TWI729105B - Makeup kit - Google Patents

Abstract

The present invention provides a cosmetic material cover that does not smudge in color or stains to food utensils during use, has an excellent effect of preventing color contamination, and has no tightness after use, and does not fall off after a long period of makeup. The group is the subject.

The cosmetic set of the present invention to solve this problem is a cosmetic set containing a first composition and a second composition. After the first composition is applied to the application site, the second composition is applied thereon, and , The first composition and the second composition are characterized by each containing the following components.

(First composition)

(A) Film-forming silicone resin

(B) Polysiloxane oil with a dynamic viscosity of 1000~1000000cs at 25℃

(C) Volatile hydrocarbon oil

(D) Coloring pigment

(Second composition)

After mixing the same amount with the mixture of the aforementioned component (A) and the aforementioned component (C) mixed with a mass ratio of 1:1, let it stand at 25°C for 60 minutes to produce phase separation, component (E) oil agent.

Description

Makeup kit

The present invention relates to a cosmetic set containing a first composition and a second composition. The present invention relates to a cosmetic set in which the first composition is applied to the application site and the second composition is applied thereon.

In recent years, in the field of cosmetics such as lipsticks and foundations, time-dependent take-off and staining of cosmetics on containers and clothes have become a major issue. Especially for lipstick, the problem that the lipstick applied to the lips is stained with coffee cups and other food utensils, as well as the time-dependent makeup removal due to the physical folding of the lips, are all problems, and various reviews have been conducted.

For example, to provide a technology to prevent color staining and make-up prevention, it has been proposed to use a first composition containing 3000 to 1000000 relative mass of polyisobutylene and volatile hydrocarbon oil, and then use it on top of 25℃. The technology of the second composition of methylphenyl polysiloxane with a dynamic viscosity of 1000 cs to 7000 cs (Patent Document 1). However, by coating the aforementioned second composition on the polyisobutylene, which is a hydrocarbon resin, prevents the volatilization of the volatile hydrocarbon oil in the first composition, and it takes a lot of time to prevent makeup loss, and sometimes even color bleeding occurs. . In addition, in order to further improve the effect of preventing makeup over time, the first composition has a relative quality of 3000~1000000. When the content of polyisobutylene is high, sometimes it may cause tightness.

[Prior Technical Literature] [Patent Literature]

[Patent Document 1] Patent No. 5719315

Therefore, using the prior art, it is hoped that the color will not be smudged during use, and the color will not be stained to the food utensils. It has an excellent effect of preventing color staining, and then there is no tightness after use, and it will not be worn for a long time. It is really difficult for the makeup kit to fall off.

In view of the above-mentioned issues, the team of the present invention has conducted intensive research and found that it is mixed with a mixture of component (A) film-forming polysiloxane resin and component (C) volatile hydrocarbon oil mixed with a mass ratio of 1:1. , Let stand for 60 minutes at 25℃, can produce phase separation, component (E) oil agent, by applying this technology to cosmetics, it is found that the color will not bloom when used, and it has an excellent effect of preventing color contamination. Makeup kits. Furthermore, by making the component (B) contain silicone oil with a dynamic viscosity of 1000 cs or more at 25°C, a cosmetic film without tightness can be formed, and the makeup will not fall off after a long period of time, thus completing the present invention.

That is, the present invention is as follows.

[1] A cosmetic kit containing the first composition and the second group In the finished cosmetics set, the first composition is applied to the application part, and then the second composition is applied on it, and the first composition and the second composition contain the following components, respectively:

(First composition)

(A) Film-forming silicone resin

(B) Polysiloxane oil with a dynamic viscosity of 1000~1000000cs at 25℃

(C) Volatile hydrocarbon oil

(D) Coloring pigment

(Second composition)

After mixing the same amount with the mixture of the component (A) and the component (C) mixed with a mass ratio of 1:1, the phase separation will occur when the mixture is allowed to stand at 25°C for 60 minutes, and the component (E) oil agent.

[2] The cosmetic kit of [1], wherein the component (A) is selected from the group consisting of trimethylsilyloxysilicate, polymethylsilsesquioxane, (acrylate/polydimethylsiloxane) One type or two or more types of (oxyalkylene) copolymer and (acrylate/stearyl alcohol acrylate/polydimethylsiloxane methacrylate) copolymer.

[3] The cosmetic kit of [1] or [2], wherein the content of the component (E) in the second composition is 50 to 99.9% by mass.

[4] The cosmetic kit of any one of [1] to [3], wherein the content of the component (E) in the second composition is 70 to 99.9% by mass.

[5] A cosmetic set such as any one of [1] ~ [4], in which The content of the component (A) in the first composition is 10-50% by mass, the content of the component (B) is 1-50% by mass, and the content of the component (C) is 20-85% by mass.

[6] The cosmetic kit of any one of [1] to [5], wherein the component (B) is a silicone oil with a dynamic viscosity of 10,000 to 1,000,000 cs at 25°C.

[7] The cosmetic kit of any one of [1] to [6], wherein the component (E) is selected from isostearate, hydroxystearate, lanolin derivatives, trimellitium One or two or more oils of acid ester, p-methoxycinnamate, and vinylpyrrolidone-based copolymer.

[8] The cosmetic kit of [7], wherein the isostearate of the component (E) is an isostearate having an Emory-type isostearic acid group.

[9] The cosmetic kit of any one of [1] to [7], wherein the component (E) is selected from the group consisting of polyglycerol-2 isostearate and polyglycerol-2 triisostearate , Polyglycerol-2 tetraisostearate, polyglycerol-10 nine isostearate, polyglycerol-10 ten isostearate, pentaerythritol tetraisostearate, glyceryl three isostearate, Ethylhexyl hydroxystearate, acetylated lanolin, tritridecyl trimellitate, ethylhexyl p-methoxycinnamate, (vinylpyrrolidone/hexadecene) copolymer One or more oils.

[10] Such as the cosmetic set of any one of [1] to [9], the cosmetic set is a lip cosmetic set.

The present invention uses the first composition in combination with the second composition containing a specific oil agent, which can provide a color that does not bloom during use, has an excellent effect of preventing color contamination, and has no tightness after use. A makeup kit that won’t fall off after a long period of time.

[Figure 1] It is a photograph of color staining confirmed in Example 2, when the first composition of Formulation Example 1, the second composition of Formulation Example 19, or the second composition of Comparative Formulation Example 8 were used in combination.

Hereinafter, the present invention will be described in detail. And the range of "~" in the manual means the value before and after the value is included.

The component (A) film-forming polysiloxane resin used in the first composition of the present invention is a compound with a silicone structure as the main skeleton and a bridge structure, which is soluble in the polysiloxane oil of component (B) In oil agents such as component (C) volatile hydrocarbon oil, if it is used in cosmetics, it can be used without particular restrictions. The film-forming property here means that a solution obtained by dissolving silicone resin in component (C) volatile hydrocarbon oil, spreading it on a petri dish and drying it, has the property of forming a film. In addition, the obtained film may be in the form of cracks caused by drying, or may be in the form of a single film.

For example, trimethylsilyloxysilicate, polymethylsilsesquioxane, (acrylate/polydimethylsiloxane) copolymer, (Acrylate/stearyl alcohol acrylate/polydimethylsiloxane methacrylate) copolymer, one or more of these can be used.

Commercial products include X-21-5616 (60% solid isododecane solution), X-21-5595 (solid 60% isododecane solution), KF-7312J (solid 50% isododecane Base ring pentasiloxane solution), KF-9021 (50% decamethyl cyclopentasiloxane solution), KP-545 (solid content 30% decamethyl cyclopentasiloxane solution), KP-549 (solid 40% methyl trimethylsiloxane solution), KP-550 (50% solid isododecane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.), BELSIL TMS 803, BELSIL PMS MK Powder (Asahi Kasei Aws-Silicone Co., Ltd.), SR1000, SilForm Flexible resin, SS4267 (35% dimethyl polysiloxane solution) (manufactured by Momentive Performance Materials Japan joint company), BY11-018 (30% decamethylcyclopentasiloxane) Alkane solution) (manufactured by Dow Corning Toray Silicone Co., Ltd.), etc., one kind or two or more kinds of these can be used.

The content of the component (A) film-forming polysiloxane resin in the first composition of the present invention is not particularly limited. It is preferably 10-50% by mass (hereinafter referred to as "%"), and more preferably 15-35% Good, 15~30% is best. When it is set to this range, it is more preferable because it can obtain a cosmetic film which does not have a tight feeling, and has an excellent makeup prevention effect, etc., and the like.

The component (B) used in the first composition of the present invention has a polysiloxane oil with a dynamic viscosity of 1000 to 1,000,000 cs at 25°C. It is a polysiloxane oil with fluidity at 1 atmosphere and 25°C. If it is two Methyl polysiloxane, methyl hydrogen polysiloxane, phenyl modified polysiloxane, alkyl modified polysiloxane There are no particular restrictions on ingredients used in cosmetics, etc., and one or two or more of these can be used. In addition, the dynamic viscosity of component (B) at 25°C is preferably 1000~1000000cs, more preferably 10000~1000000cs, and 10000~100000cs is the best. When it is set in this range, it is more preferable that it is possible to suppress the tightness caused by the silicone resin, and to obtain a cosmetic film having an excellent effect of preventing makeup from falling off. On the other hand, silicone oil with a dynamic viscosity of less than 1000 cs at 25°C can sometimes fail to achieve satisfactory color blooming prevention and makeup prevention effects, while silicone oil with a dynamic viscosity of more than 1,000,000 cs at 25° C. It will slow down the volatilization speed of component (C), and sometimes fail to obtain a satisfactory effect of preventing color blooming.

Commercially available products include KF-96-1000cs/3000cs/5000cs, KF-96H-6000cs/110,000cs/12500cs/30000cs/50,000cs/60000cs/100000cs/300,000cs/500,000 cs/1 million cs, KF-50-1000cs (the above are all made by Shin-Etsu Chemical Co., Ltd.), SH-200 C Fluid 1000CS/3000CS/5000CS/10000CS/12500CS/30000CS/60000CS/100000CS/1000000CS, BY11- 040/003/007/014/026/320 (all made by Dow Corning Toray) and the like. One type can be used alone, or two or more types can be combined to adjust to an appropriate and prescribed dynamic viscosity. In addition, the dynamic viscosity in the present invention is a value measured at 25°C using the ASTM D445 measurement method.

The content of the component (B) in the first composition of the present invention is not particularly limited, and is preferably 1-50%, more preferably 3-35%, and most preferably 5-30%. When it is set in this range, it is more preferable that it is possible to suppress the tightness caused by the silicone resin, and to obtain a cosmetic film having an excellent effect of preventing makeup from falling off.

The component (C) used in the first composition of the present invention is volatile Hydrocarbon oil is liquid at 1 atm and 25°C, has volatility, has a boiling point range of 68 to 260°C, and includes hydrocarbons with 6 to 30 carbon atoms. Generally speaking, there are no particular restrictions if it is a component used as a cosmetic raw material. Specific examples include linear hydrocarbons such as n-heptane, and isooctane (2,2,4-trimethylpentane, 2,3- Dimethylhexane, etc.), isododecane (2,2,4,6,6-pentamethylheptane, etc.), isohexadecane, isoeicosane and other side-chain hydrocarbons, or these After polymerization or copolymerization of isobutylene, n-butene, etc. (polymerization degree is preferably 4~6), the hydrogenated mixture can be used in combination of 1 or 2 or more according to needs. Commercially available products include Isopa-H (manufactured by Esso Chemical), isododecane (manufactured by Bayer), isohexadecane (manufactured by Uniqema), IP solvent 1620 MU, IP solvent 2028 MU, IP solvent 2835 (The above is made by Idemitsu Kosan Co.) etc. One or two or more of these can be used.

The content of the component (C) volatile hydrocarbon oil in the first composition of the present invention is not particularly limited. It is preferably 20-85%, more preferably 25-80%, and most preferably 30-70%. When it is set in this range, there is no tightness, and there is no color blooming during use, which is better. In addition, the mass ratio of the contained component (A) and component (C) is not particularly limited, and there will be no excellent points such as color smearing from use, (A): (C)=3:1~1:6 Better, 2:1~1:5 is better, 1:1~1:4 is best.

The component (D) colorant used in the first composition of the present invention, if it is a coloring agent commonly used in cosmetics, it can be spherical, plate-shaped, spindle-shaped, needle-shaped, etc., as well as smoke, fine particles, and pigments. There are no special restrictions on particle diameters such as grades or porous and non-porous particle structures. Inorganic colored pigments, organic colored pigments, dyes, bright pigments, metals Wait. Specific powders can include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, chromium oxide, chromium hydroxide, iron blue, ultramarine blue, iron oxide, and other colored inorganic pigments, titanium coated mica , Bismuth oxychloride, organic pigment-treated titanium coated mica, titanium dioxide coated mica, titanium dioxide coated synthetic phlogopite, titanium dioxide coated bismuth oxychloride, iron oxide titanium coated mica, iron blue treated titanium coated mica, carmine treated titanium coated mica, Fish scale foil, titanium dioxide coated glass powder, polyethylene terephthalate. aluminum. Epoxy resin laminated powder, polyethylene terephthalate. Polyolefin laminated film powder, polyethylene terephthalate. Bright pigments such as polymethyl methacrylate laminated film powder and resin laminated powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404 , Organic pigment powder such as yellow 401, red No. 3, red No. 104, red No. 106, orange No. 205, yellow No. 4, yellow No. 5, green No. 3, blue No. 1 zirconium, barium or aluminum powder, etc. Organic pigment powder, or even metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium dioxide coated titanium mica, fine particle zinc oxide coated titanium mica, barium sulfate coated titanium mica, silicon dioxide containing titanium oxide, and zinc oxide containing Compound powders such as silicon dioxide, etc., can be used in combination of one type or two or more according to needs. Moreover, these substances can also be used fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, synthetic waxes, beeswax, interfacial activity One or two or more surface treatment agents, etc.

The content of the component (D) colorant in the first composition of the present invention is not particularly limited, but 0.0001 to 30% is preferred, and 0.001 to 20% Better.

In addition to the above-mentioned components (A) to (D), the first composition of the present invention may suitably contain components used in general cosmetics, such as components other than component (D), within a range that does not hinder the effects of the present invention. Powders, oils other than ingredients (B) and (C), surfactants, monohydric alcohols, polyhydric alcohols, water-soluble polymers, para-hydroxybenzoic acid derivatives, phenoxyethanol and other preservatives, ultraviolet absorbers , Humectants, antibacterial agents, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin-beautifying ingredients (whitening agents, cell activators, skin roughening agents, blood flow promoting agents , Astringent skin agents, anti-lipid leakage agents, etc.), vitamins, amino acids, nucleic acids, hormones, crystal cage compounds, etc.

The oils are, for example, derived from animal oils, vegetable oils, synthetic oils, etc., and are not limited to properties such as solid oils, semi-solid oils, and liquid oils. Examples include hydrocarbons, greases, waxes, hardened oils, ester oils, and fatty acids. Types, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils, etc. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin, ozokerite, microcrystalline wax, ethylene propylene copolymer, montan wax, Fischer-Tropsch synthetic wax, wood wax, olive oil, castor oil, Mink oil, macadamia oil and other fats, beeswax, carnauba wax, candalis wax, spermaceti and other waxes, jojoba oil, cetyl isooctanoate titanate, isopropyl myristate, palmitic acid Isopropyl ester, octyldodecyl myristate, tricaprylin, diisostearate diglyceride, diglyceride triglyceride, tribehenate, malate diisostearate, new Pentylene glycol dicaprylate, cholesterol fatty acid ester, N-lauryl-L- Glutamate di (cholesteryl behenyl octyl dodecyl) and other esters, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methyl phenyl Polysiloxanes, fluorine-modified organopolysiloxanes and other polysiloxanes, perfluorodecane, perfluorooctane, perfluoropolyether and other fluorine-based oils, lanolin, lanolin acetate, wool Fatty acid isopropyl ester, lanolin derivatives such as lanolin alcohol, dextrin caprylate, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate Acid ester, dextrin, coconut oil fatty acid ester, dextrin (palmitic acid/caprylic acid) ester, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearate, potassium stearate and other oily gelling agents , Pentaerythritol hydrogenated rosinate, specific acrylate alkyl methyl polysiloxane ester and other oil-soluble resins, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyl polytrimethylsiloxane One type or two or more types of polysiloxane-based volatile oil agents such as low alkane and low polymerization degree dimethylpolysiloxane can be used.

Among the oil agents other than the above-mentioned components (B) and (C), the oil agent that is liquid at 25°C is not particularly limited to the content of the equivalent oil agent in the first composition of the present invention, but it is used in the following When it is above the second composition, 0-10% is preferred, and 0~5% is more preferred from the viewpoint of not easily causing color blooming.

Used in the second composition of the present invention, a mixture of component (A) and component (C) mixed at a mass ratio of 1:1, mixed in equal amounts, and left to stand at 25°C for 60 minutes, a phase-separated component ( E) The oil agent, if it can be used in cosmetics, there are no special restrictions, and it can be used.

Component (E) oil agent that can be used in the second composition of the present invention There are no particular limitations on one of the examples. Examples include polyglyceryl-2 isostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, and polyglyceryl-10 non-isostearate. Isostearates such as stearate, polyglycerol-10 decaisostearate, pentaerythritol tetraisostearate, glycerol triisostearate and other isostearates, hydroxystearate such as ethylhexyl hydroxystearate Acid ester, lanolin, acetylated lanolin, lanolin fatty acid isopropyl ester, lanolin derivatives such as lanolin, tritridecyl trimellitate, trioctyl trimellitate and other trimellitides Ester, p-methoxycinnamate such as ethylhexyl p-methoxycinnamate, vinylpyrrolidone-based copolymers such as (vinylpyrrolidone/hexadecene) copolymer, etc., one or two of these can be combined Used above. Among them, after mixing the same amount with the mixture of component (A) and component (C) mixed with a mass ratio of 1:1, then let it stand at 25°C for 60 minutes, the ease of phase separation and the prevention of color based on this From the viewpoint of blooming effect, it is selected from polyglycerol-2 isostearate, polyglycerol-2 triisostearate, polyglycerol-2 tetraisostearate, and polyglycerol-10 non-isostearate. Acid ester, polyglycerol-10 deca isostearate, pentaerythritol tetraisostearate, glycerol triisostearate, ethylhexyl hydroxystearate, acetylated lanolin, tritridecane Alcohol trimellitate, ethylhexyl p-methoxycinnamate, (vinylpyrrolidone/hexadecene) copolymer is preferably one or two or more types, and use is selected from polyglycerol-2 isostearic acid Ester, polyglycerol-2 triisostearate, polyglycerol-2 tetraisostearate, polyglyceryl-10 non-isostearate, polyglycerol-10 decaisostearate, pentaerythritol tetraisostearate One or more of fatty acid esters, glyceryl triisostearate, acetylated lanolin, tritridecyl trimellitate, (vinylpyrrolidone/hexadecene) copolymer, preferably .

In addition, in the above-mentioned isostearic acid ester, isostearic acid is a branched stearic acid of one type or a mixture of two or more types. For example, 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl)-octanoate can use the carboxylation reaction of isobutylene dimer to form a branched aldehyde with 9 carbon atoms. Then, the branched unsaturated aldehyde with 18 carbon atoms is obtained by condensation of aldehydes and aldol, which can be manufactured by hydrogenation and oxidation (hereinafter abbreviated as "aldol condensation type"). For example, Nissan Chemical Industry Co., Ltd. Sold in the market. 2-Heptylundecanoic acid, which can use Guerbet reaction to form dimers of nonanol, and then produce dimers by oxidation reaction. For example, Mitsubishi Chemical Corporation has a commercially available product with similar mixtures with several different branch positions. There are commercially available products from Nissan Chemical Industry Co., and the starting alcohol is not linear and saturated and has two methyl branched forms. There are also commercially available products from Nissan Chemical Industry Co. (hereinafter referred to as "Gebel reaction type" in general). "). In addition, methyl-branched isostearic acid can be obtained from, for example, by-products in the production of oleic acid dimers [for example, described in J. Amer. Oil Chem. Soc., 51, 522 (1974)], for example, Commercial products produced by Emery Corporation in the United States (hereinafter referred to as "Emery Type"). The dimer acid of the Emery-type isostearic acid starting material is not only oleic acid as the starting material, but sometimes contains linoleic acid, hypolinoleic acid and the like. The present invention is not particularly limited. After mixing the same amount with the mixture of component (A) and component (C) mixed with a mass ratio of 1:1, the mixture is allowed to stand at 25°C for 60 minutes. The ease of phase separation and the This is based on the viewpoints of preventing color blooming effects, etc., isostearic acid ester having an isostearic acid group of Emery type is more preferable.

Commercially available products include COSMOL 41V, COSMOL 42V, COSMOL 43V, COSMOL 44V (manufactured by Nisshin Oil Group Co., Ltd.), ANTARON V-216 (manufactured by ISP), LIPONATE TDTM (manufactured by Lipo Chemicals), purified lanolin (Nippon Purification Co., Ltd.), ACELAN SP, CRODAMOL GTIS- LQ-(JP), CRODAMOL PTIS-LQ-(JP) (All above are Croda Japan Co., Ltd.), NIKKOL Decaglyn 10-ISV (Nikko Chemical Co., Ltd.), S FACE IS-1009P (Sakamoto Pharmaceutical Co., Ltd.), etc. Use one or more of these.

The content of the component (E) in the second composition of the present invention is not particularly limited, and is preferably 50 to 99.9%, and more preferably 70 to 99.9%. In this range, by combining with the first composition, the first composition can improve the color stain prevention effect of the first composition, will not stain coffee cups, etc., will not have time-dependent makeup removal, and can obtain long-lasting makeup. It is preferable from the viewpoint of a cosmetic film with excellent makeup properties.

In addition to component (E), the second composition of the present invention may contain oily components, oil gelling agents, powders, and surface treatments, surfactants, and water-based products within the range that does not hinder the effects of the present invention. Ingredients, UV absorbers, moisturizers, antioxidants, beauty ingredients, preservatives, pigments, fragrances, and other ingredients contained in general cosmetics.

The oily ingredients are not limited to those generally used in cosmetics and solid oils derived from animal oils, vegetable oils, synthetic oils, semi-solid oils, liquid oils, and volatile oils, except for ingredient (E). Examples include hydrocarbons, Greases, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, oily gelling agents, etc. Specifically, waxes such as beeswax, spermaceti wax, Fischer-Tropsch wax, and Candelis wax can be cited. Fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol Fluorinated oils such as higher alcohols, perfluorodecane, perfluorooctane, perfluoropolyether, dextrin caprylate, dextrin laurate, dextrin palmitate, dextrin myristate, paste Refined stearate, dextrin behenate, dextrin coconut oil fatty acid ester, dextrin (palmitic acid/caprylic acid) ester, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate, stearic acid For oily gelling agents such as potassium and 12-hydroxystearate, one or two or more of these can be used.

The powder can be used in shapes such as spheres, plates, spindles, needles, etc., and particle diameters such as smoke, fine particles, and pigment grades, or particle structures such as porous and non-porous. It is not particularly limited, and examples include Inorganic powder, organic powder, pigment powder, composite powder, etc. Specific coloring agents can be exemplified by titanium oxide, zinc oxide, black titanium oxide, iron blue, ultramarine, iron oxide, iron hydroxide, black iron oxide, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, barium sulfate, Chromium oxide, chromium hydroxide, carbon black, coal tar pigments, etc., touch modifiers include silicon oxide, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, synthetic sericite, sericite , Talc, silicon carbide, boron nitride, nylon powder, polymethyl methacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystal fiber Sulfate, N-Amino acid, urethane powder, etc. In addition, pearlescent pigments include bismuth oxychloride, titanium coated mica, iron oxide coated mica, iron oxide titanium coated mica, organic pigment titanium coated mica, aluminum powder, etc., ultraviolet light The masking agent may include composite powders such as particulate titanium oxide, particulate zinc oxide, cerium oxide, particulate titanium oxide titanium coated mica, particulate zinc oxide titanium coated mica, and barium sulfate titanium coated mica. One or two of these can be used. More than species. In addition, in order to improve the dispersibility and adhesion of the powders, surface treatments such as silicones, fluorine compounds, metal soaps, oils, and other surface treatment agents can be used for surface treatment by a generally known method.

As the surfactant, any surfactant generally used in cosmetics can be used, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. For example, glycerol fatty acid esters and alkyl alcohol addenda, polyglycerol fatty acid esters and alkyl alcohol addenda, sorbitol fatty acid esters and alkyl alcohol addenda, polyoxyethylene hardened castor oil, Polyoxyalkylene co-modified organopolysiloxane, polyether modified organopolysiloxane, lecithin, etc.

In addition to water, water-based components include alcohols such as ethanol, propanol, 1,3-butanediol, 1,2-pentanediol, dipropylene glycol, polyethylene glycol, and other alcohols, glycerin, diglycerin, Glycerin such as polyglycerin, aloe vera, North American witch hazel, witch hazel, cucumber, lemon, lavender, rose and other plant extracts.

Examples of the ultraviolet absorber include ultraviolet absorbers such as benzophenone, PABA-based, and salicylic acid-based, 4-tert-butyl-4'-methoxyoxybenzone, benzophenone, and the like. Moisturizers include, for example, protein, mucopolysaccharide, collagen, elastin, keratin, etc., antioxidants include α-tocopherol, ascorbic acid, etc., and beauty ingredients include vitamins, anti-inflammatory agents, crude drugs, etc., antiseptic The agent can include, for example, parabens, phenoxy Ethanol, 1,2-pentanediol, etc.

The shapes of the first composition and the second composition of the present invention are not particularly limited. Examples include solid, semi-solid, and liquid forms. They can be easily extended from the time of use, and the effect of the present invention is significantly exhibited. Liquid or semi-solid form is preferred, and liquid form is particularly preferred. The dosage forms of the first composition and the second composition of the present invention are not particularly limited. From the viewpoints of usability and makeup retention, an oily or water-in-oil type with an oil phase as the subsequent phase is preferred. From the viewpoint that the effect of the present invention can be significantly exhibited, an oily type with a water content of 1% or less is more preferable. In addition, the shapes and dosage forms of the first composition and the second composition may be the same or different. From the viewpoint that the effects of the present invention can be easily exhibited, the same kind is preferred.

The manufacturing method of the first composition and the second composition of the present invention is not particularly limited. For example, when heating and mixing the first composition components (A) to (D) and any oily components, they can be combined with any powder and water-based components. It can be obtained by uniformly dispersing and mixing, and then filling it in a container. For the second composition, for example, when dispersing and mixing component (E) and optional oily components, it is uniformly heated and mixed with optional powders and water-based components, and then heated to dissolve. Then, it is filled into a container or mold, and the finished product can be obtained after cooling.

The cosmetic set containing the first composition and the second composition of the present invention is suitable for use as a lip cosmetic set such as lipstick, lip gloss, lip balm, lip cream, isolation lipstick, and transparent lip gloss. The method of use is preferably to use the first composition on the lips and other coated parts, and then use the second composition on it. This method of use can significantly exert the effects of the present invention. For example, after the first composition is applied, it is preferable to overlap the second composition on a part or all of the surface of the part to be applied. After the first composition is applied to the second composition The time interval is not particularly limited, and the second composition may be applied immediately after the first composition is applied. In addition, the usage amount of the first composition and the second composition is not particularly limited. For example, the mass ratio of the usage amount of the first composition to the usage amount of the second composition in the coating field is about 2:1~1:5. Good, about 1:1~1:3 is better.

[Example]

The following examples illustrate the present invention in more detail, but the present invention is not limited in any way.

<Experimental example An example of the oil agent used in the second composition component (E)> Experimental examples 1~12, experimental comparative examples 1~6

For various oils, a mixture of trimethylsilyloxysilicate (equivalent to component (A)) and isododecane (equivalent to component (C)) at a mass ratio of 1:1, and the same amount After mixing the various oils and leaving it at 25°C for 60 minutes, evaluate whether phase separation occurs according to the following evaluation criteria. The results are shown in Table 1.

(evaluation standard)

(Judgment): (Evaluation)

○: Phase separation occurs

×: no phase separation occurred

*1: SR1000 (manufactured by Momentive Performance Materials Japan Co., Ltd.)

*2: Isododecane (manufactured by Bayer)

*3: COSMOL 43V (Nissin Oils & Oils Group Co., Ltd.)

*4: COSMOL 41V (Nissin Oils & Oils Group Co., Ltd.)

*5: S-FACE IS-1009P (manufactured by Sakamoto Pharmaceutical Co., Ltd.)

*6: CRODAMOL GTIS (manufactured by Croda Japan)

*7: ACELAN SP (manufactured by Croda Japan)

*8: ANTARON V216 (manufactured by ISP Japan)

*9: LIPONATE TDTM (manufactured by Lipo Chemicals)

*10: COSMOL 43N (Nissin Oils & Oils Group Co., Ltd.)

*11: TOG (manufactured by Advanced Alcohol Industry Co., Ltd.)

*12: SALACOS 5408 (Nissin Oils & Oils Group Co., Ltd.)

*13: COSMOL 222 (Nissin Oils & Oils Group Co., Ltd.)

*14: O.D.O (Nissin Oils & Oils Group Co., Ltd.)

It can be clearly seen from Table 1 that, compared to Experimental Examples 1 to 12 where phase separation occurred, Comparative Experimental Examples 1 to 6 did not undergo phase separation and were homogeneous solutions. In addition, use polyglycerol-2 triisopropyl with Emory-type isostearic acid group In Experimental Example 1 of stearate, phase separation was found, while in Comparative Experimental Example 1 using polyglycerol-2 triisostearate having an aldol type isostearic acid group, no phase separation was found.

<Example 1 Lip cosmetic set (oily liquid)> Formulation examples 1~12, comparative formulation examples 1~4

The first composition shown in Table 2 and the second composition shown in Table 3 were prepared according to the following manufacturing method. When the first composition and the second composition obtained in Table 2 and Table 3 are used in combination, the following methods are used to evaluate the absence of color smearing, the effect of preventing color staining, the effect of preventing makeup, and the feeling of tightness. , And the results are shown in Tables 4 to 7 respectively.

(First composition)

*15: BELSIL TMS 803 (manufactured by Asahi Kasei Aws-Silicone)

* 16: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)

*17: ESTER GUM HP (manufactured by Arakawa Chemical Industry Co., Ltd.)

*18: KF-96H-100,000 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

*19: KF-96-1000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

*20: KF-96A-100cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

*21: AEROSIL300 (manufactured by NIPPON AEROSIL)

*22: FLAMENCO RED 420C (made by BASF)

(Method of manufacturing the first composition)

A. Mix and heat to dissolve the ingredients (1)~(10).

B. Add (11) to (18) to A and mix uniformly to obtain the first composition.

(Second composition)

*23: CIREBELLE 108 (manufactured by CIREBELLE)

*24: PARLEAM 18 (manufactured by NOF Corporation)

(Method of manufacturing the second composition)

A. Mix and heat to dissolve the ingredients (1)~(9).

B. Add (10) to (11) to A and mix uniformly to obtain the second composition.

(Evaluation item)

The degree of color without blooming during use

(Evaluation method 1: Sensory evaluation)

For each sample, 20 professional evaluators were used to conduct a use test to evaluate the degree of color blooming during use. Specifically, apply the first After the composition was formed, each evaluator used the following absolute evaluation standard 1 to evaluate and rate the color at the time when the second composition was applied to the first composition in seven stages. All the evaluators of each sample The average value is calculated by summing up the points, and then judged by the following judgment standards.

<Absolute Evaluation Criteria 1>

(Comment): (evaluation)

6: No blooming at all

5: Almost no blooming

4: Slightly no blooming

3: Normal

2: A little smudge

1: There is blooming

0: Smearing is very serious

<Judgment Criteria>

(Judgment): (Average point of comments)

◎: Above 5.0 ~ below 6.0

○: 3.5 or more ~ less than 5.0

△: More than 2.0 ~ less than 3.5

×: above 0 ~ less than 2.0

From the results in Table 4, it is clear that the combination of the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition (the part with the shadow in the table), and the comparative example ( Compared with the parts other than the shadows in the table), it is the one with a better degree of no color blooming during use.

(Evaluation item)

Prevent color staining effect

(Evaluation method 2: Sensory evaluation)

For each sample, 20 specialized evaluators were used to conduct a use test, and the specialized evaluators evaluated the effect of preventing color contamination. Specifically, after the first composition is applied to the lips, the second composition is applied to the first composition for 10 seconds, and then the lips are pressed with a tissue paper. Whether the color of the first composition remains on the lips of the evaluator, and according to the following absolute evaluation standard 2, it is evaluated and evaluated in 7 stages. The average value is calculated from the total evaluation points of all the sample evaluators, and then the following judgment standard is used determination.

<Absolute Evaluation Criteria 2>

(Comment): (evaluation)

6: A lot of residue

5: The residual condition is good

4: Slight residue

3: Normal

2: Only a little remains

1: No residue

0: No residue at all

<Judgment Criteria>

(Judgment): (Average point of comments)

◎: Above 5.0 ~ below 6.0

○: 3.5 or more ~ less than 5.0

△: More than 2.0 ~ less than 3.5

×: above 0 ~ less than 2.0

It is clear from the results in Table 5 that the first composition is used in combination The formulation examples 1 to 8 of the second composition and the formulation examples 9 to 12 of the second composition (the part with the shadow in the table) are compared with the comparative example (the part other than the shadow in the table), which prevents the color Those with better contamination.

(Evaluation item)

Prevent makeup effect

(Evaluation method 3: Sensory evaluation)

For each sample, 20 professional evaluators conducted a use test to evaluate the effect of preventing makeup from falling off. Specifically, after the first composition is applied to the lips, the second composition is applied to the first composition to maintain the normal life style. After 4 hours, whether the color of the first composition remains on the lips is determined. According to the following absolute evaluation standard 3, the evaluator will evaluate and rate in 7 stages, calculate the average value from the total evaluation points of all the sample evaluators, and then judge by the following criterion.

<Absolute Evaluation Criteria 3>

(Comment): (evaluation)

6: A lot of residue

5: The residual condition is good

4: Slight residue

3: Normal

2: Only a little remains

1: No residue

0: No residue at all

<Judgment Criteria>

(Judgment): (Average point of comments)

◎: Above 5.0 ~ below 6.0

○: 3.5 or more ~ less than 5.0

△: More than 2.0 ~ less than 3.5

×: above 0 ~ less than 2.0

From the results in Table 6, it is clear that the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition are used in combination (the part with shadow in the table), and the comparative example ( Compared with the parts other than the net shadow in the table), it is the one with better effect of preventing makeup from falling off.

(Evaluation item)

No tightness

(Evaluation method 4: Sensory evaluation)

For each sample, 20 professional evaluators were used to conduct a use test to evaluate the area without tightness. Specifically, after the first composition was applied to the lips, the second composition was applied to the first composition, and then the normal life pace was maintained. After 4 hours, whether there was a feeling of tightness, each reviewer based on the following Absolute evaluation standard 4, evaluated and evaluated in 7 stages, calculated the average value from the total evaluation points of all the sample evaluators, and then judged by the following judgment standards.

<Absolute Evaluation Criteria 4>

(Comment): (evaluation)

6: Can't feel very tight

5: No feeling of tightness

4: Can't feel a slight tightness

3: Normal

2: Feel a slight tightness

1: Feel tightness

0: Feel very tight

<Judgment Criteria>

(Judgment): (Average point of comments)

◎: Above 5.0 ~ below 6.0

○: 3.5 or more ~ less than 5.0

△: More than 2.0 ~ less than 3.5

×: above 0 ~ less than 2.0

It is clear from the results in Table 7 that the combination of the formulation examples 1 to 8 of the first composition and the formulation examples 9 to 12 of the second composition (the part with the shadow in the table), and the comparative example ( Compared with the parts other than the net shadows in the table), the ones with no tightness are better.

<Example 2 Lip cosmetic set (oily liquid)> Formulation examples 13~24, comparative formulation examples 5~10

The second composition shown in Table 8 was prepared according to the following manufacturing method. When the respective second composition is used in combination with the first composition of Formulation Example 1 shown in Table 2, according to the same method as in Example 1, it is evaluated that there is no color blooming, the effect of preventing color staining, and the prevention of color staining during use. Make-up effect, no tightness. The results are shown in Table 8 together. In addition, with respect to Formulation Example 19 and Comparative Formulation Example 8, the effect of preventing color contamination was evaluated according to the following experimental method. The results are shown in Figure 1.

(Method of manufacturing the second composition)

A. Mix and heat to dissolve the ingredients (1)~(19).

B. Add (20) to A and mix uniformly to obtain the second composition.

(Experimental method to prevent color contamination)

1. On synthetic leather (PBZ13001-BK: manufactured by Komatsu Refining Co., Ltd.), 0.1 g of the first composition was applied in a range of 2 cm×5 cm.

2. Coat 0.15 g of the second composition in the same range.

3. Immediately after coating the second composition, place 4 overlapping facial papers on the coating area, place a glass plate (56 g) on it, and leave it for 15 seconds.

4. Remove the bottom paper and visually confirm the degree of color staining.

As shown in Table 8, in the experimental example, a mixture of trimethylsilyloxysilicate and isododecane mixed with a ratio of 1:1 by mass was used. After mixing the amount, let it stand at 25°C for 60 minutes to produce a phase-separated oil, such as the second composition of Formulation Examples 13-24. In combination with Formulation Example 1, the color will not bloom and prevent color contamination. All items of effect, makeup prevention effect, and no tightness are superior. In contrast, the second compositions of Comparative Formulation Examples 5 to 10 in which no phase-separated oil agent was used were inferior in the degree of color smearing, color stain prevention effect, and makeup prevention effect. In addition, as shown in Fig. 1 and Fig. 2, compared with the second composition of Formulation Example 19, the color staining remained in a small part of the coating range. When Comparative Formulation Example 8 was used, it was seen that the color staining was almost comprehensive. of.

Formulation example 25: lipstick (first composition)

*25: KF-96A-5000cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

*26: IP solvent 1620 MU (manufactured by Idemitsu Kosan Co., Ltd.)

*27: METASHINE 1080RC-R (manufactured by Nippon Sheet Glass Co., Ltd.)

(Production method)

A. Heat the mixed ingredients (1)~(4) to dissolve them uniformly.

B. Add ingredients (5) to (11) to A and mix them evenly.

C. Fill the container with B to obtain lipstick.

Formulation example 26: lipstick (first composition)

*28: KF-96H-50 thousand cs (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)

A. Heat the mixed ingredients (1)~(4) to dissolve them uniformly.

B. Add ingredients (5) to (10) to A and mix them evenly.

C. Fill the container with B to obtain lipstick.

Formulation Example 27: Lip Gloss (Second Composition)

*29: CRODAMOL PTIS-LQ-(JP) (manufactured by Croda Japan Co., Ltd.)

*30: METASHINE1080RC-R (manufactured by Nippon Sheet Glass Co., Ltd.)

(Production method)

A. Heat the ingredients (1)~(10) to 110°C to dissolve them uniformly.

B. Add ingredients (11) to (19) to A and mix them evenly.

C. Fill the container with B to obtain lip gloss.

Formulation example 28: lip gloss (pour into an oily solid disc, the second composition)

*31: COSMOL 44V (manufactured by Nissin Oils and Fats Group)

*32: NIKKOL Decaglyn 5-SV (manufactured by Nikko Chemical Co., Ltd.)

* 33: PROMINENCE SF (manufactured by TOPY Industrial Co., Ltd.)

(Production method)

A. Heat the ingredients (1)~(11) to 110°C to dissolve them.

B. Add (12)~(17) to A and mix evenly.

C. After degassing B, it is filled into a container at 90°C to produce a product.

Formulation example 29: Formulation example 17: Lipstick (first composition)

*34: BELSIL PDM 1000 (manufactured by Asahi Kasei AWS)

(Production method)

A. Heat and mix the ingredients (1)~(6) to dissolve them uniformly.

B. Add ingredients (7) to (12) to A and mix them evenly.

C. Fill the container with B to obtain lipstick.

Formulation example 30: Lip gloss (second composition)

(Production method)

A. Heat the ingredients (1)~(5) to dissolve them uniformly.

B. Fill the container with A to obtain a lip gloss.

Formulation example 31: Lipstick (first composition)

*35: X-21-5849 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)

A. Heat the mixed ingredients (1)~(9) to dissolve them uniformly.

B. Add ingredients (10) to (15) to A and mix them evenly.

C. Fill the container with B to obtain lipstick.

Formulation example 32: lip gloss (pour into an oily solid disc, the second composition)

* 36: Microglass powder METASHINE MT1080TY (manufactured by Japan Sheet Glass), treated with 2% perfluorooctyl triethoxysilane

* 37: Microglass powder METASHINE MT1080TZ (manufactured by Japan Sheet Glass Co., Ltd.), treated with 2% perfluorooctyl triethoxysilane

(Production method)

A. Heat the ingredients (1)~(8) to dissolve them.

B. After filling A in the container, a lip gloss is obtained.

Formula Example 25 Lipstick and Formula Example 27 Lip Gloss, Formula Example 25 Lipstick and Formula Example 28 Lip Gloss, Formula Example 26 Lipstick and Formula Example 27 Lip Gloss, Formula Example 26 Lipstick and Formula Example 28 Lip Gloss, Formula Example 29 Lipstick And Formula For example 30 lip gloss, formula example 31 lipstick and formula example 32 lip gloss, the lip makeup kit used in the formula example will not have the phenomenon of color smearing during use, and has an excellent effect of preventing color contamination. Furthermore, There is no tightness after use, and it is also a person who does not have time-lapse makeup.

Claims (8)

A cosmetic set comprising a first composition and a second composition. After the first composition is applied to the application site, the second composition is applied thereon, and the first composition And the second composition contains the following components, (first composition) (A) film-forming silicone resin (B) silicone oil with a dynamic viscosity of 1000 to 1000000 cs at 25°C (C) volatile The hydrocarbon oil (D) coloring pigment (the second composition) and the mixture of the component (A) and the component (C) mixed at a mass ratio of 1:1 are mixed in an equal amount, and then left at 25°C for 60 minutes to produce For phase separation, component (E) oil; this component (E) contains one or more types of isostearic acid esters with Emory-type isostearic acid groups. A cosmetic set comprising a first composition and a second composition. After the first composition is applied to the application site, the second composition is applied thereon, and the first composition And the second composition contains the following components, (first composition) (A) film-forming silicone resin (B) Polysiloxane oil (C) volatile hydrocarbon oil (D) coloring pigment (the second composition) with a dynamic viscosity of 1000-1000000cs at 25°C and the component (A) mixed with a mass ratio of 1:1 After the mixture of the component (C) is mixed in equal amounts, it is allowed to stand at 25°C for 60 minutes to produce phase separation. The component (E) oil agent; the component (E) contains selected from the group consisting of pentaerythritol tetraisostearate and hydroxyl One or more of stearate, acetylated lanolin, trimellitate, p-methoxycinnamate, and vinylpyrrolidone-based copolymers. For example, the cosmetics kit of item 1 or 2 in the scope of patent application, wherein the component (A) is selected from trimethylsilyloxysilicate, polymethylsilsesquioxane, (acrylate/polydimethyl One type or two or more types of (acrylic acid ester/stearyl alcohol acrylate/polydimethylsiloxane methacrylate) copolymer and (acrylic acid ester/stearyl alcohol acrylate/polydimethylsiloxane methacrylate) copolymer. For example, the cosmetics set of item 1 or 2 in the scope of patent application, wherein the content of the component (E) in the second composition is 50 to 99.9% by mass. For example, the cosmetics kit of item 1 or 2 in the scope of patent application, wherein the content of the component (E) in the second composition is 70 to 99.9% by mass. If you apply for the cosmetics set of item 1 or 2 of the scope of patent application, the first item The content of the component (A) in the composition is 10-50% by mass, the content of the component (B) is 1-50% by mass, and the content of the component (C) is 20-85% by mass. For example, the cosmetics set of item 1 or 2 in the scope of patent application, wherein the component (B) is a silicone oil with a dynamic viscosity of 10000 to 1000000 cs at 25°C. If the cosmetic material set of item 1 or 2 is applied for, the cosmetic material set is the lip cosmetic material set.

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