KR102396751B1 - cosmetic set - Google Patents

Abstract

The present invention provides a cosmetic set that has no color bleed during use, no color transfer to tableware, etc., has an excellent effect of preventing color transfer, does not have a pulling feeling after use, and does not collapse over time make it a task The cosmetic set of the present invention that has solved the problem is a cosmetic set comprising a first composition and a second composition, wherein the second composition is applied after the first composition is applied to the application part, and further, the first composition and the agent The two compositions are characterized by containing the following components, respectively: (first composition) (A) a film-forming silicone resin; (B) a silicone oil having a kinematic viscosity of 1000 to 1000000cs at 25°C; (C) volatile hydrocarbon oils; (D) Color pigment, (Second composition) The component (A) and the component (C) are mixed in an equal amount with a mixture obtained by mixing the component (C) at a mass ratio of 1:1, and the component is phase-separated when it is left still at 25°C for 60 minutes (E) Phosphorus emulsion.

Description

cosmetic set

The present invention relates to a cosmetic set comprising a first composition and a second composition, and to a cosmetic set in which the second composition is applied after the first composition is applied to an application part.

In recent years, in makeup cosmetics, such as lip rouge and foundation, makeup collapse with time lapse and color transfer to a container, clothes, etc. have become a problem. In particular, in the case of lip rouge, the problem of color transfer of the rouge applied to the lips to tableware such as coffee cups, and the deterioration of makeup over time due to the physical contact of the lips, etc. are a problem, and various studies have been made come.

For example, as a technique for imparting a color transfer prevention effect and a cosmetic collapse prevention effect, on the first composition containing polyisobutylene and volatile hydrocarbon oil having a relative mass of 3000 to 1,000,000, the kinematic viscosity at 25°C is A technique (patent document 1) of applying a second composition containing 1000cs to 7000cs of methylphenylpolysiloxane has been proposed. However, by applying the second composition on polyisobutylene, which is a hydrocarbon-based resin, volatilization of the volatile hydrocarbon oil in the first composition is prevented, and it takes time until the cosmetic collapse prevention effect is obtained, and color bleeding occurs. there was a case In addition, when the content of polyisobutylene having a relative mass of 3000 to 1,000,000 in the first composition is increased in order to further improve the makeup crumbling effect over time, a feeling of pulling may be felt in some cases.

JP 5719315 B

Therefore, in the prior art, there is no color bleed during use, no color transfer to tableware, etc., the effect of preventing color transfer is excellent, and there is no pulling feeling after use, and the cosmetic set does not collapse over time. It was difficult to implement.

As a result of earnest research in view of the above problems, the present inventors have mixed equal amounts with a mixture of component (A) film-forming silicone resin and component (C) volatile hydrocarbon oil in a mass ratio of 1:1, 25 A cosmetic set with excellent effect of preventing color transfer without causing color bleed during use by finding that there is an oil agent, which is a component (E), which phase separates when left for 60 minutes at °C, and applying this technology to cosmetics was found to be In addition, by containing silicone oil having a kinematic viscosity of 1000 cs or more in component (B) at 25°C, a cosmetic film without a feeling of pulling was formed, and it was found that makeup did not easily collapse over time, leading to the completion of the present invention.

in other words,

[1] A cosmetic set comprising a first composition and a second composition, wherein the second composition is applied after the first composition is applied to the application part, and the first composition and the second composition each contain the following components It relates to a cosmetic set that does:

(first composition)

(A) Film-forming silicone resin

(B) silicone oil having a kinematic viscosity of 1000 to 1000000cs at 25°C

(C) volatile hydrocarbon oils

(D) colored pigment

(Second composition)

An oil agent, which is a component (E), which is phase-separated when mixed in equal amounts with a mixture obtained by mixing the component (A) and the component (C) at a mass ratio of 1:1, and allowed to stand at 25°C for 60 minutes.

[2] wherein the component (A) is trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylate/dimethicone) copolymer, (acrylate/stearyl acrylate/dimethicone methacrylate) copolymer It relates to the cosmetic set according to [1], which is one or more selected types.

[3] The cosmetic set according to [1] or [2], wherein the content of the component (E) in the second composition is 50 to 99.9 mass%.

[4] The cosmetic set according to any one of [1] to [3], wherein the content of the component (E) in the second composition is 70 to 99.9 mass%.

[5] The content of the component (A) in the first composition is 10 to 50 mass%, the content of the component (B) is 1 to 50 mass%, and the content of the component (C) is 20 to 85 mass% , to the cosmetic set according to any one of [1] to [4].

[6] The cosmetic set according to any one of [1] to [5], wherein the component (B) is a silicone oil having a kinematic viscosity of 10000 to 1000000 cs at 25°C.

[7] The component (E) is one or two or more emulsions selected from isostearic acid esters, hydroxystearic acid esters, lanolin derivatives, trimellitic acid esters, paramethoxycinnamic acid esters, and vinylpyrrolidone-based copolymers , to the cosmetic set according to any one of [1] to [6].

[8] It relates to the cosmetic set according to [7], wherein the isostearic acid ester of the component (E) is an emery-type isostearic acid group-bearing isostearic acid ester.

[9] The component (E) is isostearic acid polyglyceryl-2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl-2, nonaisostearic acid polyglyceryl-10, deca Polyglyceryl-10 isostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitate, ethylhexyl paramethoxycinnamate, ( It relates to the cosmetic set according to any one of [1] to [7], which is one or more oil agents selected from vinylpyrrolidone/hexadecene) copolymers.

[10] The cosmetic set according to any one of [1] to [9], wherein the cosmetic set is a lip cosmetic set.

According to the present invention, by using the first composition in combination with the second composition containing a specific oil agent, there is no color bleed during use, the color transfer prevention effect is excellent, and there is no feeling of pulling after use, and the It is to provide a cosmetic set that does not cause makeup collapse.

1 is a photograph confirming color transition in Example 2 when the first composition of Formula 1 and the second composition of Formula 19 or Comparative Formula 8 are combined.

The details of the present invention will be described below. In addition, in this specification, "to" shall mean the range including the numerical value before and behind it.

The film-forming silicone resin of component (A) used in the first composition of the present invention is a compound having a crosslinked structure having a siloxane structure as a main skeleton, and the silicone oil of component (B) and volatility of component (C) It is soluble in oil agents such as hydrocarbon oil, and can be used without particular limitation as long as it is used for cosmetics. Here, the film-forming property refers to having a property of forming a film after spreading a solution obtained by dissolving a silicone resin in the volatile hydrocarbon oil of component (C) on a petri dish and drying it. In addition, the obtained film may crack with drying and does not need to be obtained as a single film|membrane.

For example, trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylate/dimethicone) copolymer, (acrylate/stearyl acrylate/dimethicone methacrylate) copolymer, etc. are mentioned, These can use 1 type or 2 or more types.

Commercially available products include X-21-5616 (60% solids isododecane solution), X-21-5595 (60% solids isododecane solution), KF-7312J (50% solids 50% decamethylcyclopentasiloxane solution), KF -9021 (50% decamethylcyclopentasiloxane solution), KP-545 (solid content 30% decamethylcyclopentasiloxane solution), KP-549 (solid content 40% methyltrimethicone solution), KP-550 (solid content 50%) % isododecane solution) (product of Shin-Etsu Chemical Co., Ltd.), BELSIL TMS 803, BELSIL PMS MK Powder (Wacker Asahikasei Silicone co., ltd.), SR1000, SilForm Flexible resin, SS4267 (35% dimethylpolysiloxane solution) (manufactured by Momentive Performance Materials Japan Co., Ltd.), BY11-018 (30% decamethylcyclopentasiloxane solution) (manufactured by Toray Dow Corning Silicone Co., Ltd.), etc. and may use 1 type or 2 or more types.

Although content of the film-forming silicone resin of component (A) in the 1st composition of this invention is not specifically limited, 10-50 mass % (hereafter simply described as "%") is preferable, More preferably, 15- 35%, more preferably 15 to 30%. If it is this range, it is more preferable at the point etc. which are excellent in the cosmetic film which is excellent in no pulling feeling, makeup collapsing prevention effect, etc.

The silicone oil having a kinematic viscosity of 1000 to 1000000cs at 25°C of the component (B) used in the first composition of the present invention is a silicone oil having fluidity under the conditions of 1 atm and 25°C, dimethylpolysiloxane, methylhydride Rosenpolysiloxane, phenyl-modified silicone, alkyl-modified silicone, etc. are not particularly limited as long as they are used as cosmetics, and one or two or more thereof can be used. Moreover, it is preferable that it is 1000-100000 cs, as for the kinematic viscosity in 25 degreeC of component (B), it is more preferable that it is 10000-1000000 cs, It is especially preferable that it is 10000-100000 cs. It is more preferable at the point etc. which can suppress the pulling feeling by a silicone resin in it being this range, and the cosmetic film excellent in the cosmetic collapse prevention effect is obtained. On the other hand, if the silicone oil having a kinematic viscosity at 25°C is less than 1000cs, satisfactory color bleeding prevention effect and makeup crumbling prevention effect may not be obtained. The volatilization rate becomes slow, and a satisfactory color bleeding prevention effect may not be acquired.

Commercially available products include KF-96-1000cs/3000cs/5000cs, KF-96H-6000cs/10,000cs/12500cs/30,000cs/50,000cs/60,000cs/100,000cs/300,000cs/500,000cs/100 10,000cs, KF-50-1000cs (above, manufactured by Shin-Etsu Chemical Co., Ltd.), SH-200 C Fluid 1000CS/3000CS/5000CS/10000CS/12500CS/30000CS/60000CS/100000CS/1000000CS, BY-11-040 /003/007/014/026/320 (above, the Toray Dow Corning company make) etc. are mentioned. These can also be used, using only 1 type, or combining 2 or more types, adjusting suitably predetermined kinematic viscosity. In addition, in this invention, kinematic viscosity is a measured value in 25 degreeC by ASTM D445 measuring method.

Although content of the component (B) in the 1st composition of this invention is not specifically limited, 1-50 % is preferable, More preferably, it is 3-35 %, More preferably, it is 5-30 %. It is more preferable at the point etc. which can suppress the pulling feeling by a silicone resin in it being this range, and the cosmetic film excellent in the cosmetic collapse prevention effect is obtained.

The volatile hydrocarbon oil of component (C) used in the first composition of the present invention is liquid at 1 atm, 25° C., has volatility, has a boiling point in the range of 68 to 260° C., and is a hydrocarbon having 6 to 30 carbon atoms. and the like. Usually, it is not particularly limited as long as it is used as a cosmetic raw material, and specifically, a straight-chain hydrocarbon such as normal heptane, isooctane (2,2,4-trimethylpentane, 2,3-dimethylhexane) etc.), isododecane (2,2,4,6,6-pentamethylheptane, etc.), isohexadecane, hydrocarbons having a side chain such as isoeicosaene, or mixtures thereof, isobutene, n- Butene or the like is hydrogenated after polymerization or copolymerization (the degree of polymerization is preferably 4 to 6). Commercially available products include ISOPAR H (manufactured by Exxon Mobil Chemical), isododecane (manufactured by Bayer), isohexadecane (manufactured by Uniqema), IPsolvent 1620MU, IPsolvent 2028MU, IPsolvent 2835 (above, manufactured by Idemitsu Kosan) and the like. These can use 1 type or 2 or more types.

The content of the volatile hydrocarbon oil of component (C) in the first composition of the present invention is not particularly limited, but is preferably 20 to 85%, more preferably 25 to 80%, and still more preferably 30 to 70%. . If it is this range, it is more preferable from a point etc. which are excellent in no feeling of pulling and no color bleeding at the time of use. In addition, the content ratio in particular of the component (A) and the component (C) is not particularly limited, but (A):(C)=3:1 to 1:6 is Preferably, 2:1 to 1:5 are more preferable, and 1:1 to 1:4 are still more preferable.

If the colorant of component (D) used in the first composition of the present invention is a colorant commonly used in cosmetics, spherical shape, plate shape, spindle shape, needle shape, etc., mist shape, fine particles, pigment grade, etc. It does not specifically limit as a particle diameter or particle structure, such as porous and nonporous, etc., An inorganic colored pigment, an organic colored pigment, dye, a bright pigment, metals, etc. can be used. Specific examples of the powder include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, royal blue, ultramarine blue, and bengala, mica titanium, bismuth oxychloride, Organic Pigmented Mica Titanium, Titanium Dioxide Coated Mica, Titanium Dioxide Coated Synthetic Phosphorus Mica, Titanium Dioxide Covered Bismuth Oxychloride, Iron Oxide Mica Titanium, Wiretap Treated Mica Titanium, Carmine Treated Mica Titanium, Young Leaf, Titanium Dioxide Coated Glass Powder, Polyethylene Tere Bright pigments such as resin laminated powder such as phthalate/aluminum/epoxy laminated powder, polyethylene terephthalate/polyolefin laminated film powder, polyethylene terephthalate/polymethylmethacrylate laminated film powder, Red No. 201, Red No. 202, Red 205 Organic pigment powder such as No., Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4 , Yellow No. 5, Green No. 3, Blue No. 1, etc. Zirconium, barium, or an organic pigment powder such as aluminum lake, or metal powder such as aluminum powder, gold powder, silver powder, titanium particle titanium oxide coated mica titanium, microparticle zinc oxide coated mica titanium , barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing composite powders such as silicon dioxide, and the like can be further exemplified, and as needed, one type or a combination of two or more types can be used. In addition, these can be surfaced using one or two or more of fluorine-based compounds, silicone-based compounds, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, beeswax, surfactants, etc. You may perform a process.

Although content of the coloring agent of the component (D) in the 1st composition of this invention is not specifically limited, 0.0001 to 30 % is preferable, and 0.001 to 20 % is more preferable.

The first composition of the present invention may contain, in addition to the components (A) to (D), a component commonly used in cosmetics within a range that does not interfere with the effect of the present invention, for example, component (D) ) powders other than ), oil agents other than components (B) and (C), surfactants, monohydric alcohols, polyhydric alcohols, water-soluble polymers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, UV absorbers, moisturizers, antibacterial agents , fragrances, salts, antioxidants, pH adjusters, chelating agents, refreshing agents, anti-inflammatory agents, skin beauty ingredients (whitening agents, cell activating agents, skin roughness improving agents, blood circulation promoters, skin astringents, anti-seborrheic agents, etc.), vitamins, amino acids , nucleic acids, hormones, clathrates, etc. may be appropriately contained.

The oil agent includes, for example, hydrocarbons, oils and fats, beeswax, hydrogenated oil, ester oil, fatty acid, regardless of the origin of animal oil, vegetable oil, synthetic oil, etc., and the properties of solid oil, semi-solid oil, liquid oil, etc. and higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oil-based gelling agents, oil-soluble resins, and volatile oil agents. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, Fischer-Tropsch wax, cotton wax, olive oil, castor oil, Oils and oils such as mink oil and macadamia nut oil, beeswax such as beeswax, carnauba wax, candelilla wax, spermaceti, jojoba oil, cetyl isooctanate, isopropyl myristate, isopropyl palmitate, mi Octyldodecyl lysate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fatty acid Esters, esters such as N-lauroyl-L-glutamic acid di(cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, isostearyl alcohol Higher alcohols such as henyl alcohol, silicones such as methylphenylpolysiloxane and fluorine-modified organopolysiloxane, fluorine-based emulsions such as perfluorodecane, perfluorooctane, and perfluoropolyether, lanolin, Lanolin derivatives such as lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, dextrin octanoate, dextrin laurate, dextrin palmitic, dextrin myristate, dextrin stearate, dextrin behenate, dextrin palmitic acid, (palmitic acid) /Octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxy stearic acid, oily gelling agents such as calcium stearate, hydrogenated rosin acid pentaerythrityl, and specific acrylic acid alkylmethylpolysiloxane ester usefulness and volatile oil agents such as silicones such as resin, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane, and one or two or more of these Available.

Among the oil agents other than the components (B) and (C), with respect to the oil agent that is liquid at 25°C, the content of the oil agent in the first composition of the present invention is not particularly limited. When it applies to the above, it is preferable that it is 0 to 10 %, and it is more preferable that it is 0 to 5 % from the point that color bleeding becomes difficult to occur.

The component (E) which is phase-separated when mixed in equal amounts with the mixture which mixed component (A) and component (C) used for the 2nd composition of this invention in the mass ratio of 1:1, and left still at 25 degreeC for 60 minutes ) can be used without particular limitation as long as it is used for cosmetics.

Although it does not specifically limit as an example of the oil agent which is component (E) used for the 2nd composition of this invention, Isostearic acid polyglyceryl-2, triisostearate polyglyceryl-2, tetraisostearic acid polyglyceryl. Isostearic acid ester, hydroxystearic acid, such as Ryl-2, polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate Hydroxystearic acid esters such as ethylhexyl, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, trimellitic acid esters such as trimellitic acid tritridecyl and trimellitic acid trioctyl, paramethoxycinnamic acid and vinylpyrrolidone-based copolymers such as para-methoxycinnamic acid ester such as ethylhexyl and (vinylpyrrolidone/hexadecene) copolymer, and these may be used alone or in combination of two or more. Among these, the ease of phase separation when mixed in equal amounts with a mixture obtained by mixing the component (A) and the component (C) at a mass ratio of 1:1, and left still at 25°C for 60 minutes, and the effect of preventing color bleeding based on this, etc. In terms of, isostearic acid polyglyceryl-2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl-2, nonaisostearic acid polyglyceryl-10, decaisostearic acid polyglyceryl -10, pentaerythrityl tetraisostearate, glyceryl triisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitate, ethylhexyl paramethoxycinnamate, (vinylpyrrolidone/hexa It is more preferable to use 1 type or 2 or more types selected from decene) copolymer, isostearic acid polyglyceryl-2, triisostearic acid polyglyceryl-2, tetraisostearic acid polyglyceryl-2, Polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, glyceryl triisostearate, lanolin acetate, tritridecyl trimellitate, (vinylpyrrol It is particularly preferable to use one or more selected from the group consisting of don/hexadecene) copolymers.

In addition, in the said isostearic acid ester, isostearic acid means 1 type, or a mixture of 2 or more types of branched stearic acid. For example, 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl)-octanoic acid is converted to a branched aldehyde having 9 carbon atoms by oxo reaction of isobutylene dimer, and then this It can be produced by converting the aldehyde to a branched unsaturated aldehyde having 18 carbon atoms by aldol condensation, followed by hydrogenation and oxidation (hereinafter, abbreviated as "aldol condensation type"), which is manufactured by, for example, Nissan Chemical Industries. It is marketed. 2-heptylundecanoic acid can be produced by dimerizing nonyl alcohol by Guerbet reaction and oxidizing it, which is commercially available, for example, from Mitsubishi Chemical, and is a similar mixture with slightly different branching positions. As such, it is commercially available from Nissan Chemical Industry Co., Ltd., and a type in which the starting alcohol is not straight-chain saturated but branched at two methyl points is also commercially available from Nissan Chemical Company (hereinafter, all of them are abbreviated as “Guerbet reaction type”). In addition, methyl-branched isostearic acid is obtained as a by-product at the time of the dimer production of oleic acid, for example [For example, J. Amer. Oil Chem. Soc., 51, 522 (1974)], for example, those commercially available from Emery, Inc. in the United States (hereinafter abbreviated as "Emery type"). Another starting material of dimer acid, which is a starting material of emery-type isostearic acid, may include not only oleic acid but also linoleic acid, linoleic acid, and the like. Although it does not specifically limit in this invention, Ease of phase separation when mixed in equal amounts with the mixture which mixed component (A) and component (C) at a mass ratio of 1:1, and left still at 25 degreeC for 60 minutes, and it It is more preferable that it is an isostearic acid ester which has an emery-type isostearic acid group from a viewpoint, such as a color-bleed prevention effect based on it.

Commercially available products include Cosmol 41V, Cosmol 42V, Cosmol 43V, Cosmol 44V (manufactured by Nisshin Oilio Group), ANTARON V-216 (manufactured by ISP), LIPONATE TDTM (manufactured by Lipo Chemicals), purified lanolin ( Nippon Seika Corporation), ACELAN SP, CRODAMOL GTIS-LQ-(JP), CRODAMOL PTIS-LQ-(JP) (above, Croda Japan KK), NIKKOL Decaglyn 10-ISV (Nikko Chemicals Corporation) , S-Pace IS-1009P (Sakamoto Yakuhin Co., Ltd.), and the like, and one type or two or more types can be used from these.

Although content of the component (E) in the 2nd composition of this invention is not specifically limited, It is preferable that it is 50 to 99.9 %, and it is more preferable that it is 70 to 99.9 %. If it is within this range, by using it in combination with the first composition, the color transfer prevention effect of the first composition is increased, the color does not come off coffee cups, etc., and the makeup film does not collapse over time, and a cosmetic film excellent in makeup durability is obtained. It is more preferable in a point etc.

The second composition of the present invention contains, in addition to component (E), an oily component, an oil gelling agent, a powder and a surface-treated product thereof, a surfactant, an aqueous component, a UV absorber, Moisturizers, antioxidants, cosmetic ingredients, preservatives, pigments, fragrances, etc., may contain other ingredients commonly contained in cosmetics.

As an oily component, in addition to component (E), irrespective of the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. of animal oil, vegetable oil, synthetic oil, etc. generally used in cosmetics, hydrocarbons, oils and fats, beeswax, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, oil-based gelling agents, and the like. Specifically, beeswax such as beeswax, spermaceti, carnauba wax, and candelilla wax, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid and oleic acid, stearyl alcohol, cetyl Higher alcohols such as alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol and behenyl alcohol, fluorine-based emulsions such as perfluorodecane, perfluorooctane, and perfluoropolyether, octanic acid Dextrin, lauric acid dextrin, palmitic acid dextrin, myristic acid dextrin, stearic acid dextrin, behenic acid dextrin, palm oil fatty acid dextrin, (palmitic acid/octanic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, isostear Oil-based gelling agents, such as aluminum acid, potassium stearate, and 12-hydroxystearic acid, etc. are mentioned, These can be used 1 type, or 2 or more types.

The powder is not particularly limited by, for example, spherical shape, plate shape, needle shape, etc., haze shape, particle size such as fine particles, pigment grade, and particle structure such as porous and nonporous, inorganic powders , organic powders, pigment powders, composite powders, and the like. Specifically, as a colorant, titanium oxide, zinc oxide, black titanium oxide, iron ferrocyanide (conjou), ultramarine blue, bengala, iron sulfate, black iron oxide, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, sulfate Silicon oxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, Silicon carbide, boron nitride, nylon powder, polymethyl methacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystalline cellulose, N-asa and acyllysine, urethane powder, and the like. In addition, as a pearlescent pigment, bismuth oxychloride, mica titanium, iron oxide coated mica, iron oxide coated mica titanium, organic pigment coated mica titanium, aluminum powder, etc., as a sunscreen agent, fine particle titanium oxide, fine particle zinc oxide, cerium oxide, fine particle oxidation Composite powder, such as titanium-coated mica titanium, fine particle zinc oxide-coated mica titanium, and barium sulfate-coated mica titanium, etc. are mentioned, These can be used 1 type, or 2 or more types. On the other hand, in order to improve dispersibility and adhesion, these powders may be surface-treated by a known method with a surface treatment agent such as silicones, fluorine compounds, metal soaps, and oil agents, and may be used.

As the surfactant, any surfactant can be used as long as it is a surfactant generally used in cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. For example, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof, polyoxyethylene hydrogenated castor oil, poly and oxyalkylenealkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.

As the aqueous component, in addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, 1,2-pentanediol, dipropylene glycol, polyethylene glycol Glycerols, such as glycols, glycerol, diglycerol, and polyglycerol, plant extracts, such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, and a rose, are mentioned.

Examples of the ultraviolet absorber include ultraviolet absorbers such as benzophenone, PABA, and salicylic acid, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, and the like. For example, protein, mucopolysaccharide, collagen, elastin, keratin, etc. are mentioned, As an antioxidant, for example, alpha-tocopherol, ascorbic acid, etc. are mentioned, As a cosmetic ingredient, for example, vitamins , an anti-inflammatory agent, a crude drug, and the like, and examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol, 1,2 pentadiol, and the like.

Although it does not specifically limit as a shape of the 1st composition and 2nd composition of this invention, A solid shape, a semi-solid shape, and a liquid thing are mentioned, The spread at the time of use is smooth, and the effect of this invention is exhibited remarkably. A liquid or semi-solid shape is preferable from a point, and a liquid thing is especially preferable. Although the dosage form of the 1st composition and 2nd composition of this invention is not specifically limited, The oily or water-in-oil type which makes an oil phase a continuous phase from the point of usability and cosmetic durability, etc. is preferable. Since the effect of this invention can be exhibited remarkably, it is more preferable that it is a planetary type whose water content is 1 % or less. Moreover, although the shape and formulation of a 1st composition and a 2nd composition may be the same or different, it is preferable at the point which the effect of this invention is easy to exhibit.

Although the manufacturing method of the 1st composition and 2nd composition of this invention is not specifically limited, For example, in a 1st composition, after heating and mixing components (A) to (D) and an optional oily component, any powder or The aqueous component and the like are uniformly mixed and dispersed, and this can be filled in a container, and in the second composition, for example, after mixing and dispersing the component (E) and the optional oily component, the optional powder or the aqueous component is uniformly mixed It can be obtained by heating and mixing, pouring this into a container or mold after heating and dissolving it, filling it, and cooling it.

As a cosmetic set comprising the first composition and the second composition of the present invention, it is suitable for use as a lip cosmetic set such as rouge, lip gloss, lip treatment, lip cream, lip base for background, and lip rouge overcoat. . As a usage method, the method of applying a 2nd composition after applying a 1st composition to application parts, such as lips, is suitable, and if it is this usage method, the effect of this invention is exhibited remarkably. For example, after apply|coating a 1st composition, what is necessary is just to apply|coat a 2nd composition to the surface of a part or all of an application part repeatedly. The time interval from application of the first composition to application of the second composition is not particularly limited, and the second composition may be immediately applied after application of the first composition. In addition, the application amount of the first composition and the second composition is also not particularly limited, for example, the mass ratio of the application amount of the first composition to the application amount of the second composition in the application area is preferably about 2:1 to 1:5, , more preferably about 1:1 to 1:3.

Example

Hereinafter, the present invention will be described in detail with reference to Examples. In addition, these do not limit this invention at all.

<Example of the oil agent of the component (E) used in the second composition of Experimental Example>

Experimental Examples 1 to 12, Experimental Comparative Examples 1 to 6

For the various oil agents, a mixture of trimethylsiloxysilicic acid (corresponding to component (A)) and isododecane (corresponding to component (C)) in a mass ratio of 1:1, and an equal amount of various oil agents are mixed, 25 The following evaluation criteria evaluated whether phase separation was carried out when it left still for 60 minutes at °C. The results are shown in Table 1.

(Evaluation standard)

(Judgment): (Evaluation)

○: phase separated

x: no phase separation

* 1: SR1000 (product of Momentive Performance Materials Japan Joint Stock Company)

* 2: Isododecane (manufactured by Bayer)

＊ 3: Cosmol 43V (manufactured by Nisshin Oilio Group)

＊ 4: Cosmol 41V (manufactured by Nisshin Oilio Group)

＊ 5: S-Pace IS-1009P (manufactured by Sakamoto Yaku Hinko)

* 6: CRODAMOL GTIS (product of Croda Japan)

* 7: ACELAN SP (product of Croda Japan)

* 8: ANTARON V216 (manufactured by ISP Japan)

* 9: LIPONATE TDTM (Lipo Chemicals)

＊ 10: Cosmol 43N (manufactured by Nisshin Oilio Group)

＊ 11: TOG (manufactured by KOKYU ALCOHOL KOGYO)

* 12: Saracos 5408 (manufactured by Nisshin Oilio Group)

＊ 13: Cosmol 222 (product of Nisshin Oilio Group)

* 14: O.D.O (manufactured by Nisshin Oilio Group)

As is clear from Table 1, Experimental Examples 1 to 12 were phase-separated, whereas Comparative Experimental Examples 1 to 6 were not phase-separated and a uniform solution was obtained. In addition, although phase separation was observed in Experimental Example 1 using polyglyceryl-2 triisostearate having an emery-type isostearic acid group, comparison using triisostearic acid polyglyceryl-2 having an aldol-type isostearic acid group In Experimental Example 1, no phase separation was observed.

<Example 1 Lip Cosmetic Set (oily liquid)>

Prescription Examples 1 to 12, Comparative Prescription Examples 1 to 4

The first composition shown in Table 2 and the second composition shown in Table 3 were prepared according to the following manufacturing method. When the first composition and the second composition obtained in Tables 2 and 3 were used in combination, respectively, no color bleed, color transfer prevention effect, makeup crumbling prevention effect, and no feeling of tightness were evaluated by the following method. One result is shown in Tables 4-7, respectively.

(first composition)

* 15: BELSIL TMS 803 (manufactured by Asahi Kasei Wacker Silicone Co.)

* 16: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 17: Ester Gum HP (made by Arakawa Kagakuko)

＊ 18: KF-96H-100,000 cs (made by Shin-Etsu Chemical Co., Ltd.)

＊ 19: KF-96-1000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

* 20: KF-96A-100cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

＊ 21: AEROSIL300 (manufactured by NIPPON AEROSIL)

＊ 22: FLAMENCO RED 420C (manufactured by BASF)

(Method for preparing the first composition)

A. Components (1) to (10) are mixed and dissolved by heating.

B. (11) to (18) were added to A and uniformly mixed to obtain a first composition.

(Second composition)

* 23: CIREBELLE 108 (manufactured by CIREBELLE)

＊ 24: PARLEAM18 (NOF CORPORATION product)

(Method for preparing the second composition)

A. Components (1) to (9) are mixed and dissolved by heating.

B. (10) to (11) were added to A and uniformly mixed to obtain a second composition.

(Evaluation items)

No color bleed when in use

(Evaluation method 1: Sensory evaluation)

About each sample, the use test by 20 expert panelists was done, and the absence of smearing at the time of use was evaluated. Specifically, after applying the first composition to the lips, with respect to the absence of color bleeding when the second composition is applied on the first composition, each panel evaluates the following absolute evaluation criteria 1 to 7 to give a rating, The average value was computed from the sum total of the ratings of the panel power supply of a sample, and it judged by the following criterion.

<Absolute evaluation standard 1>

(Rating): (Rating)

6: Not spreading at all

5: Most are not spreading

4: Somewhat not spreading

3: Normal

2: It is spreading a little

1: It is spreading

0: Very spreading

<Judgment Criteria>

(Judgment): (Average of ratings)

◎: 5.0 or more and 6.0 or less

○: 3.5 or more to less than 5.0

△: 2.0 or more to less than 3.5

×: 0 or more to less than 2.0

As is clear from the results of Table 4, the Examples (shaded parts in the table) used in combination with the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition are comparative examples (other than the shaded part in the table). ), it was excellent in no smearing at the time of use.

(evaluation item)

color transfer prevention effect

(Evaluation method 2: sensory evaluation)

Each sample was tested for use by 20 expert panelists, and the color transfer prevention effect was evaluated by an expert evaluator. Specifically, after applying the first composition to the lips, and 10 seconds after the second composition is applied on the first composition, a tissue is pressed to the lips, and after the tissue is removed, the color of the first composition is applied to the lips of each panel. Visual evaluation by a professional evaluator was performed to evaluate whether there was any remaining, and the following absolute evaluation criteria 2 to 7 were evaluated to give a rating, and the average value was calculated from the sum of the ratings of all panel members of each sample, and it was determined according to the following criterion .

<Absolute evaluation standard 2>

(Rating): (Rating)

6: Very Remaining

5: Stay well

4: Some remaining

3: Normal

2: Somewhat left

1: No left

0: very little left

<Judgment Criteria>

(Judgment): (Average of the ratings)

◎: 5.0 or more and 6.0 or less

○: 3.5 or more to less than 5.0

△: 2.0 or more to less than 3.5

×: 0 or more to less than 2.0

As is clear from the results in Table 5, the Examples (shaded parts in the table) used in combination with the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition are the comparative examples (other than the shaded parts in the table). ), the color transfer prevention effect was excellent.

(evaluation item)

Anti-collapsing effect

(Evaluation method 3: sensory evaluation)

About each sample, the use test by 20 expert panelists was done, and the makeup collapse prevention effect was evaluated. Specifically, after the first composition is applied to the lips, the second composition is applied on the first composition, and then, to lead a normal life, and after 4 hours, whether the color of the first composition remains on the lips Each of the following absolute evaluation criteria 3 to 7 ratings were evaluated, and the average value was calculated from the sum of the ratings of all panel members of each sample, and it was judged according to the following criterion.

<Absolute evaluation standard 3>

(Rating): (Rating)

6: Very Remaining

5: Stay well

4: Some remaining

3: Normal

2: Somewhat left

1: No left

0: very little left

<Judgment Criteria>

(Judgment): (Average of the ratings)

◎: 5.0 or more and 6.0 or less

○: 3.5 or more to less than 5.0

△: 2.0 or more to less than 3.5

×: 0 or more to less than 2.0

As is clear from the results in Table 6, the Examples (shaded parts in the table) used in combination with the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition are the comparative examples (other than the shaded parts in the table). ), the cosmetic collapsing prevention effect was excellent.

(evaluation item)

no pulling feeling

(Evaluation method 4: sensory evaluation)

About each sample, the use test by 20 expert panelists was done, and no pulling feeling was evaluated. Specifically, after applying the first composition to the lips, after applying the second composition on the first composition, let them lead a normal life, and after 4 hours, whether they feel a pulling feeling, each panel has the following absolute evaluation criteria The evaluation was performed on a scale of 4 to 7 to give a rating, and the average value was calculated from the sum of the ratings of the panel power sources of each sample, and it was determined according to the following criterion.

<Absolute evaluation standard 4>

(Rating): (Rating)

6: I don't feel the pulling feeling very much

5: No feeling of pulling

4: I don't feel any pulling feeling

3: Normal

2: I feel some pulling

1: Feel a pulling sensation

0: I feel the pulling feeling very much

<Judgment Criteria>

(Judgment): (Average of the ratings)

◎: 5.0 or more and 6.0 or less

○: 3.5 or more to less than 5.0

△: 2.0 or more to less than 3.5

×: 0 or more to less than 2.0

As is clear from the results of Table 7, the Examples (shaded parts in the table) in which Formulation Examples 1 to 8 of the first composition and Formulation Examples 9 to 12 of the second composition were used in combination were comparative examples (other than the shaded parts in the table). ), it was excellent in no feeling of pulling.

<Example 2 Lip Cosmetic Set (oily liquid)>

Prescription Examples 13 to 24, Comparative Prescription Examples 5 to 10

The second composition shown in Table 8 was prepared according to the following manufacturing method. When each second composition was used in combination with the first composition of Formulation Example 1 shown in Table 2, no color bleed, color transfer prevention effect, makeup collapse prevention effect, and no feeling of pulling were observed in Example 1 was evaluated in the same way as The results are collectively shown in Table 8. In addition, about the formulation example 19 and the comparative formulation example 8, the effect of preventing color transfer was further evaluated by the following test method. The results are shown in FIG. 1 .

(Method for preparing the second composition)

A. Components (1) to (19) are mixed and dissolved by heating.

B. (20) was added to A and uniformly mixed to obtain a second composition.

(Test method for color transfer prevention effect)

1. On synthetic leather (PBZ13001-BK: manufactured by Komatsu Seiren Co., Ltd.), 0.1 g of the first composition is applied in a range of 2 cm × 5 cm

2. Apply 0.15 g of the second composition in the same range

3. Immediately after application of the second composition, put four overlapping tissues on the applied area, place a glass plate (56g) on it, and leave it for 15 seconds

4. Remove the tissue and visually check the color transition.

As shown in the results of Table 8, in the Experimental Example, a mixture of trimethylsiloxysilicic acid and isododecane in a mass ratio of 1:1 was mixed in equal amounts, and phase separation was performed when standing at 25° C. for 60 minutes. The second compositions of Formulation Examples 13 to 24 using the prepared oil were excellent in all items of no color bleeding, color transfer prevention effect, makeup crumbling prevention effect, and no feeling of tightness in combination with Formulation Example 1. On the other hand, the second compositions of Comparative Formulation Examples 5 to 10 using the non-phase-separated oil agent were inferior in color bleed, color transfer prevention effect, and makeup collapse prevention effect. Also, as shown in FIGS. 1 and 2 , when the second composition of Formulation Example 19 was used, color transfer remained in a small portion of the application area, whereas when Comparative Formulation Example 8 was used, almost the entire surface was A color transition was observed across the

Formulation Example 25: Lip Rouge (First Composition)

(ingredient) (%)

1. (acrylate/stearyl acrylate/dimethicone methacrylate) copolymer 35

2. Dimethylpolysiloxane*25 10

3. Dimethylpolysiloxane*18 10

4. Water-added polyisobutane*26 35

5. Talc remaining

6. Silica*21 1

7. Glass powder coated with titanium oxide*27 2

8. Red No. 202 1

9. Yellow No. 4 Aluminum Rake 1

10. Black iron oxide 0.2

11. Flavor 0.01

＊ 25: KF-96A-5000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

＊ 26: IP solvent 1620MU (manufactured by Idemitsu Kosan)

＊ 27: Meta Shine 1080RC-R (manufactured by Nippon Itagaras)

(Manufacturing method)

A. Components (1) to (4) are heated and mixed and dissolved uniformly.

B. Add components (5) to (11) to A, and mix evenly.

C. B was filled in a container to obtain lip rouge.

Formulation Example 26: Lip Rouge (First Composition)

(ingredient) (%)

1. (acrylate/dimethicone) copolymer*16 45

2. Dimethylpolysiloxane*28 5

3. Dimethylpolysiloxane*18 3

4. Water-added polyisobutane*26 40

5. Remaining amount of boron nitride

6. Silica*21 1

7. Red No. 202 1

8. Yellow No. 4 Aluminum Rake 1

9. Black iron oxide 0.2

10. Flavor 0.01

* 28: KF-96H-50 thousand cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. Components (1) to (4) are heated and mixed and dissolved uniformly.

B. Add components (5) to (10) to A, and mix evenly.

C. B was filled in a container to obtain lip rouge.

Formulation Example 27: Lip Gloss (Second Composition)

(ingredient) (%)

1. Fisher Troughshoe Wax 2

2. Palmitic Dextrin 5

3. (vinylpyrrolidone/hexadecene) copolymer*8 10

4. Diisostearyl malate *13 5

5. Tetraisostearate pentaerythrityl *29 30

6. Polyisobutane 5

7. Trimellitic acid tridecyl 25

8. Trimethylpentaphenyltrisiloxane 2

9. Lauroyl glutamate di(octyldodecyl/phytosteryl/behenyl) 5

10. Decaisostearic acid polyglyceryl-10 remaining amount

11. Silica *21 1

12. Titanium oxide coated glass powder *30 2

13. Red No. 202 0.2

14. Yellow No. 4 Aluminum Rake 0.3

15. Black iron oxide 0.2

16. Ethylhexyl paramethoxycinnamate 1

17. dl-α-topherol 0.1

18. Flavor 0.01

19. Propyl paraoxybenzoate 0.1

*29: CRODAMOL PTIS-LQ-(JP) (product of Croda Japan Co., Ltd.)

* 30: Meta Shine 1080RC-R (manufactured by Nippon Itagaras Co., Ltd.)

(Manufacturing method)

A. The components (1) to (10) are heated to 110° C. and uniformly dissolved.

B. Add ingredients (11) to (19) to A and mix evenly.

C. B was filled in a container to obtain a lip gloss.

Formulation Example 28: Lip gloss (oily solid dish pouring shape, second composition)

(ingredient) (%)

1. Synthetic Wax 7

2. Lanolin Acetate 10

3. Triisostearic acid polyglyceryl-2 *3 remaining amount

4. Ethylhexyl hydroxystearate 8

5. Tetraisostearic acid polyglyceryl-2 *31 25

6. Pentaisostearate polyglyceryl *32 10

7. N-lauroyl-L-glutamic acid (phytosteryl/octyldodecyl) 5

8. Dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/behenyl)10

9. Trimethylsiloxyphenyldimethicone 5

10. Diphenylsiloxyphenyltrimethicone 1

11. (vinyl dimethicone/methicone silsesquioxane) cross polymer 2

12. Silica ＊21 3

13. Red No. 202 0.5

14. Yellow No. 4 0.03

15. Titanium Oxide 0.4

16. Black iron oxide 0.2

17. Titanium oxide-coated synthetic phlogopite ＊33 3

＊ 31: Cosmol 44V (product of Nisshin Oilio Group)

＊ 32: NIKKOL Dacaglyn 5-SV (product of Nikko Chemicals Co., Ltd.)

＊ 33: PROMINENCE SF (product of Topico Co., Ltd.)

(Manufacturing method)

A: The components (1) to (11) are dissolved by heating to 110°C.

B: Add (12) to (17) to A, and mix uniformly.

C: After defoaming B, fill a container at 90° C. to make a product.

Prescription Example 29: Prescription Example 17: Lip rouge (first composition)

(ingredient) (%)

1. Trimethylsiloxysilicic acid *1 29

2. Residual amount of isododecane

3. Dimethylpolysiloxane *18 22

4. Trimethylsiloxyphenyldimethicone *34 6

5. Dysteadymonium Hectorite 3

6. 1,3-butylene glycol 1

7. Red No. 104 1

8. Red No. 202 0.5

9. Yellow No. 5 0.5

10. Titanium Oxide 0.5

11. PEG-9 polydimethylsiloxyethyldimethicone 0.1

12. Flavor 0.01

* 34: BELSIL PDM 1000 (manufactured by Asahi Kasei Wacker)

(Manufacturing method)

A. Components (1) to (6) are heated and mixed and dissolved uniformly.

B. Add components (7) to (12) to A, and mix evenly.

C. B was filled in a container to obtain lip rouge.

Formulation Example 30: Lip Gloss (Second Composition)

(ingredient) (%)

1. Palmitic Dextrin 7

2. Glyceryl Triisostearate 50

3. Decaisostearic acid polyglyceryl-10 remaining amount

4. Dimethylsilylated Silica 2

5. 1,2-pentanediol 0.2

(Manufacturing method)

A. The components (1) to (5) are heated and uniformly dissolved.

B. A was filled in a container to obtain a lip gloss.

Formulation Example 31: Lip Rouge (First Composition)

(ingredient) (%)

1. Trimethylsiloxysilicic acid *1 15

2. Polymethylsilsesquioxane 10

3. Polypropylsilsesquioxane 3

4. Residual amount of isododecane

5. Dimethylpolysiloxane *18 15

6. Dimethiconol *35 5

7. Trimethylsiloxyphenyldimethicone *33 8

8. Dysteadymonium Hectorite 3

9. 1,3-Butylene Glycol 1

10. Red No. 226 1

11. Red No. 202 0.5

12. Yellow No. 4 0.5

13. Titanium Oxide 0.5

14. PEG-9 polydimethylsiloxyethyldimethicone 0.1

15. Flavor 0.01

＊ 35:X-21-5849 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method)

A. Components (1) to (9) are heated and mixed and dissolved uniformly.

B. Add ingredients (10) to (15) to A, and mix evenly.

C. B was filled in a container to obtain lip rouge.

Formulation Example 32: Lip gloss (oily solid dish pouring shape, second composition)

(ingredient) (%)

1. Dibutyllauroylglutamide 5

2. Dibutylethylhexanoylglutamide 2

3. Ethylhexyl hydroxystearate 40

4. Nonaisostearic acid polyglyceryl-10 remaining amount

5. Dimethylsilylated Silica 2

6. 1,2-octanediol 0.1

7. Perfluorooctyltriethoxysilane treatment

Glass powder coated with iron oxide and titanium oxide *36 0.5

8. Perfluorooctyltriethoxysilane-treated iron oxide coated glass powder *37 0.5

*36: Microglass Metashine MT1080TY (manufactured by Nippon Ita Glass) treated with 2% perfluorooctyltriethoxysilane

*37: Microglass Metashine MT1080TZ (manufactured by Nippon Ita Glass) treated with 2% perfluorooctyltriethoxysilane

(Manufacturing method)

A. The components (1) to (8) are heated and uniformly dissolved.

B. A was filled in a container to obtain a lip gloss.

Prescription Example 25 Lip Rouge and Prescription Example 27 Lip Gloss, Prescription Example 25 Lip Rouge and Prescription Example 28 Lip Gloss, Prescription Example 26 Lip Rouge and Prescription Example 27 Lip Gloss, Prescription Example 26 Lip Gloss and Prescription Example 28 Lip Gloss, Prescription Example 29 Lip Rouge and The lip cosmetic set using the combination of Prescription Example 30 lip gloss, Prescription Example 31 lip rouge and Prescription Example 32 lip gloss and Prescription Example does not cause color bleed during use, has an excellent color transfer prevention effect, and is There was no feeling, and the makeup crumbling over time did not occur.

Claims (10)

A cosmetic set comprising a first composition and a second composition, comprising:
A cosmetic set in which the second composition is applied after the first composition is applied to the application part, and wherein the first composition and the second composition each contain the following components:
(first composition)
(A) Film-forming silicone resin
(B) silicone oil having a kinematic viscosity of 1000 to 1000000cs at 25°C
(C) volatile hydrocarbon oils
(D) colored pigment
(Second composition)
(E) nonaisostearic acid polyglyceryl-10, decaisostearic acid polyglyceryl-10, tetraisostearic acid pentaerythrityl, hydroxystearic acid ester, lanolin derivative, trimellitic acid ester, paramethoxycinnamic acid One or two or more emulsions selected from esters and vinylpyrrolidone-based copolymers. A cosmetic set comprising a first composition and a second composition, comprising:
A cosmetic set in which the second composition is applied after the first composition is applied to the application part, and wherein the first composition and the second composition each contain the following components:
(first composition)
(A) Film-forming silicone resin
(B) silicone oil having a kinematic viscosity of 1000 to 1000000cs at 25°C
(C) volatile hydrocarbon oils
(D) colored pigment
(Second composition)
(E) One or two or more emulsions selected from tetraisostearic acid pentaerythrityl, hydroxystearic acid esters, lanolin derivatives, trimellitic acid esters, paramethoxycinnamic acid esters, and vinylpyrrolidone-based copolymers. 3. The component (A) according to claim 1 or 2, wherein the component (A) is trimethylsiloxysilicic acid, polymethylsilsesquioxane, (acrylate/dimethicone) copolymer, (acrylate/stearyl acrylate/methacrylic acid) Sandimethicone) One or two or more selected from copolymers, a cosmetic set. The cosmetic set according to claim 1 or 2, wherein the content of the component (E) in the second composition is 50 to 99.9 mass%. The cosmetic set according to claim 1 or 2, wherein the content of the component (E) in the second composition is 70 to 99.9 mass%. The content of the component (A) in the first composition is 10 to 50 mass%, the content of the component (B) is 1 to 50 mass%, and the content of the component (C) in the first composition according to claim 1 or 2 The cosmetic set which is this 20-85 mass %. The cosmetic set according to claim 1 or 2, wherein the component (B) is a silicone oil having a kinematic viscosity at 25°C of 10000 to 1000000cs. The method according to claim 1, wherein the component (E) is polyglyceryl-10 nonaisostearate, polyglyceryl-10 decaisostearate, pentaerythrityl tetraisostearate, ethylhexyl hydroxystearate, lanolin acetate , Trimellitic acid tritridecyl, para-methoxycinnamic acid ethylhexyl, and (vinylpyrrolidone/hexadecene) copolymer, which is one or more oil agents selected from the group consisting of, a cosmetic set. 3. The method according to claim 2, wherein said component (E) is pentaerythrityl tetraisostearate, ethylhexyl hydroxystearate, lanolin acetate, tritridecyl trimellitic acid, ethylhexyl paramethoxycinnamate and (vinylpyrrolidone) A cosmetic set, which is one or more oil agents selected from /hexadecene) copolymer. The cosmetic set according to claim 1 or 2, wherein the cosmetic set is a lip cosmetic set.

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