JP5679421B2 - Stick cosmetic - Google Patents
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- JP5679421B2 JP5679421B2 JP2010225764A JP2010225764A JP5679421B2 JP 5679421 B2 JP5679421 B2 JP 5679421B2 JP 2010225764 A JP2010225764 A JP 2010225764A JP 2010225764 A JP2010225764 A JP 2010225764A JP 5679421 B2 JP5679421 B2 JP 5679421B2
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- 239000002537 cosmetic Substances 0.000 title claims description 47
- 239000000341 volatile oil Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 12
- -1 polyethylene Polymers 0.000 claims description 12
- 235000013871 bee wax Nutrition 0.000 claims description 11
- 239000012166 beeswax Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000004203 carnauba wax Substances 0.000 claims description 10
- 235000013869 carnauba wax Nutrition 0.000 claims description 10
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000001993 wax Substances 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 238000011156 evaluation Methods 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 5
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 210000004709 eyebrow Anatomy 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229930003427 Vitamin E Natural products 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 235000019165 vitamin E Nutrition 0.000 description 3
- 229940046009 vitamin E Drugs 0.000 description 3
- 239000011709 vitamin E Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 101100294331 Drosophila melanogaster nod gene Proteins 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- FGUZFFWTBWJBIL-XWVZOOPGSA-N [(1r)-1-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1O FGUZFFWTBWJBIL-XWVZOOPGSA-N 0.000 description 2
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 229940057429 sorbitan isostearate Drugs 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- RNNHLXAEVKCLDG-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane Chemical compound C[Si]1(C)O[SiH2]O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 RNNHLXAEVKCLDG-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229940116422 propylene glycol dicaprate Drugs 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000003009 skin protective agent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Description
本発明は、成型性が良好で、使用時の伸びが良く、塗布後のべたつきもなく、二次付着が抑制され、更に耐衝撃性に優れた棒状化粧料に関するものである。 The present invention relates to a rod-shaped cosmetic material having good moldability, good elongation at the time of use, no stickiness after application, secondary adhesion being suppressed, and excellent impact resistance.
アイライナー、アイブロウ、リップライナー、コンシーラーペンシル、アイシャドウペンシル等の棒状化粧料は、鉛筆型または繰り出して使うペンシル型の形態で使用されるものであり、固形油を含む油性成分と、顔料などの粉体を骨格として構成され、基本的性能としては、製造時の充填成型性や、伸びが良く、滑らかな感触、べたつきが少ないなどの使用性が求められる他、二次付着を抑え化粧持ちに優れることも望まれる。従来の技術では、良好な使用感触を得ようとした場合、高粘度の液状油分、半固形油分を用い、またこれらを多く配合するが、そのため棒状化粧料として十分な強度が得られず、更に、べたつき易くなるため、化粧持ち、耐二次付着性に劣るものとなってしまう。また強度を得るために固形油を増やした場合、伸びが悪く、細い形状である棒状化粧料では特に固い使用感触となってしまい化粧製品としては著しく商品価値を損なうこととなる。それらの問題点を踏まえ、トリメチルシロキシケイ酸などの有機シリコーン樹脂と揮発性油剤を用いることで、他の性能を損なわずに二次付着を抑える検討がされてきた。 Stick-shaped cosmetics such as eyeliner, eyebrow, lip liner, concealer pencil, eye shadow pencil, etc. are used in the form of pencils or pencils that are drawn out. Oily ingredients including solid oil, pigments, etc. It is composed of powder as a skeleton, and its basic performance is such as filling moldability at the time of manufacture, ease of use, smooth feel, low stickiness, etc. It is also desirable to be excellent. In the conventional technology, when trying to obtain a good feeling of use, a high-viscosity liquid oil or semi-solid oil is used, and many of these are blended. Because it becomes sticky, it will be inferior in makeup holding and secondary adhesion resistance. Further, when solid oil is increased in order to obtain strength, elongation is poor, and a stick-shaped cosmetic material having a thin shape is particularly hard to use, and the product value is significantly impaired as a cosmetic product. Based on these problems, studies have been made to suppress secondary adhesion without impairing other performances by using an organic silicone resin such as trimethylsiloxysilicic acid and a volatile oil agent.
しかし、有機シリコーン樹脂は比較的多く配合した場合、欠け、ひび、折れ等が発生し易く、脆い棒状化粧料となるため、近年に於いては特定の油剤などを組み合わせることでこれらの欠点を抑えることも検討されている。（特許文献１）、（特許文献２） However, when a relatively large amount of organic silicone resin is blended, chipping, cracking, breakage, etc. are likely to occur, resulting in a brittle stick-shaped cosmetic. In recent years, these disadvantages can be suppressed by combining specific oils. It is also being considered. (Patent Document 1), (Patent Document 2)
しかしながら、上記特許文献１、２に記載された考案では脆さの改善には不十分であり、落下試験等の耐衝撃性で十分な結果が得られず、また粘性のある油剤を用いることにより、べたつき易く、耐二次付着性も低下してしまう。 However, the devices described in Patent Documents 1 and 2 are insufficient for improving brittleness, and sufficient results cannot be obtained in impact resistance such as a drop test, and by using a viscous oil. It is easy to stick and secondary adhesion resistance is also lowered.
上記課題を解決するため鋭意検討を進めた結果、本発明はトリメチルシロキシケイ酸１〜１５重量％、揮発性油剤１０〜３５重量％、粉体２５〜５５重量％を含む棒状化粧料において、平均分子量４５０以下のポリエチレンワックス２〜２０重量％、カルナウバワックス０．１〜５重量％、ミツロウ０．１〜５重量％を含有する棒状化粧料とすることにより、成型性が良好で、使用時の伸びが良く、塗布後のべたつきもなく、二次付着が抑制され、更には耐衝撃性に優れた棒状化粧料が得られることを見出した。 As a result of diligent studies to solve the above-mentioned problems, the present invention is a stick-shaped cosmetic comprising 1 to 15% by weight of trimethylsiloxysilicic acid, 10 to 35% by weight of volatile oil, and 25 to 55% by weight of powder. molecular weight 450 or less polyethylene wax 2-20 wt% of carnauba wax 0.1 to 5 wt%, by the stick-shaped cosmetic material containing beeswax 0.1 to 5 wt%, moldability is good, use It has been found that a stick-shaped cosmetic material having good elongation, no stickiness after coating, secondary adhesion is suppressed, and further excellent in impact resistance can be obtained.
上述のように本発明では成型性が良好で、使用時の伸びが良く、塗布後のべたつきもなく、二次付着が抑制され、更には耐衝撃性に優れた棒状化粧料が得られる。 As described above, in the present invention, a rod-shaped cosmetic material having good moldability, good elongation at the time of use, no stickiness after coating, secondary adhesion is suppressed, and furthermore, excellent impact resistance is obtained.
以下、本発明の実施形態について詳述する。
なお、以下の％は重量％を示し、以後％と表示する。
本発明は、トリメチルシロキシケイ酸、揮発性油剤、平均分子量４５０以下のポリエチレンワックス、カルナウバワックス、ミツロウ及び粉体を含有する棒状化粧料である。
このような特徴的な構成を有するため、本発明の棒状化粧料は成型性が良好で、使用時の伸びが良く、耐衝撃性に優れる。また半固形油分や高粘性油分を必須としないため、塗布後のべたつきもなく、二次付着が抑制され、衣服への付着防止、化粧持ちにも好適である。
Hereinafter, embodiments of the present invention will be described in detail.
In addition, the following% shows weight% and is displayed as% after that.
The present invention is a stick-shaped cosmetic containing trimethylsiloxysilicic acid, volatile oil, polyethylene wax having an average molecular weight of 450 or less, carnauba wax, beeswax and powder.
Since it has such a characteristic configuration, the stick-shaped cosmetic of the present invention has good moldability, good elongation during use, and excellent impact resistance. Moreover, since a semi-solid oil or a highly viscous oil is not essential, there is no stickiness after application, secondary adhesion is suppressed, and it is suitable for prevention of adhesion to clothes and long-lasting makeup.
本発明において用いられるトリメチルシロキシケイ酸としては、シロキサン構造を主骨格とした架橋構造を持つ化合物で［（ＣＨ ３ ） ３ ＳｉＯ １／２ ］ ｘ ［ＳｉＯ ２ ］ ｙ で表され、市販品としては、ＫＦ−７３１２Ｆ、ＫＦ−７３１２Ｊ，ＫＦ７３１２Ｋ、Ｘ−２１−５５９５（信越化学工業社製）など揮発性油剤やシリコーン油と混合したものがあげられる。本発明の棒状化粧品に含まれるトリメチルシロキシケイ酸の量は１．０〜１５．０％が好ましく、２．０〜１３．０％であることがより好ましい。１．０％未満の場合、二次付着しやすく化粧持ちに劣り、１５．０％を越えて含まれる場合伸展性など使用性に劣るものとなってしまう。 The trimethylsiloxysilicic acid used in the present invention is a compound having a crosslinked structure having a siloxane structure as a main skeleton and represented by [ (CH 3 ) 3 SiO 1/2 ] x [SiO 2 ] y. , KF-7312F, KF-7312J, KF7312K, X-21-5595 (manufactured by Shin-Etsu Chemical Co., Ltd.), and those mixed with a volatile oil or silicone oil. 1.0-15.0% is preferable and, as for the quantity of the trimethylsiloxy silicic acid contained in the rod-shaped cosmetics of this invention, it is more preferable that it is 2.0-13.0%. If it is less than 1.0%, secondary adhesion tends to be inferior, and if it exceeds 15.0%, it will be inferior in usability such as extensibility.
本発明に用いられる揮発性油剤としては例えば、オクタメチルシクロペンタシロキサン、デカメチルシクロペンタシロキサン等の環状シリコーン、オクタメチルトリシロキサン、デカメチルテトラシロキサン等の鎖状シリコーン、軽質イソパラフィン、イソドデカン等の炭化水素系揮発性油剤などが挙げられる。これらの揮発性油剤は１種又は２種以上を適宜選択して用いることが可能であるが、肌なじみが良く、塗布後のべたつき感が少ないことより、炭化水素系揮発性油剤を用いることが好ましい。本発明の棒状化粧料に含まれる揮発性油剤の量は１０〜３５％が好ましく、１３〜３０％であることがより好ましい。揮発性油剤が１０％未満の場合二次付着し易く、化粧持ちも劣る、３５％を越えて含まれる場合耐衝撃性に劣るものとなってしまう。 Examples of the volatile oil used in the present invention include cyclic silicones such as octamethylcyclopentasiloxane and decamethylcyclopentasiloxane, chain silicones such as octamethyltrisiloxane and decamethyltetrasiloxane, carbonization such as light isoparaffin and isododecane. Examples include hydrogen-based volatile oils. These volatile oils can be used by appropriately selecting one or two or more kinds, but it is possible to use hydrocarbon-based volatile oils because they are well-familiar and less sticky after application. preferable. 10-35% is preferable and, as for the quantity of the volatile oil agent contained in the rod-shaped cosmetics of this invention, it is more preferable that it is 13-30%. When the volatile oil content is less than 10%, secondary adhesion tends to occur and the makeup lasting is poor, and when it exceeds 35%, the impact resistance is poor.
本発明に用いられる平均分子量４５０以下のポリエチレンワックスは市販品としてはＰＥＲＦＯＲＭＡＬＥＮＥ４００（ニューフェーズテクノロジー社製）などが挙げられる。平均分子量が４５０を越えるものを用いた場合、脆く固い棒状化粧料となり使用性は伸びが悪く、固い感触となり、落下試験などの耐衝撃性は劣るものとなる。また棒状化粧料に含まれる量は２〜２０％が好ましく、５〜１５％であることがより好ましい。２％未満の場合耐衝撃性に劣り、２０％を越えて含まれる場合伸展性が劣り、べたつく使用感触となってしまう。 Examples of the polyethylene wax having an average molecular weight of 450 or less used in the present invention include PERFORMALENE 400 (manufactured by New Phase Technology Co., Ltd.). When a product having an average molecular weight exceeding 450 is used, it becomes a brittle and hard stick-shaped cosmetic material, and the usability is poorly stretched and a hard feel is obtained, and impact resistance such as a drop test is inferior. Moreover, 2-20% is preferable and, as for the quantity contained in stick-shaped cosmetics, it is more preferable that it is 5-15%. If it is less than 2%, the impact resistance is poor, and if it exceeds 20%, the extensibility is inferior, resulting in a sticky feel.
本発明で用いるカルナウバワックスとしては、精製カルナウバワックスＲ−１００（横関油脂工業株式会社製）、精製カルナウバワックスＮｏ．１（株式会社セラリカＮＯＤＡ製）などの市販品を用いることができる。カルナウバワックスの含有量は棒状化粧料全量に対して０．１〜５％であることが好ましく、更には０．５〜３％であることが特に好ましい。０．１％未満の場合、耐衝撃性に劣るものとなり、５％を超えた場合、伸展性に劣るものとなる。また、ミツロウとしては、精製ミツロウＣＯ−１００（横関油脂工業株式会社製）、脱臭精製蜜蝋高酸（株式会社セラリカＮＯＤＡ製）、ＢＥＥＳＷＡＸ Ｓ（クローダジャパン社製）などの市販品を用いることができる。ミツロウの含有量は棒状化粧料全量に対して０．１〜５％であることが好ましく、更には０．５〜４％であることが特に好ましい。０．１％未満の場合、使用時に棒状化粧料がぐずつき易く、また耐衝撃性にも劣る。５％を超える場合べたつき易く、耐二次付着性に劣るものとなる。 As the carnauba wax used in the present invention, refined carnauba wax R-100 (manufactured by Yokoseki Oil & Fat Co., Ltd.), refined carnauba wax No. Commercial products such as 1 (manufactured by Celerica NODA) can be used. The content of carnauba wax is preferably 0.1 to 5%, more preferably 0.5 to 3%, based on the total amount of the stick-shaped cosmetic. When it is less than 0.1%, the impact resistance is inferior, and when it exceeds 5%, the extensibility is inferior. Moreover, as beeswax, commercially available products such as refined beeswax CO-100 (manufactured by Yokoseki Yushi Kogyo Co., Ltd.), deodorized and refined beeswax high acid (manufactured by Celerica NODA), BEESWAX S (manufactured by Croda Japan Co., Ltd.) can be used. . The beeswax content is preferably 0.1 to 5%, more preferably 0.5 to 4%, based on the total amount of the stick-shaped cosmetic. When the content is less than 0.1%, the stick-shaped cosmetic is easily blurred during use and is inferior in impact resistance. If it exceeds 5%, it tends to be sticky and has poor secondary adhesion resistance.
本発明で用いる粉体は、化粧品に使用することができる粉体の中から１種又は２種以上を適宜選択することができる。具体的には、マイカ、タルク、セリサイト、カオリン、無水ケイ酸、窒化ホウ素、炭酸カルシウム、硫酸バリウム、ナイロン末、ポリアクリル酸アルキル、無機顔料、有機顔料、パール顔料などが挙げられる。またこれらはシリコーン化合物、フッ素化合物、アミノ酸化合物、金属石鹸等で公知の方法にて表面処理を施したものを用いても良く、２種以上で複合化粉体としたものを用いることもできる。上記粉体は棒状化粧料中２５〜５５％が好ましく、３０〜５０％であることがより好ましい。２５％未満の場合、化粧料として付き、発色が不十分であり、５５％を越えて含まれる場合成型性に劣り、伸びの悪い棒状化粧料となってしまう。 The powder used in the present invention can be appropriately selected from one or more powders that can be used in cosmetics. Specific examples include mica, talc, sericite, kaolin, silicic anhydride, boron nitride, calcium carbonate, barium sulfate, nylon powder, alkyl polyacrylate, inorganic pigment, organic pigment, pearl pigment, and the like. In addition, these may be a silicone compound, a fluorine compound, an amino acid compound, a metal soap or the like which has been surface-treated by a known method, or a composite powder of two or more types may be used. The powder is preferably from 25 to 55%, more preferably from 30 to 50%, in the stick-shaped cosmetic. If it is less than 25%, it is attached as a cosmetic, and coloring is insufficient, and if it exceeds 55%, it is inferior in moldability and becomes a stick-shaped cosmetic with poor elongation.
本発明の棒状化粧料には、上記成分の他に目的に応じて、本発明の効果を損なわない範囲で上記以外の成分を配合することができる。上記以外の油性原料、ワックス、界面活性剤、防腐剤、酸化防止剤、増粘剤、美白剤、香料、保湿剤、皮膚保護剤、などを使用目的に応じて適宜選択添加することができる。またこれら任意の成分はそれぞれ１種又は２種以上を選択して配合することが可能である。 In addition to the above-described components, the rod-shaped cosmetic of the present invention can be blended with components other than those described above within a range not impairing the effects of the present invention. Oily raw materials other than the above, waxes, surfactants, preservatives, antioxidants, thickeners, whitening agents, fragrances, moisturizers, skin protective agents, and the like can be appropriately selected and added according to the purpose of use. Moreover, these arbitrary components can be blended by selecting one kind or two or more kinds, respectively.
本発明の棒状化粧料は、前記成分を配合して、常法に従って処理することにより得ることができる。特に制限されるものではないが例えば、液状及び固形の油性成分を加熱溶解した中に粉体を添加しロール機などで分散後、揮発性油剤とトリメチルシロキシケイ酸を添加し均一混合することで製造できる。更に棒状とするために、押し出し成型、溶融充填成型などの成型工程が行われるが、揮発性油剤を含むため、特に金型を用いた溶融充填成型、または筒状容器への直接溶融充填成型が好ましい。本発明の棒状化粧料は、例えば、アイブロウ、アイライナー、リップライナー、コンシーラーペンシル、アイシャドウペンシル等に適しているが、これに限定されるものではない。 The stick-shaped cosmetic of the present invention can be obtained by blending the above components and treating them according to a conventional method. Although not particularly limited, for example, by adding powder to a liquid and solid oily component dissolved by heating and dispersing with a roll machine, etc., adding a volatile oil and trimethylsiloxysilicic acid and mixing them uniformly Can be manufactured. Furthermore, in order to make it into a rod shape, molding processes such as extrusion molding and melt filling molding are performed, but since it contains a volatile oil agent, melt filling molding using a mold or direct melt filling molding into a cylindrical container is particularly performed. preferable. The bar-shaped cosmetic of the present invention is suitable for, for example, eyebrow, eyeliner, lip liner, concealer pencil, eyeshadow pencil, etc., but is not limited thereto.
更に、本発明の棒状化粧料は成型性が良好で、使用時の伸びが良く塗布後のべたつきもない等使用性が良好でありながら、耐衝撃性も優れるため繰り出して使用するペンシル型化粧製品または鉛筆型の化粧製品など細長い形状の化粧製品に用いる棒状化粧料に好適である。棒状化粧料の形状は、円柱状、楕円断面の棒状、矩形断面の棒状など特に限定されないが、断面の直径または断面の中心を通過する最短部径が１〜１０ｍｍであり、長さが２０〜２００ｍｍの形状に成型される棒状化粧料に特に好適である。また、断面の直径または断面の中心を通過する最短部径と長さの比率が１：８以上である細長い形状の棒状化粧料には更に好適である。 Furthermore, the stick-shaped cosmetic product of the present invention has good moldability, good elongation such as good stickiness after application and good usability, and excellent impact resistance. Or it is suitable for the stick-shaped cosmetics used for elongated cosmetic products such as pencil-shaped cosmetic products. The shape of the bar-shaped cosmetic is not particularly limited, such as a columnar shape, a bar shape having an elliptical cross section, a bar shape having a rectangular cross section, but the shortest diameter passing through the cross section diameter or the center of the cross section is 1 to 10 mm and the length is 20 to 20 mm. It is particularly suitable for stick-shaped cosmetics molded into a 200 mm shape. Moreover, it is more suitable for the elongate rod-shaped cosmetics whose ratio of the shortest part diameter and length which passes the center of a cross section or a cross section is 1: 8 or more.
以下、実施例を挙げて本発明を具体的に説明するが、本発明は下記の実施例に限定されるものではない。配合量は重量％である。実施例の説明に先立ち本発明で用いた効果試験方法について説明する。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated concretely, this invention is not limited to the following Example. The blending amount is% by weight. Prior to the description of the examples, the effect test method used in the present invention will be described.
［充填成型性］金型に溶融充填を行い冷却固化させた後、取り出した棒状化粧料の状態を目視にて判定した。
◎；良好
○；化粧料表面に若干のキズ
△；若干の曲がり、欠け
×；不良（流れ込まない、金型から取り出せない、折れ）
[Filling and moldability] After the mold was melt-filled and cooled and solidified, the state of the taken-out bar-shaped cosmetic was visually determined.
◎; Good ○; Slight scratch on the cosmetic surface △; Slight bend, chipping ×: Poor (does not flow, cannot be removed from mold, bent)
［硬さ］成型された棒状化粧料をレオメーター（不動工業株式会社製）にて、支点間距離２０ｍｍにて折損荷重を測定する。棒状化粧料の硬さは、その断面の直径や形状により適度な折損荷重値は異なるが、表１、２の実施例及び比較例は使用感触、使用時の折れなどを考慮し以下の基準で判定した
○；０．２５Ｎ〜０．４５Ｎ
△；０．１５Ｎ〜０．２４Ｎまたは０．４６Ｎ〜０．５５Ｎ
×；０．１４Ｎ以下または０．５６Ｎ以上
[Hardness] Using a rheometer (manufactured by Fudo Kogyo Co., Ltd.), measure the breaking load of the molded bar-shaped cosmetic at a distance between fulcrums of 20 mm. The hardness of the bar-shaped cosmetics varies depending on the diameter and shape of the cross-section, but the values of the appropriate breakage load are different, but the examples and comparative examples in Tables 1 and 2 are based on the following criteria in consideration of the feel of use and the bending during use. Judged: 0.25N to 0.45N
Δ: 0.15N to 0.24N or 0.46N to 0.55N
X: 0.14 N or less or 0.56 N or more
［耐衝撃性］成型された棒状化粧料を繰り出し式ペンシル容器に装着し２５℃２４時間静置後、５０ｃｍの高さから５回水平落下したものを目視にて判定した。
◎；異常なし
○；微かな曲がり
△；少量の欠け、曲がり（容器から繰り出し可能）
×；折れ、曲がり（容器から繰り出し不能）
[Impact resistance] The molded stick-shaped cosmetic was attached to a pay-out pencil container and allowed to stand at 25 ° C. for 24 hours.
◎; No abnormality ○; Slight curve
Δ: Small amount of chipping or bending (can be fed out of the container)
×: Folded, bent (cannot be fed out of the container)
［耐二次付着］バイオスキンプレート（ビューラックス社製）上、１ｃｍ×３ｃｍに均一となるよう塗布し、１０分後、塗布部に紙を押圧し化粧料の付着を目視にて判定した。
◎；紙への付着無し
○；紙に微量の付着
△；紙に少量の付着
×；塗布した化粧料の半分以上が紙に付着
[Secondary anti-adhesion] On a bioskin plate (manufactured by Beaulux Co., Ltd.), it was applied uniformly to 1 cm × 3 cm, and after 10 minutes, the paper was pressed against the application part, and the adhesion of the cosmetic was visually determined.
◎: No adhesion to paper ○: Small amount of adhesion to paper △; Small amount of adhesion to paper ×: More than half of applied cosmetics adhere to paper
［使用テスト］伸展性（塗布時の伸展性の良さ）、べたつき（塗布時及び直後のべたつきのなさ）、化粧持ち（化粧持ちの良さ）、使用時の状態（塗布時に棒状化粧料の崩れ、ぐずつきのなさ）の評価項目それぞれについて、１０人の専門パネルによる使用性テストを行い、１〜５点の５段階評価の平均点を求め下記評価基準に基づいて判定した。 [Usage test] extensibility (good extensibility during application), stickiness (no stickiness at the time of application and immediately after application), makeup (goodness of makeup), condition during use (disintegration of stick-shaped cosmetics during application, For each of the evaluation items, the usability test was conducted with 10 expert panels, and an average score of 1 to 5 points was evaluated based on the following evaluation criteria.
［評価基準］
◎；平均点４．０点以上。
○；平均点３．０点以上、４．０点未満。
△；平均点２．０点以上、３．０点未満。
×；平均点２．０点未満。
[Evaluation criteria]
A: Average score of 4.0 points or more.
A: Average score of 3.0 points or more and less than 4.0 points.
Δ: An average score of 2.0 points or more and less than 3.0 points.
X: Average point less than 2.0 points.
表１〜２に示す組成からなる油性固形化粧料を調整しこれを評価試料として前記評価方法に基づき、各評価項目に判定を実施した。その結果を併せて表１〜２に示す。 The oily solid cosmetic material having the composition shown in Tables 1 and 2 was prepared, and this was used as an evaluation sample, and each evaluation item was determined based on the evaluation method. The results are also shown in Tables 1 and 2.
（調整法）実施例１〜４及び比較例１〜１０を以下の方法で調整した。（１）〜（１６）を加熱溶解し、（１７）〜（２１）を加えロール機にて均一に分散混合した後、（２２）〜（２５）を添加し混合撹拌した。次いで、これを脱泡後、金型に充填し、冷却後、金型から取り出し直径３ｍｍ、長さ２５ｍｍのアイライナーを成型した。 (Adjustment method) Examples 1-4 and Comparative Examples 1-10 were adjusted by the following method. (1) to (16) were dissolved by heating, (17) to (21) were added and uniformly dispersed and mixed by a roll machine, and then (22) to (25) were added and mixed and stirred. Next, after defoaming, it was filled in a mold, cooled, and then taken out from the mold to form an eyeliner having a diameter of 3 mm and a length of 25 mm.
なお、表１〜２に示される（注１）〜（注４）の原料については、それぞれ下記の市販品を使用した。
（注１） ＰＥＲＦＯＲＭＡＬＥＮＥ４００；ニューフェーズテクノロジー社製（平均分子量４００）
（注２） ＰＥＲＦＯＲＭＡＬＥＮＥ５００；ニューフェーズテクノロジー社製（平均分子量５００）
（注３） ＰＥＲＦＯＲＭＡＬＥＮＥ６５５；ニューフェーズテクノロジー社製（平均分子量６５５）
（注４） トリメチルシロキシケイ酸（６０％）イソドデカン（４０％）混合物；信越化学工業社製
（注５） トリメチルシロキシケイ酸（５０％）デカメチルシクロペンタシロキサン（５０％）混合物；信越化学工業社製
（注６） デカメチルシクロペンタシロキサン；信越化学工業社製
In addition, about the raw material of (Note 1)-(Note 4) shown by Table 1-2, the following commercial item was used, respectively.
(Note 1) PERFORMALENE 400; manufactured by New Phase Technology (average molecular weight 400)
(Note 2) PERFORMALENE 500; manufactured by New Phase Technology (average molecular weight 500)
(Note 3) PERFORMALENE 655; manufactured by New Phase Technology (average molecular weight 655)
(Note 4) Trimethylsiloxysilicate (60%) isododecane (40%) mixture; manufactured by Shin-Etsu Chemical Co., Ltd. (Note 5) Trimethylsiloxysilicate (50%) decamethylcyclopentasiloxane (50%) mixture; Shin-Etsu Chemical (Note 6) Decamethylcyclopentasiloxane; manufactured by Shin-Etsu Chemical Co., Ltd.
表１より、トリメチルシロキシケイ酸、揮発性油剤を用いた従来の処方である比較例１は、化粧持ち、耐二次付着性は良好であるが、耐衝撃性に劣り、塗布時に棒状化粧料が崩れやすいものであった。それらの欠点を踏まえ、比較例２〜６では半固形油剤、高粘度油剤、油溶性ゲル化剤を用いているが、耐衝撃性に向上は見られず、化粧持ち、耐二次付着性は比較例１よりも劣るものであった。 From Table 1, Comparative Example 1, which is a conventional formulation using trimethylsiloxysilicic acid and a volatile oil, has a long-lasting makeup and good secondary adhesion resistance, but is inferior in impact resistance and stick-shaped cosmetic when applied. Was easy to collapse. Considering those drawbacks, Comparative Examples 2 to 6 use a semi-solid oil agent, a high-viscosity oil agent, and an oil-soluble gelling agent, but no improvement is seen in impact resistance, makeup holding, secondary adhesion resistance is It was inferior to Comparative Example 1.
しかしながら、表１〜２から判るように本発明に関わる実施例１〜４は、化粧持ち、耐二次付着性に優れ、耐衝撃性に於いても優れており、他の全ての評価項目に於いても良好であった。 However, as can be seen from Tables 1 and 2, Examples 1 to 4 according to the present invention have a cosmetic durability, excellent secondary adhesion resistance, and excellent impact resistance. It was also good.
以下に本発明の処方例を挙げる。 The formulation example of this invention is given to the following.
［実施例５］アイブロウ
（配合成分） （重量％）
（１）ポリエチレンワックス（注１） １２．０
（２）パラフィンワックス ８．０
（３）カルナウバワックス ３．０
（４）ミツロウ ３．０
（５）マイクロクリスタリンワックス ２．０
（６）キャンデリラロウ １０．０
（７）トリイソステアリン酸グリセリル ２．０
（８）イソノナン酸イソノニル ２．９６
（９）天然ビタミンＥ ０．０４
（１０）無水ケイ酸 １．０
（１１）ポリメタクリル酸メチル ３．０
（１２）合成マイカ ２４．０
（１３）黒酸化鉄 ４．１
（１４）黄酸化鉄 ３．５
（１５）ベンガラ ２．０
（１６）酸化チタン ０．４
（１７）Ｘ−２１−５５９５（注４） １０．０
（１８）イソドデカン ９．０
（製法）（１）〜（９）を加熱溶解し、（１０）〜（１６）を加えロール機にて均一に分散混合した後、（１７）〜（１８）を添加し混合撹拌した。次いで、これを脱泡後、金型に充填し、冷却後、金型から取り出して、短径２ｍｍ、長径３ｍｍの楕円断面を有し、長さ２５ｍｍのアイブロウを成型した。
[Example 5] Eyebrow (blending component) (wt%)
(1) Polyethylene wax (Note 1) 12.0
(2) Paraffin wax 8.0
(3) Carnauba wax 3.0
(4) Beeswax 3.0
(5) Microcrystalline wax 2.0
(6) Candelilla wax 10.0
(7) Glyceryl triisostearate 2.0
(8) Isononyl isononanoate 2.96
(9) Natural vitamin E 0.04
(10) Silicic anhydride 1.0
(11) Polymethyl methacrylate 3.0
(12) Synthetic mica 24.0
(13) Black iron oxide 4.1
(14) Yellow iron oxide 3.5
(15) Bengala 2.0
(16) Titanium oxide 0.4
(17) X-21-5595 (Note 4) 10.0
(18) Isododecane 9.0
(Production method) (1) to (9) were dissolved by heating, (10) to (16) were added, and the mixture was uniformly dispersed and mixed in a roll machine, and then (17) to (18) were added and mixed and stirred. Next, after defoaming, the mold was filled, cooled, and then taken out from the mold to form an eyebrow having an elliptical cross section with a minor axis of 2 mm and a major axis of 3 mm and a length of 25 mm.
上記実施例５のアイブロウは、化粧持ち、耐二次付着性に優れ、耐衝撃性に於いても優れており、他の全ての評価項目に於いても良好であった。 The eyebrow of Example 5 described above had good makeup, excellent secondary adhesion resistance, excellent impact resistance, and was excellent in all other evaluation items.
［実施例６］リップライナー
（配合成分） （重量％）
（１）ポリエチレンワックス（注１） １０．０
（２）パラフィンワックス ４．０
（３）カルナウバワックス ２．５
（４）ミツロウ ２．０
（５）マイクロクリスタリンワックス ５．０
（６）ショ糖脂肪酸エステル ３．５
（７）ダイマージリノール酸（フィトステリル／イソステアリル
／セチル／ステアリル／ベヘニル） １．０
（８）トリ（カプリル酸／カプリン酸／ミリスチン酸／ステア
リン酸）グリセリル ２．０
（９）流動パラフィン １１．９６
（１０）イソステアリン酸ソルビタン １．０
（１１）天然ビタミンＥ ０．０４
（１２）無水ケイ酸 ２．０
（１３）ポリメタクリル酸メチル ３．０
（１４）シリコーン処理セリサイト １．５
（１５）雲母チタン ２．０
（１６）黒酸化鉄 ４．５
（１７）黄酸化鉄 ３．５
（１８）ベンガラ １１．０
（１９）酸化チタン ０．５
（２０）赤色２０２号 ２．０
（２１）Ｘ−２１−５５９５（注４） １２．０
（２２）イソドデカン １５．０
（製法）配合成分（１）〜（１１）を加熱溶解し、（１２）〜（２０）を加えロール機にて均一に分散混合した後、（２１）〜（２２）を添加し混合撹拌した。次いで、これを脱泡後、樹脂製円筒軸（内径５mm長さ２００mm）に直接充填し鉛筆型リップライナーを得た。
[Example 6] Lip liner
(Compounding ingredients) (wt%)
(1) Polyethylene wax (Note 1) 10.0
(2) Paraffin wax 4.0
(3) Carnauba wax 2.5
(4) Beeswax 2.0
(5) Microcrystalline wax 5.0
(6) Sucrose fatty acid ester 3.5
(7) Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 1.0
(8) Tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl 2.0
(9) Liquid paraffin 11.96
(10) Sorbitan isostearate 1.0
(11) Natural vitamin E 0.04
(12) Silicic anhydride 2.0
(13) Polymethyl methacrylate 3.0
(14) Silicone-treated sericite 1.5
(15) Mica titanium 2.0
(16) Black iron oxide 4.5
(17) Yellow iron oxide 3.5
(18) Bengala 11.0
(19) Titanium oxide 0.5
(20) Red 202 No. 2.0
(21) X-21-5595 (Note 4) 12.0
(22) Isododecane 15.0
(Manufacturing method) Compounding components (1) to (11) are dissolved by heating, (12) to (20) are added and uniformly dispersed and mixed in a roll machine, and then (21) to (22) are added and mixed and stirred. . Next, after defoaming, it was directly filled into a resin cylindrical shaft (inner diameter 5 mm, length 200 mm) to obtain a pencil-type lip liner.
上記の実施例６の鉛筆型リップライナーは、化粧持ち、耐二次付着性に優れ、耐衝撃性に於いても優れており、他の全ての評価項目に於いても良好であった。また、シャープナーでの切削においても、欠け、崩れ等なく良好であった。 The pencil-type lip liner of Example 6 described above had good makeup, excellent secondary adhesion resistance, excellent impact resistance, and was excellent in all other evaluation items. In addition, cutting with a sharpener was good with no chipping or collapse.
［実施例７］コンシーラーペンシル
（配合成分） （重量％）
（１）セレシン ４．０
（２）マイクロクリスタリンワックス ３．０
（３）カルナウバワックス １．０
（４）ミツロウ １．０
（５）ポリエチレンワックス（注１） ６．５
（６）キャンデリラロウ ２．０
（７）ジカプリン酸プロピレングリコール １５．０
（８）スクワラン ３．０
（９）ジメチルポリシロキサン（６ｃｓ） ３．０
（１０）イソステアリン酸ソルビタン １．０
（１１）天然ビタミンＥ ０．０５
（１２）シリコーン処理マイカ ３．９
（１３）シリコーン処理酸化チタン ９．０
（１４）シリコーン処理黄酸化鉄 １．２５
（１５）シリコーン処理ベンガラ ０．２５
（１６）シリコーン処理黒酸化鉄 ０．０５
（１７）ナイロンパウダー １０．０
（１８）無水ケイ酸 １．０
（１９）合成マイカ ５．０
（２０）ポリメタクリル酸メチル １０．０
（２１）Ｘ−２１−５５９５（注４） １０．０
（２２）イソドデカン １０．０
（製法）配合成分（１）〜（１１）を加熱溶解し、（１２）〜（２０）を加えロール機にて均一に分散混合した後、（２１）〜（２２）を添加し混合撹拌した。次いで、これを脱泡後、樹脂製円筒軸（内径１０mm長さ９０mm）に直接充填し鉛筆型コンシーラーを得た
[Example 7] Concealer pencil (blending component) (wt%)
(1) Ceresin 4.0
(2) Microcrystalline wax 3.0
(3) Carnauba wax 1.0
(4) Beeswax 1.0
(5) Polyethylene wax (Note 1) 6.5
(6) Candelilla wax 2.0
(7) Propylene glycol dicaprate 15.0
(8) Squalane 3.0
(9) Dimethylpolysiloxane (6cs) 3.0
(10) Sorbitan isostearate 1.0
(11) Natural vitamin E 0.05
(12) Silicone-treated mica 3.9
(13) Silicone-treated titanium oxide 9.0
(14) Silicone-treated yellow iron oxide 1.25
(15) Silicone-treated Bengala 0.25
(16) Silicone-treated black iron oxide 0.05
(17) Nylon powder 10.0
(18) Silicic anhydride 1.0
(19) Synthetic mica 5.0
(20) Polymethyl methacrylate 10.0
(21) X-21-5595 (Note 4) 10.0
(22) Isododecane 10.0
(Manufacturing method) Compounding components (1) to (11) are dissolved by heating, (12) to (20) are added and uniformly dispersed and mixed in a roll machine, and then (21) to (22) are added and mixed and stirred. . This was then degassed and directly filled into a resin cylindrical shaft (inner diameter 10 mm, length 90 mm) to obtain a pencil-type concealer.
上記の実施例７の鉛筆型コンシーラーは、化粧持ち、耐二次付着性に優れ、耐衝撃性に於いても優れており、他の全ての評価項目に於いても良好であった。また、シャープナーでの切削においても、欠け、崩れ等なく良好であった。
The pencil-type concealer of Example 7 described above had good makeup, excellent secondary adhesion resistance, excellent impact resistance, and was excellent in all other evaluation items. In addition, cutting with a sharpener was good with no chipping or collapse.
Claims (2)
The stick cosmetic according to claim 1, wherein (b) the volatile oil is a hydrocarbon oil.
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| JP4906040B2 (en) * | 2004-08-24 | 2012-03-28 | 株式会社 資生堂 | Oily cosmetics |
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