JP6184711B2 - Oily cosmetics - Google Patents

Description

  The present invention relates to an oily cosmetic, and more specifically, improves the adhesion of the coating film on the skin and lips after application, expresses the effect of long-lasting color and the effect of less color transfer, and improves the durability of gloss and gloss The present invention relates to a cosmetic that is excellent and does not have a feeling of tension in the coated film.

In recent years, in oily cosmetics such as lipsticks, in addition to the color consistency over time, an effect that the lipstick applied to the lips does not easily transfer to a cup or clothes is also required as an important quality.
Therefore, various studies have been made to realize the effect of color retention over time and the difficulty of color transfer. For example, a technique (Patent Document 1) using a surfactant such as polyether-modified silicone or polyglyceryl-modified silicone and an agar coating treatment pigment to improve the durability, uniformity, and feel of the makeup effect, and the effect of preventing makeup collapse In order to improve color development and adhesion, a technique of blending a bivalent or trivalent metal and salts thereof, a water-soluble salt of a divalent or trivalent metal hydroxide and alginic acid, and an oil component (Patent Document 2), secondary Technology that combines methylphenyl silicone, hydrogenated polyisobutene, and lipophilic surfactant to improve adhesion-less effect and gloss durability (Patent Document 3), secondary adhesion-less effect, smooth feeling of use, improved water retention In order to achieve this, there has been a technique (Patent Document 4) that combines a volatile oil and a water-repellent polymer.

Japanese Patent Laid-Open No. 2001-233738 Japanese Patent No. 2519186 Japanese Patent No. 4757950 JP-A-9-48709

  However, the decorative film obtained by the technique of Patent Document 1 has a weak effect of not causing color transfer and is not sufficiently glossy. Moreover, although the technique of patent document 2 was able to obtain the makeup-breaking prevention effect, it was not satisfactory in terms of usability and gloss. In the technique of Patent Document 3, the effect of preventing secondary adhesion is obtained by dividing the decorative film into two layers after application, but the color retention with time is not sufficient. In the technique of Patent Document 4, the film formed after the volatile oil evaporates gives a feeling of tension and is not sufficiently glossy.

  For this reason, there has been a demand for the development of an oily cosmetic material that has an effect of being good in color and difficult to transfer, has excellent gloss and gloss, and does not have a feeling of film stickiness.

  As a result of intensive studies, the present inventors paid attention to a phenomenon in which a specific ester oil of a specific polyhydric alcohol-modified silicone and an ester oil compatible with the same is phase-separated when water is added and mixed. I thought about applying this to oily cosmetics. That is, when a cosmetic containing a polyhydric alcohol-modified silicone and the specific ester oil is applied, the polyhydric alcohol-modified silicone and the ester oil are phase-separated on the skin due to moisture in the skin or moisture in the air. Thus, the gloss of the ester oil is improved, and the viscosity of the polyhydric alcohol-modified silicone is increased by moisture, so that the cosmetic film is strengthened and the makeup sustainability is improved, and the present invention has been completed.

That is, the present invention provides the following components (A), (B), (C) and (D);
(A) Polyhydric alcohol-modified silicone represented by the following general formula (5)
[However, wherein _{S x: -C 2 H 4 (} CH 3) 2 SiO [(CH 3) 2 SiO] p Si (CH 3) 3, Gly: -C 3 H 6 O [CH 2 CH (OH) _{CH 2 O] q H, k} = 30~50, l = 1~2, m = 1~5, n = 5~15, p = 3~9, a q = 1 to 5)] (B) 2 -At least one ester oil (C) colorant (D) at 25 ° C selected from the group consisting of cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate An oily cosmetic comprising an oil having a refractive index of 1.47 or more, wherein component (B) is compatible with component (A), but at 25 ° C., component (A) is 1 1 part by weight of water is added to a solution obtained by stirring and mixing 9 parts by weight of the component and the component (B). After stirring and mixing, when allowed to stand for 30 minutes, an oily cosmetic, characterized in that component (A) and component (B) is to phase separation;
The present invention also includes the following components (A), (B), (C) and (D);
(A) Polyhydric alcohol-modified silicone represented by the following general formula (5)
[However, wherein _{S x: -C 2 H 4 (} CH 3) 2 SiO [(CH 3) 2 SiO] p Si (CH 3) 3, Gly: -C 3 H 6 O [CH 2 CH (OH) _{CH 2 O] q H, k} = 30~50, l = 1~2, m = 1~5, n = 5~15, p = 3~9, a q = 1 to 5)] (B) 2 -At least one ester oil (C) colored at 25 ° C selected from the group consisting of cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate , diisostearyl malate, and neopentyl glycol di2-ethylhexanoate Agent (D) At least one selected from the group consisting of castor oil, liquid lanolin acetate, methylphenylpolysiloxane, sucrose fatty acid ester, 2-ethylhexyl paramethoxycinnamate, and tritridecyl trimellitate An oily cosmetic comprising an oil having a refractive index of 1.47 or more, wherein component (B) is compatible with component (A), but at 25 ° C., component (A) is 1 When 1 part by weight of water is added to a solution obtained by stirring and mixing 9 parts by weight of the component and the component (B), the mixture is stirred and mixed, and then left to stand for 30 minutes, the component (A) and the component (B) are in a phase. It is an oily cosmetic characterized by being separated.

(Wherein R1 is the same as above, g is an integer of 1 ≦ g ≦ 5, and h is an integer of 0 ≦ h ≦ 500).
a, b, and c represent 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]
(B) An oily cosmetic containing an ester oil (C) colorant that is liquid at 25 ° C, wherein component (B) is compatible with component (A), but component (A) is 1 part by weight and component An oily cosmetic characterized in that component (A) and component (B) are phase-separated when 1 part by weight of water is added to and mixed with 9 parts by weight of (B). is there.

  The present invention relates to an oily cosmetic, and more specifically, by applying to the skin, the adhesion of the coating film on the skin and lips is improved, and the effect of color durability and resistance to color transfer is exhibited. The present invention relates to a cosmetic that has excellent gloss durability and does not have a feeling of tension in the coated film.

Hereinafter, the present invention will be described in detail.
Component (A) in the Present Invention Polyhydric alcohol-modified silicone represented by the following average composition formula (1) R1 _a R2 _b R3 _c SiO _{(4-abc) / 2} (1)
[Wherein, R1 represents an alkyl group having 1 to 30 carbon atoms, an aryl group, an aralkyl group or a fluorine-substituted alkyl group, an amino-substituted alkyl group, a carboxy-substituted alkyl group, and the following general formula (2):
_{-C d H 2d -O- (C 2} H 4 O) e (C 3 H 6 O) f -R4 (2)
(In the formula, R4 is a hydrocarbon group having 4 to 30 carbon atoms, or an organic group represented by R5- (CO)-), and R5 is a carbon number. 1 to 30 hydrocarbon groups, d is an integer of 0 ≦ d ≦ 15, e and f are integers of 0 ≦ e ≦ 50 and 0 ≦ f ≦ 50, respectively).
R2 represents the following general formula (3)
-QOX (3)
(Wherein, Q represents a C 3-20 divalent hydrocarbon group that may contain at least one of an ether bond and an ester bond, and X represents a polyhydric alcohol-substituted carbon having at least two hydroxyl groups. Represents a hydrogen group),
R3 represents the following general formula (4)

(Wherein R1 is the same as above, g is an integer of 1 ≦ g ≦ 5, and h is an integer of 0 ≦ h ≦ 500).
a, b, and c represent 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]

  Component (A) has the property of significantly increasing the viscosity when a small amount of water is added. In the oily cosmetic composition of the present invention, it is increased by the moisture evaporated from the skin and lips when applied to the skin and the moisture in the environment. Stickiness, adhesion to skin and lips is improved, and the effect of long-lasting color and resistance to color transfer is exhibited.

Among them, in order to obtain the secondary adhesion of the effects of the present invention, R1 contains a long chain alkyl group (having 10 to 30 carbon atoms), R2 is _{-C 3 H 6 O [CH 2} CH (OH) CH 2 O] _j H (where j = 1 to 5) is preferable.
Although it does not specifically limit, INCI name which substituted a part of methyl group of the linear methylpolysiloxane represented by following General formula (5) with lauryl group, polyglycerin group, and methylpolysiloxane through carbon or oxygen Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone is particularly excellent in viscosity increase when water is added and is preferably used. A commercially available product is KF-6105 (manufactured by Shin-Etsu Chemical Co., Ltd.).

S _x : —C ₂ H ₄ (CH ₃ ) ₂ SiO [(CH ₃ ) ₂ SiO] _p Si (CH ₃ ) ₃
Gly: —C ₃ H ₆ O [CH ₂ CH (OH) CH ₂ O] _q H
(Wherein, k = 30 to 50, l = 1 to 2, m = 1 to 5, n = 5 to 15, p = 3 to 9, q = 1 to 5)

  In the present invention, the content of component (A) is preferably 0.5 to 30% by mass (hereinafter simply referred to as%) in the total oily cosmetic, and more preferably 1 to 10%. Within this range, effects such as a feeling of close contact with the skin and a long-lasting makeup are fully exhibited.

  The component (B) used in the oily cosmetic of the present invention is an ester oil that is liquid at 25 ° C. and dissolves the component (A) uniformly, but is separated from the component (A) by adding water. . In the oily cosmetic of the present invention, the component (B) and the component (A) are in a uniform dissolved phase, but when applied to the skin, the component (B) and the component (A) are caused by moisture from the skin or water in the air. ) Are separated, and the component (B) becomes the surface layer of the coating film, which exhibits the effect of good color retention and less color transfer. The component (B) is not particularly limited, and examples thereof include glyceryl tri-2-ethylhexanoate, cetyl 2-ethylhexanoate, isotridecyl isononanoate, diisostearyl malate, and dipentyl glycol di-2-ethylhexanoate. Of these, one or more of them can be used.

  Content of a component (B) is 0.5 to 90% with respect to cosmetics whole quantity, More preferably, it is 1 to 60%. If it is this range, the effect which is hard to carry out color transfer can express notably.

  Although the component (A) of the component (B) in this invention melt | dissolves uniformly, the ester oil agent which isolate | separates from a component (A) by adding water is the mass of a component (A) and a component (B). When the solution stirred and mixed at a ratio of 1: 9 is uniformly dissolved from transparent to translucent, then 1 part by weight of water is added to the solution, and after stirring and mixing, the components (A) and ( It can be visually confirmed that B) is separated. The result of having confirmed the mixed state with various ester oils using lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (KF-6105, Shin-Etsu Chemical Co., Ltd.) as a component (A) is shown below.

(Confirmation test)
At 25 ° C., the state of the solution obtained by stirring and mixing lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone and various ester oils at a mass ratio of 1: 9 was visually confirmed. Next, 1 part by weight of water was added to 10 parts by weight of the mixture, and the mixture was stirred and mixed. The results are shown in Table 1.

As shown in Table 1, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone is composed of cetyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, isotridecyl isononanoate, neopentyl glycol di-2-ethylhexanoate and diisosodium malate. Dissolved in stearyl and became a transparent homogeneous phase. When these were mixed with water and stirred and mixed, white turbid and thickened lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone phase became the lower layer, and the upper layer became the ester oil phase, and separation was confirmed. On the other hand, the mixture in which the ester oil was polyglyceryl triisostearate became cloudy as a whole, and a separated layer was confirmed in the lower layer.

The component (C) colorant used in the oily cosmetic of the present invention can contain a coloring material that is usually used in cosmetics.
Such a color material is not particularly limited as long as it is a color material usually used in cosmetics, and may be powdery or lake-like, and may be any of inorganic pigments, organic pigments, and pearl pigments. Although not particularly limited, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, lithium titanate Colored inorganic pigments such as cobalt and manganese violet, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, silicon dioxide, aluminum oxide, magnesium oxide, zirconium oxide, White body powders such as antimony oxide, aluminum silicate, magnesium magnesium silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, barium sulfate, hydrotalcite, hydroxyapatite, boron nitride, Titanium oxide coated mica, oxide Coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine treated mica titanium, titanium oxide coated synthetic phlogopite, titanium oxide coated glass powder, titanium oxide / iron oxide coated glass powder, bismuth oxychloride, fish scale foil, Bright powder such as polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, red 201, red 202, red 205, red 226, red Organic pigment powders such as No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Dyes such as Red No. 223, Red No. 218, Orange No. 201, Red No. 3, Red No. 104, Red 106 No., Orange No. 205, Yellow No. 4, Yellow No. 5, Green No., Blue No. 1 etc. zirconium, barium or aluminum lake and other organic pigment powder, aluminum powder, gold powder, silver powder and other metal powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated mica Examples of the composite powder include titanium, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide. These may be used alone or in combination of two or more. Moreover, you may use what carried out the surface treatment by the well-known method using a fluorine compound, a silicone type compound, metal soap, surfactant, a lecithin, an amino acid, an oil agent, a hydrocarbon.

  In the present invention, the component (C) is more easily wetted with the component (A) than the component (B), and thus the color material spontaneously shifts to the phase of the component (A). Therefore, the coloring material is held in the specific polyhydric alcohol-modified silicone of (A) at the time of applying cosmetics, and is present inside the component (B) of the surface layer, so that the effect of making the color transfer difficult is exhibited. Component (C) is preferably contained in an amount of 0.001 to 40%, more preferably 0.1 to 30%.

  The oily cosmetic of the present invention can further contain component (D) an oil having a refractive index of 1.47 or more at 25 ° C. The component (D) is present in the surface layer of the coating film together with the component (B), and can produce the gloss of the coating film. These oils include castor oil, liquid lanolin acetate, polybutene, hydrogenated polyisobutene, methylphenylpolysiloxane, sucrose fatty acid ester, 2-ethylhexyl paramethoxycinnamate, tritridecyl trimellitate, and the like. As these commercial products, Pearl Ream 18, Pearl Ream 24, Pearl Ream 46 (above, manufactured by Nippon Oil & Fats), purified polybutene HV-100F (SB) (manufactured by Nippon Natural Products), polybutene 35R, polybutene 100R, polybutene 2000H (Above, manufactured by Idemitsu Petrochemical Co., Ltd.), silicone KF-54, silicone KF50-300CS, silicone KF-54HV, silicone KF-56 (above, manufactured by Shin-Etsu Chemical Co., Ltd.), silicone SH556, FZ3156 (manufactured by Dow Corning Toray) ACELAN SP (manufactured by Croda Japan), LIPONATE TDTM (manufactured by LIPO CHEMICALS), and the like.

In the present invention, the content of component (D) is 1 to 50%, more preferably 1 to 30%, based on the total amount of the cosmetic. If it is this range, the durability of gloss and gloss is fully exhibited.
In addition to the above components (A), (B), and (C), the oily cosmetic of the present invention is a component usually used in cosmetics, for example, an oily component as a base material or an emollient component, and a powder as a touch adjustment. Does not impair the effects of the present invention, such as body, powder dispersion and feel adjustment surfactant, UV absorber, moisturizer, anti-fading agent, antioxidant, antifoaming agent, cosmetic ingredients, antiseptic, fragrance, etc. It can contain suitably in the range.

Oil components other than components (B) and (D) include hydrocarbons, fats and oils, regardless of the origin of animal oils, vegetable oils, synthetic oils, and properties such as solid oils, semi-solid oils, and liquid oils. Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents.
Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, polyethylene, montan wax, and Fischer-Tropsch wax, molasses, olive oil, mink oil, macadamian nut Fats and oils such as beeswax, beeswax, carnauba wax, candelilla wax, rice bran wax, gallows, jojoba oil, isopropyl palmitate, octyldodecyl myristate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, Cholesterol fatty acid esters, esters such as N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), stearyl Higher alcohols such as alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, silicones such as fluorine-modified organopolysiloxane, fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether Lanolin derivatives such as lanolin, lanolin fatty acid isopropyl and lanolin alcohol, starch fatty acid esters, oily gelling agents such as 12-hydroxystearic acid and calcium stearate, and the like.

The powder component is not particularly limited by the shape of plates, spindles, needles, etc., the particle size of fumes, fine particles, pigment grades, the particle structure of porous, nonporous, etc. , Organic powders, composite powders, and the like. Specifically, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, magnesium magnesium silicate, mica, synthetic mica, synthetic sericite, sericite , Inorganic powders such as talc, kaolin, silica, silicon carbide, barium sulfate, boron nitride, organic powders such as magnesium stearate, zinc stearate, N-acyl lysine, polyethylene terephthalate, nylon, titanium dioxide-containing silicon dioxide And composite powders such as zinc oxide-containing silicon dioxide. These may be used alone or in combination of two or more. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. A surface-treated product may be used.
For the purpose of improving the dispersibility of the powder, any surfactant that is commonly used in cosmetics can be used as the surfactant. Nonionic surfactants, anionic surfactants, cations Ionic surfactants, amphoteric surfactants and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl other than component (A) Examples include co-modified organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin and the like, for example, α-tocopherol, ascorbic acid, etc., as cosmetic ingredients, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., as antiseptics, for example, paraoxybenzoic acid ester, phenoxyethanol, 1 , 2-pentanediol and the like.

  The oily cosmetic of the present invention is not particularly limited, but is advantageous for make-up cosmetics because of its excellent color retention and excellent effect of preventing color transfer. Specific examples include lip cosmetics such as lipsticks and lip gloss, foundations, eye liners, eye colors, cheeks, and the like. In particular, the lips with a lot of moisture transpiration are easy to exert the effect, and the color durability, the effect of hardly transferring the color, the gloss, the adhesive force, and the lack of a feeling of film tension can be suitably used in the lipstick.

Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.
Examples 1-5 and Comparative Examples 1-4: Lipstick (solid)
Stick-shaped lipsticks having the formulations shown in Table 1 below were prepared and evaluated by the following methods. The results are also shown in Table 1.

* 1: KF-6105 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 2: KF-6015 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: MYLITTL GTEH (manufactured by BASF)
* 4: Cosmall 222 (Nisshin Oilio Co., Ltd.)
* 5: Purified polybutene HV-100F (SB) (manufactured by Nippon Natural Products)
* 6: LIPONATE TDTM (LIPO CHEMICALS)
* 7: Chimica Gold Sparkle (BASF)

(Manufacturing method)
A. Ingredients (1) to (10) are uniformly dissolved at 100 ° C.
B. Add components (11) to (15) to A and mix uniformly.
C. B was dissolved and filled in a stick container and cooled and solidified to obtain a lipstick.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
A. Good color b. No color transfer c. Tsuyani. Adhesive force e. With respect to the items (i) to (e) where there is no feeling of film tension, a use test was conducted by 20 specialist panels on each sample. Each panel member gave a rating based on the following absolute evaluation criteria and assigned a score. The average value of each sample was calculated from the total score of all the panels, and the determination was made according to the following 4-step criteria. In addition, each sample was apply | coated about the good color durability of a, and after having had a normal life on the panel, whether the color of the lipstick remained on the lip after 6 hours, etc. was evaluated. Regarding the lack of color transfer, 10 minutes after application, tea was served in a coffee cup and evaluated by the shade of the lip mark transferred to the cup. Regarding the adhesive strength of the film, it was evaluated whether it was possible to draw evenly or uniformly during application.
Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad 4-step criteria (judgment): (Average score)
◎: Over 5 points: Very good ○: Over 3.5 points and 5 points or less: Good △: Over 1 point and 3.5 points or less: Slightly poor ×: 1 point or less: Defect

As is clear from the results in Table 1, the lipsticks of Examples 1 to 5 of the present invention have better color durability, less resistance to color transfer, gloss, adhesion, and coating than the lipsticks of Comparative Examples 1 to 3. It was excellent in lack of feeling.
On the other hand, in Comparative Example 1 in which the component (A) was omitted, satisfactory results were not obtained in terms of good color retention, no color transfer, and adhesion. Moreover, even in Comparative Example 2 containing PEG-3 dimethicone instead of component (A), satisfactory results can be obtained in terms of good color retention, no color transfer, adhesion, and lack of film tension. There wasn't. In Comparative Example 3 containing polyglyceryl-2 triisostearate which does not show compatibility with component (A) instead of component (B), satisfactory results can be obtained in terms of color durability, non-transfer and gloss. There wasn't.

Example 6 Gold Plate Filling Lipstick (Solid)
(Ingredient) (%)
(1) Polyethylene wax 10
(2) Liquid paraffin 10
(3) Neopentyl glycol di-2-ethylhexanoate * 8 Residual amount (4) Cetyl 2-ethylhexanoate * 9 10
(5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 1
(6) Methylphenylpolysiloxane * 10 (refractive index 1.49) 30
(7) N-lauroyl-L-glutamic acid
Di (phytosteryl, 2-octyldodecyl) * 11 1
(8) Tocopherol acetate 0.5
(9) Red No. 226 0.5
(10) Silylated silica anhydride * 12 2
(11) Bengala coated glass powder * 13 3
(12) Yellow iron oxide coated mica titanium * 14 5
(13) Rosemary extract 0.1
(14) Fragrance 0.1

* 8: Cosmall 525 (Nisshin Oillio Group)
* 9: Nikkor CIO (Nippon Surfactant Kogyo Co., Ltd.)
* 10: Silicon KF-56 (Shin-Etsu Chemical Co., Ltd.)
* 11: El Dew PS-203 (Ajinomoto Co., Inc.)
* 12: AEROSIL R972 (manufactured by Nippon Aerosil Co., Ltd.)
* 13: Metashine MC1080TA (manufactured by Nippon Sheet Glass Co., Ltd.)
* 14: TIMICA RADIANT GOLD (BASF)
(Production method)
A. Ingredients (1) to (8) are uniformly dissolved at 100 ° C.
B. Add components (9) to (14) to A and mix uniformly.
C. B was dissolved and filled in a metal pan at 90 ° C. and cooled and solidified to obtain a lipstick.
The gold-plated lipstick obtained as described above was excellent in color durability, the effect of being difficult to transfer, gloss, adhesion, and lack of film tension.

Example 7 Lip Gloss (Liquid)
(Ingredient) (%)
(1) Dextrin palmitate 10
(2) Liquid paraffin 10
(3) Diisostearyl malate * 15 40
(4) Residual amount of polyglyceryl-2 triisostearate (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 0.5
(6) Heavy liquid isoparaffin * 16 (refractive index 1.49) 5
(7) Olive oil 1
(8) Dimethylpolysiloxane 5
(9) Bengala * 17 0.5
(10) Methylsiloxane network polymer * 18 2
(11) Polyethylene terephthalate / polymethyl methacrylate laminated powder 5
(12) Phenoxyethanol 1
(13) Fragrance 0.1

* 15: Cosmall 222 (Nisshin Oilio Co., Ltd.)
* 16: Pearl Dream 18 (Nippon Yushi Co., Ltd.)
* 17: Methyl hydrogen polysiloxane treated with 2% * 18: Tospearl 2000B (Momentive Performance Materials Japan)
(Production method)
A. Ingredients (1) to (8) are uniformly dissolved.
B. Add components (9) to (13) to A and mix uniformly.
C. B was filled into a container to obtain a lip gloss.
The lip gloss obtained as described above was excellent in color durability, an effect of hardly causing color transfer, gloss, adhesion, and lack of feeling of film tension.

Example 8 Lip Gloss (Liquid)
(Ingredient) (%)
(1) Silylated silicic acid * 12 5
(2) Liquid paraffin 10
(3) Diisostearyl malate * 15 40
(4) Residual amount of polyglyceryl-2 triisostearate (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 0.5
(6) Heavy liquid isoparaffin * 16 5
(7) Olive oil 1
(8) Dimethylpolysiloxane 5
(9) Bengala * 17 0.5
(10) Methylsiloxane network polymer * 18 2
(11) Polyethylene terephthalate / polymethyl methacrylate laminated powder 5
(12) Phenoxyethanol 1
(13) Natural vitamin E 0.1

(Production method)
A. Ingredients (1) to (8) are uniformly dissolved.
B. Add components (9) to (13) to A and mix uniformly.
C. B was filled into a container to obtain a lip gloss.
The lip gloss obtained as described above was excellent in color durability, an effect of hardly causing color transfer, gloss, adhesion, and lack of feeling of film tension.

Example 9 Foundation (solid)
(Ingredient) (%)
(1) Polyethylene wax 12
(2) Microcrystalline wax 3
(3) Diisostearyl malate * 4 10
(4) Liquid paraffin Residual amount (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 8
(6) 2-Methylhexyl paramethoxycinnamate * 19 (refractive index 1.5) 15
(7) Methyl paraoxybenzoate 0.5
(8) Sorbitan sesquioleate 0.5
(9) Oxybenzone 0.5
(10) Bengala 0.5
(11) Yellow iron oxide 2
(12) Titanium oxide 5
(13) Black iron oxide 0.1
(14) Silicic anhydride 0.5
(15) Hyaluronic acid 0.1

* 19: UVINUL MC80 (BASF)
(Production method)
A. Ingredients (1) to (9) are uniformly dissolved at 100 ° C.
B. Add components (10) to (15) to A and mix uniformly.
C. B was dissolved and filled in a container at 90 ° C., and then cooled and solidified to obtain a foundation.
The foundation obtained as described above was excellent in the color durability, the effect of hardly causing the color transfer, the gloss, the adhesive force, and the lack of a feeling of film tension.

Example 10 Eyeliner (component) (%)
(1) Silylated silica anhydride * 12 10
(2) Cetyl 2-ethylhexanoate * 10 20
(3) Isododecane remaining amount (4) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1
15
(5) Polybutene * 20 10
(6) Methyl paraoxybenzoate 0.3
(7) Polyoxyethylene sorbitan monooleate 0.5
(8) Trimethylsiloxysilicic acid 1
(9) Decamethylcyclopentasiloxane 1
(10) Carbon black 5
(11) Sericite * 21 5
(12) Rose extract 0.1
(13) Fragrance 0.1

* 20: Polybutene 2000H (made by Idemitsu Kosan Co., Ltd.)
* 21: Perfluoroalkyl phosphate diethanolamine 5% treatment (production method)
A. Ingredients (1) to (9) are uniformly dissolved at 100 ° C.
B. Add components (10) to (13) to A and mix uniformly.
C. B was filled into a container to obtain an liner.
The eyeliner obtained as described above was excellent in color durability, an effect of hardly causing color transfer, gloss, adhesion, and lack of a feeling of film tension.

Example 11 Eyeliner (solid)
(Ingredient) (%)
(1) Polyethylene wax 15
(2) Mowl 2
(3) Cetyl 2-ethylhexanoate * 10 20
(4) Residual amount of isododecane (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1
15
(6) Polybutene * 20 0.5
(7) Methyl paraoxybenzoate 0.3
(8) Polyoxyethylene sorbitan monooleate 0.5
(9) Trimethylsiloxysilicic acid 1
(10) Decamethylcyclopentasiloxane 1
(11) Carbon black 5
(12) Sericite * 21 5
(13) Fragrance 0.1

* 20: Polybutene 2000H (made by Idemitsu Kosan Co., Ltd.)
* 21: Treatment with 5% perfluoroalkyl phosphate diethanolamine salt (production method)
A. Ingredients (1) to (10) are uniformly dissolved at 100 ° C.
B. Add components (11) to (13) to A and mix uniformly.
C. B was dissolved and filled in a glass jar at 90 ° C. and cooled and solidified to obtain an eyeliner.
The eyeliner obtained as described above was excellent in color durability, an effect of hardly causing color transfer, gloss, adhesion, and lack of a feeling of film tension.

Example 12 Eye color (solid)
(Ingredient) (%)
(1) Paraffin wax 5
(2) Candelilla wax 3
(3) Glyceryl tri-2-ethylhexanoate * 3 10
(4) Residual amount of squalane (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 0.5
(6) Acetic acid liquid lanolin * 22 (refractive index 1.48) 1
(7) Ethyl paraoxybenzoate 0.3
(8) Sorbitan sesquioleate 0.5
(9) Natural vitamin E 0.1
(10) Blue No. 1 1
(11) Polyethylene terephthalate / aluminum / epoxy laminated powder 10
(12) Titanium-coated mica titanium * 23 5
(13) Mica titanium * 24 10
(14) Titanium oxide coated glass powder * 25 5

* 22: Acelan SP (manufactured by Croda Japan)
* 23: DUOCROME BG (manufactured by BASF)
* 24: Timilon Super Red (Merck), treated with 2% dimethylpolysiloxane * 25: Metashine MC1080RC-R (Nippon Sheet Glass)
(Production method)
A. Ingredients (1) to (9) are uniformly dissolved at 100 ° C.
B. Add components (10) to (14) to A and mix uniformly.
C. B was dissolved and filled in a metal pan at 90 ° C., and then cooled and solidified to obtain an eye color.
The eye color obtained as described above was excellent in the color durability, the effect of hardly causing the color transfer, the gloss, the adhesion, and the lack of a feeling of film tension.

Example 13 Teak color (solid)
(Ingredient) (%)
(1) Fischer-Tropsch wax 5
(2) Microcrystalline wax 8
(3) Glyceryl tri-2-ethylhexanoate * 3 10
(4) Propylene glycol dicaprate Residual amount (5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone * 1 5
(6) Acetic acid liquid lanolin * 22 (refractive index 1.48) 1
(7) Jojoba oil 1
(8) Dimethylpolysiloxane 5
(9) Macadamia nut oil 0.1
(10) Red No. 226 0.5
(11) Talc * 26 15
(12) Zinc oxide * 27 2
(13) Barium sulfate 1
(14) Phenoxyethanol 0.5

* 26: Dimethylpolysiloxane 2% treatment * 27: Methylhydrogenpolysiloxane 5% treatment (production method)
A. Ingredients (1) to 9) are uniformly dissolved at 100 ° C.
B. Add components (10) to (14) to A and mix uniformly.
C. B was melt-filled in a resin dish at 90 ° C. and cooled and solidified to obtain a cheek color.
The cheek color obtained as described above was excellent in the color durability, the effect of hardly transferring the color, the gloss, the adhesion, and the lack of a feeling of film tension.

Claims (5)

The following components (A), (B), (C) and (D);
(A) Polyhydric alcohol-modified silicone represented by the following general formula (5)
[However, wherein _{S x: -C 2 H 4 (} CH 3) 2 SiO [(CH 3) 2 SiO] p Si (CH 3) 3, Gly: -C 3 H 6 O [CH 2 CH (OH) _{CH 2 O] q H, k} = 30~50, l = 1~2, m = 1~5, n = 5~15, p = 3~9, a q = 1 to 5)] (B) 2 -At least one ester oil (C) colorant (D) at 25 ° C selected from the group consisting of cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate An oily cosmetic comprising an oil having a refractive index of 1.47 or more, wherein component (B) is compatible with component (A), but at 25 ° C., component (A) is 1 1 part by weight of water is added to a solution obtained by stirring and mixing 9 parts by weight of the component and the component (B). After stirring and mixing, when allowed to stand for 30 minutes, oil-based cosmetic, characterized in that component (A) and component (B) is to phase separation. The following components (A), (B), (C) and (D);
(A) Polyhydric alcohol-modified silicone represented by the following general formula (5)
[However, wherein _{S x: -C 2 H 4 (} CH 3) 2 SiO [(CH 3) 2 SiO] p Si (CH 3) 3, Gly: -C 3 H 6 O [CH 2 CH (OH) _{CH 2 O] q H, k} = 30~50, l = 1~2, m = 1~5, n = 5~15, p = 3~9, a q = 1 to 5)] (B) 2 -At least one ester oil (C) colored at 25 ° C selected from the group consisting of cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate , diisostearyl malate, and neopentyl glycol di2-ethylhexanoate Agent (D) At least one selected from the group consisting of castor oil, liquid lanolin acetate, methylphenylpolysiloxane, sucrose fatty acid ester, 2-ethylhexyl paramethoxycinnamate, and tritridecyl trimellitate An oily cosmetic comprising an oil having a refractive index of 1.47 or more, wherein component (B) is compatible with component (A), but at 25 ° C., component (A) is 1 When 1 part by weight of water is added to a solution obtained by stirring and mixing 9 parts by weight of the component and the component (B), the mixture is stirred and mixed, and then left to stand for 30 minutes, the component (A) and the component (B) are in a phase. An oily cosmetic characterized by being separated.   The oily cosmetic according to claim 1 or 2, wherein (A) is lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone.   The oily cosmetic according to any one of claims 1 to 3, comprising 0.5 to 30% by mass of the component (A).   The oily cosmetic according to any one of claims 1 to 4, wherein the oily cosmetic is a lip cosmetic.