WO2017170217A1

WO2017170217A1 - Cosmetic set

Info

Publication number: WO2017170217A1
Application number: PCT/JP2017/011982
Authority: WO
Inventors: 知明篠田
Original assignee: 株式会社コーセー
Priority date: 2016-03-31
Filing date: 2017-03-24
Publication date: 2017-10-05
Also published as: KR102396751B1; KR20180126033A; CN108883043B; JP6918780B2; TW201808257A; JPWO2017170217A1; TWI729105B; CN108883043A

Abstract

The present invention addresses the problem of providing a cosmetic set which shows no color blurring in using, causes no color transfer to a cup, etc., has an excellent color transfer-preventing effect, does not give tensional senses after using and is free from trouble of smeared makeup with time. The cosmetic set according to the present invention, by which the aforesaid problem is solved, comprises a first composition and a second composition and is characterized in that: said first composition is first applied to a target area and then said second composition is applied thereon; and the first and second compositions comprise the following components respectively. (First composition) (A) A film-forming silicone resin. (B) A silicone oil having a dynamic viscosity of 1,000-1,000,000 cs at 25^°C. (C) A volatile hydrocarbon oil. (D) A coloring pigment. (Second composition) (E) An oily component which undergoes phase separation when mixed with an equal amount of a mixture, said mixture comprising the aforesaid components (A) and (C) at a mixing ratio by mass of 1:1, and then allowed to stand for 60 minutes at 25^°C.

Description

Cosmetic set

The present invention relates to a cosmetic set including a first composition and a second composition, and relates to a cosmetic set in which the second composition is applied after the first composition is applied to the application part.

In recent years, makeup cosmetics such as lipsticks and foundations have been problematic in terms of makeup collapse over time and color transfer to containers, clothes, and the like. In particular, in lipsticks, there are problems that the lipstick applied to the lips is transferred to dishes such as coffee cups, and that the makeup breaks down over time due to physical sliding of the lips. Consideration has been made.
For example, as a technique for imparting a color transfer prevention effect and a makeup breakage prevention effect, a kinematic viscosity at 25 ° C. on a first composition containing polyisobutylene having a relative mass of 3000 to 1000000 and a volatile hydrocarbon oil. A technique (Patent Document 1) has been proposed in which a second composition containing methylphenylpolysiloxane having a molecular weight of 1000 cs to 7000 cs is applied. However, by applying the second composition on polyisobutylene, which is a hydrocarbon-based resin, the volatilization of the volatile hydrocarbon oil in the first composition is hindered, and it takes time to obtain the effect of preventing makeup collapse. In some cases, color blur occurs. Further, when the content of polyisobutylene having a relative mass of 3,000 to 1,000,000 in the first composition is increased in order to further improve the cosmetic disintegration effect over time, there may be a feeling of a crispness. .

Japanese Patent No. 5719315

Therefore, in the prior art, a cosmetic set that does not bleed when used, has no color transfer to tableware, etc., has an excellent effect of preventing color transfer, has no crispness after use, and does not lose its makeup over time. It was difficult to implement.

As a result of diligent research in view of the above problems, the present inventor has obtained a mixture in which a component (A) film-forming silicone resin and a component (C) volatile hydrocarbon oil are mixed at a mass ratio of 1: 1, When mixed at an equal volume and allowed to stand at 25 ° C. for 60 minutes, it was found that there was an oil agent of component (E) that was phase-separated, and by applying this technology to cosmetics, there was no color blur at the time of use. It has been found that the cosmetic set is excellent in the effect of preventing color transfer. Furthermore, it was found that a cosmetic film having no tactile sensation was formed by adding a silicone oil having a kinematic viscosity of 1000 cs or more at 25 ° C., and the makeup was not easily broken over time. It came to.

That is,
[1] A cosmetic set comprising a first composition and a second composition, wherein the second composition is applied after the first composition is applied to the application part, and the first composition And the 2nd composition is related with the cosmetics set which is what contains the following components, respectively.
(First composition)
(A) Film-forming silicone resin (B) Silicone oil having a kinematic viscosity of 1,000 to 1,000,000 cs at 25 ° C. (C) Volatile hydrocarbon oil (D) Colored pigment (second composition)
Oil of component (E) phase-separated when mixed in an equal amount with a mixture in which component (A) and component (C) are mixed at a mass ratio of 1: 1 and left to stand at 25 ° C. for 60 minutes.

[2] The component (A) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylates / dimethicone) copolymer, and (acrylates / stearyl acrylate / dimethicone methacrylate) copolymer The cosmetic set according to [1].

[3] The cosmetic composition set according to [1] or [2], wherein the content of the component (E) in the second composition is 50 to 99.9% by mass.

[4] The cosmetic set according to any one of [1] to [3], wherein the content of the component (E) in the second composition is 70 to 99.9% by mass.

[5] The content of the component (A) in the first composition is 10 to 50% by mass, the content of the component (B) is 1 to 50% by mass, and the content of the component (C) is 20 The present invention relates to the cosmetic set according to any one of [1] to [4], which is 85% by mass.

[6] The cosmetic set according to any one of [1] to [5], wherein the component (B) is a silicone oil having a kinematic viscosity at 25 ° C. of 10,000 to 1,000,000 cs.

[7] One or more oil agents wherein the component (E) is selected from isostearic acid ester, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinnamic acid ester and vinylpyrrolidone copolymer The cosmetic set according to any one of [1] to [6].

[8] The cosmetic set according to [7], wherein the isostearic acid ester of component (E) is an isostearic acid ester having an emery type isostearic acid group.

[9] The component (E) comprises polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaisotetrastearate One or more oils selected from erythrityl, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitate, ethylhexyl paramethoxycinnamate, and (vinylpyrrolidone / hexadecene) copolymer [1 ] To the cosmetic set according to any one of [7] to [7].

[10] The cosmetic set according to any one of [1] to [9], wherein the cosmetic set is a lip cosmetic set.

The present invention uses a combination of the first composition and the second composition containing a specific oil agent, and is excellent in the effect of preventing color migration without causing color blurring during use. The present invention also provides a cosmetic set that does not lose its makeup over time.

In Example 2, it is the photograph which confirmed the color transfer at the time of combining the 1st composition of the formulation example 1 and the 2nd composition of the formulation example 19 or the comparative formulation example 8. FIG.

Details of the present invention will be described below. In the present specification, “to” means a range including numerical values before and after.

The film-forming silicone resin of the component (A) used in the first composition of the present invention is a compound having a crosslinked structure having a siloxane structure as a main skeleton, and the silicone oil of the component (B) or the component (C). As long as it is dissolved in an oil agent such as volatile hydrocarbon oil and used in cosmetics, it is not particularly limited and can be used. Here, the film-forming property means having a property of forming a film after a solution obtained by dissolving a silicone resin in the volatile hydrocarbon oil of component (C) is spread on a petri dish and dried. In addition, the obtained film | membrane may produce a crack with drying, and does not need to be obtained as one film.

For example, trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylates / dimethicone) copolymer, (acrylates / stearyl acrylate / dimethicone methacrylate) copolymer, and the like can be used. it can.
Commercially available products include X-21-5616 (solid content 60% isododecane solution), X-21-5595 (solid content 60% isododecane solution), KF-7312J (solid content 50% decamethylcyclopentasiloxane solution), KF- 9021 (50% decamethylcyclopentasiloxane solution), KP-545 (solid content 30% decamethylcyclopentasiloxane solution), KP-549 (solid content 40% methyltrimethicone solution), KP-550 (solid content 50%) Isododecane solution (manufactured by Shin-Etsu Chemical Co., Ltd.), BELSIL TMS 803, BELSIL PMS MK Powder (Asahi Kasei Wacker Silicone Co., Ltd.), SR1000, SilForm Flexible resin, SS4267 (35% dimethylpolysiloxane solution) (momentive performer) S. Materials Japan G.K.), BY11-018 (30% decamethylcyclopentasiloxane solution) (Toray Dow Corning Silicone Co., Ltd.), and the like. Can be used.

The content of the film-forming silicone resin of component (A) in the first composition of the present invention is not particularly limited, but is preferably 10 to 50% by mass (hereinafter simply referred to as “%”), more preferably 15 Is 35%, more preferably 15-30%. Within this range, it is more preferable in that a cosmetic film excellent in the effect of preventing the slipperiness and preventing the collapse of the makeup is obtained.

The silicone oil having a kinematic viscosity at 25 ° C. of 1,000 to 1,000,000 cs of the component (B) used in the first composition of the present invention is a silicone oil having fluidity under the conditions of 1 atm and 25 ° C. If it is used for cosmetics, such as siloxane, methyl hydrogen polysiloxane, phenyl modified silicone, alkyl modified silicone, etc., it will not restrict | limit, These can use 1 type (s) or 2 or more types. The kinematic viscosity at 25 ° C. of component (B) is preferably from 1,000 to 1,000,000 cs, more preferably from 10,000 to 1,000,000 cs, and particularly preferably from 10,000 to 100,000 cs. Within this range, it is more preferable in terms of being able to suppress the feeling of touch due to the silicone resin and obtaining a cosmetic film having an excellent effect of preventing makeup collapse. On the other hand, if the silicone oil has a kinematic viscosity at 25 ° C. of less than 1000 cs, it may not be possible to obtain a satisfactory color bleed prevention effect or anti-decoration effect. If the silicone oil has a kinematic viscosity at 25 ° C. of more than 1,000,000 cs, In some cases, the volatilization rate of the component (C) becomes slow, and a satisfactory color blur prevention effect cannot be obtained.
Commercially available products include KF-96-1000cs / 3000cs / 5000cs, KF-96H-6000cs / 10,000cs / 12500cs / 30,000cs / 50,000cs / 60,000cs / 100,000cs / 300,000cs / 500,000cs / 1 million cs, KF-50-1000 cs (from Shin-Etsu Chemical Co., Ltd.), SH-200 C Fluid 1000CS / 3000CS / 5000CS / 10000CS / 12500CS / 30000CS / 60000CS / 100000CS / 1000000CS, BY11-040 / 003 / 007/014/026/320 (above, manufactured by Toray Dow Corning). These can use only 1 type, or can also be used, adjusting 2 or more types suitably to predetermined | prescribed dynamic viscosity. In the present invention, the kinematic viscosity is a value measured at 25 ° C. by the ASTM D445 measuring method.

The content of component (B) in the first composition of the present invention is not particularly limited, but is preferably 1 to 50%, more preferably 3 to 35%, and still more preferably 5 to 30%. Within this range, it is more preferable in terms of being able to suppress the feeling of touch due to the silicone resin and obtaining a decorative film having an excellent effect of preventing makeup collapse.

The volatile hydrocarbon oil of component (C) used in the first composition of the present invention is liquid at 1 atm and 25 ° C., has volatility, has a boiling point in the range of 68 to 260 ° C., carbon Examples thereof include hydrocarbons having a number of 6 to 30. Usually, it is not particularly limited as long as it is used as a cosmetic raw material. Specifically, it is a straight chain hydrocarbon such as normal heptane, isooctane (2,2,4-trimethylpentane, 2,3-dimethylhexane, etc. Etc.), isododecane (2,2,4,6,6-pentamethylheptane, etc.), hydrocarbons having side chains such as isohexadecane, isoeicosaene, etc., or mixtures thereof, isobutene, n-butene, etc. (The degree of polymerization is preferably 4 to 6), and then hydrogenated ones can be mentioned, and one or more can be used in combination as necessary. Examples of the commercially available products include Isopar H (manufactured by ExxonMobil Chemical), Isododecane (manufactured by Bayer), Isohexadecane (manufactured by Unikema), IP Solvent 1620MU, IP Solvent 2028MU, IP Solvent 2835 (above, manufactured by Idemitsu Kosan) Is mentioned. These can use 1 type (s) or 2 or more types.

The content of the volatile hydrocarbon oil of component (C) in the first composition of the present invention is not particularly limited, but is preferably 20 to 85%, more preferably 25 to 80%, still more preferably 30 to 70%. If it is this range, it is more preferable at the point etc. which are excellent in the feeling of no feeling of a touch and the color bleeding at the time of use. Further, the mass ratio of the component (A) to the component (C) is not particularly limited, but (A) :( C) = 3: 1 to 1: from the viewpoint of excellent color bleeding during use. 6 is preferred, 2: 1 to 1: 5 is more preferred, and 1: 1 to 1: 4 is even more preferred.

If the colorant of component (D) used in the first composition of the present invention is a colorant usually used in cosmetics, shapes such as spheres, plates, spindles, needles, fumes, fine particles The particle size such as pigment grade or the particle structure such as porous or nonporous is not particularly limited, and inorganic colored pigments, organic colored pigments, dyes, glitter pigments, metals and the like can be used. . Specific powders include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarine, and bengara, mica Titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide-coated mica, titanium dioxide-coated synthetic phlogopite, titanium dioxide-coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium, fish scale foil, dioxide Luminous pigments such as titanium coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc., red 201, red 202, Red 205 Organic pigment powders such as red 226, red 228, orange 203, orange 204, blue 404, yellow 401, red 3, red 104, red 106, orange 205, yellow 4 , Yellow 5, green 3, blue 1, etc. zirconium, barium or aluminum lake or other organic pigment powders or metal powders such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide Examples include composite powders such as coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like, and if necessary, one or a combination of two or more may be used. it can. These are one or more of fluorine compounds, silicone compounds, metal soaps, lecithins, hydrogenated lecithins, collagens, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. Surface treatment may be performed using

The content of the colorant of component (D) in the first composition of the present invention is not particularly limited, but is preferably 0.0001 to 30%, more preferably 0.001 to 20%.

The first composition of the present invention can contain, in addition to the above components (A) to (D), components that are usually used in cosmetics as long as the effects of the present invention are not hindered. ), Oils other than components (B) and (C), surfactants, monohydric alcohols, polyhydric alcohols, water-soluble polymers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, ultraviolet absorption Agent, moisturizer, antibacterial agent, fragrance, salt, antioxidant, pH adjuster, chelating agent, refreshing agent, anti-inflammatory agent, skin beautifying agent (whitening agent, cell activator, rough skin improver, blood circulation promoter, skin Astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds and the like can be appropriately contained.

Examples of oil agents include hydrocarbons, fats and oils, waxes, hardened oils, ester oils, regardless of the origin, such as animal oils, vegetable oils, synthetic oils, and properties such as solid oils, semi-solid oils, and liquid oils. , Fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils, and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, Fischer-Tropsch wax, molasses, olive oil, castor oil, mink oil, macadamian Fats and oils such as nut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearic acid Polyglyceryl, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol Fatty acid esters, esters such as N-lauroyl-L-glutamic acid di (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methylphenyl Silicones such as polysiloxane and fluorine-modified organopolysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, octanoic acid Dextrin, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, palm Fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, oily gelling agents such as calcium stearate, hydrogenated pentaerythrityl rosin acid, specific alkyl methyl acrylate Examples include oil-soluble resins such as polysiloxane esters, volatile oils such as silicones such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane. Two or more kinds can be used.

Among the oil agents other than the components (B) and (C), the content of the oil agent in the first composition of the present invention is not particularly limited with respect to the oil agent that is liquid at 25 ° C., but the second composition described later Is preferably from 0 to 10%, more preferably from 0 to 5%, from the viewpoint that color bleeding is less likely to occur when the above is applied.

When the component (A) and the component (C) used in the second composition of the present invention are mixed in an equal amount with a mixture in which the mass ratio is 1: 1 and the mixture is allowed to stand at 25 ° C. for 60 minutes, The oil agent of component (E) to be separated is not particularly limited as long as it is used in cosmetics, and can be used.

Examples of the oil of component (E) used in the second composition of the present invention include, but are not limited to, polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, nonaisostearate Polyglyceryl-10, polyglyceryl decaisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate, isostearic acid esters such as ethylhexyl hydroxystearate, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin Lanolin derivatives such as alcohol, trimellitic acid tritridecyl, trimellitic acid ester such as trioctyl trimellitic acid, ethyl hexyl paramethoxycinnamate Para-methoxy cinnamic acid esters, (vinylpyrrolidone / hexadecene) vinyl pyrrolidone copolymers such as copolymers and the like, which may be used alone or in combination of two or more kinds. Among these, the mixture of component (A) and component (C) at a mass ratio of 1: 1 is mixed in an equal amount, and is easy to phase separate when left at 25 ° C. for 60 minutes, and to that. From the standpoint of the effect of preventing color bleeding, etc., polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaisotetrastearate It is more preferable to use one or more selected from erythrityl, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitate, ethylhexyl paramethoxycinnamate, and (vinylpyrrolidone / hexadecene) copolymer. Better Polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate, acetic acid It is particularly preferable to use one or more selected from lanolin, tritridecyl trimellitate, and (vinylpyrrolidone / hexadecene) copolymer.

In the isostearic acid ester, isostearic acid means one kind of branched stearic acid or a mixture of two or more kinds. For example, 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octanoic acid is converted to a branched aldehyde having 9 carbons by oxo reaction of isobutylene dimer, and then carbon is obtained by aldol condensation of this aldehyde. The branched unsaturated aldehyde of formula 18 can be produced by hydrogenation and oxidation (hereinafter abbreviated as “aldol condensation type”), which is commercially available, for example, from Nissan Chemical Industries. 2-Heptylundecanoic acid can be produced by dimerizing nonyl alcohol by a gerbet reaction (also referred to as Guerbet reaction or Gerbe reaction) and oxidizing it, which is commercially available from, for example, Mitsubishi Chemical Corporation. A slightly different similar mixture is commercially available from Nissan Chemical Industries, and a methyl branched type in which the starting alcohol is not linearly saturated is also commercially available from Nissan Chemical Co. (hereinafter abbreviated as "garbet reaction type"). ). Further, methyl-branched isostearic acid is obtained as a by-product at the time of dimer production of oleic acid, for example [for example, J. Amer. Oil Chem. Soc. , 51, 522 (1974)], for example, those commercially available from Emery, USA (hereinafter abbreviated as "emery type"). Further starting materials of dimer acid which is a starting material of emery type isostearic acid may include not only oleic acid but also linoleic acid, linolenic acid and the like. In the present invention, although not particularly limited, phase separation when the components (A) and (C) are mixed in an equal amount with a mixture in which the mass ratio is 1: 1 and the mixture is allowed to stand at 25 ° C. for 60 minutes. From the standpoints of ease of treatment and the effect of preventing color bleeding based thereon, it is more preferably an isostearic acid ester having an emery type isostearic acid group.

Commercially available products include Cosmol 41V, Cosmall 42V, Cosmall 43V, Cosmall 44V (Nisshin Oillio Group Co., Ltd.), ANTARON V-216 (Made by ISP), LIPONATE TDTM (Lipo Chemicals Co., Ltd.), and purified lanolin (Japan) Seika Co., Ltd.), ACELAN SP, CRODAMOL GTIS-LQ- (JP), CRODAMOL PTIS-LQ- (JP) (above, Croda Japan Co., Ltd.), NIKKOL Decaglyn 10-ISV (Nikko Chemicals Co., Ltd.), S Face IS -1009P (Sakamoto Pharmaceutical Co., Ltd.) and the like, and one or more of them can be used.

The content of component (E) in the second composition of the present invention is not particularly limited, but is preferably 50 to 99.9%, and more preferably 70 to 99.9%. Within this range, by using in combination with the first composition, the effect of preventing the color transfer of the first composition is enhanced, the color does not transfer to a coffee cup or the like, and the makeup does not collapse over time. It is more preferable in that a decorative film excellent in the above can be obtained.

In addition to component (E), the second composition of the present invention is an oily component, an oil gelling agent, a powder and a surface-treated product thereof, a surfactant, an aqueous component, as long as the effects of the present invention are not hindered. Other components usually contained in cosmetics, such as ultraviolet absorbers, humectants, antioxidants, cosmetic ingredients, preservatives, pigments, and fragrances can be contained.

Oil components include hydrocarbons, regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. that originate from animal oils, vegetable oils, synthetic oils, etc. , Oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, oily gelling agents and the like. Specifically, waxes such as beeswax, gay wax, carnauba wax, candelilla wax, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl Higher alcohols such as alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, fluorinated oils such as perfluorodecane, perfluorooctane, and perfluoropolyether, dextrin octoate, dextrin laurate, dextrin palmitate, dextrin myristate , Stearic acid dextrin, behenic acid dextrin, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester Le, aluminum isostearate, potassium stearate, include oily gelling agents such as 12-hydroxystearic acid and the like, can be used more than those one or.

The powder is not particularly limited by, for example, a spherical shape, a plate shape, a needle shape, a particle shape such as a haze shape, a fine particle, and a pigment grade, and a particle structure such as a porous shape and a nonporous shape. , Organic powders, pigment powders, composite powders and the like. Specifically, as a colorant, titanium oxide, zinc oxide, black titanium oxide, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, barium sulfate , Chromium oxide, chromium hydroxide, carbon black, tar dyes, etc., as touch modifiers, silicon oxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc , Silicon carbide, boron nitride, nylon powder, polymethyl methacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystalline cellulose, N-acyl lysine, urethane powder Chromatography, and the like. Also, as pearlescent pigments, bismuth oxychloride, mica titanium, iron oxide coated mica, iron oxide coated mica titanium, organic pigment coated mica titanium, aluminum powder, etc., UV blocking agent, fine particle titanium oxide, fine particle zinc oxide, cerium oxide In addition, composite powders such as fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, and barium sulfate-coated mica titanium can be used, and one or more of these can be used. In order to improve dispersibility and adhesion, these powders are used after surface treatment with a surface treatment agent such as silicones, fluorine compounds, metal soaps, oils and the like by a generally known method. Also good.

As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Is mentioned. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples include polyether-modified organopolysiloxane and lecithin.

Examples of the aqueous component include, in addition to water, alcohols such as ethyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, dipropylene glycol, and polyethylene glycol, glycerin, diglycerin, and the like. Examples include glycerols such as glycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
Examples of the UV absorber include UV absorbers such as benzophenone, PABA, and salicylic acid, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Examples of the humectant include proteins, Examples include mucopolysaccharides, collagen, elastin, and keratin. Examples of antioxidants include α-tocopherol and ascorbic acid. Examples of beauty ingredients include vitamins, anti-inflammatory agents, and herbal medicines. Examples of the agent include paraoxybenzoic acid ester, phenoxyethanol, and 1,2 pentadiol.

The shape of the first composition and the second composition of the present invention is not particularly limited, and examples thereof include solid, semi-solid, and liquid forms. The liquid or semi-solid form is preferable, and the liquid form is particularly preferable. The dosage form of the first composition and the second composition of the present invention is not particularly limited, but an oily or water-in-oil type in which the oil phase is a continuous phase is preferable from the viewpoints of usability and cosmetic durability. From the standpoint that the effects of the present invention can be remarkably exhibited, it is more preferable that the oil type has a water content of 1% or less. Moreover, although the shape and dosage form of a 1st composition and a 2nd composition may be the same or different, it is preferable that it is the same from the point which the effect of this invention is exhibited easily.

The method for producing the first composition and the second composition of the present invention is not particularly limited. For example, in the first composition, after components (A) to (D) and an optional oily component are heated and mixed, In the second composition, for example, the component (E) and the optional oily component can be mixed and dispersed after mixing and dispersing any powder or aqueous component uniformly in the container. These powders, aqueous components, and the like can be uniformly heated and mixed, and then poured into a container or mold after pouring and filling, and cooled.

As a cosmetic set containing the first composition and the second composition of the present invention, it is used as a lip cosmetic set such as lipstick, lip gloss, lip treatment, lip balm, lip base for foundation, lipstick overcoat, etc. Is preferred. As a method of use, a method of applying the second composition after applying the first composition to the application part such as the lips is suitable. If this method of use is used, the effect of the present invention is remarkably exhibited. . For example, after apply | coating a 1st composition, what is necessary is just to apply | coat a 2nd composition on a part or all surface of an application part. The time interval from the application of the first composition to the application of the second composition is not particularly limited, and the second composition may be applied immediately after the application of the first composition. Also, the application amount of the first composition and the second composition is not particularly limited. For example, the mass ratio of the application amount of the first composition and the application amount of the second composition in the coating region is 2: 1 to 1: 5. The degree is preferable, and it is more preferably about 1: 1 to 1: 3.

Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

<Experimental example> An example of the oil agent of component (E) used in the second composition>
Experimental Examples 1-12, Experimental Comparative Examples 1-6
About various oil agents, the mixture which mixed trimethylsiloxy silicic acid (corresponding to component (A)) and isododecane (corresponding to component (C)) in a mass ratio of 1: 1, and equal amounts of various oil agents are mixed at 25 ° C. The following evaluation criteria were used to evaluate whether or not phase separation occurred when allowed to stand for 60 minutes. The results are shown in Table 1.

(Evaluation criteria)
(Judgment): (Evaluation)
○: Phase separation ×: No phase separation

* 1: SR1000 (Momentive Performance Materials Japan GK)
* 2: Isododecane (manufactured by Bayer)
* 3: Cosmall 43V (Nisshin Oillio Group)
* 4: Cosmall 41V (Nisshin Oillio Group)
* 5: S-face IS-1009P (Sakamoto Pharmaceutical Co., Ltd.)
* 6: CRODAMOL GTIS (manufactured by Croda Japan)
* 7: ACELAN SP (manufactured by Croda Japan)
* 8: ANTARON V216 (made by IPS Japan)
* 9: LIPONATE TDTM (manufactured by Lipochemicals)
* 10: Cosmall 43N (Nisshin Oillio Group)
* 11: TOG (manufactured by Higher Alcohol Industry)
* 12: Saracos 5408 (Nisshin Oillio Group)
* 13: Cosmall 222 (Nisshin Oillio Group)
* 14: O.D. D. O (Nisshin Oillio Group)

As is clear from Table 1, the experimental examples 1 to 12 were phase-separated, while the comparative experimental examples 1 to 6 were homogeneous solutions without phase separation. In Example 1 using polyglyceryl triisostearate having an emery type isostearic acid group, phase separation was observed, but a comparative experiment using polyglyceryl-2 triisostearate having an isole type isostearic acid group. In Example 1, no phase separation was observed.

<Example 1 Lip Cosmetic Set (Oil Liquid)>
Formulation Examples 1-12, Comparative Formulation Examples 1-4
The 1st composition shown in Table 2 and the 2nd composition shown in Table 3 were prepared according to the following manufacturing method. When used in combination with the first composition and the second composition obtained in Table 2 and Table 3, respectively, there is no color blur at the time of use, an effect of preventing color transfer, an effect of preventing makeup collapse, and a lack of tactile feeling. The results evaluated by the following methods are shown in Tables 4 to 7, respectively.

(First composition)

* 15: BELSIL TMS 803 (Asahi Kasei Wacker Silicone)
* 16: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 17: Esther gum HP (Arakawa Chemical Industries)
* 18: KF-96H-100,000 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 19: KF-96-1000cs (Shin-Etsu Chemical Co., Ltd.)
* 20: KF-96A-100cs (Shin-Etsu Chemical Co., Ltd.)
* 21: AEROSIL300 (Nippon Aerosil Co., Ltd.)
* 22: FLAMENCO RED 420C (BASF)

(Production method of the first composition)
A. Components (1) to (10) are mixed and dissolved by heating.
B. (11) to (18) were added to A and mixed uniformly to obtain a first composition.

(Second composition)

* 23: CIREBELLE 108 (manufactured by CIREBELLE)
* 24: Pearl Dream 18 (manufactured by NOF Corporation)

(Method for producing second composition)
A. Components (1) to (9) are mixed and dissolved by heating.
B. (10) to (11) were added to A and mixed uniformly to obtain a second composition.

(Evaluation item)
No color blur when used

(Evaluation method 1: Sensory evaluation)
Each sample was subjected to a use test by 20 specialist panels to evaluate the absence of bleeding during use. Specifically, after applying the first composition to the lips, each panel panel has 7 levels according to the following Absolute Evaluation Criteria 1 for the absence of color bleeding when the second composition is applied onto the first composition. The average value was calculated from the total score of all the panels of each sample, and judged according to the following criteria.

<Absolute evaluation criteria 1>
(Score): (Evaluation)
6: No blurring at all 5: Little blurring 4: Somewhat blurring 3: Normal 2: Some blurring 1: Blurred 0: Very blurring <Criteria>
(Judgment): (Average score)
◎: 5.0 or more and 6.0 or less ○: 3.5 or more and less than 5.0 △: 2.0 or more and less than 3.5 ×: 0 or more and less than 2.0

As is clear from the results in Table 4, Examples (shaded portions in the table) using the combination examples of Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are comparative examples. Compared with (other than the shaded part in the table), it was excellent in no bleeding at the time of use.

(Evaluation item)
Color transfer prevention effect

(Evaluation method 2: Sensory evaluation)
Each sample was subjected to a use test by 20 professional panels, and the color transfer prevention effect was evaluated by a professional evaluator. Specifically, after applying the first composition to the lips, 10 seconds after applying the second composition onto the first composition, press the tissue against the lips, remove the tissue, and then apply to the lips of each panel. Visual evaluation by a professional evaluator is performed to determine whether the color of the first composition remains, and it is evaluated in 7 stages according to the following absolute evaluation standard 2, and given a score. From the total score of all the panels of each sample, the average value is calculated. Calculated and determined according to the following criteria.

<Absolute evaluation criteria 2>
(Score): (Evaluation)
6: Remaining 5: Remaining well 4: Remaining slightly 3: Normal 2: Remaining slightly 1: Not remaining 0: Not remaining <Criteria>
(Judgment): (Average score)
◎: 5.0 or more and 6.0 or less ○: 3.5 or more and less than 5.0 △: 2.0 or more and less than 3.5 ×: 0 or more and less than 2.0

As is apparent from the results in Table 5, Examples (shaded portions in the table) using the combination examples of Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are comparative examples. Compared with (other than the shaded part in the table), the color-transfer preventing effect was excellent.

(Evaluation item)
Anti-decoration effect

(Evaluation Method 3: Sensory Evaluation)
Each sample was subjected to a use test by 20 specialist panels to evaluate the effect of preventing the makeup from collapsing. Specifically, after the first composition is applied to the lips, the second composition is applied onto the first composition, and after having spent a normal life, the color of the first composition is changed after 4 hours. Each panel panel was evaluated according to the following Absolute Evaluation Criteria 3 and scored on the lips to give a score, and the average value was calculated from the total score of all the panels for each sample, and judged according to the following criteria. .

<Absolute evaluation criteria 3>
(Score): (Evaluation)
6: Remaining 5: Remaining well 4: Remaining slightly 3: Normal 2: Remaining slightly 1: Not remaining 0: Not remaining <Criteria>
(Judgment): (Average score)
◎: 5.0 or more and 6.0 or less ○: 3.5 or more and less than 5.0 △: 2.0 or more and less than 3.5 ×: 0 or more and less than 2.0

As is clear from the results in Table 6, Examples (shaded areas in the table) using combinations of Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are comparative examples. Compared with (other than the shaded part in the table), the effect of preventing makeup collapse was excellent.

(Evaluation item)
No sense of touch

(Evaluation Method 4: Sensory Evaluation)
Each sample was subjected to a use test by 20 specialist panels to evaluate the lack of tactile sensation. Specifically, after applying the first composition to the lips, after applying the second composition on the first composition, after having spent a normal life, after 4 hours, Each panel member evaluated it according to the following absolute evaluation criteria 4 in 7 grades, gave a score, calculated the average value from the total score of all the panels of each sample, and judged according to the following criteria.

<Absolute evaluation criteria 4>
(Score): (Evaluation)
6: Does not feel very crisp 5: Does not feel crisp 4: Does not feel crisp a little 3: Normal 2: Feels slightly crisp 1: Feels crisp 0: Feels crisp Criteria>
(Judgment): (Average score)
◎: 5.0 or more and 6.0 or less ○: 3.5 or more and less than 5.0 △: 2.0 or more and less than 3.5 ×: 0 or more and less than 2.0

As is apparent from the results in Table 7, examples (shaded areas in the table) using combinations of Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are comparative examples. Compared with (other than the shaded part in the table), it was excellent in the lack of tactile feeling.

<Example 2 Lip Cosmetic Set (Oil Liquid)>
Formulation Examples 13-24, Comparative Formulation Examples 5-10
The 2nd composition shown in Table 8 was prepared according to the following manufacturing method. When each second composition is used in combination with the first composition of Formulation Example 1 shown in Table 2 above, there is no color blur at the time of use, an effect of preventing color transfer, an effect of preventing makeup loss, and a lack of feeling of touch. Was evaluated by the same method as in Example 1. The results are also shown in Table 8. Moreover, about the prescription example 19 and the comparative prescription example 8, the color transfer prevention effect was further evaluated with the following test method. The result is shown in FIG.

(Method for producing second composition)
A. Components (1) to (19) are mixed and dissolved by heating.
B. (20) was added to A and mixed uniformly to obtain a second composition.

(Test method for color transfer prevention effect)
1. 1. 0.1 g of the first composition is applied in a range of 2 cm × 5 cm on synthetic leather (PBZ13001-BK: manufactured by Komatsu Seimitsu Co., Ltd.) 2. Apply 0.15 g of the second composition to the same range. Immediately after application of the second composition, a four-layered tissue is placed on the applied region, and a glass plate (56 g) is placed thereon and left for 15 seconds. Remove the tissue and visually check the color transfer

As shown in the results of Table 8, in the experimental example, when the trimethylsiloxysilicic acid and isododecane were mixed in an equal amount with a mixture in which the mass ratio was 1: 1 and the mixture was allowed to stand at 25 ° C. for 60 minutes, phase separation was performed. The second compositions of Formulation Examples 13 to 24 using the above-described oil agent are excellent in all items of the combination of Formulation Example 1 with no color blur, an anti-color transfer effect, an anti-decoration effect, and no crispness. It was a thing. On the other hand, the second compositions of Comparative Formulation Examples 5 to 10 using the oil agent that did not undergo phase separation were inferior in the absence of color bleeding, the effect of preventing color transfer, and the effect of preventing makeup collapse. In addition, as shown in FIGS. 1 and 2, when the second composition of Formulation Example 19 was used, the color transfer remained in a small part of the coated area, whereas Comparative Formulation Example 8 was used. The color transfer across the entire surface was observed.

Formulation Example 25: Lipstick (first composition)
(Ingredient) (%)
1. (Acrylates / stearyl acrylate /
Dimethicone methacrylate) copolymer 35
2. Dimethylpolysiloxane * 25 10
3. Dimethylpolysiloxane * 18 10
4). Hydrogenated polyisobutene * 26 35
5. 5. Talc remaining amount Silica * 21 1
7). Titanium oxide coated glass powder * 27 2
8). Red No. 202 1
9. Yellow No. 4 aluminum rake 1
10. Black iron oxide 0.2
11. Fragrance 0.01
* 25: KF-96A-5000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 26: IP solvent 1620MU (made by Idemitsu Kosan Co., Ltd.)
* 27: Metashine 1080RC-R (Nippon Sheet Glass Co., Ltd.)
(Production method)
A. Ingredients (1) to (4) are heated and mixed to dissolve uniformly.
B. Add components (5) to (11) to A and mix uniformly.
C. B was filled into a container to obtain a lipstick.

Formulation Example 26: Lipstick (first composition)
(Ingredient) (%)
1. (Acrylates / Dimethicone) Copolymer * 16 45
2. Dimethylpolysiloxane * 28 5
3. Dimethylpolysiloxane * 18 3
4). Hydrogenated polyisobutene * 26 40
5. Boron nitride remaining 6. Silica * 21 1
7). Red No. 202 1
8). Yellow No. 4 aluminum rake 1
9. Black iron oxide 0.2
10. Fragrance 0.01
* 28: KF-96H-50,000 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A. Ingredients (1) to (4) are heated and mixed to dissolve uniformly.
B. Add components (5) to (10) to A and mix uniformly.
C. B was filled into a container to obtain a lipstick.

Formulation Example 27: Lip gloss (second composition)
(Ingredient) (%)
1. Fischer-Tropsch wax 2
2. Dextrin palmitate 5
3. (Vinylpyrrolidone / hexadecene) copolymer * 8 10
4). Diisostearyl malate * 13 5
5. Pentaerythrityl tetraisostearate * 29 30
6). Polyisobutene 5
7). Tridecyl trimellitate 25
8). Trimethylpentaphenyltrisiloxane 2
9. Lauroyl glutamate di (octyldodecyl /
Phytosteryl / behenyl) 5
10. 10. Decaisostearate polyglyceryl-10 remaining amount Silica * 21 1
12 Titanium oxide coated glass powder * 30 2
13. Red No. 202 0.2
14 Yellow No. 4 aluminum lake 0.3
15. Black iron oxide 0.2
16. Ethylhexyl paramethoxycinnamate 1
17. dl-α-topherol 0.1
18. Fragrance 0.01
19. Propyl paraoxybenzoate 0.1
* 29: CRODAMOL PTIS-LQ- (JP) (manufactured by Croda Japan Co., Ltd.)
* 30: Metashine 1080RC-R (Nippon Sheet Glass Co., Ltd.)
(Production method)
A. Ingredients (1) to (10) are heated to 110 ° C. and uniformly dissolved.
B. Ingredients (11) to (19) are added to A and mixed uniformly.
C. B was filled into a container to obtain a lip gloss.

Formulation Example 28: Lip gloss (oil-based solid dish cast, second composition)
(Ingredient) (%)
1. Synthetic wax 7
2. Lanolin acetate 10
3. 3. Polyglyceryl triisostearate-2 * 3 remaining amount Ethyl hexyl hydroxystearate 8
5. Polyglyceryl-2 tetraisostearate-2 * 31 25
6). Polyglyceryl pentaisostearate * 32 10
7). N-lauroyl-L-glutamic acid (phytosteryl / octyldodecyl) 5
8). Dimer linoleic acid (phytosteryl /
Isostearyl / cetyl / stearyl / beheni 10
9. Trimethylsiloxyphenyl dimethicone 5
10. Diphenylsiloxyphenyl trimethicone 1
11. (Vinyl dimethicone / methicone silsesquioxane)
Cross polymer 2
12 Silica * 21 3
13. Red 202 0.5
14 Yellow No. 4 0.03
15. Titanium oxide 0.4
16. Black iron oxide 0.2
17. Titanium oxide-coated synthetic phlogopite * 33 3
* 31: Cosmall 44V (Nisshin Oillio Group)
* 32: NIKKOL Decaglyn 5-SV (manufactured by Nikko Chemicals Co., Ltd.)
* 33: Prominence SF (Topy Industries, Ltd.)
(Production method)
A: Components (1) to (11) are heated to 110 ° C. and dissolved.
B: (12) to (17) are added to A and mixed uniformly.
C: After defoaming B, fill the container at 90 ° C. to obtain a product.

Formulation Example 29: Formulation Example 17: Lipstick (first composition)
(Ingredient) (%)
1. Trimethylsiloxysilicic acid * 1 29
2. 2. Isododecane remaining amount Dimethylpolysiloxane * 18 22
4). Trimethylsiloxyphenyl dimethicone * 34 6
5. Disteadimonium hectorite 3
6.1,3-Butylene glycol 1
7). Red No. 104 1
8). Red No. 202 0.5
9. Yellow No.5 0.5
10. Titanium oxide 0.5
11. PEG-9 polydimethylsiloxyethyl dimethicone 0.1
12 Fragrance 0.01
* 34: BELSIL PDM 1000 (Asahi Kasei Wacker)
(Production method)
A. Ingredients (1) to (6) are heated and mixed to dissolve uniformly.
B. Add components (7) to (12) to A and mix uniformly.
C. B was filled into a container to obtain a lipstick.

Formulation Example 30: Lip Gloss (Second Composition)
(Ingredient) (%)
1. Dextrin palmitate 7
2. Glyceryl triisostearate 50
3. 3. Decaisostearate polyglyceryl-10 remaining amount Dimethylsilylated silica 2
5.1,2-Pentanediol 0.2
(Production method)
A. Ingredients (1) to (5) are heated and dissolved uniformly.
B. A was filled into the container to obtain a lip gloss.

Formulation Example 31: Lipstick (first composition)
(Ingredient) (%)
1. Trimethylsiloxysilicic acid * 1 15
2. Polymethylsilsesquioxane 10
3. Polypropylsilsesquioxane 3
4). 4. Isododecane remaining amount Dimethylpolysiloxane * 18 15
6). Dimethiconol * 35 5
7). Trimethylsiloxyphenyl dimethicone * 33 8
8). Disteadimonium hectorite 3
9. 1,3-Butylene glycol 1
10. Red No. 226 1
11. Red No. 202 0.5
12 Yellow No. 0.5
13. Titanium oxide 0.5
14 PEG-9 polydimethylsiloxyethyl dimethicone 0.1
15. Fragrance 0.01
* 35: X-21-5849 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A. Ingredients (1) to (9) are mixed by heating and dissolved uniformly.
B. Add components (10) to (15) to A and mix uniformly.
C. B was filled into a container to obtain a lipstick.

Formulation Example 32: Lip gloss (oil-based solid dish cast, second composition)
(Ingredient) (%)
1. Dibutyl lauroylglutamide 5
2. Dibutylethylhexanoylglutamide 2
3. Ethylhexyl hydroxystearate 40
4). 4. Non-isoisostearate polyglyceryl-10 remaining amount Dimethylsilylated silica 2
6.1,2-octanediol 0.1
7). Perfluorooctyltriethoxysilane treatment Iron oxide / titanium oxide coated glass powder * 36 0.5
8). Perfluorooctyltriethoxysilane treatment Iron oxide coated glass powder * 37 0.5
* 36: Microglass Metashine MT1080TY (Nippon Sheet Glass Co., Ltd.) treated with 2% perfluorooctyltriethoxysilane * 37: Microglass Metashine MT1080TZ (Nippon Sheet Glass Co., Ltd.) with 2 perfluorooctyltriethoxysilane % Processed (manufacturing method)
A. Ingredients (1) to (8) are heated and dissolved uniformly.
B. A was filled into the container to obtain a lip gloss.

Prescription Example 25 Lipstick and Prescription Example 27 Lip Gloss, Prescription Example 25 Lipstick and Prescription Example 28 Lip Gloss, Prescription Example 26 Lipstick and Prescription Example 27 Lip Gloss, Prescription Example 26 Lipstick and Prescription Example 28 Lip Gloss, Prescription Example 29 Lipstick and Prescription Example 30 Lip Gloss, Formulation Example 31 Lipstick and Formulation Example 32 Lip gloss, a lip cosmetic set used in combination with a formulation example has excellent color transfer prevention effects without causing color blurring during use. There was no feeling and the makeup did not collapse over time.

Claims

A cosmetic set comprising a first composition and a second composition, wherein the second composition is applied after the first composition is applied to the application part, and the first composition and the second composition A cosmetic set in which each composition contains the following components.
(First composition)
(A) Film-forming silicone resin (B) Silicone oil having a kinematic viscosity of 1,000 to 1,000,000 cs at 25 ° C. (C) Volatile hydrocarbon oil (D) Colored pigment (second composition)
Oil of component (E) phase-separated when mixed in an equal amount with a mixture in which component (A) and component (C) are mixed at a mass ratio of 1: 1 and left to stand at 25 ° C. for 60 minutes.
The component (A) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylates / dimethicone) copolymer, and (acrylates / stearyl acrylate / dimethicone methacrylate) copolymer. Item 2. A cosmetic set according to item 1.
The cosmetic set according to claim 1 or 2, wherein the content of the component (E) in the second composition is 50 to 99.9% by mass.
The cosmetic set according to any one of claims 1 to 3, wherein the content of the component (E) in the second composition is 70 to 99.9 mass%.
The content of the component (A) in the first composition is 10 to 50% by mass, the content of the component (B) is 1 to 50% by mass, and the content of the component (C) is 20 to 85% by mass. The cosmetic set according to any one of claims 1 to 4, wherein the cosmetic set is%.
The cosmetic set according to any one of claims 1 to 5, wherein the component (B) is a silicone oil having a kinematic viscosity at 25 ° C of 10,000 to 1,000,000 cs.
The component (E) is one or more oil agents selected from isostearic acid ester, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinnamic acid ester, and vinylpyrrolidone copolymer. Item 7. A cosmetic set according to any one of Items 1 to 6.
The cosmetic set according to claim 7, wherein the isostearic acid ester of the component (E) is an isostearic acid ester having an emery type isostearic acid group.
The component (E) is polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, The oil agent is one or more selected from glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitate, ethylhexyl paramethoxycinnamate, and (vinylpyrrolidone / hexadecene) copolymer. A cosmetic set according to any one of the above.
The cosmetic set according to any one of claims 1 to 9, wherein the cosmetic set is a lip cosmetic set.