JP2016188198A - Eyelash cosmetics - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide eyelash cosmetics that have high volume effect, are free from stickiness, have a smooth feeling of use, and also are easily removed.SOLUTION: Eyelash cosmetics comprise sunflower wax, C20-C26 branched higher alcohol, and oil-soluble film forming agent.SELECTED DRAWING: None

Description

  The present invention relates to a vaginal cosmetic, and more particularly to a vaginal cosmetic that is excellent in volume effect, has no stickiness, has a smooth use feeling, and is easy to remove.

The main effect required for cosmetics for eyelids is a cosmetic effect (volume effect) that makes the eyes look beautiful by making the eyelids appear thick and dark. In recent years, there has been an increasing demand for reducing the burden of heels due to the trend of shampoo serums, and not only the finishes of heel cosmetics but also no stickiness that causes friction to heels. In addition, there is a demand from the viewpoint of not burdening the wrinkle that it can be applied smoothly to the wrinkle without causing slickness that causes the wrinkle to be rubbed repeatedly with a mascara brush. Furthermore, when removing makeup, it is easy to remove with cleansing agents that do not contain volatile oils such as light liquid isoparaffin, isododecane, or cyclomethicone, so that it does not put a burden on the skin and surrounding skin. It has been demanded.
Conventionally, vaginal cosmetics are mainly composed of solid oils such as wax, film forming agents such as resins and synthetic polymers, and powders, and in order to have functionality that meets consumer demands, Various studies have been conducted.
For example, by using a copolymer of alkene and vinyl acetate, a polar wax, and a specific surfactant in combination, a technology that improves volume effect, good slipperiness, and longevity (see Patent Document 1), volatile hydrocarbons, By using nonionic surfactant, non-volatile non-silicone liquid oil, organic silicone resin, high melting point wax with a melting point of 95-130 ° C, semi-solid oil, organically modified clay mineral, curl-keep effect, sebum resistance A technique (see Patent Document 2) for improving the properties, cleansing properties, and adhesion properties is known.

JP 2010-83890 A JP 2012-188394 A

However, the technology for improving the volume feeling by using a solid component copolymer or wax as in the technology of Patent Document 1 requires a dedicated remover such as an eye makeup remover because the cosmetic film becomes hard, and the volume effect. When the solid component is increased in order to increase the amount, it becomes difficult to drop, and there is a problem that the burden on the soot at the time of removal is large. Moreover, in the cosmetics obtained by patent document 2, since the film | membrane which a high melting point wax forms is hard, exclusive removal agents, such as an eye makeup remover, are needed, and the non-volatile non-silicone liquid oil agent is slippery. Since it is strong, there is a drawback that the smooth usability is impaired.
The present invention relates to a vaginal cosmetic, and more specifically, an object of the present invention is to provide a vaginal cosmetic that is excellent in volume effect, has no stickiness, has a smooth feeling of use, and is easy to remove.

  In this situation, the present inventor has intensively studied, and as a result, the liquid branched higher alcohol having a carbon number of 20 to 26 pays attention to obtaining a smooth and light feeling of use without swaying on the surface. In search of solid oils that solidify higher alcohols, solid oils extracted from sunflower seeds not only solidify these higher alcohols and easily attach to cocoons, but also have no stickiness and low shear stress. It is found that a cosmetic film that is easy to remove because it spreads smoothly and is easy to blend with a cleansing agent, and that the volume effect is significantly improved by combining an oil-soluble film forming agent, and the present invention is completed. It came to.

That is, the present invention
[1] The following components (A) to (C);
(A) Sunflower wax (B) Branched higher alcohol having 20 to 26 carbon atoms
(C) Oil-soluble film forming agent
Vase cosmetics,
[2] The component (C) according to the above [1], wherein the component (C) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylates / dimethicone) copolymer, and dextrin isostearate. Cosmetics for candy,
[3] The vaginal cosmetic according to [1] or [2], further comprising a component (D) silicone powder,
[4] The bag according to any one of [1] to [3], wherein the oil-containing mass ratio of the components (A) and (B) is (A) :( B) = 30: 1 to 1: 3 It relates to cosmetics.

  According to the present invention, there is provided a vaginal cosmetic that is excellent in volume effect, has no stickiness, has a smooth feeling of use, and is easy to remove.

Hereinafter, the present invention will be described in detail. In the present specification, “to” means a range including numerical values before and after.
The component (A) sunflower wax used in the present invention is mainly composed of a monoester having a total carbon number of 32 to 62, which is composed of a long chain fatty acid and a long chain alcohol, obtained from sunflower seeds, and has a melting point of 70. Natural solid oil in the range of ~ 85 ° C. Specific examples include, but are not limited to, INCI (International Nomenclature of Cosmetic Ingredient) name, Helianthus Annuus (Sunflower) Seed Wax (Japanese name: sunflower seed wax), and the like. Yokoseki Yushi Kogyo Co., Ltd.).

  Although content of the component (A) in this invention is not specifically limited, 0.5-20 mass% (henceforth only with%) is preferable, More preferably, it is 1-15%. If it is this range, it is more preferable at the point which is more excellent in the volume effect of a cosmetic film, non-stickiness, smooth use feeling, ease of dropping, etc.

The branched higher alcohol having 20 to 26 carbon atoms of the component (B) used in the present invention is a higher alcohol having a total carbon number of 20 to 26, and has at least one branch in the hydrocarbon portion. If it is normally used for cosmetics, it can be used without particular limitation. Moreover, 1-13 are preferable and carbon number of the side chain of branched higher alcohol is although it does not specifically limit, The number of 1-3 is preferable, More preferably, it is one.
Such component (B) is not particularly limited, and examples thereof include octyldodecanol and decyltetradecanol. Among them, decyltetradecanol is combined with component (A). It is more preferable in terms of excellent smooth use feeling. Examples of the commercially available products include Euthanol G (manufactured by Cognis Japan), Risonol 24SP (manufactured by Higher Alcohol Industry), NJECOAL 240A (manufactured by Shin Nippon Rika Co., Ltd.), and the like.

  Although content of the component (B) in this invention is not specifically limited, 0.1 to 5% is preferable, More preferably, it is 0.5 to 3%. If it is this range, it is more preferable at the point which non-stickiness, ease of dropping, etc. are more excellent.

  The component (C) oil-soluble film-forming agent used in the present invention forms a film that is soluble in an oil agent such as volatile oil and does not have fluidity, and is usually used in cosmetics. If there is no particular limitation, it can be used. Here, the film having no fluidity is, for example, a film obtained by applying a mixture obtained by dissolving an oil-soluble film forming agent in volatile oil to a glass plate and volatilizing the volatile oil, and then tilting the glass plate. It is a film whose shape does not change. For example, a terpene resin, a silicone resin, a hydrocarbon resin, a vinyl acetate resin, an esterified product of dextrin and a fatty acid, the average polymerization degree of glucose of dextrin is 3 to 150, and the fatty acid has 4 to 26 carbon atoms. More than 50 mol% and not more than 100 mol% of one or more of the above-mentioned branched saturated fatty acids, and C 2-22 linear saturated fatty acid, C 6-30 linear or branched non-chain 1 type or 2 types or more selected from the group consisting of saturated fatty acids and cyclic saturated or unsaturated fatty acids having 6 to 30 carbon atoms, containing 0 mol% or more and less than 50 mol% with respect to the total fatty acids, Examples include dextrin fatty acid esters having a degree of substitution of 1.0 to 3.0. Specifically, the INCI names are TRIMETHYLSILOXYSILICATE (Japan name: trimethylsiloxysilicic acid), POLYMETHYLSILSESQUIOXANE (Japan name: polymethylsilsesquioxane), ACRYLATES / DIMETHICONE COPOLYMER (Japan name: (Acrylates / Dimethicone) copolymer), DEXTRIN ISOSTEARATE (Japanese name: dextrin isostearate) is mentioned, and these are more preferable in terms of volume effect, non-stickiness, and ease of removal. As commercial products, KF7312J (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KF-9021 (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), BY11-018 (Solid content 30%, solvent: cyclopentasiloxane, manufactured by Toray Dow Corning), KP541 (solid content 60%, solvent: isopropanol, manufactured by Shin-Etsu Chemical Co., Ltd.), SR-1000 (Momentive Performance Materials Japan) KP545 (solid content 30%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KP575 (solid content 30%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), SILFORM FLEXIBLE RESIN (momentive Performance Materials Japan) Propanol B-100 (manufactured by BASF), Yunifiruma HVY (manufactured by Chiba Flour Milling Co., Ltd.).

  The content of the component (C) in the present invention is preferably 0.5 to 25%, more preferably 1 to 15%, as the solid content concentration. If it is this range, it is more preferable at the point which the volume effect, non-stickiness, ease of dropping, etc. are more excellent.

  As the silicone powder of component (D) used in the present invention, if it is usually used in cosmetics, shapes such as spheres, plates, spindles, needles, fumes, fine particles, pigment grades, etc. There are no particular restrictions on the particle size of the particles or the particle structure such as porous or nonporous, and any silicone powder that exists as particles in cosmetics can be used. Specifically, under the INCI name, POLYMETHYLSILSESQUIOXANE (Japanese name: polymethylsilsesquioxane), VINYL DIMETHICONE / METHICONE SILSESQUIOXANE CROSSPOLYMER (Japan name: (vinyl dimethicone / methicone silsesquioxane) cross polymer), DIPHENYL DIMETHICONE / VINYL DIPHENYL DIMETHICONE / SILSESQUIOXANE CROSSPOLYMER (Japanese name: (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) crosspolymer), DIMETHICONE / VINYLDIMETHICONE CROSSPOLYMER (Japanese name: (dimethicone / vinyldimethicone) crosspolymer), etc. Commercially available products include Tospearl 145A, Tospearl 150KA (made by Momentive Performance Materials Japan), KSP-100, KSP-300 (made by Shin-Etsu Chemical Co., Ltd.), EP-5500, EP-2601 (Toray Dow Corning) Manufactured) and the like. Although not particularly limited, those having an average particle diameter of 3 to 10 μm are preferable from the viewpoint of touch, and those having a spherical or substantially spherical shape are preferably used from the viewpoint of smooth use feeling and non-stickiness. Among these, substantially spherical particles having fine silicone protrusions over the entire surface of the particles are more preferable in terms of smooth use feeling and non-stickiness. These powders are characterized by their shapes, and have a plurality of fine projections that are scientifically coupled to each other on the entire particle surface, and the projections are not easily lost. The protrusion portion has an average value of the diameter of the protrusion / the diameter of the base particle of 0.01 to 0.3, and an average value of the height of the protrusion / the diameter of the base particle of 0.01 to 0. .3 is preferable. Examples of such commercially available spherical silicone particles include Tospearl 150KA (made by Momentive Performance Materials Japan).

  The content of the component (D) in the present invention is preferably 0.5 to 20%, and more preferably 1 to 15%. Within this range, the volume effect, non-stickiness, smooth use feeling and the like are more preferable.

  In the present invention, although not particularly limited, it is preferred that the mass ratio of the component (A) and the component (B) is (A) :( B) = 30: 1 to 1: 3, more preferably (A) :( B) = 20: 1 to 1: 1. Within this range, the effects of the present invention can be maximized in terms of volume effect, non-stickiness, smooth feeling of use, ease of removal, and the like.

  In addition to the components (A) to (D) described above, the cosmetics for glazes of the present invention are usually used in cosmetics, for example, oily components other than the above components, powder components, fibers, and surfactants. , Film-forming polymer emulsion, water-based component, ultraviolet absorber, moisturizer, anti-fading agent, antioxidant, antifoaming agent, cosmetic component, preservative, perfume, etc., as appropriate, within a range not impairing the effects of the present invention be able to.

  Oily components other than the above components are not particularly limited as long as they can be used in cosmetics, and are derived from animal oils, vegetable oils, synthetic oils, etc., and solid oils, semisolid oils, liquid oils, volatile oils, etc. Regardless of properties, hydrocarbons, fats and oils, hardened oils, ester oils, fatty acids, higher alcohols other than component (B), silicone oils, fluorine oils, lanolin derivatives, oily gelation Examples include agents.

  Specifically, hydrocarbons such as paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, liquid paraffin, isododecane, hydrogenated polyisobutene, squalane, petrolatum, polybutene, Hydrogenated jojoba oil, beeswax, carnauba wax, candelilla wax, rice wax, geese wax, wax etc. wax, olive oil, castor oil, jojoba oil, mink oil, macadamian nut oil and other fats, cetyl isooctanoate , Isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate Esters such as glyceryl tribehenate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl), low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methyl Phenylpolysiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, cross-linked organopolysiloxane, fluorine-modified polysiloxane, silicone such as dimethiconol, perfluorodecane, perfluorooctane , Fluorinated oils such as perfluoropolyether, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, stearin , Fatty acids such as lauric acid, myristic acid, behenic acid, oleic acid, palmitic acid, isostearic acid, dextrin fatty acid esters other than component (C), sucrose fatty acid esters, aluminum isostearate, calcium stearate, and other oily gelling agents Etc. These oily components can be used alone or in combination of two or more as required.

  The powder component is a component other than the component (D), and if it is a powder generally used in cosmetics, particles such as spherical, plate-like, needle-like, fumes, fine particles, pigment grade, etc. It is not particularly limited by the particle structure such as diameter, porous, non-porous, etc., inorganic powders, glitter powders, organic powders, pigment powders, metal powders, composite powders, etc. Is mentioned. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, etc. Colored inorganic pigments, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite, sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, Antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, etc. white powder, titanium oxide coated mica , Titanium oxide coated bismuth oxychloride, iron oxide mica Bright powder such as Tungsten, Bituminous treated mica titanium, Carmine treated Mica titanium, Bismuth oxychloride, Fish scale foil, Polyethylene terephthalate / aluminum / epoxy laminated powder, Polyethylene terephthalate / Polyolefin laminated film powder, Polyethylene terephthalate / Polymethyl methacrylate laminated film powder Body, organic low molecular weight powder such as zinc stearate, N-acyl lysine, natural organic powder such as silk powder, cellulose powder, dextrin powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, red 3, red 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue Zirconium, barium or aluminum lake, etc. Organic pigment powder or metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide containing silicon dioxide, etc. And composite fibers, nylon, polyester, rayon, cellulose and the like. These may be surface-treated with a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, surfactant or the like. These powders can be used singly or in combination of two or more, and may be further combined.

  Examples of the fibers include synthetic fibers such as nylon, polypropylene, and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate silk, and the shape is not particularly limited, and the cross section is a circle. Any of a shape, an ellipse, a polygon, a well, a T shape, a Y shape and the like can be used. Furthermore, these fibers can be colored with a colorant as necessary, or surface treated with a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, surfactant, etc. as the type of surface treatment agent. Or may be used.

  As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Is mentioned. Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone And the like. Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples include phenyl ether phosphate. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts. Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types. These surfactants can use 1 type (s) or 2 or more types as needed.

The film-forming polymer emulsion is a system in which polymer fine particles are stably dispersed in an aqueous solvent. A liquid obtained by polymerizing a monomer emulsified with a surfactant or a milky sap that exists in nature. It is not particularly limited as long as it is usually used in cosmetics, and any of them can be used.
Examples include alkyl acrylate copolymer emulsions, alkyl acrylate / styrene copolymer emulsions, polyvinyl acetate emulsions, vinylpyrrolidone / styrene copolymer emulsions, and commercially available products include YODOSOL 32A707, YODOSOL GH810F, and YODOSOL. GH800F (manufactured by Akzo Nobel), Plexitol B-500 (manufactured by ROHM GMBH), Ricabond ET-F527 (manufactured by Chuo Science & Technology Co., Ltd.), VINYBRAN 1080, VINYBRAN 1128C, VINYBRAN 1080M, VINYBRAN 1080T, VINYBRAN GV-5651, VINYBRAN 1108 S / W (manufactured by Nissin Chemical Industry Co., Ltd.) and ANTARA 430 (manufactured by ISP). These polymer emulsions can use 1 type (s) or 2 or more types as needed.

  The aqueous component may be any component as long as it is soluble in water and water. For example, lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, 1, Glycols such as 2-pentanediol, glycerols such as glycerin, diglycerin, polyglycerin, plant extracts such as aloe vera, witch hazel, hamamelis, lavender, rose, guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, Sodium alginate, carrageenan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, alkyl-added carboxyvinyl polymer, sodium polyacrylate Arm, proteins, mucopolysaccharides, collagen, elastin, keratin, and the like.

  Examples of the ultraviolet absorber include benzoic acid ultraviolet absorbers such as paraaminobenzoic acid, anthranilic acid ultraviolet absorbers such as methyl anthranilate, salicylic acid ultraviolet absorbers such as methyl salicylate, and octyl paramethoxycinnamate. Cinnamic acid ultraviolet absorbers, benzophenone ultraviolet absorbers such as 2,4-dihydroxybenzophenone, urocanic acid ultraviolet absorbers such as ethyl urocanate, and the like. Further, hexyl diethylaminohydroxybenzoyl benzoate, dimethicodiethylbenzyl malonate, 2,4-bis {[4- (2-ethylhexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1 , 3,5-triazine, methylenebisbenzotriazole tetramethylbutylphenol, 4-tert-butyl-4′-methoxybenzoylmethane, octocrylene, octyltriazone, and the like can be used. Examples of the antioxidant include α-tocopherol and ascorbic acid, vitamins, and examples of the preservative include paraoxybenzoic acid ester and phenoxyethanol.

  Examples of the cosmetics for wrinkles of the present invention include mascara, mascara overcoat, mascara base and the like, and can be used for any of oily, oil-in-water type and water-in-oil type. The oily wrinkle cosmetic of the present invention is one that contains substantially 1% or less of water and does not contain water.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Examples 1 to 10 and Comparative Examples 1 to 6: Oily Mascara Oily mascara having the formulation shown in Table 1 below was prepared, and the volume effect, non-stickiness, and smooth use feeling were evaluated by the following methods. Moreover, the ease of dropping was evaluated by the following method. The results are also shown in Table 1.

* 1: IP solvent 1620MU (made by Idemitsu Kosan Co., Ltd.)
* 2: Leopard TL (Chiba Flour Mills)
* 3: Refined sunflower wax (manufactured by Yokoseki Oil & Fat Co., Ltd.)
* 4: BENTONE 27V (manufactured by ELEMENTIS)
* 5: NJCOAL 240A (manufactured by Shin Nippon Rika Co., Ltd.)
* 6: KF7312J (manufactured by Shin-Etsu Chemical Co., Ltd.) (solid content 50%, solvent: cyclopentasiloxane)
* 7: KP541 (solid content 60%, solvent: isopropanol, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 8: Tospearl 2000B * (average particle size 6 μm, manufactured by Momentive Performance Materials Japan)
* 9: KSP-300 (average particle size 5 μm, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 10: Silicia 550 (Fuji Silysia Chemical)

(Production method)
A. Ingredients (1) to (7) are heated to 100 ° C. and mixed uniformly.
B. Add components (8) to (17) to A and disperse uniformly.
C. Fill B into a container to make a product.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Volume effect b. No stickiness
c. Smooth feeling of use d. Ease of dropping For evaluation items a, b and c, each sample is subjected to a use test by 20 specialist panels, and each panel evaluates it according to the following absolute evaluation criteria and gives a score. The average value was calculated from the total of the scores, and judged according to the following criteria.
<Absolute evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad <Criteria>
(Judgment): (Average score)
◎: Over 5 points: Very good ○: Over 5 points, 5 points or less: Good △: Over 1 point, 3.5 points or less: Slightly poor ×: 1 point or less: Bad

For the evaluation item d, after taking 2 g of cleansing of the prescription shown below on cotton and applying to the site to be used for about 30 seconds, the ease of removal when the makeup film is wiped off by the action of removing normal mascara is as follows. Judged by.
(Cleansing prescription for evaluation)
(Ingredient) (%)
(1) Mineral oil remaining amount (2) Cetyl ethylhexanoate 20
(3) Triethylhexanoin 20
(4) Solveste tetraoleate-30 8
(5) Phenoxyethanol 0.5
(Production method)
A. Components (1) to (5) are mixed.
B. A was filled into the container to obtain cleansing.

<Criteria (ease of dropping)>
(Judgment): (Evaluation criteria)
◎: Completely fallen ○: Almost fallen △: About half fallen ×: Not fallen at all

As is clear from the results in Table 1, the oily mascara of Examples 1 to 10 of the present invention has all of the volume effect, non-stickiness, smooth feeling of use, and ease of removal compared with the oily mascara of Comparative Examples 1 to 6. It was excellent.
On the other hand, in Comparative Examples 1 to 3 using other waxes in place of the component (A), decyltetradecanol cannot be retained in the wax structure, and thus the oily crumbs are applied at the time of application. A satisfactory product was not obtained in terms of effect and smooth use feeling. In Comparative Example 4 in which the component (B) was not contained, it was easy to feel the stickiness of the resin, and the decorative film was too hard to be removed. In Comparative Example 5 in which a low-viscosity polar oil is used instead of the component (B), it is not retained in the wax structure of the component (A), so that it becomes oily at the time of application, resulting in a volume effect and a smooth feeling of use. It was not enough. In Comparative Example 6 in which the component (C) was not contained, the adhesiveness to wrinkles was not sufficient, and a satisfactory one in terms of volume effect was not obtained.

Examples 11 to 19 and Comparative Examples 7 to 12: Oil-in-water mascara Examples of oil-in-water mascara having the formulations shown in Table 2 below were prepared, and the volume effect, non-stickiness, smooth feeling of use, and ease of removal were described as examples. It evaluated using the evaluation method of 1-10 and Comparative Examples 1-6. The results are also shown in Table 2.

* 11: Unifilm HVY (Chiba Flour Mills)
* 12: Tospearl 150KA (average particle size 5μm, manufactured by Momentive Performance Materials Japan)
* 13: ACULYN 33A (solid content 28%) (Rohm & Haas)
* 14: Cyrossphere C-1504 (Fuji Silysia Chemical)
* 15: YODOSOL 810F (solid content 46%) (manufactured by Akzo Nobel)
* 16: Vinizole 1086WP (solid content 40%) (Daido Kasei Kogyo Co., Ltd.)
* 17: Vinizole 2140L (solid content 43%) (manufactured by Daido Kasei Kogyo Co., Ltd.)

(Production method)
A. Ingredients (1) to (14) are heated to 100 ° C. and mixed uniformly.
B. Components (15) to (22) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled to room temperature and filled into a container with an applicator to obtain a product.

As is apparent from the results in Table 2, the oil-in-water mascara of Examples 11 to 19 of the present invention has a volume effect, non-stickiness, a smooth feeling of use, and a drop compared to the oil-in-water mascara of Comparative Examples 7 to 12. It was excellent in all ease.
On the other hand, in Comparative Examples 7 to 9 using other waxes in place of the component (A), decyltetradecanol cannot be retained in the wax structure, so that it becomes oily when applied, We were not satisfied with the volume effect and smooth usability. In Comparative Example 10 containing no component (B), it was easy to feel the stickiness of the resin, and the decorative film was too hard to be removed. In Comparative Example 11 in which a low-viscosity polar oil is used instead of the component (B), it is not retained in the wax structure of the component (A), so that it becomes oily when applied, resulting in a volume effect and a smooth use feeling. It was not enough. In Comparative Example 12 containing no component (C), the adhesion of the mascara liquid to the wrinkles was not sufficient, and a satisfactory one in terms of volume effect was not obtained.

Example 20: Water-in-oil mascara (cream)
(Ingredient) (%)
(1) Light liquid isoparaffin * 1 Remaining amount (2) Dextrin isostearate * 11 4
(3) Dextrin palmitate * 2 5
(4) Sunflower wax * 3 3
(5) Polyethylene wax * 18 3
(6) Beeswax (melting point 65 ° C.) 5
(7) Trimethylsiloxysilicate solution * 19 15
(8) Trimethylsilsesquioxane * 20 5
(9) Dimethiconol (100,000 mPa · s) * 21 3
(10) Decyltetradecanol * 5 0.5
(11) Organically modified bentonite * 22 4
(12) Silicic acid anhydride * 23 2
(13) Black iron oxide 5
(14) N-lauroyl-L-lysine * 24 1
(15) Silicone powder * 8 3
(16) Purified water 5
(17) Alkyl acrylate copolymer emulsion * 25 5
* 18: Synthetic wax P-200 (Nippon Natural Products)
* 19: KF-9021 (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 20: SILFORM FLEXIBLE RESIN (made by Momentive Performance Materials Japan)
* 21: X-21-5849 (Shin-Etsu Chemical Co., Ltd.)
* 22: Lucentite SAN-P (Coop Chemical Co., Ltd.)
* 23: AEROSIL 200 (Nippon Aerosil Co., Ltd.)
* 24: Amihope LL (Ajinomoto Co., Inc.)
* 25: Iodosol GH256F (solid content 29%) (manufactured by Akzo Nobel)

(Production method)
A. Ingredients (1) to (15) are heated to 100 ° C. and mixed uniformly.
B. B. Ingredients (16) to (17) are mixed uniformly.
C. Add B to A and emulsify.
D. Fill the container with C to make a product.

  The water-in-oil mascara (cream-like) of the present invention was excellent in volume effect, non-sticky, had a smooth use feeling, and was easy to remove.

Example 21: Oily mascara (with fiber)
(Ingredient) (%)
(1) Residual amount of cyclopentasiloxane (2) Hydrogenated glyceryl abietate * 26 3
(3) (Acrylates / Dimethicone) Copolymer Solution * 27 15
(4) Sucrose fatty acid ester * 28 3
(5) Sunflower wax * 3 4
(6) Rice wax (melting point 80 ° C) 3
(7) Paraffin wax (melting point: 58 ° C.) 5
(8) Stearyl dimethicone (melting point 40 ° C.) 2
(9) N-vinylpyrrolidone triacontane copolymer * 29 2
(10) Decyltetradecanol * 5 3
(11) Lecithin 1
(12) Silylated silica anhydride * 30 1
(13) Carbon black 1
(14) Polyethylene terephthalate powder * 31 3
(15) Silicone powder * 32 0.5
(16) Polypropylene fiber (5T, 2mm) 0.5
(17) Nylon 12 fiber (5T, 1 mm) 1
(18) Nylon 66 fiber (17T, 2mm) 1
(19) Phenoxyethanol 1
* 26: Pine Crystal KE-311 (Arakawa Chemical Industries)
* 27: KP545 (solid content 30%, solvent: cyclopentasiloxane) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 28: Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 29: ANTARON WP660 (manufactured by ISP)
* 30: AEROSIL R-972 (manufactured by Nippon Aerosil Co., Ltd.)
* 31: Snow Reef P (Oken)
* 32: KSP-100 (average particle size 5 μm, manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A. Ingredients (1) to (11) are heated to 100 ° C. and mixed uniformly.
B. Add components (12) to (19) to A and disperse uniformly.
C. Fill B into a container to make a product.

  The oily mascara (with fiber type) of the present invention was excellent in volume effect, had no stickiness, had a smooth feeling of use, and was easy to remove.

Example 22: Oil-in-water mascara base (cream)
(Ingredient) (%)
(1) Cyclopentasiloxane 3
(2) Stearic acid 1
(3) Palmitic acid 1
(4) Decyltetradecanol * 5 0.1
(5) Sunflower wax * 3 3
(6) Microcrystalline wax * 33 3
(7) Cholesterol 2
(8) Rice sterol 2
(9) Trimethylsiloxysilicate * 34 0.5
(10) Purified water remaining amount (11) Carboxymethylcellulose 1
(12) Alkyl acrylate / vinyl acetate copolymer emulsion * 17 10
(13) Triethanolamine 1.2
(14) Titanium oxide coated glass powder 1
(15) Polyethylene terephthalate / aluminum / epoxy laminated powder 0.5
(16) Trehalose 0.5
(17) Polyvinyl alcohol 1
(18) Silicone powder * 12 3
* 33: MULTIWAXW-835MYCROCRYSTALLINEWAX (manufactured by SONNEBORN)
* 34: SR-1000 (Momentive Performance Materials Japan)

(Production method)
A. Ingredients (1) to (9) are heated to 100 ° C. and mixed uniformly.
B. Components (10) to (18) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled to room temperature and filled into a container with an applicator to obtain a product.

The oil-in-water mascara base (cream-like) of the present invention was excellent in volume effect, non-sticky, with a smooth feeling of use, and was easy to remove.

Claims (4)

The following components (A), (B) and (C);
(A) Sunflower wax (B) Branched higher alcohol having 20 to 26 carbon atoms (C) Oil-soluble film forming agent
Cosmetics containing vase. The cosmetic for make-up according to claim 1, wherein the component (C) is one or more selected from trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylates / dimethicone) copolymer), and dextrin isostearate. Fee. Furthermore, the cosmetic for wrinkles of Claim 1 or 2 containing a component (D) silicone powder. The vaginal cosmetic according to any one of claims 1 to 3, wherein the mass ratio of the components (A) and (B) is (A) :( B) = 30: 1 to 1: 3.