KR101060881B1 - Matte cosmetic composition for lip makeup or lip care - Google Patents

Abstract

The present invention relates to a matte cosmetic composition for lip makeup or lip care, and more particularly, for a lip makeup or a lip makeup containing a copolymer and a hydrocarbon-based compound composed of two or more different silicone derivatives, having an excellent matte effect and moisturizing effect. It relates to a matte cosmetic composition for lip care. The cosmetic composition according to the present invention provides a substantially matte effect that is differentiated from the existing cosmetic composition, and is excellent in application property and usability.

Matte, Moisturizing, Silicone derivative, Copolymer, Hydrocarbon, Lip care, Cosmetic composition

Description

Non-glossy cosmetic composition for lip make-up or lip care}

The present invention relates to a matte cosmetic composition for lip makeup or lip care, and more particularly, for a lip makeup or a lip makeup containing a copolymer and a hydrocarbon-based compound composed of two or more different silicone derivatives, having an excellent matte effect and moisturizing effect. It relates to a matte cosmetic composition for lip care. The cosmetic composition according to the present invention provides a substantially matte effect that is differentiated from the existing cosmetic composition, and is excellent in application property and usability.

Cosmetic compositions, especially lip makeup compositions, which are all cosmetics available on the lips, such as lipsticks, lip gloss, lip balms and lip pencils, give the skin (especially the lips; the same below) color to make the skin look beautiful and healthy while protecting the skin This is to disperse various nutrients, organic and inorganic pigments useful for the skin in oily substances such as animal and vegetable waxes, ester oils, etc., to make a uniform mixture.

That is, the cosmetic composition usually contains a solid component, a semisolid component (paste), a liquid oily component, a pigment, and other nutritional components.

The solid components include candelillan, ceresin, carnauba wax, paraffin, wax, braze, beeswax and microcrystalline lead, which increase the hardness to maintain the appearance form of the cosmetic composition, and improve the usability smoothly.

The semi-solid components (pastes) include polybutene, hydrogenated polyisobutene and dimerdilinolyl hydrogenated rosinate, etc., which increase the viscosity to increase the persistence when applying cosmetics and express an adhesive feeling of use. And gives gloss.

The liquid oil phase components include castor oil, jojoba oil, squalane, lanolin oil, oils extracted from animals and plants, synthetic ester oils, and other oils.

In addition, the cosmetic composition contains a pigment component consisting of organic and inorganic pigments, and other components such as antioxidants, preservatives, fragrance components, and nutritional components are added.

As a method for improving the moisturizing effect when applying the lip makeup cosmetics to the lips, a method containing a large amount of an oil component, which is generally a softening agent, is widely used. However, the softening oils have a disadvantage of high gloss, which makes the lips shiny and low durability, and does not last long on the lips.

Moreover, improving the moisturizing effect using a dicetearyl dimer di linoleate, bis- diglyceryl polyacryl adipate-2, a phytosteryl isosteryl cetyl steryl behenyl dimer di linoleate, etc. It is a well-known method. However, even in the case of these components there is a disadvantage that does not significantly reduce the shine.

On the other hand, the technique which contains a silicone polymer in cosmetics and produces a matte effect is already known. Japanese Patent Laid-Open No. 2004-507483 and Korean Laid-Open Patent Publication No. 2000-0063063 disclose a cosmetic composition that gives a matte effect and a soft feeling of use.

However, the components of the silicone polymer used in the above is a polymer of a single component, most of which has a problem that almost no matting effect and low persistence does not last long moisturizing effect on the lips.

Therefore, the present inventors have tried to solve the problems of the conventional cosmetic composition as described above, by containing a copolymer and a hydrocarbon-based compound consisting of two or more different silicone derivative components, the matte effect and moisturizing effect on the lips is excellent and the application The present invention has been found to provide a matte cosmetic composition for soft lip makeup or lip care.

Accordingly, an object of the present invention is to provide a matte cosmetic composition for lip makeup or lip care that is excellent in the matte effect and moisturizing effect on the lips and gently applied to the lips.

In order to achieve the above object, the present invention (a) a copolymer composed of two or more different silicone derivative components; And (b) a hydrocarbon compound; provides a matte cosmetic composition for lip makeup or lip care containing.

The matte cosmetic composition for lip makeup or lip care according to the present invention provides a substantial matte effect that is differentiated from the existing cosmetic composition and has a high sustainability and can last a long time moisturizing effect on the lips. In addition, the cosmetic composition of the present invention, when applied to the lips gently applied, provides a comfortable feeling even after applying.

The present invention provides a composition comprising (a) a copolymer composed of two or more different silicone derivative components; And (b) a hydrocarbon compound; provides a matte cosmetic composition for lip makeup or lip care containing.

Hereinafter, the present invention will be described in more detail.

(A) a copolymer composed of two or more different silicone derivative components may include a compound represented by the following Chemical Formula 1;

(H ₃ C) ₃ Si-O- (S ₁ -S ₂ .. -S _n ) -Si (CH ₃ ) ₃

In Formula 1, S means a silicone derivative segment, wherein n is an integer of 2 to 10, Sn means n different silicon derivative segments.

Preferably, the silicone derivative segment S is represented by the following formula (2):

In Formula 2, X may be the same or different, a C ₁ to C ₂₀ monovalent hydrocarbon group not containing an unsaturated bond, a OC ₁ to OC ₂₀ monovalent alkoxy group or C ₁ not containing an unsaturated bond It is selected from the aromatic hydrocarbon group of ˜C ₂₀ , more specifically may be selected from the group consisting of:

Specifically, the C ₁ to C ₂₀ monovalent hydrocarbon group not containing an unsaturated bond is a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and iso Butyl (tbutyl), t-butyl (t-butyl), pentyl (pentyl), hexyl (hexyl), octyl (octyl), decyl (decyl), dodecyl (group) and octadecyl ( octadecyl) group and at least one selected from the group consisting of;

Monovalent alkoxy groups of OC ₁ to OC ₂₀ that do not contain an unsaturated bond include one or more selected from the group consisting of a methoxy group, an ethoxy group and a stearoxy group;

C ₁ ~ C ₂₀ aromatic hydrocarbon group in the group consisting of phenyl group, naphtyl group, benzyl group, phenylethyl group, trill group and xylyl group It includes at least one selected.

M is an integer such that the average molecular weight of the silicone derivative segment S is from 100 to 10,000.

Specific examples of the copolymer composed of (a) two or more different silicone derivative components usable in the present invention include stearoxymethicone / dimethicone copolymer, stearoxymethicone / ethylmethicone / ethylmethicone copolymer, stearoxymethicone / propylmethicone copolymer, stearoxymethicone / methoxymethicone copolymer, stearoxymethicone / ethoxymethicone / ethoxymethicone copolymer and stearoxymethicone / propoxymethicone copolymer.

Copolymers composed of two or more different silicone derivative components are specifically Gransil VX-401, Gransil VX-402 and Gransil SRP from Shin Industries, Inc., Shin-Etsu Chemical Co. Commercially available products such as KF7002) and Masil Wax 135 Mod 1 from Emerald Performance Materials, Inc., but are not limited to the aforementioned materials.

The cosmetic composition of the present invention is characterized by containing (a) 0.1 to 50% by weight, more preferably 5 to 30% by weight, of a copolymer composed of two or more different silicone derivative components. If the content is less than 0.1% by weight can not fully exhibit the effect, if the content exceeds 50% by weight has a disadvantage in that the moldability is poor and broken when applied to the lips.

Moreover, it is preferable to use a hydrocarbon wax as (b) hydrocarbon compound of this invention. The hydrocarbon wax improves the matte effect of the cosmetic composition and helps to improve the moisturizing ability because it forms a film well. Hydrocarbon waxes usable in the present invention include polyethylene, ethylene propylene copolymers, or mixtures thereof.

The cosmetic composition of the present invention is characterized by containing (b) 0.1 to 40% by weight, more preferably 5 to 20% by weight of the hydrocarbon-based compound, based on the total weight of the composition. If the content is less than 0.1% by weight, the effect cannot be sufficiently exhibited. If the content is more than 40% by weight, the pigment is not easily applied to the lips and the dispersibility of the pigment is lowered.

The matte cosmetic composition for lip makeup or lip care of the present invention provides an excellent matt and moisturizing effect on the lips.

The cosmetic composition according to the present invention is a component included in other cosmetic compositions, especially lip cosmetic compositions, and other conventional cosmetic compositions such as waxes, oils, pigments, nutrients, volatile solubilizers, antioxidants, preservatives and fragrances, in particular lips It may contain components (hereinafter referred to as "other components") contained in the cosmetic composition.

Examples of the other components include conventional waxes, semi-solid or liquid hydrocarbon-based, ester-based oils, oil gelling components, volatile solvents, powders such as mica, pigments, antioxidants, preservatives, and fragrances. There are compositions, in particular lip cosmetic compositions, as the skilled person is not limited to the other ingredients listed above.

The solid waxes include microcrystalline wax, ozokerite, beeswax, candelilla wax, carnauba wax, ceresin, paraffin, montan wax, Japan wax, cocoa butter and synthetic wax, but are not limited thereto. .

The oil component may be a mineral oil such as liquid paraffin; Animal oils such as squalene and hydrosqualene; Vegetable oils such as palm oil, avocado oil, jojoba oil, sesame oil, olive oil and castor oil; Butyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, butyl stearate, polybutene, polyisobutene, hydrogenated polyisobutene, various polyols, tri-2-ethylhexyl glycerol, triglyceride oil And synthetic oils such as lactic acid myristyl, octyl dodecanol and diisostearyl malate, but are not limited thereto.

As the powder component, pigments commonly used in cosmetics, for example, mica, synthetic mica, mica, kaolin, titanium dioxide, titanium oxide coated mica, aluminum powder, iron sulfate, black iron oxide, carbon black, barium sulfate, silica, and Inorganic powders such as zeolites; And organic powders such as nylon, PMMA, polystyrene powder, polyethylene powder, cellulose powder, and the like, but are not limited thereto.

As the pigment, yellow 203, yellow 4, yellow 5, yellow 201, yellow 204, red 103, red 201, red 202, red 218, red 220, red 223, red 226 Organic pigments and pearl pigments of barium or aluminum lakes such as No. 1, Red No. 227, Blue No. 1 and Blue No. 2, and the like, and the like.

In the present invention, oil ingredients, moisturizers, antioxidants, ultraviolet absorbers, preservatives, or fragrances may be further blended within the range of not impairing the effects of the present invention as other ingredients usable in cosmetic compositions, particularly lip cosmetic compositions. have.

The cosmetic composition, particularly the lip cosmetic composition, of such a composition can be prepared by lip cosmetic compositions such as lipstick, lip gloss, lip bob, or lip pencil by a process such as heating, mixing, stirring, etc. by a conventional manufacturing method.

Hereinafter, the present invention will be described in more detail by explaining preferred embodiments of the present invention. However, the present invention is not limited to the following examples, and various forms of embodiments can be implemented within the scope of the appended claims, and the following examples are only common in the art while making the disclosure of the present invention complete. It is intended to facilitate the implementation of the invention to those with knowledge.

EXAMPLE 1 AND COMPARATIVE EXAMPLES 1-3

To prepare a lipstick composition of Example 1 and Comparative Examples 1-3 with the composition of Table 1.

Comparative Example 1 is a lipstick composition containing neither a copolymer composed of two or more different silicone derivative components and a hydrocarbon compound, Comparative Example 2 is a lipstick composition in which polyethylene is used alone as a hydrocarbon wax, and Comparative Example 3 Is a lipstick composition in which a stearoxymethicone / dimethicone copolymer is used alone as a copolymer composed of two or more different silicone derivative components. Example 1 is also a lipstick composition containing a stearoxymethicone / dimethicone copolymer and polyethylene together.

Ingredient Name (Unit: Weight%) Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 1. Candelilla Wax 10 - 10 - 2. Synthetic Wax 5 5 5 5 3. Polyethylene - 10 - 10 4. Stearoxymethicone / Dimethicone Copolymer - - 15 15 5. Tricapryline To 100 To 100 To 100 To 100 6. Jojoba You 10 10 - - 7. Hydrogenated Vegetable Oil 10 10 - - 8. Polyglyceryl-2-diisostearate 15 15 15 15 9. Dicetearyl Dimonolate 15 15 - - 10. Cocoa Butter 10 10 10 10 11.Omega 6 Ceramides 5 5 5 5 12. Mica 2 2 2 2 13. Silica 2 2 2 2 14. Incense 0.15 0.15 0.15 0.15

<Production method of Example 1 and Comparative Examples 1 to 3>

1) The raw materials 1 to 3 were dissolved after heating to 80 to 90 ℃.

2) The raw materials 4-11 were added to 1), heated to 75-80 ° C., and dissolved with stirring.

3) The raw materials 12 to 13 were added to 2) and dispersed in a homo mixer.

4) The above 3) was degassed, filtered through a filter cloth, and then flavored to form an appropriate lipstick container.

[Test Example 1]

The coating gloss of the lipstick compositions according to Comparative Examples 1-3 and Example 1 was tested using a glossmeter.

The measurement method was applied to the gloss measurement paper by reciprocating the lipstick composition according to Comparative Examples 1 to 3 and Example 3 with a constant force three times and then using a gloss meter (Gardner) to light the coating surface at a reflection angle at an angle of 60 degrees Glossiness was measured by measuring the amount of reflection at the time of shooting, and the results are shown in Table 2 below (mean value after five measurements). The smaller the numerical value shown in the results of Table 2 below, the better the matteness.

division Lipstick according to Comparative Example 1 Lipstick according to Comparative Example 2 Lipstick according to Comparative Example 3 Lipstick according to Example 1 Glossiness 35.3 25.4 29.2 23.6

As can be seen in Table 2, Example 1 containing a copolymer and a hydrocarbon-based wax composed of two or more different silicone derivative components showed a significantly lower gloss compared to Comparative Examples 1 to 3. Therefore, it was found that the matte cosmetic composition for lip makeup or lip care of the present invention has an excellent matte effect.

[Test Example 2]

The moisturizing power, applicability (softness when using) and comfort (comfort after wearing) of the lipstick compositions of Comparative Examples 1 to 3 and Example 1 were evaluated.

The evaluation was based on 30 points among 30 professional panelists who were unmarried and married women aged between 24 and 35 years and who had at least two years of makeup experience and who continuously used lipstick at least five times a week.

Specific evaluation method was evaluated after using the lipstick composition of Comparative Examples 1 to 3 and Example 1 alternately on the lips for 3 weeks, the results are shown in Table 3 below.

division Lipstick according to Comparative Example 1 Lipstick according to Comparative Example 2 Lipstick according to Comparative Example 3 Lipstick according to Example 1 1. Moisturizing 3.1 4.3 3.6 4.7 2. application property 3.2 4.2 4.1 4.8 3. Comfort 3.6 4.4 4.1 4.4 4. Rating 3.30 4.30 3.93 4.63

As can be seen in Table 3, Example 1 containing a copolymer and a hydrocarbon-based wax composed of two or more different silicone derivative components are excellent satisfaction in all items of moisture retention, application properties and comfort than Comparative Examples 1 to 3 The overall rating was the highest.

Formulation Example 1

Lip gloss was prepared according to the composition of Table 4 below.

ingredient Content (unit: weight%) 1. Polyethylene 4.0 2. Polyglyceryltriisostearate 20.0 3. Castor Oil 36.8 4. Polybutene 15.0 5. Stearoxymethicone / Dimethicone Copolymer 15.0 6. Silica 3.0 7. Mica 2.0 8. Pigment 3.0 9. Tocopheryl Acetate 1.0 10. Spices 0.2

<Manufacturing Method>

1) The raw materials 1 to 5 were dissolved by heating at 90 ° C. or higher, and then stirred with a homogenizer to prepare a mixture.

2) The mixture of 1) was adjusted to 75-85 ° C., raw materials 6-9 were added and mixed, followed by stirring with a homogenizer.

3) Degassing 2) was filtered through a filter cloth, and then the raw material 10 was put in an appropriate lip gloss container.

Formulation Example 2

A lip pencil was prepared in the composition shown in Table 5 below.

Ingredient Name Content (unit: weight%) 1. Candelilla Wax 5.0 2. Polyethylene 10.0 3. Ozokerite 4.5 4. Stearoxymethicone / Dimethicone Copolymer 5.0 5. Polyglyceryl-2-diisostearate 16.1 6. Caprylic / Capric / Mystic / Stearic Triglyceride 6.0 7. Hydrogenated Polyisobutene 1.0 8. Macadamia Oil 3.0 9. Cetearyldimethicone 2.0 10. Dimethicone Copolymer 2.0 11. Pigment 35.0 12. Urethane Powder 10.0 13. Vitamin E (Tocopherols) 0.2 14. Spices 0.2

<Manufacturing Method>

1) The raw materials 1 to 10 were dissolved by heating at 90 ° C. or higher, and then stirred with a homogenizer to prepare a mixture.

2) The mixture of 1) was adjusted to 75-85 ° C., raw materials 11-13 were added and mixed, followed by stirring with a homogenizer.

3) The above 2) was degassed and filtered through a filter cloth, and then the raw material 14 was put into a suitable lip pencil container.

Although the present invention has been described with reference to the above preferred embodiments and formulations, it is possible to make various modifications or variations without departing from the spirit and scope of the invention. Accordingly, the appended claims will cover such modifications and variations as fall within the spirit of the invention.

Claims (11)

(a) stearoxymethicone / dimethicone copolymer, stearoxymethicone / ethylmethicone copolymer, stearoxymethicone / propylmethicone copolymer, stearoxymethicone / methoxymethicone copolymer, stearoxymeth A copolymer composed of at least two different silicone derivative components selected from the group consisting of a chicon / ethoxymethicone copolymer and a stearoxymethicone / propoxymethicone copolymer; And (b) a matte cosmetic composition for lip makeup or lip care, containing a hydrocarbon-based compound which is polyethylene, ethylene propylene copolymer, or a mixture thereof. delete delete delete delete delete delete The matt cosmetic composition for lip makeup or lip care of claim 1, wherein the copolymer (a) comprising two or more different silicone derivative components is contained in an amount of 0.1 to 50% by weight based on the total weight of the composition. . delete delete The matt cosmetic composition for lip makeup or lip care according to claim 1, wherein the hydrocarbon compound (b) is contained in an amount of 0.1 to 40% by weight based on the total weight of the composition.