JP6334184B2 - Oily solid cosmetic - Google Patents

Description

  The present invention relates to an oily solid cosmetic, and more particularly, to a cosmetic that is difficult to transfer color, has a long makeup, and has excellent filling moldability.

In recent years, in oily solid cosmetics such as lipsticks, in addition to the color consistency over time, an effect that the lipstick applied to the lips does not easily transfer to a cup or clothes is also required as an important quality.
Therefore, various studies have been made to realize the effect of color retention over time and the difficulty of color transfer. For example, a technology (Patent Document 1) relating to a lipstick composition excellent in feeling of use, makeup feeling and color transfer prevention, combining volatile silicone oil and dimethylsilyl silicic anhydride and powder, methylphenyl silicone and hydrogenated polyisobutene, There has been a technique for a lip cosmetic (Patent Document 2) that combines a lipophilic surfactant, exhibits a secondary adhesion-less effect immediately after application, and has a long lasting gloss.

JP-A-8-92036 JP 2011-140481 A

  However, in the technique of Patent Document 1, the film obtained after the volatile oil has volatilized has a strong feeling and is not satisfactory in gloss. Moreover, in the technique of patent document 2, although the decorative film is divided into two layers after application, a secondary adhesion-less effect is produced, but the color retention with time is not sufficient.

  An object of the present invention is to provide an oily solid cosmetic material that is less likely to transfer color, has excellent color and gloss makeup, and has good filling moldability.

As a result of intensive studies, the present inventors have found that dimethicodiethylbenzalmalonate improves the compatibility between methylphenylpolysiloxane and ester oil, and the hydrocarbon wax and ester oil liquid at 25 ° C. Completed the present invention, which is an oily solid cosmetic containing polysiloxane and dimethicodiethylbenzalmalonate, having excellent filling moldability, difficult to transfer during application, and having excellent gloss and gloss durability. .

That is, the present invention provides the following components (A) (B) (C) (D);
(A) hydrocarbon wax (B) ester oil which is liquid at 25 ° C. (C) methylphenylpolysiloxane (D) dimethicodiethylbenzalmalonate ,
The component (B) is one or two selected from glyceryl tri-2-ethylhexanoate, diglyceryl triisostearate, diglyceryl diisostearate, cetyl 2-ethylhexanoate, diisostearyl malate, and isotridecyl isononanoate It is an oily solid cosmetic that is a combination of more than one species .

Contains hydrocarbon wax, liquid ester oil at 25 ° C, methylphenylpolysiloxane and dimethicodiethylbenzalmalonate, has excellent filling moldability, does not easily transfer, and has excellent color and gloss makeup An oily solid cosmetic is provided.

Hereinafter, the present invention will be described in detail.
The component (A) hydrocarbon waxes of the present invention include those of synthetic and natural origin, but can be used without particular limitation as long as they are used in cosmetics. Specific examples include (ethylene / propylene) copolymer, Fischer-Tropsch wax, microcrystalline wax, polyethylene wax, ozokerite wax, paraffin wax, and ceresin wax. As these commercially available products, EPS wax (melting point: 90 to 99 ° C .: manufactured by Nippon Natural Products), EP-700 (melting point: 90 to 99 ° C .: manufactured by Baker Petrolite), PERFORMALENE 500 (melting point: 83 to 92 ° C .: new phase) Technology Corp.), PERFORMALENE 655 (melting point 96-102 ° C .: New Phase Technology Corp.), CIREBELLE 109L (melting point 91-96 ° C .: CIREBELLE Corp.), CIREBELLE 108 (melting point 79-84 ° C .: CIREBELLE Corp.), MULTIWAX Examples thereof include W445 (melting point: 76 to 82 ° C .: SONNEBORN, LLC). Of these, (ethylene / propylene) copolymer and Fischer-Tropsch wax are preferable in terms of gloss and adhesion of the decorative film. In addition, the component (A) having a melting point of 70 to 110 ° C. is preferable in terms of a feeling of use that is light and spread and a glossy feeling of the decorative film. The melting point in the present invention is measured based on “Measuring Method of Melting Point of Quasi-drug Standard General Test Method”.

In this invention, a component (A) can be used 1 type or in combination of 2 or more types as needed, 1 to 20% of content is preferable and 1 to 15% is more preferable. Within this range, it is possible to obtain an oily solid cosmetic material that has a light and stretchy feel and is excellent in filling moldability.

The component (B) liquid ester oil at 25 ° C. of the present invention has fluidity at 25 ° C. and is not particularly limited as long as it is used in cosmetics. Component (B) can be made into an oily solid cosmetic by dissolving with component (A) by heating and solidifying by cooling. Specifically, glyceryl tri-2-ethylhexanoate, glyceryl tri (capryl / caprate), glyceryl diisostearate, glyceryl triisostearate, diglyceryl triisostearate, diglyceryl diisostearate, diglyceryl tetraisostearate, decaisostearate Polyglyceryl acid, propylene glycol dicaprate, isotridecyl isononanoate, pentaerythritol tetra-2-ethylhexanoate, pentaerythritol tetraisostearate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, isopropyl myristate, isopropyl palmitate , Octyldodecyl myristate, isocetyl stearate, octyldodecyl oleate, neopenty dioctanoate Glycol, succinic di-2-ethylhexyl, diisostearyl malate, myristyl lactate, dialkyl carbonate, acetate liquid lanolin, trimellitic acid tritriacontanoic decyl, and diisopropyl dimer acid and the like. Although not particularly limited, glyceryl tri-2-ethylhexanoate, diglyceryl triisostearate, diglyceryl diisostearate, cetyl 2-ethylhexanoate, diisostearyl malate, and isotridecyl isononanoate are preferred in terms of stability. Examples of these commercially available products include MYRITOR GTEH (manufactured by BASF), T.I. I. O (Nisshin Oillio Group), Cosmall 43V (Nisshin Oilio Group), Cosmall 42V (Nisshin Oilio Group), Saracos 816T (Nisshin Oillio Group), Cosmall 222 (Nisshin Oillio Group) Co., Ltd.), Este Mall DISM (manufactured by National Mimatsu Co., Ltd.), Saracos 913 (manufactured by Nisshin Oilio Group Co., Ltd.) and the like.

In this invention, a component (B) can be used 1 type or in combination of 2 or more types. The content is preferably 20 to 60%, and more preferably 35 to 50%. Within this range, it is possible to obtain an oily solid cosmetic material that is excellent in filling moldability, is not smeared with makeup, and is particularly excellent in terms of filling moldability of the cosmetic material.

Component (C) methylphenyl polysiloxane of the present invention is one in which the methyl group of dimethylpolysiloxane is partially substituted with a phenyl group. Although it does not specifically limit to molecular weight or the number of phenyl groups, It is preferable that it is a thing exceeding refractive index 1.45, and it can give glossiness to cosmetics. Specific examples include phenylmethicone, phenyldimethicone, phenyltrimethicone, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, triphenyltrimethicone, trimethylpentaphenyltrisiloxane, and the like. As these commercial products, KF-54 (refractive index 1.50, kinematic viscosity at 25 ° C. 400 mm ² / s: manufactured by Shin-Etsu Chemical Co., Ltd.), KF-56 (refractive index 1.49, kinematic viscosity at 25 ° C. 15 mm ² / s). s: manufactured by Shin-Etsu Chemical Co., Ltd.), SH556FLUID (refractive index 1.46, 25 ° C. kinematic viscosity 22 mm ² / s: manufactured by Toray Dow Corning), PH-1555 (refractive index 1.58, 25 ° C. kinematic viscosity 175 mm ² / S: manufactured by Toray Dow Corning). In particular, when the refractive index exceeds 1.5 and the kinematic viscosity at 25 ° C. exceeds 300 mm ² / s, a coating film having a film thickness can be obtained, and a glossy feeling and a makeup-enhancing effect due to film formation are good. is there. The kinematic viscosity is measured by, for example, filling a measurement sample with a glass bottle having an outer diameter of 45 mm, an inner diameter of 38 mm, and a height of 82 mm so as not to generate an air space, and closing the sample in a 25 ° C. constant temperature bath. The following day, it is obtained by measuring with a single cylindrical rotational viscometer Bismetron (registered trademark) (manufactured by Shibaura System Co., Ltd.) using an attached No. 1-4 rotor at 0.3 to 30 rpm after 1 minute.

The component (C) methylphenylpolysiloxane in the present invention can be used singly or in combination of two or more as required, and the content is preferably 1 to 60%, more preferably 20 to 50%. Within this range, it is possible to obtain an oily solid cosmetic that is particularly excellent in terms of a glossy decorative film, resistance to color transfer, and good makeup durability.

  Component (D) Dimethicodiethylbenzalmalonate of the present invention has a chemical name: α- (trimethylsilyl) -ω- (trimethylsilyloxy) poly [oxy (dimethyl) silylene] -co- [oxy (methyl) (2- { p- [2,2-bis (ethoxycarbonyl) vinyl] phenoxy} -1-methyleneethyl) silylene] -co- [oxy (methyl) (2- {p- [2,2-bis (ethoxycarbonyl) vinyl] phenoxy} prop -1-enyl) silylene], an INCI name: Polysilicone-15, which is a silicone derivative in which about 7.5% of dimethicone having a chain length of about 60 is substituted with two kinds of substituents. PARSOL SLX (made by DSM NUTRITION PRODUCTS) can be illustrated as a commercial item.

  The content of component (D) in the present invention is preferably 1 to 30%, more preferably 5 to 15%. The above range is preferred in terms of imparting viscosity to the cosmetic material, producing smooth elongation and spreading, no blur of makeup, and stability of the cosmetic material.

In the present invention, the component (C) is a component that gives gloss to the decorative film, but tends to be incompatible with the components (A) and (B). While exhibiting the effect of making color transfer difficult, it may be difficult to form an oily solid cosmetic with good moldability. By combining component (D), the uniformity is improved when mixing components (A), (B), and (C), and a uniform and stable oily solid cosmetic is formed. A cosmetic with good makeup without gloss, color and bleeding can be obtained. When the component (C) and the component (D) are contained in the range of 3: 1 to 10: 1, these effects are more exhibited. The component (D), dimethicodiethylbenzalmalonate, is widely used as a UV-B absorber, but when combined with the components (A), (B), and (C), it is difficult to transfer color and is stable. It is not known that an oily solid cosmetic excellent in the quality can be obtained.

The oily solid cosmetic of the present invention may contain a component (E) colorant. If this is a colorant usually used in cosmetics, the shape of a sphere, plate, spindle, needle, etc., the particle size of fumes, fine particles, pigment grade, etc. The particle structure is not particularly limited, and inorganic pigments, organic pigments, glitter pigments, metals and the like can be used. Specific powders include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarine, and bengara, mica Titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide-coated mica, titanium dioxide-coated synthetic phlogopite, titanium dioxide-coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium, fish scale foil, dioxide Luminous pigments such as titanium coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc., red 201, red 202, Red 205 Organic pigment powders such as red 226, red 228, orange 203, orange 204, blue 404, yellow 401, red 3, red 104, red 106, orange 205, yellow 4 Organic powder powders such as zirconium, barium or aluminum lakes such as yellow No. 5, green No. 3 and blue No. 1 or metal powders such as aluminum powder, gold powder and silver powder, titanium oxide coated mica titanium, fine particle oxidation Examples thereof include composite powders such as zinc-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide. One or more kinds may be used as necessary. it can.

  These use one or more of fluorine compounds, silicone compounds, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. However, a colorant that has not been surface-treated with a fluorine-based compound or a silicone-based compound is preferable in order to exhibit a higher cosmetic lasting effect. The content of the colorant in the present invention is preferably from 0.1 to 12%, more preferably from 0.4 to 6%.

  In addition to the above-mentioned components, the oily solid cosmetic of the present invention is a component usually used in cosmetics, for example, an oily component as a base material or an emollient component, a powder as a touch adjustment, a powder dispersion or a touch adjustment. These surfactants, ultraviolet absorbers, humectants, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, and the like can be appropriately blended within a range that does not impair the effects of the present invention.

Oily components other than components (A) to (D) include hydrocarbons, fats and oils, regardless of the origin of animal oils, vegetable oils, synthetic oils, and the properties of solid oils, semisolid oils, liquid oils, etc. Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents.
Specifically, hydrocarbons such as liquid paraffin, squalane and petroleum jelly, fats and oils such as mole, olive oil, mink oil, macadamian nut oil, waxes other than component (A), waxes, jojoba oil, isopropyl palmitate , Octyldodecyl myristate, glyceryl tribehenate, cholesterol fatty acid ester, esters such as N-lauroyl-L-glutamate (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol , Higher alcohols such as behenyl alcohol, silicones such as fluorine-modified organopolysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin Isopropyl lanolate, lanolin derivatives such as lanolin alcohols, starch fatty acid esters, 12-hydroxystearic acid, oily gelling agents such as calcium stearate.

The powder component other than component (E) is particularly limited by the shape of a plate, spindle, needle, etc., the particle size of fumes, fine particles, pigment grade, etc., the particle structure of porous, nonporous, etc. Examples thereof include inorganic powders, organic powders, composite powders, and the like. Specific examples include inorganic powders such as silica, silicon carbide, and boron nitride, and organic powders such as magnesium stearate, zinc stearate, N-acyl lysine, polyethylene terephthalate, nylon, and silicone resin. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. A surface-treated product may be used.
For the purpose of improving the dispersibility of the powder, any surfactant that is commonly used in cosmetics can be used as the surfactant. Nonionic surfactants, anionic surfactants, cations Ionic surfactants, amphoteric surfactants and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples include polyether-modified organopolysiloxane and lecithin.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin and the like, for example, α-tocopherol, ascorbic acid, etc., as cosmetic ingredients, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., as antiseptics, for example, paraoxybenzoic acid ester, phenoxyethanol, 1 , 2-pentanediol, hexanediol and the like.

The oily solid cosmetic of the present invention is a cosmetic having an oily component as a continuous phase, and when it contains an aqueous component such as water, the aqueous component is dispersed in the oily component. The aqueous component is preferably 1% or less, more preferably 0.5% or less in the cosmetic. Further, the oily solid cosmetic of the present invention is not particularly limited, but is advantageous for makeup cosmetics containing a colorant because it is excellent in the effect of hardly causing color transfer. Specific examples include lip cosmetics such as lipstick and lip gloss, foundations, eye liners, eye colors, cheeks, and the like. Among these, lip cosmetics that easily transfer colors by eating and drinking, and stick-like oily solid cosmetics are preferable because the effects of the present invention become remarkable.

Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.
Examples 1 to 10 and Comparative Examples 1 to 3: Stick-shaped lipsticks Stick-shaped lipsticks having the formulations shown in Tables 1 and 2 below were prepared. (I) No color transfer, (b) Make-up (color / gloss) The following methods were used to evaluate goodness, (c) meltability and (d) filling moldability. The results are also shown in Tables 1 and 2.

* 1: PARSOL SLX (manufactured by DSM NUTRITION PRODUCTS)
* 2: KF-54 (Shin-Etsu Chemical Co., Ltd.)
* 3: KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: SH-556 FLUID (Toray Dow Corning)
* 5: EPS wax (manufactured by Nippon Natural Products)
* 6: MULTIWAX W445 (SONNEBORN, LLC)
* 7: PERFORMALEN 655 (manufactured by New Phase Technology)
* 8: Refined carnauba wax No. 1 (melting point: 80-86 ° C: manufactured by Nippon Natural Products)
* 9: Cosmol 43V (25 ° C liquid: Nisshin Oilio Co., Ltd.)
* 10: Cosmol 222 (25 ° C liquid: Nisshin Oilio Co., Ltd.)
* 11: High Coal K-350 (25 ° C liquid: Kaneda Corporation)
* 12: Saracos 913 (25 ℃ liquid: Nisshin Oillio Group)
* 13: Saracos 816T (25 ° C liquid: Nisshin Oillio Group)
* 14: T.W. I. O (25 ℃ liquid: Nisshin Oillio Group)
* 15: PLANDOOL-S (25 ° C semi- solid : manufactured by Nippon Seika Co., Ltd.)
* 16: UVINUL MC80 (25 ° C liquid: manufactured by BASF)

(Manufacturing method)
A. Ingredients (1) to (17) are uniformly dissolved at 100 ° C.
B. Add components (18) to (22) to A and mix uniformly.
C. B was dissolved and filled in a container at 90 ° C. and cooled and solidified to obtain a stick-shaped lipstick.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
(B) No color transfer (b) Good makeup (color / gloss) (c) Melting feeling (d) Filling moldability (b)-(c) For each sample, a specialized panel 20 The use test by name was conducted. Each panel member gave a rating based on the following absolute evaluation criteria and assigned a score. The average value of each sample was calculated from the total score of all the panels, and the determination was made according to the following criteria. For (a), use a coffee cup 10 minutes after application, and the shade of lip mark transferred to the cup. For (b), apply each sample and have the panel have a normal life. Then, for the feeling of use in which the color and gloss after 6 hours melt, (c), it was evaluated whether a sensation of changing from solid to liquid at the time of application was obtained. For (d), each molded sample was allowed to stand in a constant temperature bath at 35 ° C. for 1 hour, and then a rheometer (manufactured by Fudo Kogyo Co., Ltd., NRM-2002D) was used with a compression elastic stress adapter at a speed of 6 cm / min The bending load value of the stick was measured under the conditions described above, and the case where it was 20 or more was evaluated as ○.
<Absolute evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad <Criteria>
(Judgment): (Average score)
◎: Over 5 points: Very good ○: Over 3.5 points and 5 points or less: Good △: Over 1 point and 3.5 points or less: Slightly poor ×: 1 point or less: Defect

  As is apparent from the results in Tables 1 and 2, the stick-shaped lipsticks of Examples 1 to 10 of the present invention have no color transfer and good makeup (color / gloss) compared to the lipsticks of Comparative Examples 1 to 3. It was excellent in melting feeling and filling moldability. On the other hand, in Comparative Example 1 which does not contain the component (D), none of satisfactory results were obtained in terms of good color durability, no color transfer, filling moldability, and a feeling of melting. Further, Comparative Example 2 in which component (B) was replaced with hydrocarbon oil and Comparative Example 3 in which component (A) was replaced with ester wax were not satisfactory in terms of filling moldability.

Example 11 Gold Plate Filling Lipstick (Ingredient) (%)
(1) Polyethylene wax * 7 2
(2) Ethylene / propylene copolymer * 5 4
(3) Microcrystalline wax * 6 1
(4) Dimethicodiethylbenzalmalonate * 1 10
(5) Neopentyl glycol di-2-ethylhexanoate * 17 Residual amount (6) Cetyl 2-ethylhexanoate * 18 10
(7) Diphenyl dimethicone * 2 30
(8) Tori (Capryl / Caprin / Myristine / Stearic acid)
Glyceryl * 19 5
(9) N-lauroyl-L-glutamate di (phytosteryl,
2-octyldodecyl) * 20 1
(10) Tocopherol acetate 0.5
(11) Red No. 226 0.5
(12) Silylated silica anhydride * 21 2
(13) Bengala coated glass powder * 22 3
(14) Yellow iron oxide-coated mica titanium * 23 5

* 17: Cosmall 525 (25 ° C liquid: Nisshin Oillio Group)
* 18: Nikkor CIO (25 ° C liquid: manufactured by Nippon Surfactant Co., Ltd.)
* 19: Saracos 334 (25 ° C semi- solid : manufactured by Nisshin Oillio Group)
* 20: L-Du PS-203 (25 ° C liquid: Ajinomoto Co., Inc.)
* 21: AEROSIL R972 (manufactured by Nippon Aerosil Co., Ltd.)
* 22: Metashine MC1080TA (Nippon Sheet Glass Co., Ltd.)
* 23: TIMICA RADIANT GOLD (BASF)
(Production method)
A. Ingredients (1) to (10) are uniformly dissolved at 100 ° C.
B. A is added to components (11) to (14) and mixed uniformly.
C. B was dissolved and filled in a metal pan at 90 ° C. and cooled and solidified to obtain a lipstick.
The gold plate-filled lipstick obtained as described above was excellent in non-color transfer, good makeup (color / gloss), melted feeling of use, and filling moldability.

Example 12 Lip gloss (ingredient) (%)
(1) Dextrin palmitate * 24 0.5
(2) Polyethylene wax * 7 5
(3) Liquid paraffin * 11 5
(4) Dimethicodiethylbenzalmalonate * 1 10
(5) Diphenylsiloxyphenyl trimethicone * 3 20
(6) 2-Methylhexyl paramethoxycinnamate * 16 5
(7) Diisostearyl malate * 10 20
(8) polyglyceryl-2 * 9 triisostearate remaining amount (9) heavy liquid isoparaffin * 25 10
(10) Tori (Capryle / Caprin / Myristine / Stearic acid)
Glyceryl * 19 1
(11) Olive oil 1
(12) Dimethylpolysiloxane 5
(13) Bengala * 26 0.5
(14) Methylsiloxane network polymer * 27 2
(15) Polyethylene terephthalate / polymethyl
Methacrylate laminated powder * 28 5
(16) Phenoxyethanol 1

* 24: Leo Pearl KL2 (Chiba Flour Mills)
* 25: Pearl Dream 18 (manufactured by NOF Corporation)
* 26: Treatment with 2% methylhydrogenpolysiloxane * 27: Tospearl 2000B (Momotive Performance Materials Japan)
* 28: Aurora Flakes Blue 0.01 (Kakuhachi Fish Scale)
(Production method)
A. Ingredients (1) to (12) are uniformly dissolved at 100 ° C.
B. Add components (13) to (16) to A and mix evenly.
C. B was melt-filled in a resin dish at 90 ° C. and cooled and solidified to obtain a lip gloss.
The lip gloss obtained as described above was excellent in non-color transfer, good makeup (color / gloss), melting feel and filling moldability.

Example 13: Lip balm (ingredient) (%)
(1) Paraffin wax (melting point 56-61 ° C.) 12
(2) Candelilla wax (melting point 70-75 ° C.) 5
(3) Dimethicodiethylbenzalmalonate * 1 10
(4) Phenyl trimethicone * 4 25
(5) Vaseline 5
(6) Glyceryl tri-2-ethylhexanoate * 14 Residual amount (7) Mica 15
(8) Polymethyl methacrylate powder * 29 5
(9) Refined jojoba oil * 30 0.1
(10) Tocopherol acetate 0.5
(11) Rosemary extract * 31 0.05
(12) Bengala * 32 0.1
(13) Titanium oxide 0.2

* 29: MR-7GC (manufactured by Soken Chemical)
* 30: Refined jojoba oil (manufactured by Higher Alcohol Industry)
* 31: Rosemary extract BG (Maruzen Pharmaceutical Co., Ltd.)
* 32: Bengala Cloisonne (manufactured by Miyoshi Kasei)
(Production method)
A. Ingredients (1) to (6) are uniformly dissolved at 100 ° C.
B. Add components (7) to (13) to A and mix uniformly.
C. B was dissolved and filled in a container at 90 ° C., and cooled and solidified to obtain a lip balm.
The lip balm obtained as described above was excellent in color durability, an effect of preventing color transfer, a gloss, a feeling of melting, and a filling moldability.

Claims (6)

The following components (A) to (D);
(A) a hydrocarbon wax;
(B) an ester oil which is liquid at 25 ° C;
(C) methylphenylpolysiloxane;
(D) Dimethicodiethylbenzalmalonate;
Contain,
The component (B) is one or two selected from glyceryl tri-2-ethylhexanoate, diglyceryl triisostearate, diglyceryl diisostearate, cetyl 2-ethylhexanoate, diisostearyl malate, and isotridecyl isononanoate An oily solid cosmetic that is a combination of more than one species . Furthermore, the oil-based solid cosmetics of Claim 1 containing a component (E) coloring agent. The oily solid cosmetic according to claim 1 or 2, comprising 1 to 30% of the component (D). The oily solid cosmetic according to any one of claims 1 to 3, which is a makeup cosmetic. The oily solid cosmetic according to any one of claims 1 to 4, which is in a stick form. The content of the component (A) is 1 to 20%, the content of the component (B) is 20 to 60%, and the content of the component (C) is 1 to 60%. The oily solid cosmetic according to any one of claims 1 to 5 .