が好ましい。市販品としてはPERFORMALENE500、PERFORMALENE655、PERFORMALENE725、PERFORMALENE850(いずれもニューフェーズテクノロジー社製)、EP−700、EP−1100(Baker Petrolite社製)、CIREBELLE108(CIREBELLE社製)、ムルチワックスW−445(SONNEBORN社製)、OZOKERITE WAX SP−273P(STRAHL&PITSCH INC社製)、PARACERA256(PARAMENT社製)等が挙げられる。 The component (B) hydrocarbon wax used in the present invention is a synthetic hydrocarbon wax and a hydrocarbon wax extracted from nature and purified. The melting point is preferably 40 ° C. or higher in order to maintain the shape of the oily cosmetic, particularly at a high temperature. Specific examples include polyethylene wax, ethylene / propylene copolymer, Fischer-Tropsch wax, microcrystalline wax, ozokerite wax, paraffin wax, ceresin wax, etc. Among them, polyethylene wax, ethylene-propylene copolymer, Fischer-Tropsch wax, preferable. As a commercial item, PERFORMALENE500, PERFORMALENE655, PERFORMALENE725, PERFORMOLENE850 (all made by New Phase Technology), EP-700, EP-1100 (made by Baker Petrolite), CIREBELLE108 (made by CIREBERELLE W), ORON W Product), OZOKERITE WAX SP-273P (manufactured by STRAHL & PITSCH INC), PARACERA 256 (manufactured by PARAMENT) and the like.
本発明における成分(B)の化粧料中の配合量は、本発明の効果が奏される限り特に制限はないが、5〜15%の範囲が好ましい。また、本発明において、成分(A)のプロピレン重合体と、成分(B)の炭化水素ワックスとの配合比率(A)/(B)は、0.001〜1.0が好ましく、さらに好ましくは0.1〜0.7である。0.001未満及び1.0を越える場合では、油性化粧料の温度依存性を低減させることができず、形状安定性に劣ることがある。 Although the compounding quantity in the cosmetics of the component (B) in this invention does not have a restriction | limiting in particular as long as the effect of this invention is show | played, The range of 5-15% is preferable. In the present invention, the blending ratio (A) / (B) of the propylene polymer of component (A) and the hydrocarbon wax of component (B) is preferably 0.001 to 1.0, more preferably 0.1 to 0.7. If it is less than 0.001 and exceeds 1.0, the temperature dependency of the oily cosmetic cannot be reduced, and the shape stability may be inferior.
本発明の成分(C)のポリグリセリン脂肪酸エステルは、常温にて液状、ペースト状、あるいは固形状のエステル油である。具体的には、モノイソステアリン酸ジグリセリル、ジイソステアリン酸ジグリセリル、トリイソステアリン酸ジグリセリル、ペンタオレイン酸ポリグリセリル、ジイソステアリン酸ポリグリセリル、デカイソステアリン酸デカグリセリル等が挙げられ、中でもジグリセリン脂肪酸エステルが好ましい。これらの市販品としては、コスモール41、コスモール42、コスモール43、コスモール44(いずれも日清オイリオグループ社製)、ニッコールデカグリン5−0、ニッコールデカグリン2−IS(いずれも日光ケミカルズ社製)等が挙げられる。 The polyglycerin fatty acid ester of component (C) of the present invention is a liquid, pasty, or solid ester oil at room temperature. Specific examples include diglyceryl monoisostearate, diglyceryl diisostearate, diglyceryl triisostearate, polyglyceryl pentaoleate, polyglyceryl diisostearate, decaglyceryl decaisostearate, and diglycerin fatty acid ester is preferred. As these commercial products, Cosmol 41, Cosmall 42, Cosmall 43, Cosmall 44 (all manufactured by Nisshin Oillio Group), Nikkor Decaglin 5-0, Nikkor Decagrin 2-IS (all manufactured by Nikko Chemicals) Etc.
本発明の油性化粧料には、上記成分の他に、本発明の効果を妨げない範囲で通常の化粧料に使用される成分、例えば、成分(A)〜(C)以外の油性成分、粉体およびそれらの処理物、界面活性剤、水性成分、その他の成分(防腐剤、抗菌剤、酸化防止剤、美肌用成分等)等を配合することができる。 In addition to the above-mentioned components, the oily cosmetics of the present invention include components used in ordinary cosmetics within a range that does not interfere with the effects of the present invention, such as oily components other than components (A) to (C), powders Body and processed products thereof, surfactant, aqueous component, other components (preservatives, antibacterial agents, antioxidants, skin beautifying components, etc.) and the like can be blended.
油性成分としては、化粧料に一般に使用される動物油、植物油、合成油等の起源の固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類、油性ゲル化剤類等が挙げられる。具体的には、流動パラフィン、スクワラン、モンタンワックス、ポリイソブチレン、ポリブテン等の炭化水素類、モクロウ、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、ミツロウ、ゲイロウ、カルナウバワックス、キャンデリラワックス等のロウ類、ホホバ油、2−エチルヘキサン酸セチル、乳酸イソステアリル、乳酸オクチルドデシル、乳酸オレイル、乳酸ステアリル、リンゴ酸ジイソステアリル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ロジン酸ペンタエリトリットエステル、ジオクタン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、フィトステロール脂肪酸エステル等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、トリメチルシロキシケイ酸、高重合度メチルフェニルポリシロキサン、架橋型メチルポリシロキサン、ポリオキシ変性オルガノポリシロキサン、架橋型ポリエーテル変性メチルポリシロキサン、メタクリル変性ポリシロキサン、ステアリル変性メチルポリシロキサン、オレイル変性メチルポリシロキサン、ベヘニル変性メチルポリシロキサン、ポリビニルピロリドン変性メチルポリシロキサン、高重合度ジメチルポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体、オクタン酸デキストリン、ラウリン酸デキストリン、パルミチン酸デキストリン、ミリスチン酸デキストリン、ステアリン酸デキストリン、ベヘニン酸デキストリン、ヤシ油脂肪酸デキストリン、(パルミチン酸/オクタン酸)デキストリン、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム、ステアリン酸カリウム、12−ヒドロキシステアリン酸等の油性ゲル化剤類等が挙げられ、これらを一種又は二種以上用いることができる。 The oily components include hydrocarbons, fats and oils, waxes, oils, waxes, waxes, oils, vegetable oils, synthetic oils and other solid oils, semi-solid oils, liquid oils, volatile oils, etc. , Hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, montan wax, polyisobutylene, polybutene, fats and oils such as molasses, olive oil, castor oil, mink oil, macadamian nut oil, beeswax, gay wax, carnauba wax, Wax such as candelilla wax, jojoba oil, cetyl 2-ethylhexanoate, isostearyl lactate, octyldodecyl lactate, oleyl lactate, stearyl lactate, diisostearyl malate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate Rosin acid pentaerythritol ester, dioctanoic acid neopentyl glycol, dioctanoic acid neopentyl glycol, cholesterol fatty acid ester, phytosterol fatty acid ester and the like, stearic acid, Fatty acids such as phosphoric acid, myristic acid, behenic acid, isostearic acid, oleic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane , Decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, trimethylsiloxysilicic acid, high degree of polymerization methylphenylpolysiloxane, cross-linked methylpolysiloxane, polyoxy-modified organopolysiloxane, cross-linked polyether-modified methyl polysiloxane, methacryl-modified poly Siloxane, stearyl-modified methyl polysiloxane, oleyl-modified methyl polysiloxane, behenyl-modified methyl polysiloxane, polyvinyl Loridone-modified methylpolysiloxane, high degree of polymerization dimethylpolysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane and other silicones, Fluorine oils such as fluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, octoate dextrin, laurate dextrin, dextrin palmitate, dextrin myristate, Dextrin stearate, dextrin behenate, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, de Examples thereof include oily gelling agents such as open fatty acid ester, aluminum isostearate, potassium stearate, and 12-hydroxystearic acid, and these can be used alone or in combination.
粉体成分としては、化粧料に一般に使用される粉体として用いられる粉体であれば、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、金属粉体類、複合粉体類等が挙げられる。具体的に例示すれば、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、チタン・酸化チタン焼結物、酸化クロム、水酸化クロム、紺青、群青等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母(セリサイト)、合成セリサイト、カオリン、炭化珪素、ベントナイト、スメクタイト、無水ケイ酸、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、二酸化チタン被覆雲母、二酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等のコポリマー樹脂、ポリプロピレン系樹脂、シリコーン樹脂、ウレタン樹脂等の有機高分子樹脂粉体、ステアリン酸亜鉛、N−アシルリジン等の有機低分子性粉体、シルク粉末、セルロース粉末等の天然有機粉体、赤色201号、赤色202号、赤色205号、赤色226号、赤色228号、橙色203号、橙色204号、青色404号、黄色401号等の有機顔料粉体、赤色3号、赤色104号、赤色106号、橙色205号、黄色4号、黄色5号、緑色3号、青色1号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体あるいは更にアルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体、等が挙げられ、これら粉体はその一種又は二種以上を用いることができ、更に複合化したものを用いても良い。 As a powder component, if it is a powder used as a powder generally used in cosmetics, a spherical shape, a plate shape, a needle-like shape, a haze shape, a fine particle, a particle size such as a pigment class, a porous material, It is not particularly limited by the particle structure such as non-porous, and examples thereof include inorganic powders, glitter powders, organic powders, pigment powders, metal powders, and composite powders. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, etc. Colored inorganic pigments, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide White body powders such as zirconium oxide, antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, Titanium dioxide-coated mica, titanium dioxide-coated bisoxychloride , Iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder Glittering powder such as polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, polypropylene resin, etc. , Organic polymer resin powder such as silicone resin and urethane resin, organic low molecular weight powder such as zinc stearate and N-acyl lysine, natural organic powder such as silk powder and cellulose powder, Red No. 201, Red 2 Organic pigment powder such as No. 2, Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange Organic pigment powders such as zirconium, barium or aluminum lake such as No. 205, Yellow No. 4, Yellow No. 5, Green No. 3 and Blue No. 1 or metal powder such as aluminum powder, gold powder and silver powder, fine particle titanium oxide coating Mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, composite powder such as titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, etc. are used, and these powders use one kind or two kinds or more. It is also possible to use a composite.
本発明の油性化粧料は、形状を問わず、ペースト状、クリーム状、固形状(皿流し込み状、固形粉末状、スティック状)等にて実施することができる。また、本発明の化粧料はスキンケア化粧料、毛髪化粧料、メーキャップ化粧料等に適用が可能であり、中でも口紅、ファンデーション、アイシャドウなどの、メーキャップ化粧料に好適に適用できる。 Regardless of the shape, the oily cosmetic of the present invention can be carried out in a paste form, cream form, solid form (dish-casting form, solid powder form, stick form) or the like. The cosmetic of the present invention can be applied to skin care cosmetics, hair cosmetics, makeup cosmetics, and the like, and can be suitably applied to makeup cosmetics such as lipsticks, foundations, and eye shadows.
次に実施例を挙げて本発明を更に詳細に説明するが、本発明はこれらにより何ら限定されるものではない。 EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.
製造例1
プロピレン重合体の製造は、国際公開WO2003/091289号公報記載の方法に準じて行った。得られたプロピレン重合体の融点は80℃、重量平均分子量(Mw)は30000であった。
Production Example 1
Propylene polymer was produced according to the method described in International Publication WO2003 / 091289. The resulting propylene polymer had a melting point of 80 ° C. and a weight average molecular weight (Mw) of 30000.
実施例1〜3:スティック状口紅
表1に示す処方のスティック状口紅を調製し、高温の形状保持性、柔らかな使用感、唇へのフィット感、化粧膜のツヤ感、発色の持続性について下記の方法により評価した。その結果も併せて表1に示す。
Examples 1-3: Stick-shaped lipsticks A stick-shaped lipstick having the formulation shown in Table 1 was prepared, and the high-temperature shape-retaining property, soft feeling of use, fit to lips, glossiness of the cosmetic film, and color development persistence. Evaluation was made by the following method. The results are also shown in Table 1.
(製造方法)
A:成分1〜7を100℃で均一に溶解混合する。
B:A成分に成分8〜13を添加し均一に混合する。
C:Bを容器に流し込み、冷却してスティック状口紅を得た。
(Production method)
A: Components 1 to 7 are uniformly dissolved and mixed at 100 ° C.
B: Components 8 to 13 are added to component A and mixed uniformly.
C: B was poured into a container and cooled to obtain a stick-like lipstick.
(評価方法)
下記評価項目について各々下記方法により評価を行った。
(評価項目)
イ.柔らかな使用感
ロ.唇へのフィット感
ハ.化粧膜のツヤ感
ニ.発色の持続性
へ.高温の形状保持性
イ〜ニについては、各試料について専門パネル20名による使用テストを行い、パネル各人が下記絶対評価にて6段階に評価し評点を付け、試料ごとにパネル全員の評点合計から、その平均値を算出し、下記4段階判定基準により判定した。尚、ニの発色の持続性については、各試料を唇に塗布し、パネルに通常の生活をしてもらい、6時間後の発色の持続性について評価した。
への経時安定性は、室温、40℃にて6ヶ月横置きで放置した後、各サンプルの外観観察を行い調製時と比較して、下記4段階評価基準により評価し、判定を行った。
(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
A. Soft feeling of use b. Fit to lips c. Glossiness of the decorative film. To the persistence of color development. For high-temperature shape-retaining properties (i) to (d), each sample is subjected to a use test by 20 specialist panels, and each panel member evaluates it according to the following 6 absolute ratings and gives a score. From that, the average value was calculated and judged according to the following four-step criteria. In addition, about the persistence of coloring of D, each sample was apply | coated to the lip, the panel was made to have a normal life, and the sustainability of coloring after 6 hours was evaluated.
The aging stability was evaluated by the following four-stage evaluation criteria, after the appearance of each sample was observed after standing for 6 months at room temperature and 40 ° C., and compared with the time of preparation.
<柔らかな使用感、フィット感、化粧膜のツヤ感、発色の持続性の評価>
絶対評価基準
(評点):(評価)
6点:非常に良好
5点:良好
4点:やや良好
3点:普通
2点:やや不良
1点:不良
<Evaluation of soft feeling of use, fit, gloss of makeup film, and persistence of color development>
Absolute Evaluation Criteria (Score): (Evaluation)
6 points: very good 5 points: good 4 points: slightly good 3 points: normal 2 points: slightly bad 1 point: bad
4段階判定基準
(判定):(評点の平均点)
◎ :5点を超える :非常に良好
○ :3.5点を超える5点以下:良好
△ :1.5点を超える3点以下:やや不良
× :1.5点以下 :不良
4-step criteria (Judgment): (Average score)
◎: More than 5 points: Very good ○: 5 points or less exceeding 3.5 points: Good △: 3 points or less exceeding 1.5 points: Slightly poor ×: 1.5 points or less: Bad
<高温の形状保持性の評価>
(判定):(評価)
◎ :室温放置品と40℃放置品の差がなく口紅が曲がっていない
○ :40℃放置品が僅かに口紅が曲がっているが、容器の外筒には触れない程度
△ :40℃放置品が明らかに口紅が曲がっている(容器の外筒に付いてしまう)
× :40℃放置品で口紅が折れている
<Evaluation of shape retention at high temperature>
(Judgment): (Evaluation)
◎: There is no difference between the product left at room temperature and the product left at 40 ℃, and the lipstick is not bent ○: The product left at 40 ℃ is slightly bent, but it does not touch the outer cylinder of the container △: Product left at 40 ℃ Is obviously bent lipstick (it will stick to the outer tube of the container)
×: Lipstick is broken at 40 ° C
表1の結果から明らかな如く、本発明の実施例1〜5のスティック状口紅は、比較例1〜3のスティック状口紅に比べ、柔らかな使用感、唇へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性の全てにおいて優れたものであった。これに対して、成分(A)の配合されていない比較例1では、特にフィット感、発色の持続性の点で満足いくものが得られなかった。成分(B)の配合されていない比較品2では、結晶性の高い炭化水素ワックスが配合されていないため、特に高温での形状保持性の点で満足いくものが得られなかった。成分(C)の配合されていない比較品3では、成分(B)と成分(C)以外の油剤で形成するワックスオイルゲルが良好ではなく、硬さが得られないことから、特に高温での形状保持性の点で満足いくものが得られなかった。 As is apparent from the results in Table 1, the stick-shaped lipsticks of Examples 1 to 5 of the present invention are softer than the stick-shaped lipsticks of Comparative Examples 1 to 3, the feeling of fitting to the lips, and the gloss of the cosmetic film. It was excellent in all of feeling, long-lasting color development, and high-temperature shape retention. On the other hand, in Comparative Example 1 in which the component (A) was not blended, satisfactory results were not obtained particularly in terms of fit and color development. In Comparative product 2 in which component (B) was not blended, a hydrocarbon wax having high crystallinity was not blended, and therefore, satisfactory products were not obtained particularly in terms of shape retention at high temperatures. In the comparative product 3 in which the component (C) is not blended, the wax oil gel formed with the oil agent other than the component (B) and the component (C) is not good, and the hardness cannot be obtained. What was satisfactory in terms of retention was not obtained.
実施例6:油性ファンデーション
(成分) (%)
1.タルク 15
2.カオリン 10
3.酸化チタン 10
4.ベンガラ 1
5.黄酸化鉄 4
6.黒酸化鉄 0.2
7.製造例1記載のプロピレン重合体 5
8.ポリエチレンワックス *3 6
9.マイクロクリスタリンワックス *4 7
10.ジイソステアリン酸ジグリセリル *5 10
11.スクワラン 5
12.ワセリン 5
13.トリ(カプリル/カプリン酸)グリセリル 残量
14.香料 0.1
*3:PERFORMALENE655(ニューフェーズテクノロジー社製)
*4:ムルチワックスW−445(SONNEBORN社製)
*5:コスモール42(日清オイリオグループ)
Example 6: Oily foundation (component) (%)
1. Talc 15
2. Kaolin 10
3. Titanium oxide 10
4). Bengala 1
5. Yellow iron oxide 4
6). Black iron oxide 0.2
7). Propylene polymer described in Production Example 1 5
8). Polyethylene wax * 3 6
9. Microcrystalline wax * 4 7
10. Diglyceryl diisostearate * 5 10
11. Squalane 5
12 Vaseline 5
13. Tri (capryl / capric acid) glyceryl remaining amount 14. Fragrance 0.1
* 3: PERFORMALENE 655 (manufactured by New Phase Technology)
* 4: Multi wax W-445 (manufactured by SONNEBORN)
* 5: Cosmall 42 (Nisshin Oillio Group)
(製造方法)
A:7〜12を90℃で加熱溶解する。
B:Aに1〜6を均一に分散する。
C:Bに13、14を加え、溶解、脱泡後、皿状容器に充填する。
(Production method)
A: 7-12 are heated and dissolved at 90 ° C.
B: 1 to 6 are uniformly dispersed in A.
C: Add 13, 14 to B, dissolve and degas, then fill into a dish-like container.
実施例1〜5と同様に評価した結果、実施例6の油性ファンデーションは、柔らかな使用感、肌へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性に優れた油性ファンデーションであった。 As a result of evaluation in the same manner as in Examples 1 to 5, the oil-based foundation of Example 6 was excellent in a soft feeling of use, a feeling of fitting to the skin, a glossy feeling of the cosmetic film, a durability of coloring, and a high temperature shape retention. It was an oily foundation.
実施例7:油性アイクリーム
(成分) (%)
1.製造例1記載のプロピレン重合体 2
2.エチレン・プロピレンコポリマー *6 7
3.パラフィンワックス *7 1
4.12−ヒドロキシステアリン酸 2
5.トリイソステアリン酸ジグリセリル *2 10
6.ジカプリン酸プロピレングリコール 10
7.マカデミアナッツ油 35
8.酢酸トコフェロール 0.1
9.油溶性ローズマリー抽出液 0.1
10.ヒアルロン酸水溶液 0.1
11.赤202号 0.1
12.デカメチルシクロペンタシロキサン 残量
13.香料 0.01
*6:EP−1100(Baker Petrolite社製)
*7:PARACERA256(PARAMENT社製)
Example 7: Oily eye cream (component) (%)
1. Propylene polymer described in Production Example 1 2
2. Ethylene / propylene copolymer * 6 7
3. Paraffin wax * 7 1
4.12-Hydroxystearic acid 2
5. Diglyceryl triisostearate * 2 10
6). Propylene glycol dicaprate 10
7). Macadamia nut oil 35
8). Tocopherol acetate 0.1
9. Oil-soluble rosemary extract 0.1
10. Hyaluronic acid aqueous solution 0.1
11. Red 202 0.1
12 Decamethylcyclopentasiloxane remaining amount 13. Fragrance 0.01
* 6: EP-1100 (manufactured by Baker Petrolite)
* 7: PARACERA256 (manufactured by PARAMENT)
(製造方法)
A:1〜7を90℃で加熱溶解する。
B:Aに8〜13を加えて均一に溶解後、容器に充填する。
(Production method)
A: 1 to 7 are heated and dissolved at 90 ° C.
B: Add 8 to 13 to A and dissolve uniformly, then fill the container.
実施例1〜5と同様に評価した結果、実施例7の油性アイクリームは、柔らかな使用感、肌へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性に優れた油性アイクリームであった。 As a result of evaluation in the same manner as in Examples 1 to 5, the oily eye cream of Example 7 is excellent in a soft feeling of use, a feeling of fitting to the skin, a glossy feeling of the cosmetic film, a long-lasting color development, and a high temperature shape retention. Oily eye cream.
実施例8:ペースト状リップグロス
(成分) (%)
1.製造例1記載のポリプロピレン重合体 1.5
2.フィッシャートロプシュワックス *8 1.5
3.テトライソステアリン酸ジグリセリル *9 1
4.リンゴ酸ジイソステアリル 10
5.乳酸ステアリル 10
6.水添ポリイソブテン *10 30
7.トリエチルヘキサノイン 残量
8.流動パラフィン 5
9.12−ヒドロキシステアリン酸 0.1
10.α−オレフィン・ビニルピロリドン共重合体 *11 0.5
11.無水ケイ酸 *12 3.5
12.ベンガラ 0.1
13.赤色201号 0.3
14.黒酸化鉄 0.05
15.酸化チタン 0.2
16.大豆リン脂質 0.01
17.p−メトキシケイ皮酸−2−エチルヘキシル 3
18.防腐剤 適量
19.香料 適量
*8:CIREBELLE108(CIREBELLE社製)
*9:コスモール44(日清オイリオグループ)
*10:平均分子量1000
*11:ANTARON V−220(ISP社製)
*12:AEROSIL 200(日本アエロジル社製)
Example 8: Pasty lip gloss (component) (%)
1. Polypropylene polymer described in Production Example 1 1.5
2. Fischer-Tropsch wax * 8 1.5
3. Diglyceryl tetraisostearate * 9 1
4). Diisostearyl malate 10
5. Stearyl lactate 10
6). Hydrogenated polyisobutene * 10 30
7). Triethylhexanoin remaining amount 8. Liquid paraffin 5
9.12-Hydroxystearic acid 0.1
10. α-olefin / vinyl pyrrolidone copolymer * 11 0.5
11. Silica anhydride * 12 3.5
12 Bengala 0.1
13. Red 201 No. 0.3
14 Black iron oxide 0.05
15. Titanium oxide 0.2
16. Soy phospholipid 0.01
17. p-Methoxycinnamic acid-2-ethylhexyl 3
18. Antiseptic suitable amount 19. Perfume appropriate amount * 8: CIREBELLE108 (manufactured by CIREBELLE)
* 9: Cosmall 44 (Nisshin Oillio Group)
* 10: Average molecular weight 1000
* 11: ANTARON V-220 (manufactured by ISP)
* 12: AEROSIL 200 (Nippon Aerosil Co., Ltd.)
(製造方法)
A:成分1〜10を100℃で溶解混合する。
B:Aに成分11〜19を加え、均一に混合分散する。
C:Bをチューブに流し込み、冷却してペースト状リップグロスを得た。
(Production method)
A: Components 1 to 10 are dissolved and mixed at 100 ° C.
B: Components 11 to 19 are added to A and mixed and dispersed uniformly.
C: B was poured into the tube and cooled to obtain a pasty lip gloss.
実施例1〜5と同様に評価した結果、実施例8のペースト状リップグロスは、柔らかな使用感、唇へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性に優れたペースト状リップグロスであった。 As a result of evaluation in the same manner as in Examples 1 to 5, the paste-like lip gloss of Example 8 has a soft feeling of use, a feeling of fitting to the lips, a glossy feeling of the cosmetic film, durability of color development, and high temperature shape retention. Excellent pasty lip gloss.
実施例9:アイカラー
(成分) (%)
1.デキストリン脂肪酸エステル *13 2
2.製造例1記載のポリプロピレン重合体 2
3.オゾケライトワックス *14 5
4.トリイソステアリン酸ジグリセリル *2 15.5
5.ミリスチン酸デキストリン 2
6.ベヘニン酸デキストリン 5
7.流動パラフィン 残量
8.水添ポリイソブテン *15 1.5
9.無水ケイ酸 6
10.ナイロン末 5
11.シリコーン処理タルク *16 5.5
12.赤色202号 0.05
13.黄色4号アルミニウムレーキ 0.05
14.青色1号アルミニウムレーキ 0.05
15.雲母チタン 1.5
16.防腐剤 適量
17.香料 適量
*13:レオパール TT(千葉製粉社製)
*14:OZOKERITE WAX SP−273P(STRAHL&PITSCH INC社製)
*15:平均分子量2000
*16:ジメチルポリシロキサン 5%処理
Example 9: Eye color (component) (%)
1. Dextrin fatty acid ester * 13 2
2. Polypropylene polymer described in Production Example 1 2
3. Ozoquelite wax * 14 5
4). Diglyceryl triisostearate * 2 15.5
5. Dextrin myristate 2
6). Dextrin behenate 5
7). Liquid paraffin 8 Hydrogenated polyisobutene * 15 1.5
9. Silicic anhydride 6
10. Nylon powder 5
11. Silicone-treated talc * 16 5.5
12 Red No. 202 0.05
13. Yellow No. 4 aluminum lake 0.05
14 Blue No. 1 aluminum rake 0.05
15. Mica titanium 1.5
16. Preservative appropriate amount17. Perfume appropriate amount * 13: Leo Pearl TT (Chiba Flour Mills)
* 14: OZOKERITE WAX SP-273P (STRAHL & PITSCH INC)
* 15: Average molecular weight 2000
* 16: Dimethylpolysiloxane 5% treatment
(製造方法)
A:成分1〜8を100℃で溶解混合する。
B:Aに成分9〜17を加え、均一に混合分散する。
C:Bを容器に流し込み、冷却固化してアイカラーを得た。
(Production method)
A: Components 1 to 8 are dissolved and mixed at 100 ° C.
B: Components 9 to 17 are added to A and mixed and dispersed uniformly.
C: B was poured into a container and solidified by cooling to obtain an eye color.
実施例1〜5と同様に評価した結果、実施例9のアイカラーは、柔らかな使用感、肌へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性に優れたアイカラーであった。 As a result of evaluation in the same manner as in Examples 1 to 5, the eye color of Example 9 was excellent in a soft feeling of use, a feeling of fitting to the skin, a glossy feeling of the cosmetic film, a long-lasting color development, and a high temperature shape retention. It was eye color.
実施例10:スティック状コンシーラー
(成分) (%)
1.ポリエチレンワックス *3 5
2.製造例1記載のプロピレン重合体 5
3.キャンデリラロウ 2
4.トリ−2−エチルヘキサン酸グリセリル 10
5.トリイソステアリン酸ジグリセリル *2 5
6.メチルフェニルポリシロキサン 15
7.酢酸液状ラノリン 10
8.パラメトキシケイ皮酸2−エチルヘキシル 5
9.酸化チタン 20
10.黄酸化鉄 2
11.ベンガラ 1.0
12.黒酸化鉄 0.1
13.マイカ 残量
14.防腐剤 適量
Example 10: Stick concealer (ingredient) (%)
1. Polyethylene wax * 3 5
2. Propylene polymer described in Production Example 1 5
3. Candelilla Row 2
4). Glyceryl tri-2-ethylhexanoate 10
5. Diglyceryl triisostearate * 2 5
6). Methylphenylpolysiloxane 15
7). Acetic acid liquid lanolin 10
8). 2-Ethylhexyl paramethoxycinnamate 5
9. Titanium oxide 20
10. Yellow iron oxide 2
11. Bengala 1.0
12 Black iron oxide 0.1
13. Mica remaining amount 14. Preservative appropriate amount
(製造方法)
A.成分1〜8を100℃にて混合溶解する。
B.Aに成分9〜14を90℃にて均一に混合する。
C.Bを3本ローラーにて処理する。
D.Cを脱泡し、85℃にてカプセルに溶解充填後、5℃にて冷却して、スティック状コンシーラーを得た。
(Production method)
A. Components 1 to 8 are mixed and dissolved at 100 ° C.
B. Ingredients 9 to 14 are uniformly mixed with A at 90 ° C.
C. Process B with 3 rollers.
D. C was degassed, dissolved and filled in a capsule at 85 ° C., and then cooled at 5 ° C. to obtain a stick concealer.
実施例1〜5と同様に評価した結果、実施例10のスティック状コンシーラーは、柔らかな使用感、肌へのフィット感、化粧膜のツヤ感、発色の持続性、高温の形状保持性に優れたスティック状コンシーラーであった。 As a result of evaluation in the same manner as in Examples 1 to 5, the stick-shaped concealer of Example 10 is excellent in a soft feeling of use, a feeling of fit to the skin, a glossy feeling of the cosmetic film, a color development durability, and a high temperature shape retention. It was a stick concealer.
Claims (4)
(A)重量平均分子量(Mw)が25000〜100000、融点が60℃〜100℃、ゲルパーミエーションクロマトグラフィーによる分子量分布(Mw/Mn)が4.0以下、テトラリン溶媒中135℃にて測定した極限粘度[η]が0.01〜0.5デシリットル/gであるプロピレン重合体
(B)炭化水素ワックス
(C)ポリグリセリン脂肪酸エステル
を含有することを特徴とする油性化粧料。 The following components (A) to (C);
(A) The weight average molecular weight (Mw) was 25,000 to 100,000, the melting point was 60 ° C. to 100 ° C. , the molecular weight distribution (Mw / Mn) by gel permeation chromatography was 4.0 or less, and measured at 135 ° C. in a tetralin solvent. An oily cosmetic comprising a propylene polymer (B) hydrocarbon wax (C) polyglycerin fatty acid ester having an intrinsic viscosity [η] of 0.01 to 0.5 deciliter / g .
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JP2009029718A (en) * | 2007-07-24 | 2009-02-12 | Kose Corp | Cosmetic |
EP2477601B1 (en) * | 2009-09-15 | 2017-09-13 | Union Carbide Chemicals & Plastics Technology LLC | Personal care compositions with ethylene acrylic acid copolymer aqueous dispersions |
US9233064B2 (en) * | 2010-10-20 | 2016-01-12 | Rohm And Haas Company | Hair fixatives |
JP6224316B2 (en) * | 2012-11-28 | 2017-11-01 | 花王株式会社 | Lip cosmetics |
JP6567297B2 (en) * | 2014-03-26 | 2019-08-28 | 株式会社コーセー | Solid powder cosmetic |
JP6411905B2 (en) * | 2015-02-04 | 2018-10-24 | 株式会社コーセー | Oily salmon cosmetic |
JP6647101B2 (en) * | 2015-03-30 | 2020-02-14 | 株式会社コーセー | Solid cosmetics |
CN109745243B (en) * | 2019-01-29 | 2021-07-16 | 上海欧润化妆品有限公司 | Lipstick and preparation process thereof |
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JP2858020B2 (en) * | 1989-12-04 | 1999-02-17 | 株式会社コーセー | Oily solid cosmetics |
JP3207456B2 (en) * | 1991-08-13 | 2001-09-10 | 三菱化学株式会社 | Manufacturing method of polypropylene fine particles |
JP3207458B2 (en) * | 1991-08-16 | 2001-09-10 | 三菱化学株式会社 | Manufacturing method of polypropylene fine particles |
US5302380A (en) * | 1992-06-08 | 1994-04-12 | Revlon Consumer Products Corporation | Cosmetic compositions containing atactic polypropylenes and related methods |
JP4124392B2 (en) * | 1999-12-02 | 2008-07-23 | 株式会社資生堂 | Lipstick composition |
JP2001328918A (en) * | 2000-03-15 | 2001-11-27 | Kose Corp | Oily solid cosmetic |
JP2002316910A (en) * | 2001-04-19 | 2002-10-31 | Kanebo Ltd | Oil-based cosmetic |
US20050159566A1 (en) * | 2002-04-23 | 2005-07-21 | Idemitsu Kosan Co., Ltd | Process for producing highly flowable propylene polymer and highly flowable propylene polymer |
JP2004217613A (en) * | 2002-12-27 | 2004-08-05 | Kose Corp | Oil-based solid cosmetic |
CN1867318B (en) * | 2003-10-15 | 2010-10-06 | 株式会社高丝 | Oily solid cosmetic |
JP2006052155A (en) * | 2004-08-10 | 2006-02-23 | Kose Corp | Oily solid cosmetic |
DE102005026278A1 (en) * | 2005-06-08 | 2005-10-13 | Clariant Gmbh | Composition for use as a cosmetic or pharmaceutical, e.g. as a depilatory or peeling composition, comprises alkene homo- or co-polymer wax prepared by metallocene catalysis |
JP2008189603A (en) * | 2007-02-05 | 2008-08-21 | Kose Corp | Cosmetic |
JP2008247833A (en) * | 2007-03-30 | 2008-10-16 | Kose Corp | Emulsified cosmetic |
JP5007139B2 (en) * | 2007-03-30 | 2012-08-22 | 株式会社コーセー | Surface coating powder and cosmetics containing the same |
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