KR20180126033A - Cosmetic set - Google Patents

Abstract

The present invention provides a cosmetic set which has no color bleeding at the time of use, has no color transition to a tableware or the like, is excellent in the effect of preventing color transition, has no feeling of pulling after use, and does not break makeup over time . The cosmetic set of the present invention which solves the problems is a cosmetic set comprising a first composition and a second composition wherein the first composition is applied to the application portion and then the second composition is applied, 2 composition is characterized in that it comprises the following components: (first composition) (A) a film-forming silicone resin; (B) a silicone oil having a kinematic viscosity at 25 DEG C of 1000 to 1000000 cs; (C) volatile hydrocarbon oils; (D) Coloring Pigment (Second Composition) A mixture of the component (A) and the component (C) at a mass ratio of 1: 1 was mixed in an equal amount and left at 25 占 폚 for 60 minutes. (E).

Description

Cosmetic set

The present invention relates to a cosmetic set comprising a first composition and a second composition, and relates to a cosmetic set to which the second composition is applied after applying the first composition to the application portion.

BACKGROUND ART [0002] In recent years, in make-up cosmetics such as lip balm, foundation, and the like, cosmetic collapse over time and color transfer to containers and clothes have become a problem. Particularly, in the case of the lip balm, there is a problem that the lip balm applied to the lips is colored and transferred to dishes such as coffee cups, and cosmetic collapse over time due to the physical engagement of the lips, come.

For example, as a technique for imparting a color shift preventing effect and a makeup preventive effect, a composition having a kinematic viscosity at 25 캜 is set on a first composition containing polyisobutylene and a volatile hydrocarbon oil having a relative mass of 3000 to 1000000 A technique of applying a second composition containing methylphenyl polysiloxane of 1000 cs to 7000 cs has been proposed (Patent Document 1). However, when the second composition is applied onto the polyisobutylene, which is a hydrocarbon resin, the volatilization of the volatile hydrocarbon oil in the first composition is hindered, and it takes a long time until the effect of preventing cremation is obtained, There was a case. Further, if the content of polyisobutylene having a relative mass of 3000 to 1000000 in the first composition is increased in order to further improve the creeping effect over time, a feeling of pulling may be felt.

JP 5719315 B

Therefore, in the prior art, there is provided a cosmetic set which is free from color spreading in use, has no color transition to a tableware or the like, has an excellent effect of preventing color transition, has no feeling of pulling after use, .

The present inventors have conducted intensive studies in view of the above problems, and as a result, they have found that mixing the same amount of a mixture of the component (A) film-forming silicone resin and the component (C) volatile hydrocarbon oil at a mass ratio of 1: C. for 60 minutes to find out that there is an emulsion which is a component (E) to be phase-separated. By applying this technique to cosmetics, color bleeding does not occur during use, and a cosmetic set . It has been found that a cosmetic film having no feeling of pulling is formed by containing a silicone oil having a kinematic viscosity at 25 캜 of not less than 1000 cs, and furthermore, the makeup is hardly collapsed over time.

In other words,

[1] A cosmetic set comprising a first composition and a second composition, wherein the first composition is applied to the application part and then the second composition is applied, and the first composition and the second composition each contain the following ingredients Lt; RTI ID = 0.0 > cosmetic < / RTI &

(First composition)

(A) a film-forming silicone resin

(B) a silicone oil having a kinematic viscosity at 25 DEG C of 1000 to 1000000 cs

(C) volatile hydrocarbon oil

(D) a coloring pigment

(Second composition)

(E) which is phase-separated when the components (A) and (C) are mixed at a mass ratio of 1: 1 in an equal amount and left at 25 DEG C for 60 minutes.

[2] The positive resist composition as described in [1], wherein the component (A) is at least one selected from the group consisting of trimethylsiloxysilicate, polymethylsilsesquioxane, (acrylate / dimethicone) copolymer, (copolymer of acrylate / stearyl acrylate / methacrylate dimethicone) And at least one kind selected therefrom.

[3] The cosmetic set described in [1] or [2], wherein the content of the component (E) in the second composition is 50 to 99.9 mass%.

[4] The cosmetic set described in any one of [1] to [3], wherein the content of the component (E) in the second composition is 70 to 99.9 mass%.

[5] The composition according to any one of [1] to [5], wherein the content of the component (A) in the first composition is 10 to 50 mass%, the content of the component (B) is 1 to 50 mass% , And a cosmetic set described in any one of [1] to [4].

[6] The cosmetic composition according to any one of [1] to [5], wherein the component (B) is a silicone oil having a kinematic viscosity at 25 ° C of 10,000 to 1,000,000 cs.

[7] The composition according to any one of [1] to [5], wherein the component (E) is one or more emulsions selected from isostearic acid ester, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinnamic acid ester and vinylpyrrolidone- , And a cosmetic set described in any one of [1] to [6].

[8] The cosmetic set described in [7], wherein the isostearic acid ester of the component (E) is an isostearic acid ester having an isostearic acid group of an emery type.

Wherein the component (E) is at least one selected from the group consisting of polyglyglyceryl isostearate-2, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl- Isostearic acid polyglyceryl-10, tetraisostearic acid pentaerythrityl, triisostearic acid glyceryl, hydroxystearate ethylhexyl, acetic acid lanolin, trimellitic acid trityl decyl, paramethoxycinnamate ethylhexyl, ( Vinylpyrrolidone / hexadecene copolymer), wherein the cosmetic composition of the present invention is at least one kind selected from the group consisting of polyvinylpyrrolidone / vinylpyrrolidone / hexadecene copolymer.

[10] The cosmetic set described in any one of [1] to [9], wherein the cosmetic set is a lip cosmetic set.

INDUSTRIAL APPLICABILITY The present invention can provide a coloring composition which is free from color bleeding during use and excellent in color transfer preventing effect by using a first composition and a second composition containing a specific tanning agent in combination, The cosmetic composition of the present invention does not cause cosmetic collapse of the cosmetic composition.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a photograph showing the color transfer observed when the first composition of Formulation Example 1 and the second composition of Formulation Example 19 or Comparative Example 8 were combined in Example 2. Fig.

Details of the present invention will be described below. In the present specification, " to " means a range including numerical values before and after it.

The film-forming silicone resin of the component (A) used in the first composition of the present invention is a compound having a crosslinked structure having a siloxane structure as a main skeleton. The silicone oil of the component (B) or the volatile It is soluble in an emulsion such as a hydrocarbon oil and is not particularly limited as long as it is used in cosmetics. Here, the term "film-forming property" means that a solution obtained by dissolving a silicone resin in a volatile hydrocarbon oil of component (C) is spread on a chalet and dried to form a film. The obtained coating film may be cracked by drying or may not be obtained as a single film.

Examples thereof include copolymers of trimethylsiloxysilicate, polymethylsilsesquioxane, (acrylate / dimethicone) copolymer, (acrylate / stearyl acrylate / methacrylate dimethicone) copolymer, and the like. These may be used alone or in combination of two or more.

(Solid content 60% isododecane solution), X-21-5595 (solid content 60% isododecane solution), KF-7312J (solid content 50% decamethylcyclopentasiloxane solution), KF KP-545 (solid content 40% methyltrimethicone solution), KP-550 (solid content 50%), KP-5421 (50% decamethylcyclopentasiloxane solution) BELSIL TMS 803, BELSIL PMS MK Powder (Wacker Asahikasei Silicone co., Ltd.)), SR1000, SilForm Flexible Resin (manufactured by Asahi Kasei Kogyo Co., (30% decamethylcyclopentasiloxane solution) (manufactured by Toray Dow Corning Silicone Co., Ltd.), and the like were mixed in a mortar, These can be used alone or in combination of two or more.

The content of the film-forming silicone resin of the component (A) in the first composition of the present invention is not particularly limited, but is preferably from 10 to 50 mass% (hereinafter simply referred to as "%"), more preferably from 15 35%, and more preferably 15 to 30%. Within this range, it is more preferable that a cosmetic film excellent in feeling of pulling-out, effect of preventing crease collapse is obtained, and the like.

The silicone oil having a kinematic viscosity at 25 DEG C of 1000 to 1000000 cs of the component (B) used in the first composition of the present invention is a silicone oil having fluidity under the conditions of 1 atm and 25 DEG C and is a dimethylpolysiloxane, Rosin polysiloxane, phenyl-modified silicone, alkyl-modified silicone and the like, as long as they are used as cosmetics, and they may be used alone or in combination of two or more. The kinematic viscosity at 25 캜 of the component (B) is preferably 1000 to 1000000 cs, more preferably 10000 to 1000000 cs, and particularly preferably 10000 to 100000 cs. Within this range, it is more preferable that a feeling of pulling by the silicone resin can be suppressed and a cosmetic film excellent in anti-creasing effect can be obtained. On the other hand, when silicone oil having a kinematic viscosity at 25 캜 is less than 1000 cs, a satisfactory anti-color spreading effect and anti-creasing effect may not be obtained. When silicone oil having a kinematic viscosity at 25 캜 exceeds 10000 cs, The volatilization rate is slowed and a satisfactory effect of preventing color fading may not be obtained.

Commercially available products include KF-96-1000cs / 3000cs / 5000cs, KF-96H-6000cs / 1 million cs / 12500cs / 30,000 cs / 50,000 cs / KF-50-1000cs (manufactured by Shin-Etsu Chemical Co., Ltd.), SH-200C Fluid 1000CS / 3000CS / 5000CS / 10000CS / 12500CS / 30000CS / 60000CS / 100000CS / 1000000CS, BY-11-040 / 003/007/014/026/320 (manufactured by Toray Dow Corning). These may be used alone or in combination of two or more kinds and adjusted to a predetermined kinematic viscosity appropriately. In the present invention, the kinematic viscosity is a measured value at 25 캜 according to the ASTM D445 measuring method.

The content of the component (B) in the first composition of the present invention is not particularly limited, but is preferably 1 to 50%, more preferably 3 to 35%, and still more preferably 5 to 30%. Within this range, it is more preferable that a feeling of pulling by the silicone resin can be suppressed and a cosmetic film excellent in anti-creasing effect can be obtained.

The volatile hydrocarbon oil of the component (C) used in the first composition of the present invention is liquid at a pressure of 1 atm, at 25 占 폚, is volatile, has a boiling point in the range of 68 to 260 占 폚, And the like. But is not particularly limited as long as it is used as a raw material for cosmetics. Specific examples thereof include linear hydrocarbons such as normal heptane, isooctane (2,2,4-trimethylpentane, 2,3-dimethylhexane Etc.), hydrocarbons having side chains such as isododecane (2,2,4,6,6-pentamethylheptane and the like), isohexadecane and isoeicosane, or mixtures thereof, isobutene, n- (Polymerization degree is preferably from 4 to 6), and then hydrogenation. These may be used alone or in combination of two or more as needed. Examples of commercially available products include ISOPAR H (manufactured by Exxon Mobil Kagaku), isododecane (manufactured by Bayer), isohexadecane (manufactured by Uniqema), IPSolvent 1620MU, IPSolvent 2028MU, IPSolvent 2835 (manufactured by Idemitsu Kosan Co., Ltd.) And the like. These may be used alone or in combination of two or more.

The content of the volatile hydrocarbon oil of the component (C) in the first composition of the present invention is not particularly limited, but is preferably from 20 to 85%, more preferably from 25 to 80%, still more preferably from 30 to 70% . Within this range, it is more preferable that there is no feeling of pulling and no color bleeding at the time of use. (A) :( C) = 3: 1 to 1: 6 is preferable in view of the fact that the content ratio of the component (A) to the component (C) is not particularly limited, More preferably from 2: 1 to 1: 5, and even more preferably from 1: 1 to 1: 4.

The coloring agent of the component (D) used in the first composition of the present invention may be in the form of spheres, plates, spindles, needles, fogs, fine particles, Particle diameter, particle structure such as porous, nonporous, and the like are not particularly limited, and an inorganic colored pigment, an organic colored pigment, a dye, a bright pigment, a metal and the like can be used. Specific examples of the powder include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate; coloring pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, iron oxide, Organic pigment-treated mica titanium, titanium dioxide coated mica, titanium dioxide coated synthetic gold mica, titanium dioxide coated bismuth oxychloride, titanium oxide mica, titanium mica treated with mica, carmine treated mica titanium, napkin, titanium dioxide coated glass horses, polyethylene terephthalate Red luster No. 201, red luster No. 202, red luster No. 205, etc., such as a laminate of phthalate · aluminum · epoxy laminated horses, polyethylene terephthalate · polyolefin laminated film horses, polyethylene terephthalate · polymethyl methacrylate laminated film horses, Yellow No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, etc. Organic pigment powder such as zirconium, barium or aluminum lake such as organic pigment powder, red No. 3, red No. 104, red No. 106, No. 205, No. 4, No. 5, No. 3, A composite powder such as a metal powder such as powder, powder, powder, silver powder, titanium oxide coated with titanium oxide, titanium oxide coated with fine particle zinc oxide, titanium oxide coated with barium sulfate, silicon dioxide containing titanium oxide, or silicon dioxide containing zinc oxide is further exemplified And may be used alone or in combination of two or more as necessary. They may be prepared by using one or more of fluorine-based compounds, silicone-based compounds, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, beeswax, Processing may be performed.

The content of the coloring agent of the component (D) in the first composition of the present invention is not particularly limited, but is preferably 0.0001 to 30%, more preferably 0.001 to 20%.

The first composition of the present invention may contain, in addition to the above components (A) to (D), components commonly used in cosmetics within the range not hindering the effect of the present invention, ), An emulsifier other than the components (B) and (C), surfactants, preservatives such as monohydric alcohols, polyhydric alcohols, water-soluble polymers, paraoxybenzoic acid derivatives and phenoxyethanol, (Such as a whitening agent, a cell activator, a skin roughness improving agent, a blood circulation promoting agent, a skin astringent agent, and an anti-seborrheic agent), vitamins, amino acids , A nucleic acid, a hormone, an inclusion compound and the like.

Examples of the emulsifiable concentrate include, but are not limited to, hydrocarbons, oils, waxes, hydrogenated oils, ester oils, fatty acids, and the like, regardless of the origin of animal oils, vegetable oils, synthetic oils, and solid oils, semi-solid oils, Higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oil gelling agents, oil-soluble resins, volatile emulsions and the like. Specific examples thereof include hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax and Fischer-Tropsch wax, wax, olive oil, castor oil, Mink oil and macadamia nut oil, waxes such as beeswax, carnauba wax, candelilla wax, and wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, Diisostearic acid polyglyceryl, triisostearic acid diglyceryl, tribehenic acid glyceryl, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fatty acid Esters such as N-lauroyl-L-glutamic acid di (cholesteryl / behenyloctyldodecyl), stearyl alcohol, cetyl alcohol, lauryl There may be mentioned, for example, alcohols such as methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, higher alcohols such as oleyl alcohol, isostearyl alcohol and behenyl alcohol, silicones such as methylphenyl polysiloxane and fluorine-modified organopolysiloxane, perfluorodecane, And lanolin derivatives such as lanolin alcohol, lanolin dextrin, lauric acid dextrin, palmitic acid dextrin, myristic acid dextrin, stearic acid dextrin, stearic acid dextrin, Oily gelling agents such as dextrin behenic acid, coconut oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid and calcium stearate, hydrogenated rosin acid pentaerythritol Butyl, and specific alkyl methylpolysiloxane esters, decamethylcyclopentasiloxane, octyl And volatile tackifiers such as silicones such as trimethylcyclotetrasiloxane, methyltrimethicone, and low-polymerization-degree dimethylpolysiloxane, and the like, and one or more of these may be used.

The content of the tanning agent in the first composition of the present invention is not particularly limited with respect to the tanning agent which is liquid at 25 占 폚 among the tanning agents other than the components (B) and (C) It is preferably 0 to 10%, more preferably 0 to 5%, in view of the fact that color bleeding is hardly caused when applied to the substrate.

(A) and the component (C), which are used in the second composition of the present invention, are mixed in an equal amount and the mixture is allowed to stand at 25 占 폚 for 60 minutes, ) Can be used without particular limitation insofar as they are used for cosmetics.

Examples of the emulsions as the component (E) used in the second composition of the present invention include, but are not limited to, isogastearic acid polyglyceryl-2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceride Diisostearic acid polyglyceryl-10, decylisostearic acid polyglyceryl-10, tetraisostearic acid pentaerythrityl, triisostearic acid glyceryl and the like, isostearic acid esters such as hydroxystearic acid Hydroxystearic acid ester such as ethylhexyl, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, trimellitic acid esters such as trimellitic acid tristridecyl and trimellitic trioctyl, Ethylhexyl and the like, a (vinylpyrrolidone / hexadecene) copolymer And the like, and they may be used singly or in combination of two or more kinds. Among them, a mixture obtained by mixing the components (A) and (C) in a mass ratio of 1: 1 was mixed in an equal amount, and the mixture was allowed to stand for 60 minutes at 25 캜 for easy phase separation, 2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl-2, nonisostearic acid polyglyceryl-10, decaisostearic acid polyglyceryl-2, isostearic acid polyglyceryl- -10, pentaerythrityl tetraisostearate, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, trimellitate tridecyldecyl, ethylhexyl paratethoxycinnamate, (vinylpyrrolidone / hexa Decene) copolymer, and more preferably one or more selected from isostearic acid polyglyglyceryl-2, triisostearic acid Polyglyceryl-2, tetraisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl-10, dodecyisostearic acid polyglyceryl-10, tetraisostearic acid pentaerythrityl, triisostearic acid glyceryl , Lanolin acetate, trimellitic acid tridecyldecyl (vinylpyrrolidone / hexadecene) copolymer, and the like are particularly preferably used.

In the isostearic acid ester, isostearic acid means one kind or a mixture of two or more kinds of branched stearic acids. For example, 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octanoic acid is converted to a branched aldehyde having 9 carbon atoms by the oxo reaction of an isobutylene dimer, (Hereinafter abbreviated as " aldol condensation type "), which can be produced, for example, by Nissan Kagaku Kogyo Co., Ltd. And is commercially available. 2-heptylundecanoic acid can be prepared by dimerization of nonyl alcohol with Gerber reaction (Guerbet reaction) and oxidation, which is commercially available, for example, from Mitsubishi Kagaku Co., Nissan Kagaku Kogyo Co., Ltd., and the two types in which the starting alcohol is not linearly saturated are methyl branched, are also commercially available from Nissan Kagaku Co., Ltd. (hereinafter, all are abbreviated as "Gerbere reaction type"). The methyl isostearic acid is obtained as a by-product in the production of dimer of oleic acid (see, for example, J. Amer. Oil Chem. Soc., 51, 522 (1974)], for example, those commercially available from Emery Corporation of USA (hereinafter abbreviated as "emery type"). Another starting material for the dimer acid, which is the starting material of the emery isostearic acid, may include oleic acid, linoleic acid, linoleic acid, and the like. In the present invention, although not particularly limited, it is preferable to mix the components (A) and (C) at a mass ratio of 1: 1 in an equal amount, From the standpoint of preventing color bleeding based on the above, it is more preferable to use an isostearic acid ester having an emulsion type isostearic acid group.

(Commercially available from Nippon Oil Corporation), ANTARON V-216 (from ISP), LIPONATE TDTM (from Lipo Chemicals), and lanolin (from Lipo Chemicals) NIKKOL Decaglyn 10-ISV (Nikko Chemicals Co., Ltd.)), ACELAN SP, CRODAMOL GTIS-LQ- (JP), CRODAMOL PTIS-LQ- (JP) , S-face IS-1009P (Sakamoto Yakuhin Co., Ltd.), and the like, and one or more of them can be used.

The content of the component (E) in the second composition of the present invention is not particularly limited, but is preferably 50 to 99.9%, more preferably 70 to 99.9%. When this range is used in combination with the first composition, the effect of preventing the color transfer of the first composition can be enhanced, and a cosmetic film having excellent cosmetic durability can be obtained without coloring in a coffee cup or the like, Point or the like.

The second composition of the present invention may contain, in addition to the component (E), an oil component, an oil gellant, a powder and a surface treatment product thereof, a surfactant, an aqueous component, An antioxidant, a cosmetic ingredient, an antiseptic, a coloring matter, a perfume, and other components usually contained in cosmetics.

Examples of the oily component include hydrocarbons, oils, fats and oils, which are commonly used in cosmetics in addition to the component (E), regardless of the properties of solid oils, semisolid oils, liquid oils, and volatile oils originating from animal oils, vegetable oils, Waxes, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, and oily gelling agents. Specific examples include waxes such as bees wax, wax, carnauba wax and candelilla wax, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid and oleic acid, stearyl alcohol, cetyl There may be mentioned alcohols such as alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and the like, fluorine oily products such as perfluorodecane, perfluorooctane and perfluoropolyether, (Palmitic / octenoic) dextrin, sucrose fatty acid esters, starch fatty acid esters, isostearic acid, isostearic acid, isostearic acid, malic acid, And oily gelling agents such as aluminum aluminate, potassium stearate and 12-hydroxystearic acid, and these may be used singly or in combination.

The powder is not particularly limited depending on, for example, a shape such as a sphere, a plate, a needle, etc., a shape of a mist, a particle diameter of a particle, a pigment grade, a particle structure such as porous, , Organic fractions, pigment fractions, complex fractions, and the like. Specific examples of the coloring agent include titanium oxide, zinc oxide, titanium black oxide, iron oxide ferrite, iron oxide, red iron oxide, iron oxide yellow, iron oxide black, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, Barium, chromium oxide, chromium hydroxide, carbon black, tar-based coloring matters and the like as a texture adjusting agent, silicon oxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, A binder such as silicon carbide, boron nitride, nylon powder, polymethylmethacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystalline cellulose, N- Acyllysine, urethane powder, and the like. Examples of the pearlescent pigment include fine particles of titanium dioxide, fine particles of zinc oxide, cerium oxide, fine particles of oxide such as bismuth oxychloride, mica titanium oxide, iron oxide coated mica, iron oxide coated mica titanium, organic pigment coated mica titanium and aluminum powder, Titanium-coated titanium oxide, titanium-coated titanium oxide mica, fine titanium oxide-coated mica titanium oxide, and barium sulfate coated titanium oxide mica. These may be used singly or in combination. On the other hand, these powders may be subjected to a surface treatment by a generally known method as surface treating agents such as silicones, fluorine compounds, metal soaps and emulsions in order to improve dispersibility and adhesion.

As the surfactant, any surfactant generally used as a cosmetic can be used, and examples thereof include a nonionic surfactant, an anionic surfactant, a cationic surfactant, and a positive surfactant. For example, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof, polyoxyethylene hydrogenated castor oil, poly Oxyalkylene alkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane, lecithin, and the like.

Examples of the aqueous component include, in addition to water, alcohols such as ethyl alcohol, aliphatic hydrocarbons such as propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, Glycerol such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, locust gel, Hamamelis, cucumber, lemon, lavender, rose and the like.

Examples of the ultraviolet absorber include ultraviolet absorbers such as benzophenone, PABA, and salicylic acid, and 4-tert-butyl-4'-methoxydibenzoylmethane and oxybenzone. Examples of the antioxidant include alpha -tocopherol, ascorbic acid, and the like. Examples of the cosmetic ingredient include vitamins such as vitamin D, carrageenan, , Antiinflammatory agents, herbal medicines and the like. Examples of preservatives include paraoxybenzoic acid ester, phenoxyethanol, 1,2-pentadiol, and the like.

The shape of the first composition and the second composition of the present invention is not particularly limited, and examples thereof include solid, semi-solid, and liquid phases. The spread of the composition is smooth and the effect of the present invention is remarkably exhibited , A liquid or semi-solid form is preferable, and a liquid form is particularly preferable. The formulations of the first composition and the second composition of the present invention are not particularly limited, but oily or water-in-oil type in which the oil phase is a continuous phase is preferable in terms of usability and makeup persistence. From the viewpoint that the effect of the present invention can be remarkably exhibited, it is more preferable that it is a planetary type having a water content of 1% or less. In addition, the shape and formulations of the first composition and the second composition may be the same or different, but they are preferably the same in that the effects of the present invention are easily exhibited.

The first composition and the second composition of the present invention are not particularly limited. For example, in the first composition, the components (A) to (D) and optional oily components are heated and mixed, (E) and an optional oily component are mixed and dispersed, and then an arbitrary powder or an aqueous component is homogeneously mixed and dispersed in the second composition, for example, Heating and mixing the mixture, heating and melting the mixture in a container or a mold, filling the mixture into a container or a mold, and cooling the mixture.

The cosmetic set containing the first composition and the second composition of the present invention is suitably used as a set of lip cosmetics such as lip balm, lip gloss, lip treatment, lip cream, base for lip base, lip balm overcoat . As the method of use, a method of applying the second composition after applying the first composition to a coating portion such as a lips is appropriate, and if this method is used, the effect of the present invention is remarkably exerted. For example, after the first composition is applied, the second composition may be applied over the whole or a part of the surface of the applied portion. The time interval between the application of the first composition and the application of the second composition is not particularly limited, and the second composition may be applied immediately after application of the first composition. The amount of the first composition and the second composition is not particularly limited. For example, the mass ratio of the application amount of the first composition to the application amount of the second composition in the application region is preferably about 2: 1 to 1: 5 , More preferably about 1: 1 to 1: 3.

Example

Hereinafter, the present invention will be described in detail by way of examples. They are not intended to limit the scope of the present invention.

<Experimental Example> Example of the emulsion of the component (E) used in the second composition>

Experimental Examples 1 to 12, Experimental Comparative Examples 1 to 6

A mixture of trimethylsiloxy silicate (corresponding to component (A)) and isododecane (corresponding to component (C)) at a mass ratio of 1: 1 and an equal amount of various tackifiers were mixed with various tackifiers to obtain 25 C for 60 minutes, the degree of phase separation was evaluated according to the following evaluation criteria. The results are shown in Table 1.

(Evaluation standard)

(Judgment): (evaluation)

○: Phase separation

×: No phase separation

* 1: SR1000 (product of Momentive Performance Materials Japan)

* 2: Isododecane (manufactured by Bayer)

* 3: Kosumor 43V (manufactured by Nissin Oil Rio group)

* 4: Cosol 41V (manufactured by Nippon Oil Group)

* 5: S-face IS-1009P (Sakamoto Yakuhin teacher product)

* 6: CRODAMOL GTIS (Kuroda Japan Co., Ltd.)

* 7: ACELAN SP (manufactured by Kuroda Japan)

* 8: ANTARON V216 (ISP Japan)

* 9: LIPONATE TDTM (manufactured by Lipo Chemicals)

* 10: Kosumor 43N (product of Nissin Oil Rio group)

* 11: TOG (manufactured by KOKYU ALCOHOL KOGYO)

* 12: Saracos 5408 (manufactured by Nissin Oil Rio group)

* 13: Kosomol 222 (manufactured by Nippon Oil Corporation)

* 14: O.D.O (manufactured by Nippon Oil Ryo Group)

As is clear from Table 1, Comparative Examples 1 to 6 became a homogeneous solution without phase separation, whereas Examples 1 to 12 were phase separated. In Example 1 using triisostearic acid polyglyceryl-2 having an isomeric isostearic acid group as an emery type, phase separation was observed, but comparison with triisostearic acid polyglyceryl-2 having aldol type isostearic acid group In Experimental Example 1, no phase separation was observed.

<Example 1 Lip Cosmetic Set (Oil-in-Water Liquid)>

Prescription Examples 1 to 12, Comparative Prescription Examples 1 to 4

The first composition shown in Table 2 and the second composition shown in Table 3 were prepared according to the following production methods. No color bleeding, no color shift preventing effect, no crease preventive effect, and no pulling feeling when used in combination with the first and second compositions obtained in Tables 2 and 3 were evaluated by the following methods The results are shown in Tables 4 to 7, respectively.

(First composition)

* 15: BELSIL TMS 803 (manufactured by Asahi Kasei Silicone Co., Ltd.)

* 16: KP-545 (manufactured by Shin-Etsu Chemical)

* 17: Esther blade HP (product Arakawa Kakuko)

* 18: KF-96H-10,000 cs (manufactured by Shin-Etsu Kakuko Co., Ltd.)

* 19: KF-96-1000cs (product of Shin-Etsu Kakuko Co., Ltd.)

* 20: KF-96A-100cs (product of Shin-Etsu Kakuko Co., Ltd.)

* 21: AEROSIL 300 (manufactured by NIPPON AEROSIL)

* 22: FLAMENCO RED 420C (manufactured by BASF)

(Method for producing first composition)

A. Components (1) to (10) are mixed and heated to dissolve.

(11) to (18) were added to B. A and uniformly mixed to obtain a first composition.

(Second composition)

* 23: CIREBELLE 108 (manufactured by CIREBELLE)

* 24: PARLEAM18 (manufactured by NOF CORPORATION)

(Method for producing second composition)

A. Components (1) to (9) are mixed and heated to dissolve.

B. The components (10) to (11) were added to A and uniformly mixed to obtain a second composition.

(Evaluation Items)

No color smear on use

(Evaluation method 1: Sensory evaluation)

Each sample was tested for use by 20 professional panelists and evaluated for no smearing during use. Specifically, regarding the absence of color fading when the first composition was applied to the lips and the second composition was applied on the first composition, each of the panels was evaluated by the following absolute evaluation criteria 1 to 7, The average value was calculated from the summation of the rated power of the panel power of the sample, and it was judged according to the following judgment criteria.

<Absolute Evaluation Standard 1>

(Rating) :( evaluation)

6: It is not spreading at all.

5: Mostly not spreading.

4: It is not spreading somewhat.

3: Usually

2: It is spreading a little.

1: It is spreading.

0: It is very spreading.

<Criteria>

(Judgment): (average point of rating)

?: 5.0 or more to 6.0 or less

?: Not less than 3.5 and not more than 5.0

?: 2.0 or more to less than 3.5

X: not less than 0 and not more than 2.0

As is clear from the results in Table 4, the Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are shown in Comparative Examples ), It was superior in no smearing at the time of use.

(Evaluation Items)

Prevention of color transition

(Evaluation method 2: sensory evaluation)

Each sample was tested for use by 20 professional panelists, and the effect of preventing color shift was evaluated by a professional evaluator. Specifically, after applying the first composition to the lips and then applying the second composition onto the first composition, the tissue is pressed on the lips and the color of the first composition is applied to the lips of each panel after the tissue is removed The evaluation was made by a professional evaluator, and the evaluation was made in seven stages from the absolute evaluation criteria 2 to obtain a rating, and the average value was calculated from the total rating of the panel power sources of the respective samples, .

<Absolute Evaluation Standard 2>

(Rating) :( evaluation)

6: Much remains

5: Stay well

4: Somewhat remained

3: Usually

2: Somewhat remained

1: Not available

0: Not much left

<Criteria>

(Judgment): (average point of rating)

?: 5.0 or more to 6.0 or less

?: Not less than 3.5 and not more than 5.0

?: 2.0 or more to less than 3.5

X: not less than 0 and not more than 2.0

As is clear from the results in Table 5, the examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition were used in combination are shown in Comparative Examples ), The effect of preventing color shift was excellent.

(Evaluation Items)

Anti-crease effect

(Evaluation method 3: sensory evaluation)

Each sample was subjected to a use test by 20 professional panelists to evaluate the effect of preventing cremation. Specifically, after the first composition is applied to the lips, the second composition is applied on the first composition, and then the normal life is performed. After 4 hours, the color of the first composition remains on the lips, Each of them was evaluated in the following absolute evaluation criteria 3 to 7, rated, and the average value was calculated from the sum of the ratings of the panel power sources of the respective samples.

<Absolute Evaluation Criteria 3>

(Rating) :( evaluation)

6: Much remains

5: Stay well

4: Somewhat remained

3: Usually

2: Somewhat remained

1: Not available

0: Not much left

<Criteria>

(Judgment): (average point of rating)

?: 5.0 or more to 6.0 or less

?: Not less than 3.5 and not more than 5.0

?: 2.0 or more to less than 3.5

X: not less than 0 and not more than 2.0

As is clear from the results in Table 6, the Examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition are used in combination are shown in Comparative Examples ), The effect of preventing cremation was excellent.

(Evaluation Items)

No pulling feeling

(Evaluation method 4: sensory evaluation)

Each sample was tested for use by 20 professional panelists and evaluated for no feeling of pulling. Concretely, as to whether the first composition is applied to the lips, then the second composition is applied on the first composition, then the normal life is carried out, and whether or not the user feels pulling after 4 hours, Rated from 4 to 7, rated, and the average value was calculated from the sum of the ratings of the panel power sources of the respective samples.

<Absolute Evaluation Criteria 4>

(Rating) :( evaluation)

6: I do not feel the pull feeling very much

5: I do not feel pulling

4: I do not feel the pulling feeling a little

3: Usually

2: I feel a little pulling.

1: I feel the pulling.

0: I feel a lot of pulling.

<Criteria>

(Judgment): (average point of rating)

?: 5.0 or more to 6.0 or less

?: Not less than 3.5 and not more than 5.0

?: 2.0 or more to less than 3.5

X: not less than 0 and not more than 2.0

As is clear from the results in Table 7, the examples (shaded portions in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition were used in combination were compared with Comparative Example ), The pulling feeling was excellent.

<Example 2 Lip Cosmetic Set (Oil-in-Water Liquid)>

Prescription Examples 13 to 24, Comparative Prescription Examples 5 to 10

The second composition shown in Table 8 was prepared according to the following production method. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. The results are shown in Table 1. &lt; tb &gt; &lt; TABLE &gt; . &Lt; / RTI &gt; The results are also shown in Table 8. With respect to Formulation Example 19 and Comparative Formulation Example 8, the color shift preventing effect was further evaluated by the following test methods. The results are shown in Fig.

(Method for producing second composition)

A. Components (1) to (19) are mixed and heated to dissolve.

B. (20) was added to A and uniformly mixed to obtain a second composition.

(Test method for prevention of color transition)

1. 0.1 g of the first composition is applied to a synthetic leather (PBZ13001-BK: manufactured by Komatsu Seiren Co., Ltd.) in the range of 2 cm x 5 cm

2. Apply 0.15 g of the second composition in the same range

3. Immediately after the application of the second composition, a four-layered tissue is placed on the applied area, and a glass plate (56g) is placed thereon and left for 15 seconds

4. Peel the tissue and visually confirm the color transition state

As shown in the results of Table 8, in the Experimental Example, when a mixture of trimethylsiloxy silicic acid and isododecane in a mass ratio of 1: 1 was mixed in an equal amount and allowed to stand at 25 占 폚 for 60 minutes, The second composition of Formulation Examples 13 to 24 using the emulsifiable concentrate was excellent in all items of no color smearing, color transfer preventing effect, makeup preventive effect, and pulling feeling in combination with Formulation Example 1. On the other hand, the second compositions of Comparative Formulation Examples 5 to 10 using the emulsion without phase separation were deteriorated in terms of no color bleeding, a color transfer preventing effect, and a makeup preventive effect. As shown in Figs. 1 and 2, in the case of using the second composition of Formulation Example 19, the color transfer stays in a small part of the application region, whereas when Comparative Example 8 is used, The spreading color transition was confirmed.

Prescription Example 25: Lip balm (first composition)

(ingredient) (%)

1. (Acrylate / Stearyl Acrylate / Dimethicone Methacrylate) Copolymer 35

2. Dimethylpolysiloxane * 25 10

3. Dimethylpolysiloxane * 18 10

4. Water addition polyisobutaine * 26 35

5. Talk Balance

6. Silica * 21 One

7. Titanium oxide coated glass horses * 27 2

8. Red No. 202 One

9. Yellow No. 4 aluminum rake One

10. Black iron oxide 0.2

11. Spices 0.01

* 25: KF-96A-5000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 26: IP solvent 1620MU (manufactured by Idemitsu Kosan Co., Ltd.)

* 27: Metashain 1080RC-R (manufactured by Nihon Itagaras Co., Ltd.)

(Manufacturing method)

A. The components (1) to (4) are mixed by heating and uniformly dissolved.

B. Add the components (5) to (11) to A and mix them uniformly.

C. B was filled into a container to obtain a lip balm.

Prescription Example 26: Lip balm (first composition)

(ingredient) (%)

1. (Acrylate / dimethicone) copolymer * 16 45

2. Dimethylpolysiloxane * 28 5

3. Dimethylpolysiloxane * 18 3

4. Water addition polyisobutaine * 26 40

5. Boron nitride Balance

6. Silica * 21 One

7. Red No. 202 One

8. Yellow No. 4 Aluminum Lake One

9. Black iron oxide 0.2

10. Spices 0.01

* 28: KF-96H-5,000 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. The components (1) to (4) are mixed by heating and uniformly dissolved.

B. Add the components (5) to (10) to A and mix them uniformly.

C. B was filled in a container to obtain a lip balm.

Prescription Example 27: Lip Gloss (Second Composition)

(ingredient) (%)

1. Fisher Tropsch wax 2

2. Palmitic acid dextrin 5

3. (vinylpyrrolidone / hexadecene) copolymer * 8 10

4. Malandi isostearyl * 13 5

5. Pentaerythrityl tetraisostearate * 29 30

6. Polyisobutene 5

7. Trimellitic acid tridecyl 25

8. Trimethylpentaphenyl trisiloxane 2

9. Lauroyl glutamic acid di (octyldodecyl / phytosteryl / behenyl) 5

10. Polyglyceryl-10 decaisostearic acid Balance

11. Silica * 21 One

12. Titanium oxide coated glass horse * 30 2

13. Red No. 202 0.2

14. Yellow No. 4 Aluminum Lake 0.3

15. Black iron oxide 0.2

16. Ethylhexyl paratethoxycinnamate One

17. dl-a-tocerol 0.1

18. Spices 0.01

19. Propyl paraoxybenzoate 0.1

* 29: CRODAMOL PTIS-LQ- (JP) (manufactured by Kuroda Japan Co., Ltd.)

* 30: Metashain 1080RC-R (manufactured by Nihon Itagaras Co., Ltd.)

(Manufacturing method)

A. Components (1) to (10) are heated to 110 DEG C and dissolved uniformly.

B. Add the components (11) to (19) to A and mix them uniformly.

C. B was filled into a container to obtain a lip gloss.

Prescription Example 28: Lipgloss (oily solid dish-up shape, second composition)

(ingredient) (%)

1. Synthetic wax 7

2. Acetic acid lanolin 10

3. Triisostearic acid polyglyceryl-2 * 3 Balance

4. Ethylhexyl hydroxystearate 8

5. Tetraisostearic acid polyglyceryl-2 * 31 25

6. Polyglyceryl pentaisostearate * 32 10

7. N-lauroyl-L-glutamic acid (phytosteryl / octyldodecyl) 5

8. dimerdinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 10

9. Trimethylsiloxyphenyl dimethicone 5

10. Diphenylsiloxy Phenyltrimethicone One

11. (Vinyl Dimethicone / Methicone Silsesquioxane) Crosspolymer 2

12. Silica * 21 3

13. Red No. 202 0.5

14. Yellow No. 4 0.03

15. Titanium oxide 0.4

16. Black iron oxide 0.2

17. Titanium oxide coated synthetic gold mica * 33 3

* 31: Kosumor 44V (manufactured by Nippon Oil Group)

* 32: NIKKOL Dacaglyn 5-SV (manufactured by Nikko Chemicals Co., Ltd.)

* 33: PROMINENCE SF (Tofico teacher product)

(Manufacturing method)

A: Components (1) to (11) are dissolved by heating at 110 占 폚.

B: (12) to (17) are added to A and uniformly mixed.

C: Degassed B and charged into a container at 90 ° C to obtain a product.

Prescription Example 29: Prescription Example 17: Lip balm (first composition)

(ingredient) (%)

1. Trimethylsiloxy silicate * 1 29

2. Isododecane Balance

3. Dimethylpolysiloxane * 18 22

4. Trimethylsiloxyphenyl dimethicone * 34 6

5. Diastereadamonium hectorite 3

6. 1,3-Butylene glycol One

7. Red No. 104 One

8. Red No. 202 0.5

9. Yellow No. 5 0.5

10. Titanium oxide 0.5

11. PEG-9 Polydimethylsiloxy ethyl dimethicone 0.1

12. Spices 0.01

* 34: BELSIL PDM 1000 (manufactured by Asahi Kasei)

(Manufacturing method)

A. Components (1) to (6) are mixed by heating and uniformly dissolved.

B. Add the components (7) to (12) to A and mix them uniformly.

C. B was filled in a container to obtain a lip balm.

Prescription Example 30: Lip Gloss (Second Composition)

(ingredient) (%)

1. Palmitic acid dextrin 7

2. Triisostearic acid glyceryl 50

3. Polyglyceryl-10 decaisostearic acid Balance

4. Dimethylsilylated silica 2

5. 1,2-pentanediol 0.2

(Manufacturing method)

A. Components (1) to (5) are heated and uniformly dissolved.

B. A was filled into a container to obtain lipgloss.

Prescription Example 31: Lip balm (first composition)

(ingredient) (%)

1. Trimethylsiloxy silicate * 1 15

2. Polymethylsilsesquioxane 10

3. Polypropyl silsesquioxane 3

4. Isododecane Balance

5. Dimethylpolysiloxane * 18 15

6. Dimethiconol * 35 5

7. Trimethylsiloxyphenyl dimethicone * 33 8

8. Diastereadamonium hectorite 3

9. 1,3-Butylene glycol One

10. Red No. 226 One

11. Red No. 202 0.5

12. Yellow No. 4 0.5

13. Titanium oxide 0.5

14. PEG-9 Polydimethylsiloxy ethyl dimethicone 0.1

15. Spices 0.01

* 35: X-21-5849 (Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. The components (1) to (9) are mixed by heating and uniformly dissolved.

B. Add the components (10) to (15) to A and mix them uniformly.

C. B was filled into a container to obtain a lip balm.

Prescription Example 32: Lipgloss (oily solid dish-up shape, second composition)

(ingredient) (%)

1. Dibutyllauroylglutamide 5

2. Dibutylethylhexanoyl glutamide 2

3. Ethylhexyl hydroxystearate 40

4. Non-isostearic acid polyglyceryl-10 Balance

5. Dimethylsilylated silica 2

6. 1,2-Octanediol 0.1

7. Treatment with perfluorooctyltriethoxysilane

Iron oxide · Titanium oxide coated glass horse * 36 0.5

8. Perfluorooctyltriethoxysilane-treated iron oxide-coated glass * 37 0.5

* 36: 2% of perfluorooctyltriethoxysilane treated with microglass methasine MT1080TY (manufactured by Nippon Itagaras Co., Ltd.)

* 37: 2% of perfluorooctyltriethoxysilane treated with microglass methasine MT1080TZ (manufactured by Nihon Itagaras Co., Ltd.)

(Manufacturing method)

A. Components (1) to (8) are heated and uniformly dissolved.

B. A was filled into a container to obtain a lip gloss.

Prescription Example 25 Lip gloss and prescription example 27 Lip gloss, prescription example 25 Lip gloss and prescription example 28 Lip gloss, prescription example 26 Lip gloss and prescription example 27 Lip gloss, prescription example 26 Lip gloss and prescription example 28 Lip gloss, prescription example 29 Lip gloss and prescription Prescription Example 30 Lip Gloss, Prescription Example 31 Lip Liner and Prescription Example 32 A set of lip cosmetic preparations used in combination of lip gloss and prescription example had no color spreading at the time of use and was excellent in preventing color transition, There was no feeling, and cremation in time did not occur.

Claims (10)

A cosmetic set comprising a first composition and a second composition,
Wherein the second composition is applied after applying the first composition to the application site, and wherein the first composition and the second composition each contain the following ingredients:
(First composition)
(A) a film-forming silicone resin
(B) a silicone oil having a kinematic viscosity at 25 DEG C of 1000 to 1000000 cs
(C) volatile hydrocarbon oil
(D) a coloring pigment
(Second composition)
(E) which is phase-separated when the components (A) and (C) are mixed at a mass ratio of 1: 1 in an equal amount and left at 25 DEG C for 60 minutes. The composition of claim 1 wherein said component (A) is selected from the group consisting of trimethylsiloxysilicate, polymethylsilsesquioxane, (acrylate / dimethicone) copolymer, (acrylate / stearyl acrylate / dimethicone methacrylate) And one or more selected from the group consisting of a copolymer and a cosmetic. The cosmetic set as set forth in claim 1 or 2, wherein the content of the component (E) in the second composition is 50 to 99.9 mass%. The cosmetic set according to any one of claims 1 to 3, wherein the content of the component (E) in the second composition is 70 to 99.9% by mass. The positive resist composition according to any one of claims 1 to 4, wherein the content of the component (A) in the first composition is 10 to 50 mass%, the content of the component (B) is 1 to 50 mass% C) is 20 to 85% by mass. 6. The cosmetic set according to any one of claims 1 to 5, wherein the component (B) is a silicone oil having a kinematic viscosity at 25 DEG C of 10,000 to 1,000,000 cc. 7. The composition of any one of claims 1 to 6 wherein component (E) is selected from the group consisting of isostearic acid ester, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinnamic acid ester, vinylpyrrolidone- One or more emulsifiers selected from the group consisting of cosmetics and cosmetics. The cosmetic set according to claim 7, wherein the isostearic acid ester of the component (E) is an isostearic acid ester having an emulsified isostearic acid group. 8. The composition according to any one of claims 1 to 7, wherein the component (E) is isostearic acid polyglyceryl-2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl- 10 polyglyceryl isostearate, 10 polyglyceryl decachoisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetic acid, trimellitic acid tri Decyl, ethylhexyl paratethoxycinnamate, (vinylpyrrolidone / hexadecene) copolymer, and a set of cosmetics. The cosmetic set according to any one of claims 1 to 9, wherein the cosmetic set is a lip cosmetic set.

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