JP5649905B2 - Oil-in-water mascara base material - Google Patents

Description

  TECHNICAL FIELD The present invention relates to a mascara base material that improves the usability and functionality of a mascara applied from above by applying it to a basket in advance, and more specifically, a microprojection over the entire surface of the particle surface. The present invention relates to an oil-in-water type mascara base material in which spherical silicone particles having an oil, an oil-soluble resin, and an alkyl acrylate copolymer polymer emulsion are blended. More specifically, for the effect of applying to the eyelids in advance and separating the eyelets separately without binding each other (hereinafter sometimes referred to as “separate effect”), and the makeup effect that makes the eyes stand out. In addition, the effect of making wrinkles appear thick (hereinafter sometimes referred to as “volume effect”) and the effect of applying mascara uniformly and neatly when applying mascara multiple times (hereinafter referred to as “easiness of overlaying”) The present invention relates to an oil-in-water type mascara base material that improves the usability and functionality of mascara.

Cosmetics for wrinkles such as mascara have a cosmetic effect that makes the eyes clear by curling the wrinkles or making the wrinkles thicker and longer.
Conventionally, these vaginal cosmetics have been developed according to market trends in various dosage forms, such as oil-based types, oil-in-water type and water-in-oil type emulsified types, and water-based types. I came.
The oil-based type was excellent in terms of makeup effect and its sustainability, and the water-based type was excellent in ease of application and makeup removal. The oil-in-water type and the water-in-oil type emulsified type are expected to be a dosage form that has both advantages, and various developments have been made to impart more specific functions.
The emulsion type is inferior to the oil type in terms of water resistance, oil resistance, and shape retention ability. Therefore, to improve makeup durability, increase the amount of wax, resin, and film forming agent, and curl strength. In order to impart the above, a technique of blending a fine dispersion of wax (for example, see Patent Document 1) has been studied.

  In addition, it has been said that cosmetics for vaginal use require techniques for makeup, but recently, consumers with a shallow makeup calendar often use it, so that they do not need techniques for makeup. Improved vaginal cosmetics have been developed, such as a vaginal separation effect, volume effect, and ease of overlaying.

  Specifically, a technology for blending spherical silicone resin powder into a salmon cosmetic (see, for example, Patent Document 2), and an oil-based salmon cosmetic using an oil as a continuous phase with a confetti-shaped silicone resin powder. Techniques for blending (for example, see Patent Document 3) have been studied.

  Furthermore, in order to enhance the makeup effect of mascara, a technique (for example, see Patent Document 4) that produces the ease of removing a decorative film using a mascara base material has been studied.

Japanese Patent No. 29898929 Japanese Patent Laid-Open No. 11-12132 JP 2009-149525 A JP 2004-339082 A

However, the conventional emulsifying type vaginal cosmetics can increase the wax, waxes, and film-forming agents, but can provide a cosmetic effect that makes the eyes thicker and clearer, but the system becomes harder. Since the usability deteriorated and the adhesiveness became too high, the ridges were bundled together, and there was a drawback that it was not possible to separate each one cleanly.
In addition, the technology for blending silicone resin powders is effective in preventing bundling, but because of the low adhesion of the silicone resin, it is difficult to apply a decorative film, and the makeup is satisfactory in terms of finish. The effect was not obtained.
Furthermore, the conventional mascara base material can change the characteristics of the mascara applied on top, and can give makeup effects such as ease of dropping the makeup film and thickening wrinkles to make the eyes stand out. As for the bundling of wrinkles due to the nature, no satisfactory one was obtained.

  For this reason, by pre-applying to the eyelids, the effect of making the eyelashes thicker and the effect of making the eyelashes thicker for the effect of separating the eyelets one by one without sticking them together, It has been desired to develop an oil-in-water type mascara base material that can improve the usability and functionality of mascara, which is excellent in the effect that it can be applied uniformly and neatly when it is applied to the surface.

  In such a situation, the present inventors have conducted extensive research to solve the above problems, and as a result, the spherical silicone particles having a special shape that have microprojections over the entire surface of the particles on the surface before applying the mascara. If mascara is applied from above, the mascara applied from above is excellent in the effect that the cocoons are separated from each other without bundling each other, and even when the mascara is applied multiple times to the cocoon The oil-in-water type mascara base material in which the silicone particles were fixed with an oil-soluble resin and an alkyl acrylate copolymer polymer emulsion was found.

That is, the present invention
The following components (a) to (c);
Component (a) Spherical silicone particle component (b) oil-soluble resin having fine protrusions over the entire surface of the particle surface
Component (c) Polymer emulsion which is one or more selected from the following components
Alkyl acrylate copolymer
Alkyl methacrylate copolymer
An oil-in-water type mascara base material comprising an alkyl acrylate / alkyl methacrylate copolymer is provided.

  In addition, the component (b) is selected from the group consisting of pentaerythrosyl rosin acid, candelilla resin, hydrogenated glyceryl abietic acid, acrylic-silicone graft copolymer, trimethylsiloxysilicic acid, polyvinyl isobutyl ether, and polyisobutylene. The oil-in-water type mascara base material is characterized by being two or more kinds.

  Moreover, the said component (c) is a polymer emulsion with an average particle diameter of 10-100 nm, It provides the said any oil-in-water type mascara base material characterized by the above-mentioned.

  The component (c) is one or more selected from an alkyl acrylate copolymer, an alkyl methacrylate copolymer, and an alkyl acrylate / alkyl methacrylate copolymer. Any oil-in-water type mascara base material is provided.

  The present invention is applied to the eyelids in advance, so that the eyelashes are separated from each other without being bundled together, and the effect of making the eyelids thicker and the mascara more than once for the makeup effect that makes the eyes stand out. It is related with the oil-in-water type mascara base material which improves the usability and functionality of the mascara, which is excellent in the effect that it can be applied uniformly and cleanly.

  The component (a) spherical silicone particles having fine protrusions over the entire surface of the particles used in the present invention are particles having fine protrusions on the spherical silicone particle surface. Moreover, the particle | grains of a component (a) become a shape which has a microprotrusion over the whole surface instead of a part of spherical silicone particle surface, and is a particle | grains like a so-called compound sugar. Furthermore, the microprotrusions in the particles of component (a) are chemically bonded, and unlike microparticles formed by mixing and adsorbing spherical silicone particles and different particles, the microprotrusions are different. Are particles that are not easily missing.

  The silicone particles of component (a) are organosilsesquioxane particles, and organotrialkoxysilanes such as methyltrimethoxysilane and methyltriethoxysilane described in Japanese Patent No. 3455562 are used with an alkali catalyst. It is manufactured by a method of hydrolysis / condensation.

  As the silicone particles of component (a), TOSPEARL 150KA manufactured by Momentive Performance Materials Japan can be used as a commercial product.

  The blending amount of the silicone particles of the component (a) in the oil-in-water mascara base material of the present invention is not particularly limited, but is preferably 0.5 to 15% by mass (hereinafter simply indicated as “%”), 0.5 10% is more preferable. If the blending amount of the component (a) is within this range, the mascara applied from above is superior in the effect that the cocoons are separated from each other without bundling the cocoons, and the mascara is made into cocoons multiple times. It is also superior in the effect that it can be applied uniformly and neatly when applied.

  The oil-soluble resin of the component (b) used in the present invention may be any oil-soluble resin that is usually used in cosmetics. For example, terpene resins such as rosin acid pentaerythritol and hydrogenated glyceryl abietate , Candelilla resin, acrylic-silicone graft copolymer, trimethylsiloxysilicic acid, polyvinyl isobutyl ether, polyisobutylene and the like, and these can be used alone or in combination.

  The candelilla resin is a resin component obtained by fractional extraction of candelilla wax with an organic solvent, and the resin component is preferably contained in a proportion of 65% or more, more preferably 85% or more. . The acrylic-silicone graft copolymer is a radical polymer of an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate. Examples are those described in Kaihei 2-25411, JP-A-2-132141, etc., and include INCI (International Nomenclature Cosmetic Labeling Names) names such as ACLYLATES / DIMETHICONE COPOLYMER (alkyl acrylate copolymers / dimethyl copolymers, etc.). be able to.

  Such oil-soluble resins include commercially available products such as ester gum HP (manufactured by Harima Chemicals), Pine Crystal KE-311 (manufactured by Arakawa Chemical Industries), candelilla resin E-1 (manufactured by Nippon Natural Products), silicon KP. -545 (solid content 30%) (Shin-Etsu Chemical Co., Ltd.), Silicon KP-549 (solid content 40%) (Shin-Etsu Chemical Co., Ltd.), Silicon KP-550 (solid content 40%) (Shin-Etsu Chemical Co., Ltd.) ), SR1000 (manufactured by Momentive Performance Materials Japan), silicon KF-9021 (50% cyclomethicone solution) (manufactured by Shin-Etsu Chemical Co., Ltd.), silicon KF-7312J (50% cyclomethicone solution) (Shin-Etsu Chemical) For example, Vistanex LMMH-LC (manufactured by Exxon Chemical).

  Among these oil-soluble resins, rosinic acid pentaerythritol and candelilla resin are preferable in order to further enhance the effect of uniformly and neatly applying mascara to a basket several times.

  Although the compounding quantity of the oil-soluble resin of the component (b) in the oil-in-water mascara base material of this invention is not specifically limited, 0.1 to 5% is preferable and 0.5 to 3% is more preferable. If the blending amount of the component (b) is within this range, the mascara applied from above is superior in the effect that the cocoons are separated from each other without bundling the cocoons, and the mascara is made into cocoons multiple times. It is also superior in the effect that it can be applied uniformly and neatly when applied.

The component (c) used in the present invention may be any polymer emulsion (same meaning as an emulsion polymer) that is usually used in cosmetics such as mascara. For example, INCI (International Nomenclature Cosmetic Labeling Names) It is listed as ACRYLATES COPOLYMER. Specifically, an aqueous emulsion of a copolymer using two or more of acrylic acid, methacrylic acid, or esters thereof, such as an alkyl acrylate copolymer, an alkyl methacrylate copolymer, Examples thereof include alkyl acrylate / methacrylic acid alkyl copolymers. Among these, about the alkyl group of alkyl acrylate or alkyl methacrylate, it may contain 1 type of C1-C12, or may contain 2 or more types of alkyl groups.

  The alkyl acrylate copolymer emulsion of component (c) is composed of an alkyl acrylate copolymer dispersed in water to form an emulsion, and the alkyl acrylate copolymer dispersed by volatilization of water on the heel. The particles are bonded to form a film, but the formed film characteristics vary depending on the average particle diameter of the emulsion. The average particle size of the polymer emulsion of component (c) used in the present invention is not particularly limited, but in order to further improve the effect of separating the cocoons one by one without binding the cocoons and the effect of making the cocoons thicker. Is preferably 10 to 100 nm. Here, the average particle size is a value measured at pH 7 using a submicron particle analyzer N5 manufactured by Beckman Coulter.

  Such a polymer emulsion of component (c) can be obtained by a general polymerization method such as an emulsion polymerization method, a core-shell polymerization method, a radical polymerization method, or a soap-free emulsion polymerization method. Examples of these commercially available products include YODOSOL GH800 (manufactured by Akzo Nobel, solid content 45%), YODOSOL GH41 (manufactured by Akzo Nobel, solid content 45%), and the like.

  Moreover, the polymer emulsion of the component (c) used for this invention is a polymer emulsion by which a viscosity does not increase, when an alkali is added. Here, the viscosity does not increase means that an increase in viscosity when the pH is adjusted to 7.5 using triethanolamine as an alkali in an aqueous dispersion prepared by converting the polymer emulsion to 0.3% in terms of solid content, Compared to the viscosity before neutralization with alkali, it is less than twice.

  Although the compounding quantity of the polymer emulsion of the component (c) in the oil-in-water type mascara base material of this invention is not specifically limited, 0.05-15% is preferable as solid content of a copolymer, 0.2-10% More preferred. If the blending amount of the component (c) is within this range, the mascara applied from above is superior in the effect that the cocoons are separated from each other without bundling the cocoons, and the mascara is made into cocoons multiple times. It is also superior in the effect that it can be applied uniformly and neatly when applied.

  The oil-in-water mascara base material of the present invention is blended with an oily component constituting the oil phase. Such oily components include hydrocarbons, fats and oils, regardless of properties such as solid oils, semi-solid oils, liquid oils, volatile oils, etc. , Waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyethylene wax, ethylene / propylene copolymer, paraffin wax, montan wax, Fischer-Tropsch wax, ceresin wax, ozokerite wax, molasses, olive oil, castor oil, Oils and fats such as mink oil, macadamian nut oil, beeswax, gay wax, carnauba wax, waxes such as candelilla wax, jojoba oil, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, 2 -Cetyl ethylhexanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, neopentyl glycol dioctanoate, cholesterol fat Esters, esters such as phytosterol fatty acid esters, triglycerides, diisostearyl malate, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl Higher alcohols such as alcohol, isostearyl alcohol, and behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, oleyl-modified organopolysiloxane, behenyl-modified organopolysiloxane, alkoxy-modified organopoly Silicones such as siloxane and fluorine-modified organopolysiloxane, perfluorodecane, perfluorooctane Fluorine oils such as perfluoropolyether, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate, 12-hydroxystearic acid 1 type or 2 or more types can be used.

  The blending amount of the oil component in the oil-in-water mascara base material of the present invention is not particularly limited, but is preferably 0.5 to 30%.

  In the oil-in-water mascara base material of the present invention, an aqueous component constituting the aqueous phase is blended. Examples of such aqueous components include water, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol, glycerols such as glycerin, diglycerin, and polyglycerin, aloe vera, witch hazel, hamamelis, Examples include plant extracts such as cucumber, lemon, lavender and rose, and these can be used alone or in combination.

  The blending amount of the aqueous component in the oil-in-water mascara base material of the present invention is not particularly limited, but is preferably 30 to 95%.

The oil-in-water mascara base material of the present invention preferably contains a surfactant as an emulsifier. As such surfactants, any surfactants generally used in cosmetics can be used, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric interfaces. Examples include activators.
Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone And the like.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin. In the oil-in-water mascara base material of the present invention, these surfactants can be used by appropriately selecting one or two or more of those surfactants from those described above.

  Although the compounding quantity of surfactant in the oil-in-water type mascara base material of this invention is not specifically limited, 0.01 to 10% is preferable.

  In addition to the above components, the oil-in-water mascara base material of the present invention is a component usually used in cosmetics, a water-soluble film-forming resin other than component (c), alkali, hydrocarbon, ester, vegetable oil, emulsifier Oily components such as aqueous oils, silicone oils, silicone derivatives, powders such as inorganic pigments, organic pigments and dyes, and those treated with silicones or fluorine compounds, fibers, polyhydric alcohols, water-soluble polymers, water-soluble films Formulating aqueous components such as forming resins and moisturizers, sugars, UV absorbers, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, etc. within a range that does not impede the effects of the present invention. Can do.

  Examples of the water-soluble film-forming resin other than the component (c) include polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, and the like, and one or more of them can be used.

  As the powder component, other than the component (A), if it is a powder that is used as a powder generally used in cosmetics, a spherical shape, a plate shape, a needle shape, a fume shape, a fine particle, It is not particularly limited by particle size such as pigment class, particle structure such as porous and nonporous, etc., inorganic powders, glitter powders, organic powders, pigment powders, metal powders, Examples include composite powders. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, etc. Colored inorganic pigments, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide White body powders such as zirconium oxide, antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, Titanium oxide coated mica, titanium oxide coated bismuth oxychloride Iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc. Bright powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, polypropylene resin, urethane Organic polymer resin powders such as resins, organic low molecular weight powders such as zinc stearate and N-acyl lysine, natural organic powders such as silk powder and cellulose powder, red 201, red 202 and red 205 Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Organic pigment powders such as zirconium, barium or aluminum lakes such as green No. 3 and blue No. 1, or metal powders such as aluminum powder, gold powder and silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, sulfuric acid Examples include composite powders such as barium-coated mica titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide. These powders can be used singly or in combination of two or more of them. May be.

  The fiber is not particularly limited as long as it is generally used in cosmetics, and synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate human silk, and the like. Can be mentioned. These fibers are used after being surface-treated as necessary. Examples of the surface treatment agent include a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, and surfactant.

  Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan and other semi-synthetic compounds such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer and sodium polyacrylate can be mentioned. Examples of the humectant include protein, mucopolysaccharide, collagen, elastin, keratin and the like.

  Examples of the ultraviolet absorber include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, and the like. Examples of the antioxidant include α-tocopherol and ascorbic acid, examples of the cosmetic component include vitamins, anti-inflammatory agents, herbal medicines, and examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol, and 1,2-pentadiol. Can be mentioned.

  Examples of the form of the oil-in-water mascara base material of the present invention include creams, gels, and liquids. Among these, gels obtained by gelling water with a water-soluble polymer are preferred. The method for producing an oil-in-water mascara base material of the present invention can be obtained by uniformly heating and mixing an aqueous component and an oily component, respectively, and emulsifying them.

  EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.

Examples 1 to 6 and Comparative Examples 1 to 4: Oil-in-water mascara base material (gel)
Oil-in-water type mascara base materials having the formulations shown in Tables 1 and 2 below were prepared and evaluated for the following evaluation items. The results are also shown in Tables 1-2.

(Production method)
A. Ingredients (1) to (6) are heated to 80 ° C. and mixed uniformly.
B. Components (7) to (16) are heated and mixed uniformly at 80 ° C.
C. A is added to B, emulsified, cooled to room temperature, and component (17) is added and mixed.
D. Fill the container with C to make a product.

The following evaluation items were evaluated by the following methods. In addition, after applying the oil-in-water type mascara base material, the mascara to be applied used mascara 1 having the following prescription (evaluation item)
a. No bunch when mascara is stacked on top (separate effect)
b. Makeup effect (volume effect) to make the wrinkles look thicker when the mascara is overlaid
c. Ease of overlaying mascara on top of mascara 1
(Ingredient) (%)
(1) Carboxymethylcellulose 3
(2) Purified water remaining amount (3) Sodium hydroxide 1
(4) Polyvinyl alcohol 5
(5) Black iron oxide 10
(6) Ethanol 5
(Production method)
A. Components (1) to (6) are uniformly mixed and dissolved at room temperature.
B. A is filled into a container to obtain a product.

(Evaluation method)
Regarding the evaluation items a to c, the oil-in-water type mascara base material of the examples and comparative examples is subjected to a use test by 20 professional panels, and each panel member evaluates and classifies them according to the following absolute evaluation in 7 stages. The average value was calculated from the total score of all the panels, and was judged according to the following four-step criteria.
Evaluation was made by applying an oil-in-water type mascara base material once in a bowl, drying for one minute, applying an oil-in-water type mascara base material again, and then applying the mascara 1 twice thereon. The finished feeling was evaluated.

<Absolute evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad <Criteria>
(Judgment): (Average score)
◎: More than 5 points: Very good ○: More than 3 points, 5 points or less: Good △: More than 1 point, 3 points or less: Slightly poor ×: 1 point or less: Bad

  As is clear from the results in Tables 1 and 2, the oil-in-water mascara base material of Examples 1 to 6 of the present invention is an effect that separates each other without bundling the eyelids, and makeup that makes the eyes stand out. It is an oil-in-water mascara base material that improves the usability and functionality of mascara, which is excellent in the effect of making the wrinkle thicker and the effect of applying the mascara uniformly and neatly when applied to the reed several times for the effect. . On the other hand, the comparative example 1 which does not mix | blend a component (a) has high adhesiveness of oil-in-water type mascara base material itself, and when a mascara is piled up, wrinkles will be bundled, and the favorable separate effect The volume effect was not good. Moreover, the comparative example 2 which mix | blended the spherical silicone particle | grains with a smooth surface instead of a component (a) has bad adhesiveness to the wrinkles of an oil-in-water type mascara base material itself, and when the mascara is accumulated on top, It was inferior in terms of ease of operation. Furthermore, in Comparative Example 3 in which component (b) is not blended and in Comparative Example 4 in which component (c) is not blended, the adhesive force of the oil-in-water mascara base material itself is insufficient, and the volume effect and superposition No good product was obtained in terms of ease of operation.

Example 7: Oil-in-water mascara base material (gel, fiber-filled type)
(Ingredient) (%)
(1) Stearic acid 1.5
(2) Candelilla wax 3
(3) Candelilla resin * 7 0.5
(4) Dextrin palmitate * 8 0.1
(5) Paraffin 2
(6) Polyoxyethylene sorbitan monooleate (20E.O.) 2
(7) Sorbitan sesquioleate 0.5
(8) Silicone resin powder * 2 10
(9) Bengala 0.1
(10) Yellow iron oxide 0.01
(11) Talc 1
(12) Mica titanium 1
(13) Triethanolamine 1.5
(14) Glycerin 5
(15) Styrene / vinyl pyrrolidone polymer emulsion * 9 15
(16) Polyvinyl acetate polymer emulsion * 10 5
(17) Nylon fiber (8 denier, 2 mm) 2
(18) 1,2-pentadiol 0.2
(19) Purified water remaining amount * 7: Candelilla resin E-1 (manufactured by Nippon Natural Products)
* 8: Leopard KL (manufactured by Chiba Flour Milling)
* 9: ANTARA 430 (solid content 40%) (manufactured by IPS Japan)
* 10: Viniblanc GV-5651 (solid content 40%) (manufactured by Nissin Chemical Industry)
(Production method)
A. Ingredients (1) to (7) are heated to 90 ° C. and mixed uniformly.
B. Components (8) to (19) are heated at 90 ° C. and mixed uniformly.
C. Add A to B, emulsify, and cool to room temperature.
D. Fill the container with C to make a product.

  The oil-in-water mascara base material of Example 7 has an effect that separates one by one without bundling the wrinkles, a makeup effect that makes the eyes stand out, and an effect that makes the wrinkles thicker and the mascara multiple times. It was an oil-in-water type mascara base material that improves the usability and functionality of mascara, which is excellent in the effect that it can be applied uniformly and neatly.

Example 8: Oil-in-water mascara substrate (component) (%)
(1) Methylphenyl polysiloxane 1
(2) Trimethylsiloxysilicate solution * 11 15
(3) Polyoxyethylene (30E.O.) cetyl ether 2
(4) Silicone resin powder * 2 1
(5) Silicone resin powder * 3 0.5
(6) Carbon black 0.5
(7) Polyethylene terephthalate / aluminum / epoxy laminated powder 2
(8) Polyacrylic acid polymer emulsion * 12 5
(9) L-arginine 2
(10) Polyvinyl alcohol 2
(11) Polyvinylpyrrolidone 0.1
(12) Rosemary extract 0.1
(13) Ethanol 5
(14) Purified water remaining amount * 11: Silicon KF-7312J (manufactured by Shin-Etsu Chemical Co., Ltd., 50% decamethylcyclopentasiloxane solution)
* 12: Primal ASE-60 (Nihon Acrylic Chemical Co., Ltd., solid content 30%)
(Production method)
A. Ingredients (1) to (3) are uniformly dissolved by heating to 80 ° C.
B. Components (4) to (14) are mixed uniformly and heated to 80 ° C.
C. A is added to B and emulsified.
D. Fill the container with C to make a product.

  The oil-in-water mascara base material of Example 8 has an effect of separating the cocoons without binding each other, a makeup effect that makes the eyes stand out, and an effect of making the cocoon thick and mascara multiple times. It was an oil-in-water type mascara base material that improves the usability and functionality of mascara, which is excellent in the effect that it can be applied uniformly and neatly.

The present invention is applied to the eyelids in advance, so that the eyelashes are separated from each other without being bundled together, and the effect of making the eyelids thicker and the mascara more than once for the makeup effect that makes the eyes stand out. It is related with the oil-in-water type mascara base material which improves the usability and functionality of the mascara, which is excellent in the effect that it can be applied uniformly and cleanly.
that's all

Claims (4)

The following components (a) to (c);
Component (a) Spherical silicone particle component (b) oil-soluble resin having fine protrusions over the entire surface of the particle surface
Component (c) Polymer emulsion which is one or more selected from the following components
Alkyl acrylate copolymer
Alkyl methacrylate copolymer
An oil-in-water type mascara base material comprising an alkyl acrylate / alkyl methacrylate copolymer . The component (b) is one or two selected from pentaerythrosyl rosinate, candelilla resin, hydrogenated glyceryl abietate, acrylic-silicone graft copolymer, trimethylsiloxysilicic acid, polyvinyl isobutyl ether, and polyisobutylene. It is the above, The oil-in-water type mascara base material of Claim 1 characterized by the above-mentioned. The oil-in-water type mascara base material according to claim 1 or 2, wherein the component (b) is a rosinic acid pentaerythritol and / or a candelilla resin. The oil-in-water mascara base material according to any one of claims 1 to 3, wherein the component (c) is a polymer emulsion having an average particle size of 10 to 100 nm.