KR20170038265A - Cosmetic composition having improved performance of transfer-resistant, and processing method thereof - Google Patents

Abstract

The present invention relates to a makeup composition having improved spreading properties, and a method for producing the same. In particular, provided are a wax-free makeup composition comprising silicate-based film forming agent, a silsesquioxane-based film forming agent, plate powder, and a spherical powder. Moreover, the present invention provides a method for producing a wax-free makeup composition, which comprises: a) mixing a silicate-based film forming agent, a silsesquioxane-based film forming agent, plate powder, and spherical powder; and b) producing a paste formulation composition by adding hydrocarbon oil with respect to the mixture. The makeup composition according to the present invention has improved spreading properties, has improved continuance, and has moisturization and coating properties which are not reduced compared to a conventional composition. The method can have process convenience and improved production efficiency.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to an improved makeup composition,

The present invention relates to an improved make-up composition which can be produced without the use of waxes and high levels of oil, and a method of making the same.

In the case of conventional makeup compositions such as lipsticks, it has been common practice to use wax as an essential constituent in general. The wax is added to form the desired hardness and shape of the makeup formulation, and generally has a high melting point and is used with a high content of oils and pigments. However, the above-mentioned constituting materials do not dry well on the lips or the skin surface due to their properties, so that they remain damp when used and easily appear on cups and clothes, thus causing a great inconvenience in daily life. Also, the components remaining on the skin surface without being buried were also erased from the skin condition or external environmental influences over time and did not last long.

As a result, the user of the makeup product suffers from the cumbersome process of correcting and replenishing the makeup several times a day, and has been greatly restricted in using the makeup composition freely. To solve these problems, There has been a demand for development.

In order to solve the above problems, it is thought that it is most effective to restrict the use of such substances because the main cause of the burial in the conventional makeup composition formulations is the wax and a high amount of oil. However, when a formulation is prepared without using wax, there are various technical limitations such as difficulty in forming an appropriate concentration of paste or failure to form a formulation at an appropriate hardness after hardening. In addition, there has been an attempt to apply a film forming agent used for the prevention of burying of mascara formulations and maintenance of durability, but since lips and skin have many movements and wrinkles unlike eyebrows, There is a problem in that it is hard to be commercialized, such as hardening, cracking, deterioration of feel and feeling of uncomfortable feeling.

Therefore, in order to overcome the above technical limitations, various studies have been made on makeup compositions. In addition, when the wax is included in the manufacturing process of the makeup composition, it is required to have high temperature process conditions to melt the wax, There is a problem in that the production efficiency is lowered due to the time required for the process, which necessitates quick and simple process.

Matt cosmetic composition for lip make-up or lip care (Korea Patent No. 10-1060881)

SUMMARY OF THE INVENTION The present invention has been made in order to overcome the problems of the prior art described above, and the inventors of the present invention have found that when the present invention includes two kinds of film forming agents and two types of powders, The present inventors have found that a makeup composition having good feeling can be provided even if the content of oil is reduced without using wax.

Accordingly, an object of the present invention is to provide a makeup composition which is improved in buryability and durability, and which does not deteriorate moisturizing properties and wettability.

The present invention also relates to a method for producing the makeup composition, which provides improved convenience and processability.

In order to achieve the above object,

The present invention relates to a silicate-based film forming agent; Silsesquioxane-based film forming agents; Flake powder; And a spherical powder.

The film forming agent may further optionally include a siliconized polysaccharide compound.

In addition,

a) mixing a silicate-based film former, a silsesquioxane-based film former, a plate-like powder and a spherical powder;

b) adding a hydrocarbon oil to the mixture to form a paste-form composition;

≪ RTI ID = 0.0 > a < / RTI > makeup composition.

Particularly in step a)

a-1) mixing the spherical powder and the plate-like powder;

a-2) mixing the silicate-based film forming agent and the silsesquioxane-based film-forming agent with the mixture of the spherical powder and the plate-like powder;

. ≪ / RTI >

By using the above-mentioned problem solution,

The makeup composition of the present invention has improved burying and improved durability, but does not lower the moisturizing and spreading properties as compared with the conventional ones.

According to the present invention, since the process for melting the wax is omitted, the process for preparing the makeup composition of the present invention can be performed at room temperature and the process time is reduced to 10 to 20 minutes, .

FIG. 1 is an image showing the degree of appearance of the composition of Example 1 and Comparative Example 2 on a tissue after it is applied to artificial leather. FIG.
Fig. 2 is an image showing that the composition of Example 1 and Comparative Example 2 is buried in the paper cup when it is applied directly to the lips. Fig.
Fig. 3 is an image showing the consistency of the compositions of Example 1 and Comparative Example 1. Fig.

The present invention

A makeup composition comprising a silicate based film former, a silsesquioxane based film former, a plate-like powder and a spherical powder.

Also,

a) mixing a silicate-based film-forming agent, a silsesquioxane-based film-forming agent, a plate-like powder and a spherical powder;

b) adding a hydrocarbon oil to the mixture to form a paste-form composition;

≪ RTI ID = 0.0 > a < / RTI > makeup composition.

The makeup composition of the present invention is preferably a wax-free formulation containing a small amount of oil and may be utilized as a hue makeup composition, more preferably a lip makeup composition. In this specification, the term 'wax-free' refers to a formulation that does not contain wax. Typically, lip makeup formulations and the like among the conventional makeup formulations are essentially composed of wax and a large amount of oils In contrast, the makeup composition of the present invention can be produced with only a small amount of oil without the wax by using a film-forming agent and a powder in combination. Accordingly, the makeup composition of the present invention has an effect of effectively reducing the burial after application and improving the durability.

In addition, the makeup composition of the present invention may further have an effect of improving the durability of the composition of the composition from the film forming agent. The term " persistence " refers to the phenomenon that the stability of the formulation itself changes and the dressing state decreases with time due to sebum or sweat released from the skin itself, environmental stimuli such as temperature or humidity, and the stability of the formulation itself Is a concept distinguished from "buried", which is a phenomenon in which external physical contact is applied, for example, when a cosmetic composition comes into contact with another object on the skin, or the state of the hair is lowered.

The makeup composition of the present invention will be described with reference to lip makeup products such as lipstick, lip gloss, lip balm, lip balm, and lip pencil. However, the present invention is not limited thereto and may be applied to all types of compositions It is freely available as a makeup formulation.

Hereinafter, the contents of the present invention will be described in more detail. It is to be understood, however, that the scope of the present invention is not limited thereto and that the present invention covers all of the equivalent scope of the following description.

<Make-up composition>

Film forming agent

The makeup composition of the present invention includes a silicate based film forming agent and a silsesquioxane based film forming agent as one component of the composition to provide a wax-free makeup composition for preventing embedding. The film former can be most effectively deposited and improved in consistency when mixed with the powders described below.

The silicate-based film forming agent may be selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, dimethicone / vinyltrimethylsilane, And a silsesquioxane film-forming agent may be at least one selected from the group consisting of polyvinylpyrrolidone, polyphenylsilsesquioxane, polypropylsilsesquioxane ( Polypropylsilsesquioxane, Dimethicone / Silsesquioxane Copolymer, and the like.

The silicate-based and silsesquioxane-based film-forming agents largely correspond to a silicone-based film forming agent and include a silicone-based MQ resin and may have various M / Q ratios. (Trimethylsiloxysilicate) of Dow Corning, TMS-803 (trimethylsiloxysilicate) of Wacker-Belsil, KF-7312K (trimethylsiloxysilicate and dimethicone), GE Silpropine 151 (phenylpropyldimethylsiloxysilicate), MQ1640, and the like.

In one more preferred embodiment of the present invention, trimethylsiloxysilicate is used as the silicate film forming agent and polypropylsilsesquioxane is used as the silsesquioxane film forming agent.

The two kinds of film formers of the present invention described above are characterized by being contained together. This is because the use of any one type of film forming agent can result in an uncomfortable feeling of use. For example, when only a silicate-based film forming agent such as trimethylsiloxysilicate is used, the surface of the formulation hardens like a manicure, This can cause the problem to fall. Thus, the silicate-based film forming agent and the silsesquioxane-based film-forming agent are used together to form a formulation having appropriate rigidity and flexibility.

On the other hand, in addition to the two film formers described above, the film forming agent of the present invention may further comprise a polysiloxane compound. The siliconized polysaccharide compound is preferably a material formed by reacting trimethylsiloxysilylisocyanate and a polysaccharide compound. Examples of the polysaccharide compound include cellulose, gum arabic, alginic acid, carrageenan, xanthan gum, pullulan, and the like.

The silicone polysaccharide compound may further include trimethylsiloxysilylcarbamoylpullulan formed by reacting pullulan as a polysaccharide compound. Examples of the product of trimethylsiloxycambailululan include TSPL 30-D5 (trimethylsiloxycarbamoylpullulan and cyclopentasiloxane) from Shin Etsu, TSPL 30-ID (trimethylsiloxycarbamoylpululan and isodo Decane).

The total content of film formers which may be included in the present invention is preferably 10 to 40% by weight based on the weight of the total composition. If it is contained in an amount of less than 10% by weight, the degree of film formation is insignificant, so that the effect of prevention of embossing and improvement of durability to be provided by the present invention is reduced, and if it is contained in an amount exceeding 40% by weight, the formulation is formed too hard, .

The weight ratio of the silsesquioxane-based film former to the silicate-based film former in the film former is preferably in the range of 3: 1 to 3: 3. More preferably 3: 2. However, the scope of the present invention is not limited to the above-mentioned range, and the composition of ratios may be different depending on the type, purpose of the makeup product, and degree of effect to be provided.

powder

In the makeup composition of the present invention, a spherical powder and a plate-like powder are used together.

The spherical powder may be an organic powder. Preferably, the spherical powder is selected from the group consisting of silica, polymethyl methacrylate (PMMA), polyurethane (PU), polymethylsilsesquioxane (PMSQ) Or more can be used.

As the plate-like powder, inorganic powder may be used, and preferably at least one selected from the group consisting of talc, boron nitride, mica and sericite can be used, and more preferably, mica can be used.

In the case of using only spherical powder among these materials, flaking may occur at the time of use, and when only a plate-like powder is used, the bulk transferability of the composition is lowered and the spreadability is poor. Therefore, when the spherical powder and the plate-like powder are used together, the layer of the formulation slips smoothly and can be gently developed and adhered to the skin without fluttering.

The total content of the spherical powder and the plate-like powder of the present invention is preferably 30 to 80% by weight based on the weight of the total composition. When it is contained in an amount of less than 30% by weight, a paste phase is difficult to form, and when it is contained in an amount exceeding 80% by weight, an overly complicated formulation can be formed.

In addition, the weight ratio of the spherical powder to the powder is preferably in the range of 2: 1 to 2: 2, more preferably 6: 5. However, the scope of the present invention is not limited to the above-mentioned range, and the composition of ratios may be different depending on the type, purpose of the makeup product, and degree of effect to be provided.

As described above, the makeup composition of the present invention including the film-forming agent and the powder is characterized in that it generally contains a small amount of oil as compared with the prior art without using wax. In this case, since the oil content may affect the gloss, it can be adjusted to include the proper amount in consideration of the balance with the effect of preventing the burying. However, the oil content of the makeup composition of the present invention is not limited to a particularly high level, whereas the oil content of the makeup composition of the present invention must be included at a level of 70 ~ 80%. The amount of the oil for improving the burying is preferably not more than 40% by weight, more preferably not more than 20% by weight, which corresponds to the conventional half level.

Meanwhile, the makeup composition of the present invention may further comprise a functional material such as a moisturizer, a polymer, or the like.

<Manufacturing Method>

The present invention also

a) mixing a silicate-based film-forming agent, a silsesquioxane-based film-forming agent, a plate-like powder and a spherical powder;

b) adding a hydrocarbon oil to the mixture to form a paste-form composition;

&Lt; RTI ID = 0.0 &gt; a &lt; / RTI &gt; makeup composition.

At this time, preferably, the step a)

a-1) mixing the spherical powder and the plate-like powder;

a-2) mixing the silicate-based film forming agent and the silsesquioxane-based film-forming agent with the mixture of the spherical powder and the plate-like powder;

. &Lt; / RTI &gt;

The makeup composition according to the above-described production method finally forms particles of a composition in which a film-forming agent and a hydrocarbon oil are sequentially coated on the powder. Such a structure is more effective for use and prevention of embossing, for example, after applying the make-up composition on lips or the like, it does not feel tone, and there is no bury after the applied formulation is dried.

On the other hand, the mixture of the film-forming agent and the powder prepared from the step (a) of the present invention forms a dilute paste formulation. In order to control the dilution degree of the formulation and to additionally provide various functions, the hydrocarbon- Other oils, moisturizers, functional polymers and the like may be further added.

The makeup composition of the present invention is characterized in that it is carried out at room temperature in the range of 15 to 30 占 폚 and the total process time is about 10 to 20 minutes.

In order to prepare a makeup composition containing a conventional wax, a high temperature condition was required to melt the wax having a melting point of 90 ° C or higher, and the process of melting the wax was also repeated three to four times Most of the heating and dissolving processes are necessary, which takes about one hour or more. On the other hand, the present invention can reduce the inconvenience of the process, thereby improving the convenience and processability as well as reducing the cost, thereby improving the overall production efficiency.

Evaluation Examples and Experimental Examples 1 to 4 relating to the effects of the present invention will be described below. In the experiment, makeup compositions having compositions of the following Examples 1, 2 and 3 were used. However, the following test examples correspond to experimental examples of the constitution and effect of the present invention, and the scope and effect of the present invention are not limited thereto.

< Example  1 and Comparative Example  1>

Kinds
Chemical name

Example  One
content ( % )
Comparative Example 1
content( % ) Plate powder Mica 27.0 30.0 Spherical powder Polymethylsilsesquioxane 17.0 20.0 Spherical powder Polymethyl methacrylate 4.0 8.0 Pigment Red # 7 Lake 10.0 10.0 Film forming agent Trimethylsiloxysilylcarbamylflurane 5.0 - Film forming agent Trimethylsiloxysilicate 3.0 - Film forming agent Polypropyl silsesquioxane 2.0 - Silicone oil Cyclopentasiloxane 5.0 5.0 Silicone oil Dimethicone 10.0 10.0 Silicone oil Diphenylsiloxy phenyl trimecicone 5.0 5.0 Hydrocarbon oil Phyto Squalane 5.0 5.0 Moisturizer Butyleneglycol 4.0 4.0 Polymer Dimethicone / Vinyl Dimethicone Crosspolymer 3.0 3.0

The makeup compositions of Example 1 and Comparative Example 1 were prepared according to the contents and combinations shown in Table 1 above. Example 1 is a makeup composition of the present invention, and Comparative Example 1 is a makeup composition that does not contain a film-forming agent as compared with that of the makeup composition of the present invention.

< Comparative Example  2>

Chemical name

Comparative Example 2
content( % ) Dicaprylyl carbonate 20.0 Vinyl dimethicone / methicone silsesquioxane crosspolymer 5.0 Polyglyceryl-2-phthalic anhydride 17.0 Diisostearyl malate 8.0 Jojoba ester 8.0 Trioctyldodecylcitrate 7.0 Dimethicone 6.0 Ethylene / propylene copolymer 4.0 Synthetic wax 5.0 Polyethylene 5.0 Hydrogenated castor oil isostearate 3.0 Alumina 2.0 Red # 7 Lake (CI 15850) 10.0

The makeup composition of Comparative Example 2 was prepared according to the contents and combinations of the ingredients listed in Table 2 above. The makeup composition of Comparative Example 2 corresponds to a conventional makeup composition using a wax.

< Manufacturing example >

1) Mix powder raw material and coloring matter into a blender and mix for 1 minute.

2) Add the film-forming agent and silicone to the mixed raw material 1) and mix for 1 minute.

3) 2) into a kneader, add hydrocarbon oil, moisturizer and polymer, and mix in two stages for 15 minutes.

< Evaluation example >

In this evaluation example, the properties of the above Example 1, Comparative Example 1, and Comparative Example 2 concerning the embedding, persistence and spreadability were evaluated. The evaluation was carried out by sensory evaluation of the group consisting of 30 members and evaluated by 1 ~ 5 points (1: low to 5: very good) according to the excellent degree. The total score per item is shown as the average value.

The results are shown in Table 3 below.

Example  One Comparative Example  One Comparative Example  2 No Bury 4.3 2.0 1.0 Persistence 4.1 2.7 2.3 Brittle 3.9 3.6 4.0

Referring to Table 3, it can be seen that Example 1 is not buried in comparison with Comparative Example 2, and the durability is maintained at an equal level while the durability is improved. In addition, the composition of Example 1 was not much different from the composition of Comparative Example 1, which did not contain a film forming agent, compared with the composition of Example 1, and it was confirmed that the stability was improved.

In the following Experimental Examples, several experimental examples of the sensory evaluation result are specifically described.

< Experimental Example  1> - Bury experiment 1

The difference in the burying characteristics was confirmed by comparing Example 1 and Comparative Example 2.

As a test method, each composition of Example 1 and Comparative Example 2 was applied to an artificial leather three times, rolled, covered with a tissue, pressed for one minute with a paperweight, and then compared to a tissue. The results of Experimental Example 1 are shown in Fig.

Referring to FIG. 1, it can be seen that, in the case of the conventional wax-containing formulation of Comparative Example 2 (bottom), the applied composition was noticeably spread on the tissue, whereas in Example 1 (top)

< Experimental Example  2> - Bury experiment 2

The difference in the burying characteristics of the compositions of Example 1 and Comparative Example 2 was confirmed through a method different from that of Experimental Example 1.

As a test method, the compositions of the compositions of Example 1 and Comparative Example 2 were applied to the lips, and then the degree of appearance of the composition on the paper cups when the water contained in the paper cups were consumed for 30 minutes was compared. The results of Experimental Example 2 are shown in Fig.

Referring to FIG. 2, it can be seen that the composition applied to the lips clearly appears in the case of Example 1 (left side), whereas that of Comparative Example 2 (right side) is clear.

< Experimental Example  3> - Persistence test

To determine the extent to which the presence of the film former is affected by the persistence of the composition, a persistence test was conducted using the compositions of Example 1 and Comparative Example 1 above.

As a test method, after applying compositions of Example 1 and Comparative Example 1 to artificial leather, the artificial leather was immersed in a solution of caprylic / capric triglyceride and water in a ratio of 1: 4 (presumed to be similar to the skin condition) Shaking for minutes. The results are shown in FIG.

Referring to FIG. 3, in the case of Example 1 (left), the first coating state was maintained almost without erasure, whereas in Comparative Example 1 (right), a lot of whitened portions were observed.

In addition, the following experiments were conducted using the compositions of Example 1 and Comparative Example 2 to verify that the makeup compositions of the present invention have a degree of dryness suitable for use as compared to makeup compositions comprising conventional waxes. This is shown in Experimental Example 4 below.

< Experimental Example  4> - Drying experiment

Measurement of skin surface moisture evaporation

In order to measure the degree of moisture evaporation on the skin surface, the average value of ten skin testees was determined by skin touch. The results are shown in Table 4 below.

Example  One Comparative Example  2 Right after 40 43 After 2 hours 30 33 After 5 hours 24 27

Example 1, which is a makeup composition according to the present invention, has a drying degree similar to that of Comparative Example 2, which is a makeup composition containing a conventional wax, at a level that does not cause a significant difference in practical use can confirm. Thus, it can be seen that the makeup composition according to the present invention does not particularly suffer from pulling or drying as compared with the conventional formulations.

Sensory evaluation of dryness

This sensory evaluation was carried out by sensory evaluation of a group consisting of 10 members and evaluated as 1 ~ 5 points (1: almost not felt ~ 5: very intense) for each item according to the excellent degree. As a result of the evaluation, Example 1 showed an average of 2.4 and Comparative Example 2 averaged 2.1.

As a result of the above evaluation examples and the results of Experimental Examples 1 to 4, it can be seen that the makeup composition according to the present invention is a wax-free formulation and is a makeup composition that is improved in burying and excellent in durability, have.

Claims (17)

Silicate-based film forming agents; Silsesquioxane-based film forming agents; Flake powder; And a spherical powder.
The method according to claim 1,
Wherein the film forming agent further comprises a siliconized polysaccharide compound.
3. The method of claim 2,
Wherein the silicone polysaccharide compound is trimethylsiloxysilylcarbamoylpullulan. &Lt; Desc / Clms Page number 15 &gt;
The method according to claim 1,
The silicate film former may be selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, dimethicone / vinyltrimethylsiloxysilicate cross And a polymer (Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer).
The method according to claim 1,
The silsesquioxane film-forming agent may be selected from the group consisting of polyphenylsilsesquioxane, polypropylsilsesquioxane, dimethicone / silsesquioxane copolymer, By weight based on the total weight of the composition.
The method according to claim 1,
Wherein the silicate-based film forming agent is trimethylsiloxysilicate, and the silsesquioxane-based film forming agent is polypropylsilsesquioxane.
The method according to claim 1,
Wherein the spherical powder is at least one selected from the group consisting of silica, polymethylmethacrylate (PMMA), polyurethane (PU), polymethylsilsesquioxane (PMSQ) and nylon.
The method according to claim 1,
Wherein the plate-like powder is at least one selected from the group consisting of talc, boron nitride, mica, and cericite.
The method according to claim 1,
Wherein the weight ratio of the silsesquioxane-based film former to the silicate-based film former is 3: 1 to 3: 3.
The method according to claim 1,
Wherein the total content of said film formers is from 10 to 40% by weight relative to the weight of the total composition.
The method according to claim 1,
Wherein the weight ratio of the spherical powder to the plate powder is 2: 1 to 2: 2.
The method according to claim 1,
Wherein the total content of the spherical powder and the plate-like powder is 30 to 95% by weight based on the weight of the total composition.
The method according to claim 1,
Wherein the amount of the oil contained in the makeup composition is 40 wt% or less based on the total weight of the composition.
a) mixing a silicate-based film former, a silsesquioxane-based film former, a plate-like powder and a spherical powder;
b) adding a hydrocarbon oil to the mixture to form a paste-form composition;
&Lt; / RTI &gt;
15. The method of claim 14,
The step a)
a-1) mixing the spherical powder and the plate-like powder;
a-2) mixing the silicate-based film forming agent and the silsesquioxane-based film-forming agent with the mixture of the spherical powder and the plate-like powder;
&Lt; / RTI &gt;
15. The method of claim 14,
Wherein the moisturizing agent and the functional polymer are further added in the step b).
17. The method according to any one of claims 14 to 16,
Wherein the makeup composition is prepared at a temperature of 15 to 30 占 폚.

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