CN108883043A

CN108883043A - Cosmetics external member

Info

Publication number: CN108883043A
Application number: CN201780021285.9A
Authority: CN
Inventors: 筱田知明
Original assignee: Kose Corp
Current assignee: Kose Corp
Priority date: 2016-03-31
Filing date: 2017-03-24
Publication date: 2018-11-23
Anticipated expiration: 2037-03-24
Also published as: TWI729105B; TW201808257A; KR102396751B1; CN108883043B; JPWO2017170217A1; KR20180126033A; WO2017170217A1; JP6918780B2

Abstract

Problem of the present invention is that provide when in use it is not permeable dye, do not caused on tableware etc. contamination, it is anti-contamination excellent effect and also use after do not have tight feeling, also not at any time take off adornment cosmetics external member.The cosmetics external member of the invention for solving the project is characterized in that, it includes the 1st composition and the 2nd compositions, 1st composition is applied to coating part, then the 2nd composition is applied on it, and the 1st composition and the 2nd composition contain ingredient below respectively, the silicone resin (B) of (the 1st composition) (A) epithelium formative 25 DEG C of kinematic viscosity be 1000 ~ 1000000cs silicone oil (C) volatility hydrocarbon ils (D) coloring pigment (the 2nd composition) with 1:Simultaneously the finish of ingredient (E) mutually separated occurs when standing 60 minutes for 25 DEG C for mixture mixed in equal amounts that 1 mass ratio mixing aforesaid ingredients (A) and aforesaid ingredients (C) obtain.

Description

Cosmetics external member

Technical field

The present invention relates to the cosmetics external member comprising the 1st composition and the 2nd composition, it is related to for the 1st composition being applied to The cosmetics external member for being coated with position, then applying the 2nd composition on it.

Background technique

In recent years, in the makeup cosmetics such as lipstick, foundation cream, adornment is taken off caused by process at any time, in container, clothes Contamination Deng on becomes problem.Particularly, for lipstick, the lipstick being coated on lip is infected on tablewares such as coffee cup etc. The de- adornment passed through at any time caused by problem, physics rubs mutually of lip etc. becomes problem, has carried out various grind Study carefully.

For example, as the technology for assigning anti-staining effects and anticreep adornment effect, propose comprising have 3000 ~ Using the kinematic viscosity contained at 25 DEG C on the polyisobutene of 1000000 relative mass and the 1st composition of volatility hydrocarbon ils For the technology (patent document 1) of the 2nd composition of the methyl phenyl silicone of 1000cs ~ 7000cs.However, by conduct It is coated with aforementioned 2nd composition on the polyisobutene of hydrocarbon system resin, hampers the volatilization of the volatility hydrocarbon ils in the 1st composition, obtains It needs to expend the time to anticreep adornment effect, occurs to seep dye sometimes.In addition, in order to further increase the de- adornment passed through at any time effect Fruit shows sometimes if increasing the content of the polyisobutene of the relative mass with 3000 ~ 1000000 in the 1st composition Tight feeling out.

Existing technical literature

Patent document

Patent document 1：No. 5719315 bulletins of Japanese Patent No..

Summary of the invention

Subject to be solved by the invention

Therefore, in the prior art, it is difficult to which realization will not seep dye when in use, will not cause contamination, anti-contamination effect on tableware etc. Do not have after fruit is excellent and use tight feeling, will not through at any time taking off the cosmetics external member of adornment.

The means used to solve the problem

The present inventor in view of the above subject furtherd investigate as a result, it has been found that, exist with 1:1 quality is than blending constituent (A) Mixture mixed in equal amounts obtained from silicone resin and ingredient (C) volatility hydrocarbon ils of epithelium formative simultaneously stands 60 at 25 DEG C The finish of the ingredient (E) mutually separated occurs when minute, discovery is not sent out when foring use by the way that the technology is applied to cosmetics The raw cosmetics external member for seeping dye and anti-contamination excellent effect.Further, by being in 25 DEG C of kinematic viscosity containing ingredient (B) The silicone oil of 1000cs or more forms the makeup film without tight feeling, it has further been found that, it is difficult to process at any time takes off adornment, thus Complete the present invention.

That is, being related to：

[1] cosmetics external member, it includes the 1st composition and the 2nd compositions, and the 1st composition is applied to coating position, is then existed The 2nd composition is applied thereon, and the 1st composition and the 2nd composition contain ingredient below respectively,

(the 1st composition)

(A) silicone resin of epithelium formative

(B) 25 DEG C kinematic viscosity be 1000 ~ 1000000cs silicone oil

(C) volatility hydrocarbon ils

(D) coloring pigment

(the 2nd composition)

With with 1:Mixture mixed in equal amounts that 1 mass ratio mixing aforesaid ingredients (A) and aforesaid ingredients (C) obtain and at 25 DEG C The finish of the ingredient (E) mutually separated occurs when standing 60 minutes.

[2] the cosmetics external member according to [1], wherein aforesaid ingredients (A) are selected from trimethylsiloxy silicon Acid, polymethylsilsesquioxane, (acrylate/dimethicone) copolymer, (acrylate/stearyl acrylate base ester/bis- First silicone methacrylates) it is one kind or two or more in copolymer.

[3] the cosmetics external member according to [1] or [2], wherein aforesaid ingredients (E's) in aforementioned 2nd composition contains Amount is 50 ~ 99.9 mass %.

[4] the cosmetics external member according to any one of [1] ~ [3], wherein the aforesaid ingredients in aforementioned 2nd composition (E) content is 70 ~ 99.9 mass %.

[5] the cosmetics external member according to any one of [1] ~ [4], wherein the aforesaid ingredients in aforementioned 1st composition (A) content is 10 ~ 50 mass %, and the content of aforesaid ingredients (B) is 1 ~ 50 mass %, and the content of aforesaid ingredients (C) is 20 ~ 85 matter Measure %.

[6] the cosmetics external member according to any one of [1] ~ [5], wherein aforesaid ingredients (B) are the movements at 25 DEG C Viscosity is the silicone oil of 10000 ~ 1000000cs.

[7] the cosmetics external member according to any one of [1] ~ [6], wherein aforesaid ingredients (E) are selected from isostearic acid Ester, hydroxy stearic acid ester, lanolin derivative, trimellitate, methoxy cinnamic acid ester, vinyl pyrrolidone type copolymerization One kind or two or more finish in object.

[8] the cosmetics external member according to [7], wherein the isostearate of aforesaid ingredients (E) is with Emery type Isostearic acid base isostearate.

[9] the cosmetics external member according to any one of [1] ~ [7], wherein aforesaid ingredients (E) are selected from polyglycereol -2 Isostearate, -2 pentaerythritol tetraisostearate of polyglycereol, nine isostearate of Natrulon H-10, gathers three isostearate of polyglycereol -2 Ten isostearate of glycerol -10, four isostearic acid pentaerythritol esters, three glyceryl isostearates, hydroxy stearic acid ethylhexyl, Acetylated lanolin, tri trimellitate (tridecyl) ester, methoxy cinnamic acid ethylhexyl, (vinyl pyrrolidone/ten Six carbenes) one kind or two or more finish in copolymer.

[10] the cosmetics external member according to any one of [1] ~ [9], wherein aforesaid cosmetic product external member is lip makeup Product external member.

Invention effect

The present invention is provided when in use not by using the 1st composition and the 2nd combination of compositions containing specific finish Occur seep dye, it is anti-contamination excellent effect and also use after without tight feeling, will not at any time through taking off adornment cosmetics set Part.

Detailed description of the invention

[Fig. 1] confirms the 1st composition of combination formula example 1 in example 2 and Formulation Example 19 or compares Formulation Example 8 The photo of contamination when 2 composition.

Specific embodiment

Details of the invention are described below.It should be noted that " ~ " refers to including the numerical value before and after it in this specification Range.

The silicone resin of the epithelium formative of ingredient (A) used in the 1st composition of the invention is that have with siloxanes Compound of the structure as the cross-linked structure of main framing is dissolved in silicone oil, volatility hydrocarbon ils of ingredient (C) of ingredient (B) etc. In finish, as long as the substance used in cosmetics, then can use without particular limitation.Here, epithelium formative is Refer to have to sprawl in ware and silicone resin is dissolved in solution obtained from the volatility hydrocarbon ils of ingredient (C) and forms skin after drying The property of film.It should be noted that gained epithelium can be cracked with dry, not obtained in the form of a film can also be with.

For example, trimethylsiloxy silicic acid, polymethylsilsesquioxane, (the poly- silicon of acrylate/diformazan can be enumerated Oxygen alkane) copolymer, (acrylate/stearyl acrylate base ester/dimethicone methacrylate) copolymer etc., they can It is one kind or two or more to use.

As commercially available product, X-21-5616 (the Permethyl 99A solution that solid component is 60%), X-21-5595 can be enumerated (the Permethyl 99A solution that solid component is 60%), KF-7312J (the decamethylcyclopentaandoxane solution that solid component is 50%), KF-9021 (50% decamethylcyclopentaandoxane solution), KP-545 (solid component be 30% decamethylcyclopentaandoxane solution), KP-549 (the methyl trimethoxy polysiloxane solution that solid component is 40%), (Permethyl 99A that solid component is 50% is molten by KP-550 Liquid) (SHIN-ETSU HANTOTAI's chemical industry (strain) corporation), BELSIL TMS 803, BELSIL PMS MK Powder (Asahi Chemical Industry ワッカーシリコー Application Co., Ltd.), SR1000, SilForm Flexible resin, (35% dimethyl polysiloxane is molten by SS4267 Liquid) (モメ Application ティ Block パフォーマ Application スマテリア Le ズジャパ Application contract commercial firm system), BY11-018 (30% decamethylcyclopentaandoxane solution) (eastern レダウコーニ Application グシリコー Application (strain) corporation) etc., they can It is one kind or two or more to use.

The content of the silicone resin of the epithelium formative of ingredient (A) in the 1st composition of the invention is not particularly limited, Preferably 10 ~ 50 mass % (hereinafter referred to as " % "), more preferably 15 ~ 35%, further preferably 15 ~ 30%.If it is the model It encloses, then it is more preferable from excellent makeup films such as no tight feeling, anticreep adornment effect etc. consideration is obtained.

Ingredient (B) used in the 1st composition of the invention is 1000 ~ 1000000cs in 25 DEG C of kinematic viscosity Silicone oil is silicone oil under conditions of 1 air pressure, 25 DEG C with mobility, as long as dimethyl polysiloxane, methyl hydrogen Substance used in the cosmetics such as polysiloxanes, phenyl modified silicone, alkyl-modified silicone is then not particularly limited, they can be with Using one kind or two or more.In addition, ingredient (B) is preferably 1000 ~ 1000000cs, more preferably in 25 DEG C of kinematic viscosity 10000 ~ 1000000cs, particularly preferably 10000 ~ 100000cs.If it is the range, from being able to suppress because of silicone resin Caused by tight feeling, the considerations such as to obtain in terms of the makeup film of anticreep adornment excellent effect more preferable.On the other hand, if it is 25 DEG C kinematic viscosity be lower than 1000cs silicone oil, then be unable to get gratifying anti-dyeing effect, anticreep adornment effect sometimes, If it is 25 DEG C kinematic viscosity be greater than 1000000cs silicone oil, then the evaporation rate of ingredient (C) is slack-off, sometimes no To gratifying anti-dyeing effect.

As commercially available product, ten thousand cs/ of KF-96-1000cs/3000cs/5000cs, KF-96H-6000cs/1 can be enumerated (the above are letters by ten thousand cs/100 of 12500cs/3 ten thousand cs/5, ten thousand cs/6, ten thousand cs/10, ten thousand cs/30, ten thousand cs/50 ten thousand cs, KF-50-1000cs More chemical industry (strain) corporation), SH-200 C Fluid 1000CS/3000CS/5000CS/10000CS/12500CS/ 30000CS/60000CS/100000CS/1000000CS, BY11-040/003/007/014/026/320, (the above are eastern レダウコーニ Application グ corporation) etc..They can be used only a kind, or combine two or more and appropriate adjustment is defined movement Viscosity come using.It should be noted that in the present invention, kinematic viscosity is obtained by ASTM D445 measuring method in 25 DEG C of survey Definite value.

The content of ingredient (B) in the 1st composition of the invention is not particularly limited, preferably 1 ~ 50%, more preferably 3 ~ It 35%, is more preferably 5 ~ 30%.If it is the range, caused by be able to suppress because of silicone resin tight feeling, obtain Considerations are more preferable in terms of the makeup film of anticreep adornment excellent effect etc..

The volatility hydrocarbon ils of ingredient (C) used in the 1st composition of the invention can be enumerated in 1 atmospheric pressure, 25 It DEG C is liquid, with volatility, the range that boiling point is 68 ~ 260 DEG C, hydrocarbon that carbon atom number is 6 ~ 30 etc..As long as in general, can Substance as cosmetic material, is not particularly limited, specifically, the hydrocarbon of the straight chains such as normal heptane, isooctane can be enumerated (2,2,4- trimethylpentane, 2,3- dimethylhexane etc.), Permethyl 99A (2,2,4,6,6- five methylheptane etc.), different 16 Alkane, Isoeicosane etc. have side chain hydrocarbon or their mixture, by isobutene, n-butene etc. polymerize or be copolymerized (degree of polymerization is excellent It is selected as 4 ~ 6) substance obtained from back end hydrogenation etc., one kind or two or more use can be combined as needed.It, can be with as commercially available product Enumerate アイソパー H (エ Network ソ Application モービル chemical company system), Permethyl 99A (バイエ Le corporation), isohexadecane (the above are go out by (ユニケマ corporation), IP ソ Le ベ Application ト 1620MU, IP ソ Le ベ Application ト 2028MU, IP ソ Le ベ Application ト 2835 The emerging production corporation of light) etc..They can be used one kind or two or more.

The content of the volatility hydrocarbon ils of ingredient (C) in the 1st composition of the invention is not particularly limited, preferably 20 ~ 85%, 25 ~ 80%, further preferably 30 ~ 70% are more preferably.If it is the range, from no tight feeling, use when without infiltration The considerations such as the excellent aspect of metachromia are more preferable.In addition, ingredient (A) and ingredient (C's) is not particularly limited containing mass ratio, from making Used time, metachromia is excellent etc. to be considered without seeping, preferably (A):(C)=3:1~1:6,2 are more preferably:1~1:It 5, is more preferably 1: 1~1:4。

Ingredient (D) used in the 1st composition of the invention if colorant be usually used coloring in cosmetics Agent, then for the partial sizes such as the shapes such as spherical, plate, fusiform, needle-shaped, smoke-like, particle, pigment-level or Porous, non-porous Grain structures such as matter etc. are not particularly limited, can be used inorganic colored pigments, organic colored pigments, dyestuff, bright pigment, Metal class etc..As specific powder, may be exemplified out the white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, The colored inorganics such as iron oxide, carbon black, chromium oxide, chromium hydroxide, Prussian blue, ultramarine, iron oxide red pigment, mica titanium, chlorine oxygen Change synthesis phlogopite, titanium dioxide that bismuth, organic pigment processing mica titanium, the mica of titanium dioxide covering, titanium dioxide cover The bismuth oxychloride of covering, iron oxide mica titanium, Prussian blue processing mica titanium, carmine processing mica titanium, guanin, titanium dioxide The glass powder of titanium covering, polyethylene terephthalate aluminium ring oxygen layer fold powder, polyethylene terephthalate Ester polyolefin stacked film powder, polyethylene terephthalate polymethyl methacrylate layers fold the resin layers such as film powder The bright pigments such as folded powder, No. 201 red, No. 202 red, No. 205 red, red 226, red No. 228, orange 203 Number, No. 204 orange, blue organic pigments powders such as No. 404, yellow 401, No. 3 red, No. 104 red, No. 106 red, orange The organic pigments powder such as color 205, yellow 4, Sunset Yellow FCF, green 3, blue zirconiums, barium or the aluminum lake such as No. 1 or also The metal-powders such as aluminium powder, bronze, silver powder, the mica titanium of particulate titanium dioxide covering, the mica titanium of particulate zinc oxide covering, barium sulfate Composite granules such as the mica titanium of covering, the silica containing titanium oxide, the silica containing zinc oxide etc., as needed can group Close one kind or two or more use.It should be noted that fluorine system compound, silicone compound, metallic soap, lecithin can be used in they The one kind or two or more reality of rouge, hydrolecithin, collagen, hydrocarbon, higher fatty acids, higher alcohol, ester, wax, wax, surfactant etc. Apply surface treatment.

The content of the colorant of ingredient (D) in the 1st composition of the invention is not particularly limited, preferably 0.0001 ~ 30%, it is more preferably 0.001 ~ 20%.

1st composition of the invention is other than above-mentioned ingredient (A) ~ (D), in the model for not interfering effect of the invention Enclose, can containing ingredient used in usual cosmetics, such as can suitably contain powder other than ingredient (D), ingredient (B), (C) finish, surfactant, unary alcohol, polyalcohols, water soluble polymer, P-hydroxybenzoic acid derivative, benzene other than The preservatives such as ethoxy-ethanol, ultraviolet absorbing agent, moisturizer, antibacterial agent, fragrance, salt, antioxidant, pH adjusting agent, chelating Agent, freshener, anti-inflammatory agent, skin makeup ingredient (whitening agent, cell activator, pachylosis improver, blood flow ameliorant, skin Skin astringent, anti-grease leakage agent etc.), vitamins, amino acids, nucleic acid, hormone, packet connect compound etc..

As finish, no matter it can be cited for example that the sources such as animal oil, vegetable oil, synthetic oil and solid oil, semisolid The hydro carbons of the characters such as oil, liquid oil, grease type, wax class, hardening oils, ester oil class, fatty acid, higher alcohols, silicone oils, Fluorine system oils, lanolin derivative class, oily gelling agent class, oil-soluble resin, volatility finish etc..Specifically, can lift Atoleine, saualane, vaseline, paraffin, ceresine, microwax, ethylene propylene copolymer, lignite wax, Fischer Tropsch waxes etc. out The grease types such as hydro carbons, vegetable wax, olive oil, castor oil, ermine oil, macadimia nut oil, beeswax, Brazil wax, candelila wax, spermaceti Etc. wax class, SIMMONDSIA CHINENSIS SEED OIL, isooctyl acid spermaceti base ester, isopropyl myristate, isopropyl palmitate, myristic acid octyldodecyl Base ester, tricaprylin, two isostearic acid polyglycerol esters, three isostearic acids, two glyceride, San behenic acid glyceride, malic acid Two iso stearyl esters, two sad neopentyl glycol ester, cholesterol fatty acid ester, (gallbladder consolidates alkenyl to N- lauroyl-Pidolidone two Mountain Yu base octyldodecyl) esters, stearyl alcohol, cetanol, laruyl alcohol, oleyl alcohol, isooctadecanol, the behenyl alcohol such as ester etc. be advanced Silicones, perfluoro decane, perfluorooctane, the perfluoropolyether such as alcohols, methyl phenyl silicone, fluorine richness organopolysiloxane etc. It is the lanolin derivatives such as fluorine system finish class, lanolin, acetylated lanolin, lanolin fatty acid isopropyl esters, lanolin alcohol, pungent Sour dextrin ester, lauric acid dextrin ester, Dextrin palmitate ester, myristic acid dextrin ester, stearic acid dextrin ester, behenic acid dextrin ester, Coco-nut oil fatty acid dextrin ester, (palmitinic acid/octanoic acid) dextrin ester, sucrose fatty ester, starch aliphatic ester, 12- hydroxy stearate The oily gelling agent such as acid, calcium stearate class, hydroabietic acid pentaerythritol ester, specific acrylic acid alkyl methyl polysiloxane ester Equal oil-soluble resins, decamethylcyclopentaandoxane, octamethylcy-clotetrasiloxane, methyl trimethoxy polysiloxanes, low polymerization degree diformazan The one kind or two or more of these can be used in volatility finish of the silicones such as based polysiloxane etc. etc..

In finish other than mentioned component (B), (C), in the finish that 25 DEG C are liquid, the 1st composition of the invention In the content of the finish be not particularly limited, be difficult to when applying aftermentioned 2nd composition above to seep dye in terms of etc. go out Hair, preferably 0 ~ 10%, more preferably 0 ~ 5%.

Used in the 2nd composition of the invention and with 1:1 quality is more mixed than what blending constituent (A) and ingredient (C) obtained Close object mixed in equal amounts and the ingredient (E) that mutually separates occurs when standing 60 minutes for 25 DEG C as long as finish cosmetics in use Substance, then can use without particular limitation.

An example of finish as ingredient (E) used in the 2nd composition of the invention, is not particularly limited, Ke Yiju - 2 isostearate of polyglycereol, three isostearate of polyglycereol -2, -2 pentaerythritol tetraisostearate of polyglycereol, Natrulon H-10 nine are different out The different tristearin such as stearate, ten isostearate of Natrulon H-10, four isostearic acid pentaerythritol esters, three glyceryl isostearates The hydroxy stearic acid esters such as acid esters, hydroxy stearic acid ethylhexyl, lanolin, acetylated lanolin, lanolin fatty isopropyl propionate, The trimellitates such as the lanolin derivatives such as lanolin alcohol, tri trimellitate (tridecyl) ester, trioctyl trimellitate (TOTM), to first The vinyl such as the methoxy cinnamic acids esters such as oxygroup cinnamic acid ethylhexyl, (vinyl pyrrolidone/hexadecene) copolymer Pyrrolidones based copolymer etc., they can combine one kind or two or more use.Among these, from with 1:1 mass ratio is mixed The mixture mixed in equal amounts that synthesis point (A) and ingredient (C) obtain and mutually separation easiness and base when standing 60 minutes for 25 DEG C In the viewpoints such as this anti-dyeing effect, more preferably using selected from -2 isostearate of polyglycereol, the different tristearin of polyglycereol -2 three It is acid esters, -2 pentaerythritol tetraisostearate of polyglycereol, nine isostearate of Natrulon H-10, ten isostearate of Natrulon H-10, four different hard Resin acid pentaerythritol ester, three glyceryl isostearates, hydroxy stearic acid ethylhexyl, acetylated lanolin, tri trimellitate (ten Trialkyl) ester, methoxy cinnamic acid ethylhexyl, a kind or 2 kinds in (vinyl pyrrolidone/hexadecene) copolymer More than, particularly preferably using selected from -2 isostearate of polyglycereol, three isostearate of polyglycereol -2, the different tristearin of polyglycereol -2 four It is acid esters, nine isostearate of Natrulon H-10, ten isostearate of Natrulon H-10, four isostearic acid pentaerythritol esters, three different hard Glycerol, acetylated lanolin, tri trimellitate (tridecyl) ester, (vinyl pyrrolidone/hexadecene) copolymerization It is one kind or two or more in object.

In addition, the isostearic acid in aforementioned isostearate refers to a kind in the stearic acid of branch or of more than two kinds mixed Close object.Such as 5,7,7- trimethyl -2- (1,3,3- trimethyl butyl)-octanoic acid can be manufactured by following manner：Pass through isobutyl The carbongl group synthesis reaction of alkene dimer and be made carbon atom number be 9 branched chain aldehyde, be then made up of the aldol condensation of the aldehyde The branch unsaturated aldehyde that carbon atom number is 18, then carries out plus hydrogen, oxidation are to manufacture (hereinafter referred to as " aldol condensation type "), It is commercially available by such as Nissan Chemical Industries Company.2- heptylundecanoic acid can by by nonyl alcohol using Guerbet reaction ( Referred to as Guerbet reaction, guerbet reaction) and dimerization and aoxidize and manufacture, branch commercially available by such as Mitsubishi Chemical Ind The slightly different similar mixtures in position are commercially available by Nissan Chemical Industries Company, and further originating alcohol is not linear saturation 2 A position branch goes out the type of methyl similarly by (the following overall referred to as " Guerbet reaction of Nissan Chemical companies market Type ").In addition, methyl branch isostearic acid as such as oleic acid dimer manufacture when by-product and obtain (such as J.Amer.Oil Chem.Soc., 51,522 (1974) are middle to be recorded), it can enumerate commercially available by such as U.S. Emery company etc. Substance (hereinafter referred to as " Emery type ").The further starting material of the dimeric dibasic acid of initial substance as Emery type isostearic acid Matter includes not only oleic acid, sometimes further includes linoleic acid, linolenic acid etc..In the present invention, be not particularly limited, from with 1:1 matter It measures the mixture mixed in equal amounts obtained than blending constituent (A) and ingredient (C) and mutually separation at 25 DEG C standing 60 minutes is easy Property and set out based on viewpoints such as this anti-dyeing effects, the more preferably isostearate of the isostearic acid base with Emery type.

As commercially available product, U スモー Le 41V, U スモー Le 42V, U スモー Le 43V, U スモー can be enumerated Le 44V (day clear オイリオグループ Co., Ltd. corporation), ANTARON V-216 (ISP corporation), LIPONATE TDTM (リ Port ケミカ Le ズ corporation), refined wool fat (Nippon Seika K.K.), ACELAN SP, CRODAMOL GTIS-LQ- (JP), CRODAMOL PTIS-LQ- (JP) (the above are クローダジャパ Application Co., Ltd.), NIKKOL Decaglyn 10-ISV (daylight ケミカ Le ズ Co., Ltd.), S Off ェイス IS-1009P (this drug of slope Co., Ltd.) Deng can be used one kind or two or more in them.

The content of ingredient (E) in the 2nd composition of the invention is not particularly limited, preferably 50 ~ 99.9%, more preferably It is 70 ~ 99.9%.If it is the range, from by being imitated with the 1st combination of compositions using the anti-contamination for improving the 1st composition Fruit, obtain will not be in the upper contamination such as coffee cup and will not be in terms of process at any time takes off the excellent makeup film of adornment, makeup retentivity Equal considerations are more preferable.

2nd composition of the invention in the range for not interfering effect of the invention, can contain other than ingredient (E) Oil components, oily gelling agent, powder and their surface treatment, surfactant, water composition, ultraviolet absorbing agent, guarantor The other compositions contained in the usually cosmetics such as humectant, antioxidant, Cosmetic Ingredient, preservative, pigment, fragrance.

As oil components, ingredient (E) can be enumerated no matter with conventional use of animal oil, plant in external cosmetics No matter the hydro carbons of the characters such as the solid oil in the sources such as oil, synthetic oil, lard, liquid oil, ethereal oil, grease type, wax class, Harden oils, ester oil class, fatty acid, higher alcohols, silicone oils, fluorine system oils, oily gelling agent class etc..Specifically, Wax class such as beeswax, spermaceti, Brazil wax, candelila wax, stearic acid, lauric acid, myristic acid, behenic acid, different can be enumerated It is the higher alcohols such as the fatty acids such as stearic acid, oleic acid, stearyl alcohol, cetanol, laruyl alcohol, oleyl alcohol, isooctadecanol, behenyl alcohol, complete The fluorine systems finish such as fluorine decane, perfluorooctane, perfluoropolyether class, sad dextrin ester, lauric acid dextrin ester, Dextrin palmitate ester, meat Myristic acid dextrin ester, stearic acid dextrin ester, behenic acid dextrin ester, coco-nut oil fatty acid dextrin ester, (palmitinic acid/octanoic acid) dextrin The oily gelling agent classes such as ester, sucrose fatty ester, starch aliphatic ester, isostearic acid aluminium, potassium stearate, 12- hydroxy stearic acid Deng they can be used one kind or two or more.

As powder, not over partial sizes such as the shapes such as example spherical, plate, needle-shaped, smoke-like, particle, pigment-level, more Grain structures such as Kong Zhi, non-porous matter etc. are particularly limited to, can enumerate inorganic particle class, organic powder class, pigment powder class, Composite granule class etc..Specifically, titanium oxide, zinc oxide, black oxidation titanium, Prussian blue, group can be enumerated as colorant Blueness, iron oxide red, iron oxide yellow, iron oxide black, aluminium oxide, magnesia, zirconium oxide, magnesium carbonate, calcium carbonate, barium sulfate, oxidation Chromium, chromium hydroxide, carbon black, tar pigment etc. can enumerate silica, alumina silicate, magnesium silicate, silicon as thoughts and feelings regulator Sour magnalium, mica, synthetic mica, synthesis sericite, sericite, talcum, silicon carbide, boron nitride, nylon powder, polymethyl Sour methyl esters, acrylonitrile-methacylate copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, Silk powder, avicel cellulose, N- acyl-lysine, polyurethane powder etc..In addition, can be enumerated as pearlescent pigment Bismuth oxychloride, mica titanium, the mica of iron oxide covering, the mica titanium of iron oxide covering, the mica titanium of organic pigment covering, aluminium powder End etc. can enumerate the cloud that particulate titanium dioxide, particulate zinc oxide, cerium oxide, particulate titanium dioxide cover as ultraviolet light screener Composite granules such as female titanium, the mica titanium of particulate zinc oxide covering, the mica titanium of barium sulfate covering etc., a kind or 2 can be used in they Kind or more.It should be noted that these powders can use silicone, fluorine compounds class, metallic soap to improve dispersibility, adhesion The surface treating agents such as class, finish class be surface-treated using by generally well-known method.

As surfactant, as long as arbitrary substance then can be used in the conventional use of surfactant of cosmetics, it can To enumerate nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant Deng.For example, fatty acid glyceride and its aklylene glycol addition product, polyglyceryl fatty acid ester and its aklylene glycol can be enumerated Addition product, sorbitan fatty acid esters and its aklylene glycol addition product, Crodaret, polyoxy alkylidene Alkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane, lecithin etc..

As water composition, in addition to water, it can be cited for example that the alcohols such as ethyl alcohol, propylene glycol, 1,3-BDO, 1,2- The glycerols such as the glycols such as pentanediol, dipropylene glycol, polyethylene glycol, glycerol, diglycerol, polyglycereol, aloe, hamamelis, The plant extraction liquids such as witch hazel, cucumber, lemon, lavender, rose.

As ultraviolet absorbing agent, it can be cited for example that the ultraviolet radiation absorptions such as benzophenone series, PABA system, salicylic acid system Agent, 4- tert-butyl -4'- methoxy dibenzoylmethane, oxybenzone etc., as moisturizer, it can be cited for example that albumen Matter, mucopolysaccharide, collagen, elastin laminin, keratoprotein etc., as antioxidant, it can be cited for example that alpha-tocopherol, ascorbic acid Deng as Cosmetic Ingredient, it can be cited for example that vitamins, antiphlogistic, crude drug etc. can be enumerated as preservative to hydroxyl Benzoic ether, phenoxetol, 1,2 pentanediols etc..

It as the shape of the 1st composition and the 2nd composition of the invention, is not particularly limited, solid-like, half can be enumerated Solid-like, liquid, it is light from spreading force when using, significantly play effect of the invention from the aspect of, preferably liquid or Semi-solid, particularly preferably liquid.The dosage form of 1st composition and the 2nd composition of the invention is not particularly limited, from using Property, makeup retentivity viewpoint etc. set out, preferably using oily mutually as the oiliness or water-in-oil type of continuous phase.From can significantly play Out from the perspective of effect of the invention, more preferably the content of water is 1% oiliness type below.In addition, the 1st composition and the 2nd Shape, the dosage form of composition may be the same or different, from the viewpoint of being easy to play effect of the invention, preferably It is identical.

The manufacturing method of 1st composition and the 2nd composition of the invention is not particularly limited, such as in the 1st composition, can With by after ingredient (A) ~ (D) and optional oil components heating mixing, by optional powder, water composition etc., uniformly mixing divides It dissipates, is filled with obtaining in container, in the 2nd composition, such as ingredient (E) and optional oil components can be mixed and be divided After dissipating, optional powder, water composition etc. are evenly heated mixing, flow into filling container or mold after being heated dissolution In, cooling obtains.

As the cosmetics external member comprising the 1st composition and the 2nd composition of the invention, it is suitable as lipstick, lip gloss, profit Lipstick, lip frost（lip cream）, bottom adornment lip undertone（リップベース）, lipstick housing（Kou Red オーバーコート）Deng Lip makeup product external member.As application method, it is appropriate that the 1st composition is applied to lip etc. and is coated with position and on it Using the method for the 2nd composition, as long as the application method, then significantly play effect of the invention.For example, the 1st group of coating Some or all of surface overlapping the 2nd composition of coating after closing object, at coating position.After the coating of the 1st composition, Time interval until being coated with the 2nd composition is not particularly limited, and can be coated with the 2nd group at once after the coating of the 1st composition Close object.In addition, the 1st composition is with the application amount of the 2nd composition it is not also specifically limited, for example, the in dispensing area the 1st combines The mass ratio of the application amount of object and the application amount of the 2nd composition is preferably 2:1~1:5 or so, it is more preferably 1:1~1:3 or so.

Embodiment

Hereinafter, enumerating embodiment, the present invention will be described in detail.It should be noted that these are to the present invention without any restriction.

An example > of the finish of ingredient (E) used in the 2nd composition of < experimental example

Experimental example 1 ~ 12, experiment comparative example 1 ~ 6

It, will be with 1 for various finishes:1 mass ratio mixes trimethylsiloxy silicic acid (being equivalent to ingredient (A)) and different ten The mixture that dioxane (being equivalent to ingredient (C)) obtains is mixed with the various finishes of equivalent, and when standing 60 minutes for 25 DEG C, is passed through Following evaluation criteria evaluate whether to occur mutually to separate.The results are shown in tables 1.

(evaluation criteria)

(judgement)：(evaluation)

○ ：Generation mutually separates

× ：Do not occur mutually to separate.

[table 1]

*1：SR1000 (モメ Application ティ Block パフォーマ Application スマテリア Le ズジャパ Application contract commercial firm system)

*2：Permethyl 99A (バイエ Le corporation)

*3：U スモー Le 43V (day clear オイリオグループ corporation)

*4：U スモー Le 41V (day clear オイリオグループ corporation)

*5：S- Off ェイス IS-1009P (this pharmaceutical industries of slope corporation)

*6：CRODAMOL GTIS (クローダジャパ Application corporation)

*7：ACELAN SP (クローダジャパ Application corporation)

*8：ANTARON V216 (アイエスピージャパ Application corporation)

*9：LIPONATE TDTM (リ Port ケミカ Le ズ corporation)

*10：U スモー Le 43N (day clear オイリオグループ corporation)

*11：TOG (advanced アルコー Le industrial group system)

*12：サラ U ス 5408 (day clear オイリオグループ corporation)

*13：U スモー Le 222 (day clear オイリオグループ corporation)

*14：O.D.O (day clear オイリオグループ corporation).

As shown in Table 1, the generation of experimental example 1 ~ 12 mutually separates, and on the other hand, comparative experiments example 1 ~ 6 does not occur mutually to separate And form uniform solution.In addition, the experiment of three isostearate of polyglycereol -2 using the isostearic acid base with Emery type In example 1, it was found that mutually separate, but real using the comparison of three isostearate of polyglycereol -2 of the isostearic acid base with alcohol aldehyde type It tests in example 1, does not find mutually to separate.

< embodiment 1 lip makeup product external member (oiliness liquid) >

Formulation Example 1 ~ 12 compares Formulation Example 1 ~ 4

According to following manufacturing methods, the 2nd composition shown in the 1st composition and table 3 shown in table 2 is prepared.Pass through following methods Without infiltration dye, anti-contamination when evaluating use when the 1st composition obtained in table 2 and table 3 and the 2nd composition to be respectively combined to use Effect, anticreep adornment effect, without tight feeling, result is shown in table 4 ~ 7.

(the 1st composition)

[table 2]

*15：BELSIL TMS 803 (Asahi Chemical Industry ワッカーシリコー Application corporation)

*16：KP-545 (chemical industrial company of SHIN-ETSU HANTOTAI system)

*17：エステ Le ガ system HP (Arakawa Chemical Industries corporation)

*18：Ten thousand cs of KF-96H-10 (chemical industrial company of SHIN-ETSU HANTOTAI system)

*19：KF-96-1000cs (chemical industrial company of SHIN-ETSU HANTOTAI system)

*20：KF-96A-100cs (chemical industrial company of SHIN-ETSU HANTOTAI system)

*21：AEROSIL300 (Japanese アエロジ Le corporation)

*22：FLAMENCO RED 420C (BASF AG's system).

(manufacturing method of the 1st composition)

A. ingredient (1) ~ (10) are mixed and heated dissolution.

B. (11) ~ (18) are added into A and are uniformly mixed, and the 1st composition is obtained.

(the 2nd composition)

[table 3]

*23：CIREBELLE 108 (CIREBELLE corporation)

*24：パールリー system 18 (day oil corporation).

(manufacturing method of the 2nd composition)

A. ingredient (1) ~ (9) are mixed and heated dissolution.

B. (10) ~ (11) are added into A and are uniformly mixed, and the 2nd composition is obtained.

(assessment item)

It is contaminated when use without infiltration

(evaluation method 1：Sensory evaluation)

For each sample, carries out the use carried out by 20 people of panel and test, being contaminated without infiltration when evaluation uses.Specifically, For contaminating without seeping after the 1st composition is coated on lip, when the 2nd composition is coated on the 1st composition, group each one press It is evaluated and is given a mark with 7 stages according to following absolute evaluation benchmark 1, it is always calculated by the scoring of the group crew of each sample Average value is determined by following determinating references.

1 > of < absolute evaluation benchmark

(scoring)：(evaluation)

6：It is contaminated entirely without seeping

5：It is contaminated almost without seeping

4：Slightly contaminated without infiltration

3：Commonly

2：It is a small amount of to seep dye

1：Seep dye

0：It is serious to seep dye

< determinating reference >

(judgement)：(equalization point of scoring)

◎：5.0 or more ~ 6.0 or less

○：3.5 or more ~ it is lower than 5.0

△：2.0 or more ~ it is lower than 3.5

×：0 or more ~ it is lower than 2.0.

[table 4]

As shown in Table 4, the Formulation Example 9 ~ 12 of the Formulation Example 1 ~ 8 of the 1st composition and the 2nd composition is applied in combination Embodiment (shadow part in table) compared with comparative example (part other than shadow part in table), it is excellent without dye is seeped when use It is different.

(assessment item)

Anti- staining effects

(evaluation method 2：Sensory evaluation)

It for each sample, carries out the use carried out by 20 people of panel and tests, anti-contamination is evaluated by special evaluation personnel and is imitated Fruit.Specifically, using paper handkerchief after the 1st composition is coated on lip, after being coated with the 2nd composition 10 seconds on the 1st composition Lip is pressed, after removing paper handkerchief, carries out the color of the 1st composition on the lip by special each group of evaluation personnel visual valuation Whether remain, evaluated according to following absolute evaluation benchmark 2 with 7 stages and given a mark, is commented by the group crew of each sample Divide and always calculate its average value, is determined by following determinating references.

2 > of < absolute evaluation benchmark

(scoring)：(evaluation)

6：There are many residual

5：It remains more

4：Slightly remain

3：Commonly

2：It does not remain slightly

1：It does not remain

0：It does not remain seriously

< determinating reference >

(judgement)：(equalization point of scoring)

◎：5.0 or more ~ 6.0 or less

○：3.5 or more ~ it is lower than 5.0

△：2.0 or more ~ it is lower than 3.5

×：0 or more ~ it is lower than 2.0.

[table 5]

As shown in Table 5, the Formulation Example 9 ~ 12 of the Formulation Example 1 ~ 8 of the 1st composition and the 2nd composition is applied in combination Embodiment (shadow part in table) compared with comparative example (part other than shadow part in table), anti-contamination excellent effect.

(assessment item)

Anticreep adornment effect

(evaluation method 3：Sensory evaluation)

For each sample, carries out the use carried out by 20 people of panel and test, evaluate anticreep adornment effect.Specifically, by the 1st Composition be coated on lip after, the 2nd composition is coated on the 1st composition after, excessively common life, after 4 hours, for Whether the color of 1 composition remains on lip, group each one evaluated according to following absolute evaluation benchmark 3 with 7 stages And give a mark, its average value is always calculated by the scoring of the group crew of each sample, is determined by following determinating references.

3 > of < absolute evaluation benchmark

(scoring)：(evaluation)

6：There are many residual

5：It remains more

4：Slightly remain

3：Commonly

2：It does not remain slightly

1：It does not remain

0：It does not remain seriously

< determinating reference >

(judgement)：(equalization point of scoring)

◎：5.0 or more ~ 6.0 or less

○：3.5 or more ~ it is lower than 5.0

△：2.0 or more ~ it is lower than 3.5

×：0 or more ~ it is lower than 2.0.

[table 6]

As shown in Table 6, the Formulation Example 9 ~ 12 of the Formulation Example 1 ~ 8 of the 1st composition and the 2nd composition is applied in combination Embodiment (shadow part in table) compared with comparative example (part other than shadow part in table), anticreep adornment excellent effect.

(assessment item)

Without tight feeling

(evaluation method 4：Sensory evaluation)

For each sample, carries out the use carried out by 20 people of panel and test, evaluate without tight feeling.It will specifically, being directed to 1st composition be coated on lip after, the 2nd composition is coated on the 1st composition after, excessively common life, after 4 hours, needle To whether tight feeling is felt, each one is evaluated with 7 stages according to following absolute evaluation benchmark 4 and is given a mark for group, by each examination The scoring of the group crew of sample always calculates its average value, is determined by following determinating references.

4 > of < absolute evaluation benchmark

(scoring)：(evaluation)

6：It totally can not feel tight feeling

5：Imperceptible tight feeling

4：Slightly imperceptible tight feeling

3：Commonly

2：Slightly feel tight feeling

1：Feel tight feeling

0：Seriously feel tight feeling

< determinating reference >

(judgement)：(equalization point of scoring)

◎：5.0 or more ~ 6.0 or less

○：3.5 or more ~ it is lower than 5.0

△：2.0 or more ~ it is lower than 3.5

×：0 or more ~ it is lower than 2.0.

[table 7]

As shown in Table 7, the Formulation Example 9 ~ 12 of the Formulation Example 1 ~ 8 of the 1st composition and the 2nd composition is applied in combination Embodiment (shadow part in table) compared with comparative example (part other than shadow part in table), it is excellent in terms of no tight feeling.

< embodiment 2 lip makeup product external member (oiliness liquid) >

Formulation Example 13 ~ 24 compares Formulation Example 5 ~ 10

The 2nd composition shown in table 8 is prepared according to following manufacturing methods.It will be formulated shown in each 2nd composition and above-mentioned table 2 1st combination of compositions of example 1 evaluates imitating when using without infiltration dye, anti-contamination in use, by method same as Example 1 Fruit, anticreep adornment effect, without tight feeling.Its result is shown in table 8 together.In addition, for Formulation Example 19 and comparing Formulation Example 8, into one Step evaluates anti-staining effects by following test methods.The results are shown in Fig. 1.

(manufacturing method of the 2nd composition)

A. ingredient (1) ~ (19) are mixed and heated dissolution.

B. (20) are added into A and are uniformly mixed, and the 2nd composition is obtained.

(test methods of anti-staining effects)

1. in synthetic leather (PBZ13001-BK：Little Song Refining Co., Ltd. system) on, the 1st group is coated with the range of 2cm × 5cm Close object 0.1g

2. being coated with the 2nd composition 0.15g with same range

3. immediately loading the paper handkerchief of 4 overlappings on the region of coating after the coating of the 2nd composition, loading glass plate on it It (56g) and places 15 seconds

4. removing paper handkerchief and visual confirmation contamination situation.

[table 8]

As shown in the result of table 8, in experimental example, using with 1:1 mass ratio mixes trimethylsiloxy silicic acid The mixture mixed in equal amounts that obtains with Permethyl 99A and the Formulation Example of finish mutually separated occurs when standing 60 minutes for 25 DEG C 13 ~ 24 the 2nd composition in the case where the combination with Formulation Example 1, no infiltration dye, anti-staining effects, anticreep adornment effect, without tight Whole projects of sense are excellent.On the other hand, using the 2nd combination of the comparison Formulation Example 5 ~ 10 for the finish for not occurring mutually to separate Object is wanting in without infiltration dye, anti-staining effects, anticreep adornment effect.In addition, as depicted in figs. 1 and 2, using the 2nd of Formulation Example 19 the In the case where composition, contamination is only limitted to few part among dispensing area, on the other hand, uses the feelings for comparing Formulation Example 8 In condition, confirm almost throughout entire contamination.

Formulation Example 25：Lipstick (the 1st composition)

(ingredient) (%)

1. (acrylate/stearyl acrylate base ester/

Dimethicone methacrylate) copolymer 35

2. dimethyl polysiloxane * 25 10

3. dimethyl polysiloxane * 18 10

4. Parleam * 26 35

5. talcum surplus

6. silica * 21 1

7. the glass powder * 27 2 of titanium oxide covering

8. No. 202 1 red

9. No. 4 aluminum lakes 1 of yellow

10. iron oxide black 0.2

11. fragrance 0.01

*25：KF-96A-5000cs (SHIN-ETSU HANTOTAI's chemical industry (strain) corporation)

*26：IP ソ Le ベ Application ト 1620MU (the emerging production corporation of light out)

*27：メタシャイ Application 1080RC-R (Japanese plate glass corporation)

(manufacturing method)

A. ingredient (1) ~ (4) are heated and is mixed, uniform dissolution.

B. adding ingredient (5) ~ (11) into A, and uniformly mix.

C. B is filled in container and obtains lipstick.

Formulation Example 26：Lipstick (the 1st composition)

(ingredient) (%)

(1. acrylate/dimethicone) copolymer * 16 45

2. dimethyl polysiloxane * 28 5

3. dimethyl polysiloxane * 18 3

4. Parleam * 26 40

5. boron nitride surplus

6. silica * 21 1

7. No. 202 1 red

8. No. 4 aluminum lakes 1 of yellow

9. iron oxide black 0.2

10. fragrance 0.01

*28：Ten thousand cs of KF-96H-5 (SHIN-ETSU HANTOTAI's chemical industry (strain) corporation)

(manufacturing method)

A. ingredient (1) ~ (4) are heated and is mixed, uniform dissolution.

B. adding ingredient (5) ~ (10) into A, and uniformly mix.

C. B is filled in container and obtains lipstick.

Formulation Example 27：Lip gloss (the 2nd composition)

(ingredient) (%)

1. Fischer Tropsch waxes 2

2. Dextrin palmitate ester 5

(3. vinyl pyrrolidone/hexadecene) copolymer * 8 10

4. two iso stearyl ester * 13 5 of malic acid

5. four isostearic acid pentaerythritol ester * 29 30

6. polyisobutene 5

7. trimellitic acid tridecane base ester 25

8. trimethyl pentaphenyltrisiloxane 2

9. lauroyl glutamate two (octyldodecanol/

Phytosterol/behenyl alcohol) ester 5

10. ten isostearate surplus of Natrulon H-10

11. silica * 21 1

12. the glass powder * 30 2 of titanium oxide covering

13. No. 202 0.2 red

14. No. 4 aluminum lakes 0.3 of yellow

15. iron oxide black 0.2

16. methoxy cinnamic acid ethylhexyl 1

17.dl- alpha-tocopherol 0.1

18. fragrance 0.01

19. propylparaben 0.1

*29：CRODAMOL PTIS-LQ- (JP) (クローダジャパ Application strain

Formula commercial firm system)

*30：メタシャイ Application 1080RC-R (Japanese plate glass corporation)

(manufacturing method)

A. ingredient (1) ~ (10) are heated to 110 DEG C, and uniform dissolution.

B. into A, ingredient (11) ~ (19) is added in A and are uniformly mixed.

C. B is filled in container and obtains lip gloss.

Formulation Example 28：(oily solid ware flows into shape to lip gloss（）, the 2nd composition)

(ingredient) (%)

1. synthetic wax 7

2. acetylated lanolin 10

3. the three isostearate * of polyglycereol -2,3 surplus

4. hydroxy stearic acid ethylhexyl 8

5. -2 pentaerythritol tetraisostearate * 31 25 of polyglycereol

6. five isostearic acid polyglycerol ester * 32 10

7.N- lauroyl-Pidolidone

(phytosterol/octyldodecanol) ester 5

8. dimerized linoleic acid (phytosterol/

Isooctadecanol/cetanol/stearyl alcohol/behenyl alcohol ester 10

9. trimethylsiloxyphenyl dimethicone 5

10. diphenyl silicon phenyl front three polysiloxanes 1

(11. vinyl dimethicone/polymethyl siloxane silsesquioxane)

Cross-linked polymer 2

12. silica * 21 3

13. No. 202 0.5 red

14. yellow No. 4 0.03

15. titanium oxide 0.4

16. iron oxide black 0.2

17. the synthesis phlogopite * 33 3 of titanium oxide covering

*31：U スモー Le 44V (day clear オイリオグループ corporation)

*32：NIKKOL Decaglyn 5-SV (daylight ケミズ plants of formulas of カ Le

Commercial firm's system)

*33：プロミネ Application ス SF (トピー industrial group system)

(manufacturing method)

A：Ingredient (1) ~ (11) are warming up to 110 DEG C and are dissolved.

B：(12) ~ (17) are added into A, and are uniformly mixed.

C：After B deaeration, it is filled in container at 90 DEG C and product is made.

Formulation Example 29：Formulation Example 17：Lipstick (the 1st composition)

(ingredient) (%)

1. trimethylsiloxy silicic acid * 1 29

2. Permethyl 99A surplus

3. dimethyl polysiloxane * 18 22

4. trimethylsiloxyphenyl dimethicone * 34 6

5. distearyl dimethylammonium hectorite 3

6.1,3- butanediol 1

7. No. 104 1 red

8. No. 202 0.5 red

9. Sunset Yellow FCF 0.5

10. titanium oxide 0.5

11.PEG-9 poly dimethyl siloxy ethyl dimethicone 0.1

12. fragrance 0.01

*34：BELSIL PDM 1000 (Asahi Chemical Industry's ワッカー corporation)

(manufacturing method)

A. ingredient (1) ~ (6) are heated and is mixed, uniform dissolution.

B. adding ingredient (7) ~ (12) into A, and uniformly mix.

C. B is filled in container and obtains lipstick.

Formulation Example 30：Lip gloss (the 2nd composition)

(ingredient) (%)

1. Dextrin palmitate ester 7

2. three glyceryl isostearates 50

3. ten isostearate surplus of Natrulon H-10

4. dimetylsilyl silica 2

5.1,2- pentanediol 0.2

(manufacturing method)

A. by ingredient (1) ~ (5) heating and uniform dissolution.

B. A is filled in container and obtains lip gloss.

Formulation Example 31：Lipstick (the 1st composition)

(ingredient) (%)

1. trimethylsiloxy silicic acid * 1 15

2. polymethylsilsesquioxane 10

3. poly- propyl silsesquioxane 3

4. Permethyl 99A surplus

5. dimethyl polysiloxane * 18 15

6. dimethiconol * 35 5

7. trimethylsiloxyphenyl dimethicone * 33 8

8. distearyl dimethylammonium hectorite 3

9.1,3- butanediol 1

10. No. 226 1 red

11. No. 202 0.5 red

12. yellow No. 4 0.5

13. titanium oxide 0.5

14.PEG-9 poly dimethyl siloxy ethyl dimethicone 0.1

15. fragrance 0.01

*35：X-21-5849 (chemical industrial company of SHIN-ETSU HANTOTAI system)

(manufacturing method)

A. ingredient (1) ~ (9) are heated and is mixed, uniform dissolution.

B. adding ingredient (10) ~ (15) into A, and uniformly mix.

C. B is filled in container and obtains lipstick.

Formulation Example 32：Lip gloss (oily solid ware flows into shape, the 2nd composition)

(ingredient) (%)

1. dibutyl lauroyl glutamide 5

2. dibutylethyl caproyl glutamine 2

3. hydroxy stearic acid ethylhexyl 40

4. nine isostearate surplus of Natrulon H-10

5. dimetylsilyl silica 2

6.1,2- ethohexadiol 0.1

7. perfluoro capryl triethoxysilane is handled

The glass powder * 36 0.5 of iron oxide titanium oxide covering

8. perfluoro capryl triethoxysilane is handled

The glass powder * 37 0.5 of iron oxide covering

*36：The マイ Network ログラスメタシャイ Application handled with perfluoro capryl triethoxysilane with 2% MT1080TY (Japanese plate glass corporation)

*37：The マイ Network ログラスメタシャイ Application handled with perfluoro capryl triethoxysilane with 2% MT1080TZ (Japanese plate glass corporation)

(manufacturing method)

A. ingredient (1) ~ (8) homogeneous heating is dissolved.

B. A is filled in container and obtains lip gloss.

25 lipstick of Formulation Example and 28 lip gloss of 27 lip gloss of Formulation Example, 25 lipstick of Formulation Example and Formulation Example, 26 lipstick of Formulation Example and 28 lip gloss of 27 lip gloss of Formulation Example, 26 lipstick of Formulation Example and Formulation Example, 30 lip gloss of 29 lipstick of Formulation Example and Formulation Example, 31 mouthfuls of Formulation Example It is red with 32 lip gloss of Formulation Example, combination formula example and the lip makeup product external member used does not occur to seep dye when in use, anti-contamination is imitated Fruit is excellent, and without tight feeling after use, and de- adornment does not also occur for process at any time.

Claims

1. cosmetics external member, it includes the 1st composition and the 2nd compositions, and the 1st composition is applied to coating position, is then existed The 2nd composition is applied thereon, and the 1st composition and the 2nd composition contain ingredient below respectively,

(the 1st composition)

(A) silicone resin of epithelium formative

(B) 25 DEG C kinematic viscosity be 1000 ~ 1000000cs silicone oil

(C) volatility hydrocarbon ils

(D) coloring pigment

(the 2nd composition)

The finish of ingredient (E), with 1:The mixture that 1 mass ratio mixing aforesaid ingredients (A) and aforesaid ingredients (C) obtain Mixed in equal amounts and 25 DEG C stand 60 minutes when, generation mutually separate.

2. cosmetics external member according to claim 1, wherein aforesaid ingredients (A) are selected from trimethylsiloxy silicon Acid, polymethylsilsesquioxane, (acrylate/dimethicone) copolymer, (acrylate/stearyl acrylate base ester/bis- First silicone methacrylates) it is one kind or two or more in copolymer.

3. cosmetics external member according to claim 1 or 2, wherein aforesaid ingredients (E's) in aforementioned 2nd composition contains Amount is 50 ~ 99.9 mass %.

4. cosmetics external member described according to claim 1 ~ any one of 3, wherein the aforesaid ingredients in aforementioned 2nd composition (E) content is 70 ~ 99.9 mass %.

5. cosmetics external member described according to claim 1 ~ any one of 4, wherein the aforesaid ingredients in aforementioned 1st composition (A) content is 10 ~ 50 mass %, and the content of aforesaid ingredients (B) is 1 ~ 50 mass %, and the content of aforesaid ingredients (C) is 20 ~ 85 matter Measure %.

6. cosmetics external member described according to claim 1 ~ any one of 5, wherein aforesaid ingredients (B) are that 25 DEG C of movement is viscous Degree is the silicone oil of 10000 ~ 1000000cs.

7. cosmetics external member described according to claim 1 ~ any one of 6, wherein aforesaid ingredients (E) are selected from isostearic acid Ester, hydroxy stearic acid ester, lanolin derivative, trimellitate, methoxy cinnamic acid ester, vinyl pyrrolidone type copolymerization One kind or two or more finish in object.

8. cosmetics external member according to claim 7, wherein the isostearate of aforesaid ingredients (E) is with Emery type Isostearic acid base isostearate.

9. cosmetics external member described according to claim 1 ~ any one of 7, wherein aforesaid ingredients (E) are selected from polyglycereol -2 Isostearate, -2 pentaerythritol tetraisostearate of polyglycereol, nine isostearate of Natrulon H-10, gathers three isostearate of polyglycereol -2 Ten isostearate of glycerol -10, four isostearic acid pentaerythritol esters, three glyceryl isostearates, hydroxy stearic acid ethylhexyl, Acetylated lanolin, tri trimellitate (tridecyl) ester, methoxy cinnamic acid ethylhexyl, (vinyl pyrrolidone/ten Six carbenes) one kind or two or more finish in copolymer.

10. cosmetics external member described according to claim 1 ~ any one of 9, wherein aforesaid cosmetic product external member is lip makeup Product external member.