JP6526999B2 - Hair cosmetics - Google Patents

Description

The present invention relates to a hair cosmetic, and more particularly, sunflower wax, branched higher alcohol having 18 to 28 carbon atoms, silicone resin powder, ( dimethicone / vinyl dimethicone) crosspolymer or ( dimethicone / phenyl vinyl dimethicone) cross A hair cosmetic containing a polymer, which is excellent in hair setting effect and no stickiness, light in use feeling of spreading, lightness of hair after use, and excellent in retention of hair setting power. It is a thing.

  Hair cosmetics have various items depending on their applications. Among them, hair setting agents are for adjusting and maintaining the hair in a free shape, and various forms such as spray type, gel type, lotion type and foam type are commercially available depending on the usability. Among them, the one containing a wax component and generally referred to as a hair wax is often a cream type, and various studies have been made from the aspect of portability and functionality.

  For example, a combination of glycosyl trehalose, candelilla wax and microcrystalline wax, which reduces stiffness and improves hair styling and washing during hair washing (see, for example, Patent Document 1), N-long-chain acyl amino acid surfactant , A technology for obtaining a hair cosmetic excellent in smoothness and tackiness of the finish, and hair setting ability by combining a specific film forming agent, a polyhydric alcohol, and a vegetable oil (see, for example, Patent Document 2), N- Technology for enhancing hair penetration and flexibility and directing hair repair feeling by combining an acyl amino acid diester, volatile hydrocarbon oil, dimethiconol, and a specific silicone oil (see, for example, Patent Document 3), etc. was there.

JP, 2009-107975, A JP, 2009-120576, A JP, 2011-105631, A

  However, in the hair setting material obtained by the technique of Patent Document 1, the combination of glycosyl trehalose, candelilla wax and microcrystalline wax improves the washability and the hair setting property, but as the blending amount of wax increases, the wax has The hardness also affects the cosmetic film, and there is a drawback that the feeling of use is heavy and the user feels a sense of discomfort. In the hair cosmetic composition obtained by the technique of Patent Document 2, the combination of N-long-chain acyl amino acid surfactant, specific film-forming agent, polyhydric alcohol, and vegetable oil results in smooth finish and no stickiness. And although the thing excellent in hair setting ability is obtained, there existed a fault of producing stickiness and feeling in use becoming heavy as the quantity of surfactant increases. Furthermore, in the oily hair cosmetic composition obtained by the technique of Patent Document 3, the permeability to hair and the flexibility are enhanced by combining N-acyl amino acid diester, volatile hydrocarbon oil, dimethiconol, and a specific silicone oil. Although it is possible to produce a feeling of repair on the hair, the cosmetic film is too soft and there is a drawback that the effect of maintaining the setting power of the hair is lacking.

  Under these circumstances, the inventor of the present invention has intensively studied and, as a result, first examined a component for improving the usability as a hair cosmetic, when a branched higher alcohol having 18 to 28 carbon atoms is used, smooth use is obtained. I found that I could get a feeling. Next, as a result of various investigations on the component to be solidified in the case of using the higher alcohol as a hair setting agent, the wax derived from a plant has various composition distribution, and the usability as a hair cosmetic and the hair setting effect It was found that sunflower wax, which is a solid oil extracted from sunflower seeds, is particularly effective.

  Moreover, as a result of examining the component which is excellent in usability and durability of the effect, a set of hair is obtained by combining silicone resin powder and (dimethicone / vinyl dimethicone) cross polymer or (dimethicone / phenyl vinyl dimethicone) cross polymer. The inventors have found that they are excellent in effect, non-sticky and light in use feeling, and further impart a moist feeling to hair, and are excellent in the effect of maintaining the setting power of hair, and have completed the present invention.

The following components (a) to (d);
(A) sunflower wax (b) branched higher alcohol having 18 to 28 carbon atoms (c) silicone resin powder (d) ( dimethicone / vinyl dimethicone) crosspolymer or hair containing ( dimethicone / phenylvinyl dimethicone) crosspolymer It relates to cosmetics.

  The present invention relates to a hair cosmetic wherein the component (b) is 2-decyltetradecanol.

  The present invention relates to a hair cosmetic wherein the component (c) is polymethylsilsesquioxane.

  Furthermore, it relates to a hair cosmetic comprising a silicone oil selected from dimethylpolysiloxane and methylphenylpolysiloxane as the component (e), wherein the component (d) and the component (e) form a gel. It is.

  The present invention relates to a hair cosmetic in which the content mass ratio (a) / (b) of the components (a) and (b) is in the range of 0.1 to 9.

  Further, the present invention relates to a hair cosmetic containing component (f) Fischer-Tropsch wax.

  The present invention relates to a hair cosmetic for hair setting.

  The hair cosmetic composition of the present invention is excellent in the setting effect of the hair, not sticky, light in use feeling of the coating and the like, and further imparts a moist feeling on the hair and a sustained effect of the setting power of the hair.

  Hereinafter, the present invention will be described in detail. In addition, in this specification, "-" shall mean the range including the numerical value before and behind that.

  The sunflower wax (a) used in the hair cosmetic composition of the present invention is mainly composed of monoesters of total carbon number 32 to 62 composed of long chain fatty acids and long chain alcohols obtained from sunflower seeds and has a melting point Is a natural solid oil in the range of 70-85 ° C. Specifically, HELIANTHUS ANNUUS (SUNFLOWER) SEED WAX (Japanese name: sunflower seed wax) etc. are mentioned under the name of INCI (INTERNATIONAL NOMENCLATURE OF COSMETIC INGREDIENT) etc. Etc.).

  The content of the component (a) in the present invention is not particularly limited, but it is 0.5 to 15% by mass (hereinafter, the mass% is simply expressed as "%") in terms of the hair setting effect. Is more preferable, and 1 to 10% is more preferable.

  The branched higher alcohol having 18 to 28 carbon atoms of component (b) used in the hair cosmetic composition of the present invention is one having at least one branch in the hydrocarbon portion, which is generally used in cosmetic compositions. If there is, it can be used without particular limitation. The number of carbon atoms is preferably 18 to 24 carbon atoms, and more preferably 20 to 24 carbon atoms. The number of carbon atoms in the side chain of the branched higher alcohol is preferably 1 to 13. The number of branches is not particularly limited, but is preferably 1 to 3, and more preferably 1.

  Examples of such component (b) include, but are not limited to, isostearyl alcohol, octyldodecanol, 2-decyltetradecanol and the like, among which 2-decyltetradecanol is particularly preferred. It is more preferable in the point of the hair setting effect by shape retention when it combines with a component (a). Commercially available products include isostearyl alcohol EX (manufactured by higher alcohol industry), Oitanol G (manufactured by Kognis Japan), oleyl alcohol 90VR (manufactured by higher alcohol industry), lysolol 18SP (manufactured by higher alcohol industry), lysinol 24SP (manufactured by higher alcohol industry) High-grade Alcohol Industry Co., Ltd.), Engecole 200A (made by New Nippon Rika Co., Ltd.), Engecole 240A (made by New Japan Rika Co., Ltd.), and the like.

  The content of the component (b) in the present invention is not particularly limited, but is preferably 0.1 to 25%, and more preferably 1 to 15% in terms of lightness in use feeling and moist feeling on hair.

  In the present invention, the present invention relates to a hair cosmetic composition obtained by appropriately containing the component (a) and the component (b) described above, but a higher effect can be achieved by setting the contained ratio to a specific range. Can be expected. That is, the range of (a) / (b) = 0.1 to 9 is preferable, 0.5 to 7 is more preferable, and 1 to 6 is more preferable.

  The silicone resin powder of component (c) used in the hair cosmetic composition of the present invention is a powder of silicone resin and is particularly limited as long as it is solid at 25 ° C. at one atmospheric pressure. is not. The component (c) is present as particles in the hair cosmetic composition of the present invention and is distinguished from the component (d) described later. Although the component (c) can embody usability superiority in elasticity, it is not particularly limited as long as it is generally used for cosmetics. Specifically, it is not particularly limited to the shape of spheres, plates, spindles, needles, etc., the shape of fumes, particles of particles, particles of pigments, etc., or the particle structure of particles such as high or low quality. Any one can be used. The average particle size is not particularly limited, but is generally in the range of 1 to 30 μm. In addition, the average particle diameter in this invention is a value when it measures using laser diffraction * scattering type particle size distribution measuring apparatus (The Horiba, Ltd. laser diffraction / scattering type particle size distribution measuring apparatus LA-910).

  Commercial products include Tospearl 145A, Tospearl 150KA (manufactured by Momentive Performance Materials Japan), Trefil E-506S, Trefil E-508, EP-5500, EP-2601 (manufactured by Toray Dow Corning), and the like. Be

  Among the components (c) described above, although not particularly limited, those having an average particle diameter of 3 to 10 μm are preferable in terms of feel, and spherical or substantially spherical ones are preferably used. Among them, substantially spherical particles having silicon microprotrusions all over the particle surface are preferable in terms of no stickiness and lightness in use. These powders are characterized in their shape and have a plurality of scientifically coupled microprotrusions on the entire particle surface with a plurality of microprotrusions, and the projections are not easily lost. The projections have an average diameter of projections / diameter of base particles of 0.01 to 0.3, and an average height of projections / diameter of base particles of 0.01 to 0 Preferably, .3. Commercially available products of such approximately spherical silicone particles include TOSPEARL 150KA (manufactured by Momentive Performance Materials Co., Ltd.) and the like.

  The content of the component (c) in the present invention is not particularly limited, but is preferably 0.1 to 20%, and more preferably 1 to 10 in view of no stickiness and lightness in feeling upon use. % Is preferred.

The (dimethicone / vinyl dimethicone) crosspolymer or (dimethicone / phenyl vinyl dimethicone) crosspolymer of component (d) used in the hair cosmetic composition of the present invention crosslinks the organopolysiloxanes dimethicone, vinyl dimethicone and phenyl dimethicone. It is a polymer obtained by making it have a three-dimensional crosslinked structure in part. It can be used without particular limitation as long as it is usually used for cosmetics.
Although it is possible to simply contain the component (d), it will be particularly excellent in terms of no stickiness if it is present in the hair cosmetic in a state of being swollen with the component (e) described later and other oils. .

Furthermore, the hair cosmetic composition of the present invention contains, as component (e), a silicone oil selected from dimethylpolysiloxane and methylphenylpolysiloxane. This is not particularly limited as long as it is usually used for cosmetics, but one having a viscosity of 400 mPa · s or less at 25 ° C. under one atmosphere is preferable. The component (e) is a component that contributes to the improvement of the gloss to the hair and the usability. It is also possible to use it as a solvent for the swelling of the component (d) described above, and in the present invention, it is also possible to use the one obtained by mixing the component (d) with the component (e) and swelling gelled beforehand. It is particularly excellent in terms of the effect of no stickiness.
As commercial products, KSG-6, KSG-15, and KSG-16 as a mixture of component (d) and dimethylpolysiloxane, and as a mixture of component (d) and phenyltrimethicone, KSG-8, KSG-18 (more than And Shin-Etsu Chemical Co., Ltd.).

  The content of the component (d) in the present invention is not particularly limited, but it is preferably 0.3 to 5%, further 0.5 to 3% in terms of no stickiness and lightness in use feeling Is more preferred.

Component (f) Fischer-Tropsch wax can be used in the hair cosmetic composition of the present invention in addition to the components (a) to (e).
The Fischer-Tropsch wax of the component (f) used in the present invention is a petroleum-based wax synthesized by the Fischer-Tropsch method, and any one may be used without particular limitation as long as it is generally used for cosmetics. The component (f) having a melting point of 70 to 120 ° C. is preferable because it gives a hair setting effect and non-stickiness more remarkably. Examples of commercially available products within this range include SASOLWAX C80, SASOLWAX H1 (manufactured by SASOL), CIREBELLE 108, CIREBELLE 109L, and CIREBELLE 303 (manufactured by CIRBEELLE).

  The content of the component (f) in the present invention is not particularly limited, but it is preferably 0.5 to 10% in view of imparting the setting effect of the hair and the non-stickiness more remarkably, etc. 1 to 5% is more preferable.

  The hair cosmetic composition of the present invention comprises, in addition to the above components (a) to (f), powders generally used in cosmetics, powders such as oil components, inorganic pigments, organic pigments and pigments, and their silicone treatment Substances, fluorine compound treated substances, surfactants, fibers, polyhydric alcohols, water-soluble polymers, water-soluble film-forming resins, aqueous components such as moisturizers, saccharides, ultraviolet absorbers, anti-fading agents, antioxidants, An antifoaming agent, a cosmetic component, an antiseptic, a flavoring agent, etc. can be contained in the range which does not prevent the effect of this invention.

  The oily component is other than the components (a), (b), (d) and (e), and any oil generally used for cosmetics can be used without any restriction, and animal oil, vegetable oil, Use hydrocarbons, fats and oils, ester oils, fatty acids, higher alcohols, fluorinated oils etc regardless of the origin such as synthetic oil etc. and properties of semi-solid oil, liquid oil, volatile oil etc. Can. Specifically, hydrocarbons such as liquid paraffin, squalane and vaseline, oils and fats such as olive oil, mink oil and macadamian nut oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, dioctanoic acid Neopentyl glycol, glyceryl tri (caprylic / capric acid), jojoba oil, glyceryl tri-2-ethylhexanoate, esters such as diisostearyl malate, fatty acids such as isostearic acid, oleic acid, oleyl alcohol, isostearyl Examples thereof include higher alcohols such as alcohol, fluorinated oils such as perfluorodecane, perfluorooctane and perfluoropolyether, and oil-soluble cosmetic ingredients.

  The powder component is other than the component (c), and in the case of a powder generally used as a powder for cosmetics, it has a spherical, plate-like, needle-like shape, fumed, fine particles, It is not particularly limited by particle size such as pigment grade, particle structure such as porous or nonporous, etc., and inorganic powders, bright powders, organic powders, pigment powders, metal powders, Composite powder etc. are mentioned. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine etc. Colored inorganic pigments, talc, muscovite, phlogopite, flash mica, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, White matter powder such as antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium oxide coated mica , Titanium oxide coated bismuth oxychloride, iron oxide mica Bright powder such as tan, bitumen-treated mica titanium, carmine-treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder Body, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, polypropylene resin, urethane resin, etc. Organic polymer resin powder, Organic low molecular weight powder such as zinc stearate, N-acyl lysine, etc. Natural powder such as silk powder, cellulose powder, dextrin powder, Red No. 201, Red No. 202, Red 2 No.5, red 226, red 228, orange 203, orange 204, blue 404, yellow 401 etc., red 3, red 104, red 106, red 205, orange 205, yellow 4, yellow Organic pigment powder such as zirconium, barium or aluminum lake such as No.5, Green No.3 and Blue No.1 or metal powder such as aluminum powder, gold powder or silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica Composite powders such as titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and fibers of nylon, polyester, rayon, cellulose and the like can be mentioned. These may be surface-treated with a fluorine compound, silicone oil, powder, oil, gelling agent, emulsion polymer, surfactant and the like. These powders may be used alone or in combination of two or more, and may be used in combination.

  As the surfactant, any surfactant which is generally used in cosmetics can be used, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Can be mentioned.

  The aqueous component may be any component soluble in water, and in addition to water, for example, propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin, polyglycerin, aloe vera, winch Plant extracts such as hazel, hamamelis, cucumber, lemon, lavender and rose water can be mentioned.

  The UV absorbers include, for example, benzophenone type, PABA type, cinnamic acid type, salicylic acid type, etc., for example, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, 2-ethylhexyl paramethoxycinnamate 2, Examples include 4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, hexyl diethylaminohydroxybenzoyl benzoate, bisethylhexyl oxyphenol methoxyphenyl triazine and the like.

  Antioxidants include, for example, tocopherol, ascorbic acid, etc., cosmetic components include, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., and examples of preservatives include, for example, p-hydroxybenzoic acid ester, phenoxyethanol, 1,2-pentadiol, etc. .

  The hair cosmetic composition of the present invention may be in any form such as liquid, gel, cream or solid, and it is an oil-based component since it contains an component (a) to (f) as an oil component. It can be made into a dosage form. It is also possible to make a water-in-oil type hair cosmetic composition in which an aqueous component is emulsified in this oil type. In addition, it is also possible to use the oil component of the present invention as the oil to be emulsified to form an oil-in-water hair cosmetic.

  The present invention is applicable to the various dosage forms described above, and among them, an oil-based, water-in-oil type in which oil is a continuous layer is preferable in terms of achieving the effects of the present invention. Further, the use of the hair cosmetic is not particularly limited, but it is preferable to use as a hair styling agent in terms of usability and the setting effect of the hair.

  The present invention will be described in detail by way of examples. In addition, these do not limit the present invention at all.

Inventions 1 to 17 and Comparatives 1 to 6: Hair setting agent (solid oily form)
The hair setting agent of the formulation shown in the following Tables 1 to 3 is prepared, and the followings are described with respect to the setting effect of the hair, no stickiness, lightness of use feeling of spreading, lightness of hair after use, and maintenance of setting power of hair. It evaluated by the method. The results are also shown in Tables 1 to 3.

* 1: MULTIWAX W 445 (melting point 76-82 ° C, manufactured by SONNEBORN)
※ 2: Refined sunflower wax (melting point: 74-80 ° C, manufactured by YOKOSEKI YOKOI
* 3: PERFORMALENE 500 (melting point 83-88 ° C, manufactured by New Phase Technology)
* 4: CIREBELLE 108 (melting point 80-85 ° C, manufactured by CIREBELLE)
* 5: Lithonol 24SP (manufactured by Kokyushu Alcohol Industry Co., Ltd.)
* 6: KSG-16 (Shin-Etsu Chemical Co., Ltd., 25% solids dimethylpolysiloxane solution)
* 7: TOSPEARL 150KA (average particle size 5 μm, manufactured by Momentive Performance Materials Japan)
* 8: TOSPEARL 145KA (average particle size 4.5 μm, spherical, manufactured by Momentive Performance Materials Japan)

(Manufacturing method)
A. Ingredients (1) to (12) are uniformly heated and dissolved at 110 ° C.
B. Add components (13) to (18) to A and mix uniformly.
C. B was filled in a jar container at 90 ° C. and cooled to obtain a hair setting agent (oily solid).

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
B. Set effect of hair b. There is no stickiness Ha. Lightness of the feeling of use of fill-out. Feel moist of hair after use. Duration of hair setting power For the items of (a) to (e), the use test was conducted by 20 expert panels for each sample. Each sample was applied to the hair, and evaluations were made immediately after use for b), b) and c), and after 6 hours for b) and h), evaluation was performed by touching the hair. With respect to each item, each panel rated and graded in 7 steps according to the following absolute evaluation criteria, calculated the average value from the total score of all members of the panel, and judged according to the following 4 criteria.

Absolute evaluation criteria (score): (evaluation)
6: very good 5: good 4: somewhat good 3: normal 2: somewhat bad 1: bad 0: very bad

Four-step criterion (judgment): (average score)
:: more than 5 points: very good ○: more than 3.5 points but less than 5 points: good :: more than 1 point less than 3.5 points: somewhat defective ×: less than 1 point: defective

As apparent from the results of Tables 1 to 3, the hair setting agents of the present inventions 1 to 17 of the present invention use the setting effect of the hair, no stickiness, and spreading as compared with the hair setting agents of the comparative products 1 to 6 It was excellent in the lightness of the feeling, the moist feeling of the hair after use, and the sustained effect of the setting power of the hair.
On the other hand, in the comparative product 1 in which polyethylene wax is blended instead of the sunflower wax of the component (a), the cosmetic film becomes too strong, and a satisfactory one is obtained in terms of lightness of use feeling and moist feeling of hair. It was not done. Moreover, in the comparative product 2 which does not contain a component (a), a cosmetic film was soft and was not satisfactory in the point of the setting effect of hair, and the continuation of the setting power of hair. Moreover, in the comparative product 3 which is not mix | blending the 2-decyl tetradecanol of a component (b), the perviousness to hair is not felt and the satisfactory thing also in the point of the moistness of hair was not obtained. Moreover, in the comparative product 4 using glyceryl 2-ethylhexanoate instead of the component (b), the cosmetic film is soft and further oily feeling is generated, and the hair setting power is maintained and no stickiness is satisfied. I could not get anything Moreover, in the comparative product 5 which is not mix | blending the silicone powder of a component (c), a cosmetic film produced stickiness and was not able to be obtained satisfactory. Furthermore, in Comparative product 6 which does not contain the (dimethicone / vinyl dimethicone) crosspolymer of the component (d), the feeling of use is heavy, the stickiness of the cosmetic film is felt, and the setting power of the hair is not sustained. I could not get anything

Example 2: Hair-dressing agent (water-in-oil type gel-like)
(Component) (%)
(1) (palmitic acid / octanoic acid) dextrin 2
(2) Sunflower wax * 2 2
(3) Fischer-Tropsch wax * 9 2
(4) Octyl dodecanol * 10 1
(5) 2-decyl tetradecanol * 6 0.5
(6) Light liquid isoparaffin remaining amount (7) Polyisobutylene ※ 11 0.5
(8) Dimethyl distearyl ammonium hectorite * 12 3
(9) Silicone resin powder * 2 2
(10) (Dimethicone / phenyl vinyl dimethicone)
Cross polymer ※ 13 5
(11) Carbon black 0.1
(12) Purified water 10
(13) Edetate disodium 0.01
(14) 1,2-pentanediol 1
(15) sorbitan sesquioleate 0.5
(16) Phenoxyethanol 0.5
(17) Glycerin 0.5
※ 9: CIREBELLE 109L (made by CIREBELLE)
※ 10: Oitanoru G (manufactured by Kognis Japan)
※ 11: Opanol B-100 (manufactured by BASF)
※ 12: Lucentite SAN (Coop Chemical Co., Ltd.)
* 13: KSG-18 (Shin-Etsu Chemical Co., Ltd., solid content 15% diphenylsiloxyphenyl trimethicone solution)

(Manufacturing method)
A. Ingredients (1) to (7) are dissolved by heating at 100 ° C., and ingredients (8) to (11) are uniformly mixed.
B. Ingredients (12) to (17) are added to A and emulsified.
C. B was filled in a tube container to obtain a hair setting agent (water-in-oil gel form).

  The hair setting composition of Example 2 was excellent in hair setting effect, no stickiness, lightness of feeling of use of spreading, moist feeling of hair after use, and maintenance of setting power of hair.

Example 3: Hair setting agent (in-water oil type gel-like)
(Component) (%)
(1) Stearic acid 3
(2) Sunflower wax * 2 6
(3) Fischer-Tropsch wax * 9 0.5
(4) bee wax 2
(5) 2-decyl tetradecanol * 14 1
(6) (Dimethicone / vinyl dimethicone) crosspolymer * 7 0.5
(7) Serisite ※ 15 5
(8) Silica * 16 2
(9) Bengala coated mica titanium 0.1
(10) Silicone resin powder * 7 5
(11) Triethanolamine 2
(12) Purified water balance (13) Alkyl acrylate copolymer emulsion * 17 10
(14) Ethanol 10
(15) Natural vitamin E 0.5
(16) sorbitan sesquioleate 0.5
(17) Lecithin 0.5
* 14: Enjecor 240A (manufactured by New Japan Chemical Co., Ltd.)
※ 15: 2% dimethicone treatment ※ 16: Psylicia 550 (Fuji Silysia Chemical Ltd.)
※ 17: YODOSOL GH810F (Akzo Nobel product, 45% solid content)

(Manufacturing method)
A. Ingredients (1) to (6) are dissolved by heating at 100 ° C., and ingredients (7) to (10) are uniformly mixed.
B. Ingredients (11) to (17) are added to A and emulsified.
C. B was filled in a jar container to obtain a hair setting agent (in oil-in-water gel form).
The hair setting composition of Example 12 was excellent in the setting effect of the hair, no stickiness, lightness of feeling of using the spread, moist feeling of the hair after use, and maintenance of setting power of the hair.

Example 4: Hair setting agent (oil-based liquid)
(Component) (%)
(1) Dextrin palmitate 1
(2) Sunflower wax ※ 2 3
(3) Trimethylsiloxy silica * 18 10
(4) Isostearyl alcohol * 19 5
(5) (Dimethicone / vinyl dimethicone)
Cross polymer ※ 7 2.5
(6) Light liquid isoparaffin balance (7) Decamethylcyclopentasiloxane 20
(8) Phenyl glycol 1
(9) Silicone resin powder * 7 5
(10) Tocopheryl acetate 0.5
※ 18: Silicon KF-7312J (Shin-Etsu Chemical Co., Ltd., solid content 50% decamethylcyclopentasiloxane solution)
※ 19: Lithonol 18SP (made by high-grade alcohol industry company)

(Manufacturing method)
A. Ingredients (1) to (8) are dissolved by heating at 90 ° C.
B. Add components (9) to (10) to A and mix uniformly.
C. B was filled in a container with an applied body to obtain a hair setting agent (oil-based liquid).

  The hair setting composition of Example 4 was excellent in hair setting effect, no stickiness, lightness of feeling of use of spreading, moist feeling of hair after use, and sustained setting power of hair.

Example 5 Hair-dressing agent (oil-based stick-like)
(Component) (%)
(1) Fischer-Tropsch wax * 4 5
(2) Sunflower wax * 1 10
(3) Trimethylsiloxy silica * 19 10
(4) Decamethylcyclopentasiloxane 5
(5) 2-decyl tetradecanol * 6 20
(6) Liquid paraffin remaining amount (7) (dimethicone / vinyl dimethicone)
Cross polymer * 7 1
(8) Silicone resin powder * 7 5
(9) Carbon black 10
(10) Serisite 10
(11) Dipropylene glycol 1

(Manufacturing method)
A. Ingredients (1) to (7) are dissolved by heating at 90 ° C.
B. Add components (8) to (11) to A and mix uniformly.
C. B was filled in a mold and loaded in a container to obtain a hair setting agent (oil-like stick-like).

  The hair setting composition of Example 5 was excellent in hair setting effect, no stickiness, lightness of feeling of use of spreading, moist feeling of hair after use, and maintenance of setting power of hair.

Claims (7)

The following components (a) to (d);
(A) containing sunflower wax (b) branched higher alcohol 18-28 carbon atoms (c) a silicone resin powder (d) (dimethicone / vinyl dimethicone) crosspolymer or (dimethicone copolymers on / phenyl vinyl dimethicone) crosspolymer Hair cosmetics (except those of aerosol type and spray type). The hair cosmetic according to claim 1, wherein the component (b) is 2-decyltetradecanol. The hair cosmetic according to claim 1, wherein the component (c) is polymethylsilsesquioxane. The hair cosmetic according to any one of claims 1 to 3, further comprising a silicone oil selected from dimethylpolysiloxane and methylphenylpolysiloxane as the component (e). The hair cosmetic preparation according to any one of claims 1 to 4, wherein the content mass ratio (a) / (b) of the components (a) and (b) is in the range of 0.1 to 9. The hair cosmetic composition according to any one of claims 1 to 5, further comprising component (f) Fischer-Tropsch wax. The hair cosmetic composition according to any one of claims 1 to 6, which is for hair setting.